International Journal of Engineering Trends and Technology (IJETT) – Volume3 Issue 6 Number2–Dec 2012 EXPERIMENTAL STUDY ON PARTIAL REPLACEMENT OF CEMENT BY BENTONITE IN PAVERBLOCK J. Chamundeeswari Department of Civil Engineering Bharath University, Selaiyur, Chennai-73. ABSTRACT Cement concrete continuous to be pre-eminent construction materials for use in any type of civil engineering applications. Performance of any civil engineering structures in terms of their strength and stability has with stood the test of time but the life span of the structures has become a matter of concern. This is on account of the environment becoming chemically ever more aggressive. The atmosphere is found increasingly laden with higher percentage sulphur dioxide & carbon dioxide. Due to the production of cement which is one of the ingredient in the preparation of Concrete, equal amount of Carbon-di-oxide evolves which is the important reason for ozone depletion. In order to replace the cement which is the main ingredient in concrete, lots of innovative materials are compared to the composition of cement .In this project, cement is partially replaced by bentonite. It includes the composition of cement. The specimens are tested for 7 days and 28 days strength and their behavior are studied under compression as per the method recommended by the Indian standards. In this paper ,the study and the replacement of cement by Bentonite to find out the strength parameters of concrete specimen .The replacement includes of 10%,20%,30%,40%,50%.Finally the optimum percentage is arrived. KEYWARDS: Bentonite, cement, optimum percentage INTRODUCTION In this paper, an attempt has made to overcome this problem by the limited use of Bentonite powder in place of Cement. Bentonite is a clay generated frequently from the alteration of volcanic ash, consisting predominantly of smectite minerals, usually montmorillonite.Bentonite presents strong colloidal properties and its volume increases several times when coming into contact with water, creating a gelatinous and viscous fluid The special properties of bentonite (hydration, swelling, water absorption, viscosity, thixotropy) make it a valuable material for a wide range of uses and applications. Bentonite deposits are normally exploited by quarrying. Extracted bentonite is distinctly solid, even with a moisture content of approximately 30%. The material is initially crushed and, if necessary, activated with the addition of soda ash (Na2CO3). Bentonite is subsequently dried (air and/or forced drying) to reach a moisture content of approximately 15%. According to the final application, bentonite is either sieved (granular form) or milled (into ISSN: 2231-5381 http://www.ijettjournal.org Page 41 International Journal of Engineering Trends and Technology (IJETT) – Volume3 Issue 6 Number2–Dec 2012 powder and super fine powder form). For special applications, bentonite is purified by removing the associated gangue minerals, or treated with acids to produce acid-activated bentonite (bleaching earths), or treated with organics to produce organoclays.The following are the types of bentonite Sodium bentonite,Calcium bentonite andPotassium bentonite LABORATORY TEST Concrete is an artificial material which is made up of cement, fine aggregate, coarse aggregate and water. In this paper, an attempt has been made to replace cement by Bentonite.Hence the properties of material have been arrived by conducting laboratory tests and the results. Cement 53 grade cement is used for the experimental study. Compressive Strength 53 Mpa, Specific Gravity3.15, Initial Setting Time 30 min, Final Setting time 570 min. Fine aggregate A concrete with better quality can be made with sand consisting of rounded grains rather than angular grains. The sand used belongs to the Zone 3. Fineness modulus 3.24, Specific Gravity 2.58, Size Passing through 4.75mm sieve, Water absorption ratio 1%. Coarse Aggregate Aggregate must be clean and free from impurities. The coarse aggregate used in this study is of the size 10mm. Fineness modulus 4, Specific Gravity 2.69, Size Passing through 12 mm and retaining in 10mm sieve, Water absorption ratio 0.50%. Water As per IS-456,2000 the minimum pH value of water is 6.Locally available potable water with pH value of 7.35 was used in present work Water is an important in gradient of concrete as it actively participates in chemical reactions with cement. Clean portable water conforming to IS 456-2000 was used for the preparation of concrete mixture. Water cement ratio (W/C) ISSN: 2231-5381 http://www.ijettjournal.org Page 42 International Journal of Engineering Trends and Technology (IJETT) – Volume3 Issue 6 Number2–Dec 2012 The ratio of cement by weight is termed as “water-cement ratio” and the strength and quality of concrete primarily depends upon this ratio. Slump Cone Test Table .4 Slump Cone Test W/C Ratio % of Water Volume of water in Slump in mm ml 0.35 35 1050 20 0.35 35 1050 18 0.35 35 1050 20 Bentonite Bentonite is available in powder and solution form,which can replaces cementupto 50% of cement used in the concerte. Table.5 Properties Of Bentonite Chemical composition Titanium Oxide TiO2 01.25 Ferric Oxide Fe2O3 10.91 Silica SiO2 54.26 Aluminum Al2O3 18.34 PhysicalCharacteristics Specific Gravity 2.4 pH 8 to 8.8 Bulk Density gms / cc 0.6 ISSN: 2231-5381 http://www.ijettjournal.org Page 43 International Journal of Engineering Trends and Technology (IJETT) – Volume3 Issue 6 Number2–Dec 2012 Concrete Mix Detail Table .6 Mix Proportion in kg/ m3 Cement Fine aggregate 578.57 kg 384.67 kg Mix Proportion of M50 Grade Concrete Coarse aggregate 1140.78 kg Water – Cement ratio 0.35 Proportioning of concrete mixture consists of determination of the respective ingredients necessary to produce concrete having adequate workability, strength and durability for the particular strength and for various exposure conditions. The mixture proportions for the controlled concrete of M50 grade was arrived from the trial mixes as per Indian Standard (IS 10262 – 1982) specifications and found to be 1:0.65:1.95 (W/C = 0.35). This Mixture was used throughout the study. The concrete mix design was proposed to achieve the compressive strength of50MPa after 28 days curing. Fig.1 Casted Specimen Fig.2 compression test for specimen RESULTS In this study, an attempt has been made to evaluate the mechanical properties such as compressive strength with and without bentonite. The compressive strength of the cubes after replacing the cement by 10%, 20%, 30%,40%,50% with Bentonite is studied after 28 days. Compressive Strength of Concrete The compressive strength of concrete with and without bentonite is studied. Tests are conducted and the results are as follows ISSN: 2231-5381 http://www.ijettjournal.org Page 44 International Journal of Engineering Trends and Technology (IJETT) – Volume3 Issue 6 Number2–Dec 2012 Table.7. compressive test result SAMPLE 7DAYS COMPRESSIVE 28 DAYS COMPREESIVE C₁₀₀ B₀ STRENGTH (N/MM2) 38.020 C₉₀ B₁₀ 36.750 53.955 C₈₀ B₂₀ 31.860 47.370 C₇₀B₃₀ 23.570 41.847 C₆₀ B₄₀ 18.690 30.589 C₅₀B₅₀ 14.230 24.003 STRENGTH(N/MM2) 56.929 Fig.3.7thday compressive strength ISSN: 2231-5381 http://www.ijettjournal.org Page 45 International Journal of Engineering Trends and Technology (IJETT) – Volume3 Issue 6 Number2–Dec 2012 Fig.4.4 28th day compressive strength Fig.4.5 comparison of 7th and 28th day compressive strength ISSN: 2231-5381 http://www.ijettjournal.org Page 46 International Journal of Engineering Trends and Technology (IJETT) – Volume3 Issue 6 Number2–Dec 2012 CONCLUSION From this experiment, we conclude that, by the usage of bentonite powder, we can increase the compressive strength and decrease the cement content in concrete up to 30%. As the cement content in the concrete is reduced, the usage of cement wills also decreases thereby the ozone layer depletion by emission of carbon-di-oxide from the cement factory will also reduce and the environment will also kept clean. Replacing the amount of cement used by bentonite powder decreases the total expenses of cement by 50% REFERENCE 1. Utilization of Pakistani bentonite as partial replacement of cement in concrete Construction and Building Materials, Volume 30, May 2012, Pages 237-242 Shazim Ali Memon, Rao Arsalan, Sardar Khan, Tommy Yiu Lo 2. Effects of supplementary cementing materials on the properties of cement and concrete Cement and Concrete Research, Volume 32, Issue 10, October 2002, Pages 1551-1558 Ş. Targan, A. Olgun, Y. Erdogan, V. Sevinc 3. Methods of Tests for strength of Concrete IS: 516 – 1959, 15th reprint August 1993, Bureau of Indian Standards, New Delhi. 4. Interaction of bentonite with supercritically carbonated concrete Applied Clay Science, Volume 42, Issues 3–4, January 2009, Pages 488-496 F.J. Huertas, A. Hidalgo, M.L. Rozalén, S. Pellicione, C. Domingo, C.A. GarcíaGonzález, C. Andrade, C. Alonso 5. Pakistani bentonite in mortars and concrete as low cost construction material Applied Clay Science, Volume 45, Issue 4, August 2009, Pages 220-226 J. Mirza, M. Riaz, A. Naseer, F. Rehman, A.N. Khan, Q. Ali ISSN: 2231-5381 http://www.ijettjournal.org Page 47