10 CHEMISTRY 19.04.09 sundayherald STANDARDGRADE (GENERAL) 2008 PART 1 The Periodic Table shows the names of the elements. (b) B 1. 3. (a) C E F sodium oxygen platinum (b) D D aluminium (c) F lithium (d) A and E nitrogen 2. (a) A and C C (b) E B (c) C A 1. (a) B and D A B C D E F (b) Identify the element discovered in 1807. You may wish to use page 8 of the data booklet to help you. A B C D E F (c) Identify the element which is used as the catalyst in the Ostwald Process. A B C D E F (d) Identify the two elements which form a covalent compound. 2. A B C D E F The grid shows the names of some elements. (a) Identify the two elements whi which exist as diatomic molecules. A hydrogen A B helium B C oxygen C D silicon D E carbon E ANSWERS (a) Identify the two elements which have similar chemical properties. You may wish to use page 8 of the data booklet to help you. sundayherald 19.04.09 11 A A Iron oxide B B C C Potassium permanganate Silver bromide ANSWERS D Copper iodate D 2. E Which of the following substances is a non-conductor but becomes a good conductor on melting? A Solid potassium fluoride (c) Identify the element which must be present for iron to rust. B Solid argon C Solid potassium A 3. B C D Solid tetrachloromethane Particles with the same electron arrangement are said to be isoelectronic. Which of the following compounds contains ions which are isoelectronic? D A Na2S E 3. Which of the following compounds contains both a halide ion and a transition metal ion? B D CaCl2 4. V MgCl2 C KBr Electricity can be produced using electrochemical cells. The graph shows the variation of concentration of a reactant with time as a reaction proceeds. sodium chloride solution metal X metal Y A copper lead B copper magnesium C copper copper D copper nickel Concentration/mol l metal Y –1 0.20 metal X D (b) Identify the arrangement which would produce the largest vol largest voltage. larg You may wish to use page 7 of the data booklet to help you. A B C D 0.05 10 20 30 Time/s 40 50 –1 –1 0.0050 mol l s . C 0 0075 mol l–1 s–1 D 0.0150 mol l–1 s–1 B A C 0.10 What is the average reaction rate during the first 20 s? –1 –1 A 0.0025 mol l s (a) Identify the arrangement which would not produce electricity. B 0.15 0 5. The potential energy diagram below refers to the reversible reaction involving reactants R and products P. Potential energy –1 /kJ mol 90 80 70 60 50 R 40 30 20 10 0 CONTINUED ON NEXT PAGE B A D C 1. 1. 2. 3. 4. HIGHER 2007 (b) Identify the element which has the electron arrangement 2,4. You may wish to use page 1 of the data booklet to help you. P Reaction pathway 19.04.09 sundayherald What is the enthalpy change, in kJ mol–1, for the reverse reaction P → R? A CO2 A + 30 B 6. B + 10 C CCl4 D – 40 D CH4 A the formation of one mole of salt B the formation of one mole of water C the neutralisation of one mole of acid D the neutralisation of one mole of alkali. Which equation represents the first ionisation energy of a diatomic element, X2? A 1 2 X2(s) → X+(g) B 1 2 X2(g) → X–(g) + C X(g) → X (g) D X(s) → X–(g) 8. NH3 C – 10 The enthalpy of neutralisation in an acid/alkali reaction is always the energy released in 7. 12. Which of the following compounds has polar molecules? Which of the following chlorides is likely to have least ionic character? 13. How many moles of oxygen atoms are in 0.5 mol of carbon dioxide? A 0.25 B 0.5 C 1 D 2 14. A fullerene molecule consists of 60 carbon atoms. atoms. Approximately how many such molecules are present in 12 g of this type of carbon? A 1.0 × 1022 1.2 × 1023 C 6.0 × 1023 25 D 3.6 × 10 B A BeCl2 B CaCl2 C LiCl D CsCl 9. Which of the following chlorides is most likely to be soluble in tetrachloromethane, CCl4? A Barium chloride B Caesium chloride C Calcium chloride D Phosphorus chloride 10. Which of the following compounds exists as discrete molecules? A Sulphur dioxide B Silicon dioxide C Aluminium oxide D Iron(II) oxide 11. An element (melting point above 3000 °C) forms an oxide which is a gas at room temperature. Which type of bonding is likely to be present in the element? A Metallic B Polar covalent C Non-polar covalent 15. Avogadro’s Constant is the same as the number of A molecules in 16.0 g of oxygen B atoms in 20.2 g of neon C formula units in 20.0 g of hydroxide D ions in 58.5 g of sodium chloride. sodium 16. The equation for the complete combustion of propane is: C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(") 3 3 30 cm of propane is mixed with 200 cm of oxygen and the mixture is ignited. What is the volume of the resulting gas mixture? (All volumes are measured at the same temperature and pressure.) A 90 cm B 3 120 cm 3 C 140 cm3 D 210 cm 3 17. A mixture of carbon monoxide and hydrogen can be converted into water and a mixture of hydrocarbons. nCO + (2n + 1)H2 → nH2O + hydrocarbons D Ionic What is the general hydrocarbons produced? hydrocarbons produced? A CnH2n–2 B CnH2n C CnH2n+1 D CnH2n+2 formula for the ANSWERS 4. C 5. C 6. B 7. C 8. A 9. D 10. A 11. C 12. B 13. C 14. A 15. B 16. C 17. D 12