International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 Material Selection using Multi-criteria decision making methods (MCDM) for design a multi-tubular packed-bed Fischer-Tropsch reactor (MPBR) Javier Martínez-Gómez#1, Ricardo A. Narváez C.*2, 1 Instituto Nacional de Eficiencia Energética y Energías Renovables (INER), Adress: 6 de Diciembre N33-32, Quito, Ecuador. Tel +593 (0) 2 3931390 ext: 2079, Abstract- The future of the fossil fuel supply is uncertain. For this reason, it is necessary the transition from a fossil based to a biobased for greenhouse gas emissions reduction targets, and climate change. In this regards, multi tubular packed-bed reactor Fischer-Tropsch (MPBR) appears has an essential technology to improve and reduce cost of operation. For design a MPBR, many studies has been used CFD for detailed evaluation of reaction systems. This research use Multi-criteria decision making methods (MCDM) for the material selection of a MPBR. This project focuses on the design for selecting an alternative material which best fits the technological requirements to make the pipes and the vessel of a MPBR and reduce the cost of production. The MCMD methods implemented are complex proportional assessment of alternatives with gray relations (COPRAS-G), operational competitiveness rating analysis (OCRA), a new additive ratio assessment (ARAS) and Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) methods. The criteria weighting was performed by compromised weighting method composed of AHP (analytic hierarchy process) and Entropy methods. The ranking results showed that ASME SA-106 and ASME SA-106 would be the best materials for the pipes and the vessel of a MPBR. Keywords - Multi-criteria decision making methods, MCDM, material selection, multi-tubular packedbed reactor Fischer-Tropsch reactor, MPBR. I. INTRODUCTION The future of the world‟s oil supply is at this point uncertain. Over the last few years, a major concern has arisen regarding the decreasing global oil reserves, increment of fuel demand in emerging economies and the associated increasing crude oil price both driven by a strong world demand and by political instabilities in oil producing regions. The transition from a fossil based to a biobased economy is absolutely essential in climate protection and ISSN: 2231-5381 greenhouse gas emissions reduction targets. Agricultural feedstock like woodchips and residual of non-food parts of cereal crop, can be valorized and be integrated in a second-generation Biomass to Liquid process to synthetize liquid biofuels via the Fischer-Tropsch (FT) synthesis [1-2]. The FT synthesis is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen into liquid hydrocarbons. A variety of synthesis-gas compositions can be used. For iron-based catalysts promote the water-gas-shift reaction and thus can tolerate the optimal H2:CO ratio is around 1.2–1.5. This reactivity can be important for synthesis gas derived from coal or biomass, which tend to have relatively low H2:CO ratios (<1). In addition, FT synthesis is known for its highly exothermicity (ΔHR=–165 kJ mol−1CO) [3]. Four main types of commercial FT reactors are commonly implemented in industrial processes: the fluidized-bed reactor, the multi-tubular packed-bed Fischer-Tropsch reactor (MPBR), the slurry phase reactor (SPR) and the circulating fluidized-bed reactor. Two operating processes have been developed: the high-temperature FT processes (573 – 623 K, HTFT) and the low temperature FT processes (473 – 523 K, LTFT). HTFT based on iron catalysts yields essentially C1 to C15 hydrocarbons in circulating fluidized-bed reactors while LTFT processes lead mainly to linear long chain hydrocarbons (waxes and parafins) [1], [2]. Many variables such reactant inlet temperature, coolant flow rate, catalyst loading ratio, and space velocity are involved in multichannel FT reactor design [4]. In this sense, many studies used the computational fluid dynamics (CFD) is widely used for detailed evaluation of reaction systems [5-6]. However, when many process and coolant channels are involved, for large-scale reactors, CFD is highly computationally intensive and time consuming CFD therefore may not be able to handle all the channels; the problem is unrealistically large, because it deals with rigorous physics such as flow patterns over the entire domain [4-5] Other studies has been performed by based on a kinetic model for the conversion of syngas. The product slate is then http://www.ijettjournal.org Page 273 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 calculated from a simplified kinetic model to describe the overall advancement of the reaction followed by a distribution equations to calculate different products in order to design a FT [6-7]. But none of them, has been developed a previous study of the selection of material for the Fischer Tropsch reactor. Usually engineers and researchers use certain materials based on experience and other studies. I. I. MATERIAL SELECTION FOR MCDM The selection of the most convenient material for a precise purpose is a crucial function in the design and development of products. Materials selection has become an important source at engineering processes because of economical, technological, environmental parameters [9-10] Materials influence product function, the life cycle of the product, who is going to use or produce it, usability, product personality, environment and costs in multiple, complex and not always quantitative way. The improper selection of one material could negatively affect productivity, profitability, cost and image of an organization because of the growing demands for extended producer responsibility [9-10]. For this reason, the development of products and success and competitiveness of manufacturing organizations also depends on the selected materials [11-12]. Material selection carried out several research processes that give off assessment methods to compare the behavior of elements according to their characteristic properties (density, yield strength, specific heat, cost, corrosion rate, thermal diffusivity, etc.) with efficiency indicators in order to select the best alternative for a given engineering application [11]. Thus, efforts need to be extended to identify those criteria that influence material selection for a given engineering application to eliminate unsuitable alternatives and select the most appropriate alternative using simple and logical method [13]. Comparing candidate materials, ranking and choosing the best material is one of most important stages in material selection process. Multi criteria decision making methods (MCDM) appear as an alternative in engineering design due to its adaptability for different applications. The MCDM methods can be broadly divided into two categories, as (i) multi-objective decision-making (MODM) and (ii) multi-attribute decision-making (MADM). There are also several methods in each of the abovementioned categories. Priority-based, outranking, preferential ranking, distance-based and mixed methods are some of the popular MCDM methods as applied for evaluating and selecting the most suitable materials for diverse engineering applications. In most MCDM methods a certain weight is assigned to each material requirement ISSN: 2231-5381 (which depends on its importance to the performance of the design). Assigning weight factor to each material property must be done with care to prevent bias or getting the answer you intended as Here are some engineering applications where MCDM have been regarded as selection tools, performed by Jahan, Ismail, Sapuan, Mustapha [14] “Material screening and choosing methods -A review”, developed by [15] “Evaluating the construction methods of cold-formed steel structures in reconstructing the areas damaged in natural crises, using the methods AHP and COPRAS-G”, studied by [16] “Materials selection for lighter wagon design with a weighted property index method”, developed by [11] Material selection for the tool holder working under hard milling conditions using different multi criteria decision making methods”. This paper solves the problem of selecting the material a MPBR using recent mathematical tools and techniques for accurate ranking of the alternative materials for a given engineering application. In this paper, it has been studied the material decision for pipes and vessel of the reactor by four preference ranking- based MCDM methods, i.e. COPRAS-G, OCRA, ARAS and TOPSIS methods have been implemented. The criteria weighting was performed by compromised weighting method composed of AHP and Entropy methods. For these methods, a list of all the possible choices from the best to the worst suitable materials is obtained, taking into account different material selection criteria. II. MATERIALS AND METHODS II. I DEFINITION OF THE DECISION MAKING PROBLEM To optimize the material selection for a MPBR is necessary to know the most important properties of the design and operation. It is necessary to note, that normally FT reactor is operated in the temperature range of 150–300 °C [1-2]. Higher temperatures lead to faster reactions and higher conversion rates but also tend to favor methane production. Typical pressures range from one to several tens of atmospheres. Increasing the pressure leads to higher conversion rates and also favors formation of longchained alkanes, both of which are desirable. In addition, it is necessary the heat removal capability that has a major impact on the products selectivity: a temperature increase has the effect of rising methane production as well as results in catalyst deactivation associated to sintering and coking. In Fig. 1 is illustrated the schema of a MPBR commercial. http://www.ijettjournal.org Page 274 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 Figure 1. Schema of a MPBR. In order to meet for the material selection, it has been identified the most important properties based on the bibliography [1-5]. The most in one of the most important material property is considered to be cost ( ), the low values of which are desired in order to provide a competitive advantage among manufacturers. In addition, higher pressures would be favorable, but the benefits may not justify the additional costs of high-pressure equipment. Furthermore, higher pressures can lead to catalyst deactivation via coke formation. The second property required is corrosion rates (R), the lowest values of corrosion rate are necessary to maintain the useful life or the reactor. A high Yield strength (Y) and Fracture toughness ( ) because it is possible to increase the pressure which leads to higher conversion rates and also favors formation of longchained alkanes. Thermal conductivity (λ) to transfer heat from one part of the reactor to another very quickly and efficiently. Maximum temperature at service ( ) which leads to higher conversion rates. Low thermal expansion (α) is important in order to produce low thermal stress. Finally Specific Heat ( ) is important to the transfer of thermal energy. Among these eight criteria, the cost, corrosion rate and thermal expansion, are a nonbeneficial properties. Eight alternatives for the pipes and the vessel of a MPBR were taken into consideration: AISI 316 austenitic stainless steel, AISI 430 ferritic stainless steel, AISI 4140 Steel, AISI 304 austenitic stainless steel, PM 2000 ODS Iron Alloy, PM 1000 ODS Nickel Alloy, ASME SA106 and ASME SA-516. The properties of the materials alternatives for a MPBR with their quantitative data are given in Table 1 and their average values were used Table 1. Material properties for a MPBR (A) Cost [ ] Material ( ) (1) AISI 316 austenitic stainless steel (2) AISI 430 ferritic stainless steel (B) Corrosion rate [ ] ( ) (C) Yield strength [MPa] ( ) (E) (D) Maximum Thermal temperature conductivity at service of [ ] material [ ] ( ) ( ) (F) Fracture toughness. [ ] ( ) (G) Thermal expansion [ ] ( ) (H) Specific Heat [ ] ( References ) 4,2 2,05 290 16,3 897,5 195 1,6 0,5 [1-5, 10, 12] 3,6 2,67 513,5 24,9 842 203 1,04 0,46 [1-5, 10, 12] 4,3 2,67 415 42,7 845 201 1,22 0,47 [1-5, 10, 12] 5,1 2,02 215 16,2 827,5 17,3 1,73 0,5 [1-5, 10, 12] 112,5 0,125 603 10,9 1350 34 1,5 0,48 [1-5, 10, 12] 112,5 0,125 602 12 1200 32 1,29 0,44 [1-5, 10, 12] (7) ASME SA-106 1,5 0,6 407,5 51 650 114 1,36 0,46 [1-5, 10, 12] (8) ASME SA-516 1,75 1,4 447,5 52 650 128 1,2 0,47 [1-5, 10, 12] (3) AISI 4140 Steel (4) AISI 304 austenitic stainless steel (5) PM 2000 ODS Iron Alloy (Al 5,5%, Cr 19%, Fe 74,5 %, Ti 0,50%, Y2O3 0,50 %) (6) PM 1000 ODS Nickel Alloy (Al 0.3%, Cr 20%, Fe 3,5%,Ni 75,6%, Ti 0,5%, Y2O3 0,60 %) II. II. CRITERIA WEIGHTING The criteria weights are calculated using a compromised weighting method, where the AHP and Entropy methods were combined, in order to take into account the subjective and objective ISSN: 2231-5381 weights of the criteria and to obtain more reasonable weight coefficients. The synthesis weight for the jth criteria is: http://www.ijettjournal.org (1) Page 275 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 where αj is the weight of jth criteria obtained via AHP method, and βj is the weight of jth criteria obtained through Entropy method. II. II. I. ANALYTIC HIERARCHY PROCESS (AHP) The AHP method was developed by [17] to model subjective decision-making processes based on multiple criteria in a hierarchical system. The method composes of three principles: a) Structure of the model. b) Comparative judgment of the alternatives and the criteria. c) Assessing consistency in results. a) Structure of the model. In order to identify the importance of every alternative in an application, each alternative has been assigned a value. The ranking is composed by three levels: 1). general objective, b). criteria for every alternative, c). alternatives to regard (Saaty, 1980). b) Comparative judgment of the alternatives and the criteria. The weight of criteria respect to other is set in this section. To quantify each coefficient it is required experience and knowledge of the application [17] classified the importance parameters show in Table II. The relative importance of two criteria is rated using a scale with the digits 1, 3, 5, 7 and 9, where 1 denotes „„equally important‟‟, 3 for „„slightly more important‟‟, 5 for „„strongly more important‟‟, 7 for „„demonstrably more important‟‟ and 9 for „„absolutely more important‟‟. The values 2, 4, 6 and 8 are applied to differentiate slightly differing judgements. The comparison among n criteria is resume in matrix A ( ), the global arrange is expressed in equation (2). manufacturing systems. Journal of Manufacturing Technology Management). c) Consistency assessment In order to ensure the consistency of the subjective perception and the accuracy of the results it is necessary to distinguish the importance of alternatives among them. In equations (4) and (5) is shown the consistency indexes required to validate the results. (4) (5) Where: : Number of selection criteria. : Random index. : Consistency index. : Consistency relationship. Largest eigenvalue. If should be greater than 0,1, otherwise, the importance coefficient (1-9) has to be set again and recalculated [17] II. II. II. ENTROPY METHOD Entropy method indicates that a broad distribution represents more uncertainty than that of a sharply peaked one [13]. Equation (6) shows the decision matrix A of multi-criteria problem with alternatives and criteria: ; ; (6) where =1 (2) Afterwards, from matrix it is determined the relative priority among properties. The eigenvector is the weight importance and it corresponds with the largest eigenvector ( ): (3) The consistency of the results is resumed by the pairwise comparison of alternatives. Matrix can be ranked as 1 and = n (Ozden Bayazit. Use of AHP in decision making for flexible ISSN: 2231-5381 is the performance value of the alternative to the criteria. The normalized decision matrix is calculated (ZH Zou), in order to determine the weights by the Entropy method. (7) The Entropy value obtained as: http://www.ijettjournal.org of criteria can be (8) Page 276 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 where is a constant that guarantees and m is the number of alternatives. The degree of divergence ( ) of the average information contained by each criterion can be obtained from Eq. (9): (9) Thus, the weight of Entropy of defined as: (11) criteria can be where alternative on criterion. The value of is determined by (the smallest value or (10) II. II. III. COPRAS-G METHOD COPRAS-G method [13] is a MCDM method that applies gray numbers to evaluate several alternatives of an engineering application. The gray numbers are a section of the gray theory to confront insufficient or incomplete information [13]. White number, gray number and black number are the three classifications to distinguish the uncertainty level of information. The uncertainty level can be expressed by three numbers: white, gray and black. Let the number , and , where has two real numbers, (the lower limit of ) and (the upper limit of ) is defined as follows [13]: a) White number: if = , then is the interval performance value of lower limit) and (the biggest value or upper limit). Step 3: Normalize the decision matrix, using the following equations. Eq. (12) is applied for or lower limit values, whereas, Eq. (13) is used for or upper limit values. (12) (13) Step 4: Calculate the weights of each criterion. Step 5: Determine the weighted normalized decision matrix, by mean of the equations (14) and (15). has the complete information. b) Gray number: , means insufficient and uncertain information. c) Black number: if and (14) , then information. (15) has no meaningful The COPRAS-G method uses a stepwise ranking and evaluating procedure of the alternatives in terms of significance and utility degree. The procedure of applying COPRAS-G method is formulated by the following steps [13]: Step 1: Selection of a set of the most important criteria, describing the alternatives and develop the initial decision matrix, . Step 6: The weighted mean normalized sums are calculated for both the beneficial attributes based on equation (16) and non-beneficial attributes based on equation (17) for all the alternatives. (16) (17) Step 7: Determine the minimum value of . (18) ISSN: 2231-5381 http://www.ijettjournal.org Page 277 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 Step 8: Determine the relative significances or priorities of the alternatives. The priorities of the candidate alternatives are calculated on the basis of with equation (19). The greater the value of , the higher is the priority of the alternative. The alternative with the highest relative significance value ( ) is the best choice among the feasible candidates. difference in performance scores for criterion , between alternative and the alternative whose score for criterion is the highest among all the alternatives considered. Step 2: Calculate the linear preference rating for the input criteria ( ) using equation (23): (23) (19) Step 9: Determine significance value. the maximum relative Step 3: Compute the preference ratings with respect to the beneficial criteria. The aggregate performance for alternative on all the beneficial or output criteria is measured using the equation (24): (20) Step 10: Calculate the quantitative utility ( ) for alternative through the equation (21). The ranking is set by the . (21) With the increase or decrease in the value of the relative significance for an alternative, it is observed that its degree of utility also increases or decreases. These utility values of the candidate alternatives range from 0 % to 100 %. The best alternative is assigned according to the maximum value 100%. (24) where indicates the number of beneficial attributes or output criteria and is calibration constant or weight importance of output criteria. The higher an alternative‟s score for an output criterion, the higher is the preference for that alternative. It can be mentioned that Step 4: Calculate the linear preference rating for the output criteria ( ) using the equation (25): (25) II. II. IV. OCRA METHOD The OCRA method was developed to measure the relative performance of a set of production units, where resources are consumed to create value-added outputs. OCRA uses an intuitive method for incorporating the decision maker‟s preferences about the relative importance of the criteria. The general OCRA procedure is described as below [18]: Step 1: Compute the preference ratings with respect to the non- beneficial criteria. The aggregate performance of alternative with respect to all the input criteria is calculated using the following equation: (i=1,2,…,m, j=1,2,…,n) (22) where is the measure of the relative performance of alternative and is the performance score of ith alternative with respect to input criterion. If alternative is preferred to alternative with respect to criterion, then . Then term ISSN: 2231-5381 indicates the Step 5: Compute the overall preference ratings ( ) as follows in equation (26): (26) The alternatives are ranked according to the values of the overall preference rating. The alternative with the best overall preference rating receives the first rank. II. II. V. ARAS METHOD The ARAS method is based on utility theory and quantitative measurements. The steps of ARAS method are as follows [19]: Step 1: Determine the normalized decision matrix, using linear normalization procedure for beneficial attributes [19]. For non-beneficial attributes, the normalization procedure follows two steps. At first, the reciprocal of each criterion with respect to all the alternatives is taken as follows: (27) In the second step, the normalized values are calculated as follows: http://www.ijettjournal.org Page 278 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 (28) Step 2: Determine the weighted normalized decision matrix, D. Step 3: Determine the optimality function ( ) for ith alternative by means of the equation (29): (29) (34) Where and are the index set of benefit criteria and the index set of cost criteria, respectively. Step 4: The distance between the ideal and nadir solution is quantified. The two Euclidean distances for each alternative are computed as given by equations (35) y (36): The optimality function has a direct and proportional relationship with values in the decision matrix and criteria weights. Step 4: Calculate the degree of the utility ( ) for each alternative. The values of is calculated by means of equation (30): (35) (30) The utility values of each alternative range from 0% to 100%. The alternative with the highest is the best choice among the material alternatives. II. II. VI. TOPSIS METHOD The basic idea of TOPSIS is that the best decision should be made to be closest to the ideal and farthest from the non-ideal [20]. Such ideal and negativeideal solutions are computed by considering the various alternatives. The highest percentage corresponds to the best alternative. The TOPSIS approach is structured by the following procedure [20]: Step 1: Normalize the decision matrix by is performed using the equation 31. (31) Where is the performance measure of (36) Step 5: The relative closeness ( by equation (37). ) is computed ; (37) The highest alternatives. coefficients correspond to the best II. II. VII. SPEARMAN’S RANK CORRELATION COEFFICIENT The Spearman‟s rank correlation coefficient measures the relation among nonlinear datasets. Its purpose is to quantify the strength of linear relationship between two variables. If there are no repeated data values, a perfect Spearman correlation of +1 or −1 occurs when each of the variables is a perfect monotone function of the [21]. The Spearman‟s rank correlation is computed by equation (38). criterion respect to alternative. Step 2: Sync the weight and the normalized matrix (38) , see equation (32). (32) Step 3: The ideal solutions ( ) and nadir solutions ( ) are determined using (33) and (34): (33) ISSN: 2231-5381 Where: : Spearman‟s rank coefficient : Difference between ranks of each case : Number of pairs of values. III. RESULTS The weight of each criteria have been computed by the AHP method and Entropy method regarding its importance for the pipes and the vessel of a MPBR. After the determination of the weights of different criteria using the AHP and Entropy methods, these weights were applied to the MCDM http://www.ijettjournal.org Page 279 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 methods. The results has been developed with the methods COPRAS-G, OCRA, ARAS and TOPSIS. The different steps involved in these methods were discussed above. The results have been compared in order to determine their convergence and sensibility and ranked the best solutions. III. I. CRITERIA WEIGHTING The comparison among properties of every alternative are in Table 1. The properties identification appears under the name of each property as ( ), ( ), ( ), ( ), (Y), ( ), (λ), and ( ). The weight of each alternative was assigned according to the AHP and Entropy methods. The criteria weighting was firstly performed by the AHP method to obtain the subjective weights of different evaluation criteria. After the decision hierarchy for the problem was designed, the criteria was compared pairwise based on the experience of the author using the scale given in section 3.1.1. In Table 2 is can be showed the scale of relative importance used in the AHP method. The coefficients were assigned based on the characteristic for a MPBR. Table 2. Scale of relative importance Definition Intensity of importance Equal importance 1 Moderate importance 3 Strong importance 5 Very strong importance 7 Extreme importance 9 Intermediate importance 2, 4, 6, 8 account the importance of each criteria. The most important criteria to generate the matrix was considered ( ); slightly more important were taken ( ), ( ), and ( ); strongly more important was considered ( ); demonstrably more important were taken ( ), ( ), ( ). The results are consistent due to the value of the consistency index ( =0,018 for pipes and =0,019 for the vessel) and the consistency ratio which are lower than the limit 0,1. At the final step, the compromised weights of the criteria ( ) were calculated using the Eq. (1). In Table 4 the weight coefficient of every criterion was determined for the pipes of a MPBR. The most representative values are ( ) 54,5 % and (Y), 16,5 %. On the other hand, less than 29 % of the overall weight is distributed in ( ), ( ), ( ), ( ), (λ), and ( ). In Table 5 is presented the decision matrix generated for the vessel of the MPBR. The most important criteria to generate the matrix were considered ( ) and ( ),; slightly more important were taken ( ), ( ) and ( ); strongly more important were considered ( ) and ( ); demonstrably more important was taken ( ). The results are consistent due to the value of the consistency index and the consistency ratio which are lower than the limit 0,1. In Table 6 the weight coefficient of every criterion was determined for the vessel of the MPBR. The most representative values are ( ) 48,3 %, ( ) 13,3 % and ( ) 14,1 %. On the other hand, less than 24,3 % of the overall weight is distributed in ( ), ( ), ( ), ( ) and (λ), In Table 3 is illustrated the decision matrix generated for the pipes of the MPBR which take into Table 3. Comparison among criteria for balanced scales AHP Method for the pipes of the MPBR ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) 1 3 3 3 5 7 7 7 0,333 1 1 1 3 5 5 5 0,333 1 1 1 3 5 5 5 0,333 1 1 1 3 5 5 5 0,2 0,333 0,333 0,333 1 3 3 3 0,143 0,2 0,2 0,2 0,333 1 1 1 0,143 0,2 0,2 0,2 0,333 1 1 1 0,143 0,2 0,2 0,2 0,333 1 1 1 ISSN: 2231-5381 http://www.ijettjournal.org Page 280 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 Table 4. Criteria weighting by the AHP ( ), balanced scales entropy ( ),) and compromised weighting ( ) methods for the pipes of the MPBR. ( ) ( ) ( ( ) ) ( ) ( ) ( ) ( ) 0,348 0,160 0,160 0,160 0,073 0,033 0,033 0,033 0,219 0,023 0,144 0,081 0,153 0,046 0,164 0,170 0,545 0,027 0,165 0,093 0,080 0,011 0,038 0,040 Table 5. Comparison among criteria for balanced scales AHP Method for the vessel of MPBR. ( ) ( ) ( ) ( ) 1 1 3 3 1 1 3 0,333 0,333 0,333 0,333 ( ) ( ) ( ) ( ) 3 5 5 7 3 3 5 5 7 1 1 1 3 3 5 0,333 1 1 1 3 3 5 0,333 1 1 1 3 3 5 0,200 0,200 0,333 0,333 0,333 1 1 3 0,200 0,200 0,333 0,333 0,333 1 1 3 0,143 0,143 0,200 0,200 0,200 0,333 0,333 1 Table 6. Criteria weighting by the AHP ( ), balanced scales entropy ( ),) and compromised weighting ( ) methods for the vessel of the MPBR. ( ) ( ) ( ) ( ) 0,27 0,27 0,113 0,113 0,219 0,023 0,164 0,483 0,051 0,133 4.2 COPRAS-G For application of COPRAS-G method for the materials of the pipes of a MPBR, the related decision matrix is first developed from the gray numbers applied in COPRAS-G are resumed in Table VII. Equations 16 and 17 allow to develop decision matrix which is then weighted normalized, as is given in Table VIII. Later, the normalized matrix and the weight are compared by means of equations 19 y 20. Table IX exhibits the priority values (Qi) and quantitative utility (Ui) values for the candidate alternatives of the pipes of FischerTropsch reactor, as calculated using equations (19) and (21) respectively. Table X also shows the ranking of the alternative material as 7-3-8-1-4-2-5-6. ASME SA-106 and AISI 4140 steel, obtain the first ISSN: 2231-5381 ( ) ( ) ( ) ( ) 0,113 0,048 0,048 0,025 0,046 0,153 0,144 0,081 0,170 0,075 0,141 0,018 0,064 0,035 and second ranks respectively, in contrast PM 1000 ODS Nickel Alloy and PM 2000 ODS Iron Alloy have the last rank. For the materials of the vessel of a MPBR, the related decision matrix is are resumed in Table VII. In Table VIII exhibits the weight normalized decision matrix Table IX shows the priority values (Qi) and quantitative utility (Ui) values and ranking alternatives for the candidate alternatives of the vessel of a MPBR. The ranking of the alternative material are 7-8-2-3-1-4-5-6. ASME SA-106 and ASME SA-516, obtain the first and second ranks respectively, in contrast PM 1000 ODS Nickel Alloy has the last rank. http://www.ijettjournal.org Page 281 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 TABLE I. Material 1 2 3 4 5 6 7 8 Material 1 2 3 4 5 6 7 8 DECISION MATRIX OF COPRAS-G METHOD FOR THE PIPES AND VESSEL OF THE MPBR. ) 278 281 274 228 38 44 125 139 ( 1,8 2,53 2,53 1,93 0,1 0,1 0,3 0,8 TABLE II. NORMALIZED MATRIX MADE OF GRAY NUMBERS FOR THE PIPES OF THE MPBR. ( 0,00 8 0,00 6 0,00 7 0,01 0 0,05 6 0,05 6 0,00 1 0,00 2 ) 0,01 1 0,01 0 0,01 2 0,01 3 0,44 4 0,44 4 0,00 5 0,00 6 ( 0,00 4 0,00 6 0,00 6 0,00 4 0,00 0 0,00 0 0,00 1 0,00 2 ) 2,3 2,81 2,81 2,12 0,15 0,15 0,9 2 ) 0,00 5 0,00 7 0,00 0 0,00 5 0,00 0 0,00 0 0,00 2 0,00 5 TABLE III. ( 270 496 410 205 578 578 330 380 TABLE IV. ( 0,00 7 0,00 5 0,00 6 0,00 8 0,04 9 0,04 9 0,00 1 0,00 2 ) 0,01 0 0,00 9 0,01 1 0,01 2 0,39 3 0,39 3 0,00 5 0,00 5 ) 310 531 420 225 628 626 485 515 ( 14,5 22,4 42,6 16 10,6 11,7 40 41 ( 1,4 0,98 1,09 1,56 1,34 1,14 1,25 1,08 ( ) ( ) ( ) ( ) 0,01 0,01 0,00 0,00 0,00 0,00 0,00 0,00 3 5 6 7 5 5 1 3 0,02 0,02 0,00 0,01 0,01 0,01 0,00 0,00 3 5 9 1 0 0 1 3 0,01 0,02 0,01 0,01 0,01 0,01 0,00 0,00 9 0 8 8 0 0 1 3 0,01 0,01 0,00 0,00 0,00 0,01 0,00 0,00 0 1 7 7 9 1 1 2 0,02 0,03 0,00 0,00 0,01 0,01 0,00 0,00 7 0 4 5 6 6 0 0 0,02 0,03 0,00 0,00 0,01 0,01 0,00 0,00 7 0 5 5 4 4 0 0 0,01 0,02 0,01 0,02 0,00 0,00 0,00 0,00 6 3 6 6 7 8 1 1 0,01 0,02 0,01 0,02 0,00 0,00 0,00 0,00 8 4 7 6 7 8 1 1 PI, RI, QI AND UI VALUES FOR THE PIPES OF THE MPBR. Material Material 1 2 3 4 5 6 7 8 ( ) ( ) 18,1 440 460 112 27,4 815 869 125 42,8 811 879 128 16,4 750 905 119 11,2 1325 1375 30 12,3 1180 1220 20 62 600 700 103 63 595 705 117 ( ) 3,4 5 2,5 4,7 3,2 5,4 4,3 5,9 25 200 25 200 0,6 2,4 0,8 2,7 1 Pi 0,027 Ri 0,089 Qi 0,122 Ui 36,287 Rank 4 2 0,034 0,112 0,110 32,772 6 3 0,035 0,058 0,181 54,123 2 4 0,024 0,089 0,119 35,375 5 5 0,024 0,138 0,086 25,575 7 6 0,024 0,137 0,085 25,479 8 7 0,030 0,028 0,335 100,000 1 8 0,033 0,059 0,174 52,009 3 ) 1,8 1,1 1,35 1,9 1,6 1,44 1,27 1,32 ( ) 0,00 0,00 5 6 0,00 0,00 3 4 0,00 0,00 4 5 0,00 0,00 5 7 0,00 0,00 5 6 0,00 0,00 4 5 0,00 0,00 4 4 0,00 0,00 4 5 ( 0,45 0,42 0,41 0,45 0,44 0,4 0,44 0,45 ) 0,55 0,5 0,53 0,55 0,52 0,48 0,48 0,49 ( 0,00 5 0,00 4 0,00 4 0,00 5 0,00 5 0,00 4 0,00 5 0,00 5 ) 0,00 6 0,00 5 0,00 6 0,00 6 0,00 6 0,00 5 0,00 5 0,00 5 NORMALIZED MATRIX MADE OF GRAY NUMBERS FOR THE VESSEL OF THE MPBR. ( 0,00 8 0,01 1 0,01 1 0,00 8 0,00 0 0,00 0 0,00 1 0,00 4 ISSN: 2231-5381 ) 0,01 0 0,01 2 0,01 2 0,00 9 0,00 1 0,00 1 0,00 4 0,00 9 ( 0,01 7 0,01 2 0,01 3 0,01 9 0,01 7 0,01 4 0,01 5 0,01 3 ) 0,02 2 0,01 4 0,01 7 0,02 3 0,02 0 0,01 8 0,01 6 0,01 6 ( 0,00 1 0,00 2 0,00 3 0,00 1 0,00 1 0,00 1 0,00 3 0,00 3 ) 0,00 1 0,00 2 0,00 3 0,00 1 0,00 1 0,00 1 0,00 4 0,00 4 ( 0,01 7 0,01 6 0,01 5 0,01 7 0,01 6 0,01 5 0,01 6 0,01 7 ) 0,02 1 0,01 9 0,02 0 0,02 1 0,01 9 0,01 8 0,01 8 0,01 8 http://www.ijettjournal.org ( 0,00 1 0,00 1 0,00 1 0,00 1 0,00 0 0,00 0 0,00 1 0,00 1 ) 0,00 1 0,00 1 0,00 1 0,00 1 0,00 0 0,00 0 0,00 1 0,00 1 ( 0,00 0 0,00 0 0,00 0 0,00 0 0,00 0 0,00 0 0,00 0 0,00 0 ) 0,00 1 0,00 0 0,00 0 0,00 1 0,00 0 0,00 0 0,00 0 0,00 0 ( 0,00 2 0,00 4 0,00 4 0,00 4 0,00 7 0,00 6 0,00 3 0,00 3 Page 282 ) 0,00 2 0,00 4 0,00 4 0,00 5 0,00 7 0,00 6 0,00 4 0,00 4 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 PI, RI, QI AND UI VALUES FOR THE VESSEL OF THE MPBR. TABLE V. Material 1 Pi 0,024 Ri 0,037 Qi 0,160 Ui 60,604 Rank 5 2 0,025 0,032 0,184 69,738 3 3 0,026 0,035 0,169 64,094 4 4 0,025 0,040 0,151 57,112 6 5 0,026 0,240 0,047 17,865 7 6 0,024 0,238 0,045 17,090 8 7 0,025 0,021 0,264 100,000 1 8 0,025 0,024 0,233 88,058 2 4.3 OCRA Firstly, the aggregate performance of each alternative with respect to all the input criteria is calculated with equation (22). Applying equation (24), the aggregate performance of the alternatives on all the beneficial or output criteria are then determined and subsequently, the linear preference ratings for the output criteria are calculated. Finally, the overall preference rating for each alternative material is determined using equation (26). The detailed computations of this method for the pipes of a MPBR are illustrated in Table XII. In this method, the ranking material alternatives is obtained as 7-81-2-4-3-6-5, which suggests that ASME SA-106 attains the top rank. ASME SA-516 is the second best choice and PM 1000 ODS Nickel Alloy has the last rank and PM 2000 ODS Iron Alloy is the second last rank. In case of the vessel of the MPBR the computation details for OCRA method for are showed in Table XIII. For this method, the ranking material alternatives is obtained as 7-8-1-4-2-3-6-5. This results suggests that ASME SA-106 is and ASME SA-516 are the best choices for the vessel of a MPBR. On the other hand, PM 1000 ODS Nickel Alloy and PM 2000 ODS Iron Alloy obtain the last rank or alternative materials. COMPUTATION DETAILS FOR OCRA METHOD FOR THE PIPES OF THE MPBR. TABLE VI. Material Rank 1 40,115 39,106 0,018 0,009 39,075 3 2 39,981 38,973 0,022 0,013 38,946 4 3 39,644 38,635 0,023 0,014 38,609 6 4 39,966 38,958 0,012 0,003 38,921 5 5 1,009 0,000 0,049 0,040 0,000 8 6 1,031 0,022 0,049 0,040 0,022 7 7 41,111 40,102 0,009 0,000 40,062 1 8 40,807 39,798 0,014 0,005 39,763 2 TABLE VII. COMPUTATION DETAILS FOR OCRA METHOD FOR THE VESSEL OF THE MPBR. Material Rank 1 35,420 33,366 1,457 1,448 34,774 3 2 35,343 33,289 0,022 0,013 33,262 5 3 35,003 32,949 0,023 0,014 32,923 6 4 35,908 33,854 0,012 0,003 33,817 4 5 2,054 0,000 0,049 0,040 0,000 8 6 2,104 0,050 0,049 0,040 0,050 7 7 37,078 35,024 0,009 0,000 34,984 1 8 36,617 34,563 0,014 0,005 34,527 2 ISSN: 2231-5381 http://www.ijettjournal.org Page 283 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 best solution for the pipes of a MPBR. In contrast, PM 1000 ODS Nickel Alloy has the last rank. For the vessel of the reactor, the values of and , and the ranking achieved by the material alternatives are illustrated in Table XVII. The ranking material alternatives is obtained as 7-8-4-21-3-5-6. ASME SA-106 is the best choice between the alternatives and ASME SA-516 is the second best solution for the material of the vessel of a MPBR. On the other hand, PM 1000 ODS Nickel Alloy and PM 2000 ODS Iron Alloy obtain the last rank or alternative materials. 4.4 ARAS Weighted normalized decision matrix for ARAS method for the pipes of a MPBR, as given in Table XIV, and using equations (29) the optimality function ( ) for each of the materials alternative is calculated. Then, using the equation (30) the corresponding values of the utility degree ( ) are determined for all the alternatives. The values of and , and the ranking achieved by the material alternatives for the pipes of the MPBR are exhibited in Table XV. In this method, the ranking material alternatives is obtained as 7-8-4-1-2-3-6-5. It is revealed from this table that ASME SA-106 is the best alternative and ASME SA-516 is the second TABLE VIII. WEIGHTED NORMALIZED DECISION MATRIX FOR ARAS METHOD FOR THE PIPES OF THE MPBR. ( ) ( ) ( ( ) ( ) 1 0,063 0,001 0,023 0,012 0,012 0,000 0,000 0,006 2 0,074 0,001 0,013 0,008 0,013 0,000 0,001 0,006 3 0,062 0,001 0,016 0,005 0,013 0,000 0,001 0,006 4 0,052 0,001 0,032 0,012 0,013 0,003 0,000 0,006 5 0,002 0,015 0,011 0,018 0,008 0,001 0,000 0,006 6 0,002 0,015 0,011 0,016 0,009 0,002 0,001 0,006 7 0,177 0,003 0,017 0,004 0,016 0,000 0,001 0,006 8 0,152 0,001 0,015 0,004 0,016 0,000 0,001 0,006 TABLE IX. ( ) SI, UI AND RANK VALUES IN ARAS METHOD FOR THE PIPES OF THE MPBR. Material TABLE X. ( ) ) ( ) Material Rank 1 0,118 0,525 4 2 0,115 0,514 5 3 0,103 0,459 6 4 0,118 0,528 3 5 0,063 0,279 8 6 0,063 0,279 7 7 0,224 1,000 1 8 0,196 0,872 2 WEIGHTED NORMALIZED DECISION MATRIX FOR ARAS METHOD FOR THE VESSEL OF A MPBR. ( ) ( ) ( ) ( ) 1 0,052 0,001 0,014 0,003 2 0,061 0,001 0,021 3 0,051 0,001 4 0,043 5 0,002 6 ( ) ( ) ( ) ( ) 0,017 0,003 0,010 0,004 0,002 0,018 0,002 0,006 0,004 0,018 0,002 0,018 0,002 0,004 0,004 0,001 0,013 0,029 0,017 0,004 0,010 0,004 0,020 0,015 0,015 0,017 0,001 0,015 0,003 0,002 0,020 0,017 0,016 0,019 0,001 0,013 0,003 7 0,146 0,004 0,016 0,004 0,018 0,002 0,003 0,006 8 0,125 0,002 0,019 0,004 0,018 0,002 0,003 0,006 Material ISSN: 2231-5381 http://www.ijettjournal.org Page 284 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 TABLE XI. SI, UI AND RANK VALUES IN ARAS METHOD FOR THE VESSEL OF THE MPBR. Material Rank 1 0,104 0,517 5 2 0,116 0,581 4 3 0,101 0,502 6 4 0,121 0,605 3 5 0,088 0,440 8 6 0,092 0,459 7 7 0,200 1,000 1 8 0,178 0,889 2 MPBR. On the other hand, PM 1000 ODS Nickel Alloy has the last rank. In Table XXI is shown the weighted and normalized decision matrix for the vessel of the MPBR. The ideal and nadir ideal solutions are presented in Table XXII for the vessel of the MPBR. The ranking of materials for the vessel of the MPBR is illustrated in Table XXIII. The ranking of the alternative material are 7-8-3-2-1-4-6-5. For TOPSIS method ASME SA-106 is the best choice between the alternatives and ASME SA-516 is the second best choice for the material vessel of a MPBR. On the other hand, PM 1000 ODS Nickel Alloy has the last rank and PM 2000 ODS Iron Alloy is the second last rank. 4.5 TOPSIS The decision matrix given in Table I was normalized using equation (32) for the application of the TOPSIS method and this was multiplied by the compromised weights obtained. In Table XVIII is shown the weighted and normalized decision matrix for the pipes of the MPBR. The ideal and nadir ideal solutions, determined by equations (33) and (34), are presented in Table XIX for the pipes of the Fischer-Tropsch reactor. The distances from the ideal ( ) and nadir ideal solutions ( ) and the relative closeness to the ideal solution ( ) are measured using equations (35)–(37). The materials for the pipes of the MPBR could be ranked by the relative degree of approximation and the ranking is shown in Table XX. The ranking of the alternative material are 7-8-3-1-4-2-5-6. For TOPSIS method ASME SA-106 is the best alternative and ASME SA-516 is the second best choice for the pipes of a TABLE XII. EIGHTED AND NORMALIZED DECISION MATRIX, Mate rial 1 OF TOPSIS METHOD FOR THE PIPES OF THE MPBR. ( ) ( ) ( ( ) 0,026 0,411 0,225 0,176 0,339 0,501 0,409 0,374 2 0,023 0,535 0,399 0,269 0,318 0,522 0,266 0,344 3 0,027 0,535 0,322 0,462 0,319 0,516 0,312 0,351 4 0,032 0,405 0,167 0,175 0,312 0,044 0,442 0,374 5 0,706 0,025 0,468 0,118 0,509 0,087 0,383 0,359 6 0,706 0,025 0,467 0,130 0,453 0,082 0,330 0,329 7 0,009 0,120 0,316 0,552 0,245 0,293 0,347 0,344 8 0,011 0,281 0,347 0,563 0,245 0,329 0,307 0,351 ( ) ( ) ( ) ) ( ) TABLE XIII. HE IDEAL AND NADIR IDEAL SOLUTIONS OF TOPSIS METHOD FOR THE PIPES OF THE MPBR. ( ) ( ) ) ( ) ( ) ( ) 0,006 0,001 0,023 0,044 0,051 0,004 0,002 0,018 0,413 0,021 0,065 0,009 0,024 0,000 0,001 0,016 ISSN: 2231-5381 http://www.ijettjournal.org ( ) ( ( ) Page 285 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 TABLE XIV. OMPUTATION DETAILS FOR TOPSIS METHOD FOR THE PIPES OF THE MPBR. Material 1 0,040 0,399 0,909 Rank 4 2 0,049 0,400 0,892 6 3 0,037 0,399 0,915 3 4 0,041 0,397 0,906 5 5 0,411 0,033 0,074 7 6 0,411 0,029 0,065 8 7 0,034 0,410 0,924 1 8 0,038 0,409 0,915 2 TABLE XV. EIGHTED AND NORMALIZED DECISION MATRIX, Materia l 1 2 3 4 5 6 7 8 ( ) 0,02 6 0,02 ( ) 0,411 3 0,02 7 0,03 0,535 0,535 0,405 2 0,70 6 0,70 0,025 6 0,00 9 0,01 0,120 0,025 0,281 1 ( ) 0,40 9 0,26 ( OF TOPSIS METHOD FOR THE VESSEL OF MPBR. ) ( ) ( ) ( ( ) ) 0,501 0,225 0,374 0,176 0,339 0,522 0,399 0,344 0,269 0,318 6 0,31 2 0,44 0,516 0,322 0,351 0,462 0,319 0,044 0,167 0,374 0,175 0,312 2 0,38 3 0,33 0,087 0,468 0,359 0,118 0,509 0,082 0,467 0,329 0,130 0,453 0 0,34 7 0,30 0,293 0,316 0,344 0,552 0,245 0,329 0,347 0,351 0,563 0,245 7 TABLE XVI. HE IDEAL AND NADIR IDEAL SOLUTIONS OF TOPSIS METHOD FOR THE VESSEL OF THE MPBR. ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( 0,005 0,001 0,035 0,039 0,053 0,008 0,036 0,018 0,341 0,027 0,059 0,003 0,046 0,003 0,008 0,009 TABLE XVII. OMPUTATION DETAILS FOR TOPSIS METHOD FOR THE VESSEL OF THE MPBR. Material 1 0,330 0,039 0,895 Rank 5 2 0,333 0,034 0,908 4 3 0,331 0,030 0,917 3 4 0,326 0,055 0,855 6 5 0,030 0,339 0,081 8 6 0,032 0,339 0,085 7 7 0,339 0,023 0,935 1 8 0,338 0,023 0,937 2 III. VI SPEARMAN’S CORRELATION COEFFICIENTS In Table 24 and Table 25 is shown the Spearman‟s correlation coefficients for the pipes and the vessel of the MPBR. These represent the mutual correspondence among MCDM methods. The ISSN: 2231-5381 magnitude of this parameter for the pipes of the MPBR exceeds 0,57 for the relation between all the methods. In case of the relation between COPRASG, ARAS and TOPIS methods, the Spearman‟s correlation coefficients exceeds 0,7. http://www.ijettjournal.org Page 286 ) International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 Table 24. Spearman‟s correlation indexes for the pipes of the MPBR OCRA ARAS TOPSIS COPRAS 0,571 0,571 0,952 OCRA - 0,893 0,702 ARAS - - 0,702 Table 25. Spearman‟s correlation indexes for the vessel of the MPBR COPRA S OCRA ARAS OCRA 0,571 - ARAS 0,702 0,893 - TOPSIS 0,810 0,810 0,952 The Spearman‟s correlation coefficients for the vessel of the MPBR exceeds 0,57 for the relation of all the cases. In case of the relation between COPRAS-G, ARAS and TOPIS methods, the Spearman‟s correlation coefficients exceeds 0,81. IV DISCUSSION For design a MPBR, many studies has been used CFD for detailed evaluation of reaction systems [5] However, for this design usually engineers use certain materials based on experience and other studies, but they do not make a preliminary selection. The MCDM are an important tool to recognize and identify the best material alternative in a bunch of several of them. These methods can adapt to different sort of environments and conditions that would affect the final result and that is why these approaches are applied in different areas of science, engineering and management. Figure 2. ISSN: 2231-5381 In this case, we take advantage of MCDM methods in order know the best alternative for the pipes and the vessel of the MPBR. In Fig. 2 is resumed the overall rank of each MCDM method for the pipes of the MPBR. It has been observed than in all the cases, the best alternative and second best alternative correspond with ASME SA-106 and ASME SA-516 because it low cost and good ( ). In addition, PM 1000 ODS Nickel Alloy and PM 2000 ODS Iron Alloy are presented on the last rank alternatives in all the MCDM methods considered. On the other hand In Fig. 3 is illustrated the overall rank of each MCDM method for the vessel of the MPBR. It has been observed than in all the best alternative and second best alternative correspond with ASME SA-106 and ASME SA-516 because it low cost and good ( ) and PM 1000 ODS Nickel Alloy and PM 2000 ODS Iron Alloy appear on the last rank alternatives in the most of the MCDM analyzed too. The method validation was correlated by Spearman‟s coefficients. The magnitude of this parameter for the pipes and the vessel of the MPBR exceeds 0,57 for the relation between all the methods. The results show that make a MPBR with ASME SA-106 and ASME SA-516 could reduce the manufacturing cost with a good corrosion rate, yield strength and fracture toughness. This properties should improve the life at service of the MPBR. In addition, it should take into account that the maximum temperature at service it is around 650°C. In case of the maximum temperature at service overpass this value it should choose other alloy. Finally, the high thermal conductivity of this alloys suggest to control the outer surface of the MPBR. Rank materilas vs. alternative materials for the pipes of the MPBR http://www.ijettjournal.org Page 287 International Journal of Engineering Trends and Technology (IJETT) – Volume 34 Number 6- April 2016 Figure 3 Rank materilas vs. alternative materials for the vessel of an MPBR V CONCLUSIONS Use of bioenergy energy produced from organic matter or biomass has the potential to increase energy security, promote economic development, and decrease global warming pollution. For this reason, it is necessary to improve the design of the technology to produce bioenergy in an efficiency way. In this paper the material selection problem for a MPBR has been solved utilizing a decision model. The alternative materials were successfully evaluated using all the considered methods. Ranking scores which were used to rank the alternative materials were obtained as results of the methods. The model includes the COPRAS-G, OCRA, ARAS and TOPSIS methods for the ranking of the alternative materials according to determined criteria. The weighting of the material properties was performed using the compromised weighting method composes of the AHP and Entropy methods According to the results, ASME SA-106 would be the best material for the pipes and the vessel of a MPBR and ASME SA-516 the second best choice. The main contribution to the field of this results is to obtain a material with an adequate corrosion rate and mechanical properties with the lowest cost. In contrast, it is necessary to take into account that the maximum temperature at service is 650 °C for these alloy and control the outer surface of the MPBR. It was validated that the MCDM approach is a viable tool in solving the complex material selection decision problems. Spearman‟s rank correlation coefficient was found to be very useful in assessment of the correlation between all the ranking methods. The model which was developed for the material selection for the pipes and the vessel of a ISSN: 2231-5381 MPBR can be applied on other mechanical components for material selection problems. The materials analyzed in this paper are used in industrial applications and their workability are reasonable. In this way they could be used in industrial applications and for build a MPBR. ACKNOWLEDGEMENTS The authors of this research acknowledge to the Secretaría Nacional de Planificación y Desarrollo (SENPLADES) for financing the execution of the present research. This work was sponsored by the Prometeo project of the Secretaria de Educación Superior, Ciencia, Tecnología e Innovación (SENESCYT) held in the Republic of Ecuador. The information necessary to complete this work was given by the Ministerio de Electricidad y Energía Renovable (MEER) of Ecuador REFERENCES [1] Iglesia, E. 1997. Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts. 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