IMPEDANCE METHODS FOR ANALYZING SURFACE PLASMONS Quirino Balzano, Igor Smolyaninov, and Christopher C. Davis Department of Electrical and Computer Engineering ●Classical solutions to Maxwell’s equations at the interface between a dielectric and a metal ●A metal is a dense electron-hole plasma ●A metal has a complex dielectric constant with a large negative part. ●For example, for gold at 632.8nm ε 2=-15.73-j0.968 Kretschman total internal reflection geometry for plasmon excitation Dielectric (absorber) layer IMPEDANCE TRANSFORMATION Plasmon resonances in gold revealed by an impedance analysis If a slab structure is modeled as a series of transmission lines then the impedance observed at the first interface, at location z= d relative to a final interface at z=0 is PLASMON RESONANCE WITH GOLD n=1.5 1.0 Z3 = Z2 " [ Z 3 cos(kd ) + jZ 2 sin(kd )] Z 2 cos(kd ) + jZ 3 sin(kd ) This approach can be applied in slab structures to analyze electromagnetic wave reflection and transmission 0.8 REFLECTANCE SURFACE PLASMONS Gold layer slab semi-infinite medium semi-infinite medium Z2 Z1 Z3" Surface layer thickness d=0 d=5nm d=10nm 0.6 Surface layer n=2.25 0.4 0.2 Impedance transformation reduces the number of interfaces by one Substrate The Maryland Optics Group 0.0 10 30 50 ANGLE (degrees) 70 90 The resonance angle is very sensitive to a surface layer on the gold Z3 PLASMON RESONANCE WITH GOLD n=1.5 1.0 n2 - air or dielectric surface wave (plasmon) semi-infinite medium ngold θ Z1 semi-infinite medium Z3" Z 3" − Z 1' ρ= " Z 3 + Z 1' E REFLECTANCE 0.8 0.6 Surface layer thickness d=0 d=5nm d=10nm Surface layer n=2.25 0.4 0.2 n1 - substrate For P(TM) waves Z ' = Z cos(θ ) 0.0 35 39 43 ANGLE (degrees) 47