International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Spatial Distribution of Ground Water Quality in and around Vyasarpadi, North Chennai by using GIS techniques K. Ilayaraja*, and A. Ambica Department of Civil Engineering Bharath University, Selaiyur, Chennai-73 ABSTRACT All living organisms are dependent upon pure oxygen, water, soil etc. in one form or other to maintain metabolic processes that produce energy for growth and reproduction. Groundwater is the most important natural resource required for drinking to many people around the world, especially in rural areas. Due to the rapid increase in rapid urbanisation and industries the air, water, soil and the nature are being polluted by dispose their wastes into water bodies and contaminate them. The level of concentration of various phisco-chemical parameters determines the quality of ground water. Therefore the study was undertaken with the aim to analysis the ground water quality in the study area with the goal to analyse the physico-chemical character of the water samples and to create the spatial distribution map of the analysed water samples by calculating the water quality index. GIS is an effective tool to represent the spatial distribution. A geodatabase and various thematic maps were created for the water quality representative parameters such pH, Carbonates and Bi- carbonates, Dissolved oxygen, Electrical Conductivity, Chlorides, Total Hardness and Alkalinity. The physico-chemical results were compared to the standard guideline values as recommended by the World Health Organization (WHO) for drinking and public health in order to have an overview of the present groundwater quality. Chlorides concentration in most of the wells located are within the maximum permissible limit specified by BIS and WHO Standard. Key words: Geographical Information System, Spatial analysis, Water Quality Index 1 Introduction The worlds total water resources are estimated to be 1.37x10 8 Million ha-m. Of these, about 97.61% is salt water in oceans and 2.39% is available as surface water and 0.29% as ground water. It is the largest source of fresh water in the hydrologic cycle. Chemicals passing ISSN: 2231-5381 http://www.ijettjournal.org Page 15 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 through several hydrological zones, reach the ground water system. The pore spaces in the unsaturated zones are occupied by air and water. These adsorbed chemicals will be decomposed by oxidation and microbial activity. The pore spaces are also unsaturated and as chemical percolated through the zone and aerobic biological degradation. Water is relatively more prone to pollution than air because it is more viscous having lesser moment of inertial possessing closer molecular distance than air (Trivedi and Raj 1992). Luciano Gomes. Estela P.Troiani. Jorge Nozaki (2009) have analyzed the environmental impact on a stream in Maringa city, Parana state, Brazil and blamed the tanneries. Deterioration of the quality of the stream water and the ground water is mainly due to discharge of tannery effluent in the stream. The concentration of the TDS, TSS, Chlorides were very very high. Gultekin Tarcan et al., (2009) found that effluent from the tanneries caused irreparable damage to the soil and as well as water. Fertility of the soil was affected due to discharge from tanneries. E.Leghouchi. E.Laib. M.Guerbet (2007) said that chrome tanning was in practice in the nearby tanneries caused damage to the vegetation and so also the sediments & water. Gurunatha Rao V.V.S, M. Thangarajan (1999) in their assessment through mass transport modeling reported that the ground water pollution due to discharge of tannery effluents in Upper Palar basin. They found that concentration of TDS, TSS and Chlorides were very high and which is mainly due to tannery effluents. Karthikeyan and Meenakshi (1991) examined the Ground water quality in and around the tannery units located in the southern side of Dindigul town. The amount of total solids, hardness & chlorides were several times higher than the tolerable limits for drinking and Industrial purposes. Vardaraj et.al (1994) worked on the toxic effect of tannery effluent on the biochemical constituent in different issue of pillaglobosa. Manonamani et al. (1991) The tannery effluent affect the water quality of irrigation canal by way of altering the algae, fungi, bacteria and actinomycete population. Vullierment and carre (1982) studied the effect of tannery effluent on the ground water quality parameters such as pH, temperature, BOD, suspended and dissolved solids, sulphur, chromium and nitrogen. He found that chromium and TSS concentration were very high and several times more than the tolerable limits for drinking purposes. Roa et.al (1982) studied the activity pattern of the fish, water snail and other aquatic fauna in the river and found that they are affected due to tannery effluents. The aim of ther study is to analysis the gorund water quality in the study area. Therefore the objective of the study is to analyse the physico-chemical character of the water samples and to create the spatial distribution ISSN: 2231-5381 http://www.ijettjournal.org Page 16 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 map of the analysed water samples by calculating the water quality index. Different themes interpreted from topographical data on 1:50,000 scale were converted into raster format using colour scanner. These raster maps were geometrically rectified using Ground Control Points (GCP) and converted into vector format by on screen digitization method using Arc GIS software. These vectorised themes were put into GIS environ using common projection coordinates so as to obtain better results in overlay analysis. GIS is a computer based integrated database management system in which large volumes of geo referenced spatial data derived from variety of sources are efficiently stored, organized, manipulated, retrieved, analysed and displayed according to the user defined specifications. Spatial analysis module in ArcGIS (version 9.2) software has been used for the present study. Spatial analysis of drinking water quality was carried out by interpolation of sampling points by the algorithmic method ‘Inverse Distance Weighted’ (IDW). The locations of the sampling stations were imported into GIS software as point layer. Each sample point was assigned by a number and stored in the point attribute table. The attribute data file contains values of all physico-chemical parameters in separate columns for each sampling station. The geodatabase was used to generate the spatial distribution maps of the analyzed water quality parameters such pH, EC, Alkalinity, Hardness, DO, Chlorides, Carbonates and Bicarbonates. 2. Materials and Methods District maps, block maps, Survey of India topo sheets on 1:50,000 scale and soil atlas. In order to identify and transform the information recorded, light table, enlargement reduction process and various drawings and measuring instruments, computer with Arc GIS 9.1, software have been used during the course of map preparation and final sptial maps generation. Bureau of Indian standards for drinking water, the Central Public Health Environmental Engineering Organization and WHO’s Standard Guidelines for Portable Water (Table 1). The generalized flow chart adaopted for the present study is given in the figure 1. ISSN: 2231-5381 http://www.ijettjournal.org Page 17 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Table 1 WHO’s standards and Indian standards for physical and chemical parameters Indian standards S. NO Parameter WHO Desirable limit 1 pH 2 3 4 5 6 7 8 9 Total hardness(mg/l) Chlorides (mg/l) Sulphate (mg/l) TDS(mg/l) Nitrate(mg/l) Total alkaline(mg/l) Sodium Fluorides Preferably<8.0 (between 6.5-8.5) 500 mg/l (as CaCO3) 250 mg/l --1000 mg/l ----200 mg/l 1.5 mg/l Permissible limits 6.5-8.5 No relaxation 300 250 200 500 45 200 ----- 600 1000 400 1000 100 350 ----- GIS FIELD TEST SAMPLE LOCATION/GPS SAMPLE COLLECTION INSITUpH,EC GEO PROCESSING LABORATORY TESTALKALINITY,HARDNES S, DO,CHLORIDES,CARBO NATES AND BICARBONATES BASE MAP ANALYSIS SPATIAL DISTRIBUTION OF G.W QUALITY Figure 1 Flow chart of methodology ISSN: 2231-5381 http://www.ijettjournal.org Page 18 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 3. Study area Chennai is a low-lying area and the land surface is almost flat. It is geographically located at latitude of 13° 6' 40” N and Longitude of 80° 15' 53” E (Figure 2). The even topography of the land throughout the district renders sub-divisions into natural regions rather difficult. It rises slightly as the distance from the sea-shore increases but the average elevation of the city is not more than 22' above mean seal-level, while most of the localities are just at sealevel and drainage in such areas remains a serious problem. A total of 15 gorund watersamples are collected from Vyasarpadi, North Chennai. The depth of the wells, bore wells ranged from approximately 30-60 feet in these stations and their locations were located by handheld GPS (Table 2). Table 2. The locarions of the samples with their latitude and longitude S.NO LATTITUDE(N) LONGITUDE(E) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 13°06.720’ 13°06.802’ 13°06.864’ 13°06.784’ 13°06.894’ 13°06.751’ 13°06.664’ 13°06.569’ 13°06.665’ 13°06.807’ 13°06.845’ 13°06.849’ 13°06.714’ 13°06.988’ 13°06.737’ 080°15.339’ 080°15.391’ 080°15.520’ 080°15.728’ 080°15.732’ 080°15.589’ 080°15.680’ 080°15.387’ 080°15.432’ 080°15.408’ 080°15.413’ 080°15.367’ 080°15.346’ 080°15.336’ 080°15.423’ ISSN: 2231-5381 http://www.ijettjournal.org SOURCE BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL BORE WELL Page 19 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Figure 2 Base map of the study area with the sample locations ISSN: 2231-5381 http://www.ijettjournal.org Page 20 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 4. Result and Discussion Understanding the groundwater quality is important seeing that it is the main factor determining its suitability for drinking use. Physical and chemical parameters including statistical measures, such as minimum, maximum, mean and standard deviation, are reported in Table 3. The following water quality parameters were selected and their respective maps were prepared namely, pH, EC, Chloride, Total hardness, Dissolved oxygen, Carbonates, Bicarbonates. (i) pH: The results of the ground water sample analysed it is seen that pH in all the wells were above the maximum permissible limit ie., between 9.0 and 11.0 specified by Bereau of Indian Standard (BIS). The pH value in study area lies between 9.0 and 9.99. The sample locations 9,11,14&15 has pH varies between 9.2 - 9.38 as the lowest one. The sample locations 1,5,,7,8,12 &13 has observed pH as 9.79 - 9.99 as the max value. The average value is been distributed for remaining samples as 9.2 - 9.78. The distribution of pH from 9.0 to 9.99 is spatially plotted in study area using arc gis as a spatial map (Figure 3) Table 3. Result of Analyzed parameters of the groundwater samples SNO. pH EC ALKALINITY HARDNESS DO (mmhos/cm) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 9.9 9.3 9.3 9.5 9.8 9.7 9.8 9.9 9.8 9.8 9.3 9.8 9.9 9.8 9.6 980 978 981 980 980 997 986 982 983 979 995 990 986 981 980 ISSN: 2231-5381 CHLORIDES CARBONATES BICARBONATES 18 15 18 19 12 17 15 20 30 14 20 18 18 12 16 17 35 9.5 8.5 23 48 7.5 12.5 27 26 20 7.5 32 20.5 37 (mg/l) 35 50 27.5 27.5 35 65 22.5 32.5 40 40 40 27.5 50 26.5 50 250 630 350 450 350 500 245 375 250 670 555 340 370 400 610 16 9.6 14 4 12 12 10.8 11.2 12.8 12 14 13.6 14.4 14.8 6.5 75.812 89.59 60.3 43 64.61 103.38 60.3 120.61 77.535 172.3 63.75 55.99 94.76 68.92 120 http://www.ijettjournal.org Page 21 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Fig 3 Spatial Distribution of pH ISSN: 2231-5381 http://www.ijettjournal.org Page 22 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 (ii) Carbonates The Carbonates value in study area lies between 12.00 - 19.99. The sample locations 5,9&14 has carbonates varying between 12.00 - 13.59 as the minimum value. The sample locations 4,8&11 has observed carbonates as 10.9 -15.9 as the max value. The average value is been distributed for remaining samples varying between 13.6 - 13.8. The distribution of carbonates from 12.00 – 19.99 is spatially plotted in study area using arc gis as a contour map(Figure 4) (iii) Bi-Carbonates The Bi-carbonates value in study area lies between 7.50 – 47.99. The sample locations 2,3,4,7,8,&12 has bi-carbonates varies between 7.50 - 15.59 as the minimum value. The sample locations 6 has observed bi-carbonates as 39.90 – 47.99 as the max value. The average value is been distributed for remaining samples varying between 26 – 40. The distribution of bi- arbonates from 8 - 74 is spatially plotted in study area using arc gis as a contour map (Figure 5). (iv) Dissolved Oxyen The DO value in study area lies between 4 - 14.9. The sample locations 4 has DO varies between 4 - 5.9 as the minimum value. The sample locations 1,3,11,13&14 has observed DO as 13 - 14.9 as the max value. The average value is been distributed for remaining samples varying from 6 - 12.9. The distribution of DO from 4 - 14.9 is spatially plotted in study area using arc gis as a contour map (Figure 6). (v) Electrical conductivity The EC value in study area lies between 979 - 996. The sample locations 1,3,4,5,913&15 has EC varies between 979 - 980 as the minimum value. The sample locations 6&10 rest has observed EC as 985 - 996 as the max value. The average value is been distributed for samples ISSN: 2231-5381 http://www.ijettjournal.org Page 23 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 981 – 992. The distribution of EC from 979 - 996 is spatially plotted in study area using arc gis as a spatial map (Figure 7). Figure 4 Spatial Distribution of Carbonates ISSN: 2231-5381 http://www.ijettjournal.org Page 24 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Figure 5 Spatial Distribution of Bicarbonates ISSN: 2231-5381 http://www.ijettjournal.org Page 25 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Figure 6 Spatial Distribution of Dissolved Oxygen ISSN: 2231-5381 http://www.ijettjournal.org Page 26 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Figure 7 Spatial Distribution of EC ISSN: 2231-5381 http://www.ijettjournal.org Page 27 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 (vi) Chlorides The Chlorides value in study area lies between 36.75 - 172.29. The sample locations 3,4,7,11&12 has chlorides varying between 36.75 - 63.35 as the minimun value. The sample locations 6&3 has observed chlorides 145.18 – 172.29 as the maximum value. The average value is been distributed between the remaining samples as 63.86-145.17. The distribution of chlorides from 53-88 is spatially plotted in study area using arc gis as a contour map (Figure 8) (vii) Total Hardness The Hardness value in study area lies between 245 - 699. The sample locations 1,7&9 has Hardness as the lowest value varying between 245 - 335. The sample locations 10&15 has observed hardness as the highest value varying between 608 – 699. The average value is been distributed for remaining samples 336 – 607. The distribution of Hardness from 245 - 699 is spatially plotted in study area using arc gis as a contour map (Figure 9). (viii) Alkalinity The Alkalinity value in study area lies between 6.65 – 54.99. The sample locations 6 has alkalinity varies between 6.65 – 19.30 as the minimum value. The sample locations 13&15 has observed alkalinity as 45.32 -54.99 as the max value. The average value is been distributed for remaining samples between 16.31 – 45.31. The distribution of Alkalinity from 16-44 is spatially plotted in study area using arc gis as a contour map (Figure 10). 5. Conclusion From the results of the ground water sample analysed it is seen that pH in all the wells were above the maximum permissible limit ie., between 9.0 and 11.0 specified by Bereau of Indian Standard (BIS). Chlorides concentration in most of the wells located are within the maximum permissible limit specified by BIS and WHO Standard. Total Hardness in the well near the industries exceeds the limit in the entire well situated near the tannery. The range near the tannery was found to be 450 mg/l to 700 mg/l. Dissolved oxygen in the obtained water samples are within the permissible limits. Alkalinity obtained from water samples are ISSN: 2231-5381 http://www.ijettjournal.org Page 28 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 comparatively high. Similarly, Electrical conductivty concentration was more in the wells near the industries. Its concentration was well above the maximum permissible limit. The range of concentration was 900 to 1000 mmhos/cm. ISSN: 2231-5381 http://www.ijettjournal.org Page 29 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Figure 8 Spatial Distribution of Chlorides Figure 9 Spatial Distribution of Hardness ISSN: 2231-5381 http://www.ijettjournal.org Page 30 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 Figure 10 Spatial Distribution of Alkalinity ISSN: 2231-5381 http://www.ijettjournal.org Page 31 International Journal of Engineering Trends and Technology (IJETT) – Volume1 Issue2 – May 2011 References Kamaraju MVV (1997) Groundwater potential evaluation of West Godavari district, Andhra Pradesh State, IndiaA GIS approach. Groundwater34(2):pp 318–334. Priti Singh and I.A. Khan (2011) Ground water quality assessment of Dhankawadi ward of Pune by using GIS. International Journal of Geomatics and Geosciences, Volume 2, (2): pp 688 – 703. Prashant N. Rajankar ∙ Dilip H. Tambekar ∙ Satish R. 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