IMPEDANCE METHODS FOR ANALYZING SURFACE PLASMONS Quirino Balzano, Igor Smolyaninov, and Christopher C. Davis Department of Electrical and Computer Engineering ●Classical solutions to Maxwell’s equations at the interface between a dielectric and a metal ●A metal is a dense electron-hole plasma ●A metal has a complex dielectric constant with a large negative part. ●For example, for gold at 632.8nm e2=-15.73-j0.968 Kretschman total internal reflection geometry for plasmon excitation Dielectric (absorber) layer IMPEDANCE TRANSFORMATION Plasmon resonances in gold revealed by an impedance analysis If a slab structure is modeled as a series of transmission lines then the impedance observed at the first interface, at location z= d relative to a final interface at z=0 is PLASMON RESONANCE WITH GOLD n=1.5 1.0 0.8 [ Z 3 cos( kd ) jZ 2 sin( kd )] Z3 Z2 Z 2 cos( kd ) jZ 3 sin( kd ) " REFLECTANCE SURFACE PLASMONS This approach can be applied in slab structures to analyze electromagnetic wave reflection and transmission Gold layer 0.6 Surface layer n=2.25 0.4 30 10 50 ANGLE (degrees) 90 70 The resonance angle is very sensitive to a surface layer on the gold semi-infinite medium Z2 Z1 Z3" d=0 d=5nm d=10nm 0.0 slab semi-infinite medium Surface layer thickness 0.2 Impedance transformation reduces the number of interfaces by one Substrate The Maryland Optics Group Z3 PLASMON RESONANCE WITH GOLD n=1.5 1.0 n2 - air or dielectric surface wave (plasmon) semi-infinite medium ngold Z1 semi-infinite medium Z3" Z Z Z Z " 3 " 3 ' 1 ' 1 E REFLECTANCE 0.8 0.6 Surface layer thickness d=0 d=5nm d=10nm Surface layer n=2.25 0.4 0.2 n1 - substrate For P(TM) waves Z Z cos( ) ' 0.0 35 39 43 ANGLE (degrees) 47 SURFACE PLASMONS The Maryland Optics Group • Classical solutions to Maxwell’s equations at the interface between a dielectric and a metal • A metal is a dense electron-hole plasma • A metal has a complex dielectric constant with a large negative part. • For example, for gold at 632.8nm e2=-15.73-j0.968 The Maryland Optics Group PLASMON EXCITED IN TIR GEOMETRY surface wave (plasmon) n2 - air or dielectric ngold E n1 - substrate The Maryland Optics Group PLASMON RESONANCE WITH GOLD n=1.5 1.0 REFLECTANCE 0.8 Surface layer thickness d=0 d=5nm d=10nm 0.6 Surface layer n=2.25 0.4 0.2 0.0 10 30 50 ANGLE (degrees) 70 90 The Maryland Optics Group PLASMON RESONANCE WITH GOLD n=1.5 1.0 REFLECTANCE 0.8 0.6 Surface layer thickness d=0 d=5nm d=10nm Surface layer n=2.25 0.4 0.2 0.0 35 39 43 ANGLE (degrees) 47 The Maryland Optics Group IMPEDANCE TRANSFORMATION If a transmission line of characteristic impedance Z0 and of length d is terminated in a load impedance ZL, then the impedance observed at the beginning of the line, at location z= -d relative to a load at z=0 is [Z L cos(kd) jZ 0 sin( kd)] Z in Z 0 Z 0 cos(kd) jZ L sin( kd) This approach can be applied in slab structures to analyze electromagnetic wave reflection and transmission The Maryland Optics Group Kretschman total internal reflection geometry for plasmon excitation Dielectric (absorber) layer Gold layer Substrate The Maryland Optics Group surface wave (plasmon) n2 - air or dielectric ngold n1 - substrate