International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 Pond Ash and Foundry Sand: Opportunities for Development of Eco-Friendly High Strength Concrete Gaurav Kantibhai Patel1, Prof. Jayeshkumar Pitroda2, Student of final year of M.E. in C.E &M., B.V.M. Engineering College, Vallabh Vidhyanagar 2 Assistant Professor & Research Scholar, Civil Engg Department, B.V.M. Engineering College, Vallabh Vidhyanagar- Gujarat-India 1 ABSTRACT -To produce low cost concrete by replacement of fine aggregate with pond ash and used foundry sand & also reduce disposal and pollution problems due to pond ash and used foundry sand. The innovative use of pond ash and used foundry sand in concrete formulations as a fine aggregate replacement material was tested as an alternative to traditional concrete. The fine aggregate has been replaced by used foundry sand accordingly in the range of 0%, 10%, 20%, 30%, 40% & 50% by weight and pond ash 20% for M-20 grade and M-40 grade concrete. Concrete mixtures were produced, tested and compared in terms of workability and strength with the conventional concrete. These tests were carried out to evaluate the mechanical properties for 7, 14 and 28 days. As a result, the compressive strength increased up to 30% addition of used foundry sand and 20% pond ash. Keywords : Pond ash, used Foundry sand, waste materials,Eco friendly concrete, Green Concrete, Compressive Strength, water Absorption EXPERIMENTAL MATERIALS A. Materials INTRODUCTION Use of Industrial Waste and by-products in concrete will lead to green environment and such concrete can be called as “Green Concrete”. Pond ash is produced as a result of combination of coal; Fly ash and bottom ash are mixed together with water to form a slurry, which is pumped to the ash pond area. In ash pond area, ash gets settled and excess water is decanted. This deposited ash is called Pond ash. This is used as filling materials including the construction of roads and embankments. Selected pond ash is used for manufacturer of building products like lime fly ash bricks/ blocks etc. Foundries for the metal-casting industry generate by products such as used foundry sand. Metal ISSN: 2231-5381 foundries use large amount of the metal casting process. Foundries successfully recycle and reuse the sand many times in a foundry and the remaining sand that is termed as foundry sand is removed from foundry. Use of foundry sand in various engineering applications can solve the problem of disposal of foundry sand and other purposes. Used Foundry sand can be used in concrete to improve its strength and other durability factors. Foundry Sand can be used as a partial replacement of fine aggregates or total replacement of fine aggregate and as supplementary addition to achieve different properties of concrete. To reduce disposal and pollution problems emanating from these industrial wastes, it is most essential to develop profitable building materials from them. Keeping this in view, investigations were undertaken to produce low cost concrete by blending various ratios of fine aggregate with used foundry sand and Pond Ash. a) Pond Ash Pond ash is produced as a result of combination of coal; Fly ash and bottom ash are mixed together with water to form a slurry, which is pumped to the ash pond area. In ash pond area, ash gets settled and excess water is decanted. This deposited ash is called Pond ash. The disposal of Pond ash will be a big challenge to environment, especially when the quantum increases from the present level. Hence worldwide research work was focused to find alternative use of this waste material and it’s in concrete industry is one of the effective methods of utilization. The disposal of fly ash will be a big challenge to environment, especially when the quantum increases from the present level. Hence http://www.ijettjournal.org Page 301 International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 worldwide research work was focused to find alternative use of this material and its use in concrete industry is one of the effective methods of utilization. Increase in demand and decrease in natural resource of fine aggregate for the production of concrete has resulted in the need of identifying a new source of fine aggregate. The possibility of utilization of thermal power plant by product pond ash as replacement to fine aggregate in concrete is taken into consideration. Chemical Composition of pond ash and Physical Properties of Pond Ash show in table 1 and table 2. Table 2 Physical Properties of pond ash Physical properties Value Specific gravity 1.89 Liquid limit (%) 60 % Passing through 75 µ sieve 16 Coefficient of uniformity 3.61 Coefficient of Curvature 1.81 Water Absorption 16 % (Source: Report, KCT laboratory, Ahmedabad, Gujarat, India) b) Foundry sand Metal foundries use large amounts of the metal casting process. Foundries successfully recycle and reuse the sand many times in a foundry and the remaining sand that is termed as foundry sand is removed from foundry. This study presents the information about the civil engineering applications Fig.1 Pond Ash (Source: Vanakbori Power station, Vanakbori, Gujarat, India) of foundry sand, which is technically sound and is Table 1 Chemical Composition of pond ash environmentally safe. Use of foundry sand in various engineering applications can solve the Sr. Chemical No. Composition 1 CaO% 0.25 sand, coated with a thin film of burnt carbon, 2 SiO % 73.6 residual binder and dust. Foundry sand can be used 3 Al O % 9.1 in concrete to improve its strength and other 4 MgO% 0.05 5 SO % 0.01 6 NaO % 0.004 of fine aggregate and as supplementary addition to 7 K O% 0.002 achieve different properties of concrete. Chemical 8 Total Chloride% 0.002 9 Loss on Ignition% 3.7 10 Fe O % 1.35 11 TiO % Nil 2 2 3 3 2 2 2 3 2 Value (%) problem of disposal of foundry sand and other purposes. Foundry sand consists primarily of silica durability factors. Foundry Sand can be used as a partial replacement of cement or as a partial replacement of fine aggregates or total replacement Composition of Used Foundry Sand and Physical Property of Used Foundry Sand show in table 3 and table 4. (Source: Report, KCT laboratory, Ahmedabad, Gujarat, India) ISSN: 2231-5381 http://www.ijettjournal.org Page 302 International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 Table 5 Physical Property of Coarse Aggregate Sr. No 1 2 3 4 Fig.2 Foundry sand ( Source: Margo Cast Iron, Mehsana, Gujarat, India) Table: 3 Chemical Composition of Used 5 6 Foundry Sand Constituents Value SiO2 83.93 Al2 O3 0.021 Fe2O3 0.95 CaO 1.03 MgO 1.77 SO3 0.057 Na2O3, K20, SrO, TiO2 10.052 LOI 2.99 7 8 Specific Gravity 2.44 Bulk Relative Density, kg/m3 2589 Absorption, % Moisture content, % 0.45 0.15 Sr. No Name of Tests Natu ral Sand 1 Specific Gravity 2.65 2 Fineness Modulus 2.79 3 4 c) Coarse Aggregate Natural coarse aggregate locally available from Amarnath qurry works, Jashavant gath (bhemal, Danta) has been used size 20 mm and 10mm.Physical Property of coarse aggregate show in table 5. ISSN: 2231-5381 10mm 2.0 2.1 - 2.8 2.8 2.6-2.9 0.7 0.9 Max.2.0 % 5.9 5.0 - 6.9 9.3 - 10.85 16.49 Max.45% 29.84 21.77 Max.45% 12.92 25.56 Max.45% d) FINE AGGREGATE (SAND) Locally available fine aggregate from Bannas River (in Deesa) has been used having present size less than 4.25 mm. property of sand show in table 6 Table 6. Property of Sand Table: 4 Physical Property of Used Foundry Sand Value Fineness Modulus of the Coarse Aggregate Specific Gravity of Coarse aggregate Water Absorption (%) Elongation Index (%) Flakiness index (%) Aggregate Abrasion Value (%) Aggregate Crushing Value Aggregate Impact value 20mm (Source: Testing Report, KCT Laboratory, Ahmedabad, Gujarat, India) (Source: Geo Test House, Vadodara, Gujarat, India) Properties Physical Property Requirements of MORTH sec no.500 5 sieve analysis for grading Water Absorpti on (%) Bulk Density (kg/m3) II 0.99 % 1759 IS Code IS 2386 (Part III)1963 IS 2386 (Part I)1963 IS 2386 (Part I)1963 IS 2386 (Part III)1963 IS 2386 (Part III)1963 Permissib le limit - see IS 383-1970 Table 4 0.7% to 1.3% - (Source: Testing Report, KCT Laboratory, Ahmedabad, Gujarat, India) http://www.ijettjournal.org Page 303 International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 e) Cement The most common cement used is an ordinary Portland cement. The Ordinary Portland Cement of 53 grade (HATHI cement OPC) conforming to IS: 8112-1989 is be use. Many tests were conducted on cement; some of them are consistency tests, setting tests, soundness tests, etc Chemical Compositions of cement and Physical Property of cement show in table 7 and table 8. Table 7 Chemical Compositions of cement Sr. No Chemical Composition IS Code Test result (%) Require ments as per IS: 12269 1 Lime Saturation Factor (%) IS: 4032 0.91 0.8-1.02 2 Alumina Iron Ratio(%) IS: 4032 1.16 min. 0.66 3 Insoluble Residue(%) IS: 4032 1.44 Max.2% 4 Magnesia(%) IS: 4032 5 Sulphuric Anhydride(%) IS: 4032 2.11 Max.3% 6 Loss on Ignition(%) IS: 4032 2.38 Max. 4% 7 Chloride IS: 4032 0.025 - Table.8 Physical Property of cement Sr. No 1 2 3 Physical Property Fineness Specific Surface m2/Kg Soundness in mm setting time in min (a) Initial IS Code Test result (%) IS: 4031 299 IS: 4031 1.25 IS: 4031 108 (b) Final 5 2.77 Max.6% Consistency in % Compressive strength in N/mm2 (a) After 3 days (b)After 7 Days (Source: Testing Report, KCT Laboratory, Ahmedabad, Gujarat, India) ISSN: 2231-5381 4 Min. 30 min Max. 600 min 222 IS: 4031 Requir ements as per IS: 12269 Min. 225 m2/Kg Max. 10mm 27 - 36.9 27Mpa 44.9 37 Mpa IS: 4031 (Source: Testing Report, KCT Laboratory, Ahmedabad, Gujarat, India) DESIGN MIX (As Per IS 10262 – 2009) A mix M20 and M40 grade was designed as per Indian Standard method and the same was used to prepare the test samples. The design mix proportion is done in Table 9. http://www.ijettjournal.org Page 304 International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 W 203.85 235.56 EXPERIMENTAL METHODOLOGY The evaluation of Used Foundry Sand and pond ash for use as a replacement of fine aggregate material begins with the concrete testing. Concrete contains cement, water, fine aggregate, coarse aggregate and grit. With the control concrete, i.e. 10%, 20%, 30%, 40% and 50% of the fine aggregate is replaced with used foundry sand and 20% of the fine aggregate is replaced with pond ash. The data from the used foundry sand and pond ash is compared with data from a standard concrete without used foundry sand. Three cube samples were cast on the mould of size 150*150*150 mm for each concrete mix with partial replacement of fine aggregate with w/c ratio were also cast. After about 24 h the specimens were de-moulded and water curing was continued till the respective specimens were tested after 7,14 and 28 days for compressive strength and water absorption tests. Compressive strength Test Compressive strength tests were performed on compression testing machine using cube samples. Three samples per batch were tested with the average strength values reported in this paper. The loading rate on the cube is 35 N/mm2 per min. The comparative studies were made on their characteristics for concrete mix ratio of with partial replacement of fine aggregate with used foundry sand and pond ash. 434.60 295.66 434.60 357.22 295.66 264.89 234.11 203.33 298.98 298.98 362.39 267.27 G 447.31 447.31 651.90 651.90 434.60 434.60 434.60 434.60 447.31 447.31 447.31 447.31 CA 670.97 670.97 307.77 384.72 651.90 651.90 651.90 651.90 670.97 670.97 670.97 670.97 F 0.00 79.27 153.89 153.89 230.83 153.88 76.944 0.00 237.81 317.08 396.36 158.54 PA 0.00 158.54 153.89 0.00 153.89 153.89 153.89 0.00 158.54 158.54 158.54 158.54 FA 792.72 634.18 475.63 317.09 158.54 0.00 465.00 465.00 307.78 461.66 615.55 769.44 413.30 413.30 413.30 465.00 465.00 465.00 B2 B3 B4 465.00 A3 A4 413.30 413.30 413.30 C DESIGN MIX PURPORTION (WEIGHT IN KG) A5 A2 EXPERIMENTAL SET UP B5 TYPE-B M40 B1 B0 TYPE-A M20 A1 A0 TYPES Table 9: Concrete Design Mix (M20 and M40 Mix) Proportions (C: Cement, PA: Pond Ash, FS: Foundry Sand, FA: Fine aggregate, CA: Coarse Aggregate, G: Grit, W: Water) Figure: 3 Setup of Compression Strength Testing Machine ISSN: 2231-5381 http://www.ijettjournal.org Page 305 International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 7 Days 14 Days 28 Days 37.19 38.07 38.67 COMPRESSIVE STRENGTH (N/mm2) Table 10: Compressive Strength of Cubes (150x150x150mm) For M20 & M40 Mix at 7, 14, 28 Days Avg. Compressive Strength Concrete ( N/mm2) Mix 7 Days 14 Days 28 Days A0 13.70 14.96 20.89 A1 14.22 15.11 21.78 A2 14.52 15.56 21.93 A3 15.70 16.74 23.11 A4 13.48 14.96 21.63 A5 13.19 14.07 20.74 B0 26.22 27.85 37.19 B1 26.37 27.26 38.07 B2 27.70 28.89 38.67 B3 29.78 31.11 42.22 B4 24.59 25.48 37.63 B5 24.15 24.74 35.70 45.00 40.00 35.00 30.00 25.00 20.00 15.00 10.00 5.00 0.00 42.22 37.63 35.70 31.11 27.85 27.26 28.8929.78 25.48 24.74 26.22 26.37 27.70 24.59 24.15 B0 (0% FS + 0% PA) B1 (10% FS + 20% PA) B2 (20% FS + 20% PA) B3 (30% FS + 20% PA) B4 (40% FS + 20% PA) B5 (50% FS + 20% PA) % REPLACEMENT OF FOUNDRY SAND AND POND ASH WITH FINE AGGREGATE IN M40 GRADE CONCRETE MIX Figure: 5 % Replacement of Foundry Sand and pond ash V/S Compressive Strength (N/mm2) of Concrete for M40 mix at 7, 14 and 28 days Water Absorption Test 7 Days 14 Days 21.93 20.89 21.78 28 Days 23.11 21.63 20.74 COMPRESSIVE STRENGTH (N/mm2) 25.00 20.00 15.00 16.74 14.96 15.11 15.5615.70 14.96 14.07 13.70 14.22 14.52 13.48 13.19 10.00 5.00 0.00 A0 A1 (0% FS (10% + 0% FS + FA) 20% PA) A2 (20% FS + 20% PA) A3 (30% FS + 20% PA) A4 (40% FS + 20% PA) A5 (50% FS + 20% PA) % REPLACEMENT OF FOUNDRY SAND AND POND ASH WITH FINE AGGREGATE IN M20 GRADE CONCRETE MIX Figure: 4 % Replacement of Foundry Sand and pond ash V/S Compressive Strength (N/mm2) of Concrete M20 mix at 7, 14 and 28 days ISSN: 2231-5381 The cubes after casting were immersed in water for 28 days curing. They were then weighted and this weight was noted as the wet weight of the cube. These specimens were then oven dried at the temperature 1100C until the mass became constant and again weighed. This weight was noted as the dry weight of the cube. % Water Absorption = [(WW – DW) / DW] x 100 Where, WW = Wet Weight of Cube, DW = Dry Weight of Cube. TABLE 11: Water Absorption of Cubes (150x150x150mm) M20 & M40 Mixes at 28 Days Avg. Water Absorption (%) Concrete Mix At 28 Days A0 1.42 A1 1.40 A2 1.39 A3 1.38 A4 1.42 A5 1.45 B0 1.48 B1 1.44 B2 1.41 B3 1.32 B4 1.45 B5 1.46 http://www.ijettjournal.org Page 306 International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 WATER ABSORPTION (%) 28 Days 1.50 1.42 1.40 1.45 1.42 1.39 1.38 1.40 ACKNOWLEDGMENT 1.30 A0 (0% FS + 0% FA) A1 (10% FS + 20% PA) A2 (20% FS + 20% PA) A3 (30% FS + 20% PA) A4 (40% FS + 20% PA) A5 (50% FS + 20% PA) % REPLACEMENT OF FOUNDRY SAND AND POND ASH WITH FINE AGGREGATE IN M20 GRADE CONCRETE MIX WATER ABSORPTION (%) Figure: 6 % Replacement of Foundry Sand and pond ash V/S Water Absorption (%) of Concrete M20 mix at 7, 14 and 28 days 28 Days 1.48 1.50 strength at 30% replacement and 20% pond ash replacement. c) The water absorption decreased up to 30% replacement of fine aggregate by used foundry sand d) Environmental effects from wastes and disposal problems of waste can be reduced through this research. 1.44 1.45 1.46 1.41 1.40 1.32 1.30 1.20 B0 B1 B2 B3 B4 B5 (0% (10% (20% (30% (40% (50% FS + FS + FS + FS + FS + FS + 0% 20% 20% 20% 20% 20% PA) PA) PA) PA) PA) PA) % REPLACEMENT OF FOUNDRY SAND AND POND ASH WITH FINE AGGREGATE IN M40 GRADE CONCRETE MIX Figure: 7 % Replacement of Foundry Sand and pond ash V/S Water Absorption (%) of Concrete M20 mix at 7, 14 and 28 days CONCLUSIONS Based on limited experimental investigation concerning the water absorption and compressive strength of concrete, the following observations are made regarding the resistance of partially replaced foundry sand and pond ash. a) Compressive strength increase when replacement of used foundry sand percentage increases when compare to traditional concrete. b) From this test, replacement of fine aggregate with this used foundry sand material provides maximum compressive ISSN: 2231-5381 The Authors thankfully acknowledge to Dr. C. L. Patel, Chairman, Charutar Vidya Mandal, Er. V. M. Patel, Hon. Jt. Secretary, Charutar Vidya Mandal, Mr. Kantibhai Patel, Rakesh construction, mehsana. Dr. F. S. Umrigar, Principal, B.V.M. Engineering College, Prof. J. J. Bhavsar, Associate Professor, PG Coordinator, Civil Engineering Department, B.V.M. Engineering College Vallabh Vidyanagar, Gujarat, India for their motivations and infrastructural support to carry out this research. REFERENCES [1] Ashis Kumar Bera etal., (April, 2007), compac tion characteristics of pond ash, 'Journal of ma terials in Civil Engg', 19(4), pp 349357. [2] Bruce A. Dockter etal., (1999),international as h utilization symposium, 1999 centre for use o f bottom ash and fly ash in rammed earth const ruction applied energy research, university of Kentucky. [3] S.A. Haldive, Dr. A. R. Kambekar ,Experimental Study on Combined Effect of Fly Ash and Pond Ash on Strength and Durability of Concrete, International Journal of Scientific & Engineering Research Volume 4, Issue 5, May-2013 , ISSN 2229-5518 [4] Abichou T. Benson, C. Edil T., 1998a.Database on beneficial reuse of foundry by- products. Recycled materials in geotechnical applications, Geotech. Spec. Publ.No.79, C. Vipulanandan and D.Elton, eds., ASCE, Reston, Va., 210-223 [5] Dushyant R.Bhimani, Prof. Jayeshkumar Pitroda,Prof. Jaydevbhai J.Bhavsar, “A Study On Foundry Sand: Opportunities For Sustainable And Economical Concrete”, International Journal Global Research Analysis (GRA) Jan 2013Volume: 2 Issue: 1ISSN No 2277 – 8160 Page No. 60 [6] Dushyant R.Bhimani, Prof. Jayeshkumar Pitroda,Prof. Jaydevbhai J.Bhavsar, “Effect of Used Foundry Sandand Pozzocrete Partial http://www.ijettjournal.org Page 307 International Journal of Engineering Trends and Technology (IJETT) – Volume 9 Number 6 - Mar 2014 Replacement with Fine Aggregate and Cement in Concrete”, International Journal of Innovative Technology and Exploring Engineering (IJITEE) ISSN: 2278-3075, Volume-2, Issue-4, March 2013 [7] Dushyant R.Bhimani, Prof. Jayeshkumar Pitroda,Prof. Jaydevbhai J.Bhavsar, “Used Foundry Sand: Opportunities For development Of Eco-Friendly Low Cost Concrete’ International Journal of Advanced Engineering Technology, Vol. IV/ Issue I/Jan.-March., 2013/63-66 [8] Fredlund, D.G., Morgenstern, N.R., Widger, R.A., 1978.Shear strength of soils.Can.Geotech.J.,Ottawa,15(3),313-321 [9] IS 10262:2009, recommended guidelines for concrete mix Design, BIS. New Delhi, India, 2009. [10] IS 2386-1963 – PART I- Particle Size And Shape [11] IS 2386-1963 –Part Ill-Specific Gravity, Density, Voids‘Raio, Absorptlon And Bulking [12] IS 456-2000, Plain and Reinforced Concrete Code of practice (fourth revision, BIS. New Delhi. [13] IS: 383-1970, Specification for Coarse and Fine Aggregates from natural sources for concrete (Second revision). [14] M.S. Shetty. Concrete Technology, Book AUTHORS BIOGRAPHY Gaurav Kantilal Patel was born in 1990 in Mehsana, Mehsana District, Gujarat. He received his Bachelor of Engineering degree in Civil Engineering from the U.V.Patel Engineering college,Kherva, Ganpat University, Mehsana, Gujarat. In 2012 At present he is Final year student of Master`s Degree in Construction Engineering and Management from Birla Vishwakarma Mahavidyalaya, Gujarat Technological University. Prof. Jayeshkumar R. Pitroda was born in 1977 in Vadodara City. He received his Bachelor of Engineering degree in Civil Engineering from the Birla Vishvakarma Mahavidyalaya, Sardar Patel University in 2000. In 2009 he received his Master's Degree in Construction Engineering and Management from Birla Vishvakarma Mahavidyalaya, Sardar Patel University. He joined Birla Vishvakarma Mahavidyalaya Engineering College as a faculty where he is Assistant Professor of Civil Engineering Department with a total experience of 13 years in the field of Research, Designing and education. He is guiding M.E. (Construction Engineering & Management) Thesis work in the field of Civil/ Construction Engineering. He has papers published in National Conferences and International Journals. ISSN: 2231-5381 http://www.ijettjournal.org Page 308