AN ABSTRACT OF THE THESIS OF Kathy K. Verb le for the degree of Master of Science in Soil Science presented on June 1, 1998. Title: Investigations of Soil Morphology, Hydrology, Reduction-Oxidation Potentials, and Stratigraphy on a Selected Hills lope in Western Oregon Abstract approved: Redacted for privacy J. Herb Huddleston Hydric soils are defined through the hydric soil definition, and a means to identify hydric soils has been established through hydric soil criteria and Field Indicators of Hydric Soils in the U.S. However, the field indicators are a recent development that requires more research and testing to increase our knowledge of correlations between soil morphology, hydrology, and soil processes and properties for all types of landscapes and geomorphic processes. The main objective of this study was to evaluate the Field Indicators capability to identify those soils that met the hydric soil definition on a selected hillslope. Further research and investigation was done to determine whether the study area would meet federal specifications for jurisdictional wetlands and assess stratigraphic units and geomorphic processes that contributed to the present hydrological conditions. Morphological observations; soil physical, chemical, and mineralogical analysis; collection and analysis of piezometric, precipitation, soil temperature, and reduction-oxidation potential data; vegetation characterization; and geomorphological and stratigraphical investigation were used to characterize the soils and study transect (Sites 1 through 4) on the backslope-footslope of Witham Hill in Corvallis, Oregon. Hydrologic, redox potential, and soil temperature data provided documentation that the soils of Sites 2, 3, and 4 meet the conditions in the hydric soil definition. Seasonal perched water tables ranging from 9.7-12.6 cm occur over a discontinuity consisting of slowly permeable clays on the upper footslope; and temporary episaturation that gives way to endosaturation with an average water table at 5.5 cm occurs on the lower footslope. Redox data that indicated continuous iron reduction for 21 to 30 weeks correlated with the morphological properties for each of the three sites. However, morphological characteristics of the soils on the upper footslope did not correspond with the Field Indicators of Hydric Soils in the U.S., Version 3.2, 1996. Two major factors that prevented positive outcomes for any indicators were layer thickness requirements and the inability to round a color that fell between color chips. A third factor was the requirement that at least 60% of a designated layer have a depleted matrix. The first two issues were addressed by the Field Indicator Committee of the National Technical Committee for Hydric Soils in the Field Indicators of Hydric Soils in the United States, Version 4 issued in March 1998. Further investigation into study area characteristics found that: (1) physical and mineralogical analysis supports the presence of four stratigraphic units on the upper footslope; (2) mineralogy indicates that the two clay units and the Spencer Formation that underlies the area may share a common origin and that the clay units could be colluvial material from the eroded Spencer Formation of once-higher surfaces; and (3) soils at Sites 2, 3, and 4 meet the three criteria for identification of jurisdictional wetlands. C Copyright by Kathy K. Verb le June 1, 1998 All Rights Reserved Investigations of Soil Morphology, Hydrology, Reduction-Oxidation Potentials, and Stratigraphy on a Selected Hills lope in Western Oregon by Kathy K. Verb le A THESIS submitted to Oregon State University in partial fulfillment of the requirements for the degree of Master of Science Presented June 1, 1998 Commencement June 1999 Master of Science thesis of Kathy K. Verb le presented on June 1, 1998 APPROVED: Redacted for privacy Major Professor, representing Soil Science Redacted for privacy Head or Chair of Department of Crop and Soil Science Redacted for privacy Dean of Gra ate School I understand that my thesis will become part of the permanent collection of Oregon State University libraries. My signature below authorizes release of my thesis to any reader upon request. Redacted for privacy Kathy K. Verble, Author ACKNOWLEDGMENT I wish to thank my advisor, Dr. Herb Huddleston, for the opportunity, guidance, and patience he has provided over the past several years. A thank you to committee members Dr. Jerry Kling, Dr. Robert Frenkel, and Dr. Terry Gerros for their time and effort. I want to express my appreciation to Will Austin who helped construct and install equipment, provided assistance and encouragement, and was a source of information and a sounding board for ideas; to Bob Frenkel for his assistance in the vegetation characterization; to Reed Glasmann who provided many hours of his time, his friendship, and guidance through mineralogy; and to Joan Sandeno who volunteered her help in thesis preparation. A thank you to Janet Morlan and the Oregon Division of State Lands for funding this study in the Wet Soil project in Oregon. TABLE OF CONTENTS Page Chapter 1. Hydric Soils and Their Identification 1 Introduction 1 Background 1 Explanation of Problem 4 Objectives 5 Methodology 6 Chapter 2. Soil Morphology and Characterization of the Witham Hill 7 Backslope-Footslope Study Site Introduction 7 Background 7 Description of Study Area General Climate 11 11 11 Methods 14 Results and Discussion 15 Morphological 15 Physical and Chemical Mineralogical Classification 20 29 36 Conclusion Chapter 3. Hydrologic Regime and Reducing Environment at the Witham Hill Backslope-Footslope Study Site Introduction 36 39 39 TABLE OF CONTENTS (Continued) Page Background General Hydrology Reducing Environment Growing Season Methods General Equipment Construction and Installation Data Collection and Interpretation Results and Discussion Site 1 Site 2 Site 3 Site 4 Plots A-F Summary of All Sites and Plots Conclusion Chapter 4. Field Indicators of Hydric Soils Application to the Witham Hill Backslope-Footslope Study Site 39 39 40 42 48 48 48 49 52 55 56 58 71 79 89 100 102 105 Introduction 105 Background 106 Methods 108 Results and Discussion 108 Conclusion 113 TABLE OF CONTENTS (Continued) Page Chapter 5. Hydrophytic Vegetation and Wetlands at the Witham Hill Backslope-Footslope Study Site 117 Introduction 117 Background 117 Wetland Hydrology Criterion Hydric Soil Criterion Hydrophytic Vegetation Criterion 118 121 121 Methods 126 Results and Discussion 127 Wetland Hydrology Hydric Soils Hydrophytic Vegetation Conclusion Chapter 6. Geomorphology and Stratigraphy of the Witham Hill Backslope-Footslope Study Site 127 129 129 139 141 Introduction 141 Background 141 Geological Overview 144 Investigation 147 Results and Discussion 149 Observations Mineralogical Analysis Interpretation 149 152 159 TABLE OF CONTENTS (Continued) Page Geomorphology Stratigraphy Summary 159 164 173 Chapter 7. Summary and Conclusions 174 Literature Cited 180 Appendices 192 Appendix A NRCS Soil Characterization Data Appendix B Soil Profile Descriptions Appendix C Field Measurement Data Appendix D Vegetation Characterization Data Appendix E Mineralogy Laboratory Procedures 193 212 220 307 312 LIST OF FIGURES Figure Page 2.1 Location of study area in western Oregon 12 2.2 Cross-section diagram of site and plot locations on the WSW-ENE transect 13 Random powder mount XRD patterns of weathered bedrock samples from Pits 1, 2, and 3 30 Random powder mount XRD pattern of the 3Bsstyl clay horizon 31 SEM micrographs of gypsum crystals and clay matrix from the 3Bsstyl horizon 33 X-ray energy spectrometry of the crystals and matrix from the 3Bsstyl horizon 34 Diagram of the instrumented sites and plots, excavated pits and trench, and vegetation plots 50 Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Site 1 57 2.3 2.4 2.5 2.6 3.1. 3.2. 3.3. Electrode potentials (top) at 10 cm, 30 cm, and 50 cm depths and duration of saturation as measured by piezometers (bottom) at Site 1 59 3.4. Precipitation data (bottom) and water table data (top) below the soil surface as observed a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Site 2 60 3.5. Water table data (top) below the soil surface with the errant 75 cm piezometer graphed separately at Site 2 62 LIST OF FIGURES (Continued) Figure Page 3.6. Electrode potentials (top) at 10 cm, 30 cm, and 50 cm depths and duration of saturation as measured by piezometers (bottom) at Site 2 64 3.7. Groundwater dissolved oxygen values (bottom) from piezometric water and electrode potentials (top) at Site 2 66 Soil temperature data at 10 cm, 30 cm, and 50 cm depths at Site 2 69 Soil temperature data (bottom) and electrode potentials (top) at Site 2 70 3.8. 3.9. 3.10. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Site 3 72 3.11. Electrode potentials (top) at 50 cm, 30 cm, and 10 cm depths and duration of saturation as measured by piezometers (bottom) at Site 3 74 3.12. Groundwater dissolved oxygen values (bottom) from piezometric water and electrode potentials (top) at Site 3 76 3.13. Soil temperature data at 10 cm, 30 cm, and 50 cm depths at Site 3 78 3.14. Soil temperature data (bottom) and electrode potentials (top) at Site 3 80 3.15. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 100 cm, 50 cm, and 25 cm depths at Site 4 81 3.16. Water table data (top) below the soil surface with the errant 84 75 cm piezometer graphed separately at Site 4 LIST OF FIGURES (Continued) Figure Page 3.17. Electrode potentials (top) at 25 cm, 50 cm, and 100 cm depths and duration of saturation as measured by piezometers (bottom) at Site 4 85 3.18. Groundwater dissolved oxygen values (bottom) from piezometric water and electrode potentials (top) at Site 4 87 3.19. Soil temperature data at 25 cm, 50 cm, and 100 cm depths at Site 4 88 3.20. Soil temperature data (bottom) and electrode potentials (top) at Site 4 90 3.21. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot A 92 3.22. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot B 93 3.23. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot C 95 3.24. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot D .... 96 3.25. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot E 98 3.26. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot F 99 6.1. Physiographic provinces of Oregon 145 LIST OF FIGURES (Continued) Figure 6.2. Page Cross-section of the study trench showing the stratigraphy from Site 1 to Site 3 150 XRD patterns of the 2Crt sample from Site 1 153 6.4. XRD patterns of the 2Bt1 gray clay horizon of Site 2 155 6.5. 156 6.3. XRD patterns of the 3Bss olive clay horizon of Site 2 6.6. XRD patterns of the 4BCt horizon of Site 2 157 6.7. XRD patterns of the 2Bt gray clay horizon of Site 3 158 6.8. XRD patterns of the 3Bsstyl and 3 Bssty2 olive clay horizons of Site 3 160 6.9. XRD patterns of the 4BCt horizon of Site 3 161 6.10. XRD patterns of the AB horizon of Site 2 and a Greenback sample from the Bethel surface 163 6.11 XRD patterns of the <2 pm Mg-Glycol samples from horizons at Site 3 167 6.12. XRD patterns of the 2Bt gray clay horizon of Site 3 and a 2Bt Malpass horizon from a Dayton soil 169 6.13. Willamette Valley faults 171 LIST OF TABLES Table Page 2.1. Morphological characteristics of the study area soils 16 2.2. Morphological features of the study area soils 17 2.3. Physical characteristics of the study area soils 21 2.4. Chemical characteristics of the study area soils 22 3.1. Periods of continuous saturation within the upper 30 cm, seasonal mean water table levels, and periods of oxygen and iron reduction for the four pedons of the study area 101 Periods of continuous saturation within the upper 30 cm and seasonal mean water table levels for plots between Sites 1-4 103 3.2. 4.1. Application of field indicators to the study area soils 5-1. 109 Wetland indicator category of plant species under natural conditions 123 5.2. Dominance determination for Site 1 131 5.3. Dominance determination for Site 2 133 5.4. Dominance determination for Site 3 135 5.5. Dominance determination for Site 4 137 6.1. Analysis of selected peak intensities for Site 2 165 6.2. Analysis of selected peak intensities for Site 3 165 DEDICATION This thesis is dedicated to Bobbie, a friend, whose journey on earth has ended. Investigations of Soil Morphology, Hydrology, Reduction-Oxidation Potentials, and Stratigraphy on a Selected Hills lope in Western Oregon Chapter 1 HYDRIC SOILS AND THEIR IDENTIFICATION Introduction "Wet soils" now known as hydric soils, wetland soils, hydromorphic soils, aquic soils, waterlogged soils, meadow soils, and many other names throughout the world (Dudal, 1992) were at one time, and in some instances still are today, considered socioeconomic nuisances. Wetness is a factor that may limit land use related to crop production, construction, recreation, health and contamination by affecting root growth, bearing strength and slope stability, trafficability, microbial activity, and the movement of solutes. In the last few decades, "wet soils" have become increasingly important in issues of land development, land management, and environmental preservation with the rising need for expansion and use of marginal soils. "Wet soils", excluding Histosols, occupy approximately 10% of the non-ice-covered landmass according to the FAO-Unesco Soil Map of the World (Dudal, 1992). Intervention through damming, drainage, irrigation, and construction has changed the dynamics of free flowing water through landscapes, resulted in degradation of water quality, led to subsidence of organic soils, and destroyed or disrupted vital natural ecosystems. Background In the United States, a means to define and characterize "wet soils" became necessary, in large part, because of the need by federal and state agencies for the identification, inventory, management, and regulation of wetlands. The necessity led to the recognition of a new class of soils, hydric soils, and the means to identify them with the development of the hydric soil definition, the hydric soil criteria, and the Field Indicators of Hydric Soils in the U.S. Federal regulation of wetlands for the maintenance of water quality began to take effect on a broad scale in the 1970s (National Research Council, 1995). The Federal Water Pollution Control Act Amendments of 1972 extended the U.S. Army Corps of Engineers (USACE) and the Environmental Protection Agency (EPA) regulative authority to wetlands. The Clean Water Act 1977, Section 404, revised the Corps' regulatory authority and heightened the need for procedures to identifying and delineating wetlands (National Research Council, 1995). In the late 1970s, the Fish and Wildlife Service (FWS) requested that a wet class of soils be developed to aid in identifying wetlands for the National Wetlands Inventory of the USA (Mausbach, 1994). The Soil Conservation Service (SCS) now called the National Resource Conservation Service (NRCS), agreed to develop the wet soil classification and a list of "wet soils." Work on the list began in 1977 under the leadership of W.B. Parker (National Research Council, 1995). The term "hydric soil" was coined by Cowardin et al. (1979) in a FWS publication on the classification of wetlands and became the accepted designation for a specific class of wet soils. The main objective of the SCS was to define and create a class of soils that normally would support hydrophytic vegetation and could be identified with data from the Soil Resource Inventory (SRI) of the National Cooperative Soil Survey. The agency considers "hydric soil" as a "technical soil grouping" developed "for the application of national legislation concerned with the environment and with agricultural commodity production" (Soil Survey Division Staff, 1993). The hydric soil definition was to set the standard for defining a hydric soil (Mausbach, 1994) while the hydric soil criteria were designed primarily for creating a list of hydric soils based on soil attributes documented in Soil Taxonomy and listed in the Soil Interpretations Record (SIR) database (National Research Council, 1995). The first list of hydric soils was distributed to State SCS staff in 1980 for review and testing. In 1981, the SCS formed an ad hoc committee called the National Technical Committee for Hydric Soils (NTCHS) (National Research Council, 1995). The task of the NTCHS was to review the comments, finalize the hydric soil definition, and issue an approved list of hydric soils (Mausbach, 1994). The committee was eventually expanded in 1985 to include representatives from the U.S. Forest Service, the U.S. Fish and Wildlife Service (FWS), the Bureau of Land Management (BLM), Corps of Engineers (USACE), and the Environmental Protection Agency (EPA) (National Research Council, 1995). The expansion provided a body of representatives from agencies who must contend with hydric soils and jurisdictional wetland issues. The hydric soil definition and the first edition of the National List of Hydric Soils in the USA were published in 1985 (US Department of Agriculture, Soil Conservation Service, 1985). Over the past 20 years, the hydric soil definition and the hydric soil criteria have evolved through testing and reviewing. The present definition and criteria focus on saturation, duration of saturation, growing season, anaerobic conditions (in the definition but not in the criteria), and the upper part of the soil profile. The definition provides a concept of a hydric soil but does not provide explicit factors for identifying hydric soils in the field. The criteria, as mentioned, were designed primarily for generating a list by searching existing NRCS database. The inappropriate use of the criteria for on-site field identification or verification of hydric soils was inevitable in the absence of field procedures for identifying hydric soils. In response to the misuse, the interagency NTCHS committee began in 1994 to compile a list of indicators of distinct morphological features that are observable in the field as a result of soil pedogenic processes in soils that are saturated for long durations (National Research Council, 1995). A first draft version for review was issued in 1995 with input from various regional, state and local agencies, universities, and the private sector (US Department of Agriculture, Natural Resources Conservation Service, 1996). Later that year, the NTCHS approved the Field Indicators of Hydric Soils in the United States for identifying and verifying the presence of hydric soils in the field. Explanation of Problem Identifying hydric soils under field conditions has become increasingly important as hydric soils have become the "most common and useful general indicator to support the substrate criterion for wetlands" (National Research Council, 1995). Most hydric soils have characteristic morphologies as a result of the biogeochemical processes taking place during repeated periods of saturation or inundation. The present field indicators are based on the soil morphological properties, which are known to be associated with saturation and reduction through past research and testing. The hydric soil field indicators are under continuous scrutiny and revision as our knowledge broadens on the long-term effects of soil wetness. However, the characterization of wet soils by morphological features related to biogeochemical processes has limitations (Dudal, 1992). Problems arise in identifying hydric soils when soil morphological indicators are weak, nonexistent, difficult to interpret, or when the soil morphology is inconsistent with the landscape, 5 vegetation, and hydrology (US Department of Agriculture, Natural Resources Conservation Service, 1996). In addition, studies on hydric soil morphology have focused largely on areas where the occurrence of hydric soils is highest: areas with relatively flat topography, glacial or coastal plain geomorphology, and high summer rainfall areas (National Research Council, 1995). Meaningful characterization of all hydric soils will require continued research on the correlation between soil morphology and hydrologic conditions for all types of landscapes and geomorphic processes. The National Research Council (1995), in their report reviewing the scientific basis for identification and delineation of wetlands, recommended that more emphasis be placed on the development of field indicators for hydric soils and more studies be done on soils that are difficult to classify in the field. The increased breadth of correlations will insure consistent identification and compliance. Objectives In 1991, the Department of Crop and Soil Science at Oregon State University initiated a wet soil monitoring program to investigate the hydrology, morphology, and reducing conditions of various soils in Oregon. The program was part of the Wet Soils Monitoring Project initiated by the Soil Conservation Service. The national project is an effort among wet soil researchers at Land Grant Universities in eight states to investigate relationships among soil hydrology, oxidationreduction reactions, temperature, and morphology (US Army Corps of Engineers, 1996). A hillslope wet soil monitoring project was undertaken as part of Oregon State University's program in 1995 with 6 the goal to aid in the understanding of these relationships and in the advancement of hydric soil identification. The three main objectives of the hillslope wet monitoring project were: (1) Determine if the soils along a selected backslope-footslope transect are hydric according to the hydric soil definition (Federal Register, July 13, 1994). (2) Determine if the soils meet any of the current indicators in the Field Indicators of Hydric Soils in the United States Ver. 3.2 (US Department of Agriculture, Natural Resources Conservation Service, 1996). (3) Evaluate the Field Indicators capability to identify those soils that meet the hydric soil definition. Additional objectives were to: (1) Determine (if the soils are hydric) whether any part of the study area could be considered a jurisdictional wetland. (2) Assess the possible geomorphic processes that resulted in the present hydrology and soil morphological characteristics. Methodology The objectives were accomplished through soil morphological observations; soil physical, chemical, and mineralogical analysis; the collection and analysis of hydrologic, climate, and biological activity data, vegetation characterization; and geomorphological and stratigraphical investigation. Methods for each area of research are presented within the appropriate following chapters. Each chapter reviews the literature for the accepted methods of research and current concepts of hydric soil processes and properties. 7 Chapter 2 SOIL MORPHOLOGY AND CHARACTERIZATION OF THE WITHAM HILL BACKSLOPE-FOOTSLOPE STUDY SITE Introduction The purpose of this chapter is to describe soil morphological properties and selected physical, chemical, and mineralogical properties. Soil morphology is obtained mainly by field identification of soil attributes and variations that can provide a great deal of information for interpretations and inferences about soil properties and qualities. Soil characterization is accomplished mainly through measurements of physical, chemical, and mineralogical properties by laboratory procedures and provides quantitative data for determining and interpreting soil properties. Background Historically, soil color has been one of the most used morphological properties to describe and classify soils. Soil color can serve as an indicator of the pedoenvironment and of past and present soil processes. Soil color is due primarily to soil organic matter and secondary iron oxides that form coatings on individual clay, silt, and sand particles. Soil color interpretation is based on location within a soil profile. In surface horizons, humic materials give the soil its dark colors. Loss of organic substances from the surface horizons by translocation is slowed by the complexation of mobile organic ligands with iron (De Coninck, 1980). In subsurface horizons, soil hue is a function of the type and proportion of iron oxides present (Schwertmann and Taylor, 1989). The type of iron oxide formed is influenced by the pedoenvironment (moisture, pH, Eh, temperature, ionic environment, etc.) (Schwertmann, 1993). Thus, the type of iron oxide formed is useful in gaining information about a soil's pedogenic environment. In general, iron gives aerobic soils their yellowish to reddish hues with high chromas (Schwertmann and Taylor, 1989) and anaerobic soils their grayish, greenish, and bluish colors with low chromas (van Breemen, 1988b). Removal of iron by leaching or lateral movement leaves soils with the light-gray colors of its matrix minerals. Reviews by Schwertmann (1988), Schwertmann and Taylor (1989), and Schwertmann (1993) provide data on iron oxide identification, formation, and occurrence. Iron oxide identification can be determined by the use of mineral-specific colors, dissolution methods, and X-ray diffraction. Some forms of iron oxides, their characteristic colors, and occurrences are discussed briefly. Goethite (a- FeOOH) is the most stable phase of iron oxide under soil conditions (Gotoh and Patrick Jr, 1974) and thus is the most widespread Fe oxide in soils. Goethite is recognized by its hues between 7.5YR and 2.5Y. Goethite can be formed from either Fe2+ or Fe3+ cations in solution. Ferrihydrite (5Fe203.9H20) is recognized by a hue of 5-7.5YR and values <6. Ferrihydrite has poor crystallinity and forms in reducing environments where reoxidation of Fe2+ cations occurs relatively quickly or where constituents such as organic matter impede the crystalline growth of other oxides. Lepidocrocite (y- FeOOH) has hues of 5-7.5YR with values > 6 in well-crystalline forms or 10YR in low concentrations. Lepidocrocite requires Fe2+ ions for formation and therefore is indicative of soils with reducing environments. Lepidocrocite occurs mostly as orange concentrations in seasonally saturated soils and forms by slow oxidation of Fe2+ ions. 9 Many physical, chemical, and biological properties and processes affect soil morphology. An important physical property of a soil is particle-size distribution. A soil's texture greatly affects ion adsorption, rate of water movement, and translocation of solutes. Textural variations within a soil profile affect the hydrologic properties of a soil and can alter a soil's moisture regime. Not all textural variations and contrasting textural changes (discontinuities) can be identified or interpreted easily in the field. Lab particle-size distribution analysis provides size distribution of individual particles from colloidal clay (<0.2 jam) fraction to coarse fractions and can aid in pedogenic and geologic interpretations (Soil Survey Laboratory Staff, 1995). One biochemical process that affects iron distribution and thus soil morphology is reductive dissolution. Reduction-oxidation (redox) reactions result in the solubilization (reduction) of iron and manganese oxides by bacterial respiration in anaerobic conditions. The mobile reduced ions may be transported by water movement out of the soil profile and/or horizon or may diffuse to areas of higher 02 partial pressures and accumulate as Fe and Mn oxides (Schwertmann, 1993; van Breemen, 1988b). Processes and effects of reductive dissolution of iron and manganese oxides have been reviewed by many authors: Ponnamperuma et al. (1967,1968); van Breemen (1987, 1988a, 1988b); Turner and Patrick Jr (1968); Ponnamperuma (1972); Gambrell and Patrick Jr (1978). Reductive processes which occur through microbial reduction and complexation by organic ligands (Schwertmann, 1988) are affected by the organic matter content of a soil (Dobos et al., 1990). Microbial reduction requires an energy source that is supplied by soil organic carbon. Low quantities of organic matter limit microbial reduction and formation of Fe and Mn organic complexes. Rowell (1981) reported 10 that organic matter content less than 1.5% greatly affects the soil's capacity for reduction and that organic matter content greater than 3% can lead to highly reduced conditions. One component of a soil that can affect both iron translocation and pH is aluminum. Soil pH is important because it plays a major role in reduction-oxidation reactions, activity of microorganisms, solubility of various compounds, complexation reactions, and adsorption of ions to exchange sites (McLean, 1982). Aluminum can serve as a proton donor during iron reduction resulting in exchangeable Fe2+ if the exchange complex has A13÷. "Forced" ion exchange occurs when Al3+ is hydrolyzed to Al-hydroxide or Al-hydroxy species of lower charge and Fe2+ replaces the hydrolyzed aluminum (van Breemen, 1988a). Color variations in mineral soils as a result of redox processes involving Fe and Mn compounds in continuous or recurrent reducing conditions are called "redoximorphic features." The features are visual evidence of reduction, translocation, and oxidation of free oxides resulting from the water table regime. Many studies (Boersma et al., 1972; Veneman et al., 1976; Vepraskas and Wilding, 1983; Frammeier, et al., 1983; Evans and Franzmeier, 1986; and Cogger and Kennedy, 1992) have correlated the occurrence of redox features with water table behavior. Thus, soil color and color patterns commonly are used in the field to indicate soil moisture regimes (Soil Survey Division Staff, 1993), infer soil-drainage classes, and to identify hydric soils (US Department of Agriculture, Natural Resources Conservation Service, 1996). Vepraskas (1994) describes the three major categories of redox features: (1) redox concentrations, (2) redox depletions, and (3) reduced matrices. Redox concentrations include: masses (soft bodies); nodules and concretions (firm irregularly shaped bodies); and pore 11 linings (coatings on a pore surface or impregnation of the matrix adjacent to a pore). Redox depletions are bodies with low chroma (.2) and values of 4 or more where Fe-Mn oxides or Fe-Mn oxides and clay have been stripped out. Reduced matrices have Fe2+ that gives the soil low chroma color (.2) in situ but oxidizes to Fe3+ when exposed to air. Description of Study Area General The study area is on a backslope-footslope transition on Witham Hill at the OSU poultry farm. Witham Hill is northwest of Corvallis and lies on the western margin of the southern Willamette Valley in Benton County, Oregon (Fig. 2.1). The low hill ranges in absolute elevation from 85.3 m to 146.2 m (280-480 ft). The WSW-ENE transect ranging from 86.2 m to 103.4 m (283-340 ft) in elevation was selected to include a dry upland soil and a wet drainageway soil. The hillslope shape (Ruhe, 1975) changes from a convex-linear shoulder to a concave-linear footslope just below Site 1 (at the top of the transect) and then changes to linear-linear level at Plot F (near the lower end of the transect) (Fig. 2.2). The slope gradient ranges from 23% at Plot A to 2% at Site 4. According to the Soil Survey Staff (1975a), the soils of the upper and mid transect positions are underlain by sedimentary bedrock and the soils of the lower portion of the transect were developed in recent (Holocene) alluvium. Climate The climate is characterized by a moderate marine climate of cool, wet winters and warm, dry summers giving the soils a xeric moisture regime and a mesic temperature regime. The average annual precipitation in the low elevations of the study area ranges from 101.6 12 Figure 2.1. Location of study area in western Oregon. (a) Corvallis in southern Willamette Valley (from McDowell, 1991). (b) Topo of Witham Hill 44°34'14" N and 123°18'00" W. IRK:HEEL (a) BASIN ';;;11 V.777: '!!!! 0 Albany SOUTHER .. . WILLAMETTE" ........ VALLEY .. . . 619 (b) MARRSON :."/ .1.Actrs6iv .... ....... ....... ....... V-2-1 - \\ ..... Dui Figure 2.2. Cross-section diagram of site and plot locations on the WSW-ENE transect. 1 BC2 E 3 Sites (1-4) and Plots (A-F) F 4 14 cm to 114.3 cm (40 to 45 inches), 50 percent of which falls from December through February (Taylor and Bartlett, 1993). Mean high and low temperature ranges between 32° and 18° (C) in summer and between 4.5° and 0° (C) in the winter. The average monthly mean temperature is 4.20C in January and 18.80C in July (Taylor and Bartlett, 1993). Methods Four backhoe pits were excavated to a depth of 1.5 m (5 ft) along one transect. Soil profiles were described using standard terminology as given in the Soil Survey Manual (Soil Survey Division Staff, 1993). Soil color determinations were made using Munsell Soil Color Charts. Particular attention was given to soil color and redoximorphic features. Color was not rounded to the nearest chip as practiced by Natural Resource Conservation Service (Soil Survey Division Staff, 1993). Color notations were made with plus (+) or minus (-) when appropriate. A (+) or (-) next to a value and/or chroma indicates which chip was the closest match when the sample color was between color chips. Redoximorphic features were identified and described by type according to Vepraskas (1994). Abundance, size and distinctness of redox features were noted according to the Soil Survey Manual (Soil Survey Division Staff, 1993). It was assumed that reddish masses and concentrations were mainly composed of iron and that black masses and concentrations were composed mainly of manganese. Soil profiles were sampled with the aid of Warren Lynn, a Natural Resource Conservation Service (NRCS) soil scientist, following standard procedures (Soil Survey Laboratory Staff, 1996). The NRCS National Soil Survey Laboratory (NSSL), Lincoln, Nebraska performed characterization analysis. Soil characterization data sheets from the 15 NSSL on physical, chemical, and mineralogical properties are in Appendix A. Additional mineralogical analyses were performed on samples from selected horizons. X-ray diffraction (XRD) analyses were run on random powder mounts (Moore and Reynolds, Jr., 1989) of bulk samples from a clay horizon from Pit 3 and the soft bedrock from Pits 1, 2, and 3 to identify the major mineralogy. Analyses were made with a Phillips XRG 3100 Automated XRD unit using monochromatic Cu Ka radiation at 40kV and 35mA. The random power mounts were run in the 6-650 20 increment. In addition, the Site 3 clay sample also was analyzed with scanning electron microscopy (SEM). The sample was mounted on an Al stud with Duco cement and sputter coated with AuPd. The sample was examined with an AMR 1000 scanning electron microscope equipped with a Kevex energy dispersive X-ray analyzer. Results and Discussion Morphological Selected morphological properties are presented in Tables 2.1 and 2.2. Detailed profile descriptions of morphological observations are in Appendix B. Textural classes in the profile descriptions were determined from field texture. There were some contrasting morphologies between the soil profiles of the four pedons at the study site. Obvious differences between the soils were solum depths, soil colors, occurrence of clay horizons, location and abundance of redoximorphic features, and accumulations of white crystals (Table 2.1 and 2.2). Pit 1, located on the backslope, had the shallowest solum with fractured bedrock starting at 95 cm below the soil surface. A cambic B horizon has developed over slightly weathered sandstone. The 16 Table 2.1. Morphological characteristics of the study area soils. Depth Horizon Hue (cm) Matrix Color Moist Texture Dry Structure Boundary grade-size-shape Site #1 0 -7 7-19 19-46 46-65 65-95 95-130 130-155 Al 0 -7 7-14 14-27 27-36 36-50 50-70 70-92 92-109 109-142 142-155 155-170 Al 0 -7 7-16 16-27 27-42 42-91 91-120 120-135 135-153 153-175 Al A2 A3 BA 10YR 10YR 10YR 10YR 10YR Bwl Bw2/2Crt 10YR 2Crt 2.5Y-10YR 3/3 3/3 3/3 4/3 5/4 4/4 6/3-4/6 5/3 5/3 5/3 6/3 6/4 6/4 7/3-4/6 cl cl cl cl cl 5/3 5/3 5+/2 5+/2 sil sil sicl sic 2FSBK 2FSBK 2MSBK 1MPR/2MSBK 2MPR 1CSBK cs gs gs gs 2VFSBK 2VFSBK 2MSBK 1CSBK 1MPR/2MSBK cs as 2MPR/2CSBK aw OMA OMA OMA gw cs cs cs gi gw Site #2 A2 A3 AB B/E E/B 2Bt1 3Bt2 3Bss 4BCt1 4BCt2 10YR 10YR 10YR 10YR 10YR-10YR-7.5YR 10YR-10YR-7.5YR 2.5Y 2.5Y 2.5Y 2.5Y-7.5YR-7.5YR 2.5Y-2.5Y-10YR 3/2+ 3/2+ 3+/2 4/2 5/2-4/4-4/6 5/2-5/6-4/6 5/2 5/3+ 4/4 6/3-5/6-4/6 6/3-6/4-6/8 6/2-6/4-5/6 7/2-6/6-5/6 6/2 cl el cl sicl sic gs gs cs 6/3+ c 6/4 7/3-6/6-5/6 7/3-7/4-7/8 c cl cl 5/2+ sil sil 2MGR 6/2+-5/6-5/6 7/2-6/6-6/6 6/2 6/2-6/3 6/4-6/3 6/4 7/3-6/8 cl 2MSBK 2CSBK aw OMA OMA OMA gs gs gs 1CSBK gs 4/1 4/1 4/1 3/1 3/1 3/1 3/1 sic sic 2MGR 2FSBK 2FSBK 2FSBK 2CPR 2MPR cs cs cs gs gs ab Site #3 A2 B/E E/B 2Bt 3Bss 3Bsstyl 3Bssty2 4BCt 10YR 10YR 3/2+ 10YR-10YR-7.5YR 10YR-10YR-7.5YR 2.5Y 2.5Y 2.5Y 2.5Y 2.5Y-10YR 4/2 4/2+-4/6-4/6 5/2-5/6-5/6 4/2 4/2-5/3 5/4-5/3 5/4 6/3-5/8 10YR 10YR 10YR 10YR 10YR 10YR 10YR 3/1 3/1 3/1 2/1 2/1 2/1 2/1 5+12 sicl c c c c 1CSBK/2FSBK sicl Site #4 0 -6 6-18 18-35 35-51 51-90 90-133 133-163 Al A2 AB BA Bt Bssl Bss2 c c c c c OMA cw cs cw Table 2.2. Morphological features of the study area soils. Depth cm Horizon Surface and Matrix Features *" Additional Color moist Features Fe masses/depletions amount size rom Additional Additional Additional Features Features Features Site 0 -7 7-19 19-46 46-65 65-95 95-130 130-155 Al 0 -7 7-14 14-27 27-36 36-50 50-70 70-92 92-109 109-142 142-155 155-170 Al 0 -7 7-16 Al A2 FeM-mfd & OR-cd 16-27 B/E E/B OR-fd FeM-cfd FeM-mfp FeM-cff FeM-cff A2 A3 BA Bwl Bw2/2Crt 2Crt DP-fff FeM-fff FeC-ff FeC-ff FeC-ff 10YR 5/6 FeCC & CCO CF-cd Site 2 A2 A3 AB FeM-mfd/cmd FeM-cfp/fmp 5YR 4/6 & 7.5YR 4/6 10YR 4/6 & 7.5YR 3/4 10YR 4/6 & 7.5YR 4/6 FeM-mfd FeM-cff FeM-cff & DP-cmd 7.5YR 5/6 & 7.5YR 5/8 10YR 5/8 10YR 5/8 & 5Y 5/2 FeM-mff B/E E/B 2Bt 1 3Bt2 3Bss 4BCt1 4BCt2 MnN-ff MnN-ff MnN-ff MnN-ff FeN-ff & MnC-ff FeN-ff & MnC-if MnS-vfp SLS-vfd SLS-fd SLS-cp CF-fd CF-fd CF-fd CF-vfp CF-vfp GY-ffp Site 3 27-42 42-91 91-120 120-135 135-153 153-175 0- 6 6-18 18-35 35-51 2Bt 3Bss 3Bsstyl 5YR 4/6 & 7.5YR 4/6 7.5YR 5/8 7.5YR 4/6 10YR 5/8 10YR 5/6 10YR 5/6 3Bssty2 MnFeC-ff MnFeC-ff MnS-cp MnFeC-ff FeC-ff SLS-fd FeC-ff & MnM-ffd SLS-md MnN-cf & MnM-ffp SLS-md MnS-fp & MnN-ff SLS-md 4BCt Al A2 AB BA CF-fd CF-ff CF-vff GY-fmd/fmp CF-fp/fd GY-ffp CF-fd OR-md FeM-mfd/mff/cfd FeM-mfd/cff/mmd FeM-mfd/cff Site 4 7.5 YR 4/6 7.5YR 4/6-3/4 & 5YR4/6 7.5YR 5/8 & 5YR 3/4-4/6 MnS-vff FeC-fff & MnS-fd OR-md OR-fd MnN-cf 7.5YR 4/6-5/6 Bt 51-90 MnN-ff/fm SLS-vfd FeM-fff 90-133 Bssl 10YR 3/4 SLS-cd FeM-fff 10YR 3/4 133-163 Bss2 SLS-md * Abbreviations taken from Soil Survey Staff (1993) unless otherwise noted ** M = masses, DP - depletions, C - concretions, N - nodules, S = stains, CO - coatings, CF = clay films SLS = slickensides, GY = gypsum, OR = oxidized rhizospheres CF 18 bedrock is composed of sandstone with some areas of interbedded siltstone. Matrix hue of the soils was 10YR while the dominant matrix hue of the underlying sandstone was 2.5Y. Color values and chromas were > 3. The only redoximorphic features were small (<0.5 mm) Fe concretions between 7 cm and 65 cm beneath the soil surface and a few fine Fe masses between 65 cm and 95 cm. Soils dominated by high chromas and few iron redox features are associated with very short periods of saturation (Veneman, et al., 1976). The fact that no redox features other than small concretions occur within the upper 65 cm indicates quick changes between reductive and oxidative conditions (Blume, 1988). Soils in Pits 2 and 3 had very similar morphology and were different in many ways from soil in Pit 1. Pit 2 (17.4 m downslope from Pit 1) and Pit 3 (30.9 m downslope from Pit 2) had sola that were 170 cm deep to highly weathered sandstone. In addition, Pits 2 and 3 had a clay substratum that was lacking in Pit 1. A contrasting texture change and an abrupt boundary (Table 2.1) suggest a discontinuity between the 1OYR subsurface horizons and the 2.5Y clay substratum. The soils in Pits 2 and 3 showed a trend toward higher values and lower chromas in the horizons compared to soils in Pit 1. Macromorphic redox features in Pit 2 started at 7 cm below the soil surface with many faint iron masses. Distinct iron masses and manganese nodules were present at 14 cm below the soil surface. Macromorphic features in Pit 3 included a dominant matrix value and chroma of 4/2 at 7 cm below the soil surface. Common distinct oxidized rhizospheres, many distinct iron masses, and few Mn.-Fe concretions were also present at this depth. The B/E and E/B horizons over the clay substratum and redoximorphic concentrations close to the soil surface of Pits 2 and 3 suggest that water is perching over the slowly permeable clays. 19 Impeding layers can cause a restriction in water distribution and lead to perched water tables and more rapid saturation conditions (Knapp, 1978). Franzmeier et al. (1983) found that gray (chroma ..2) horizons were zones through which water fluctuated the most and duration of saturation was the longest. Simonson and Boersma (1972) found that faint and distinct concentrations increased with an increase in water saturation, and Blume (1988) concluded that slow changes between reductive and oxidative conditions favored the formation of iron and manganese masses over concretions. Interesting was the difference in the thickness of the solum above the clay horizons for Pits 2 and 3. Although the land slope is between 5-6% for both sites, the solum above the clay at Site 2 was 70 cm thick and 42 cm thick at Site 3. The transitional B/E and E/B horizons occur between 36 and 70 cm in Pit 2 and between 16 and 42 cm in Pit 3. Field interpretations suggest that the Pit 3 depleted horizons are closer to the surface due to the shallower solum above the clay horizons. Slickensides, which are common in swelling clays that are subject to changes in water state (Soil Survey Division Staff, 1993), were observed in the clay horizons of Pits 2 and 3. The slickensides were fairly large with the largest approximately four to five inches deep and up to a foot across. Also noted in the lower horizons of the clay substratum were clear and white fibrous crystal accumulations that looked like gypsum. Pit 2 had few, prominent white crystals in the 413Ct1 horizon. The 3Bssty 1 horizon of Pit 3 had distinct and prominent clear and white crystal clusters. The underlying 3Bssty2 horizon had a few prominent white crystals. The Pit 4 soils, located on the lower footslope, had different morphology from the other three pits. The silty clay surface horizons and clay subsoil and substratum had very dark colors (s3 values and 20 1 chromas). Macromorphic redox features started at the soil surface with many distinct oxidized rhizospheres. Oxidized rhizospheres are "iron coatings" on plant roots. Leakage of oxygen from plant roots, in species that can transport oxygen to their roots in saturated soils, oxidize nearby ferrous (reduced) iron compounds (Vepraskas, 1994). Many and common, faint and distinct iron masses began at 6 cm below the soil surface. Slickensides were noted starting at 51 cm below the soil surface. Mineral-specific colors of iron oxides were used for field identification of the types of oxides present. The dominant hue colors (10YR and 2.5Y) of the soils in all the pits indicate that a large portion of the iron that coats the matrix materials is probably goethite. The majority of the redo)dmorphic iron concentrations appear to be ferrihydrite (hue of 5-7.5YR and values <6). There may be some lepidocrocite in the matrix and redox concentrations (hues of 5 -7.5YR with values <6 in forms that have poor crystallinity). The redox concentrations are believed to lack any hematite (hues of 5YR or redder) since hematite does not occur in soils with ferrihydrite (Schwertmann and Taylor, 1989). The natural drainage classes for the soils, based on redoximorphic features, are moderately well drained on the backslope (Site 1), somewhat poorly drained on the upper footslope (Sites 2 and 3), and poorly drained soils on the lower footslope (Site 4). Physical and Chemical Selected physical and chemical characterization data for the four pedons studied are listed in Tables 2.3 and 2.4. Some soil properties varied markedly between soil pedons and within soil profiles. 21 Table 2.3. Physical characteristics of the study area soils. Depth Horizon Particle-size distribution* Texture Clay % Silt % Sand % Fine clay % Fine clay/ Total clay Clay-free COLE** LEP^/clay Sand % (cm) Site #1 0 -7 7-19 19-46 46-65 65-95 95-130 130-155 Al 0 -7 7-14 14-27 27-36 36-50 50-70 70-92 92-109 109-142 142-155 155-170 Al 0 -7 7-16 16-27 27-42 42-91 91-120 120-135 135-153 153-175 Al 0- 6 6-18 18-35 35-51 51-90 90-133 133-163 A2 A3 BA Bwl Bw2/2Crt 2Crt A2 A3 AB B/E E/B 2Bt1 3Bt2 3Bss 4BCtl 4BCt2 A2 cl cl cl cl cl sicl sic 27.8 28.2 30.4 29.5 29.1 32.1 41.2 48.2 48.3 47.4 48.3 47.7 52.9 52.9 sil sil 25.0 26.5 28.5 31.2 31.4 32.9 56.0 58.2 57.3 27.7 34.9 52.7 50.7 49.2 48.7 48.1 47.9 35.2 30.2 30.2 43.8 36.3 Site #2 22.3 22.8 22.3 20.1 20.5 19.2 8.8 11.6 12.5 28.5 28.8 25.0 26.6 30.5 38.2 61.5 61.5 60.7 59.3 31.7 53.7 53.3 49.3 45.2 28.9 28.3 29.3 30.4 61.8 Site #3 21.3 20.1 20.2 16.6 9.6 10.2 10.0 10.3 6.5 43.8 47.4 52.4 54.5 56.1 58.8 62.0 46.4 44.8 37.2 33.7 36.9 33.9 32.2 cl cl cl sicl sic c c cl cl sil sil B/E E/B cl 2Bt 3Bss c c 3Bsstyl c 3Bssty2 4BCt c Al sic sic A2 AB BA sicl sicl c Bt c c Bssl c Bss2 24.0 23.5 22.2 22.2 23.2 15.0 5.9 Site #4 9.8 7.8 10.4 11.8 7.0 7.3 5.8 9.0 9.1 9.6 8.9 8.2 8.5 15.5 3.0 3.1 3.1 3.2 3.1 4.5 10.0 0.045 0.040 0.039 0.045 0.034 0.085 0.080 0.162 0.142 0.128 0.153 0.117 0.265 0.194 0.047 0.035 0.025 0.026 0.027 0.024 0.149 0.156 0.166 0.188 0.132 0.088 0.083 0.086 0.073 0.266 0.268 0.290 0.37 0.36 0.34 0.35 0.32 0.34 0.61 0.62 0.63 0.59 0.54 3.4 42.7 42.7 33.8 28.6 10.5 0.42 0.43 0.45 0.48 0.69 0.69 0.56 0.48 0.33 3.5 3.7 3.4 3.7 4.0 3.8 3.9 4.0 10.5 0.061 0.037 0.026 0.025 0.184 0.190 0.188 0.180 0.244 0.139 0.085 0.065 0.299 0.309 0.310 0.304 23.5 26.4 29.9 30.7 29.1 24.9 23.2 0.54 0.56 0.57 0.56 0.52 0.42 0.37 5.7 6.7 4.6 3.9 6.3 5.6 6.6 0.116 0.085 0.137 0.105 0.075 0.152 0.176 0.265 0.179 0.261 0.193 0.134 0.259 0.284 9.3 9.6 9.8 10.8 10.1 11.1 34.4 35.9 36.0 16.3 18.8 10.5 11.5 13.8 18.2 Abbreviations taken from Soil Survey Staff (1993) unless otherwise noted ** COLE = coefficient of linear extensibility ^LEP = Linear Extensibility Percent 0.32 0.32 0.32 0.30 0.28 0.26 0.38 3.2 3.2 3.4 3.3 3.5 5.0 3.6 3.4 2.5 2.3 Table 2.4. Chemical characteristics of the study area soils. Depth Horizon (cm) pH Exch. Active pH cliff. Orgn C wt pct Orgn M wt pct Dithionite-Citrate Extractable Fe Al Mn ( percent on <2-mm basis) 0 -7 7-19 19-46 46-65 65-95 95-130 130-155 0 -7 7-14 14-27 27-36 36-50 50-70 70-92 92-109 109-142 142-155 155-170 Al A2 A3 BA Bwl Bw2/ 2Crt 2Crt Al A2 A3 AB B/E E/B 2Bt1 3Bt2 3Bss 4BCt1 4BCt2 0 -7 Al 7-16 A2 16-27 B/E 27-42 E/B 42-91 2Bt 91-120 3Bss 120-135 3Bsstyl 135-153 3Bssty2 153-175 4BCt 0 -6 6-18 18-35 35-51 51-90 90-133 133-163 Al A2 AB BA Bt Bssl Bss2 4.7 5.3 4.6 5.8 5.2 Site 1 6.9 1.7 7.0 1.6 7.0 2.3 7.1 1.8 7.2 2.6 7.8 2.0 5.6 0.4 4.9 4.9 5.0 4.7 4.5 4.8 4.1 4.2 4.3 4.8 5.0 Site 2 7.1 2.2 7.1 2.2 7.0 2.0 6.3 1.6 6.9 2.4 6.0 1.2 4.7 0.6 6.4 2.2 4.8 0.5 7.4 2.6 7.0 2.0 4.8 4.5 4.4 4.3 4.4 4.8 6.6 6.8 7.0 Site 3 5.5 0.7 5.2 0.7 5.3 0.9 5.2 0.9 4.9 0.5 5.2 0.4 6.7 0.1 7.1 0.3 7.4 0.4 5.67 2.76 1.47 0.89 0.39 0.26 0.18 0.15 0.03 9.8 4.8 2.5 4.6 4.4 4.8 5.0 5.9 7.0 6.9 Site 4 5.3 0.7 4.9 0.5 5.4 0.6 5.8 0.8 6.5 0.6 7.1 0.1 7.5 0.6 9.16 3.99 2.43 1.57 1.03 0.95 0.79 15.8 5.2 5.4 3.37 2.08 1.27 0.64 0.42 0.26 0.10 5.58 2.93 1.45 1.13 0.67 0.61 0.27 0.20 0.16 0.09 0.05 5.8 3.6 2.2 1.1 0.7 0.4 0.2 9.6 5.1 2.5 1.9 1.2 1.1 0.5 0.3 0.3 0.2 0.1 1.5 0.7 0.4 0.3 0.3 0.1 6.9 4.2 2.7 1.8 1.6 1.4 Amonium Oxalate Extractable Fe Feo/Fed ratio Al (percent on <2-mm basis) 2.6 2.6 2.6 2.6 2.7 2.5 3.1 0.2 0.2 0.2 0.2 0.2 0.2 0.2 TR TR TR TR TR 0.29 0.29 0.27 0.22 0.26 0.30 0.35 0.23 0.23 0.22 0.17 0.17 0.20 0.26 0.11 0.11 0.10 0.08 0.10 0.12 0.11 2.2 2.7 2.6 2.9 2.9 2.9 2.6 2.8 2.9 4.8 0.9 0.2 0.2 0.3 0.3 0.2 0.3 0.2 0.2 0.3 0.2 0.1 TR TR TR TR TR TR 0.78 0.87 0.72 0.59 0.48 0.52 0.24 0.14 0.10 0.31 0.04 0.20 0.22 0.23 0.23 0.18 0.21 0.19 0.15 0.14 0.16 0.11 0.35 0.32 0.28 0.20 0.17 0.18 0.09 0.05 0.03 0.06 0.04 2.3 2.5 2.8 2.8 2.5 2.6 2.5 2.3 3.1 0.2 0.2 0.3 0.3 0.3 0.2 0.2 0.1 0.2 0.1 0.1 0.1 TR 0.74 0.82 0.65 0.48 0.22 0.24 0.17 0.17 0.11 0.19 0.20 0.24 0.23 0.23 0.16 0.14 0.14 0.13 0.32 0.33 0.23 0.17 0.09 0.09 0.07 0.07 0.04 3.6 4.5 4.8 4.7 3.8 2.6 3.1 0.3 0.4 0.4 0.4 0.2 0.2 0.2 0.3 0.3 0.4 0.5 0.4 0.2 0.2 1.66 0.36 0.42 0.45 0.35 0.34 0.33 0.37 0.45 0.39 0.29 0.24 0.26 TR TR TR 0.1 0.2 0.2 2.14 1.83 1.12 0.62 0.82 . 23 Textural variations and one probable discontinuity were identified in the field and speculations made about possible additional discontinuities. Particle-size distribution data were used to confirm and identify discontinuities. A common manipulation of particle-size data is to compute sand and/or silt separates on a clay-free basis, since clay distribution is subject to pedogenic change (Soil Survey Laboratory Staff, 1995). Sand is likely to be less altered by soilforming processes and weathering. Clay-free sand percentages are shown in Table 2.3. A change from 4.5% to 10.0% between the Bw2/2Crt and 2Crt horizons at Pit 1 indicates that a discontinuity may exist. In Pits 2 and 3, a higher clay-free sand percentage in the 2Bt horizon suggest a discontinuity between the E/B horizons and the 2Bt horizons and a discontinuity between the 2Bt horizons and the 3Bss horizons. A third discontinuity in the soils at Pits 2 and 3 is suggested between the 3Bss and 4BCt horizons. The clay-free sand percentages also point to some mineralogical differences in the bedrock that underlies the backslope and upper footslope. The bedrock at Pits 1 and 3 have approximately 10% clayfree sand while Pit 2 sandstone has an average of 2.4 percent. The difference is likely due to the interbedding of sandstone and siltstone. Another method that can aid in the examination of soil development and properties uses the fine-clay (<0.2 p.m) fraction. The ratio of fine-clay (colloidal) to total clay in Table 2.3 can be used to determine the presence of illuvial clay (Soil Survey Laboratory Staff, 1995). The ratio of fine-clay to total clay is normally at least one-third higher in an illuvial argillic horizon compared to the overlying or underlying horizons. The 2Bt1 and 3Bt2 horizons of Pit 2 showed a large absolute increase, 23% and 20% respectively, in fine-clay from the overlying eluvial horizon and the underlying 4BCt horizons with a fine-clay to 24 total clay ratio increase of 80% from the overlying horizons. The 2Bt horizon in Pit 3 had a similar absolute increase in fine-clay but a smaller ratio increase of 44%. The ratios when considered alone could indicate the clay horizons are argillic. However, when considered with the discontinuities, the large ratio increase in the 2Bt horizon suggest the clay is from stratification and not from illuviation. Pit 4 soils show a very slight increase in fine-clay and in the fine-clay to total clay ratio to 35 cm and then both start to decrease with depth. The slight increase does not indicate illuviation. Slickensides, which were noted in the clay horizons of Pits 2, 3, and 4 during field characterization, were investigated with lab analysis. COLE (Table 2.3) is a "value that denotes the fractional change in the clod dimension from a dry to a moist state" and can be used "to make inferences about shrink-swell capacity and clay mineralogy" (Soil Survey Laboratory Staff, 1995). Values up to 0.17 cm/ cm in Pit 2 and up to 0.19 cm/ cm in Pit 3 clay horizons indicate an abundance of expandable clay minerals. In addition, the ratio of linear extensibility percent (LEP) to total clay percent indicates that the clay horizons are very smectitic (>0.15). COLE values for the soil horizons in Pits 1, 2, and 3 range from low (<0.03 cm /cm) to high (0.06-0.09 cm/cm) shrink-swell classes. COLE values for soils of Pit 4 indicate high levels of shrink-swell clays for all horizons. Erratic values for soils in Pit 4 are probably from the nature of the different alluvial deposits. Soil organic matter content (Table 2.4) was calculated from organic carbon content. Organic carbon content can be used as an indirect measurement of organic matter (Soil Survey Laboratory Staff, 1995). The "Van Bemmelen factor" of 1.724, which is based on the assumption that organic matter contains 58% organic C, was used for the conversion. 25 The organic matter content of all the soil pits shows a trend of increasing organic matter content downslope. Pit 1 soils have 5.8% organic matter in the upper 7 cm. Pit 2 soils have 9.6% organic matter content in the upper 7 cm and 5.1% to 14 cm. Pit 3 soils have 9.8% in the upper 7 cm and 4.8% to 16 cm. Both Pits 2 and 3 have 2.5% organic matter down to 27 cm. Pit 4 soils have 15.8% in the upper 6 cm with over 4% down to 35 cm. The abundance of organic matter in these soils is likely due to the dominant vegetation that consist of a variety of annual and perennial grasses (Oades, 1988). The increase of organic matter content downslope is due to the increase in soil moisture and duration of saturation that slows decomposition of organic matter (Oades, 1988). Soil solution pH (1:1 water) and exchangeable pH (1:2 CaC12) were determined for each horizon of the four pedons (Table 2.4) at the NSSL from samples taken during the dry summer season. Soil solution pH (active pH) ranges from moderately acid to slightly alkaline (5.6 to 7.8) at Pit 1 and very strongly acid to slightly alkaline (4.7 to 7.5) at Pits 2, 3, and 4. The exchangeable pH ranges from extremely acid to neutral (pH 4.1 to 7.0). Comparison of pH between soils of Pit 1 and Pit 2 show a decrease in pH in Pit 2 subsurface horizons. Comparison of pH between soils of Pit 2 and Pit 3 show a decrease in pH in Pit 3 surface and subsurface horizons. The decrease in pH could be the long-term result of reduction-oxidation processes. A decrease in pH can occur from a process called ferrolysis where displaced cations are replaced by exchangeable Fe2+ ions and lost by leaching or lateral flow. Upon oxidation, H+ replaces the adsorbed Fe2+ ion and within days is replaced by A13+. In this system, "exchangeable Fe2+ is the immobile, potentially acid component" (van Breemen, 1988b). In some reductive 26 reactions, the reduction of iron consumes less hydrogen ions than the oxidation of iron produces, which can result in a long-term net increase in acidity as shown by the following reactions: 1 /24 C6H1206(aq) + Fe0OH(s) +1 3/4 H+(aq) = Fe2÷(aq) Fe2+(aq) 1/4 HCO3- (aq) + 1 3/2 H20(1) 1/4 O2(g) +1 1/2 H20(1) = Fe0OH(s) + 2H+(aq) Usually, exchangeable pH is 0.5 to 1.5 units lower than active pH due to the salt cations (CaC12) putting exchangeable aluminum into solution and subsequent hydrolysis (Foth and Ellis, 1988; Soil Survey Laboratory Staff, 1995). Soils at Pit 3 and Pit 4 were within the expected 0.5 to 1.5 unit change, but soils at Pit 1 and Pit 2 had a difference in pH up to 2.6 units lower in some horizons. The large change between the pH values may indicate a relatively large amount of Al in the soils in Pits 1 and 2. Although acid soils with pH 5.5 or more have little exchangeable aluminum (A13+), hydrolysis of hydroxy forms of Al can be a major source of hydrogen ions between pH 4 and 7.5 (Foth and Ellis, 1988). Chemical dissolution analysis performed on the soils included dithionite-citrate extractable Fe, Mn, Al and ammonium oxalate extractable Fe and Al (Table 2.4). Dithionite-citrate extractable iron (Fed) is considered a measure of the "free" Fe oxides or total pedogenic Fe in the soil (Soil Survey Laboratory Staff, 1995). Ammonium oxalate extractable iron (Feo) is considered a measure of the poorly crystalline Fe (Schwertmann, 1988) . The Fe./ Fed ratio gives an approximation of the relative proportion of ferrihydrite (Schwertmann, 1988). All four pedons at the study site contain an appreciable amount (2.2% to 4.8%) of iron oxides (Fed). The soils of Pits 1, 2, and 3 have values between 2.2% and 3.1% and Pit 4 has the highest values that range up to 4.8%. 27 The B/E and E/B horizons of Pits 2 and 3 have segregated areas of high and low chroma colors, which indicate repeated periods of reduction, translocation, and oxidation of iron and manganese. However, the redistribution of iron appears to be occurring within the depleted horizons. The iron oxide (Fed) content of 2.9% and 2.8%, respectively, indicates that Fe2+ iron is not being translocated out of the horizons. In fact, the data infers a slight increase in iron content compared to the horizons above and below. The results were unexpected since slope and soil heterogeneity, which are associated with hydraulic properties, promote subsurface lateral flow (throughflow) (Zaslaysky and Rogowski, 1969) and lateral translocation of Fe2+ iron (Blume, 1988). There may be some vertical movement of Fe2+ either by eluviation from the surface horizons or by upward movement of Fe2+ toward higher 02 partial pressures from lower wetter horizons. Another possibility is that translocation of Fe2+ by lateral flow from upslope is greater than the amount of Fe2+ ions being translocated out. The hillslope's geomorphic and geometric components could be contributing to this phenomenon. The hilislope at Sites 2 and 3 is a concave-linear footslope compared to convexlinear backslope at Site 1. Flow lines of infiltrating water converge in a concave landscape position (Ruhe, 1975) and the break in slope with a decrease in relief would slow down the rate of flow (Whipkey and Kirkby, 1978) and could create a "sink" for Fe that is being translocated from upslope. The clay horizons of Pits 2 and 3 have a 2.5Y hue that is often associated with soils that have low free-iron content (Daniels et al., 1960). However, the clays have high free-iron content ranging from 2.3% to 2.9%. We can infer from the data that the color in the clay horizons is inherited from the primary minerals of the parent material 28 in which they were formed. Since the clay horizons have the same hue as the underlying sandstone, residual formation was considered. However, the particle-size distribution, particularly the clay-free sand percentage, indicates that the clays are not residuum. Further investigation on discontinuities and source of the clays is discussed in Chapter 6. In soils of Pits 2 and 3, the increase in the relative proportion of ferrihydrite (Feo/Fed) correlates with the increased organic matter content and redoximorphic features. Soil surface and subsurface horizons have two to seven times as much ferrihydrite as the clay substratum. In addition, soils in Pits 2 and 3 have two to three times more ferrihydrite than the soils in Pit 1. The increase downslope of ferrihydrite is attributed to an increase in reducing conditions. Blume (1988) and Van Breemen (1988b) indicated that in many cases a larger fraction of poorly crystalline Fe oxide (Feo) was found in environments that had seasonally saturated soils. Dithionite-citrate extractable manganese (Mnd) (Table 2.4) is considered the "easily reducible Mn" (Soil Survey Laboratory Staff, 1995). Only trace amounts of manganese were in the soils of Pits 1 and 2. Manganese content increased downslope starting in Pit 3 soils and reached high levels (>0.2%) (Ponnamperurna, 1972) in Pit 4 soils. The trend could indicate that manganese is extensively redistributed within the landscape. Manganese is reduced at a higher redox potential than iron (Gotoh and Patrick Jr, 1972) and thus is more mobile. A study by McDaniel et al. (1992) showed that Mn is distributed independent of silicate clay and Fe oxides and generally increases downslope. However, the higher levels of manganese in the soils at Pit 4 could also partially be due to manganese inherited from alluvial parent materials. 29 Dithionite-citrate extractable aluminum (Ala) and ammonium oxalate extractable aluminum (Al.) data are listed in Table 2.4. Ala represents the aluminum substituted in Fe oxides (Schwertmann and Taylor, 1989) while Al. is an estimate of the total pedogenic aluminum in allophane, imogolite, and organically bound aluminum (Soil Survey Laboratory Staff, 1995). Comparison of the Ala and Al. data suggests that a majority of the aluminum in the soils is complexed with iron oxides. Substitution of Al for Fe in goethite is common (Norrish and Taylor, 1961) and can range up to 33 mole percent (Schwertmann and Taylor, 1989). According to Schwertmann (1988), the extent of Al substitution reflects the activity of Al in a system and the activity of Al is controlled by factors such as pH, type of Al compound, stability of Al-organic complexes, and silicate activity. Mineralogical The mineralogical characterization by the National Soil Survey Laboratory (Appendix A) shows the mineralogy of selected horizons for the <21-1,M fraction. The fine-clay mineral assemblage indicates that the soils are smectitic with lesser amounts of vermiculite, interlayered smectite, mica, and kaolinite. Supplemental X-ray diffraction analyses were run on random powder mounts of the Pit 1, 2, and 3 sandstone samples and a sample of the 3Bsstyl clay horizon from Pit 3. The diffractograms of the sandstone samples (Fig. 2.3) show that Pit 1 2Crt, Pit 2 4BCt 1, and Pit 3 4BCt horizons have small peaks at 3.06-3.08A and 2.87A that may be gypsum. The 3l3ssty 1 clay horizon of Pit 3, where the highest accumulation of gypsum was noted (Fig. 2.4), differs from the sandstone horizons in that the sample shows sharp intense peaks at 7.61A and 3.06A. Figure 2.3. Random powder mount XRD patterns of weathered bedrock samples from Pits 1, 2, and 3. [1] Gypsum - CaS0412H20 7500 S 5000 0 C C 2500 Pit 2-413Ct1 Pit 3-4BCt 10 20 30 40 2-Theta(deg) 50 60 Figure 2.4. Random powder mount XRD pattern of the 3Bsstyl clay horizon. [1] Gypsum - CaSO4!2H20 400035003000- -3 2500c 0 Pit 3-3Bssty1 5 2000 ca) 1500- 1000500- 10 20 2-Theta(deg) 32 To confirm the identification of gypsum, scanning electron microscopy (SEM) was performed on the 3Bssty 1 clay sample from Pit 3. The SEM scan shows very large crystals (Fig. 2.5a) concentrated within the soil matrix and in some instances engulfing the matrix within the crystal structure (Fig. 2.5b). The accompanying X-ray energy spectrometry (Fig. 2.6) shows that the crystal mineralogy is mainly calcium sulfate and that the soil matrix is completely void of any microscopic calcium or sulfate. Gypsum (CaSO42H20) is the most common sulfate mineral in soils (Doner and Lynn, 1977) but is an anomaly for the subhumid Willamette Valley soils. Gypsum can be either lithogenic or pedogenic. Lithogenic gypsum is inherited from the parent material. Pedogenic gypsum is formed as a secondary product of pedogenic processes (Hallmark, 1985). Although improbable, lithogenic evaporates may have formed in the basin sediments of the Willamette Valley during the Miocene- Pliocene periods. Gradual uplifting of the coast and filling of the basin with sediments caused a gradual retreat of the ocean shoreline before the valley became separated from the ocean (Orr et al., 1992). Evaporation in a chemical system receiving new solution from the sea usually results in gypsum, anhydrite and some halite evaporites (Williams et al., 1954). However, high rates of evaporation were unlikely in the moist semitropical environment (Orr et al., 1992) that existed. In addition, any evaporites would have leached from the soils in Oregon's wet climate. A pedogenic origin is a more plausible hypothesis. Pedogenic gypsum could originate from marine sandstones that were once reducing in chemical character. Snavely Jr. and Wagner (1963) state that it was likely that a nearshore environment existed along the eastern margin of the present Willamette Valley during the late 33 Figure 2.5. SEM micrographs of gypsum crystals and clay matrix from the 3Bsstyl horizon. (a) Gypsum crystals. (b) Crystals engulfing matrix. (a) (b) 34 Figure 2.6. X-ray energy spectrometry of the crystals and matrix from the 3Bsstyl horizon. (a) Crystal mineralogy. (b) Matrix mineralogy. (a) (b) 0 Cursor= Vert=366 Window 0.000 -40.950= 17737 cnt 35 Eocene. They found beds of massive arkosic and volcanic sandstones containing interbedded carbonaceous siltstone along the southeastern margin of the basin. These Eocene beds were formed in shallow-water marine and brackish-water environments. Tidal flats probably formed along the retreating edges of the ancient Pacific shoreline providing organic accumulations and some areas of stagnant marine waters. Under this type of reducing marine environment, along with iron and sulfate rich sediments, pyrite (FeS2) could form (Doner and Lynn, 1977). Once the sea had receded, 02 would have started to oxidize the pyritic exposed sediments. Acid sulfate soils and jarosite are usually the result (Doner and Lynn, 1977). However, if calcium carbonates or other Ca-bearing materials (Ritsema and Groenenberg, 1993) are present, acidity is neutralized and gypsum forms. It is also possible for jarosite and gypsum to occur together (Doner and Lynn, 1977). Van Breemen (1982) described jarosite as a pale yellow (2.5-5Y 8/38/6) mineral that forms only in an acid (pH 2 to 4) environment, but can persist for decades at pH values above 4 and eventually hydrolyze to goethite. A third possibility is that the volcanic basalt foundation under the sandstone formation is influencing the chemical properties in the lower solum. The basalt foundation could be cracked and broken by faults and joints from tensions created during the subduction of the Juan de Fuca plate beneath the North American plate. Water movement through the network of faulting could provide the sandstones with a source of sulfur from dissolution of pyrite when the groundwater table rises. Combined with the calcium from plagioclase feldspars in the arkosic sandstones, gypsum could form. In summary, gypsum accumulation in the lower clay horizons and traces of gypsum in the sandstones is likely attributed to the stratified arkosic sandstones and interbedded sulfate rich siltstones. 36 Most of the gypsum is probably seasonal with the calcium sulfate being brought up into the lower clay horizons from the sandstones with the seasonal rise in water table levels. The gypsum diffuses to and precipitates in the aerated cracks caused by the high shrink-swell clays during the dry summer season. Retention of the gypsum in the moist Willamette Valley climate is probably due to the hillslope's stratigraphy that has restricting clay horizons, which prevents deep leaching. Classification The soils on the upper transect (Pits 1, 2, and 3) were originally classified by the Soil Conservation Service as fine, mixed, mesic Ultic Haploxerolls and very fine, mixed, mesic Aquultic Haploxerolls (Soil Survey Staff, 1975a). The soils on the lower transect (Pit 4) were classified as very fine, montmorrillonitic, mesic Typic Pelloxererts. According to current morphologic features and characterization, the soils were classified as: Ultic Haploxerolls for Pit 1, Aeric Humaquepts for Pit 2, Vertic Epiaquepts for Pit 3, and Typic Endoaquerts for Pit 4. Conclusion High chromas and few iron redox features indicate very short periods of saturation and reductive conditions in soils at Site 1. Redoximorphic concentrations within 7 cm of the soil surface in soils of Pits 2 and 3 and concentrations at the surface in soils of Pit 4 show that iron and manganese are being reduced and oxidized high within the soil profile. The presence of iron masses composed of ferrihydrite and lepidocrocite suggests a reducing environment with periodic saturation for long durations. 37 In comparing the surface and subsurface soils of Pits 1, 2 and 3, the increase in the relative proportion of ferrihydrite (Feo /Fed) correlated with increased organic matter content and redoximorphic features. Manganese content varied according to landscape position. Only trace amounts of manganese (Mai) were in the soils of Pits 1 and 2 on the upper transect. Manganese content increased downslope starting in Pit 3 soils and reached high levels (>0.2) in Pit 4 soils. Field morphological investigation suggested the presence of one and possibly more discontinuities. Physical analysis confirmed the presence of three discontinuities on the upper transect. Horizons with zones of depletion over clay horizons and evidence of a discontinuity suggest that the low hydraulic conductivity of the clays on the upper transect restricts vertical water movement and creates a seasonal perched water table. The clay horizons of Pits 2 and 3 have the same hue as the underlying sandstone but the particle-size distribution indicates that the clays are probably not residuum. Further investigation on the source of the clays is discussed in Chapter 6. Soil morphologic features and soil characterization data provide for some contrasting preliminary interpretations at Sites 2 and 3. Low chroma and high (?_4) value matrix colors that occur in subsurface horizons indicate zones of iron depletion. However, dissolution extractions indicate the amount of pedogenic iron in the AB, B/E, and E/B horizons of Pit 2 and the B/E and E/B horizons of Pit 3 is slightly higher than in the horizons above or below. Possible causes could be from the eluviation of Fe2+ from surface horizons, upward diffusion of Fe2+ toward higher 02 partial pressures, and translocation of Fe2+ by lateral flow from upslope along with the decrease in flow rate due to the concavity of the slope at Sites 2 and 3. 38 Soil morphology, along with physical, chemical, and mineralogical data, suggests a complex stratigraphic and pedogenic history resulting in soils with pedogenic features superimposed across several lithologic discontinuities. 39 Chapter 3 HYDROLOGIC REGIME AND REDUCING ENVIRONMENT AT THE WITHAM HILL BACKSLOPE-FOOTSLOPE STUDY SITE Introduction Currently, the hydric soil definition defines hydric soils as soils "that formed under conditions of saturation, flooding, or ponding long enough during the growing season to develop anaerobic conditions in the upper part" (Federal Register, July 13, 1994). The definition encompasses duration of saturation, depth to saturation, presence of anaerobic conditions, and soil temperature, which are important factors in both the formation and verification of hydric soils. The objective of this chapter is to examine these factors through a detailed characterization of the hydrology and reducing environment of the study site soils to determine if the soils are hydric according to the hydric soil definition issued by the National Technical Committee for Hydric Soils (NTCHS). Background General The NTCHS Technical Standard Committee is currently working on technical standards to clarify the definition of hydric soils and provide measurable specifications to evaluate when the definition has been met (US Department of Agriculture, Natural Resource Conservation Service, 1995). The National Technical Committee for Hydric Soils (1996) has proposed that the "upper part" be defined as less than 30.5 for loamy or finer textured soils and less than 15 cm for sandy soils. The National Research Council (1995) indicates, based on available data, that "reasonable hydrologic thresholds would include a 40 depth to water table of < 1 ft (30 cm) for a continuous period of at least 14 days during the growing season, with a mean interannual frequency of 1 out of 2 years." The council concluded that the thresholds are consistent with those defined for formation of hydric soils according to Hydric Soils of the Unites States (US Department of Agriculture, Soil Conservation Service, 1991). Growing season, in determining hydric soils, is defined as "the portion of the year when soil temperatures are above biologic zero in the upper part" (US Department of Agriculture, Soil Conservation Service, 1991). Biological zero is at 5°C (41°F) (Soil Survey Staff, 1975b) at 50 cm beneath the soil surface (National Technical Committee for Hydric Soils, 1996) and is considered the threshold that biological activity is assumed to be negligible. Hydrology Hydrology is recognized as the driving force behind the development of hydric soils. The hydrologic parameters for determining hydric soils are defined in terms of duration of continuous saturation, flooding, or ponding within a given distance of the soil surface during the growing season. Saturated soil conditions are normally considered to exist when pores are filled with water and the pore water has zero pressure (at the water surface) or positive pressure (below the water surface). Negative pressure occurs above the water table (water surface) in the unsaturated zone. However, saturation can extend above the water table in a tension-saturated zone (negative pressure) called the capillary fringe (Freeze and Cherry, 1979; Stephens, 1996). The capillary fringe zone can range from 10 cm in very coarse material to greater than 100 cm in fine-textured clays (Stephens, 1996). But for 41 surface horizons, consideration must be given to large pore spaces created by flora and fauna that decrease capillary rise (National Research Council, 1995). Thus, in most cases, the water table is considered a reasonable approximation of the saturated zone. Field piezometers, which are open to water flow at the bottom and to the atmosphere at the top, can be used to measure the elevation of groundwater. Height of a water column in a piezometer is an indication of the pressure potential of pore water and is expressed as pressure head (Hillel, 1980). Freeze and Cherry (1979) define a water table as the free surface in the soil-groundwater system where pore water is at atmospheric pressure. The surface of a column of water in a piezometer is at atmospheric pressure and has zero pressure head. In unconfined aquifers and perched aquifers, the surface is called the piezometric surface, which can be used as an indication of water table levels (Freeze and Cherry, 1979). Piezometers can not measure negative pressure potentials and, therefore, can not be used to measure the capillary fringe. The capillary fringe in which pores are saturated by capillarity and the water held by surface tension (Bouma et al., 1974; Hillel, 1980) can be measured by tensiometers, which measure matrix potential (Freeze and Cherry, 1979; Hillel, 1980). Zones of saturation can be a major factor in the genesis of a soil's morphology and development of hydric soils. Saturation can be continuous from the upper to the lower horizons, restricted to horizons near the surface due to slowly permeable horizons, or upper and lower saturated horizons can be separated by a layer without free water. The International Committee on Soils with Aquic Soil Moisture Regimes defines soils that are saturated in all layers from the upper boundary of saturation to a depth of 2 m or more, as having endosaturation (Vepraskas, 1994). This type of saturation usually has 42 oxidized conditions above reduced horizons. Soils that are saturated in layers above unsaturated layers within a depth of 2 m have episaturation. Perched water tables formed over horizons having low saturated hydraulic conductivity are characteristic of episaturation. Both epi- and endosaturation can occur when a perched water table is present above an aerated zone that has a rising groundwater table beneath (Dudal, 1990). Reducing Environment Although the hydric soil definition is based on anaerobic conditions (reduction and removal of molecular oxygen), there is still debate about whether the hydric soil concept should be based on the depletion of oxygen (anaerobiosis) or more intense reducing environments involving the reduction of iron. The reduction of iron has become the accepted parameter for characterizing anaerobic environments in morphological evaluations and an alternate threshold for research (Bohn, 1971). The absence of oxygen in the field is not verifiable without installed equipment, but the hydrologic and reducing environment can be inferred from morphological properties related to the reduction-oxidation of manganese and iron. The reducing environment is influenced by oxygen supply, microbial community, organic matter, pH, soil temperature, and abundance of electron donors (Gambrell and Patrick Jr, 1978). Development of anaerobic conditions occurs when the soil is near depletion or depleted of molecular oxygen. The depletion of oxygen in saturated soils is caused by biological activity. Oxygen is used by microorganisms (mainly bacteria) in the obtainment of chemical energy and the process involves oxidation-reduction reactions (Rowell, 1981). As heterotrophic aerobic and facultative microbes decompose organic 43 matter (oxidation reaction) for an energy source, they utilize oxygen as the electron acceptor (reduction reaction). In saturated soils, the diffusion rate of oxygen is 104 times slower than diffusion in the gaseous phase and microbes demand for oxygen exceeds supply (Rowell, 1981). Once all 02 has been reduced, heterotrophic facultative and anaerobic microbes use alternate inorganic soil components as electron (hydrogen) acceptors (Ponnamperuma et al., 1967; Gambrell and Patrick Jr, 1978). Microbes continue to oxidize organic matter in a thermodynamic sequence of reduction-oxidation (redox) reactions involving the reduction of NO3-, Mn4+, Fe3+, and 5042- (Turner and Patrick Jr, 1968; van Breemen, 1988a; Ponnamperuma, 1972; Patrick and Jugsujinda, 1992). Iron has been found to play a dominant role in periodically wet soils since it is usually the dominant oxidant in the absence of oxygen (van Breemen, 1988a). Reduction of these minerals affects their solubility, movement, and concentrations (Rowell, 1981; Bohn et al., 1985; van Breemen, 1988b). Transfer of electrons in redox reactions creates an electrochemical potential that can be measured. The electron activity (pE) can be measured electrically in reference to a standard substance, (H2), and is commonly referred to as redox potential (Eh) (Rowell, 1981). The Eh is defined as the energy gained in the transfer of 1 mole of electrons from an oxidant to hydrogen (Freeze and Cherry, 1979) and is related to the distribution of ion oxidation states by the Nernst equation at equilibrium conditions (Bohn, 1971): Eh (volts) = Eh° + RT in Joxidant] nF [reductant] Eh° = standard potential of the redox couple F = faraday constant R = gas constant T = absolute temperature in Kelvin n = number of transferred electrons 44 The most widely accepted method to measure redox potentials in soils is with permanently installed platinum electrodes. The electrode potential is a measurement of the tendency of a substance to donate or accept electrons (Bohn et al, 1985). According to Bohn (1971), soil redox potentials cannot be quantitatively evaluated in terms of individual redox couples due to mixed couple potentials in the nonequilibrium system. A redox potential is a semi-quantitative measurement (Ponnamperuma, 1972) of a mixed potential that is the weighted average of all redox couples present in the system (Bohn, 1971). Platinum electrodes are used because platinum is responsive to changes of redox conditions in natural systems and platinum is "inert", responding only to the potential of the electrons. Redox couples affect the mixed potential in proportion to their ability to exchange electrons with the electrode surface (Bohn, 1971). As microbes utilize the sequence of electron acceptors, the redox potential lowers due mainly to redox couples that have lower affinity for electrons (Rowell, 1981). The redox potential also depends, in part, on pH, soil temperature, and the concentrations of reactants (Rowell, 1981). The concentration of reactants is especially important since the final potential is determined by the system which is in excess (Ponnamperuma, 1972). A soil's hydrogen ion activity (pH) influences mineral equilibrium which regulates the dissolution and precipitation of solids, the sorption and desorption of ions, and the concentration of ions (Ponnamperuma, 1972). Therefore, interpretation of Eh measurements needs to include the pH factor. In general, a higher soil pH requires lower redox potentials for the reduction of Mn and Fe oxides. In addition, when soils become saturated and anaerobic, the pH changes and stabilizes between pH 6 and 7 after a few weeks or 45 months (Ponnamperuma, 1972). The increase of pH in acid soils is the consequence of chemical reduction of acidic or inert components to their basic or weekly acidic counterparts and to the formation of ionic Fe2÷ that involves consumption of H+ (van Breemen, 1987). The increase is due mostly to the reduction of iron since Fe oxides are usually more abundant than other oxidants (Ponnamperuma, 1972). The decrease of pH in alkaline soils is due to the accumulation of CO2, which usually exceeds the pH-increasing effect of iron reduction (van Breemen, 1987). To remove pH variability between soils and obtain a common threshold for reduction analysis, redox potentials usually are adjusted to pH 7. However, the adjustment factor is still under debate. Stability of solids in equilibrium with their soluble forms is expressed by Eh-pH diagrams (stability field diagrams). Theoretical Eh-pH diagrams based on thermodynamics have been established for the redox equilibria of manganese and iron (Ponnamperuma et al., 1967 and 1969; Collins and Buol, 1970a) and provide a negative Eh/pH slope of 177mV per pH unit for equilibrium conditions. Some researchers have had poor agreement with the theoretical relationships. Collins and Buol (1970b) found that results in soils with rapid rates of ion movement under mass-flow and conditions of slow oxidation disagreed with theoretical equilibrium predictions. Ponnamperuma (1972) concluded thermodynamic relationships could be developed only for soil solutions whose potentials are equilibrium potentials but not for soils whose potentials are mixed. Some researchers have used an adjustment factor of -59 mV in Eh for each pH unit change from pH 7. The factor, which is based on the change in Eh between a buffered pH 4 and pH 7 solution, has become an accepted adjustment for soil potentials even though the value has not been thoroughly evaluated insitu (Bohn, 1971). The 46 NTCHS Technical Standard Committee currently is investigating a recommended Eh-pH slope. Many laboratory experiments and some in situ studies have been done to determine critical redox potentials at which reduction of nitrate, manganese compounds, and iron compounds occur. Manganese and iron reduction has been found to occur within a wider range of Eh values than the start of nitrate reduction. Turner and Patrick Jr (1968) found that the point of oxygen depletion and the beginning of nitrate reduction in 10 soil-water suspensions (corrected to pH 7 by the -59 mV per unit pH change) was within +300 to +350 mV. The authors found the greatest amount of reducible Mn at a potential of +200 mV. Patrick Jr and Jugsujinda (1992) found oxygen depletion occurred at +350 mV in their study on redox potentials in soil-water suspensions with a pH maintained at 6.5. The authors had thresholds of +200 mV for the appearance of Mn(II) and +100 mV for Fe2+. Gotoh and Patrick Jr (1972,1974) reported Mn reduction between potentials of +300 mV and +200 mV in soil-water suspensions regulated at pH 6 and pH 8 and Fe reduction at potentials between +300mV and +100mV in soil-water suspensions regulated at pH 6 and pH 7. Patrick Jr and Henderson (1981) had critical redox potentials for Mn between +250 and +200 mV and iron at +100 mV for soil-water suspensions held at a constant pH 7. Bohn et al. (1985) gave a range of +400 to +200 mV for Mn potentials and +300 to +100 mV for Fe potentials but noted the potentials were measured over a range of pHs. Cogger et al. (1992), in an in situ study, reported Fe2+ in soils at potentials below +200 mV with unadjusted pH values between 6 and 7. Austin (1997) found detectable levels of Fe2+ with colormetric indicators at +300 mV in some Willamette Valley soils. As can be seen, an attempt to define critical threshold potentials has not been successful. An important point made by Ponnamperuma 47 (1972) is that studies done in soil-water suspensions came closer to obtaining the expected theoretical relationships than studies done in soils. A soil can be saturated without becoming anaerobic if the environment is unfavorable for organisms such as low organic matter content, low soil temperatures, pH, or if the water is aerated by movement (Daniels et al., 1973). In addition, rates of oxygen depletion and reduction reactions are controlled in large part by the amount of organic matter and soil temperature. Studies have shown the importance of organic matter content on microbial activity and dissolution of iron and manganese. Meek et al. (1968) observed lower Eh values with the addition of organic matter to soils. Dobos et al. (1990) found that the addition of organic carbon had a marked affect on iron reduction and chroma colors under alternating oxidizing and reducing conditions. Couto et al. (1985) found that the lack of an energy source in the substrata prevented iron reduction. Soil temperature influences diffusion rates, biological activity, and the rate of redox potential depression. Bonner and Ralston (1968) observed decreased microbial activity and a decline in redox potentials in saturated soils as soil temperatures decreased. Meek et al. (1968) subjected organically amended soils to higher temperatures and found a substantial increase in microbial activity and higher quantities of reduced Mn and Fe. The soil's anaerobic environment can, in part, be characterized by measuring groundwater dissolved oxygen content (DO) of a soil. Cogger and Kennedy (1992) found that horizons with DO levels <5 mg/ L for more than 80% of the time they were saturated had low redox potentials and were reduced for part of the year. Horizons with DO levels <5 mg/L for 60-80% of the time were reduced only in microsites. Dissolved oxygen content of 1.5 mg/L was found by Austin 48 (1997) to be a conservative threshold for anaerobiosis in selected Willamette Valley soils. Cogger et al. (1992) found that groundwater dissolved oxygen data combined with soil redox measurements gave the most comprehensive picture of the soil-ground water redox environment. Growing Season The definition of growing season and its application has been controversial and continues to be assessed. The concept of biological zero with the assumption that biological activity and reduction reactions cease at a specified threshold for regions with widely differing climate can lead to errors in evaluating hydrologic data (National Research Council, 1995). A review of studies in the Wet Soil Monitoring Project showed that the current concept of growing season was not applicable in most studies (US Army Corps of Engineers, 1996). The National Research Council (1995) found that a number of studies indicated that significant microbial activities occur at temperatures below the biological zero threshold in a wide variety of climates. Methods General Four sites (Sites 1 through 4) located approximately four meters from the four soil pits (Pits 1 through 4) were instrumented with open wells, nests of piezometers, permanently installed electrodes, and thermocouples. Six additional plots (Plots A-F) were placed between the four main sites and instrumented with a limited number of piezometers to provide additional data on the spatially dynamic nature 49 of the hydrology. Figure 3.1 presents the layout of the instrumented sites, plots, and adjacent excavated pits. Readings were taken weekly during the rainy season from October through June but were suspended from early summer to mid autumn when precipitation was minimal and water tables fell beneath well depths. Readings were taken on the same day of each week to ensure unbiased readings. Complete field measurement data files are given in Appendix C. Equipment Construction and Installation Piezometers and Wells Piezometers and wells were constructed following procedures outlined by Austin (1994). Piezometers were constructed from 1.9 cm O.D. 200psi PVC pipe. Horizontal slits were cut in the lower 8 cm of each PVC pipe and geo-fabric was glued over the slits and open end of the pipe to prevent clogging in situ with soil particles. A PVC cap with a small hole drilled in its top to facilitate air entry was placed over the top of the upper end of each piezometer. Piezometers were installed in triplicate at 20 cm, 35 cm, and 75 cm depths at Sites 1, 2, and 3 and at 25 cm, 50 cm, and 100 cm depths at Site 4. Plots A-F had one piezometer installed at 20 cm, 35 cm, and 75 cm depths. Placement of piezometers was determined by random selection. An auger hole approximately 2 cm in diameter was dug to 3 cm beyond the desired depth for each piezometer and the bottom of the holes filled with 3 cm of sand. The slotted ends of the piezometers were placed in the holes and sand was poured in until the slatted portions of the pipes were embedded in a sand layer. Bentonite was poured in the holes around the piezometers to create a bentonite plug 50 Figure 3.1. Diagram of the instrumented sites and plots, excavated pits and trench, and vegetation plots. Plot A well piezometers 24.5 m veg. Site 1 well electrodes piezometers thermocouples Pit 1 16.3 m Plot B well piezometers trench 5.3 m Plot C well piezometers 5.8 m veg. Site 2 well electrodes piezometers thermocouples Pit 2 piezometers thermocouples Pit 3 11 m Plot D well piezometers 19.7 m Plot E well piezometers 110.2 m veg. Site 3 well electrodes 63.2 m Plot F well Gravel Road piezometers 36 m veg. Site 4 therm. electrodes well piezometers Pit 4 51 that extended to the soil surface to prevent water from running down the sides of the pipes. A well (open borehole) was installed at 100 cm depth at all sites. Wells were built from 3.18 cm O.D. 160psi PVC pipe with horizontal slits along the entire section of the pipe to be placed underground. Geo-fabric was glued over the slits and open end of the pipe. A PVC cap with a small air hole was placed over the open end of the well. Auger holes were dug 3 cm beyond the desired depth and the extra 3 cm filled with sand. Each well was placed in a hole and sand was poured around the pipe to the ground surface. Platinum Electrodes Platinum electrodes were constructed according to procedures outlined by Austin (1994) and Szogi and Hudnall (1990). The electrodes were quality checked in a pH-buffered quinhydrone solution (Bohn, 1971). Only electrodes that varied less than plus or minus 10 mV from established test values were used. The electrodes were installed in triplicate at 10 cm, 30 cm, and 50 cm depths at Sites 1, 2, and 3 and at 25 cm, 50 cm, and 100 cm depths at Site 4. Electrodes were installed by making pilot holes perpendicular with the soil surface with a metal rod somewhat larger than the diameter of the electrodes. The holes were made 2 cm shallower than the desired depth. Electrodes were placed in the holes using a hollow copper tube to push them down the hole and embed them the final 2 cm into the undisturbed soil. Pilot holes were back-filled with bentonite and capped with 5 cm of soil. The 10 cm electrodes, due to the shallow depth, were installed at a 36° angle to the soil surface. The angle allowed shallow installation while still keeping the mercury properly positioned around the copper wire. Precautions were taken to insure no foot traffic over the installations. 52 Thermocouples Type K, ungrounded, inconel sheathed thermocouples that were premanufactured to four foot lengths and calibrated to plus or minus 3 degrees Fahrenheit (Austin, 1993) were used for the project. The thermocouples were fitted with male connectors for field application. Prior to installation, the thermocouples were tested by immersion into a cooled liquid at a known temperature. Installation of the majority of thermocouples was accomplished simply by slowing pushing them into the soil to the desired depth. If any resistance was encountered, a pilot hole was made within 2 cm of the desired depth with a steel rod that had the same diameter as the thermocouple. The thermocouple was then inserted and pushed the last 2 cm into undisturbed soil. A PVC pipe with a cap at one end was placed over the male connectors to keep them dry. Data Collection and Interpretation Saturation Depth to the water surface in the piezometers was taken as a direct indicator of the water table level. Open wells provided an indication of saturated conditions somewhere in the soil profile. The capillary fringe that can occur above the water table was not measured in this study. However, when correlating hydrologic data to redox data and morphological features this variable should be kept in mind. The capillary fringe zone can range from 10 cm in very coarse material to greater than 100 cm in fine-textured clays (Stephens, 1996). Austin (1994) found that the capillary fringe ranged from 10 cm in silt loam and silty clay loam to 20 cm in silty clay or clay soils in selected Willamette Valley soils. 53 Depth to the water surface was determined by measuring the distance from the top of the piezometers and wells to the standing water surface. This was accomplished by blowing air into a metered acrylic tube as it was lowered into each piezometer and well. The method is similar to the one used by Hudnall and Wilding (1992). When the tube contacted the water surface, the bubbling sound of air through water could be heard. Measurements from the metered tube were noted and later input into spreadsheets. The spreadsheets were formatted to subtract the length of piezometric pipe that extended above the soil surface for each piezometer and well from the field measurement. The corrected reading gave the depth to the free water surface below the soil surface. Corrected data from triplicate piezometers at each depth were averaged for graphing and interpretation. Precipitation Daily precipitation data were obtained from the Oregon Climate Service at Oregon State University. The daily precipitation data were averaged weekly to coincide with the weekly data readings. Weekly averages are given in the data files in Appendix C. Rain events, for the purpose of this analysis, refer to weekly totals. Anaerobiosis and Iron Reduction Reductive conditions were characterized by measuring reduction-oxidation (redox) potentials with permanently installed platinum electrodes. Redox potentials were taken using a portable Radio Shack digital voltmeter and a Corning calomel reference electrode. A salt bridge (Veneman and Pickering, 1983) between the soil and reference electrode was created by placing the reference 54 electrode into a syringe that was inserted into moist soil and that contained a 4 M HC1 solution. Readings were recorded as thousandths of a volt once the millivolt reading drift was no greater than 3 mV per minute. The measured redox potentials were adjusted by adding +244 mV (Jones, 1966) in order to reference the potentials to the standard hydrogen electrode (Eh). In addition, potentials were adjusted to remove pH variability between soils and obtain a common threshold for reduction analysis. The average pH at each measured depth for the two field seasons and an adjustment factor of -59 mV for each pH unit change from pH 7 was used to calculate the adjustment of redox potentials to pH 7. Average readings from the triplicate electrodes at each depth were calculated and used for graphing. A redox potential of +350 mV was used as the threshold for the onset of anaerobiosis and a redox potential of +200 mV was used as the threshold for iron reduction. The thresholds were chosen based on a review of redox potentials done insitu or in soil cores. In situ variability among some of the replicate electrodes was high. Patterns were watched the first year and a few electrodes were questionable. The electrodes were left in place but an additional electrode was installed as close as possible to each of the electrodes in question. Readings taken on the originals and replacements during the second year showed the variability was not due to electrode failure. Cogger et al. (1992) found that electrode variability was greater in changing or intermediate redox environments and declined under wellreduced states indicating microsite differences. The variability in the study site electrode readings is believed to be from microsite differences, so the data from the original electrodes were used for the analysis. 55 In addition to redox potentials, anaerobic conditions were characterized by groundwater dissolved oxygen (DO) measurements. The DO measurements were taken in the soil water of each piezometer. The piezometers were pumped and allowed to recharge with fresh ground water before DO readings were taken near the bottom of each piezometer with an Orion Model 820 oxygen meter. Groundwater dissolved oxygen content of 1.5 mg/ L was found by Austin (1997) to be a conservative threshold for anaerobiosis in selected Willamette Valley soils and was used as a threshold value for analysis. Temperature Ambient air and soil temperature readings were taken with a Digi-Sense Model 8528-40 digital thermometer. Soil Solution pH Soil solution pH was measured periodically in the soil water of the piezometers. A Sper Scientific Model 850001 pH analyzer was used for the measurements. The average pH for the two wet seasons at the 75 cm, 35 cm, and 20 cm depths were (a) 5.19, 5.54, 5.73 for Site 1; (b) 6.0, 5.88, 5.82 for Site 2; and (c) 5.51, 5.59, 5.71 for Site 3. The average pH for the two wet seasons at the 100 cm, 50 cm, and 25 cm depths at Site 4 were 7.09, 6.03, and 5.82. Results and Discussion Data on saturation, anaerobiosis, reduction-oxidation potentials, and soil temperature will be evaluated to determine if the soils of each site along the study transect are hydric. Characteristics of soils at 56 each site and trends within each soil profile are discussed. Comparison of data will be made to determine the differences or similarities between the sites and the overall trend within the study area. Both years of the study (9/95 - 9/97) had wetter-than-normal water seasons which run from October 1st to September 30th. Rainfall was 158.45 cm and 161.49 cm for the first and second water year, respectfully, compared to a normal precipitation of 109.22 cm. Site 1 Saturation Piezometer and rainfall data are presented in Figure 3.2. No initial response to precipitation was noted in the first field season until the second week of December, at which time free water was recorded in the well and at all three piezometer depths. A 9.5 cm rain event brought the total seasonal precipitation to 44.6 cm. Water was first noted in the second field season the first week of December with a 7.8 cm rain event and a seasonal total precipitation of 46.9 cm. Again, free water was recorded in the well and at all three piezometer depths. Most saturation lasted less than a week with a few episodes of oneweek duration. Free water, when observed, occurred at every depth with the exception of three episodes. The saturation data indicate several trends: (1) after initial soil moisture recovery of at least 44 cm of precipitation, the soils were saturated to some degree from rain events greater than 7 cm the first field season and 5.7 cm the second field season; (2) once field capacity was reached, there was very little lag time between these precipitation events and water table response; (3) episodes of saturation were one week or less. Figure 3.2. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Site 1. 0 9 rag -20 -3 0 c.) co AA A- = -60 co -80 'CD El _cp -100 *21.74 cm Co a) _c U) -4 a) Lei ON D FF1 M AM JON D J F M AM 1995 - 1997 well D 75 cm v 35cm o 20 cm ppt J 58 An estimated mean water table at Site 1 for the very short periods of saturation would be 14.9 cm below the soil surface for the first field season and 16.4 cm for the second field season. Anaerobiosis and Iron Reduction Reduction-oxidation potentials (Eh) are presented in Figure 3.3. The onset of anaerobic conditions, as indicated by potentials below +350 mV, occurred for only one period that lasted between one and two weeks at 30 cm and 50 cm beneath the soil surface. The potentials never dropped below the +200 mV threshold for iron reduction. The high Eh values indicate the soils are well aerated the entire wet seasons. Site Summary The soils at this site were not continuously saturated nor had anaerobiosis for any periods of 14 days or longer within the upper 30. Therefore, the soils do not meet the hydric soil definition. Site 2 Saturation Piezometer and rainfall data are presented in Figure 3.4. Initial response to precipitation in the first field season was observed in the 100 cm well at the end of October. Water was observed at the 75 cm depth the second week of November and at the 35 cm and 20 cm depths two weeks later. The piezorneter data indicate that the soil was saturated continuously within the upper 20 cm from the last week of November to the last week of March and between 20 cm and 30 cm Figure 3.3. Electrode potentials (top) at 10 cm, 30 cm, and 50 cm depths and duration of saturation as measured by piezometers (bottom) at Site 1. 700 600500400Cl) 300 > 200 g 100 w Duration of Saturation 20 cm an 35 cm 75 cm sommm 1111101 NM IN ammo moilmo ONDJFM AM1995JOND JFM AMJ 1997 Figure 3.4. 0 U co Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Site 2. 0 -20 -40 co o -60 O E -80 ..r) -100 X 16 *21.74 cm 12 a) 8 U) o_ 4 ONDJFM AM JOND 1995-1997 1171111111f well 75 cm 35cm J FMniAMJ 20 cm 0 ppt O 61 until through the first week of April. The water table fluctuated between 8 cm and 46.5 cm below the soil surface from April to June. In the second field season, initial water was observed the third week of November at all piezometric depths due to a high intensity rain event. The soil was saturated continuously within the upper 20 cm until the end of March, between 20 cm and 30 cm through the end of April, and between 30 and 75 cm through the second week of May. One of the triplicate 75 cm piezometers gave erratic readings that were not consistent with the other two piezometers. Figure 3.4 shows the average water table from all three 75 cm piezometer data, but when the data from the third possibly errant piezometer are graphed separately (Fig. 3.5) this piezometer shows a different pressure head than indicated by the other two 75 cm piezometers. This piezometer contained water for only six weeks during the first field season. The second field season the piezometer consistently had water but indicated that the water table was 40 cm to 60 cm beneath the level indicated by the other two 75 cm piezometers. There are a few possible explanations for the data from the 75 cm piezometers. It is assumed that the first and second 75 cm piezometers are above the clay or not far enough into the clay to have an effect on their hydraulic head, since the 2Bt1 clay horizon starts at 70 cm beneath the soil surface at this site. The third 75 cm piezometer could have become completely clogged in the first field season and partially unclogged in the second field season when water was observed but with a lower hydraulic head. A second possibility is that this piezometer is further into the clay horizon and is picking up a different pressure potential. The pressure head at an average of 66.2 cm could be from loss of pressure due to frictional resistance to movement of water in the clays. Dissipation of kinetic energy due to friction against pore walls and Figure 3.5. Water table data (top) below the soil surface with the errant 75 cm piezometer graphed separately at Site 2. 0 E C.) \t4Mk -20 n Ir. :11 VZ7-.tt -40 co 0 -60 -80 a). -10 -100 *21.74 cm Co a) U) U) ONDJFM AM1995-1997 JOND JFM II well 1 I o 75 cm i 35cm I I I 20 cm i III TI AM ppt 63 pore throats (viscous forces) can be significant when discharge is large. The different pressure head could be indicating the pressure head of the rising regional groundwater table. However, these conclusions do not account for the lack of water in the first field season. A third plausible assumption is the presence of some type of macrovoid. In the first field season, the macrovoid could have appeared and drained the piezometer. Before the next wet season began, maintenance was done at the sites. All the piezometers were resealed with bentonite to the soil surface. It was noted that some of the deeper piezometers took large amounts of bentonite, presumably because of large cracks that formed in the high shrink-swell clays below 70 cm. The water levels indicated by the 20 cm and 30 cm piezometers, the first and second 75 cm piezometers, and the well are believed to be from episaturation caused by a perched water table that is occurring above the clay horizons. Further discussion and evidence of episaturation is found in the analysis of Site 3 and Plots B and C data. The mean water table was calculated using the head from the 20 cm and 35 cm piezometers. The mean water table for the first field season was 12.5 cm below the soil surface from 11/28/95 to 5/30/96. The mean water table for the second field season was 12.7 below the soil surface from 11/21/96 to 5/03/97. Anaerobiosis and Iron Reduction Reduction-oxidation potentials (Eh) are presented in Figure 3.6. Conditions fluctuated between aerobic and anaerobic conditions, as indicated by potentials above and below +350 mV, at all depths the first month of the wet season. The onset of extended anaerobiosis began the first week of December at all three depths the first field Figure 3.6. Electrode potentials (top) at 10 cm, 30 cm, and 50 cm depths and duration of saturation as measured by piezometers (bottom) at Site 2. 700 600500400U) 300 > 200 100 Duration of Saturation -- 20 cm 35 cm 75 cm L _tZ NMI ,k11111111116111111111 _111111111111111111111111 11111111111 11111111111111 I 1111111111111 I 111111 OND J FM AM JOND JFM AMJ 1995-1997 Eh 10 cm Eh 30 cm Eh 50 cm 65 season. In the second field season, anaerobiosis again began the first week of December at the 30 and 50 cm depths and the third week of December at 10 cm. Water levels fluctuated between the soil surface and 16 cm causing the delayed anaerobiosis at the 10 cm depth. Iron reduction, as indicated by potentials below 200 mV, did not occur for any significant period at 10 cm below the soil surface. However, anaerobiosis occurred at 10 cm from 12/05/95 to 4/25/96 the first field season and from 12/24/96 to 6/01/97 in the second field season. Iron reduction at 30 cm below the soil surface occurred mainly from 12/19/95 to 5/30/96 in the first field season and from 12/19/96 to 5/16/97 in the second field season. Reducing conditions at 50 cm generally occurred earlier, lasted longer, and had lower Eh values than at 30 cm. Reduction at 50 cm occurred from 12/12/95 to 6/14/96 in the first field season and from 12/10/96 to 5/16/97 in the second field season. The dissolved oxygen (DO) values (Fig. 3.7) show some trends but do not correlate well with redox potentials. Gradual depletion of DO from the system in late fall with increased precipitation was observed as expected. Although the Eh data indicate that the soils were anaerobic and iron reduction was occurring, the data show the DO levels were seldom below the 1.5 mg/L value found in other anaerobic Willamette Valley soils (Austin, 1997). However, Cogger and Kennedy (1992) found that soils with DO levels less than 5 mg/L for greater than 80% of the time in the wet season had low redox potentials in Puget Lowland soils of western Washington. The average dissolved oxygen (DO) values were: 3.9 mg/L at the 20 cm depth, 2.3 mg/L at the 35 cm depth, 4.6 mg/L at the 75 cm depth, and 3.4 mg/L in the 100 cm well. Some of the DO data from 75 cm may seem to contradict conditions inferred from the Eh data The highest DO values occurred Figure 3.7. Groundwater dissolved oxygen values (bottom) from piezometric water and electrode potentials (top) at Site 2. 700600500- 4003O0 .7) .? 200 rg 100 -12 -10 , 0 fi . -ss", . ,......, ,:. . ......... 1 P. 1; ^ _. . \Jr/0k_ ri PM ra ;a !AI PA 61 ,...... - ,,,.. . Ir. 7 8 6 4 -2 J111111111111111111111111111111111111111111111111111111111111111111111 L0 ONDJ FM AM JOND J FM AMJ 1995 -1997 Eh 10 cm 0 Eh 30 cm Eh 50 cm DO 20 cm --v-- DO 35 cm DO 75 cm 67 mostly at the 75 cm depth, which might be expected because both organic matter and microbial activity decrease with depth. But redox potentials indicate that reduction was more intense with depth at Site 2, which is partly attributed to sufficient levels of organic matter content (1.2%) However, it must be noted that Eh measurements are taken at 50 cm versus 75 cm for the DO values. . In addition, higher than expected values of dissolved oxygen at all measured depths are believed to be attributed to 02 introduced into the piezometers when the DO readings were taken. It is surmised that the recharged water in the piezometers was not deep enough in most cases to offset the diffusion of air from the air-water interface and that 02 was introduced as the probe was moved up and down. Saturation and Eh The duration of saturation data and Eh data (Fig. 3.6) indicate there was a one to two-week initial lag period between saturation and reducing conditions. The onset of extended anaerobic conditions occurred within one week of saturation at all three depths in the first field season and within two weeks of saturation at 30 cm and 50 cm and within five weeks at 10 cm in the second field season. In the spring, Eh values at 30 cm and 50 cm were not significantly affected by brief periods of unsaturated conditions, as were the Eh values at 10 cm. The low response is attributed to a biological activity flush as temperatures rose. Consumption of 02 and production of CO2 by microbes would exceed diffusion rates of 02 into the soils and diffusion of CO2 out of the soils at deeper depths. It is also plausible that the low response may indicate that the macropores are drained but the micropores are not. 68 Soil Temperature Soil temperature (Fig. 3.8) remained above 5°C except on two occasions during the first field season. The first drop below 5°C was in December at the 10 cm depth. The second drop occurred at the 10 cm and 30 cm depths in February. Neither occurred during the recognized growing season for the valley. No drops occurred below 5°C at 50 cm below the soil surface. Eh values and soil temperatures (Fig. 3.9) of the saturated soils were well correlated at some times and were not well correlated at others. In general, the initial seasonal decrease in soil temperature had no effect on Eh values. Eh values continued to decrease with the onset of saturation in the early winter. In mid winter and late winter, decreases in temperature correlated with slight increases in Eh values at 10 cm but had no effect on the Eh values at 30 cm beneath the soil surface. The increase in soil temperatures in spring increased biological activity, causing the Eh values to decrease at the 30 cm and 50 cm depths. Site Summary The soils of this site exceeded the thresholds for continuous saturation with anaerobic conditions in the upper 30 cm during the portion of the year when soil temperatures are above 5°C (41°F) at 50 cm and meet the hydric soil definition. Continuous saturation occurred for an average of 19.5 weeks and anaerobic conditions for an average of 26 weeks. Figure 3.8. Soil temperature data at 10 cm, 30 cm, and 50 cm depths at Site 2. -5 0ND J F M AM J ON D J FM A M 1995- 1997 Temp 10 cm v Temp 30 cm L Temp 50 cm Figure 3.9. Soil temperature data (bottom) and electrode potentials (top) at Site 2. 700 600500 400 1 300 0 .? 200- a) co E 100 .c '` o w Oboe ogN go 8og0 vo gm" 0 %438 ° .631ritmoM Xm wom m0 0 _11111111111111111111111111111111111111111111111111111111111111111111I J ONDJ FM A M JON D FM A M -20 g) 15 0 10 5 0 1995-1997 Eh 10 cm Temp 10 cm v Eh 30 cm Eh 50 cm Temp 30 cm Temp 50 cm 0 -1 71 Site 3 Saturation Piezometer and rainfall data are presented in Figure 3.10. Initial response to precipitation in the first field season was observed the second week of November in the 100 cm well. One week later the water table was observed in the 75 cm piezometers and within two weeks in the 35 cm and 20 cm piezometers. Like the soils at Site 2, water appeared at all measured depths the third week of November due to a high intensity rainfall event in the second field season. The piezometer data indicate two pressure potentials. The 20 cm and 35 cm piezometer data have a pressure head that is believed to indicate episaturation above the 2Bt clay horizon that starts at 42 cm beneath the soil surface. The well data (free water) correspond with the level of water indicated by the 20 cm and 35 cm piezometer pressure head potentials, which suggests that the piezometric data are giving true estimates of the piezometric surface. The 75 cm piezometer data that have a different pressure potential from the 20 and 30 cm piezometers could be indicating loss of pressure due to frictional resistance to movement of water in the clays as discussed for Site 2 or the pressure head of a regional ground water table. The piezometers would be located approximately 33 cm into the slowly permeable gray clay 2Bt horizon. Since all three 75 cm piezometers are showing lower pressure heads, it is unlikely that the piezometers are giving erratic readings or that macrovoids are draining the piezometers (which is believed to be occurring at Site 2). Water was noted one week earlier at 75 cm than at 20 and 35 cm the first field season. The data could indicate either a rising regional ground water table or localized vertical flow down shrinkage cracks. Subsurface bypass or pipeflow (turbulent flow) can give lower Figure 3.10. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Site 3. ° -20 C-) co co -60 -80 *21.74 cm -4 FM AM JOND OND 1995-1997 well 75 cm 35cm 0 FM AM 20 cm ppt 0 73 horizons a rapid response to rainfall (Atkinson, 1978; Whipkey and Kirkby, 1978). As noted in Chapter 2 and shown in Tables 2.2 and 2.3, the 2Bt gray clay horizon had very high COLE values (>0.09), LEP/clay ratio (>0.15) that indicates smectitic mineralogy, and pressure faces. All these characteristics indicate high shrink-swell clays. However, the surface horizons of soils at Sites 2 and 3 indicate only moderate (COLE values 0.03 to 0.06) shrink-swell ability while the subsurface horizons above the 2Bt clay horizon have a low (COLE values <0.03) shrink-swell class. Examination of the soil profile in July and again in September showed no evidence of large channels. The soil was saturated continuously within the upper 20 cm until the third week of March and between 20 cm and 30 cm through the first week of April in the first field season. The water table responded to the seasonal decrease in precipitation with episodic saturation from April through May. In the second field season, the soil was continuously saturated within the upper 20 cm until the end of March and between 20 cm and 30 cm to the first week of May. The second pressure head indicates water was at 75 cm from the initial response to the end of May in the first field season and from initial response to the third week of May in the second field season. The mean perched water table for both field seasons was 9.7 cm below the soil surface from 11/28/95 to 5/24/96 and 9.8 cm from 11/21/96 to 5/03/97. The mean for the second pressure head was 53.4 cm below the soil surface from 11/21/95 to 5/30/96 and 53.4 cm from 11/21/96 to 5/10/97. Anaerobiosis and Iron Reduction Reduction-oxidation potentials (Eh) are presented in Figure 3.11. Conditions fluctuated between aerobic and anaerobic conditions, as indicated by potentials above and below +350 mV, at all depths the Figure 3.11. Electrode potentials (top) at 10 cm, 30 cm, and 50 cm depths and duration of saturation as measured by piezometers (bottom) at Site 3. 700 600 500 400 17; 300 3) 200 100 Duration of Saturation 20 cm 35 cm 75 cm JIII ONDJ FM AM JOND J FM AMJ I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1995 1997 I I I I I I I I I 1 I I I I I I I I I I I I I I I I I I I 75 first month of the wet season. The onset of extended anaerobiosis began the third week of November at all three depths the first field season. In the second field season, anaerobiosis again began the third week of November at 50 cm and the last week of November at the 10 and 30 cm depths. The Eh values indicate a different reducing environment than exists in the soil at Site 2, particularly at the 10 cm and 50 cm depths. Redox potentials were much lower and iron reduction continuous at the 10 cm depth but potentials were higher at the 50 cm, which is the reverse of reduction in the soils of Site 2. Differences in Eh values and reducing conditions between the soils of Site 3 and the soils of Site 2 at the 10 cm and 50 cm depths are attributed to two factors. Site 3 soils at 10 cm have longer reduction periods and more intense reducing conditions (lower Eh) due to a higher mean seasonal water table (9.8 cm versus 12.6 cm). Site 2 soils at 50 cm have longer reduction periods and more reduced conditions due to higher organic matter content (1.2% versus 0.7%). Overall, reducing conditions at Site 3 were less intense in the second field season than in the first. Iron reduction at 10 cm below the soil surface occurred mainly from 11/28/95 to 5/24/96 in the first field season and mainly from 12/05/96 to 5/03/97 in the second field season. Reduction at 30 cm beneath the soil surface occurred from 12/05/95 to 5/30/96 in the first field season and from 11/27/96 to 5/16/97 in the second field season. Reduction at 50 cm occurred from 12/05/95 to 5/30/96 in the first field season and from 12/05/96 to 5/16/97 in the second field season. The average dissolved oxygen (DO) values (Fig. 3.12) at the 20 cm and 35 cm depths was 2.4 mg/L for the two wet seasons. The average DO value in the 75 cm piezometer was 6.9 mg/L and the average DO in the 100 cm well was 3.4 mg/L. The DO values were Figure 3.12. Groundwater dissolved oxygen values (bottom) from piezometric water and electrode potentials (top) at Site 3. 3 E 700 600 500 400 300 200 100 12 10 w rs 11 I ez r:s r -, " " zi" 113 ar s V IQ -8 r.4 t.-T, IQ IQ 6 4 -2 _JI11111111111111111111111111111111111111111111111111111111111111111111 LO OND FM AM JOND JFM AMJ 1995 -1997 Eh 10 cm Eh 30 cm e DO 20 cm DO 35 cm Eh 50 cm 0 DO 75 cm 77 lower at the 20 cm depth compared to the Site 2 values due to higher water columns in the piezometers. The higher DO values at the 75 cm depth compared to Site 2 values were due partly to lower levels of microbial activity as confirmed by the higher redox potentials at 50 cm. The higher values also were due partly to the diffusion of oxygen from the air-water interface in the piezometers as discussed in the section on soils of Site 2. Saturation and Eh The duration of saturation data and Eh data (Fig. 3.11) indicate the onset of anaerobic conditions occurred one week prior to continuous saturation at all three depths in the first field season. The loss of dissolved oxygen was probably due to a combined heavy rain event and microbial flush. Onset of anaerobic conditions occurred within one week of saturation at all three depths during the second field season. Brief periods of unsaturated conditions in the spring did not significantly affect Eh values at 30 cm but had a slightly greater effect on the Eh values at the 10 cm depth. The low responses, like those at Site 2, are attributed to biological activity flush as temperatures rise. Soil temperature Soil temperatures (Fig. 3.13) in the first field season paralleled the soil temperatures at Site 2 except the two episodes below 5°C were a few degrees lower than at Site 2. The second field season temperature data show a drop below 5°C in December and again in January at the 10 cm depth. The temperature did not drop below 5°C at 50 cm. Figure 3.13. Soil temperature data at 10 cm, 30 cm, and 50 cm depths at Site 3. 30 0 o p MZ -- e Alb v Ell kV/ 1111 mmum 41,m V cp 0 V 0 0 ONDJ FM AM JOND J FM AM 1995 - 1997 0 Temp 10 cm Temp 30 cm o Temp 50 cm 79 Soil temperatures and Eh values (Fig. 3.14) of the saturated soils were not well correlated. Like the soils of Site 2, the initial seasonal decrease in soil temperature had no effect on Eh values, and Eh values continued to decrease with the onset of saturation in the early winter. In mid winter and late winter, some drops in temperature were associated with very slight increases in Eh at all depths and other drops seemed to be unrelated to Eh. The increase in soil temperatures in early spring increased biological activity and affected Eh values to varying degrees. The 10 cm Eh values decreased the most, the 30 cm Eh values were slightly affected, and the 50 cm Eh values showed no response. Site Summary The soils of this site exceeded the thresholds for continuous saturation with anaerobic conditions in the upper 30 cm during the portion of the year when soil temperatures are above 5°C (41°F) at 50 cm and meet the hydric soil definition. Continuous saturation occurred for an average of 21.5 weeks and anaerobic conditions for an average of 26 weeks. Site 4 Saturation Piezotneter and rainfall data are presented in Figure 3.15. Initial response to precipitation in the first field season was observed the second week of November in the 100 cm well and the 50 cm piezometer. Two weeks later water was observed in the 25 cm piezometer and the 100 cm piezometers. The second field season had a similar pattern of wetting as the first. Water was first observed in Figure 3.14. Soil temperature data (bottom) and electrode potentials (top) at Site 3. 700 600 500 400 3 300 0 .? 200 a) 5 100 -20 0 mm w 15 S%® 00 rn a) 0 Mm ° rR" RiOw EM* o t1 op O 2 Rieu V* no 10 'Iii)414WIT°(1"181-InMi 5 0 ONDJ FM AM JOND 1995-1997 Eh 10 cm 0 Temp 10 cm " J FM AMJ Eh 30 cm Eh 50 cm Temp 30 cm Temp 50 cm 00 Figure 3.15. Precipitation data (bottom) and water table data (top) below the soil surfaceas observed in a well at 100 cm and piezometers at 100 cm, 50 cm, and 25 cm depths at Site 4. 0 , Era = = a) ots .21), -20 C.) -40 o -60 co -80 0 _a -100 X "21.74 cm -o co a) _c co= U) a) L. a. M AM JOND ON D 1995-1997 well o 100 cm v 50 cm o FM AM 25 cm ppt 82 the 100 cm well and the 50 cm piezorneter the second week of November; one week later in the 25 cm; and in the 100 cm piezometer the last week of November. The hydrology of this soil is different than at the other sites. Water in the 100 cm well indicated that saturated conditions existed somewhere within 100 cm of the soil surface. However, the wetting pattern was not from the bottom up from a rising water table as evidenced by the lack of water in the 100 cm piezometer when the 50 cm piezometer had water. Saturation was not occurring from the surface down as evidenced by lack of water in the 25 cm piezometer. The data suggest the initial wetting of this soil occurred from 50 cm upward. Two physical soil factors could account for this pattern of wetting. Soil physical characteristic data from Chapter 2 (Table 2.3) showed the Bt clay horizon between 51cm and 90 cm had a slightly lower fine clay to total clay ratio and a lower COLE index than the overlying clay horizons, which would imply a discontinuity. The lower COLE index (0.075) compared to the overlying horizon (0.105) indicates this horizon has less shrink-swell capacity, therefore, less propensity toward cracking. These two factors, along with the piezometer data, suggest that rain water could be flowing down along ped faces and macro cracks (bypass flow or pipeflow) formed by the drying of the shrink-swell soils during the summer months. The water slows and forms a perched water table at the Bt horizon as indicated by water in the 50 cm piezometer when no water is in the 100 cm piezometer. Like Site 2, one of the triplicate 75 cm piezometers gave erratic readings that were not consistent with the other two piezometers. Compared to Fig. 3.15 where all three 75 cm piezometer data are 83 averaged, the errant piezometer data are graphed separately in Fig. 3.16. Pressure heads from the other two 75 cm piezometers correspond to the pressure heads given by the 25 cm and 50 cm piezometers. Water appeared in the divergent (#1) piezometer at least two weeks later than the other two piezometers in both field seasons. In addition, this piezometer indicated a large difference in average pressure potentials for the two field seasons, 57.8 cm in the first field season compared to 38.3 cm in the second field season. This divergent piezometer may be positioned in a macrovoid of some type that affects the hydraulic head, or the piezometer may be partially clogged. The data from the 25 cm, 50 cm, and two of the 75 cm piezometers, along with the well data, suggest that the pattern of wetting occurred both upward and downward from a perched water table at 50 cm below the soil surface. Within two weeks, either the wetting front had reached the 100 cm depth or the ground water had risen to meet the perched water table. Continuous saturation was observed within the upper 30 cm from the last week of November through the first week of May in the first field season and from the third week of November through the first week of May in the second field season. The mean water table for both field seasons was 5.5 cm below the soil surface from 11/28/95 to 5/30/96 and 5.5 cm from 11/27/96 to 6/01/97. Anaerobiosis and Iron Reduction Reduction-oxidation potentials (Eh) are presented in Figure 3.17. The onset of anaerobic conditions began the second week of November at the 50 and 100 cm depths and the third week of November at 25 cm in the second field season. Reducing conditions differed in the soils of this site compared to the soils at the other sites. Figure 3.16. Water table data (top) below the soil surface with the errant 75 cm piezometer graphed separately at Site 4. 0 "Sligreit.:AA, E 9-a) r NV -20 p. ra tcu 0 3 0 -40 112 Wol -uu -80- TD -Q -100 `21.74 cm ca a) a) T co co o_ 0 nil! r""' '1iirirtii1i1i1IIIIIITI1I r: NDJFM AMJONDJFM A 1995 1997 well 100 cm 50 cm 25 cm 1 II IT III ppt MJ Figure 3.17. Electrode potentials (top) at 25 cm, 50 cm, and 100 cm depths and duration of saturation as measured by piezometers (bottom) at Site 4. 700 600 500 400 IT') 300 3) 200 100 w Duration of Saturation 25cm 50cm 100 cm ONDJ FM AM JOND J FM AMJ 1995-1997 Eh 25 cm Eh 50 cm Eh 100 cm 86 The overall Eh values at the 25 cm depth indicate stronger (lower Eh) reducing conditions at this depth than exist in the other soils. Iron reduction occurred concurrently with anaerobiosis at 25 cm, within one week at 50 cm, and within three weeks at 100 cm in the first field season. Reduction occurred at 25 cm from 11/14/95 to 6/14/96; at 50 cm from 11/21/95 to 5/30/96; and at 100 cm from 12/19/95 to 5/30/96. Reduction in the second field season occurred at 25 cm from 11/27/96 to 6/1/97; at 50 cm from 12/05/96 to 6/01/97; and at 100 cm from 3/22/97 to 6/1/97. The dissolved oxygen (DO) values (Fig. 3.18) were very erratic and difficult to correlate with Eh values in the first field season. However, a pattern emerged in the second field season. Average DO values of 1.8 mg/L at the 25 cm and 50 cm depths correlated well with the Eh data. The average DO value for the 100 cm piezometer was 5.0 mg/L while the average value for the 100 cm well was 3.0 mg/L. Saturation and Eh The duration of saturation data (Fig. 3.17) indicate there was no initial lag period between saturation and reducing conditions for either field season. Anaerobic conditions occurred concurrently with saturation at all three depths the first field season. In the second field season, anaerobiosis occurred one week before saturation at the 50 and 100 cm depths and concurrently with saturation at 25 cm. Once saturated, the soils were continuously saturated and reduced at the 25 and 50 cm depths except for a brief episode at the 25 cm depth. Soil temperature Soil temperatures (Fig. 3.19) remained above 5°C except for one occasion at the 25 cm depth in February of the first field season and Figure 3.18. Groundwater dissolved oxygen values (bottom) from piezometric water and electrode potentials (top) at Site 4. OND J F M AM JOND FM 1995 -1997 Eh 25 cm Eh 35 cm Eh 100 cm DO 25 cm v DO 50 cm DO 100 cm AM J Figure 3.19. Soil temperature data at 25 cm, 50 cm, and 100 cm depths at Site 4. 30 ^25 0 220 20 rn a) o 0 v9v 13-1510 a) E 5 a) u) 0 0 _5 OND J FM AM JOND J FM AM 1995-1997 0 Temp 25 cm v Temp 50 cm o Temp 100 cm 89 one occasion at the 25 cm depth in December during the second field season. Correlation between soil temperatures and Eh values (Fig. 3.20) of the saturated soils shows that the initial seasonal decrease in soil temperature had an effect on the rate and intensity of the onset of reducing conditions. Slightly higher soil temperatures in the first field season led to a sharper decline in Eh values and a more intense reducing environment than in the second field season. In mid-winter and late winter, major drops in temperature caused very slight increases in Eh at all depths. Increase in soil temperatures in early spring increased biological activity and affected Eh values differently in the two field seasons. Eh values in the first field season show little response to the increase in soil temperatures. The Eh values in the second field season showed a distinct inverse relationship, with Eh values decreasing as soil temperatures increased at all measured depths. Site Summary The soils of this site exceeded the thresholds for continuous saturation with anaerobic conditions in the upper 30 cm during the portion of the year when soil temperatures are above 5°C (41°F) at 50 cm and meet the hydric soil definition. Continuous saturation occurred for an average of 24 weeks and anaerobic conditions for an average of 29 weeks. Plots A - F Additional data on the hillslope hydrology were provided by piezometers spaced between the four main sites. These data are presented in Figures 3.21 through 3.26. Figure 3.20. Soil temperature data (bottom) and electrode potentials (top) at Site 4. 700 600 500400 3 300200100 _c 'Mn Npo, vGimme 0.0.00y 0 73av°,7 0 _ .MI;49[imm 0 0 ONDJ FM A M I I I I I I I I I I I -20 -15 -10 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I JON D Eh 50 cm Temp 25 cm Temp 50 cm I J 1995-1997 Eh 25 cm -5 0 I I I I I I I I I I I I I I I I FM A M Eh 100 cm ° I Temp 100 cm I I I J I -0 0 91 Saturation Plot A (located 24.5 m upslope from Site 1) piezometric data (Fig. 3.21) show very similar hydrology as Site 1. The soils are somewhat dryer than Site 1 soils as indicated by the lack of free water at any time in the 20 cm piezometer. Saturation within the upper 30 cm occurred for episodes that lasted less than two weeks. Plot B (located 6.3 m downslope from Site 1) piezometric data (Fig. 3.22) show a strong contrast from Site 1 data. Saturation occurs high in the profile for extended periods. Water was observed in the 75 cm piezometer from the last week in November through the third week of March in the first field season and from the third week in November to the first week of April in the second field season. The soil was saturated continuously within the upper 30 cm for two weeks (from the first week of December to the third week of December) and for five weeks (from the first week of January to the second week of February) in the first field season. During the second field season, the soil within the upper 30 cm was saturated continuously for four different episodes that lasted two to four weeks. The average water table was 16.8 cm beneath the soil surface from 11/28/95 to 3/8/96 and 19.1 cm from 11/21/96 to 3/22/97. The water table observed at Plot B could be indicative of episaturation caused by water perching over the restrictive clay horizons that start at approximately 72 cm below the soil surface at this site. The well data cannot be used to indicate rising water from the 100 cm depth since open construction would allow water to drain into the well at the restrictive boundary. Water initially occurred in the 35 cm and 75 cm on the same date, which indicates that water levels are being influenced by the slowly permeable gray clay horizon. Perching water would account for the significant change in hydrology over a short 6.3 m distance between Site 1 and Plot B. Figure 3.21. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot A. g V 0 -20 `t -40 = -60 cp 0 -80 T s) -100 -16 *21.74 cm V -12 co a) _c 7-3 -8 ED_ co a) Q. 0N F D M Ar M JON D FM A M 1995 1997 well a 75 cm 35cm 20 cm ppt Figure 3.22. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot B. 0 -20 `t -40 =0 -60 (1 -80 16 >< _ca -100 *21.74 cm as 12 a) _a -8 ED_ U) -4 a) ON D FM AM JON D 1995 - 1997 well C3 75 cm 35cm o J FM AMJ 20 cm ppt 0 94 Plot C (located 5.3 m downslope from Plot B and 5.8 m upslope from Site 2) piezometric data (Fig. 3.23) are very similar to Site 2 data but with shorter duration of saturation. Continuous saturation was observed within the upper 30 cm from the last week of November to the third week of March in the first field season and from the third week of November through the third week of March in the second field season. The water table is believed to be indicative of episaturation, like that of Plot B. The 2Bt clay horizon of this plot starts at approximately 81 cm below the soil surface. The average water table was 12.2 cm beneath the soil surface from 11/28/95 to 5/24/96 and 14.6 cm from 11/21/96 to 5/03/97. Plot D (located 11 m downslope from Site 2) piezometric data (Fig. 3.24) are very similar to Site 3 data. The piezometric data indicate two pressure heads. Water was first observed in the 75 cm piezometer the second week of November and at the 35 cm and 20 cm piezometers two weeks later. The 2Bt clay horizon started at approximately 42 cm beneath the soil surface at this plot creating episaturation higher in the soil profile than at Plots B and C. This 75 cm piezometer embedded over 30 cm into the clay horizons could, like the 75 cm piezometers of Site 3, be indicating loss of pressure due to frictional resistance to movement of water in the clays or the pressure head of a rising groundwater table. The soil was saturated continuously within the upper 30 cm from the last week of November to the first week of April in the first field season and from the third week of November to the first week of May in the second field season. The average perched water table was 7.8 cm below the soil surface from 11/28/95 to 5/24/96 and 9.1 cm from 11/21/96 through 5/03/97. This second pressure head was 59.1cm and 67.3 cm beneath the soil surface in the first and second field season, respectively. Figure 3.23. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot C. ° -20 c.) -60 U) -80 0 .o -100 *21.74 cm ci ON D liiiii J FM AM J ON D 1995 - 1997 well 75 cm 35cm 0 FM AM 11 J 20 cm ppt Figure 3.24. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot D. 0 t -20 C.) -40 co o -60 -80 *21.74 cm ON D J r-ir'1-'111Irl--lir-'1--F M AM J ON D J F M A M rJ 1995 1997 well 75 cm 35cm o 20 cm ppt 97 Plot E (located 9.7 m downslope from Plot D and 10.2 m upslope from Site 3) piezometric data (Fig. 3.25) also were very similar to Site 3 data except for lack of a second pressure head. The 2Bt clay horizon started at approximately 61 cm beneath the soil surface at this plot. Given soil variability, the clay horizons may start well below 61 cm, and the 75 cm piezometer may not be far enough into the clay to affect the hydraulic head. The soil was saturated continuously within the upper 30 cm from the last week of November to the first week of April in the first field season and from the third week of November to the first week of April in the second field season. The average water table was 8.1 cm beneath the soil surface from 11/28/95 to 5/24/96 in the first field season and 9.2 cm from 11/21/96 to 5/03/97 in the second field season. Plot F (located 3.2 meters downslope from Site 3 and 36 meters upslope from Site 4) piezometric data (Fig. 3.26) indicate hydrology similar to that of Plot E and Site 3. Like Plot E data, there was no indication of a second pressure head. The 2Bt clay horizon began at 72 cm, which indicates the 75 cm piezometer has the pressure head of the perched water table as does the 35 cm and 20 cm piezometers. Continuous saturation occurred within the upper 30 cm from the last week of November through the first week of March in the first field season and from the third week of November to the end of March in the second field season. The average water table was 14.3 cm beneath the soil surface from 11/28/95 to 5/24/96 in the first field season and 13.9 cm from 11/21/95 to 5/03/97 in the second field season. The higher average water table at Plot E (14.1 cm) compared to Site 3 (9.7 cm) is to due anthropogenic disturbance. An elevated gravel road was constructed with fill between Site 3 and Plot F. Water from subsurface lateral flow from upslope is impeded by the Figure 3.25. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot E. C) U -20 -40 co = -60 U) 0 -80 16 R. ..c) -100 12 CO as a) 8 4 0 0N D M AM 0 JON D 1995 1997 75 cm 35cm 0 20 cm ppt Figure 3.26. Precipitation data (bottom) and water table data (top) below the soil surface as observed in a well at 100 cm and piezometers at 75 cm, 35 cm, and 20 cm depths at Plot F. 0 U a) -20 t -40 c/9 =0 -60 co -80 Tv _o -100 *21.74 cm CO a) a) co a) OND AM JFM AMJ J 1995 - 1997 well o 75 cm 35cm o 20 cm ppt 100 obstruction, breaks out, and becomes surface flow along the lower section of the road. Summary for All Sites and Plots Periods of continuous saturation within the upper 30 cm, seasonal mean water table levels, onset of anaerobiosis, and periods of Fe reduction for the four pedons of the study area are summarized in Table 3.1. Soil temperature as related to growing season is not considered a factor in determining whether the four sites have hydric soils, since the soil temperature never went below 5°C at 50 cm beneath the soil surface. Continuous saturated conditions were not found at Site 1 but varied from 19 to 25 weeks at Sites 2, 3, and 4. Duration of continuous saturation averaged 19.5 weeks at Site 2, 21.5 weeks at Site 3, and 24 weeks at Site 4. Seasonal mean water tables ranged from 12.6 cm at Site 2 to 5.5 cm at Site 4. Anaerobic conditions provided in Table 3.1 occur within 30 cm of the soil surface. For Sites 3 and 4, this could be synonymous with "in the upper 30 cm" as the 10 cm data showed the same reducing environment. Site 2 data at the 10 cm depth showed a different reducing environment than at 30 cm. Anaerobiosis occurred for four to five months at the 10 cm depth but iron reduction was sporadic and very brief. It is assumed that around 13 cm, where the mean seasonal water table level occurs, the environment is more like the reducing environment expressed by the 30 cm redox potentials. Data show the onset of anaerobiosis began anywhere from two weeks before continuous saturation to two weeks after and continued for up to ten weeks past the end of continuous saturation. Extensive periods of iron reduction lagged behind conditions of continuous Table 3.1. Periods of continuous saturation within the upper 30 cm, seasonal mean water table levels, and periods of oxygen and iron reduction for the four pedons of the study area. Hydrologic Data Seasonal Mean Water Table Levels Site Continous Saturation within the Upper 30 cm Site 1 less than two weeks Site 2 Site 3 Site 4 Main Periods of Anaerobic Conditions at 25-30 cm Onset of Anaerobiosis Iron Reduction not applicable one week period none 11/28/95 4/04/96 11/21/96 4/05/97 12.5 cm 12.7 cm 12/05/95 12/05/96 12/19/95 - 5/30/96 11/28/95 4/04/96 11/21/96 5/03/97 9.7 cm 9.8 cm 11/21/95 11/27/96 12/05/95 5/30/96 11/28/95 - 5/04/96 11/21/96 - 5/10/97 5.5 cm 5.5 cm 11/14/95 11/21/96 12/19/95 5/16/97 11/27/95 - 5/16/97 11/14/95 6/14/96 11/27/96 - 6/01/97 102 saturation for three to four weeks in Site 2 soils, one week in Site 3 soils, and one week or less in Site 4 soils. Duration of anaerobic conditions ranged from an average of 26 weeks at Site 2, 26 weeks at Site 3, and 29 weeks at Site 4. Table 3.2 summarizes the hydrologic data for the six additional plots (Plots A-F). The additional hydrologic data provided by the piezometers placed between the four main sites indicate that the boundary for non-hydric soils and hydric soils is probably between Site 1 and Plot B or at Plot B. Site 1 soils had a few episodes of saturation that lasted less than two weeks compared to Plot B soils that had several episodes that lasted two to five weeks. Plot B had an average seasonal water table at 17 cm. Perching water could account for the significant change in hydrology over the short 6.3 m distance between Site 1 and Plot B. This hydric soil boundary would correlate with the hillslope morphology, since the two clay layers on the upper transect were found to taper to an end where a slight break in slope is evident below Site #1. Conclusion The summarized hydrologic and reductive data provide evidence that the soils of Sites 2, 3, and 4 meet the conditions for "saturated, flooded, or ponded long enough during the growing season to develop anaerobic conditions in the upper part" and are hydric soils according to the hydric soil definition. The hydrologic data indicate that the initial precipitation in late fall and early winter replaced soil moisture content lost to dry summers. Once field capacity was reached through frequent small rain events or through major high intensity and/or long duration rain events, further precipitation led to perched water tables and 103 Table 3.2. Periods of continuous saturation within the upper 30 cm and seasonal mean water table levels for plots between Sites 1-4. Hydrologic Data Plots Continous Saturation within the Upper 30 cm Seasonal Mean Water Table Levels Plot A less than 1 week not applicable Plot B 12/05/95 - 12/19/95 1/02/96 - 2/09/96 4 episodes at 2-4 weeks (96-97) 16.8 19.1 Plot C 11/28/95 3/23/96 11/21/96 3/22/97 12.2 14.6 Plot D 11/28/95 4/04/96 11/21/96 5/03/97 7.8 9.1 Plot E 11/28/95 4/04/96 11/21/96 - 4/05/97 8.1 9.2 11/28/95 - 3/08/96 11/21/96 - 3/30/97 14.3 13.9 Plot F 104 episaturation. Episaturation occurred at Sites 2 and 3 and Plots B-F with temporary episaturation occurring at Site 4. Water levels fluctuated with rain events, but water tables remained fairly stable and soil stayed saturated high in the soil profiles for a majority of the wet season (October June). The reduction-oxidation potentials support the occurrence of varying reducing environments at Sites 2, 3, and 4. The onset of anaerobiosis began less than two weeks after continuous saturation at these sites. Generally, iron reduction occurred between one and four weeks after continuous saturation began and lasted two to eight weeks after continuous saturation ended. The onset of significant periods of iron reduction correlated with average saturation levels. Soils at Site 2 with the lowest mean water table level (12.6 cm) had the longest lag time between saturation and iron reduction versus Site 4 soils with the highest mean water table (5.5 cm) where iron reduction occurred simultaneous with saturation. In addition, the hydrologic data and redox data correlated with the morphological properties noted in Chapter 2 for each of the four pedons. Short episodic saturation events in Site 1 soils that averaged around 16 cm beneath the soil surface correspond to the occurrence of fine iron concretions. The mean water table levels for Sites 2 and 3 corresponded to horizons that had at least 30% high value and low chroma (4/2) matrix colors and many distinct iron masses. Nearsurface saturation in the soils of Site 4 is associated with the presence of oxidized rhizospheres found at the surface and many distinct iron masses at 6 cm beneath the soil surface. 105 Chapter 4 FIELD INDICATORS OF HYDRIC SOILS - APPLICATION TO THE WITHAM HILL BACKSLOPE-FOOTSLOPE STUDY SITE Introduction The publication, Field Indicators of Hydric Soils in the United States (US Department of Agriculture, Natural Resources Conservation Service, 1996) is designed as a guide to help identify hydric soils in the field based on soil morphology. The purpose of the indicators is to provide a field method for identifying soils that meet the hydric soil definition without the need for further data collection. The indicators are based on the concept that hydric soils exhibit morphological evidence of long-term hydrologic and redox conditions. Indicators are classified according to texture classes and further defined by geographic location. The indicators were designed to be region specific to adapt to regional variations in hydric characteristics. A soil in question can be classified as hydric when one positive hydric soil indicator is found. However, the lack of an indicator does not exclude the soil from being hydric. The availability of field indicators for identification of hydric soils is a recent development with the first version being drafted and accepted for use in 1995. The current list is but a beginning; changes and additions are anticipated as the indicators are field-tested and more field data are collected. The development of field indicators to characterize all hydric soils requires understanding of processes and interactions in soils and the conditions that fuel them. The Interagency Field Indicator Committee welcomes recommendations and supporting documentation from anyone involved with research on wet soils. The committee defines supporting documentation as soil 106 pedon descriptions, water table data, duration of saturation data, redox potential measurements, a, a' dipyridyl test results, and vegetative data (US Department of Agriculture, Natural Resources Conservation Service, 1996). The purpose of this chapter is to apply the current indicators (Ver. 3.2, July 1996) to the study site soils. One objective is to determine if the soils can be considered hydric based on their morphologies and the morphological requirements of current indicators. Another goal is to examine and evaluate the indicator's capability to identify those soils at the study area that met the hydric soil definition and provide recommendations based on the results. Background Indicators are based on soil morphological properties that are formed by the accumulation or loss of iron, manganese, sulfur, and organic carbon (US Department of Agriculture, Natural Resources Conservation Service, 1996). The most commonly used morphological parameters in the indicators are soil color and soil color patterns. Soil color and color patterns are mainly related to the oxidation state of Fe compounds and the accumulation or depletion of Fe and Mn as previously discussed in Chapter 2. Indicators and interpretations of morphological characteristics are based on the prevailing idea that soils with seasonally high water tables have areas of redoximorphic concentrations and gray or low chroma (< 2) matrix colors or depletions in the zone of fluctuation. The assumptions are based on many studies that have documented the relationships and correlation between morphological features and saturation (Boersma et al., 1972; Veneman et al., 1976; Vepraskas and Wilding, 1983; Franzmeier et al., 1983; Evans and Franzmeirer, 107 1986; Schwertmann and Taylor, 1989; Mausbach and Richatdson, 1994; Cogger and Kennedy, 1992). Numerous studies, however, have found soils where seasonally high water tables and low-chroma colors are not always well correlated. Evans and Franzmeier (1986) reported seasonally saturated soils with three or four chroma colors. Daniels et al. (1971) found 3-chroma redox features in horizons that were saturated 25% of the time. Vepraskas et al. (1974) found 5_2 chromas lacking in some seasonally saturated soils with perched water tables. Franzmeier et al. (1983) noted that some soils with periodic high water tables had 3 chromas. Vepraskas and Wilding (1983) found that soils with a seasonally perched water table on backslope and toeslope positions had color chromas along ped faces. The Field Indicator Committee recognizes that all hydric soils do not show the characteristic morphologies on which the indicators are based. Studies have documented cases were saturation has not resulted in characteristic redoximorphic features. Bouma (1973) described soils that had perched water tables for several months but lacked redox features. Austin (1994) found in some Willamette Valley soils that had saturation for durations less than 10% of the wet season did not have redoximorphic features. Some factors known to affect the development or visibility of characteristic morphologies are: parent materials that are reddish (high amounts of Fe) or grayish (low amounts of Fe); dark soils; soils with high pH or low organic matter content; low soil temperatures; and aerated groundwater. Other factors less studied but known to affect morphological characteristics are isomorphous substitution of Al for Fe in Fe oxides (Norrish and Taylor, 1961; Barron and Torrent, 1984) and absorption of phosphorus by Fe oxides (Willet and Cunningham, 1983). 108 Methods Evaluation of field indicators was deferred until the soil morphology of each site was documented in complete profile descriptions. The goal was to prevent any bias in determinations. The field indicator guide was then applied to the soil profile descriptions of each site. The Field Indicator Committee recognizes the occurrence of soil colors between the Munsell chips. The procedure for specifying soil color requires that a chroma between 2 and 3 (as an example) should be listed as 2+. A chroma of 2+ can not be rounded and would not meet an indicator that requires a chroma of 2 or less (US Department of Agriculture, Natural Resources Conservation Service, 1996). The field indicators for "all soils" (A), for "loamy and clayey soils" (F), and test indicators (T) were used. All indicators in these four sections (F, A, TA, TF) that were designated for use in the publication's "A" Land Resource Region (LRR) were considered. Results and Discussion All applicable indicators are given in Table 4.1 along with the specific requirements of each indicator. The table also shows whether the soils at each site met an indicator's requirements. If a soil did not meet the requirements but came close to doing so, "deficiencies" in the soil's morphology were noted. Although all applicable indicators were considered, only the indicators that came close to matching the morphology of the study site soils are discussed in detail. The F3 Depleted Matrix indicator requires a layer at least 15 cm thick starting within 25 cm of the soil surface that has a depleted matrix of chroma 2 in 60% of the layer. A depleted matrix, as outlined in the indicator's glossary, can range from a matrix value of 6 Table 4.1. Application of field indicators to the study area soils. INDICATORS REQUIREMENTS MEET CLOSE REASON FAILED mucky modified mineral layer > 10 cm starting within 15 cm None None no mucky mineral layer layer with > 60% gleyed matrix starting within 30 cm None None no gleyed matrix layer > 15 cm thick starting within 25 cm > 60% depleted matrix chroma < 2 None Site 2 matrix 3+/2 (versus 4/2) layer 13 cm thick 1) 4/2 layer 9 cm thick 2) layer 11 cm thick with LOAMY AND CLAYEY SOILS Fl Loamy Mucky Mineral F2 Loamy Gleyed Matrix F3 Depleted Matrix Site 3 30% 4/2+ F4 Depleted Below Dark Surface F5 Thick Dark Surface layer > 15 cm thick starting within 30 cm > 60% depleted matrix chroma < 2 layers above: < 3/2 None layer > 15 cm thick starting below 30 cm > 60% depleted matrix chroma < 2 layers above: hue N and value < 3 to 30 cm and < 3/1 in remainder of epipedon None Site 2 Site 3 None matrix 3+/2 layer 13 cm thick layers above: 3/2+ 1) 50% depleted matrix layer above 4/2 and 4/2+ no hue N epipedons Table 4.1, Continued. INDICATORS REQUIREMENTS MEET CLOSE layer > 10 cm thick entirely within 30 cm matrix < 3/1 and > 2% dist./prom. redox or matrix < 3/2 and > 5% redox Site 4 Site 2 matrix 3+/2 layer > 10 cm thick entirely within 30 cm with redox depletions of > 5/< 2 matrix < 3/1 and > 10% depletions or matrix < 3/2 and > 20% depletions None None no depletions layer > 5 cm thick entirely within upper 15 cm redox conc. > 5% distinct/prominent *Site 3 *Site 4 Site 2 faint redox conc. *meets requirements, but for use in closed depressions Al Histosols > 40 cm organic soil material layer in the upper 80 cm None None not histosols A2 > 20 cm thick surface horizon of organic soil material None None no histic epipedons F6 Redox Dark Surface F7 Depleted Dark Surface F8 Redox Depressions REASON FAILED ALL SOILS Histic epipedon Table 4.1, Continued. INDICATORS A3 Black Histic A4 Hydrogen Sulfide A10 Muck REQUIREMENTS MEET CLOSE layer > 20 cm of peat, mucky peat, muck starting within 15 cm hue > 10YR, < 3/1 None None not histic hydrogen sulfide odor within 30 cm None None no hydrogen sulfide odor layer > 2 cm thick of muck starting within 15 cm matrix < 3/1 None None no muck layer > 15 cm thick 60% depleted matrix < 2 chroma starting below 30 cm layers above: > 10YR, < 2.5 value to a depth of 30 cm and < 3/1 remainder of epipedon None None no layers with < 2.5 value above depleted matrix REASON FAILED TEST-LOAMY AND CLAYEY TF 7 Thick Dark Surface 2/1 112 or more and chroma 2 or less with or without redox concentrations to a matrix value of 4 and a chroma of 1 with 2% redox concentrations as soft masses and/or pore linings. Site 2 soils failed the indicator due to two slight deficiencies. The A3 horizon of Pit 2 soils had a matrix of 3+/2 and a layer thickness of 13 cm. Since colors cannot be rounded to meet an indicator's requirements, the A3 horizon matrix with a value of 3+ did not fall within the definition of a depleted matrix. In addition, the horizon was 2 cm short of the thickness requirement. Site 3 soils had two horizons whose morphologies were close to the specifications of the F3 indicator. The A2 horizon had a depleted matrix (4/2) but was only 9 cm thick. The 11 cm thick B/E horizon failed the thickness requirement. In addition, the horizon had a matrix color of 4/2+ that occupied only 30% of the horizon. The F4 indicator, Depleted Below Dark Surface, has similar requirements as the F3 indicator but starts within the upper 30 cm. An additional requirement that layers above the depleted matrix have values of 3 and chromas of 2 was included. The A2 horizon of Site 2 soils failed for the same reasons given above for the F3 indicator plus the overlying horizons of Pit 2 had a matrix color of 3/2+. The E/B horizon of Pit 3 failed this indicator due to a depleted matrix that had only a 50% matrix color of 5/2 and because overlying layers had matrix colors of 4/2 and 4/2+. The F6 indicator, Redox Dark Surface, requires a layer at least 10 cm thick that is entirely within 30 cm of the soil surface with a matrix color of 3/1 with ?_ 2% distinct/prominent redox concentrations or a matrix color of 3/2 with ?_ 5% distinct/ prominent redox concentrations. The soil of Site 4 had a positive result for this indicator. Both the A2 and BA soil horizons of Pit 4 met the requirements. The soil of Site 2 came very close to meeting the 113 requirements but failed because the A3 horizon had a matrix value of 3+. The F8 indicator, Redox Depressions, requires a layer at least 5 cm thick entirely within the upper 15 cm that has 5% distinct or prominent redox concentrations or pore linings. Site 2 soils failed because of faint redox concentrations but Site 3 and Site 4 soils met the requirements. However, this indicator's use is restricted to closed depressions subject to ponding and cannot be considered as a positive outcome for soils at Sites 3 and 4. Conclusion Site 2 and Site 3 soils did not comply with any of the fourteen designated hydric field indicators. Site 4 soils did meet the F6 indicator. The soils of Site 2 came closer to meeting the morphological requirements of some indicators than did the Site 3 soils, even though the soils of Site 3 had longer saturation and reduction. The soils of Site 3 had a slightly higher mean seasonal water table (9.8 cm vs. 12.6 cm), longer continuous duration of saturation (21.5 weeks vs. 19.5 weeks), lower average Eh values at 20 cm and 35 cm, and longer duration of iron reduction (24.5 weeks vs. 22 weeks) than Site 2 soils. The two main factors that prevented positive outcomes for Sites 2 and 3 soils were the inability to round colors that fell between color chips and layer thickness requirements. A third factor was the lack of at least 60% depleted matrix within a designated horizon. Site 2 soils came closer to meeting requirements of the F6 indicator than to any other indicator. Failure was due to a matrix of 3+/2 in the A3 horizon versus the required 3/2 matrix color. Site 2 soils also failed the F3 indicator due to a matrix of 3+/2 versus a required value of 4 and by being 2 cm too thin to meet the layer thickness requirement. 114 Soils of Site 3 came closer to meeting requirements of the F3 indicator than to any other indicator. There were two horizons of Site 3 soils that were considered for this indicator: (1) the A2 depleted matrix (4/2) layer that was 9 cm versus a required 15 cm thick; and (2) the E/B horizon that was 11cm thick and had a 30% depleted matrix (4/2+) versus a required 60% depleted matrix. The Witham Hill wet soil study site was visited in July 1997 by a group from the Wet Soils Monitoring Project, members of the National Technical Committee for Hydric Soils, and members of the Field Indicator Committee. Holes were dug, field indicators were applied, hydrologic and redox potential data were reviewed, and opinions liberally expressed. Two consensus were reached in the field that day. A majority felt that the matrix color of the A3 horizon at Site 2 was 3/2 versus the 3+/2 originally noted. This change would mean that the soils of Site 2 would meet the F6 indicator. A second consensus was that the soil morphology of Site 3 needed to be covered by an indicator, since the hydrologic and redox potential data did indicate that the soils of Site 3 were hydric. Version 4 of the Field Indicators of Hydric Soils in the United States (US Department of Agriculture, Natural Resources Conservation Service, 1998) was issued in March 1998 during the writing of this thesis. The new version has changed the way colors that fall between Munsell color chips are applied. Color values now can be rounded to the nearest color chip but chromas cannot. The change enables the A3 horizon at Site 2, with the debated 3+/2 matrix color, to meet the F6 indicator that required a _3/2 matrix. A second change in the new version that affects the study site soils is an addition to the F3 Depleted Matrix indicator. The addition allows the layer thickness requirement to be lowered from 15 cm to 5 cm if the depleted matrix is within the upper 15 cm of the mineral soil. 115 The A2 horizon of soils at Site 3 now meet the requirements to enable a positive response to this indicator. Based on soil morphology, hydrologic regime and reductionoxidation conditions of the soils at the study site, recommendations to the Field Indicator Committee would focus on layer thickness requirements, the handling of soil colors between color chips, and the 60% requirement for a depleted matrix. Thickness requirements, as noted by the change made to indicator F3 in the 1998 version, are reconsidered on an indicator by indicator basis. Guidelines based on soil color, a qualitative parameter whose description is affected by many factors, are going to have indefinite areas of interpretation. Identification of soil color in the field can vary not only with the quality of light and soil moisture but with personal assessment and unintentional bias. Although Munsell notations are decimal and could be refined to any desired degree (Kollmorgen Instruments Corporation, 1994), doing so on an individual basis in the field would increase the personal assessment error factor. Rounding of soil colors that fall between two color chips on the Munsell soil color charts is the normal practice of soil surveyors (Soil Survey Division Staff, 1993). Noting a (+/-) beside the chip number is an alternative if more precision is required. However, in light of the technical factors and the differences in personal assessment that exist in designating a chip color, exactness is not probable. Rounding to the nearest color chip seems a reasonable procedure that would allow for the variances of personal judgement without jeopardizing the indicator's validity. In fact, before the 1998 revision, the inability to round color values to the nearest color chip would have, in the assessment of the author (and that of several others), failed Site 2 soils from meeting the F6 indicator. For these reasons, further consideration should be given to rounding not only value but also chroma. 116 The B/E and E/B horizons of Pits 2 and 3 present a strong case for reviewing the requirement that a depleted matrix make up 60% of a horizon for many indicators. The B/E horizons ranged from 35% depleted matrix at Site 2 to 30% depleted matrix at Site 3 and the E/B horizons ranged from 60% depleted matrix at Site 2 to 50% depleted matrix at Site 3. Other factors besides duration of saturation and reduction need to be considered. There may be physical properties or chemical processes that result in no net loss of iron or that prevent removal of iron from a horizon while still having iron redistributed into areas of segregated high and low chroma colors. 117 Chapter 5 HYDROPHYTIC VEGETATION AND WETLANDS AT THE WITHAM HILL BACKSLOPE-FOOTSLOPE STUDY SITE Introduction The soils at Sites 2, 3, and 4 of the Witham Hill study area were concluded to be hydric soils in Chapter 3. The determinations were made in order to evaluate the field indicator's capability to identify those soils that met the hydric soil definition on a selected hillslope. However, the confirmation of the study site soils as hydric raises the possibility of a wide occurrence of hillslope hydric soils in the Willamette Valley and prompts the controversial question as to whether the study area could be a jurisdictional wetland. The objective of this chapter is to characterize the vegetation of the study site and to determine if the study site area could be a jurisdictional wetland according to federal regulations and current wetland identification procedures. Background There are two regulatory definitions of wetlands, the U.S. Army Corps of Engineers (USACE) 1977 definition, used by the USACE and the EPA, and the 1985 Food Security Act (FSA) definition, used by the Natural Resources Conservation Service. Wetlands are defined by the USACE as "those areas that are inundated or saturated by surface or groundwater at a frequency and duration sufficient to support, and that under normal circumstances do support, a prevalence of vegetation typically adapted for life in saturated soil conditions" (Federal Register, 1982). 118 Wetlands have three essential characteristics and criteria: wetland hydrology, hydric soils, and hydrophytic vegetation. The physical and chemical characteristics of hydric soils and the presence of hydrophytic vegetation are dependent on and are the result of the hydrologic regime. This cause-and-effect relationship allows inference among the three variables of wetlands. Vegetation is often used to support the presence of hydric soils and is part of the supporting documentation accepted by the Field Indicator Committee for review of indicators and hydric soils. Hydrology, which is often difficult to evaluate without costly and time demanding research, is often inferred and characterized from the assessment of both soils and vegetation (National Research Council, 1995). However, from a jurisdictional standpoint for wetland determinations the three parameters are independently determined. The criteria and procedures for determining wetlands and delineating their boundaries are in the National Food Security Act Manual (NFSAM) (Soil Conservation Service, 1994) and the Corps of Engineers Wetlands Delineation Manual (Environmental Laboratory, 1987). Federal regulations require the use of one of the manuals in determining wetlands. The former is used for delineating wetlands on agricultural lands by the National Resources Conservation Service (NRCS) and the latter is for determinations by the U.S. Army Corps of Engineers (USACE) and the Environmental Protection Agency (EPA) on non-agricultural lands and for Section 404 permits. The 1987 Corps manual will be the focus of this review and determination. Wetland Hydrology Criterion Wetland hydrology according to the Corps manual "encompasses all hydrologic characteristics of areas that are periodically inundated 119 or have soils saturated to the surface at some time during the growing season." Wetland hydrology involves three basic elements: inundation or saturation, critical depth of saturation, and duration of inundation or saturation in relation to growing season. In the definition of wetlands, inundation refers to "a condition in which water from any source temporarily or permanently covers a land surface." Saturation, in the definition, refers to "a condition in which all easily drained voids (pores) between soil particles in the root zone are temporarily or permanently filled with water to the soil surface at pressures greater than atmospheric." However, one of the primary field hydrologic indicators, "visual observation of soil saturation" (paragraph 49.b.2 in the 1987 manual), states that the "depth to saturated soils will always be nearer the surface" than the water level observed in a soil pit "due to the capillary fringe." Thus, the capillary fringe (with negative pressure) is indirectly considered in the determination of saturation and the requirement for saturation to the surface. Although no indication is given by the Corps on how to estimate the capillary fringe zone, the range can be from 10 cm in very coarse material to greater than 100 cm in fine-textured clays (Stephens, 1996). Austin (1993) found that the capillary fringe ranged from 10 cm in silt loam and silty clay loam to 20 cm in silty clay or clay soils, in selected Willamette Valley soils. The Corps does, however, discuss an acceptable depth to saturation in paragraph 49.b.2, "it must occur within a major portion of the root zone (usually within 12 inches of the surface) of the prevalent vegetation. The major portion of the root zone is that portion of the soil profile in which more than one half of the plant roots occur." This reference could be taken as an indication that saturation within the 12 inches (30 cm) of the surface is acceptable as a positive 120 indicator of wetland hydrology if the major portion of roots are within this zone. The saturation requirement would concur with the hydric soil definition established by the National Technical Committee for Hydric Soils that requires saturation within the upper 30.5 cm. The threshold also concurs with studies that found most roots in wetlands are concentrated in the upper 30 cm (National Research Council, 1995) and that surface saturated conditions are not necessary for development of wetland communities (Kelsey and Hootman, 1992). Duration is based on continuous inundation or saturation during the growing season. To be considered as having wetland hydrology, an area must be "inundated or saturated to the surface continuously for at least 5% of the growing season in most years (50% probability of recurrence)" according to the Corps manual. The growing season months of the mesic soil temperature regime of Soil Taxonomy is assumed to be March-October (US Department of Agriculture, Soil Conservation Service, 1991). However, the Corps regards the soil temperature regimes that are based on broad regions as not being sufficiently site-specific (HQUSACE, 1992). The primary accepted definition of growing season is considered the portion of the year when soil temperatures are above biologic zero (5°C or 41°F) at 50 cm beneath the soil surface, however, the Corps allows this period to be approximated by the number of frost-free days. The "starting and ending dates for the growing season are based on 28 degrees F air temperature threshold at a frequency of 5 years in 10." Other primary field hydrologic indicators for identifying wetland hydrology include: visual observation of inundation or saturation, watermarks, drift lines, sediment deposits, and drainage patterns. Secondary field hydrologic indicators (requires two in the absence of a primary indicator) include: oxidized rhizospheres in the upper 12 121 inches, water-stained leaves, local soil survey hydrology data for identified soils, and the FAC-neutral test for vegetation. Hydric Soils Criterion The 1987 manual uses the most recent version of the National Technical Committee for Hydric Soils (NTCHS) hydric soil definition and hydric soil criteria. The current hydric soil definition was discussed in Chapter 3. The current hydric soil criteria (criteria 3 and 4) require frequently ponded or flooded soils for long durations (7 days to 1 month) or very long durations (greater than 1 month) during the growing season. The Field Indicators of Hydric Soils in the United States developed by NTCHS are used as supplementary information but are not used by the Corps for identifying hydric soils. The Corps lists several indicators for determining whether a soil meets the definition and criteria for hydric soils. The indicators include: organic soils, histic epipedons, sulfidic material, aquic or peraquic moisture regime, reducing soil conditions, soil colors, soils appearing on hydric soil lists, iron and manganese concretions, high organic matter content in surface horizons, streaking of subsurface horizons by organic matter, and organic pans. Hydrophytic Vegetation Criterion The term hydrophyte originally referred to plants growing in water or very wet soil (Tiner, 1991). Today, federal delineation manuals define hydrophytic vegetation as the "sum total of macrophytic plant life that occurs in areas where the frequency and duration of inundation or soil saturation produce permanently or 122 periodically saturated soils of sufficient duration to exert a controlling influence on the plant species present." Wetland vegetation consists of plants that require soil saturation to become established or to persist and those that tolerate the stresses caused by soil saturation (National Research Council, 1995). Hydric soils have at least periodic anaerobic conditions that result in absence of oxygen, which is a common stress for most plants. The duration and intensity of reduction determines the degree of stress. The greater the reduction, as measured by the redox potential, the more severe the stress on plants. Additional stress is caused when anaerobic microbial activity results in various toxic products (Meek and Stolzy, 1978). The 1987 USACE manual uses the National List of Plant Species that Occur in Wetlands: 1988 National Summary (Reed, 1988) for identification of hydrophytic vegetation as required by the 1987 rule implementing the Food Security Act of 1985. The 1988 list originally was developed as an appendix to the Classification of Wetlands and Deepwater Habitats of the United States by Cowardin et al. (1979). The National List of Vascular Plant Species that Occur in Wetlands: 1996 National Summary is a draft revision of the 1988 list. The revision was developed to aid in determining the presence of hydrophytic vegetation for wetland regulation under the Clean Water Act Section 404 and the implementation of the swampbuster provisions of the Food Security Act (National Research Council, 1995). The national plant lists are divided into 13 regional lists corresponding to the geographic regions developed for the National List of Scientific Plant Names issued by the USDA in 1982 (National Research Council, 1995). The division allows each species to be assigned regional indicators to reflect ecotypic variation within species 123 from region to region. The national indicator status for each species is the range of regional indicators. The plant lists categorize vascular plants into five basic "wetland indicator status" groups (Table 5.1). The indicator status is based on the fidelity rating system that was created by the FWS during the development of its Annotated National Wetland Plant Species Data Base in the 1970's (National Research Council, 1995). The fidelity rating is based on frequency of occurrence of a plant species in wetlands and is used in evaluating the predominance of hydrophytic vegetation. Table 5.1. Wetland indicator category of plant species under natural Conditions (from Reed, 1988). Wetland Indicator Status Obligate wetland Facultative wetland Facultative Facultative upland Upland (OBL) (FACW)^ (FAC)A (FACU)A (UPL) Estimated probability of occurrence in wetlands Estimated probability of occurrence in nonwetlands >99% <1% 67-99% 34-66% 1-33% 1-33% <1% 34-66% 67-99% >99% A subdivided by (+) and (-) to specify a higher or lower portion of frequency The five categories range from obligate wetland (OBL) species that are virtually restricted to wetlands to upland (UPL) species that are mostly excluded from wetlands. Facultative (FAC) species occupy wetlands in varying degrees and thus were broken down into three categories with a gradation of percentage of occurrence in wetlands 124 (Reed, 1988). Species not occurring in wetlands in any region are not included on the list and are considered upland species. Other designations include: NI for no indicator as there was insufficient information, NA for no agreement as a consensus could not be reached, and (*) for a tentative designation based on limited information or conflicting reviews. As can be seen by the categories, most plants that grow in wetlands do not grow strictly in water or saturated soils but can exist in terrestrial habitats over a range of moisture status. Out of the nearly 7,000 vascular plant species found in U.S. wetlands, only 27 percent are "obligate wetland" species that nearly always occur in wetlands (Federal Interagency Committee for Wetlands Delineation, 1989). About 21% are "facultative upland" species that have been observed in wetlands, which illustrates species adaptations to wet environments (Tiner, 1991). Tiner (1991) discussed the ability of ecotypes, populations with different genetically based morphological and/or physiological characteristics, to adapt to specific environmental conditions that differ from the typical species habitat. A hydrophytic plant could represent an entire population of a species or only a subset of individuals genetically adapted to their environment. The ability to adapt results in plant communities that are commonly made up of populations with differing affinities for wet conditions and makes the use of the "predominance of hydrophytic vegetation" for evaluating the vegetative criteria complicated. In general, the indicator groups are indicative of different levels of soil moisture: dominance of UPL and/or FACU species with low amounts or absence of OBL or FACW species is evidence of infrequent flooding or saturation; dominance by OBL or FACW species is indicative of frequent or extended periods of flooding or saturation; 125 and dominance of 50% or more by OBL, FACW, or FAC species with low amounts or absence of UPL species is evidence of saturation or flooding (National Research Council, 1995). FAC and FACU are considered less reliable indicators of a wetland since they are less restricted to wetland conditions. However, their ecotypes can range from populations that occur in slightly stressful moisture conditions to populations that always occur in wetlands (National Research Council, 1995). The basic vegetation indicator in the 1987 manual that is considered indicative of hydrophytic vegetation is when more than 50% of the dominant species are OBL, FACW, or FAC. Under the dominance measure, plant communities are considered predominantly hydrophytic if more than 50% of the dominant species are hydrophytic. Less abundant species are not considered in the determination. The system is based on the assumption that dominant taxa have adapted and reflect the long-term hydrologic regime. This assumption could be a potential problem in marginal situations if the nondominant species are better indicators of the hydrologic regime (National Research Council, 1995). Other indicators of hydrophytic vegetation in the 1987 manual that can be used to strengthen a case for the presence of hydrophytic vegetation are: visual observation of species growing in areas of prolonged inundation and/or saturation; morphological, physiological, and reproductive adaptations; and technical literature that provides a strong indication that species present are commonly found in areas where soils are periodically saturated for long periods. 126 Methods The procedures in the 1987 manual allow alternative sampling methods and the use of an alternative dominance measure called the "50/20 rule" from the 1989 manual (Federal Interagency Committee for Wetlands Delineation, 1989), which was developed and later rejected. Plant communities were evaluated at each of the main sites (Site 1 through 4). Since the vegetation consisted of diverse and patchy herb communities, a multiple-quadrant sampling approach similar to the methods presented in the 1989 manual was chosen. Five 0.50 m2 sampling units were chosen within a 2 m by 2.5 m grid area by using a random numbers table. The sampling units were located 1 m north of each equipped site in order to avoid disturbance of vegetation when measuring soil and hydrology parameters. The units were sampled in the middle of May and the first week of June to encompass early and late emergent plant species. Vegetation was described in terms of species composition and relative abundance of species. Abundance was measured by estimating percentage of the sampling area covered by vertical projection of plant foliage onto the quadrats. The most abundant species were considered the dominant species. The alternative "50/20 rule" given in the 1989 federal manual was used for selecting dominant species. The basic dominance method was also applied in order to see if the outcome would be the same. However, the basic method was not used because the sampling method for "comprehensive determination" in the 1987 manual is based on a number of observation points along several transects with one sampling quadrant at each observation point. Determination of dominant species according to the "50/20 rule" is accomplished by: first ranking the species by their mean cover, beginning with the most 127 abundant species; determining the dominance threshold number, which is 50% of the total mean cover; then cumulatively summing the mean cover of the ranked species beginning with the most abundant until 50% of the total for all species mean cover (threshold number) is immediately exceeded. All species contributing to the cumulative total plus additional species having 20% of the total mean cover value is considered a dominant species (Federal Interagency Committee for Wetlands Delineation, 1989). Once plants were identified by genus and species, the National List of Plant Species that Occur in Wetlands: 1988 National Summary (Region) and the 1993 Northwest Region 9 Supplement were consulted to determine the "wetland indicator status" of each plant. Although the National List of Vascular Plant species that. Occur in Wetlands: 1996 Northwest (Region 9) draft has been issued, a January 1996 memorandum by the Corps warns that changes to the 1988 national plant list or regional versions of the national list should not be used until official approval. Results and Discussion Wetland Hydrology As mentioned earlier, wetland hydrology according to the Corps "encompasses all hydrologic characteristics of areas that are periodically inundated or have soils saturated to the surface at some time during the growing season." Although the hydrologic data from the piezometers (Chapter 3) did not indicate surface saturation, the soils at Sites 2, 3, and 4 had extended periods of saturation from November through April in the major portion of the root zone (within 30 cm of the surface). The mean water table for the two field seasons was 12.6 cm at Site 2, 9.8 cm at Site 3, and 5.5 cm at Site 4. In 128 addition, the soils at Sites 3 and 4 could be considered to be saturated "to the surface" based on the mean water table data and assumed capillary rise of at least 10 cm. According to the 1987 manual, an area must be "inundated or saturated to the surface continuously for at least 5% of the growing season in most years (50% probability of recurrence)" to be considered as having wetland hydrology. The growing season would be 365 days based on soil temperature above biological zero (5°C or 41°F) at 50 cm beneath the soil surface, since the soil temperature never reached this threshold. Based on frost-free days, 28° F temperature threshold for a frequency of 5 years in 10 years, the growing season in Benton County would be from March 15th to November 10th for a total of 240 days (Soil Survey Staff, 1975a). Based on "5% of the growing season", 5 percent would be 18 days or 12 days depending on whether the "biological zero threshold" or "28° F temperature threshold" was used to determine the growing season. Saturation data were given in Table 3.1. The data show that continuous saturation within the upper 30 cm occurred at: Site 1 for two, one-week duration periods, Site 2 for an average of 19.5 weeks (136.5 days), Site 3 for an average of 21.5 weeks (154 days), and Site 4 for an average of 24 weeks (168 days). If the "biological zero threshold" were used for determining the growing season, the periods of saturation "during the growing season" far exceed the 18 days continuous saturation requirement. If the "28° F temperature threshold" were used to determine growing season, the only applicable times of saturation would be after March 15th. Soils at Site 2 would have been considered to have continuously saturated soils for 21days (to 4/04/96) the first growing season and 22 days (to 4/05/97) the second growing season. Soils at Site 3 would have had continuously saturated soils for 21 days (to 4/04/96) the first growing 129 season and 50 days (to 5/03/97) the second growing season. Site 4 soils would have had 51 days (to 5/04/96) the first growing season and 57 days (to 5/10/97) the second growing season. Either of the growing season methods results in Sites 2, 3, and 4 meeting the wetland hydrology criteria. However, the wetland classification would be different depending on which growing season method was used. Based on the "biological zero" growing season, Sites 2, 3, and 4 would be classified (according to paragraph 48, Table 5 in the 1987 manual) as hydrologic zone III "regularly inundated or saturated" wetland since duration of saturation is >25% - 75% of the growing season. Based on the "28° F temperature threshold" growing season, Site 2 would be classified as a hydrologic zone V "irregularly inundated or saturated" wetland because duration of saturation is 512.5% of the growing season. Site 3 and Site 4 would be classified as hydrologic zone IV "seasonally inundated or saturated" wetlands, which are saturated for > 12.5-25% of the growing season. Hydric Soils The 1987 manual uses the most recent version of the National Technical Committee for Hydric Soils (NTCHS) hydric soil definition and hydric soil criteria. The current hydric soil definition was discussed in Chapter 3 where it was determined from data collected for two years that the soils at Sites 2, 3 and 4 meet the hydric soil definition and are hydric soils. Hydrophytic Vegetation Detailed characterization showing plant species and percent areal cover of quadrants at Sites 1 through 4 is given in Appendix D. Tables 5.2 through 5.5 show plant species present, their indicator 130 status, and dominance determinations. Although the alternative "50/20" rule was used for selecting dominant species, the tables also show which five species would have been considered dominant if cover classes that are used in the 1987 manual had been considered. Also included, but not utilized in the determinations, is the indicator status given in the 1996 National List of Vascular Plant Species that Occur in Wetlands. Site 1 (Table 5.2), located on the backslope, had a plant community dominated by Arrhenatherum elatius (Tall Oatgrass) and Agrostis tenuis (Colonial Bentgrass). The indicator status for the former is UPL and the indicator status of the latter is FAC. If the basic dominance rule in the 1987 manual had been used, the additional dominant species would be Poa pratensis (FAC), Festuca dertonensis (upland) and Galium aparine (FACU). Site 2 (Table 5.3), located downslope from Site 1, had a plant community dominated by Agrostis stolonifera (Creeping Bentgrass), Festuca rubra (Red Fescue), and Festuca arundinacea (Tall Fescue). The indicator status for A. stolonifera was changed from a FAC+ to FAC* in the 1993 supplement. The pending 1996 version changes the status to FACW*. The indicator status for F. rubra is FAC+ and the status for F. arundinacea is Fac-. At Site 2, the additional dominant species using the basic dominance rule would be P. pratensis (FAC) and A. tenuis (FAC). Site 3 (Table 5.4) had a plant community dominated by Agrostis stolonifera (Creeping Bentgrass) and Festuca rubra (Red Fescue). Additional dominant species would be F. arundinaciea (FAC-), Holcus lanatus (FAC) and Carex tumulicola (FACU*) for the basic rule. Site 4 (Table 5.5) had a plant community dominated by Alopecurus pratensis (Meadow Foxtail) and Lotus corniculatus (Birds- Table 5.2. Dominance determination for Site 1. SPECIES Agrostis stolonifera L. Agrostis tenuis Sibth. Alopecurus pratensis L Arrhenatherum elatus (L.) J. & K. Pres' Brodiaea coronaria (Salisb.) Engl. Brodiaea hyacinthina (Lindl.) Baker Bromus commutatus Schrad. Bromus mollis Schrad. Carex densa (L.H. Bailey) L.H. Bailey Carex leporina L. Cardamine oligosperma Nutt. Carex tumulicola Mackenzie Carex unilateralis Mackenzie Cerastium viscosum L. Cirsium vulgare (Savi) Ten. Daucus carota L. Eleocharis palustris (L.) Roem. & J.A. Schultes Epilobium glandulosum Lehm. Festuca dertonensis (All.) (F. bromoides) Festuca pratensis Huds. Festuca rubra L. Festuca arundinacea Schreb. 50/20 RULE BASIC DOMINANT RULE INDICATOR STATUS * Mean % 1996 Mean % 1993 1988 List areal Rank Dom. areal Cover Mid- Rank PNW List spec. cover cover class point Suppl. FAC+ FAC* FACW* FAC FACW UPL FACW UPL UPL OBL FAC FACW FACW UPL FACU 24.0 2 * 24.0 2 15 48.0 1 * 48.0 3 37.5 1 2.5 2.5 0.2 0.2 0.2 0.2 0.6 0.4 0.6 0.4 1 1 2.5 2.5 15.0 2 15 OBL FACW FACW FAC FAC FACU* FACU FACW FACU _ OBL OBL 15.0 FACU+ FAC FACU- 1 2 FAC+ FAC- 4 FAC+ A 4 Table 5.2, Continued. SPECIES Galium aparine L. Geranium dissectum L. Holcus lanatus L. Juncus effusus L. Juncus tenuis Wilid. Lotus comiculatus L. Montia fontana L. Montia linearis (Dougl.) Greene Myosotis discolor Pers. Parentucellia viscosa (L.) Caruel Poa pratensis L. Ranunculus orthorhynchus Hook. Rumex acetosella L. Trifolium dubium Sibth. Trifolium spp. Veronica arvensis L. Vicia sativa L. INDICATOR STATUS * 50/20 RULE BASIC DOMINANT RULE 1988 1993 1996 Mean % Mean % List PNW List areal Rank Dom. areal Cover Mid- Rank Suppl. cover spec. cover class point FACU FACU 2.2 5 2.2 1 2.5 5 0.6 0.6 1 2.5 FAC FACW+ FAC FAC OBL FAC FACW FACW FACW- FACWFAC OBL FACW FACFACU+ FACWFACU UPL FACW FACFAC FAC FACW FACU+ FACU+ UPL 0.6 19.5 0.6 FACU+ FACU+ UPL 3 0.6 1 2.5 19.5 2 15 0.6 1 2.5 UPL 0.6 0.6 1 2.5 Total mean cover = 112.5 Dominance Threshold Number = ( 50% x total mean cover) = 56.25 20% of the total mean cover = (.20 x 112.5) = 22.5 * All species without an indicator status are considered upland plants 3 Table 5.3. Dominance determination for Site 2. SPECIES Agrostis stolonifera L. Agrostis tenuis Sibth. Alopecurus pratensis L Arrhenatherum elatus (L.) J. & K. Presl Brodiaea coronaria (Salisb.) Engl. Brodiaea hyacinthina (Lindl.) Baker Bromus commutatus Schrad. Bromus mollis Schrad. Carex densa (L.H. Bailey) L.H. Bailey Carex leporina L. Cardamine oligosperma Nutt. Carex tumulicola Mackenzie Carex unilateralis Mackenzie Cerastium viscosum L. Cirsium vulgare (Savi) Ten. Daucus carota L. Eleocharis palustris (L.) Roem. & J.A. Schultes Epilobium glandulosum Lehm. Festuca dertonensis (All.) (F. bromoides) Festuca pratensis Huds. Festuca rubra L. Festuca arundinacea Schreb. INDICATOR STATUS * 50/20 RULE BASIC DOMINANT RULE 1988 1993 1996 Mean % Mean % List PNW List areal Rank Dom. areal Cover Mid- Rank cover Suppl. spec. cover class point FAC* FACW* FAC+ 32.5 2 32.5 3 37.5 2 FAC 3.7 1 3.7 5 2.5 5 FACW UPL FACW UPL UPL OBL FAC FACW FACW FAC FACU* FACW UPL FACU 0.2 1 2.5 0.2 0.2 1 2.5 2.5 2.5 1 2.5 OBL FACW FAC FACU FACW FACU OBL OBL FACU+ FAC FACU- 0.2 FAC+ FAC- FAC+ 34.1 27.4 1 3 * 34.1 27.4 3 3 37.5 37.5 1 3 Table 5.3, Continued. SPECIES Galium aparine L. Geranium dissectum L. Holcus lanatus L. Juncus effusus L. Juncus tenuis Willd. Lotus corniculatus L. Montia fontana L. Montia linearis (Dougl.) Greene Myosotis discolor Pers. Parentucellia viscosa (L.) Caruel Poa pratensis L. Ranunculus orthorhynchus Hook. Rumex acetosella L. Trifolium dubium Sibth. Trifolium spp. Veronica arvensis L. Vicia sativa L. INDICATOR STATUS * 50/20 RULE BASIC DOMINANT RULE 1988 1993 1996 Mean % Mean % List PNW List areal Rank Dom. areal Cover Mid- Rank Suppl. cover spec. cover class point FACU FACU 2.9 2.9 1 2.5 FAC FACW+ FACW FAC FACWFAC OBL FAC FACW FACWFAC OBL 0.2 0.2 1 2.5 FACW FACFACU+ FAC FACWFACU FACU+ UPL FACW FACFAC FACW FACU+ UPL 1.1 1.1 1 2.5 5.0 1 2.5 0.4 1 2.5 5.0 0.4 4 4 _ UPL FACU+ FACU+ UPL 1.6 1.6 1 2.5 Total mean cover = 111.8 Dominance Threshold Number = ( 50% x total mean cover) = 55.9 20% of the total mean cover = (.20 x 111.8) = 22.4 * All species without an indicator status are considered upland plants Table 5.4. Dominance determination for Site 3. SPECIES Agrostis stolonifera L. Agrostis tenuis Sibth. Alopecurus pratensis L Arrhenatherum elatus (L.) J. & K. Presl Brodiaea coronaria (Salisb.) Engl. Brodiaea hyacinthina (Lindl.) Baker Bromus commutatus Schrad. Bromus mollis Schrad. Carex densa (L.H. Bailey) L.H. Bailey Carex leporina L. Cardamine oligosperma Nutt. Carex tumulicola Mackenzie Carex unilateralis Mackenzie Cerastium viscosum L. Cirsium vulgare (Savi) Ten. Daucus carota L. Eleocharis palustris (L.) Roem. & J.A. Schultes Epilobium glandulosurn Lehm. Festuca dertonensis (All.) (F. bromoides) Festuca pratensis Huds. Festuca rubra L. Festuca arundinacea Schreb. INDICATOR STATUS * 50/20 RULE BASIC DOMINANT RULE 1988 1993 1996 Mean % Mean % List PNW List areal Rank Dom. areal Cover Mid- Rank Suppl. cover spec. cover class point FAC+ FAC* FACW* 36.0 36.0 3 37.5 1 _ FAC 2.4 2.4 1 2.5 FACW FACW 0.3 0.3 1 2.5 UPL UPL 0.4 4.5 UPL OBL FAC FACW FACW FAC FACU* FACW UPL FACU OBL FACW FAC FACU FACW FACU OBL OBL FACU+ FAC FAC+ FACU- FAC- FAC+ 0.4 4.5 1 0.2 5.0 1 0.3 0.4 0.2 0.3 0.4 0.2 1 28.0 28.0 11.9, 0.2 5.0 11.9 5 3 1 1 1 1 3 2 2.5 2.5 _ 2.5 2.5 2.5 2.5 2.5 37.5 15 . 2 Table 5.4, Continued. SPECIES Galium aparine L. Geranium dissectum L. Holcus lanatus L. Juncus effusus L. Juncus tenuis Willd. Lotus corniculatus L. Montia fontana L. Montia linearis (Dougl.) Greene Myosotis discolor Pers. Parentucellia viscosa (L.) Caruel Poa pratensis L. Ranunculus orthorhynchus Hook. Rumex acetosella L. Trifolium dubium Sibth. Trifolium spp. Veronica arvensis L. Vicia sativa L. INDICATOR STATUS * 50/20 RULE BASIC DOMINANT RULE 1988 1993 1996 Mean % Mean % List PNW List areal Rank Dom. areal Cover Mid- Rank Suppl. cover spec. cover class point FACU FACU 0.9 1 0.9 2.5 0.4 0.4 1 2.5 FAC FAC 9.8 4 9.8 2 15 4 FACW+ FACW FAC FACWFAC OBL FACW FACWFAC OBL FACW FACFACU+ FAC FACWFACU FACU+ UPL FACW FACFAC FACW FACU+ UPL UPI, FACU+ FACU+ UPL 2.5 2.5 1 2.5 1.4 1.4 1 2.0 2.0 1 2.5 2.5 1.4 1.4 1 2.5 1 1 2.5 2.5 = 54.2 0.4 0.4 Total mean cover = 108.4 Dominance Threshold Number = ( 50% x total mean cover) 20% of the total mean cover = (.20 x 108.4) = 21.7 * All species without an indicator status are considered upland plants Table 5.5. Dominance determination for Site 4. SPECIES Agrostis stolonifera L. Agrostis tenuis Sibth. Alopecurus pratensis L Arrhenatherum elatus (L.) J. & K. Presl Brodiaea coronaria (Salisb.) Engl. Brodiaea hyacinthina (Lindl.) Baker Bromus commutatus Schrad. Bromus mollis Schrad. Carex densa (L.H. Bailey) L.H. Bailey Carex leporina L. Cardamine oligosperma Nutt. Carex tumulicola Mackenzie Carex unilateralis Mackenzie Cerastium viscosum L. Cirsium vulgare (Savi) Ten. Daucus carota L. Eleocharis palustris (L.) Roem. & J.A. Schultes Epilobium glandulosum Lehm. Festuca dertonensis (All.) (F. bromoides) Festuca pratensis Huds. Festuca rubra L. Festuca arundinacea Schreb. 50/20 RULE INDICATOR STATUS * BASIC DOMINANT RULE Mean % 1993 1996 Mean % 1988 List areal Rank Dom. areal Cover Mid- Rank List PNW cover spec. cover class point Suppl. 4 15 FACW* 10.9 4 10.9 2 FAC* FAC+ FAC FACW UPL FACW UPL UPI, OBL FAC FACW FACW 30.5 2 13.7 3 * 30.5 3 37.5 2 13.7 2 15 3 _ OBL FACW FACW FAC FAC FACU* FACU FACW UPL FACU FACU OBL OBL 4.4 5.0 4.4 5.0 1 1 2.5 2.5 _ 2 15 0.2 7.1 0.2 1 2.5 4.8 2.2 4.8 2.2 1 2.5 2.5 7.1 _ _ FACU+ FAC FACU- FAC+ FAC- 1 FAC+ . Table 5.5, Continued. SPECIES Galium aparine L. Geranium dissectum L. Holcus lanatus L. Juncus effusus L. Juncus tenuis Wilid. Lotus corniculatus L. Montia fontana L. Montia linearis (Dougl.) Greene Myosotis discolor Pers. Parentucellia viscosa (L.) Caruel Poa pratensis L. Ranunculus orthorhynchus Hook. Rumex acetosella L. Trifolium dubium Sibth. Trifolium spp. Veronica arvensis L. Vicia sativa L. INDICATOR STATUS * 50/20 RULE BASIC DOMINANT RULE 1988 1993 1996 Mean % Mean % List PNW List areal Rank Dom. areal Cover Mid- Rank Suppl. cover spec. cover class point FACU FACU FAC FACW+ FAC FAC OBL FAC FACW FACW FACW- FACWFAC OBL FACW FACFACU+ FACWFACU UPL FACW FACFAC FAC FACW FACU+ FACU+ UPL UPL FACU+ FACU+ UPL 3.0 8.5 5 1.5 71.8 0.6 0.8 5.8 1 * 3.0 8.5 2 15 1.5 1 1 2.5 62.5 2.5 2.5 2 15 71.8 0.6 0.8 5.8 1 1 1 2.5 Total mean cover = 170.8 Dominance Threshold Number ( 50% x total mean cover) 85.4 20% of the total mean cover = (.20 x 170.8) = 34.2 * All species without an indicator status are considered upland plants 5 1 139 foot Trefoil). The indicator status for A. pratensis is FACW and L. corniculatus has a FAC status. Additional dominant species under the basic rule would be Bromus commutatus (upland), A. stolonifera (FAC*), and Juncus effusus (FACW). Hydrophytic vegetation is considered present when more than 50% of the dominant species are OBL, FACW, or FAC (FAC- has less probability of occurring in wetlands than FAC). The "50/20" rule resulted in three dominant species at Site 2 and only two dominant species at Sites 1, 3, and 4. In order for the community to be dominated by hydrophytic vegetation, both species would need to be FAC or wetter at the latter sites. Under these guidelines and the "50/20" rule, Sites 2, 3, and 4 had hydrophytic vegetation. Even with the additional dominant species under the basic dominant rule, Sites 2, 3, and 4 would meet the 50% dominant measure. Plant community composition on the upper slope showed no sharp discontinuities; however, a downslope transition was apparent. The transition zone between Site 1 and Site 2 started at Plot B with a change from A. elatus to F. rubra and F. arundinacea. Holcus lanatus and Juncus tenuis began appearing with variable occurrence at Site 2. Both increased downslope but still did not occur uniformly. A. pratensis appeared at Site 3 and increased downslope. Other species that occurred in areas around Site 3 but were not in the sampling quadrants were Briza minor (FAC), Camassia quamash (FACW*), and Juncus bufonius (FACW+). Conclusion The criterion for wetland hydrology was met by soils at Sites 2, 3, and 4 based on saturation within 30 cm of the soil surface. The soils of Sites 2, 3, and 4 met the requirements in the hydric soil 140 definition as determined in Chapter 3 and, therefore, met the hydric soil criterion. Sites 2, 3, and 4 had hydrophytic vegetation based on the 50% dominance measure. Therefore, Sites 2, 3, and 4 met the three essential characteristics and criterion of wetlands and would be considered jurisdictional wetlands by federal regulations. In this study, plant communities that are dominated by more than 50 percent facultative (FAC) species satisfied the hydrophytic vegetation criteria at Sites 2 and 3. Controversy continues over FAC species and the application of the "50% rule" since FAC species have broad ecological amplitude and have no affinity for either wetlands or nonwetlands. The 1987 manual does allow vegetation dominance to be computed without the inclusion of facultative species ("FACneutral" tests) in some circumstances. However, studies on sites dominated by facultative species showed eliminating FAC species from the determination resulted in the failure to exceed the 50% threshold even on poorly drained hydric soils (National Research Council, 1995). Since Sites 2 and 3 had positive indicators for both wetland hydrology and hydric soils, the FAC plant communities are considered indicative of hydrophytic vegetation (Step 13.a. pg. 70) by the Corps. 141 Chapter 6 GEOMORPHOLOGY AND STRATIGRAPHY OF THE WITHAM HILL BACKSLOPE-FOOTSLOPE STUDY SITE Introduction Soil development and morphological characteristics are greatly influenced by geomorphic setting and stratigraphy. Landscape and stratigraphy to a large degree control the flow of energy and water (Mausbach and Richardson, 1994) that are major factors in pedogenesis and in the formation of hydric soils. The objective of this investigation was to obtain information that would further our understanding of the geomorphic processes that resulted in the present hydrology, morphological characteristics, and development of hydric soils at the study site. Review of past research on the geology and geomorphic associations in the Willamette Valley in addition to mineralogical analyses were use to identify geomorphic surfaces, determine stratigraphic units, and identify possible sources of soil materials. Background Landscape position usually dictates water movement (Richardson, et al., 1992) that in turn influences the moisture status, distribution of soluble materials, and soil development. Hydric soils are found predominately in flat landscapes such as floodplains, depressions, backwater areas, and landscapes that have closed drainage systems. Landscapes with relief and open systems are normally not considered as being wet and usually have well drained to moderately well drained soils (Mausbach and Richardson, 1994). Stratigraphy influences soil characteristics by altering a landscape's hydrology. Stratigraphic units can provide a vertical 142 textural contrast that affects hydraulic conductivity, water flow, and soil drainage (Mausbach and Richardson, 1994). In addition, the unit's continuity and distribution affect the direction of subsurface water movement (Richardson and Daniels, 1993). Soil-geomorphic-stratigraphic relationships in foothills of the Willamette Valley are complex due to lithostratigraphic units and geomorphic surfaces consisting of materials of different origin and age from different erosional and depositional events (Glasmann et al., 1980). Studies and mapping of stratigraphic units and geomorphic surfaces in the Willamette Valley have been extensive in the last 30 years. Geomorphic surfaces, portions of the landscape "specifically defined in space and time" (Ruhe, 1975) that represent episodes of landscape development, were initially defined and mapped in the valley by Balster and Parsons (1968). This and other research (Balster and Parsons, 1969; Parsons, et al., 1968; Parsons, et al, 1970) demonstrated the correlation between soil, stratigraphy, and geomorphic surfaces of the valley. Models of stratigraphic units, geomorphic surfaces, and the relationship between the stratigraphy and soils were developed. However, most of the studies and research have focused on the regional silty and clayey soils of the valley floor terraces. Some site-specific studies (Gelderman, 1970; Gelderman and Parsons, 1972; Glasmann and Kling, 1980; Glasmann et al., 1980) have been done on the higher pediments and foothills but no comprehensive valley-wide studies have been published. Mineralogical characteristics of soils have been used as an aid in the delineation of stratigraphic units and geomorphic surfaces and the identification of material origin. The types of minerals, weathering status of minerals, and clay content, can be used to identify lithologic discontinuities that differentiate among stratigraphic units (Ruhe, 143 1975). Mineral composition reflects the environment in which parent material and soils were formed, while the weathering status of minerals and mineral distribution in soil profiles is an indication of the uniformity of soil development. A sequence of weathering from the bedrock upward may be seen in the micas and clays (Cady, 1960) in a residuum soil profile. The intensity of weathering in a residual soil decreases progressively down through the profile. Weathering combined with clay movement usually results in an accumulation of a relatively large amount of one clay in a particular horizon (Cady, 1960). Mica is mostly a primary mineral and thus the amount and size of mica is greatest in bedrock and progressively decreases upwards with the increase in weathering. Through weathering, mica can alter to vermiculite, which further weathers to smectite, chlorite, and kaolinite (Fanning and Keramidas, 1977). Smectite can be weathered further to kaolin or chlorite. Kfeldspar weathers to kaolinite or halloysite while plagioclase feldspar weathers to smectite. Due to mica and feldspar weathering and downward clay translocation (mostly smectite), more vermiculite and kaolinite are expected in the upper horizons and more smectite and halloysite in the subsurface horizons. The presence of better-ordered kaolin with depth is due to geologic kaolin instead of pedogenic kaolin. The soil environment also influences the location and relative amounts of minerals in a soil profile. Smectite is more abundant in moist conditions and, therefore, can increase with depth or in lower footslope and toeslope positions. Chlorite, chloritic intergrades, and kaolinite usually occur in dryer conditions in the upper profile or on summit and shoulder positions. Crystalline mineral components can be identified and semiquantitative estimates of their relative abundance in soils can be made by X-ray diffraction (XRD) analysis (Moore and Reynolds Jr, 144 1989). Each mineral has distinctive diffraction angles resulting from interatomic distances within crystalline structures. XRD produces peaks on a graph corresponding to angles of diffraction from the mineral crystalline spacing. The minerals can be identified and distinguished from one another by subjecting the sample to various treatments, running the XRD for each treatment, and observing the peaks which show the effect on the interplanar spacing along the axis perpendicular to the platy surfaces (Soil Survey Staff, 1996). Estimations of mineral concentrations are based on the intensities of diffraction peaks, which are related to the number of diffraction planes in a sample (Moore and Reynolds Jr, 1989). Geological Overview The Willamette Valley in western Oregon is located approximately 40 miles inland from the Pacific Ocean (Fig. 6.1). The valley is about 130 miles in length and 20-40miles in width and occupies about 3,500 square miles (Orr et al., 1992). The valley is divided physiographically into two units by the Salem-Eola Hills (Balster and Parsons, 1968) with the southern section narrower and flatter (Baldwin, 1981). The Columbia River is the northern boundary. The two ranges that enclose the valley the Coast Range to the west and the Cascade Range to the east converge near Cottage Grove to form the southern boundary (Baldwin, 1981). The Willamette River flows northward, and with its numerous tributaries, drains the valley to the Columbia. Structurally the Willamette Valley is a forarc basin, a partially enclosed downwarp, created by the formation and subsidence of volcanic foundation rocks (Orr et al., 1992). According to Orr et al. (1992), the area west of the Cascades was part of a broad continental 145 Figure 6.1. Physiographic provinces of Oregon. 146 shelf of the ocean during the early Eocene to Pliocene time. The foundation rocks of the shelf were formed when a volcanic island chain collided and accreted to the North American plate. A basin was formed between the Cascades and the ridge of subsiding inactive seamounts to the east of the accretion. The trough-like configuration of the valley formed later with the uplift of the Coast Range and continued subsidence of the basin. The valley, from its creation, started filling with alluvial deposits and isolated volcanic flows. During the Tertiary age, the partially enclosed basin received submarine flows, breccias, and tuffaceous sediments from a chain of volcanic peaks to the west of the thencurrent shoreline (Baldwin, 1981). These sediments were interfingered with sediments from the Cascades, detritus from the Klamath terrain (Snavely and Wagner, 1963), and marine deposits from the sea. Today, the geology of the valley and surrounding foothills consist of early Tertiary basalt, sandstone, and shale; Eocene to Miocene sandstones, siltstones, and claystones; Plio-Pleistocene sediments from the surrounding landscape and the Columbia River; and Pleistocene lacustrine deposits from an external source of glacial-melt runoff. The unique and complex geologic history of erosional and depositional events in the Willamette Valley has left lithostratigraphic units and geomorphic surfaces consisting of materials of different origin and age. The Pleistocene lacustrine deposits from large-scale floods brought in sediments from outside provenances (Allison, 1953) that have had a major influence on soil development in the valley. As summarized by Orr et al. (1992), the multiple ice-age floods occurred as Lake Missoula in Montana repeatedly filled and emptied in catastrophic events when the Clark Fork River was dammed by ice lobes and breached. The water rushed across Idaho, Washington, and 147 through the Columbia Gorge to form temporary lakes in the valley. The lacustrine slackwater sediments and ice-rafted erratics (Allison, 1953) settled on the valley floor and surrounding lower foothills simultaneously with sediment from local fluvial events and other internal geomorphic processes (McDowell, 1991). The sediments from the "Spokane Flood" or "Bretz Floods" and "Ancient Missoula floods" (Reckendorf, 1993) formed distinct banded layers in the valley floor and lower pediments that Allison (1953) named the Willamette Silts. Balster and Parsons (1969) redefined this silty unit as the Willamette Formation and divided the formation into four lithostratigraphic units based on morphology, mineralogy, and aerial distribution. The youngest deposit is the Greenback Member (12 ka -15 ka yrs., Reckendorf, 1993; 13 ka yrs., McDowell, 1991) and is a light gray, silty material that has predominantly silt-sized quartz and feldspars. Below the Greenback is the Malpass Member that is massive gray clay with irregular thickness. Next, the Irish Bend Member (50-60 ka yrs., Reckendorf, 1993; 35-40 ka yrs., McDowell, 1991) has brown, faintly bedded micaceous silts. This unit overlies the Wyatt Member that is composed of local sandy and silty alluvium. McDowell (1991) gives an overview of proposed stratigraphic schemes of the Willamette Formation and discusses a two-stage developmental model that has evolved for the stratigraphy and origin of the deposits. Investigation Soil samples were collected from soil pits at Sites 1, 2, and 3. A trench 61.5 m (202 ft) long was excavated to a depth of 1.2 m (4 ft) on the upper transect from above Site 1 to Site 3 at an absolute elevation of 99.7-93 m (Fig. 3.1). Measurements of depths to horizons and stratigraphic unit boundaries corresponding to those observed in pit 148 soil profiles were recorded at various points along the trench. Any rock fragments found in the trench walls were tagged and their positions recorded. A National Resource Conservation Service (NRCS) soil survey crew determined absolute elevation of the sites with a laser level from county benchmarks #441. X-ray diffraction analyses were performed on samples from selected soil horizons from Pits 1, 2, and 3 to identify and estimate the relative proportions of the crystalline mineral components. Air-dry soil samples were separated for analysis following procedures outlined by Glasmann (J.R. Glasmann, 1997, Procedures for clay mineral separation, Mimeographed handout, Dept. of Geosciences, Oregon State University, Corvallis, Oregon) and are detailed in Appendix E. In general, the traditional less than < 2gm fraction is used to prepare oriented sample mounts that are free of most of the non-clay minerals (Towe, 1974). However, even though clay is considered any colloidal material < 2 1.1,M in size, clay minerals can be much larger (Moore and Reynolds, 1989). Sample mounts of the <15 gm fraction were made in order to identify any >2 gm clay minerals and non-clay minerals. A paste method (Theisen and Harward, 1962) was used to make oriented clay film mounts of <2 gm and <15 pm samples from selected horizons. The slides of the <15 I.M1 material were equilibrated at Mg+2 54% relative humidity. Slides of the <2 pm material received five different treatments: Mg+2 54% relative humidity, Mg+2-glycol, Mg÷2- glycerol, K+54% relative humidity, and K+1100C. Pretreatment with Mg+2 saturation insured homoionic clay specimens (de Kimpe, 1993) and allowed the identification of basal peaks for most smectites (1515.5 A), mica (10 A), and kaolin (7.1-7.5 A). Further treatments were necessary to distinguish vermiculite (14.2 A), chlorite (14.2 A), chloritic intergrade (14-15 A), and beidellite (14-15 A) 001 basal peaks from 149 smectite 001 basal peak, to distinguish these minerals from each other, and to discern between kaolinite and halloysite. Analyses were made with a.Phillips XRG 3100 Automated XRD unit using monochromatic Cu K.< radiation at 40kV and 35mA. The slides were run in the 2-34° 20 portion of the spectra for the <2 p.m Mg+2-glycol and the <15 pm Mg+2 54%RH samples. The <2 p.m samples with the Mg+2 54%RH, Mg+2-glycerol, K+ 54%RH, and K+110°C were run in the 2-14° 29 range. The "d" (A) values of the spacing of reflections were observed for each treatment. Mineral identification was based on "d" values from Brindley and Brown (1980) and JADE Search/match software for computer facilitated mineralogy interpretations. Relative proportions of minerals were determined by the intensities of diffraction maxima. Results and Discussion Observations Field observations of the substratum provided morphological evidence of stratification. Two distinct banded clay units could be traced up the hillslope in the trench where they thinned and tapered to an end (Fig. 6.2). In addition, physical analysis confirmed there was a significant change in particle-size distribution between the overlying silty clay loam horizons and the clay horizons. The upper clay layer (2Bt) is grayish brown (2.5Y 5/2) and tapers to an end at an absolute surface elevation of 97.9 m and 89 cm below the surface. The underlying clay layer (3l3ss) is light olive brown (2.5Y 5/4) and tapers to an end at a surface elevation of 96.8 m and 124 cm below the soil surface. Both clay layers tapered to an end where a slight break in slope is evident below Site 1 that is at an elevation of 99.1 m. At Site 2, the Figure 6.2. Cross-section of the study trench showing the stratigraphy from Site 1 to Site 3. 102 100 92 90 C 2 D Site locations along 61.5 meter trench Cr, BC horizon 3B horizons 2B horizons BA, Bw horizons B/E, E/B horizons A horizons 151 gray clay layer (2Btl) ranged from 70 cm to 92 cm beneath the soil surface and the underlying olive clay layer (3Bss) ranged from 92 cm to 142 cm beneath the soil surface. At Site 3, the gray clay layer (2Bt) ranged from 42 cm to 91 cm beneath the soil surface and the underlying olive clay layer (3Bss) ranged from 91 cm to 153 cm beneath the soil surface. Beneath the surficial clay loam layer at Site 1 was slightly weathered bedrock that was light yellowish brown (2.5Y 7/3) sandstone interbedded with siltstone. Light yellowish brown (2.5Y 6/3) highly weathered soft siltstone and / or sandstone was beneath the lower olive clay layers at Sites 2 and 3. The weathered bedrock at Site 2 had 28.8% sand content compared to 5.9% for Site 1 and 6.5% for Site 3, which shows the bedrock variability. The upper gray clay horizon has the same characteristics of the massive gray clay described by Gelderman (1970) as the Malpass Member of the Willamette Formation. The gray clay described by Gelderman as "dense, cracks on drying into large polyhedral peds . . . has slickensides, contains iron-manganese segregations, and has few to common fine yellowish brown mottles" could very well be describing the 2Bt horizon of Site 3. At the Witham Hill site, however, the gray clay occurs at a higher elevation than the Malpass typically is found as a stratigraphic unit beneath the Calapooyia surface on the valley floor (Balster and Parsons, 1968, 1969; Parsons et al., 1970). The Malpass Member is one of the least investigated and understood units of the Willamette Formation, and its extent and genesis are still debated. Reckendorf (1993) stated that the Malpass has been found on the next higher Bethel surface, which is on hillslopes below 80 m in elevation (Gelderman and Parsons, 1972). Gelderman (1970) observed Malpass-like clays above 106 meter during his research but found none on the Bethel unit or higher at his study 152 area near McCoy in Polk County. No other studies were found that documented the Malpass Member above an elevation of 80 meters, which would place it on the Brateng surface. Some believe the Malpass clay is from glacial meltwater deposits (Allison, 1953). Others speculate that part of the sediments could be from a local source, possibly from eroded fine-textured soils on the foothills and the claystones, siltstones, and tuffs of the Spencer Formation (Reckendorf, 1993). Gelderman (1970) speculated that the Malpass Member could be from material carried by turbidity currents from topographic highs to topographic lows. Balster and Parsons (1969) concluded the deposit was from the Willamette River systems. Glasmann and Kling (1980) and Glasmann et al. (1980) defined the Brateng surface that ranges from 80 to 122 meters in elevation and includes low convex hilltops, sideslopes, and toeslopes that have been mantled only by the Greenback Member. The Upper Brateng surface ranges from 86 to 122 meters in elevation and has a paleosol that is associated with the Spencer Formation. The Lower Brateng ranges in elevation from 80 to 86 meters and lacks the paleosol. Mineralogical Analysis Soil samples from selected horizons from Sites 1, 2, and 3 were analyzed by XRD. A sample of the 2Crt horizon of Site 1 (the site with no clay layers) was analyzed. The diffraction patterns (Fig. 6.3) show a mineral assemblage that includes smectite, vermiculite, mixed-layer vermiculite/mica, mica, well-ordered kaolinite, quartz, plagioclase feldspar and K-feldspar, and a trace of beidellite. Smectite was the dominant clay fraction. The difference in the peaks between the two size fractions indicate that a majority of the vermiculite and mica are in the >2 pm fraction as expected. 153 Figure 6.3. XRD patterns of the 2Crt sample from Site 1. (a) <1511m. (b) <21.1.m. (a) 1-2Crt <15um Mg54%RH [1] Mg-smectite, hydrated, n=3-7 [2] DIVERMICULITE .5 OIVERMICULJTE REICHW 0 [31 Ill to 2M#1 - (K,H30)Al2Si3A1010(OH)2 [4] Kaolinite <15urn Oriented Slide [5] Quartz, syn - Si02 [6] Albite, calcian, ordered - (Na,Ca)AI(Si,AI)308 [7] Microcline, intermediate - KAISi308 5000- 4000- 4 17') 0 3000- O) "a. 2000- 6 5 10003 0 11111 5.0 4 II )1 I 15 r 4 ti I 20 2-Theta(deg) 25 117,",1 I 30 1-2Crt <2um (b) 6000 1= Mg Glycol 2= K110C 3= K 54%RH 5000- 4= Mg54%RH 5= Mg Glycol 13- 1 4000- 0 3000- 2000- 1000- 5.0 10 15 20 2-Theta(deg) 25 30 I 1 154 Soils sampled at Site 2 were from the 2Btl, 3Bss, and 4BCt1 horizons. The 2Bt1 gray clay horizon <15 gm and <2 gm diffraction patterns (Fig. 6.4) indicate that the mineral assemblage includes smectite, beidellite, vermiculite, mica, ordered kaolinite, quartz, plagioclase feldspar, K-feldspar, amphibole, and goethite. The sharp mica and kaolinite peaks indicate well-ordered minerals that are not highly weathered. Beidellite followed by smectite are the dominant clay minerals. The less intense mica peaks in the <2 gm compared to the <15 gm fraction indicate some of the mica is in the >2 gm range. The olive clay 3Bss horizon sample from Site 2 (Fig. 6.5) has similar diffraction patterns as the 2Bt1 horizon. The main differences are that the 3Bss horizon has less mica, beidellite and vermiculite; some disordered kaolinite; no amphibole; and an additional peak at 3.88 A that could be muscovite. Site 2 soft bedrock 4BCt1 <15 gm and <2 gm diffraction patterns (Fig. 6.6) show a mineral assemblage that includes smectite, beidellite, vermiculite, mixed-layer vermiculite/ mica, mica, disordered kaolinite, quartz, plagioclase feldspar, K-feldspar, and goethite. The <2 gm patterns show that the clay mineralogy is very smectitic with only a trace of vermiculite, beidellite, and mica. The sharp, intense vermiculite and mica peaks in the <15 gm fraction show that the majority of these minerals are in the >2 gm fraction as expected in weathered bedrock. At Site 3, samples of the 2Bt, 3Bsstyl, 3Bssty2, and 4BCt horizons were analyzed. The diffraction patterns of the <15 gm and <2 gm fraction of the 2Bt gray clay horizon (Figs. 6.7) are very similar to the 2Bt1 Site 2 diffraction patterns with the exception of having disordered kaolinite. Both smectite and beidellite were the dominant clay mineral. 155 Figure 6.4. XRD patterns of the 2Bt1 gray clay horizon of Site 2. (a) <15pm. (b) <21.t.rn. (a) 6000- 2-2Bt1 <15um Mg54%RH [1] Mg-smectite, hydrated, n=3-7 [2] DIVERMICULJTE .5 DIVERMICUUTE REICHW 0 13) ltite -2M #1 - (K,H30)Al2Si3A1010(OH)2 141 Kaolinite <15um Oriented Slide [5] Quartz, syn - Si02 [6] Albite, caldan, ordered - (Na,Ca)Al(SI,A1)308 [7] Microcline, intermediate - KAISi308 5000- 1r) 4000- 3000(7) a) 6 2000- 10003 0 5.0 r ITT 10 r 15 20 2-Theta(deg) 25 30 2-2Bt1 <2um (b) 1= Mg Glycol 2= K110C 7500- 3= K 54%RH 4= Mg54%RH 5= Mg Glycol 5000= 0 to E' 2500- 5.0 10 15 20 2-Theta(deg) I 25 r 30 156 Figure 6.5. XRD patterns of the 3Bss olive clay horizon of Site 2. (a) <151.1.m. (b) <21..tm. 2-3Bss <15um Mg54%RH (a) [1] Mg- smectite, hydrated, n=3-7 [2] DIVERMICULITE .5 DIVERMICULITE REICHW 0 [3] - (K,H30)Al2Si3A1010(OH)2 [4] Kaolinite <15um Oriented Slide [5] Quartz, syn - Si02 [6] Albite, calcian, ordered - (Na,Ca)Al(Si,A1)308 [7] Microcline, intermediate - KAISi308 6000 5000 3 1.13' 4000 C 4 O 0 3000 a) 2000 7 1000 5.0 10 15 20 25 30 2-Theta(deg) 2-3Bss <2um (b) 4500- 1= Mg Glycol 2= K110C 4000- 3= K 54%RH 4= Mg54%RH 3500- 5= Mg Glycol 3000 ° 2500 2 2000a) C 15001-000 500- 5.0 10 15 20 2-Theta(deg) 2'5 30 157 Figure 6.6. XRD patterns of the 4BCt horizon of Site 2. (a) <154m. (b) <24m. (a) 2-4BCt1 <15um Mg54%RH 5000- [1] Mg-smectite, hydrated, n=3-7 [2] DIVERMICULITE .5 DIVERMICULITE REICHW 0 - (K,H30)Al2Si3A1010(OH)2 r31 [4] Kaolinite <15um Oriented Slide [5] Quartz, syn - S102 [6] Albite, caldan, ordered - (Na,Ca)Al(SLA1)308 [7] Microdine, intermediate - KAISi308 4000- = 3000- 00 4 2000-1 1000- 7 4 Nr6,7 II Ili 5.0 10 15 20 2-Theta(deg) mi 4 6 ki .11,1 I 25 7:16 e NM I 30 2-4BCt1 <2um (b) 1= Mg Glycol 2= K110C 3= K 54%RH 7500 4= Mg54%RH 5= Mg Glycol 2500 5.0 10 15 20 2-Theta(deg) 2'5 30 7 e t 158 Figure 6.7. XRD patterns of the 2Bt gray clay horizon of Site 3. (a) <15i.im. (b) (a) 3-2Bt <15um Mg54%RH [1] Mg-smectite, hydrated, n=3-7 [2] DIVERMICULITE .5 DIVERMICULITE REICHW 0 - (C,H30)Al2Si3A1010(OH)2 [3] [4] Kaolinite <15um Oriented Slide [5] Quartz, syn - S102 [6] Albite, calcian, ordered - (Na,Ca)Al(SLA0308 [7] Microcline, intermediate - KAISi308 50002 4000- O 0 3000rD 6 20007 5 10003 6 111-11II 5.0 4 , 15 T 25 20 2-Theta(deg) 30 3-2Bt <2um (b) 4500- 1= Mg Glycol 2= K110C 4000 3= K 54%RH 4= Mg54%RH 3500- 5= Mg Glycol c?, 3000= 0 0 2500ca, c 2000 15001000 500- 5.0 1110 1,111 15 2-Theta(deg) 1 i 1 r 25 I r r r r 30 r I 159 The 3Bsstyl, 3Bssty2 of Site 3 are horizons that contained white crystal clusters, white crystal strands, and clear crystals that started at a depth of 102 cm and are believed to be gypsum. The majority of the crystals are in the forther horizon. Bulk random powder mounts were examined (Chapter 2) on the 3Bsstyl that confirmed the crystals are gypsum. Diffraction patterns of oriented film mounts of the 3Bsstyl and 3Bssty2 (Fig. 6.8) <151.irn and <2 p.m fraction show almost identical patterns as the overlying 2Bt horizon but there are some differences. In the <2 pm fraction, there is less mica and kaolinite. Some differences in the <15 gm fraction of the 3Bsstyl horizon are the greater amount of quartz and an additional feldspar peak at 3.75 A. The differences in the <15 µm fraction of the 3Bssty2 horizon include: a smaller amount of quartz than in either the 2Bt or 3Bssty 1 samples; a great increase in the K-feldspar peak 3.27 A intensity; and an additional peak at 6.47 A that could be lepidocrocite. The 4BCt soft bedrock patterns of Site 3 (Fig. 6.9) look similar to the overlying clay horizons with the exception of an additional peak at 2.73 A that could be amphibole, a decrease in the relative quantity of beidellite, and the lack of the high K-feldspar peak. Interpretation Geomorphology The geomorphic surface of the upper transect at the study site is believed to be the Upper Brateng surface over a completely truncated paleosol. The Upper Brateng usually has the Spencer paleosol that is lacking on the Lower Brateng surface. However, the authors that defined the Brateng surfaces (Glasmann and Kling, 1980; Glasmann et 160 Figure 6.8. XRD patterns of the 3Bsstyl and 3Bssty2 olive clay horizon of Site 3. (a) <15pm. (b) <2pm. (a) 3- 3Bsstyl & 3Bssty2 <15um Mg54%RH 6000- 5000- S 4000 o 0 -5; (72 3000 o 2000- 1000- 5.0 (b) 6000 15 30 20 2-Theta(deg) 3- Bsstyl <2um 1= Mg Glycol 2= K110C 3= K 54%RH 5000- 4= Mg54%RH 5= Mg Glycol 4000- 0 l 3000- 2000- 1000 5.0 10 11111,1,, 15 20 2-Theta(deg) 1-V1 25 161 Figure 6.9. XRD patterns of the 4BCt horizon of Site 3. (a) <151im. (b) <2gm. (a) 3 -4BCt <15um Mg54%RH 5000- [1] Mg-smectite, hydrated, n=3-7 [2] DIVERMICUUTE .5 DIVERMICUUTE REICHW 0 [3] Illite-2M #1 - (K,H30)Al2Si3A1010(OH)2 [4] Kaolinite <15um Oriented Slide [5] Quartz, syn - Si02 [6] Albite, calcian, ordered - (Na,Ca)Al(Si,A1)308 [7] Microcline, intermediate - KAISi308 4000- 1r) S 3000 O 0 4 2000 7 7 1000 7 sz 4 3 0 ti 5.0 (b) 10 15 20 2-Theta(deg) 25 3-4BCt <2um 1= Mg Glycol 2= K110C 6000- 3= K 54%RH 4= Mg54%RH 5= Mg Glycol 5000- 5.0 ITIII 10 1'5 20 2-Theta(deg) 25 30 162 al., 1980) did note that soil variability in the Brateng is high, and that the paleosol above 86 m has been removed in some steep areas by erosion or other influences from the valley floods and truncated to some degree in most other areas. The Brateng surface typically has Ultic Haploxeralf and Aquic Xerochrept soils (Reckendorf, 1993) which was the original classification of the study site soils in the 1975 soil survey (Soil Survey Staff, 1975). The dark brown and grayish brown silt loam and clay loam surface soils which are 42 to 70 cm thick on the upper part of the transect are characteristic of the Greenback Member derived from late Lake Missoula floods. Glasmann (1979) found the Greenback deposition was 65-70 cm thick on upland sites and had an average particle-size fraction of 25% clay, 55.4% silt, and 19.6% sand. Figure 6.10 shows a comparison of an XRD diffraction pattern of the AB horizon (27-36 cm) from Site 2 with a diffraction pattern of the Greenback Member from the Bethel surface (J.R. Glasmann, 1997, Xray Diffraction Laboratoly, Dept. of Geosciences, Oregon State University, Corvallis, Oregon) taken from the OSU swine farm taken at 33-38 cm. The surface soils of the study area do not have interlayered chloritic intergrade and are less micaeous than the Bethel surface. The comparison shows that the Greenback Member is highly variable in mineralogy. Glasmann (1979) found that in the Greenback, mica peaks were more intense in samples from the valley floor compared to those taken at higher elevations and that in elevations above 80 m much of the Greenback material may be locally derived. In addition, erratics were found that are thought to be indicative of the Greenback Member. The Greenback has lightly weathered erratic rock fragments of small pebbles to boulders (Glasmann and Kling, 1980). The erratics include granite, quartzite, phyllite, slate, 163 Figure 6.10. XRD patterns of the AB horizon of Site 2 and a Greenback sample from the Bethel surface. (a) Site 2. (b) Bethel. 2-AB <2um Mg-Glycol (a) 3000- 2500- .17.) 2000 - c :5 1500a) 10001 500- 7 5.0 10 15 20 2-Theta(deg) I F 25 30 swine farm 33-38 cm <2um Mg-Glycol (b) 3000 2500 -111 2000 0 1500 1000 500 1111 5.0 10 15 20 2-Theta(deg) 25 30 164 schist, gneiss, basalt, and granodiorite (Allison, 1935). These rocks are foreign to the Willamette River watershed, which do not include Pleistocene continental till and outwash (Reckendorf, 1993). Erratics ranging from 3.5 cm to 11 cm in diameter were found in the study site trench located from 53 cm to 71 cm below the soil surface and above the upper gray clay layer. The erratics included fragments that were metasedimentary quartzite and large grain mafic with amphibole (J.R. Glasmann, 1997, Dept. of Geosciences, Oregon State University, Corvallis, Oregon personal communication). Other erratics were found as the sides of the trench sloughed in. These included altered volcanic tuff and a metamorphic rock high in biotite. The sites transect grades gently from the Upper Brateng surface to the Ingram unit. The Ingram surfaces include the higher of two flood plain levels of the Willamette River and landscapes associated with smaller streams (Balster and Parsons, 1968). The alluvium of the study site Ingram surface is from the latter. Three typical geomorphic surfaces are not represented at this study site due to incision by the Ingram unit. These geomorphic surfaces are the Lower Brateng, the Bethel (Gelderman, 1970) which is characterized by Greenback over Irish Bend, and the Calapooyia unit. Stratigraphy The mineralogical properties of clay horizons and weathered bedrock at the Witham Hill study site were investigated to identify stratigraphic units and possible source of material origin. Comparison of the mineralogy between horizons at Sites 1, 2, and 3 shows little lateral variation. Comparison of the relative amounts of clay minerals and quartz in the <2 p.m and <15 prn fractions between horizons of pedons at Site 2 and 3 are summarized in Tables 6.1 and 6.2. Relative Table 6.1. Selected peak intensities for Site 2. Horizons Smectite Beidellite j Vermiculite xx 2Bt1 xxx xxx x 3Bss xx x 4BCt1 xxx x xx Mica Kaolinite xxx xx x xx x xx Quartz xx xxx x Table 6.2. Selected peak intensities for Site 3. Horizons Smectite Beidellite 2Bt x xx xx 3Bsstyl xxx 3Bssty2 xx xxx 4BCt xxx x Vermiculite x x xx xx Mica Kaolinite Quartz xxx xx xx x xx xxx xx x x xxxx xx x 166 peak intensities between horizons, not within horizons, (columns, not rows) are denoted with X's with (x) the lowest and (xxxx) the highest relative quantity. Although the XRD patterns show that the mineralogy of the sampled horizons is very similar, there are differences that indicate discontinuities and that the clay horizons are not residual. The distribution of minerals does not indicate normal weathering horizonation. The relative peak intensities in Tables 6.1 and 6.2 and the overlaid diffraction patterns of Site 3 in Figure 6.11 show that the gray clay horizon (2Bt) is more micaceous than the underlying olive clay horizons (3Bss). The increase in mica higher in the profile is inconsistent with normal residual weathering were mica decreases with increased weathering higher in a soil profile. The soft bedrock (4BCt) horizon has lower amounts of quartz and a clay mineralogy that is much more smectitic than the overlying clay horizons indicating another lithologic discontinuity. Mineralogical similarities between the gray and olive clay horizons suggest that the two clay units may share a common origin. Overall, the diffraction analysis of the <15 gm patterns indicate that the mineralogy is rich in quartz and feldspars that are not severely weathered, which suggest relatively young soils. The possibility that the clays are sediments brought in with the Missoula Floods is unlikely since the >2 gm size vermiculite, mica, and feldspars in the clay horizons are not indicative of transported sediments. Micas have soft characteristics that allow them to be broken down during transport and sedimentation resulting in small particles (Fanning and Keramidas, 1977) while feldspars break down due to their easy cleavage (Williams et al., 1954). The >2 gm size vermiculite, mica, and feldspars do not confirm that the gray clay is not Malpass clay, since some researchers believe Figure 6.11. XRD patterns of the <2 m Mg-Glycol samples from horizons at Site 3. 50001 = 2Bt 2 = 3Bssty1 3 = 3Bssty2 4000- 4 = 4BCt 0 (-) 3000- a) 2000- 1000- 5.0 20 1I5 2-Theta(deg) 25 30 168 the Malpass is from local sources (Bolster and Parsons, 1969; Gelderman, 1970) or a mixture of local and extra-valley provenance (Reckendorf, 1993). However, comparison of an XRD diffraction pattern of the 2Bt gray clay horizon (Fig. 6.12) with a diffraction pattern of Malpass from the 2Bt1 horizon of a Dayton soil in Benton county (NRCS site identification number 920R003005) indicates dissimilar mineralogy. The clays are believed to be derived from local slope-related transport of colluvial material from the Spencer Formation after the paleosol had been eroded away. The clays do not have the kaolinitic mineralogy (Glasmann, 1979) associated with the Spencer Formation paleosol. Mass-wasting of the paleosol down to bedrock on the study site and once-higher landforms could have exposed the highly weatherable Spencer Formation. Erosion of the formation could have deposited clayey colluvial material on the footslopes. Baldwin (1981) traced the Eocene Spencer Formation through Corvallis and the surrounding areas. The upper part of the Spencer Formation is fine to medium-grained arkosic and micaceous sandstone, siltstone, claystones, and shale, with minor conglomerate and tuffs (Baldwin, 1981). According to Glasmann et al. (1980), the formation is friable and has lateral interfingering of different rock types resulting in lithologic variability over short distances. The authors noted that the fine-textured (clayey) beds have grayish brown to light olive gray colors and to a lesser extent can have yellowish brown to strong brown colors. Glasmann and Kling (1980) noted that the clay mineralogy of the clayey weathered tuff, and the paleosol that occurs over these tuffaceous beds show a dominance of smectite (beidellite). Based on mineralogy of the clay horizons, the colluvium had predominantly smectitic (partially beidellite) mineralogy and 169 Figure 6.12 XRD patterns of the 2Bt gray clay horizon of Site 3 and a 2Bt Malpass from a Dayton soil. (a) Site 3. (b). Dayton (a) 4500- 3-2Bt <2um Mg-Glycol 40003500- 3000- 00 2500.c55 a) 1500- 1000, 5000 1 5.0 10 -I I T 15 20 2-Theta(deg) 15 20 2-Theta(deg) 1 I- 1 I 25 30 25 30 Dayton Malpass <2um Mg-Glycol (b) 40003500- 3000= 2500- 0 2000 a) z 15001000- 500- I 5.0 I 10 170 probably developed from interfingered claystone and tuffaceous beds of the Spencer Formation. The truncated paleosol of the study site and higher surface could have been displaced by mass wasting caused by faulting disturbances and/or seismic activity before the late Pleistocene glacier-outburst floods. Glasmann and Kling (1980) found, based on electron micrographs of quartz-sand grains, that the paleosol is highly erodable and that much of the material of the Greenback in elevations above 80 m may be locally derived from the paleosol and saprolite of the Spencer Formation. On et al. (1992) summarized the likely events that took place during the valley's history. Renewed local uplifting, faulting, and folding occurred during the Pliocene epoch as major folds of the Coast Range block formed from the subduction of the Juan de Fuca plate beneath the North American plate. Two local "normal faults" that are due to folding and flexing of rocks from crustal extension and stretching are the Kings Valley and the Corvallis faults. Both faults run northeast by southwest and are located to the west and northwest of Corvallis (Fig 6.13). In addition, the Calapooia fault runs to the northeast of Corvallis and the Owl Creek fault to the east. The faults show movement into the Pleistocene time. Periods of rapid subsidence during this time would have caused catastrophic earthquakes. Evidence of large-scale seismic activity as late as the Holocene period has been discovered in buried coastal swamps. Later, during the series of Pleistocene floods, high-energy floodwaters with hydraulic surging and ebbing could have completely reworked the homogenized colluvium. The shoreline (Site 1) was left striped down to the sandstone and the clayey colluvium settled with the distinct tapering at its uppermost limits. Presumably this series of events occurred during two or more episodes of instability to create the 171 Figure 6.13. Willamette Valley faults (from Orr et al, 1992). oc, 2G Nytk. le 6 Hillsboro X Pt, AN. X.,\C"I'' ? Lake 0..0 \?4 C.4.4mt ':Inumin.win. Portland *Beaverton P wivartiette basin IAN ottlNe. - \trt Woodburn Silverton s) WC, 172 lower olive clay horizons and the upper gray clay horizon before the final flooding phase that deposited the Greenback Member. This would account for the occurrence of higher mica content in the upper gray clay horizon than in the lower olive clay horizons. It could be postulated that the olive clay layers were reworked by the fluctuating shoreline of the flood event that deposited the Irish Bend sediments. Following this deposition, a period of stability ensued that led to the formation of an argillic horizon in the Irish Bend Member that later was partially truncated by additional flood events (Parsons et al., 1968; Balster and Parsons, 1969). This period of stability followed by subsequent flood events may also account for the less ordered mica in the olive clays than in the gray clay and the clay films found in the lower olive clay horizons (3Bsstyl and 3Bssty2) but not in the upper olive clay horizons. Yet another flood, perhaps the one that was responsible or partly responsible for deposition of the Malpass Member, could have reworked colluvial or side-valley alluvial material that had eroded between flooding events resulting in the gray clay layer (2Bt1 and 2Bt) at Sites 2 and 3. However, this scenario would place fluctuating lake heights between 96 and 98 m in absolute elevation, which is higher in elevation than found by Glasmann (1979). The author found almost complete erosion of the Spencer paleosol between 80 and 86 m (Lower Brateng surface), presumably by lakeshore erosion processes when the Irish Bend Member was deposited, and very little erosion of the paleosol above 86 m (Upper Brateng surface). 173 Summary Landscape and soil development has been from a complex sequence of local and regional processes. The results of the investigation support the presence of four distinct stratigraphic units and suggest that the clay horizons are colluvial material from the eroded bedrock of the Spencer Formation. Speculation was made about mass-wasting of the paleosol associated with the formation an about the tapering of the two clay units on the hillslope from fluctuating shorelines of lakes created during the many Missoula Flood events. Further analysis to look at quartz-sand grain morphology (Glasmann and Kling, 1980) with scanning electron microscopy (SEM) would be needed to confirm local and transported mineralogy and grain characteristics. In addition, radiocarbon dating and the isotopic 018 signature would aid in finding the age of the soil materials and identifying the source (Birkeland, 1984) 174 Chapter 7 SUMMARY AND CONCLUSION The soil morphology of Site 1 suggests a mostly aerobic environment within the upper 65 cm. High chromas and few iron redox features indicate very short periods of saturation and reductive conditions. The soil morphology of Sites 2, 3, and 4 suggests episodic saturation and anaerobic and iron reducing environments that lasts for extensive periods of time. Redoximorphic concentrations within 7cm of the soil surface in soils of Pits 2 and 3 and concentrations at the surface in soils of Pit 4 indicate that iron and manganese are being reduced and oxidized high within the soil profile. Zones of depletion over clay horizons in Pits 2 and 3 and evidence of a discontinuity suggest that clays are restricting vertical water movement and creating a seasonal perched water table. The hydrologic data and redox data correlated well with the morphological properties for each of the four pedons. Short one-week episodic saturation events that averaged around 16 cm beneath the surface of Site 1 soils correspond to the occurrence of iron concretions less than 0.5 mm in diameter. Mean seasonal water table levels for Sites 2 and 3 (12.6 cm and 9.8 cm respectively) corresponded to horizons that had at least 30% high value and low chroma (4/2) matrix colors and many distinct iron masses. The near surface mean seasonal water table in the soils of Site 4 is associated with oxidized rhizospheres found at the surface and many distinct iron masses found at 6 cm beneath the soil surface. The hydrologic, redox potential, and soil temperature data provide documentation that the soils of Sites 2, 3, and 4 meet the conditions in the hydric soil definition for "saturated, flooded, or ponded long enough during the growing season to develop anaerobic 175 conditions in the upper part." Hydrologic data indicate that water tables remained fairly stable and soils stayed saturated high in the soil profiles for a majority of the wet season (October June) at Sites 2, 3, and 4. The data show that the soils were continuously saturated at some depth within 30 cm from the soil surface for 19-20 weeks at Site 2, 19-24 weeks at Site 3, and 23-25 weeks at Site 4. The growing season had no bearing on the time of saturation since biological zero (5°C at 50 cm) was never reached. Hydrologic data indicate that the hydrologic regime on the upper footslope of Witham Hill is the result of seasonal perched water tables and episaturation as the result of a discontinuity consisting of slowly permeable clays. On the lower footslope, Site 4 hydrologic data suggest temporary episaturation that gives way to endosaturation. This hydrologic regime is believed to be the result of alluvial deposition of clays on a lower drainage landscape. Reduction-oxidation potentials indicate varying reducing environments within the upper 30 cm at Sites 2, 3, and 4. Anaerobiosis began in November and December between two weeks before to two weeks after the onset of continuous saturation at all the sites. Soils at Site 2 had the lowest mean water table (12.6) and the longest lag time between continuous saturation and the onset of anaerobiosis and iron reduction, whereas Site 4 soils had the highest mean water table (5.5 cm) and the shortest lag time. Extended periods of iron reduction occurred three to four weeks after onset of continuous saturation at Site 2, after one week at Site 3, and from two weeks before to one week after at Site 4. Reduction continued for 21 to 30 weeks into the month of May at Sites 2 and 3 and into June at Site 4. Although morphological properties generally concurred with hydrologic and redox potential data, Site 2 and Site 3 morphological 176 characteristics did not correspond with any of the fourteen applicable indicators in the Field Indicators of Hydric Soils in the U.S., Version 3.2. Commonly accepted factors known to affect the development or visibility of characteristic morphologies (parent materials that are reddish or grayish; dark soils; soils with high pH or low organic matter content; low soil temperatures; and aerated groundwater) were not factors in the study site soils. In addition, the soils of Site 2 came closer to meeting some indicator criteria than did Site 3 soils, even though the soils of Site 2 had a lower mean seasonal water table (12.5 cm versus 9.8 cm); shorter duration of saturation (19 and 20 weeks versus 19 and 24 weeks); and shorter duration of iron reduction (21 and 23 weeks versus 24 and 25 weeks). Site 2 soils failed one indicator only because the matrix was 3+/2 versus the specified 3/2. The two major factors that prevented positive outcomes for soils of Sites 2 and 3 were the inability to round colors that fell between color chips and layer thickness requirements. A third factor was the requirement that at least 60% of a designated layer have a depleted matrix. The Witham Hill wet soil study site was visited in July 1997 by a group from the national Wet Soils Monitoring Project, members of the National Technical Committee for Hydric Soils, and members of the Field Indicator Committee. The field trip resulted in a change to the F3 Depleted Matrix indicator to incorporate the morphological characteristic of soils at Site 3. The additional specification, which decreases the layer thickness requirement under certain conditions, is in the Field Indicators of Hydric Soils in the United States, Version 4 issued in March 1998. The discussion during the field trip about the Site 2 soils did not evolve beyond soil color notation. A majority of the group felt that the matrix color of the A3 horizon at Site 2 was 3/2 versus the 3+/2 177 originally noted. The differences in opinions about the "correct" Munsell color highlight the problem of trying to be exact with a qualitative parameter that is affected by many factors, not the least of which is personal judgement. Version 4 addresses the problem of soil notation by changing the way colors that fall between Munsell color chips are applied. Values can now be rounded to the nearest color chip but chromas cannot. The change enables the A3 horizon at Site 2 with the debated 3+/2 matrix color to meet the F6 indicator that required a _.3/2 matrix. However, it is believed that further consideration should be given to rounding not only value but also chroma. The B/E and E/B horizons of Pits 2 and 3 present a case for either reviewing the requirement that a depleted matrix make up 60% of a horizon for many indicators or consider developing a new regional indicator to cover the observed morphology. Other factors besides duration of saturation and reduction may need to be investigated. There may be physical properties or chemical processes that influence redistribution or iron without removal and/or net loss of iron from a horizon, as.was the situation at the study site. The B/E and E/B horizons located directly over the perching clay horizons had iron reduction occurring from 21 to 25 weeks per wet season but had iron oxide (Fed) contents that indicated no net loss of Fe (II) iron by translocation out of the horizons. Once the soils of Sites 2, 3, and 4 were determined to be hydric soils, two questions important to land management surfaced were apparent: (1) are areas of the study site wetlands and (2) what conditions and events resulted in the hydrologic regime on the hillslope. Wetlands have three essential characteristics and criteria: wetland hydrology, hydric soils, and hydrophytic vegetation. Review of 178 the criterion for wetland hydrology and hydrophytic vegetation resulted in confirmation of wetland characteristics at Sites 2, 3, and 4 based on saturation within the 30 cm of the soil surface and the 50% dominance measure. The hydrophytic vegetation criterion was satisfied at Sites 2 and 3 by plant communities that are dominated by more than 50 percent facultative FAC species and at Site 4 by communities that are dominated by more than 50 percent FACW species. Geomorphic processes that resulted in the present hydrologic conditions on the hillslope were investigated by examining past research on Willamette Valley geomorphic surfaces and geologic history, and by performing mineralogical analyses on the study site soils. Mineralogical properties of the surface horizon, clay horizons, and weathered bedrock were investigated to identify stratigraphic units and possible sources of material origin. The results of the mineralogical analysis support the presence of four distinct stratigraphic units on the upper transect with the upper unit identified as the Greenback Member of the Willamette Formation. The geomorphic surface of the upper transect at the study site is believed to be the Upper Brateng over the Spencer Sandstone Formation. The paleosol that is usually associated with the Upper Brateng is believed to have been removed by catastrophic local events. The lower transect is a poorly drained soil on a younger alluvial Ingram surface created by drainageway incision and deposition on older surfaces. Mineral analysis suggests that the two clay units and the sandstone at the study site share a common origin. However, morphological characteristics of the clay horizons and mineralogical differences indicate that the clay horizons are not residual, and a discontinuity exists between the lower clay unit and the sandstone. 179 The >2 i.tm vermiculite and mica in the clay units indicate local slope-related transport. The clay horizons are thought to be colluvial material from erosion of interfingered clayey beds and tuffaceous beds of the Spencer Formation sandstones after the paleosol had been removed. Speculation was made about mass wasting of the paleosol and about the tapering of the two clay units. Mass wasting caused by faulting disturbances and/or seismic activity could have displaced the paleosol and once higher surface of the study site. Late Pleistocene glacier-outburst floods could have reworked the colluvial fill on the footslope to form the clay units. If these factors and events can be considered a reasonable speculation, many regional and localized components and conditions came together to create the complex geomorphology, landscape, and soils of the study area. 180 LITERATURE CITED Allison, I.S. 1935. Glacial erratics in Willamette Valley. Bulletin of the Geological Soc. Am. 46:615-632. Allison, I.S. 1953. Geology of the Albany quadrange, Oregon. Oregon Dept. Geol. and Min. Ind. Bull. 37. pp. 1-18. Atkinson, T.C. 1978. Techniques for measuring subsurface flow on hillslopes. p. 73-120. In M.J. Kirkby (ed) Hills lope hydrology. John Wiley 85 Sons, New York. Austin, W. 1994. Duration of saturation and redox potentials in selected Willamette Valley soils. M.S. Thesis. Oregon State Univ., Corvallis, Oregon. Austin, W. 1997. Colormetric field indicators of dissolved oxygen and ferrous iron. Poster 231. p. 84. In Agronomy Abstracts. ASA, Madison, WI. Baldwin, E.M. 1981. Geology of Oregon. 3rd ed., Kendall/Hunt Publishing Co., Dubuque, Iowa. Balster, C.A. and R.B. Parsons. 1968. Geomorphology and soils, Willamette Valley, Oregon. Oregon Agric. Exp. Stn. Special Report No. 265. Balster, C.A. and R.B. Parsons. 1969. Late pleistocene stratigraphy, Southern Willamette Valley, Oregon. Northwest Science 43:116129. Barron, V., and J. Torrent. 1984. Influence of aluminum substitution on the color of synthetic hematites. Clays and Clay Minerals 32:157-158. Birkeland, P.W. 1984. Soils and geomorphology. Oxford University Press, Oxford, N.Y. Blume, H.P. 1988. The fate of iron during soil formation in humidtemperate environments. p. 749-777. In J .W Stucki et al. (eds.) Iron in Soils and Clay Minerals. D. Reidel, Dordrecht. 181 Boersma, L., G.H. Simonson and D.G. Watts. 1972. Soil morphology and water table relations: II. Correlation between annual water table fluctuations and profile features. Soil Sci. Soc. Amer. Proc. 36:649-653. Bohn, H.L. 1971. Redox potentials. Soil Science 112:39-45. Bohn, H.L., B.L. McNeal, and G.A. O'Connor. 1985. Soil chemistry. John Wiley & Sons, Inc., New York. Bonner, F.T. and C.W. Ralston. 1968. Oxidation-reduction potential of saturated forest soils. Soil Sci. Soc. Amer. Proc. 32:111-112. Bouma, J. 1973. Use of physical methods to expand soil survey interpretations of soil drainage conditions. Soil Sci. Soc. Am. Proc. 37:413-421. Bouma, J., F.G. Baker, and P.L.M. Veneman. 1974. Measurements of water movement in soil pedons above the water table. University of Wisconsin-Madison. College of Agriculture and Life Sciences. Information Circular Number 27. Brindley, G.W. and G. Brown. 1980. Crystal structure of clay mineral and their x-ray identification. Monograph 5:5. Mineralogical Society, London. Cady, J.G. 1960. Mineral occurrence in relation to soil profile differentiation. 4:418-424. In 7th Int. Congress of Soil Sci., Madison, WI. Cogger, C.G. and P.E. Kennedy. 1992. Seasonally saturated soils in the puget lowland I. saturation, reduction, and color patterns. Soil Science 153(6):421-433. Cogger, C.G., P.E. Kennedy and D. Carlson. 1992. Seasonally saturated soils in the Puget lowland II. Measuring and interpreting redox potentials. Soil Science 154(1):50-58. Collins, J.F. and S.W. Buol. 1970a. Effects of fluctuations in the EhpH environment on iron and/or manganese equilibria. Soil Science 110:111-118. Collins, J.F. and S.W. Buol. 1970b. Patterns of iron and manganese precipitation under specified Eh-pH conditions. Soil Science 110:157-162. 182 Couto, W., C. Sanzonowicz, and A.De 0. Barcellos. 1985. Factors affecting oxidation-reduction processes in an Oxisol with a seasonal water table. Soil Sci. Soc. Amer. J. 49:1245-1248. Cowardin, L.M., V. Carter, F.C. Go let, and E.T. La Roe. 1979. Classification of wetlands and deepwater habitats of the United States. U.S. Fish & Wildlife Service Pub. FWS/OBS-79/31. U.S. Gov. Print. Office, Washington, DC. Daniels, R.B., E.E. Gamble, and S.W. Buol. 1973. Oxygen content in the ground water of some North Carolina Aquults and Udults. p. 153-166. In Bruce, R.R. et al. (eds.) Field soil water regime. SSSA Spec. Publ. 5. Madison, WI. Daniels, R.B., E.E. Gamble, and L.A. Nelson. 1971. Relations between soil morphology and water-table levels on a dissected North Carolina coastal plain surface. Soil Sci. Soc. Am. Proc. 35:781-784. Daniels, R.B., G.H. Simonson and R.L. Handy. 1960. Ferrous iron content and color of sediments. Soil Science 91(6) :378-382. De Coninck, F. 1980. Major mechanisms in formation of spodic horizons. Geoderma 24:101-128. de Kimpe, C.R. 1993. Clay and silt analysis. p. 719-730. In M.R. Carter (ed.) Soil Sampling and Methods of Analysis. Canadian Soc. of Soil Sci., Lewis Publishers, Boca Raton, FL. Dobos, R.R., E.J. Ciolkosz and W.J. Waltman. 1990. The effect of organic carbon, temperature, time, and redox conditions on soil color. Soil Science 150(2):506-512. Doner, H.E. and W.C. Lynn. 1977. Carbonate, halide, sulfate, and sulfide minerals. p. 75-98. In J.B. Dixon and S.B. Weed (eds.) Minerals in soil environments. Soil Sci. Soc. Am., Madison, WI. Dudal, R. 1992. Wet soils. p. 1-4. In J.M. Kimble (ed.) Proceedings of the eighth international soil correlation meeting (VII ISCOM): Characterization, classification, and utilization of wet soils. USDA, Soil Conservation Service, National Soil Survey Center, Lincoln, NE. 183 Environmental Laboratory. 1987. Corps of Engineers wetland delineation manual. Technical Report Y-87-1, U.S. Army Engineer Waterways Experiment Station, Vicksburg, MS. Evans, C.V. and D.P. Franzmeier. 1986. Saturation, aeration, and color patterns in a toposequence of soils in north-central Indiana. Soil Sci. Soc. Am. J. 50:975-980. Fanning, D.S. and V.Z. Keramidas. 1977. Micas. p. 195-258. In J .B . Dixon and S.B. Weed (eds.) Minerals in soil environments. Soil Sci. Soc. Am., Madison, WI. Federal Interagency Committee for Wetlands Delineation. 1989. Federal manual for identifying and delineating jurisdictional wetlands. U.S. Army Corps of Engineers, U.S. Environmental Protection Agency, U.S. Fish and Wildlife Service, and USDA Soil Conservation Service. Washington, DC. Cooperative Technical Publication. Federal Register. 1982. "Title 33: Navigation and navigable waters; Chapter 2. Regulatory Programs of the Corps of Engineers". U.S. Government Printing Office, Washington, DC. 47(138), 31, 810. Federal Register. July 13, 1994. Changes in hydric soils of the United States. Washington, DC. Foth, H.D. and B.G. Ellis. 1988. Soil fertility. John Wiley & Sons, New York. Franzmeier, D.P., J.E. Yahner, G.C. Steinhardt and H.R. Sinclair Jr. 1983. Color patterns and water table levels in some Indiana soils. Soil Sci. Soc. Am. J. 47:1196-1202. Freeze, R.A. and J.A. Cherry. 1979. Groundwater. Prentice-Hall, Inc., Englewood Cliffs, N.J. Gambrell, R.P. and W.H. Patrick Jr. 1978. Chemical and microbiological properties of anaerobic soils and sediments. p. 375-423. In D.D. Hook and R.M.M. Crawford (eds.) Plant life in anaerobic environments. Ann Arbor Science Publishers Inc., Ann Arbor, MI. Gelderman, F.W. 1970. Willamette and associated soils on late pleistocene geomorphic surfaces, Polk County, Oregon. M.S. Thesis. Oregon State Univ., Corvallis, Oregon. 184 Gelderman, F.W. and R.P. Parsons. 1972. Argixerolls on late pleistocene surfaces in northwestern Oregon. Soil Sci. Soc. Amer. Proc. 36:335-341. Glasmann, J.R. 1979. The geomorphology and stratigraphy of Elkins road watershed. M.S. Thesis. Oregon State Univ., Corvallis, Oregon. Glasmann, J.R., R.B. Brown, and G.F. Kling. 1980. Soil-geomorphic relationships in the western margin of the Willamette Valley, Oregon. Soil Sci. Soc. Am. J. 44:1045-1052. Glasmann, J.R. and G.F. Kling. 1980. Origin of soil materials in foothill soils of Willamette Valley, Oregon. Soil Sci. Soc. Am. J. 44:123-130. Gotoh, S. and W.H. Patrick Jr. 1972. Transformation of manganese in a waterlogged soils as affected by redox potential and pH. Soil Sci. Soc. Amer. Proc. 36:738-742. Gotoh, S. and W.H. Patrick Jr. 1974. Transformation of iron in a waterlogged soil as influenced by redox potential and pH. Soil Sci. Soc. Amer. Proc. 38:66-71. Hallmark, C.T. 1985. Family mineralogy of soils with free carbonates and gypsum. p. 53-60. In . J.A. Kittrick (ed.) Mineral classification of soils. SSSA Spec. Publ. 16., Madison, WI. Hillel, D. 1980. Fundamentals of soil physics. Academic Press, Inc., San Diego, CA. HQUSACE. 1992. Clarification and interpretation of the 1987 manual. Memorandum CECW-OR March 6. US Army Engineer Waterways Experiment Station, Vicksburg, MS. Hudnall, W.H. and L.P. Wilding. 1992. Monitoring soil wetness conditions in Louisiana and Texas. p.135-147. In J . M. Kimble (ed.) Proceedings of the eighth international soil correlation meeting (VII ISCOM): Characterization, classification, and utilization of wet soils. USDA, Soil Conservation Service, National Soil Survey Center, Lincoln, NE. Jones, R.H. 1966. Oxidation-reduction potential measurement. ISA Journal Nov. 1966, 40-44. 185 Kelsey, P.D. and R.G. Hootman. 1992. Relationships between water tables, plant communities, and hydric soils: west Chicago prairie, West Chicago, Illinois. Soil Survey Horizons 33(3):53-58. Knapp, B.J. 1978. Infiltration and storage of soil water. p. 43-72. In M.J. Kirkby (ed) Hills lope hydrology. John Wiley & Sons, New York. Kollmoren Instruments Corporation. 1994. Munsell soil color charts. Macbeth Division, New Windsor, NY. Mausbach, M.J. 1994. Classification of Wetland Soils for Wetland Identification. Soil Survey Horizons 35(1):17-25. Mausbach, M.J. and J.L. Richardson 1994. Biogeochemical processes in hydric soil formation. Current Topics in Wetland Biogeochemistry 1:68-127. McDaniel, P.A., G.R. Bathke, S.W. Buol, D.K. Cassel and A.L. Fa len. 1992. Secondary manganese/iron ratios as pedochemical indicators of field-scale throughflow water movement. Soil Sci. Soc. Am. J. 56:1211-1217. McDowell, P.F. 1991. Quaternary stratigraphy and geomorphic surfaces of the Willamette Valley, Oregon. pp 156-164. In geology of north america, quaternary nonglacial geology. Vol K-2. Geological Soc. Am., Inc. McLean, E.O. 1982. Soil pH and lime requirements. p. 199-224. In A.L. Page et al. (eds.) Methods of soil analysis, Part 2. Chemical and microbiological properties. ASA, SSSA, Madison, WI. Meek, B.D., A.J. MacKenzie and L.B. Grass. 1968. Effects of organic matter, flooding time, and temperature on the dissolution of iron and manganese from soil in situ. Soil Sci. Soc. Amer. Proc. 32:634-638. Meek, B.D. and L.H. Stolzy. 1978. Short-term flooding. p. 351-373. In D.D. Hook and R.M.M. Crawford (eds.) Plant life in anaerobic environments. Ann Arbor Science. Ann Arbor, MI. Moore, D.M. and R.C. Reynolds Jr. 1989. X-ray diffraction and the identification and analysis of clay minerals. Oxford University Press, Oxford, N.Y. 186 National Research Council. 1995. Wetlands: Characteristics and boundaries. National Academy Press, Washington, DC. National Technical Committee for Hydric Soils. 1996. Minutes. Annual Meeting. August 27-29, 1996, Palmer, AK. Norrish, K. and R.M. Taylor. 1961. The isomorphous replacement of iron by aluminium in soil goethites. J. Soil Science 12:294-306. Oades. 1988. The retention of organic matter in soils. Biogeochemistry 5:35-70. Orr, E.L., W.N. Orr, and E.M. Baldwin. 1992. Geology of Oregon. 4th ed. Kendall/Hunt Publ. Co., Dubuque, IA. Parsons, R.B., C.A. Balster, and A.O. Ness. 1970. Soil development and geomorphic surfaces, Willamette Valley, Oregon. Soil Sci. Soc. Amer. Proc. 34:485-491. Parsons, R.B., G.H. Simonson, and C.A. Balster. 1968. Pedogenic and geomorphic relationships of associated aqualfs, albolls, and xerolls in western Oregon. Soil Sci. Soc. Amer. Proc. 32:556-563. Patrick Jr, W.H. and R.E. Henderson. 1981. Reduction and reoxidation cycles of manganese and iron in flooded soil and in water solution. Soil Sci. Soc. Am. J. 45:855-859. Patrick Jr, W.H. and A. Jugsujinda. 1992. Sequential reduction and oxidation of inorganic nitrogen, manganese, and iron in flooded Soil. Soil Sci. Soc. Am. J. 56:1071-1073. Ponnamperuma, F.N. 1972. The chemistry of submerged soils. Advances in Agronomy. 24:29-96 Ponnamperuma, F.N., E.M. Tianco, and T. Loy. 1967. Redox equilibria in flooded soils: I. The iron hydroxide systems. Soil Science 103(6):37-382. Ponnamperuma, F.N., E.M. Tianco, and T. Loy. 1969. Redox equilibria in flooded soils: II. The manganese oxide systems. Soil Science 108(1):48-57. 187 Reckendorf, F. 1993. Geomorphology, stratigraphy, and soil interpretations, Willamette Valley, Oregon. pp. 178-200. In J . M. Kimble (ed) Proceedings of the 8th int. soil management workshop: Utilization of soil survey information for sustainable land use. USDA. Washington, DC. Reed, R.T. 1988. National list of plant species that occur in wetlands: National summary. U.S. Fish and Wildlife Service. Biol. Report 88(24). U.S. Gov. Print. Office, Washington, DC. Richardson, J.L. and R.B. Daniels. 1993. Stratigraphic and hydraulic influences on soil color development. Soil Sci. Soc. Am. Special Pub. 31:109-125. Richardson, J.L., L.P. Wilding, and R.B. Daniels. 1992. Recharge and discharge of groundwater in the aquic moisture regime illustrated with flownet analysis. p. 212-219. In J . M. Kimble (ed.) Proceedings of the eighth international soil correlation meeting (VII ISCOM): Characterization, classification, and utilization of wet soils. USDA, Soil Conservation Service, National Soil Survey Center, Lincoln, NE. Ritsema, C.J. and J.E. Groenenberg. 1993. Pyrite oxidation, carbonate weathering, and gypsum formation in a drained potential acid sulfate soil. Soil Sci. Soc. Am. J. 57:968-976. Rowell, D.L. 1981. Oxidation-reduction. p. 401-461. In D.J. Greenland and M.H.B. Hayes (eds.) The chemistry of soil processes. John Wiley 8s Sons Ltd., . Ruhe, R.V. 1975. Geomorphology. Houghton Mifflin Co., Boston. Schwertmann, U. 1988. Occurrence and formation of iron oxides in various pedoenvironments. pp. 267-308. In J .W Stucki et al. (eds.) Iron in soils and clay minerals. D. Reidel, Dordrecht. Schwertmann, U. 1993. Relations between iron oxides, soil color, and soil formation. p. 51-69. In Soil color. Soil Sci. Soc. Am. Special Publ. 31, Madison, WI. Schwertmann, U. and R.M. Taylor. 1989. Iron oxides. pp. 379-438. In J.B. Dixon 86 S.B. Weed (eds.) Minerals in soil environments. 2nd ed. SSSA Book Ser. No. 1. Soil Sci. Soc. Am., Madison, WI. 188 Soil Conservation Service. 1994. National food security act manual. Title 180. USDA Soil Conservation Service, U.S. Gov. Print. Office, Washington, DC. Soil Survey Division Staff. 1993. Soil survey manual. USDA Handbook No. 18. US Govt. Print. Office, Washington, DC. Soil Survey Laboratory Staff. 1995. Soil survey laboratory information manual. USDA-NRCS Soil Survey Invest. Report No. 45. US Govt. Print. Office, Washington, DC. Soil Survey Staff. 1975a. Soil survey of Benton County area, Oregon. USDA, Soil Conservation Service, US Govt. Print. Office, Washington, DC. Soil Survey Staff. 1975b. Soil Taxonomy: A basic system of soil classification for making and interpreting soil surveys. Soil Conservation Service. USDA Agriculture Handbook No. 436. US Govt. Print. Office, Washington, DC. Soil Survey Staff. 1996. Mineralogy. p. 351-360,662. In Soil survey laboratory methods manual. USDA Soil Survey Investigations Report No. 42. US Govt. Print. Office, Washington, DC. Snavely, Jr., P.D. and H.C. Wagner. 1963. Tertiary geologic history of Western Oregon and Washington. Report of Investigations No. 22. Department of Conservation, Olympia, WA. Stephens, D.B. 1996. Vadose zone hydrology. CRC Press, Boca Raton, FL. Szogi, A.A. and W.H. Hudnall. 1990. Measurement of redox potentials in soils with permeanently installed platinum electrodes. Manuscript 91-09-5227. Louisiana Agric. Exp. Stn. Taylor, G.H. and A. Bartlett. 1993. The climate of Oregon, climate zone 2 Willamette Valley. Special Report 914. Agri. Exp. Station, Oregon State University, Corvallis, OR. Theisen, A.A. and M.E. Harward. 1962. A paste method for preparation of slides for clay mineral identification by x-ray diffraction. Soil Sci. Soc. Am. Proc. 26:90-91. Tiner, R.W. 1991. The concept of a hydrophyte for wetland identification. BioScience 41(4): 236-247. 189 Towe, K.M. 1974. Quantitative clay petrology: The trees but not the forest? Clays and Clay Minerals 22:375-378. Torrent, J., U. Schwertmann, H. Fechter and F. Alferez. 1983. Quantitative relationships between soil color and hematite content. Soil Science 136(6):354-358. Turner, F.T. and W.H. Patrick Jr. 1968. Chemical changes in waterlogged soils as a result of oxygen depletion. Trans. 9th Intern. Congress Soil Sci. Adelaide, Australia. 4:53-65. US Army Corps of Engineers. 1996. Preliminary investigations of hydric soil hydrology and morphology in the United States. Wake ley, J.S., S.W. Sprecher, and W.C. Lynn (eds.). Technical Report WRP-DE-13, U.S. Army Engineer Waterways Experiment Station, Vicksburg, MS. US Department of Agriculture, Natural Resources Conservation Service. 1995. Proceedings of the national cooperative soil survey conference. San Diego, CA. July10-14. USDA, US Govt. Print. Office, Washington, DC. US Department of Agriculture, Natural Resources Conservation Service. 1996. Field indicators of hydric soils in the United States. G.W. Hurt, Whited, P.M. and Pringle, R.F. (eds). In Cooperation with the National Technical Committee for Hydric Soils, Washington, DC. US Department of Agriculture, Natural Resources Conservation Service. 1998. Field indicators of hydric soils in the United States. G.W. Hurt, P.M. Whited, and R.F. Pringle (eds). USDA, NRCS, Fort Worth, TX. US Department of Agriculture, Soil Conservation Service. 1985. Hydric soils of the United States. In Cooperation with the National Technical Committee for Hydric Soils, Washington, DC. US Department of Agriculture, Soil Conservation Service. 1991. Hydric soils of the United States. In Cooperation with the National Technical Committee for Hydric Soils, Washington, DC. van Breemen, N. 1982. Genesis, morphology, and classification of acid sulfate soils in coastal planes. p. 95-_. In J.A. Kittrick et al. (eds.) Acid sulfate weathering. Soil Sci. Soc. Am. Spec. Pub1.10. Madison, WI. 190 van Breemen, N. 1987. Effects of redox processes on soil acidity. Netherlands J. of Agri. Science 35:271-279. van Breemen, N. 1988a. Effects of seasonal redox processes involving iron on the chemistry of periodically reduced soils. p. 797-809. In J.W. Stucki et al. (eds.) Iron in Soils and Clay Minerals. D. Reidel, Dordrecht. van Breemen, N. 1988b. Long-term chemical, mineralogical, and morphological effects on iron-redox processes in periodically flooded soils. p. 811-823. In J.W. Stucki et al. (eds.) Iron in Soils and Clay Minerals. D. Reidel, Dordrecht. Veneman, P.L.M. and E.W. Pickering. 1983. Salt bridge for field potential measurements. Commun. in Soil Sci. Plant Anal. 14(8):669-677. Veneman, P.L.M., M.J. Vepraskas and J. Bouma. 1976. The physical significance of soil mottling in a Wisconsin toposequence. Geoderma 15:103-118. Vepraskas, M.J. 1994. Redoximorphic features for identifying aquic conditions. N. Carolina Agricultural Research Service. Tech. Bull. No. 301. North Carolina State Univ., Raleigh, NC. Vepraskas, M.J., F.G. Baker, and J. Bouma. 1974. Soil mottling and drainage in a mollic hapludalf as related to suitability for septic tank construction. Soil Sci. Soc. Am. Proc. 38:497-501. Vepraskas, M.J. and L.P. Wilding. 1983. Aquic moisture regimes in soils with and without low chroma colors. Soil Sci. Soc. Am. J. 47:280-285. Whipkey, R.Z. and K.J. Kirkby. 1978. Flow within the soil. p. 121144. In M.J. Kirkby (ed) Hillslope hydrology. John Wiley &Sons, New York. Willet, I.R., and R.B. Cunningham. 1983. Influence of sorbed phosphate on the stability of ferric hydrous oxide under controlled pH and Eh conditions. Aust. J. Soil Res. 21:301-308. Williams, H., F.J. Turner, and C.M. Gilbert. 1954. Petrography. W.H. Freeman, San Francisco, CA. 191 Zaslaysky, D. and A.S. Rogowski. 1969. Hydrologic and morphologic implications of anisotropy and infiltration in soil profile development. Soil Sci. Soc. Amer. Proc. 33:594-599. 192 APPENDICES 193 Appendix A NSSL Soil Characterization Data *** S960R-003-001 PRIMARY CHARACTERIZATION DATA (BENTON COUNTY, OREGON *** PRINT DATE 07/23/97 ; FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT FINE-SILTY, MIXED, SUPERACTIVE, MESIC ULTIC HAPLOXEROLL UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 NATIONAL SOIL SURVEY CENTER - PEDON 96P 347, SAMPLES 96P 2696- 2702 - GENERAL METHODS 1B1A, 2A1, 28 SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SAMPLED AS REVISED TO . -1-- SAMPLE ; . DEPTH -2-- HORIZON (CM) NO. 07 96P2696S 7- 19 96P2697S 19- 46 96P26988 96P2699S 46- 65 96P2700S 65- 95 96P2701$ 95-130 96P2702S 130-155 A2 A3 BA Bwl Bw2 2Cr/Bt ORGN TOTAL C N 6Alc PCT (CM) 7 7- 19 19- 46 46- 65 65- 95 95-130 130-155 6B4a <2MM -4-- -6-- -7-- -8-- -9-- -10- -11- -12- -13- -14- 48.2 48.3 47.4 48.3 47.7 52.9 52.9 24.0 23.5 22.2 22.2 23.2 15.0 5.9 9.0 9.1 9.6 8.9 8.2 8.5 15.5 32.5 33.0 32.6 33.4 32.7 39.9 43.1 15.7 15.3 14.8 14.9 15.0 13.0 9.8 10.2 9.6 9.3 9.2 10.2 7.6 2.7 9.7 9.9 9.4 9.3 9.4 5.8 2.3 3.7 3.6 3.4 3.3 3.2 1.3 0.8 0.3 0.3 0.1 0.3 0.2 0.3 0.1 -15- -16- -W- -18- -19- -20- - -)(-COARSE FRACTIONS(MM)-)(>2MM) - - - - WEIGHT - - - WT 1 2 5 20 .1- PCT OF -2 -5 -20 -75 75 WHOLE > <- PCT OF <75MM(3B1)-> SOIL VC 0.1 -- 14 14 0.1 --TR -- TR --13 0.1 --13 --TR TR --7 -- 0.2 3 TR -- 1 17 5 3 -- EXTR TOTAL (- - DITH-CIT - -)(RATIO/CLAY)(ATTERBERG )(- BULK DENSITY -) COLE (- - -WATER CONTENT - -) WRD P S EXTRACTABLE 15 - LIMITS - FIELD 1/3 OVEN WHOLE FIELD 1/10 1/3 15 WHOLE FE AL MN CEC BAR LL PI MOIST BAR DRY SOIL MOIST BAR BAR BAR SOIL 6S3b 6R3c 6C2b 6G7a 602a 8D1 801 4F1 4F 4A5 4Ald 4Alh 401 484 4B1c 481c 482a 4C1 PPM <- PERCENT OF <2MM --> PCT <0.4MM <- - Gicc - - -> CM/CM <- - -PCT OF <2MM - -> CM/CM 2.6 2.6 2.6 2.6 2.7 2.5 3.1 3.37 2.08 1.27 0.64 0.42 0.26 0.10 AVERAGES, -5-- (- - -TOTAL - - -)(- -CLAY- -)(- -SJLT- -)(- - - - - -SAND- - CO3 FINE COARSE VF F CLAY SILT SAND FINE M C LT .002 .05 LT LT .002 .02 .05 .10 .25 .5 .002 -.02 -.05 -.10 -.25 -.50 -1 -.05 -2 .0002 .002 < PCT OF <2MM (3A1) 27.8 28.2 30.4 29.5 29.1 32.1 41.2 Al DEPTH 0- -3-- DEPTH 25-100: 0.2 0.2 0.2 0.2 0.2 0.2 0.2 PCT CLAY 30 TR TR TR TR TR 0.89 0.84 0.77 0.75 0.81 --- 1.28 1.08 PCT 0.46 0.45 0.42 0.46 0.48 0.75 0.82 .1-75MM 1.27 1.28 1.33 1.35 1.39 1.12 1.16 14 1.45 1.44 1.49 1.54 1.54 1.43 1.46 0.045 0.040 0.039 0.045 0.034 0.085 0.080 30.5 27.5 27.7 27.3 26.5 45.0 39.6 12.7 12.6 12.8 13.5 14.1 24.0 33.7 0.23 0.19 0.20 0.19 0.17 0.24 0.07 *** PRIMARY CHARACTERIZATION DATA *** PRINT DATE 07/23/97 S960R-003-001 ; FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT SAMPLED AS USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; PEDON 96P 347, SAMPLE 96P 2696- 2702 : -13- (- NH4OAC EXTRACTABLE BASES -) ACID- EXTR (- - - -CEC DEPTH (CM) CA 5B5a 6N2e MG 5B5a 602d NA 5B5a 6P2b < 0- 7 7- 19 19- 46 46- 65 65- 95 95-130 130-155 8.5 8.6 8.2 8.7 9.0 17.5 19.4 ANALYSES: 4.2 4.7 5.2 6.3 6.6 13.2 14.8 0.1 TR 0.3 0.1 0.1 0.2 0.3 ITY AL K SUM 5B5a BASES 642b 6H5a 6G9c MEG / 100 G 0.8 0.5 0.4 0.4 0.3 0.6 13.6 13.8 14.1 15.5 16.0 31.5 1.0 35.5 16.9 14.2 13.0 11.4 10.6 13.6 11.7 S= ALL ON SIEVED <2mm BASIS SUM CATS 5A3a NH4OAC 5A8c - -> 30.5 28.0 27.1 26.9 26.6 45.1 47.2 24.8 23.6 23.3 22.1 23.6 41.2 44.6 AL SAT - -) BASES + AL 5A3b 5G1 -14- -15- -BASE SAT- CO3 AS RES. SUM NH4 CAC03 OHMS OAC <2MM /CM 6E1g 8E1 5C3 5C1 PCT - < 45 49 52 58 60 70 75 55 58 61 70 68 76 80 -16- -17- -18- COND.(MMHOS /CM 81 -19- - -PH - - -) CACL2 H2O .01M 801f 1:2 -> 0.07 0.02 -- 0,01 0.02 -20- 5.2 5.4 4.7 5.3 4.6 5.8 5.2 8C1f 1:1 6.9 7.0 7.0 7.1 7.2 7.8 5.6 *** S960R-003-001 SAMPLED AS PRIMARY CHARACTERIZATION DATA (BENTON COUNTY, OREGON ; : PRINT DATE 07/23/97 FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE NATIONAL SOIL SURVEY CENTER SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 PEDON 96P 347, SAMPLES 96P 2696- 2702 - GENERAL METHODS 1B1A, 241, 2B -1-- -2-- -3-- -4-- ACID OXALATE EXTRACTION SAMPLE NO. 96P2696 96P2697 96P2698 96P2699 96P2700 96P2701 96P2702 HZ NO 1 2 3 4 5 6 7 OPT DEN 8J 0.07 0.07 0.05 0.03 0.04 0.02 0.02 FE SI AL 6C9b 6V2b 6012b 0.29 0.29 0.27 0.22 0.26 0.30 0.35 0.11 0.10 0.11 0.10 0.10 0.14 0.17 -5-- -6-- PHOSPHOUS CITACID 6S5 RET 654b -7-KCL MN 6D3b -8-- TOTAL C 6A2e <- P C T of< 2mm-><-PPM ->< 0.23 0.23 0.22 0.17 0.17 0.20 0.26 *** -9-- -W- -W- -13- -14- -15- -16- -W- -18- -19- -20- (- -WATER CONTENT- - )(- - WATER DISPERSIBLE - - - MIN AGGRT 0.06 15 12<- - PIPETTE - - >< - HYDROMETER - > SOIL STABL BAR BAR BAR BAR CLAY SILT SAND CLAY SILT SAND CONT <5mm 4B1c 4Bla 4Bla 4B2b <- - - 3Alc - - -><- - - SML - - -> 8F1 401 < 2 m m >< POT> ) PERCENT of 24.0 22.4 21.7 22.9 22.7 35.7 50.5 PRIMARY CHARACTERIZATION DATA *** S960R-003-001 SAMPLED AS USDA-NRCS-NSSC-SOIL SURVEY LABORATORY PRINT DATE 07/23/97 FINE-LOAMY, MIXED, MES1C TYPIC XERUMBREPT PEDON 96P 347, SAMPLE 96P 2696- 2702 ; ; -12- -15- -16- -17- -18- K20 >< Na20 < -20- -19- > . FRACT < ION < NUMBER <- - >< < TCLY TCLY TCLY >< X-RAY SAMPLE 7A21 - peak size MT 2 MT 3 MT 3 QZ 2 QZ 2 KK 2 KK 2 KK 2 MI 1 MI ----- - ->< >< -> EGME > REIN > 702 FD SAMPLE ION < < ->< >< - 7A21 - - - - >< SMEC SMEC SMEC NUMBER < - ->< Peak Size - - ->< 1 SAND SILT MINERALOGY (2.0-0.002mm) ->< OPTICAL THERMAL DTA - ->< - TGA - ->TOT RE< GRAIN COUNT >< 7A3c - >< - 7A4c 7B1a - - Percent - - - ->< Percent X-RAY CSI CSI CSI CSI CS1 CSI QZ43 OP 3 HNtr QZ50 BT 4 BYtr QZ34 BT 2 BYtr 50 61 CSI 46 CSI CSI FK29 PR 2 BYtr FK20 OW 2 ZRtr FK24 OP 1 CAtr FP 7 OW 2 GNtr MS 7 CD 1 GNtr OW16 CD 1 HNtr MS 6 ZRtr CAtr FP 6 PR 1 RUtr FE 9 GN 1 ZRtr > > INTER > PRETA > TION >< -> >< >< >< >< BT 5 POtr ZEtr FE 5 ZEtr POtr MS 6 PR 1 ZEtr FE 4 CDtr RUtr OP 5 HNtr CLtr FP 4 POtr MZtr FRACTION INTERPRETATION: TCLY Total Clay, <0.002mm Coarse Slit, 0.02-0.05mm CS1 MINERAL INTERPRETATION: MT MS ZR CA montmorillon muscovite zircon calcite RELATIVE PEAK SIZE: KK BT PO ZE kaolinite biotite plant opal zeolite 5 Very Large INTERPRETATION (BY HORIZON): SMEC = Smectlte PEDON MINERALOGY BASED ON SAND/SILT; MIXED BASED ON CLAY: SMECTITIC FAMILY MINERALOGY: MIXED COMMENTS: 4 Large INTER PRETA TION - > <mg /g>< - -> 2 MI 2 QZ 1 < FRACT < 96P2698 96P2698 96P2698 96P2700 96P2700 96P2700 96P2702 96P2702 96P2702 -14- -13- CLAY MINERALOGY ( <.002mm) ->< THERMAL ELEMENTAL >< - DTA - ->< - TGA - -> 5102 AL203 Fe203 Mg0 Ca0 >< 7A4c 7C4a- >< 7A6b > < ->< - - - Percent Percent < 96P2698 96P2700 96P2702 *** QZ FE CD RU quartz iron oxides chalcedony rutile 3 Medium 2 Small MI OP HN CL mica opaques hornblende chlorite 1 Very Small FK PR potas feldsp pyroxene BY FD beryl feldspar 6 No Peaks FP OW GN MZ plag-feldspa oth-weath mn garnet monazite PRIMARY CHARACTERIZATION DATA (BENTON COUNTY, OREGON S960R -003 -002 *** PRINT DATE 07/23/97 ; FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT FINE, SMECTICTIC, MESIC VERTIC PALEXERALF ; SAMPLED AS REVISED TO UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE NATIONAL SOIL SURVEY CENTER SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 96P 348, SAMPLES 96P 2703- 2713 - PEDON - GENERAL METHODS 1B1A, 2A1, 2B -7-- SAMPLE DEPTH HORIZON (CM) NO, ORGN TOTAL C N DEPTH 6Alc PCT (CM) 0- 7 7- 14 14- 27 27- 36 36- 50 50- 70 70- 92 92-109 109-140 142-155 153-170 6B4a <2MM -10- -11- -12- -13- 52.7 50.7 49.2 48.7 48.1 47.9 35.2 30.2 30.2 43.8 36.3 22.3 22.8 22.3 20.1 20.5 19.2 8.8 11.6 12.5 28.5 28.8 34.9 34.9 33.9 33.9 34.3 35.2 27.7 23,3 22,1 25.0 25.3 9.3 9.6 9.8 10.8 10.1 11.1 34.4 35.9 36.0 16.3 18.8 17.8 15.8 15.3 14.8 13.8 12.7 7.5 6.9 8.1 18.8 11.0 8.6 9.7 9.1 8.5 8.3 8.2 4.0 5.0 5.0 19.6 11.9 9.9 9.2 9.2 8.2 8.4 7.6 3.5 4.1 5.0 6.9 12.8 -14- - C .5 -1 3.5 3.4 3.4 3.1 3.3 2.9 1.2 0.2 0.3 0.5 0.3 0.4 0.4 1.4 1.6 1.5 0.5 0.3 0.5 0.3 3.8 0.1 -15- -16- -17- -18- -19- -20- - - -)(-COARSE FRACTIONS(MM)-)(>2MM) VC - - - - WEIGHT - - - WT 1 2 5 20 .1- PCT OF -2 -5 -20 -75 75 WHOLE > <- PCT OF <75MM(3B1) -> SOIL 0.1 0.2 0.1 TR 0.1 0.1 TR 0.6 0.6 TR -- ----------- 14 13 13 12 12 11 5 7 9 17 ------------ EXTR TOTAL (- - DITH-CIT - -)(RATIO/CLAY)(ATTERBERG )(- BULK DENSITY -) COLE (- - -WATER CONTENT - -) WRD P EXTRACTABLE 15 - LIMITS - FIELD 1/3 OVEN WHOLE FIELD 1/10 S 1/3 15 WHOLE FE AL MN CEC BAR LL PI MOIST BAR DRY SOIL MOIST BAR BAR BAR SOIL 6S3b 6R3c 6C2b 6G7a 6D2a 801 8D1 4F1 4F 4A5 4Ald 4Alb 4D1 484 481c 4B1c 4B2a 4C1 PCT <0.4MM <- - G /CC - - -> CM/CM <- - -PCT OF <2MM - -> CM/CM PPM <- PERCENT OF <2MM --> 2.2 2.7 2.6 2.9 2.9 2.9 2.6 2.8 2.9 4.8 0.9 5.58 2.93 1.45 1,13 0.67 0.61 0.27 0.20 0.16 0.09 0.05 AVERAGES, -9-- (- - -TOTAL - - -)(- -CLAY- -)(- -SILT- -)(- - - - - -SANDF M FINE CO3 FINE COARSE VF CLAY SILT SAND LT .002 .02 .05 .10 .25 LT .002 .05 LT -.25 -.50 -.05 -2 .0002 .002 -.02 -.05 -.10 .002 (3A1) PCT OF <2MM < 25.0 26.5 28.5 31.2 31.4 32.9 56.0 58.2 57.3 27.7 34.9 Al 0- 7 96P2703S A2 7- 14 96P2704S A3 96P2705S 14- 27 AE 96P2706S 27- 36 El 96P2707S 36- 50 E2 96P2708S 50- 70 96P27095 70- 92 '28ssb 96P2710S 92-109 3Bssbl 96P2711S 109-140 3Bssb2 96P2712S 142-155 4C 96P2713S 153-170 4Bg -8-- DEPTH 25-100: 0.2 0.2 0.3 0.3 0.2 0.3 0.2 0.2 0.3 0.2 0.1 PCT CLAY 0.1 TR TR TR TR TR 42 1.05 ---- 0.84 0.72 0.66 0.63 0.64 0.62 0.66 0.65 TR TR 1.46 1.03 PCT 1.02 1.18 1.32 1.37 1.46 1.51 1.28 1.25 1.20 0.60 0.50 0.43 0.40 0.40 0.44 0.45 0.46 0.46 0.86 0.66 .1-75MM 9 1.17 1.31 1.42 1.48 1.58 1.62 1.94 1.93 1.90 0.047 0.035 0.025 0.026 0.027 0.024 0.149 0.156 0.166 35.6 29.1 27.8 25.7 24.2 23.7 38.4 40.6 43.3 15.0 13.2 12.2 12.6 12.6 14.4 25.0 26.6 26.6 23.7 23.0 0.21 0.19 8.21 0.18 0.17 0.14 0.17 0.18 0.20 PRIMARY CHARACTERIZATION DATA *** S960R-003-002 SAMPLED AS ;.FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; PEDON 96P 348, SAMPLE 96P 2703- 2713 -1-- (CM) 7 71427365070- 14 27 36 50 70 92 -3-- -4-- -5-- -6-- -7-- -10- -11SAR <- - - - - ---- -MEG / 100 G (- -CEC-) EXCH NH4SUM NA CATS OAC 5A3a 5A8c 502 > PCT 8.0 7.1 6.3 6.5 6.8 7.4 13.9 16.0 16.8 16.1 18.2 3.7 3.4 3.7 4.1 4.7 5.1 10.5 12,2 12.5 11.2 13.2 32.4 29.4 26.2 26.3 25.0 25.9 41.5 42.3 41.4 38.2 40.1 CA MG NA 681b 601b 6Plb (- NH4OAC EXTRACTABLE BASES -) ACIDCA MG NA K SUM ITY 585a 5B5a D85a 585a BASES 682e 602d 6P2b 6Q2b 6H5a DEPTH 0- -2-- 92-109 109-140 142-155 153-170 0.1 ---TR 0.1 0.5 0.6 0.6 0.5 0.6 0.4 0.4 0.3 0.3 0.2 0.4 0.5 0.5 0.6 0.4 0.4 12.2 10.9 10.3 10.9 11.7 13.0 25.4 29,3 30.5 28.2 32,4 20.2 18.5 15.9 15.4 13.3 12.9 16.1 13.0 10.9 10.0 7.7 -8-- -9-- 26.2 22.3 20.4 20.6 19.9 21.0 34.9 38.6 37.1 40.5 36.0 K CO3 HCO3 F CL 1 50 1 1 1 2 SO4 NO2 6Lld 6W1b DEPTH 601b < 0- 38 37 39 41 47 1 -14- 611b 6J1b 6U1b MEQ / LITER 6K1d -16- -17- 61 69 74 74 81 -18- 4.4 )PRED. TOTAL ELEC. ELEC. H2O SALTS COND. CORO. EST. 8A3a 81 6M1d 8A 805 MMHOS MMHOS > <- -PCT- -> /cm /cm NO3 7 0.13 0.03 ---- 1.9 1.5 1.8 1.2 0.1 TR 3.9 3.4 0.1 105.5 MMHOS/CM OF 1:2 WATER EXTRACT (81) & EXCH NA AS EXTRACTABLE NA FOR LAYERS ANALYSES: S= ALL ON SIEVED <2mm BASIS TR 1, 2, 0.76 3, 0.01 0.21 0,23 0.27 0.19 0.11 4, 5, -19- CASO4 AS (- - - -PH GYPSUM SAT CACL2 <2MM <20MM PASTE .01M 6F1a 6F4 8C1b 8Clf <- -PCT -> 1:2 47 49 50 53 59 62 73 76 82 70 90 7- 14 14- 27 27- 36 36- 50 50- 70 70- 92 92-109 109-140 142-155 153-170 -15- BASE CARBONATE SATURATION AS CAC03 SUM NH4OAC <2MM <20MM 5C3 5C1 6E1g 8E1 <- -PCT- > <- -PCT -> TR TR TR TR TR 2 -13- -12- WATER EXTRACTED FROM SATURATED PASTE ( (CM) 5E PRINT DATE 07/23/97 6, 7, 8, 10, 11, 4.9 4.9 5.0 4.7 4.5 4.8 4.1 4.2 4.3 4.8 5.0 -20- - -) H2O 8C1f 1:1 7.1 7.1 7.0 6.3 6.9 6.0 4.7 6.4 4.8 7.4 7.0 'fee S960R-003-002 SAMPLED AS P R ! M A R Y C H A R A C T E R (BENTON COUNTY, OREGON I Z A T I O N SAMPLE NO. HZ NO -2- -3- -4- -6- ACID OXALATE EXTRACTION PHOSPHOUS GITRET ACID 6S4b 6S5 96P2703 1 96P2704 2 96P2705 3 96P2706 4 96P2707 5 96P2708 6 96P2709 7 96P2710 8 96P2711 9 96P2712 10 96P2713 11 8J 0.11 0.10 0.09 0.07 0.05 0.05 0,02 0.02 0.01 0.02 0.01 PRINT DATE 07/23/97 UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE NATIONAL SOIL SURVEY CENTER SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 - PEDON 96P 348, SAMPLES 96P 2703- 2713 - GENERAL METHODS 101A, 2A1, 2B OPT DEN eee ) ; FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT . -1-- DATA FE SI 6C9b 6V2b 6G12b 0.78 0.87 0.72 0.59 0.48 0.52 0.24 0.14 0.10 0.31 0.04 0.11 0.12 0.08 0.13 0.11 0.12 0.14 0.13 0.04 0.16 0.09 AL -8-- -7-- KCL TOTAL MN 603b C 6A2e <- P C T of< 2mm-><-PPM ->< 0.20 0.22 0.23 0.23 0.18 0.21 0.19 0.15 0.14 0.16 0.11 -9- -10- -11- -n- -14- -15- -u- -2o- (- -WATER CONTENT- - )(- - - - WATER DISPERSIBLE - - - - ) MIN AGGRT 15 0.06 12<- - PIPETTE - - >< - HYDROMETER - > SOIL STABL BAR BAR BAR BAR CLAY SILT SAND CLAY SILT SAND CONT <5mm 481c 4Bla 4B1a 4B2b <- - - 3Alc - - -><- - - SML - - -> 8F1 4G1 < 2 m m >< PCT> PERCENT of 25.5 22.6 20.8 20.7 20.7 27.5 35.0 36.9 36.9 35.1 32.6 *** PR IMARY CHARACTER I ZATI ON S960R-003-002 SAMPLED AS USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; ; < FRACT < ION < NUMBER <- - >< - < 96P2705 96P2708 96P2709 96P2711 96P2712 96P2713 SAMPLE TCLY TCLY TCLY TCLY TCLY TCLY FRACT < ION < MT MT MT MT X-RAY >< 7A2I >< >< >< - peak size KK 2 KK 2 4 4 3 4 MM MT KK KK KK KK 2 2 3 2 2 2 MI MM VR QZ KH KH NUMBER < - ->< CSi CSI CS CS CS CS CS CS CS CS CS CS CS CS CS CS CS CS CS CS MT 2 QZ 2 MI 2 PRINT DATE 07/23/97 -13- -14- -15- CLAY MINERALOGY (<.002mm) ->< THERMAL ELEMENTAL DTA - ->< - TGA - -> SI02 AL203 Fe203 Mg0 Ca0 7A6b >< 7A4c >< 7C4a- ->< Percent Percent -16- -17- K20 >< Na20 < -18- -19> ----- - ->< >< -> EGME INTER > RETN PRETA > TION 7D2 -><mg/g>< - -> QZ 2 MI 2 QZ 1 SMEC SMEC SMEC SMEC SMEC QZ 1 QZ 1 - - X-RAY - - ->< - 7A21 - 96P2705 96P2705 96P2705 96P2705 96P2708 96P2708 96P2708 96P2708 96P2709 96P2709 96P2709 96P2709 96P2711 96P2711 96P2711 96P2711 96P2712 96P2712 96P2712 96P2712 2 2 2 1 1 2 *** FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT PEDON 96P 348, SAMPLE 96P 2703- 2713 -12- SAMPLE DATA - >< - >< Peak Size- - ->< SAND SILT MINERALOGY (2.0-0.002mm) - - THERMAL - - - ->< - - - - - - - OPTICAL DTA - ->< - TGA - ->T0T RE< GRAIN COUNT >< 7A3c - >< - 7A4c 781a - - Percent Percent 54 57 55 54 58 QZ45 OP 3 HNtr GCtr QZ47 OW 2 RUtr CAtr QZ45 CD 3 POtr RUtr QZ45 PR 2 GNtr TMtr QZ43 BT 2 RUtr TMtr >< >< >< >< FK25 OW 2 BYtr TEtr FK24 DT 2 ZEtr GStr FK29 BT 1 ZEtr CLtr FK31 CD 1 ZRtr MS 8 CD 2 ZRtr TMtr MS 6 PR 2 POtr FP 6 FE 3 PO PR MS 6 FZ 1 BYtr TMtr FP 7 OW 1 POtr FP 4 FK26 CD 1 GNtr CLtr BT 3 GNtr GStr FP 5 BYtr GNtr OP 4 CDtr ZRtr FE 4 OW 1 GNtr OP 3 HN 1 GStr FE 5 BT 1 ZEtr MS 3 HNtr CLtr OP 3 BYtr RUtr FE14 FP 6 PR HN MS 4 OPtr CLtr OW 3 ZRtr CAtr 1 BYtr 1 ZEtr RUtr FE 6 HN 1 TMtr 1 POtr 1 PR 1 ZRtr > > > >c INTER PRETA TION -> *** PRIMARY CHARACTERIZATION DATA S960R-003-002 SAMPLED AS USDA-NRCS-NSSC-SOIL SURVEY LABORATORY -1-- -2-- -3-- -4-- *** PRINT DATE 07/23/97 ; ; FINE-LOAMY, MIXED, MESIC TYPIC XERUMBREPT PEDON 96P 348, SAMPLE 96P 2703- 2713 -5-- -6-- -9-- -n- -6-- -7-- CSI Coarse Silt, 0.02-0.05mm -10- -14- -15- -u- -16- -19- FRACTION INTERPRETATION: TCLY Total Clay, <0.002mm MINERAL INTERPRETATION: KK MS CD ZR TM kaolinite muscovite chalcedony zircon tourmaline RELATIVE PEAK SIZE: MM FP PO ZE RU mont-mica plag-feldspa plant opal zeolite rutile 5 Very Large 4 Large MI FE PR CL CA mica Iron oxides pyroxene chlorite calcite 3 Medium INTERPRETATION (BY HORIZON): SMEC = Smectite PEDON MINERALOGY BASED ON SAND/SILT: MIXED BASED ON CLAY: SMECTITIC FAMILY MINERALOGY: SMECTITIC IF ARGILLIC; COMMENTS: MIXED 2 Small MT BT GN GS VR montmorillon biotite garnet QZ glass GC FZ vermiculite 1 Very Small OP HN quartz opaques hornblende glas-coat gr feldspathoid 6 No Peaks FK OW potas feldsp oth-weath mn BY TE beryl KH tremolite halloysite -20- PRIMARY CHARACTERIZATION DATA (BENTON COUNTY, OREGON S960R-003-003 SAMPLED AS REVISED TO PRINT DATE 07/23/97 ; ; : FINE, SMECTICTIC, MESIC VERTIC HAPLOXERALF VERY-FINE, SMECTICTIC, MESIC VERTIC PALEXERAlf UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE NATIONAL SOIL SURVEY CENTER SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 96P 349, SAMPLES 96P 2714- 2722 - PEDON - GENERAL METHODS 181A, 2A1, 2B -1-- DEPTH SAMPLE -2-- -3-- HORIZON -4-- -5-- -6-- -7-- -.05 -2 .0002 A2 AE E 2Bt 3Bss 3Bs 4BSS 5Cr ORGN TOTAL C N DEPTH 6Alc PCT (CM) 0- 7 7- 16 16- 27 27- 42 42- 91 91-120 120-135 135-153 153-175 25.0 26.6 30.5 38.2 61.5 61.5 60.7 59.3 31.7 Al 684a <2MM -10- -11- -12- -13- .002 -.02 53.7 53.3 49.3 45.2 28.9 28.3 29.3 30.4 61.8 21.3 20.1 20.2 16.6 9.6 10.2 10.0 10.3 6.5 38.0 36.5 35.3 33.2 23.1 21.7 21.7 23.1 48.2 10.5 11.5 13.8 18.2 42.7 42.7 33.8 28.6 10.5 -.05 -.10 (3A1) 15.7 16.8 14.0 12.0 5.8 6.6 7.6 7.3 13.7 8.8 7.1 8.3 6.9 4.3 4.5 5.0 4.4 4.3 -.25 -.50 8.8 8.9 8.2 6.7 3.8 4.1 3.8 3.6 1.4 3.4 3.4 3.2 2.6 1.3 1.3 0.9 1.4 0.5 -14- - C .5 -1 0.2 0.5 0.4 0.4 0.1 0.2 0.2 0.7 0.3 -15- -16- -17- -18- -19- -20- - - -)(-COARSE FRACTIONS(MM)-)(>2MM) VC - - - - WEIGHT - - - WT .1- PCT OF 1 2 5 20 -2 -5 -20 -75 WHOLE 75 > <- PCT OF <75MM(3B1) -> SOIL 0.1 0.2 0.1 TR 0.1 0.1 0.1 0.2 TR -------2 -- -- 12 -- TR 13 12 10 TR ----- 5 6 TR 5 8 -- 2 -----2 -- EXTR TOTAL (- - DITH-CIT - -)(RATIO/CLAY)(ATTERBERG )(- BULK DENSITY -) COLE (- - -WATER CONTENT - -) WRD 1/3 OVEN WHOLE FIELD 1/10 15 - LIMITS FIELD 1/3 15 WHOLE P S EXTRACTABLE BAR BAR BAR SOIL FE AL MN CEC BAR LL PI MOIST BAR DRY SOIL MOIST 4Ald 4Alh 401 801 801 4F1 4F 4A5 4B4 481c 481c 482a 4C1 6S3b 6R3c 6C2b 6G7a 602a PPM <- PERCENT OF <2MM --> PCT <0.4MM <- - G/cc - - -> CM/CM <- - -PCT OF <2MM - -> CM/CM 2.3 2.5 2.8 2.8 2.5 2.6 2.5 2.3 3.1 5.67 2.76 1.47 0.89 0.39 0.26 0.18 0.15 0.03 AVERAGES, -9-- PCT OF <2MM < 7 096P2714S 7- 16 96P2715S 16- 27 96P2716S 96P2717S 27- 42 96P2718S 42- 91 96P2719S 91-120 96P2720S 120-135 96P2721S 135-153 96P2722S 153-175 -8-- (- - -TOTAL - - -)(- -CLAY- -)(- -SILT- -)(- - - - - -SANDF M CLAY SILT SAND FINE CO3 FINE COARSE VF .10 .25 .05 LT LT .002 .02 .05 LT .002 .002 (CM) NO. *** DEPTH 42- 92: 0.2 0.2 0,3 0.3 0.3 0.2 0.2 0.1 0.2 PCT CLAY 0.1 0.1 0.1 TR -- TR 0,1 0.2 0.2 62 PCT 0.97 0.83 0.66 0.58 0.61 0.64 0.71 0.77 1.44 1.03 1.20 1.27 1.28 1.24 1.21 1.17 1.19 0.67 0.44 0.40 0.38 0.44 0.43 0.46 0.47 0.81 .1-75MM 5 1.23 1.34 1.37 1.38 2,06 2.04 1.96 1.97 0.061 0.037 0.026 0.025 0.184 0.190 0.188 0.180 39.3 30.5 28.7 27.8 40.8 42.7 44.2 44.1 16.7 11.8 12.1 14.4 26.8 26.4 27.8 28.0 25.8 0.23 0.22 0.21 0.17 0.17 8.20 0.19 0.19 *** PR IMARY CHARACTERIZATION DATA *** PRINT DATE 07/23/97 S960R-003-003 FINE, SMECTICTIC, MESIC VERTIC HAPLOXERALF ; SAMPLED AS USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; PEDON 96P 349, SAMPLE 96P 2714-, 2722 - -13- (- NH4OAC EXTRACTABLE BASES -) ACIDITY CA MG NA K SUM 585a BASES 5B5a 5B5a 5B5a 602b 6P2b 6H5a 6N2e 602d DEPTH (CM) <- - 0- 7 7- 16 16- 27 27- 42 42- 91 91-120 120-135 135-153 153-175 _ _ ----- -MEQ / 100 8.2 6.3 6.1 7.4 16.6 22.3 44.0 27.1 27.0 3.8 3.1 3.6 5.0 11.6 0.2 0.2 0.7 TR 13.1 16.3 17.2 16.6 1.0 1.3 1.3 1.3 CA MG NA 6N1b 601b 6P1b -- 0.5 0.3 0.3 0.3 0.5 0.4 0.4 0.4 0.4 12.5 9.7 10.2 12.9 29.4 36.8 62.0 46.0 45.3 (- -CEC- -) EXCH SUM NH4NA OAC CATS 5A8c 5D2 5A3a > PCT G 18.4 17.8 15.9 14.7 13.8 10.4 5.3 5.6 4.8 30.9 27.5 26.1 27.6 43.2 47.2 67.3 51.6 50.1 24.3 22.1 20.2 22,2 37.8 39.5 43.1 45.9 45.6 TR TR 1 1 2 2 2 2 2 K CO3 HCO3 F CL SO4 NO2 6L1d 6W1b DEPTH 6Q1b < 0- 5E 1 1 1 2 BASE SATURATION SUM NH4OAC 5C3 5C1 <- -PCT- > 40 35 39 47 68 78 92 89 90 611b 6J1b 6Ulb MEQ / LITER 6K1d 44 50 58 78 93 100 100 99 )PRED. H2O 0.19 0.05 0.01 11.6 25.5 8.3 3,9 7.9 14.1 5.9 2.6 3.6 5.1 3.7 3.0 0.1 0.1 0.1 TR 0.2 0.3 0.4 0.5 0.3 0.6 0.2 0.1 1.2 23.9 45.4 0.6 0.5 18.3 8.8 0.8 102.4 102.6 102.6 83.3 0.1 MMHOS/CM OF 1:2 WATER EXTRACT (81) & EXCH NA AS EXTRACTABLE NA FOR LAYERS ANALYSES: Sw. ALL ON SIEVED <2mm BASIS -17- -18- 0.1 0.3 0.1 TR 1, 2, 1.90 3.63 1.54 0.96 0.17 1.23 3.08 0.92 0.46 4, 5, -19- CASO4 AS (- - - -PH GYPSUM SAT CACL2 <2MM <20MM PASTE .01M 6Fla 6F4 8C1b 8Clf <- -PCT -> 1:2 1 TOTAL ELEC. ELEC. SALTS COND. COND. EST. 8A3a 81 6M1d 8A 8D5 MMHOS MMHOS > <- -PCT- -> /cm /cm NO3 -16- 51 7 7- 16 16- 27 27- 42 42- 91 91-120 120-135 135-153 153-175 715- CARBONATE AS CAC03 <2MM <20MM 6E1g 8E1 <- -PCT -> WATER EXTRACTED FROM SATURATED PASTE ( (CM) SAR -14- 4.8 6.4 6.8 6.8 4.8 4.5 4.4 4.3 4.4 4.8 6.6 6.8 7.0 -20- -) H2O 8Clf 1:1 5.5 5.2 5.3 5.2 4.9 5.2 6.7 7.1 7.4 *** S960R-003-003 SAMPLED AS PRIMARY CHARACTERIZATION DATA (BENTON COUNTY, OREGON ; : PRINT DATE 07/23/97 FINE, SMECTICTIC, MESIC VERTIC HAPLOXERALF UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE NATIONAL SOIL SURVEY CENTER SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 - PEDON 96P 349, SAMPLES 96P 2714- 2722 - GENERAL METHODS 181A, 2A1, 28 -4-- ACID OXALATE EXTRACTION SAMPLE NO. 96P2714 96P2715 96P2716 96P2717 96P2718 96P2719 96P2720 96P2721 96P2722 HZ NO 1 2 3 4 5 6 7 8 9 OPT DEN 8J 0.10 0.09 0.08 0.06 0.02 0.03 0.02 0.02 0.01 AL FE SI 6C9b 6V2b 6G12b 0.74 0.82 0.65 0.48 0.22 0.24 0.17 0.17 0.11 0.12 0.11 0.11 0.10 0.13 0.16 0.15 0.16 0.14 -10- PHOSPHOUS CITRET ACID 6S4b 6S5 KCL MN 6D3b TOTAL <-PCT of< 2mm-><-Ppm ->< 0.19 0.20 0.24 0.23 0.23 0.16 0.14 0.14 0.13 C 6A2e -11- -12- -13- -14- -15- -16- -17- -18- -19- -20- (- -WATER CONTENT- - )(- - - - WATER DISPERSIBLE - - - - ) MIN AGGRT 0.06 15 12<- - PIPETTE - - >< - HYDROMETER - > SOIL STABL BAR BAR BAR BAR CLAY SILT SAND CLAY SILT SAND CONT <5mm 4B1c 4Bla 481a 4B2b <- - - 3A1c - - -><- - - SML - - -> 8F1 4G1 < 2mm >< PCT> PERCENT of 25.1 22.3 21.5 22.3 38.6 36.4 39.5 39.1 37.7 *** PRIMARY CHARACTERIZATION DATA *** S960R-003-003 SAMPLED AS ; FINE, SMECTICTIC, MESIC VERTIC HAPLOXERALF USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; PEDON 96P 349, SAMPLE 96P 2714- 2722 PRINT DATE 07/25/97 -13< SAMPLE FRACT < ION < NUMBER <- - >< - < 96P2716 96P2718 96P2719 96P2721 96P2722 TCLY TCLY TCLY TCLY TCLY KK MT MT MT MT < FRACT < SAMPLE ION < < NUMBER 96P2716 96P2716 96P2716 96P2716 96P2718 96P2718 96P2718 96P2718 96P2719 96P2719 )6P2719 )6P2719 )6P2721 96P2721 )6P2721 )6P2721 )6P2722 )6P2722 96P2722 < - ->< CS CS CS CS CS CS CS CS CS CS CS >< >< >< >< X-RAY 7A21 - 3 4 4 4 4 - - peak size MM KK KK KK FO 2 3 2 2 2 MI VR MI QZ KK 2 2 2 1 2 MT 2 MI 2 QZ 1 QZ 2 QZ 1 MI QZ 1 1 -15- -16- CLAY MINERALOGY (<.002mm) ->< THERMAL ELEMENTAL DTA - ->< - TGA - -> S102 AL203 Fe203 MgO Ca0 K20 7A6b >< 7A4c >< 7C4a- - -- - ->< Percent Percent SAND SILT MINERALOGY (2.0-0.002mm) THERMAL ->< OPTICAL >< - DTA - ->< - TGA - ->TOT RE< GRAIN COUNT - 7A2i - - - - >< - 7A3c - >< - 7A4c >< 781a Peak Size - - ->< - - - Percent - - - ->< percent X-RAY -17- >< Na20 < ->< >< -18- -19- -20> -> EGME > REIN INTER PRETA > 702 TION -><mg/g>< - -> CMIX SMEC SMEC SMEC SMEC - >< 55 48 45 CS CS CS CS CS CS CS CS -14- 53 53 QZ44 PO 3 ZEtr RUtr QZ40 MS 3 POtr GOtr FK35 OW 2 BYtr GNtr QZ4O CD 2 FZ 1 RUtr QZ39 BT 4 HNtr FK28 BT 3 CLtr GAtr FK34 PR 2 CDtr SStr QZ33 CD 2 FZtr CTtr FK32 BT 1 ZRtr TMtr FK23 CD 3 GNtr FP 5 OW 2 ZRtr ZOtr FP 7 BT 2 CLtr RUtr FP 9 MS 1 POtr FP 7 HN 1 GNtr MZtr FE 9 OP 2 POtr MS 5 PR 1 BYtr FE 4 GS 1 BYtr TEtr FE 6 PR 1 ZRtr FE 6 PR 1 ZEtr GOtr FP 8 PR 1 RUtr >< >< >< >< FE 4 HN 1 GNtr OP 3 CD 1 TMtr OP 4 OWtr FZtr TMtr OP 4 HN 1 RUtr HN 3 ZRtr GNtr OP 4 OW 1 CTtr MS 3 BY 1 POtr MS 6 OW 4 ZRtr CTtr FZ 1 BYtr BT 3 ZE 1 CLtr > > INTER > PRETA > TION >< -> PRIMARY CHARACTERIZATION DATA *** *** S960R-003-003 SAMPLED AS ; FINE, SMECTICTIC, MESIC VERTIC HAPLOXERALF USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; PEDON 96P 349, SAMPLE 96P 2714- 2722 PRINT DATE 07/25/97 . -2-- -3-- -4-- -5-- -6-- -7-- -8-- -9-- -10- -11- -12- -13- -14- -15- -16- -17- -18- -19- FRACTION INTERPRETATION: TCLY. Total Clay, <0.002mm Coarse Silt, 0.02-0.05mm CSI MINERAL INTERPRETATION: KK FP OW ZR ZO kaolinite plag-feldspa oth-weath mn zircon zoisfte RELATIVE PEAK SIZE: MM MS PR mont-mica muscovite pyroxene BY VR beryl vermiculite 5 Very Large 4 Large MI FE HN GN GS 3 Medium INTERPRETATION (BY HORIZON): CMIX . Mixed - Clay PEDON MINERALOGY BASED ON SAND/SILT: Mixed BASED ON CLAY: SmectitIc FAMILY MINERALOGY: Smectitic COMMENTS: mica Iron oxides hornblende garnet glass SMEC = Smectlte 2 Small MT OP CD TM FZ montmorlllon opaques chalcedony tourmaline feldspathoid 1 Very Small QZ PO ZE RU GO quartz plant opal zeolite rutile glaucophane 6 No Peaks FK BT CL GA SS potas feldsp blotlte chlorite glass aggreg spon splcule -20- *** 5960R-003-004 SAMPLED AS REVISED TO PRIMARY CHARACTERIZATION DATA (BENTON COUNTY, OREGON : SND PRINT DATE 07/23/97 ; FINE SMECTITIC, MESIC VERTIC NAPLOXERALF FINE, SMECTICTIC, MESIC TYPIC HAPLOXERERT : ; UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE NATIONAL SOIL SURVEY CENTER SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 - PEDON 96P 350, SAMPLES 96P 2723- 2729 - GENERAL METHODS 1B1A, 2A1, 2B -1-- SAMPLE NO. DEPTH -2-- 096P2723S 6 6- 18 96P2724S 96P2725S 18- 35 96P2726S 35- 51 96P27275 51- 90 96P2728S 90-133 96P2729S 133-163 HORIZON Al A2 BA Btl Bt2 Bssl Bss2 ORGN TOTAL C N DEPTH 0- -3-- (CM) (CM) 6Alc PCT 6 6- 18 18- 35 35- 51 51- 90 90-133 133-163 raw ) 9.16 3.99 2.43 1.57 1.03 0.95 0.79 AVERAGES, 6B4a <2MM -4-- -5-- -6-- -7-- -8-- -9-- -10- -11- -12- -13- (- - -TOTAL - - -)(- -CLAY- -)(- -SILT- -)(- - - - - -SANDCLAY SILT SAND FINE CO3 FINE COARSE VF F 14 LT .002 .05 LT LT .002 .02 .05 .10 .25 -2 .002 -.05 .0002 .002 -.02 -.05 -.10 -.25 -.50 < PCT OF <2MM (3A1) 43.8 47.4 52.4 54.5 56.1 58.8 62.0 46.4 44.8 37.2 33.7 36.9 33.9 32.2 9.8 7.8 10.4 11.8 7.0 7.3 5.8 23.5 26.4 29.9 30.7 29.1 24.9 23.2 36.6 37.2 31.7 28.3 29.2 27.6 27.2 9.8 7.6 5.5 5.4 7.7 6.3 5.0 3.9 9.7 3.5 3.0 2.0 4.3 3.2 3.4 2.5 3.1 3.2 2.8 2.2 2.0 1.6 1.1 1.9 -14- - C .5 -1 0.8 0.4 2.7 1.5 1.8 1.5 0.6 0.5 0.5 0.2 0.1 -15- -16- -17- -18- -19- -20- - - -)(-COARSE FRACTIONS(MM)-)(>2MM) VC - - - - WEIGHT - - - WT 1 2 5 20 .1- PCT OF -2 -5 -20 -75 75 WHOLE > <- PCT OF <75MM(3B1)-> SOIL 0.1 0.1 0.4 1.1 0.2 -- TR -------- -- --6 4 7 9 5 3 3 -------- EXTR TOTAL (- - DITH-CIT - -)(RATIO/CLAY)(ATTERBERG )(- BULK DENSITY -) COLE (- - -WATER CONTENT - -) WRD P S EXTRACTABLE 15 - LIMITS - FIELD 1/3 OVEN WHOLE FIELD 1/10 1/3 15 WHOLE FE AL MN CEC BAR LL PI MOIST BAR DRY SOIL MOIST BAR BAR BAR SOIL 6S3b 6R3c 6C2b 6G7a 6D2a 801 801 4F1 4F 4A5 4Ald 4Alh 401 484 481c 481c 4B2a 4C1 PPM <- PERCENT OF <2MM --> PCT <0.4MM <- - G/cc - - -> CM/CM <- =:-PCT OF <2MM - -> CM/CM 3.6 0.3 0.3 1.20 0.79 0.23 0.32 0.116 203.4 34.5 0.39 4.5 0.4 0.3 1.03 0.51 1.01 1.29 0.085 32.9 24.0 0.09 4.8 0.4 0.4 0.87 0.45 1.19 1.75 0.137 42,1 23.4 0.22 4.7 0.4 0.5 0.89 0.45 1.12 1.51 0.105 38.0 24.4 0.15 3.8 0.2 0.4 0.49 1.19 1.48 0.075 38.8 27.6 0.13 2.6 0.2 0.2 0.96 0.48 1.23 1.88 0.152 40.6 28.3 0.15 3.1 0.2 0.2 0.95 0.48 1.15 1.87 0.176 45.5 29.8 0.18 DEPTH 25-100: PCT CLAY 56 PCT .1-75MM 6 PRIMARY CHARACTERIZATION DATA *** *** PRINT DATE 07/23/97 S960R-003-004 FINE SMECTITIC, MESIC VERTIC HAPLOXERALF ; SND SAMPLED AS USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; PEDON 96P 350, SAMPLE 96P 2723- 2729 : -13- (- -CEC- -) EXCH NA NH4SUM OAC CATS 502 5A3a 5A8c > PCT (- NH4OAC EXTRACTABLE BASES -) ACIDCA 5B5a 6N2e DEPTH (CM) MG 5B5a 602d NA 5B5a 6P2b < 0- 6 6- 18 18- 35 35- 51 51- 90 90-133 133-163 SUM 5B5a BASES 602b K ITY 6H5a MEQ / 100 G 18.7 16.6 18.5 19.9 7.3 7.7 9.4 11.0 0.6 0.2 0.3 0.4 0.4 0.4 0.4 27.6 24.9 28.6 31.7 33.6 33.7 18.8 19.2 1.1 1.0 0.4 0.4 53.9 54.3 1.0 62.1 54.9 54.6 55.1 34.5 30.0 26.0 23.4 13.2 7.4 8.1 52.5 48.6 45.8 48.6 1 2 2 88 87 96 92 WATER EXTRACTED FROM SATURATED PASTE ( CA MG DEPTH 6N1b < - - (CM) 0- 6 2.0 NA 601b 6Plb 1.1 1.1 .. ------ SO4 NO2 6J1b 6U16 601b 611b - _ - - -MEQ / LITER 6Kld 6L1d 6W1b 0.7 0.9 1.1 0.2 K 0.3 CO3 HCO3 1.7 F CL. 44 53 51 62 65 1 56.4 58.9 5E BASE SATURATION SUM NH4OAC 5C1 5C3 <- -PCT- > 45 52 58 1 TR 13.2 61.3 62.4 SAR 1 -14- CARBONATE AS CAC03 <2MM <20MM 8E1 6Elg <- -PCT -> )PRED. TOTAL ELEC. ELEC. SALTS COND. COND. NO3 81 8A3a EST. 805 MMHOS MMHOS 8A 6M1d /cm /cm > <- -PCT- -> TR MMHOS/CM OF 1:2 WATER EXTRACT (81) & EXCH NA AS EXTRACTABLE NA FOR LAYERS S. ALL ON SIEVED <2mm BASIS 2, 3, -18- 0.55 4, 3.21 0.16 0.05 0.04 0.05 0.13 0.07 5, 6, -19- CASO4 AS (- - - -PH SAT CACL2 GYPSUM <2MM <20MM PASTE .01M 8C1b 8C1f 6F4 6F1a 1:2 <- -PCT -> H2O 167.9 -17- 5.0 6- 18 18- 35 35- 51 51- 90 90-133 133-163 ANALYSES: -16- -15- 7, 4.6 4.4 4.8 5.0 5.9 7.0 6.9 -20- -) H2O 8C1f 1:1 5.3 4.9 5.4 5.8 6.5 7.1 7.5 *** 5960H-003 -004 PRIMARY CHARACTERIZATION DATA (BENTON COUNTY; OREGON ** PRINT DATE 07/23/97 SAMPLED AS : SW) ; FINE SMECTITIC, MESIC VERTIC HAPLOXERALF UNITED STATES DEPARTMENT OF AGRICULTURE NATURAL RESOURCES CONSERVATION SERVICE NATIONAL SOIL SURVEY CENTER SOIL SURVEY LABORATORY LINCOLN, NEBRASKA 68508-3866 SSL - PROJECT 96P 69, (CP960R145) OR-WET-BENTON CO.-96 - PEDON 96P 350, SAMPLES 96P 2723- 2729 - GENERAL METHODS 181A, 2A1, 2B -WACID OXALATE EXTRACTION SAMPLE NO. 96P2723 96P2724 96P2725 96P2726 96P2727 96P2728 96P2729 HZ NO OPT DEN 8J FE SI AL 6C9b 6V2b 6G12b <- P C T o f < 2 m m - > < - 1 2 3 4 5 6 7 0.25 0.20 0.23 0.12 0.09 0.11 PHOSPHOUS CITACID 6S5 RET 6S4b 1.66 2.14 1.83 1.12 0.62 0.82 0.15 0.16 0.19 0.25 0.27 0.28 0.36 0.42 0.45 0.35 0.34 0.33 P KCL MN TOTAL C 6D3b 6A2e P M ->< - -11- -12- -13- -14- -15- -16- -W- -18- -19- -20- (- -WATER CONTENT- - )(- - - - WATER DISPERSIBLE - - - - ) MIN AGGRT 0.06 1215 <- - PIPETTE - - >< - HYDROMETER - > SOIL STABL BAR BAR BAR BAR CLAY SILT SAND CLAY SILT SAND CONT <5mm 481c 4B1a 4Bla 4B2b <- - - 3A1c - - -><- - - SML - - -> 8F1 4G1 - - - ----- -PERCENT of < 2 m m >< PCT> 30.0 31.7 31.0 31.9 38.2 39.8 41.7 PRIMARY CHARACTERIZATION DATA *** S960R-003-004 SAMPLED AS SND ; FINE SMECTITIC, MESIC VERTIC HAPLOXERALF USDA-NRCS-NSSC-SOIL SURVEY LABORATORY ; PEDON 96P 350, SAMPLE 96P 2723- 2729 PRINT DATE 07/25/97 : -1-- -2-- -3-- -4-- -5-- -6-- -7-- -8-- < FRACT < SAMPLE < NUMBER Tab---: 7A2I <- - >< - - - - peak size TCLY TCLY TCLY TCLY 96P2725 96P2727 96P2728 96P2729 MT MT MT MT 3 3 9 3 KK KM VR VR 2 2 2 2 VR KH KK KK 2 2 2 2 >< LE QZ KH KH 1 1 2 2 -10- -11- -12- -13- CLAY MINERALOGY (<,0e2mm) ->< THERMAL >< >< X-RAY ION < -9-- - ILIc---:<5.!0! 1.1.L.!°.! -15- -16- -17- -18- >< ELEMENTAL F...!0! -1g4a -Cr. ...T. .N.!224 Percent >< ->< Percent -14- -19- -20> -> EGME INTER REIN PRETA : -><mg/g>4 - -> QZ 1 SMEC SMEC SMEC SMEC < SAND SILT MINERALOGY (2.0-0.002mm) - ->< THERMAL ->< OPTICAL >< - DTA - ->< - TGA - ->TOT RE< GRAIN COUNT - - 7A21 - - - - >< - 7A3c - >< - yAlm - >< 781a < - ->< - - - Peak Size - - ->< - - - Percent - - - ->< Percent FRACT < SAMPLE NUMBER 96P2725 96P2725 96P2725 X-RAY CSI CSI CSI QZ26 BT 4 60 GS 1 FK17 PO 4 OWtr OP16 CD 3 ZRtr FE11 MS 2 ZEtr > >< >< >< >< ION < < - FP 9 HN 2 GNtr > INTER > PRETA > TION ->< - -> AM 4 PR 1 CRtr FRACTION INTERPRETATION: TCLY Total Clay, <0.002mm Coarse Silt, 0.02-0.05mm CSI MINERAL INTERPRETATION: MT OP CD ZR montmorilion opaques chalcedony zircon RELATIVE PEAK SIZE: KK FE MS ZE kaolinite iron oxides muscovite zeolite 5 Very Large INTERPRETATION (BY HORIZON): SMEC = Smectite PEDON MINERALOGY BASED ON SAND/SILT: BASED ON CLAY: FAMILY MINERALOGY: COMMENTS: 4 Large VR FP HN GN vermiculite plag-feldspa hornblende garnet 3 Medium 2 Small LE AM PR CR lepldocroclt amphibole pyroxene cristobalite 1 Very Small QZ BT GS KH quartz biotite glass halloysite 6 No Peaks FK PO OW potas feldsp plant opal oth-weath mn 212 Appendix B Soil Profile Descriptions 213 PIT 1 Pedon classification: Ultic Haploxeroll Pedon description Al 0 to 7 cm; dark brown (10YR 3/3) loam, brown (10YR 5/3) dry; moderate fine subangular blocky structure; slightly hard, friable; sticky and slightly plastic; many very fine roots; many very fine tubular pores; clear smooth boundary. A2 7 to 19 cm; dark brown (10YR 3/3) loam, brown (10YR 5/3) dry; few fine iron concretions less than 0.5 millimeters in diameter that streak when ped is scraped; moderate fine subangular blocky structure; hard, friable; sticky and slightly plastic; common very fine roots; many very fine tubular pores; gradual smooth boundary. A3 19 to 46 cm; dark brown (10YR 3/3) loam, brown (10YR 5/3) dry; few fine iron concretions less than 0.5 millimeters in diameter; moderate medium subangular blocky structure; hard, friable; sticky and slightly plastic; few very fine roots; many very fine and common fine tubular pores; less than 1 percent sandstone fragments; gradual smooth boundary. BA 46 to 65 cm; brown (10YR 4/3) clay loam, pale brown (10 YR 6/3) dry; few fine faint dark grayish brown (10YR 4/2) depletions along pores; few fine iron concretions less than 0.5 millimeters in diameter; weak medium prismatic structure parting to moderate medium subangular blocky; hard, friable; sticky and slightly plastic; few very fine, few medium, and few coarse roots; many very fine and few fine tubular pores; 1 percent sandstone fragments; gradual smooth boundary. Bwl 65 to 95 cm; yellowish brown (10YR 5/4) clay loam, light yellowish brown (10YR 6/4) dry; few fine faint yellowish brownish (10YR 5/6) masses of iron, faint brownish yellow (10YR 6/6) dry; moderate medium prismatic structure; hard, friable; slightly sticky and slightly plastic; few very fine, few fine, and few medium roots; many very fine and few fine tubular pores; 2 percent sandstone fragments; gradual irregular boundary. Bw2/Crt 95 to 130 cm; The Bw2 part is dark yellowish brown (10YR 4/4) clay loam, light yellowish brown (10YR 6/4) dry. It has weak coarse subangular blocky structure; slightly hard, friable; slightly sticky and slightly plastic; few very fine roots. It contains 50 percent sandstone fragments. The Crt part is light yellowish brown (2.5Y 6/3) and dark yellowish brown (10YR 4/6) weathered sandstone, pale yellow (2.5Y 7/3) and dark yellowish brown (10YR 4/6) dry that has common prominent strong brown (7.5YR 5/8) and dark brown (7.5YR 3/4) iron and clay coatings on fracture planes. Some fracture planes have clay loam accumulations that are 1 to 5 millimeters thick. The horizon has a gradual wavy boundary. 2Crt 130 to 155 cm; weathered and interbedded sandstone and siltstone; few very fine roots along fractures; common distinct clay films on fracture planes. 214 PIT 2 Pedon classification: Aeric Humaquept Pedon description Al 0 to 7 cm; very dark grayish brown (10YR 3/2+) silt loam, brown (10YR 5/3) dry; moderate very fine subangular blocky structure; hard, friable; slightly sticky and slightly plastic; many very fine and common fine roots; clear smooth boundary. A2 7 to 14 cm; very dark grayish brown (10YR 3/2+) silt loam, brown (10YR 5/3) dry; many fine faint yellowish red (5YR 4/6) and strong brown (7.5YR 4/6) masses of iron, distinct yellowish red (5YR 5/6) and strong brown (7.5YR 5/6) dry; moderate very fine subangular blocky structure; hard, friable; slightly sticky and slightly plastic; many very fine and common fine roots; abrupt smooth boundary. A3 14 to 27 cm; very dark grayish brown (10YR 3+/2) silt loam, grayish brown (10YR 5+/2) dry; many fine distinct and common medium distinct dark yellowish brown (10YR 4/6) and dark brown (7.5YR 3/4) masses of iron, prominent yellowish brown (10YR 5/6) and brown (7.5YR 4/4) dry; few fine manganese nodules; moderate medium subangular blocky structure; hard, friable; slightly sticky and slightly plastic; many very fine and common fine roots; common very fine irregular pores; gradual smooth boundary. AB 27 to 36 cm; dark grayish brown (10YR 4/2) silt loam, grayish brown (10YR 5+/2) dry; common fine prominent and few medium prominent dark yellowish brown (10YR 4/6) and strong brown (7.5YR 4/6) masses of iron, yellowish brown (10YR 5/6) and strong brown (7.5YR 5/6) dry; few fine manganese nodules less than 1.0 mm in diameter; weak coarse subangular blocky structure; hard, friable; sticky and slightly plastic; many very fine and common fine roots; common very fine tubular pores; gradual smooth boundary. B/E 36 to 50 cm; 35 percent dark grayish brown (10YR 5/2), grayish brown (10YR 6/2) dry and 65 percent dark yellowish brown (10YR 4/4) and strong brown (7.5YR 4/6) silt loam, light yellowish brown (10YR 6/4) and strong brown (7.5YR 5/6) dry; planar faces of peds have low chroma depletion about 1.0 mm thick; few fine manganese nodules less than 2 millimeters in diameter; weak medium prismatic structure parting to moderate medium subangular blocky; hard, friable; sticky and slightly plastic; common very fine roots; common very fine vesicular pores; clear smooth boundary. E/ B 50 to 70 cm; 60 percent grayish brown (10YR 5/2), light gray (10YR 7/2) dry and 40 percent yellowish brown (10YR 5/6) and strong brown (7.5YR 4/6) silty clay loam, brownish yellow (10YR 6/6) and strong brown (7.5YR 5/6) dry; planar faces of peds are more strongly depleted and have thicker layer of depletion than horizon above; few fine manganese nodules less than 2 millimeters in diameter; moderate medium prismatic structure parting to moderate coarse subangular blocky; hard, friable; 215 sticky and slightly plastic; few very fine roots; common very fine vesicular pores; abrupt wavy boundary. 2Bt1 70 to 92 cm; grayish brown (2.5Y 5/2) silty clay, light brownish gray (2.5Y 6/2) dry; many fine distinct strong brown (7.5YR 5/6) and strong brown (7.5YR 5 / 8) masses of iron, distinct reddish yellow (7.5YR 6 / 6) and reddish yellow (7.5YR 6/8) dry; massive structure; very hard, very firm; sticky and plastic; few very fine roots; few very fine tubular pores; few distinct clay films in pores; very few distinct slickensides; gradual wavy boundary. 3Bt2 92 to 109 cm; light olive brown (2.5Y 5/3+) silty clay, light olive brown (2.5Y 6/3+) dry; common fine faint yellowish brown (10YR 5/8) masses of iron, faint brownish yellow (10YR 6/8) dry; few fine iron nodules and few fine manganese concretions; massive structure; very hard, very firm; sticky and plastic; few very fine roots; few very fine tubular pores; few distinct clay films in pores; few distinct slickensides; 2 percent sandstone fragments; gradual smooth boundary. 3Bss 109 to 142 cm; olive brown (2.5Y 4/4) silty clay, light yellowish brown (2.5Y 6/4) dry; common medium distinct olive gray (5Y 5/2) depletions along pores; common fine faint brownish yellow (10YR 5/8) masses of iron, faint yellowish brown (10YR 6/8) dry; few fine iron nodules and few fine manganese concretions; massive structure; very hard, very firm; sticky and plastic; few very fine roots; few very fine tubular pores; few distinct clay films in pores; common prominent slickensides; 2 percent sandstone fragments; gradual smooth boundary. 4BCt1 142 to 155 cm; light yellowish brown (2.5Y 6/3), strong brown (7.5YR 5/6), and strong brown (7.5YR 4/6) silty clay loam, pale yellow (2.5Y 7/3), reddish yellow (7.5YR 6/6), and strong brown (7.5YR 5/6) dry with yellowish brown (10YR 5/8) areas of less weathered sandstone, brownish yellow (10YR 6/8) dry; very few prominent black (N 2.5/) manganese stains on fracture planes; few very fine roots; few very fine tubular pores; very few prominent clay films along root channels; few fine prominent white gypsum crystal clusters; abrupt broken boundary. 4BCt2 155 to 170 cm; light yellowish brown (2.5Y 6/3) silty clay loam, pale yellow (2.5Y 7/3) dry with light yellowish brown (2.5Y 6/4) and brownish yellow (10YR 6/8) areas of less weathered sandstone, pale yellow (2.5Y 7/4) and yellow (10YR 7/8) dry; very few prominent black (N 2.5/) manganese stains on fracture planes; few very fine roots; very few prominent clay films along root channels. 216 PIT 3 Pedon classification: Vertic Epiaquept Pedon description Al 0 to 7 cm; very dark grayish brown (10YR 3/2+) silt loam, grayish brown (10YR 5/2+) dry; moderate medium granular structure; slightly hard, friable; slightly sticky and slightly plastic; many very fine roots; clear smooth boundary. A2 7 to 16 cm; dark grayish brown (10YR 4/2) silt loam, grayish brown (10YR 5+/2) dry; common distinct strong brown (7.5YR 4/6) oxidized rhizospheres; many fine distinct yellowish red (5YR 4/6) and strong brown (7.5YR 4/6) masses of iron, prominent yellowish red (5YR 5/6) and strong brown (7.5YR 5/6) dry; few fine manganese-iron concretions; weak coarse subangular blocky structure parting to moderate fine subangular blocky; hard, friable; slightly sticky and slightly plastic; many very fine roots; clear smooth boundary. B/E 16 to 27 cm; 30 percent dark grayish brown (10YR 4/2+), light brownish gray (10YR 6/2+) dry and 50 percent dark yellowish brown (10YR 4/6) and strong brown (7.5YR 4/6), yellowish brown (10YR 5/6) and strong brown (7.5YR 5/6) dry and 20 percent dark yellowish brown (10YR 4/4) silt loam, yellowish brown (10YR 5/4) dry; few distinct strong brown (7.5YR 5/8) oxidized rhizospheres; few fine manganese-iron concretions less than 1.0 mm in diameter; common prominent black (N 2.5/) manganese stains on ped faces; moderate medium subangular blocky structure; very hard, firm; slight sticky and slightly plastic; common very fine and few fine roots; few fine tubular pores; clear smooth boundary. E/B 27 to 42 cm; 50 percent grayish brown (10YR 5/2), light gray (10YR 7/2) dry and 35 percent yellowish brown (10YR 5/6) and strong brown (7.5YR 5/6) silty clay loam, brownish yellow (10YR 6/6) and reddish yellow (7.5YR 6/6) dry; 15 percent common fine distinct strong brown (7.5YR 4/6) masses of iron, distinct strong brown (7.5YR 5/6) dry; few fine manganese-iron concretions less than 1.0 mm in diameter; moderate coarse subangular blocky structure; very hard, firm; sticky and plastic; common very fine roots; few fine tubular pores; abrupt wavy boundary. 2Bt 42 to 91 cm; dark grayish brown (2.5Y 4/2) silty clay, light brownish gray (2.5Y 6/2) dry; many fine prominent yellowish brown (10YR 5/8) masses of iron, prominent brownish yellow (10YR 6/8) dry; few fine iron concretions; massive structure; very hard, firm; sticky and plastic; common very fine roots; few distinct clay films along root channels; few distinct slickensides starting at 65 cm; gradual smooth boundary. 3Bss 91 to 120 cm; dark grayish brown (2.5Y 4/2) and light olive brown (2.5Y 5/3) silty clay, light brownish gray (2.5Y 6/2) and light yellowish brown (2.5Y 6/3) dry; common fine faint yellowish brown (10YR 5/6) masses of iron, faint yellowish brown (10YR 5/6) dry; few fine iron concretions; few fine distinct black (N 2.51) masses of manganese; massive structure; very hard, firm; sticky and plastic; few very fine roots; few faint clay films 217 along root channels; many distinct slickensides; gradual smooth boundary. 3Bsstyl 120 to 135 cm; light olive brown (2.5Y 5/4) and light olive brown (2.5Y 5/3) clay, light yellowish brown (2.5Y 6/4) and light yellowish brown (2.5Y 6/3) dry; common fine faint yellowish brown (10YR 5/6) masses of iron, faint yellowish brown (10YR 5/6) dry; common fine black manganese nodules; few fine prominent black (N 2.5/) masses of manganese; massive structure; very hard, firm; sticky and plastic; few very fine roots; few very fine tubular pores; very few faint clay films along root channels and few distinct clay films on ped faces; many distinct slickensides; 1 percent sandstone fragments; few medium distinct and few fine distinct clear gypsum crystals and few fine and few medium prominent white gypsum crystal clusters; gradual smooth boundary. 3Bssty2 135 to 153 cm; light olive brown (2.5Y 5/4) silty clay, light yellowish brown (2.5Y6/4) dry; few fine manganese nodules; few prominent black (N 2.5/) manganese stains on ped faces; few distinct black (N 2.5/) manganese coatings on sandstone fragments; weak coarse subangular blocky structure; very hard, firm; sticky and plastic; few very fine roots; few prominent clay films along root channels and few distinct clay films on ped faces; many distinct slickensides; 5 percent sandstone fragments; few fine prominent white gypsum crystal clusters; gradual smooth boundary. 4BCt 153 to 175 cm; light yellowish brown (2.5Y6/3) and yellowish brown (10YR 5/8) silty clay loam, pale yellow (2.5Y 7/3) and brownish yellow (10 YR 6/8) dry; common prominent black (N2.5/) manganese stains on fracture planes; few very fine roots; few distinct clay films along root channels and few distinct clay films on fracture planes. 218 PIT 4 Pedon classification: Typic Endoaquert Pedon description Al 0 to 6 cm; very dark gray (10YR 3/1) silt loam, dark gray (10YR 4/1) dry; many distinct strong brown (7.5YR 4/6) oxidized rhizospheres; moderate medium granular structure; slightly hard, friable; slightly sticky and slightly plastic; many very fine roots; clear smooth boundary. A2 6 to 18 cm; very dark gray (10YR 3/1) silt loam, dark gray (10YR 4/1) dry; many distinct strong brown (7.5YR 5/8) oxidized rhizospheres; many fine distinct strong brown (7.5YR 4/6), many fine faint dark brown (7.5YR 3/4), and common fine distinct yellowish red (5YR 4/6) masses of iron, faint strong brown (7.5YR 5/8) and strong brown (7.5YR 4/6) and faint yellowish red (5YR 5/8) dry; very few faint black (N 2.5/) manganese stains on ped faces; moderate fine subangular blocky structure; hard, friable; sticky and slightly plastic; many very fine roots, common very fine pores; clear smooth boundary. AB 18 to 35 cm; very dark gray (10YR 3/1) silty clay loam, dark gray (10YR 4/1) dry; few distinct strong brown (7.5YR 5/8) oxidized rhizospheres; many fine distinct strong brown (7.5YR 4/6) and common fine faint dark reddish brown (5YR 3/4) masses of iron, prominent strong brown (7.5YR 5/6) and distinct reddish brown (5YR 4/4) dry; isolated areas of many medium distinct yellowish red (5YR 4/6) masses of iron, yellowish brown (5YR 5/6) dry; few fine faint iron concentrations; common medium distinct manganese-iron cemented granular peds; common fine manganese nodules; few distinct black (N 2.5/) manganese stains on ped faces; moderate fine subang-ular blocky structure; hard, friable; sticky and plastic; many very fine roots, common very fine pores; clear smooth boundary. BA 35 to 51 cm; black (10YR 2/1) silty clay loam, very dark gray (10YR 3/1) dry; many fine distinct strong brown (7.5YR 4/6) and common fine faint dark brown (7.5YR 3/4) masses of iron, prominent strong brown (7.5YR 5/6) and (7.5YR 4/6) dry; common medium distinct manganese-iron cemented granular peds; moderate fine subangular blocky structure; hard, friable; sticky and plastic; common very fine roots; common very fine pores; 1 percent basalt fragments; clear wavy boundary. Bt 51 to 90 cm; black (10YR 2/1) silty clay, very dark gray (10YR 3/1) dry; few fine and medium manganese nodules; moderate coarse prismatic structure when dry; extremely hard, firm; sticky and plastic; few very fine roots; few very fine pores; few faint clay films; very few distinct slickensides; clear smooth boundary. Bssl 90 to 133 cm; black (10YR 2/1) silty clay, very dark gray (10YR 3/1) dry; few fine faint dark yellowish brown (10YR 3/4) masses of iron, dark yellowish brown (10YR 4/4) dry; moderate medium prismatic structure when dry; extremely hard, firm; sticky and plastic; few very fine roots; few very fine pores; common distinct slickensides; clear wavy boundary. 219 Bss2 133 to 163 cm; black (10YR 2/1) silty clay, very dark gray (10YR 3/1) dry; few fine faint dark yellowish brown (10YR 3/4) masses of iron, dark yellowish brown (10YR 4/4) dry; massive structure; extremely hard, firm; sticky and plastic; few very fine roots; many distinct slickensides. 220 Appendix C Field Measurement Data 221 KEY FOR FIELD MEASUREMENT DATA Instrument* identification: W = well P E = piezometer = platinum electrode TC = thermocouple DO = dissolved oxygen *instrument depths in centimeters *instrument replication given as 1,2, or 3 (if applicable) Example: P-75-2 Data record is for a piezometer at the 75 cm and is the second replicate instrument at this depth for this soil plot. Data identification: Field data piezometer measurements adjusted to subtract the length of piezometric pipe that extended above the soil surface. all other measurements unadjusted. Corrected (Average) average values of replicated field data. electrode data corrected to a standard hydrogen electrode value (Eh) by adding +244mV. electrode data adjusted by factor of -59mV for each soil pH unit change from pH 7. Raw PZ data readings taken in the field without any adjustments. Miscellaneous: Highlighted data - extrapolated data that was filled in to facilitate graphing. 222 WITHAM HILL DATA Field Data W-100 Site 1 Benton County 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 -27.8 -14.9 -7.3 -6.9 P-75-1 P-75-2 P-75-3 P-35-1 -17.8 -6.7 0.3 P-35-2 P-35-3 P-20-1 -5.8 -4.7 -4.5 P-20-2 P-20-3 E-50-1 E-50-2 E-50-3 E-30-1 E-30-2 E-30-3 377 333 390 109 64 74 80 163 149 322 341 301 325 295 338 282 382 102 167 156 368 80 165 149 230 227 240 213 332 288 308 274 344 250 336 282 337 340 347 11.9 11.3 11.3 14.4 11.3 10.2 8.8 1.4 10.5 10.4 10.6 13.3 10.7 10.0 9.6 351 E-10-1 E-10-2 E-10-3 375 372 387 TC-50 TC-30 TC-10 AMBIENT 11.8 10.4 7.5 377 351 DO-W100 11.8 D075-1 D075-2 D075-3 10.6 10.4 D035-1 D035-2 D035-3 9.3 9.7 11.2 D020-1 D020-2 D020-3 8.7 9.2 9.4 Corrected Average -98.1 9.1 9.4 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 W-100 P-75 P-35 P-20 -27.8 -9.7 -8.0 -5.0 -98.1 E-50 E-30 E-10 504 496 547 219 300 535 268 289 402 453 436 478 462 447 TC-50 TC-30 TC-10 AMBIENT 11.8 10.4 7.5 11.9 11.3 11.3 14.4 11.3 10.2 8.8 1.4 10.5 10.4 10.6 13.3 10.7 10.0 9.6 2.51 0.26 2.96 3.74 2.71 6.38 0.66 7.52 3.38 Dec 8.59 9.50 6.88 PPT in. PPT cm DO 100 DO 75 DO 35 0.06 Oct 0.15 2.26 0.55 0.82 5.74 1.40 2.08 0.7 Nov 1.78 11.8 10.1 10.1 511 9.1 223 WITHAM HILL DATA 10\ 10 \ 95 DO 20 Benton County Site 1 10/17/95 10/24/95 10 \ 31 \95 11 \07\95 95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 9.1 Saturation (graphing) 20 cm 35 cm 75 cm Data Lines (graphing) 2 1 350 200 5 1.5 350 200 5 1.5 350 200 5 350 200 5 350 200 5 1.5 1.5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 76.5 69.7 78.5 79.0 2.0 Solution pH 75 cm 35 cm 20 cm A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 20.0 32.8 41.0 16.5 17.8 18.0 224 WITHAM HILL DATA 12/26/95 1/02/96 Site 1 1/12/96 Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 1/26/96 -39.5 -21.5 -13.0 -14.0 -63.0 -42.5 -34.0 -30.5 -22.0 -2.0 1.0 -10.5 -58.0 -32.0 -13.5 -13.5 -27.0 -19.0 -8.0 0.0 4.0 -17.5 -11.5 -2.0 -3.5 -6.0 -14.0 -20.5 0.0 P-20-1 P-20-2 P-20-3 E-50-1 1/19/96 -25.5 -4.0 P-35-2 P-35-3 Benton County 2/02/96 -12.5 -11.5 -6.0 2109/96 2/17/96 2/23/96 3/01/96 3/08/96 369 297 394 370 288 389 367 287 389 238 383 333 261 371 351 368 256 415 399 366 376 332 359 364 380 9.3 8.6 7.4 5.8 7.7 7.5 6.7 14.3 10.3 10.7 11.9 15.0 3/01/96 3/08/96 485 368 334 389 328 305 376 334 312 410 343 336 378 245 384 337 376 212 370 217 342 349 364 279 364 308 364 310 372 300 378 318 331 330 352 8.8 7.2 4.5 2.9 9.3 9.2 8.9 12.2 10.2 9.5 8.6 8.0 9.4 8.3 8.2 9.1 7.1 5.8 D0-W100 15.4 10.1 9.3 9.2 D075-1 D075-2 D075-3 12.1 11.8 10.9 11.3 11.3 8.4 8.2 7.7 0035-1 D035-2 D035-3 12.8 10.3 D020-1 D020-2 D020-3 11.8 E-50-2 E-50-3 E-30-1 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT Corrected Average 402 384 13.5 12.1 288 255 321 192 311 270 324 298 314 8.3 7.1 352 195 348 343 372 354 328 240 317 395 342 289 324 232 346 353 365 398 340 7.0 5.4 2.7 3.5 9.5 9.4 9.4 10.7 9.0 9.5 9.5 12.2 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 -39.5 -16.2 -9.8 -10.0 -63.0 -35.7 -23.0 489 490 507 425 416 467 453 521 489 475 518 481 501 TC-50 TC-30 TC-10 AMBIENT 8.8 7.2 4.5 2.9 9.3 9.2 8.9 12.2 10.2 9.5 8.6 8.0 9.4 8.3 8.2 9.1 7.1 5.8 PPT in. 0.08 1.5 Jan 1.75 3.26 4.09 3.81 4.45 480 557 0.20 473 424 311 396 12.8 8.8 8.2 8.8 8.9 E-50 E-30 E-10 DO 100 DO 75 DO 35 313 314 351 12.1 W-100 P-75 P-35 P-20 PPT cm 328 276 386 2/02/96 8.9 7.1 8.1 7.9 8.8 9.7 5.7 5.3 7.7 10.2 9.8 2/09/96 2/17/96 7.1 490 468 537 490 482 521 463 475 488 531 486 478 563 7.0 5.4 2.7 3.5 9.5 9.4 9.4 10.7 9.0 9.5 9.5 12.8 9.3 8.6 7.4 5.8 7.7 7.5 6.7 14.3 10.3 10.7 11.9 15.0 1.27 6.5 0.04 0.55 March 11.38 1.40 1.73 Feb 8.28 10.39 15.4 12.5 11.7 10.1 11.2 8.9 2/23/96 -58.0 -19.7 -14.5 -17.3 -22.0 -3.8 -1.3 -3.8 8.3 330 386 3.23 16.51 9.3 8.5 8.0 0.10 4.48 9.2 8.3 8.8 481 537 4.39 225 WITHAM HILL DATA 12/26/95 1/02/96 Site 1 1/12/96 DO 20 1/19/96 12.0 1/26/96 Benton County 2/02/96 2/09/96 2/17/96 3/01/96 3/08/96 350 200 350 200 350 200 5 1.5 5 1.5 5 1.5 6.2 2/23/96 10.0 Saturation (gr; 20 cm 35 cm 75 cm Data Lines (graphing) 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 3 2 2 3 2 3 2 1 1 1 1 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 Solution pH 75 cm 35 cm 20 cm 5.24 5.20 5.27 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-2 P-75-3 65.0 61.5 54.0 52.5 88.5 82.5 75.0 69.0 P-35-1 P-35-2 P-35-3 55.5 35.0 29.0 58.0 48.0 P-20-1 30.5 30.0 25.0 P-75-1 P-20-2 P-20-3 47.5 42 40 49 83.5 72.0 54.5 52.0 38 31 25 20 22 25 48.5 40.5 32.5 39.5 226 WITHAM HILL DATA 3/15/96 3/23/96 Site 1 3/30/96 4/04/96 4111196 Field Data Benton County 4/18/96 W-100 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 353 345 395 358 362 394 362 334 389 362 334 389 254 379 320 416 254 373 222 365 327 369 383 393 222 365 327 369 383 393 13.3 13.9 16.5 24.0 -88.0 -65.0 -58.5 -58.5 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-50-1 355 E-50-2 E-50-3 281 E-30-1 378 330 394 368 324 385 370 319 390 363 470 314 356 380 370 302 395 260 378 358 419 393 349 262 379 362 423 399 342 288 368 348 398 369 339 305 369 358 400 403 293 274 402 354 227 E-10-2 E-10-3 242 367 340 403 370 370 374 353 322 393 325 353 TC-50 TC-30 TC-10 AMBIENT 9.2 9.7 11.4 17.7 10.8 10.5 10.3 10.2 9.8 10.3 12.8 10.3 10.9 10.6 18.6 12.6 12.9 11.8 10.0 12.2 12.0 10.7 9.2 11.4 11.7 11.3 11.3 E-30-2 E-30-3 E-10-1 13.1 321 311 368 371 DO-W100 5.7 D075-1 5.0 5.2 5.0 D075-2 D075-3 391 404 331 389 355 399 12.2 12.8 13.1 17.2 12.8 12.7 12.5 15.1 13.7 14.7 14.8 18.7 5/04/96 5/09/96 5/16/96 5/24/96 501 508 477 550 499 463 499 463 551 551 12.2 12.8 13.3 13.9 16.5 24.0 D035-1 D035-2 D035-3 D020-1 D020-2 D020-3 Corrected Average 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 W-100 P-75 P-35 P-20 4/25/96 -88.0 -60.7 E-50 E-30 E-10 476 474 550 493 490 556 504 492 557 496 493 538 497 502 535 519 519 482 465 526 TC-50 TC-30 TC-10 AMBIENT 9.2 9.7 11.4 17.7 10.8 10.5 10.3 13.1 10.2 9.8 10.3 12.8 10.3 10.9 10.6 18.6 12.6 12.9 11.8 10.0 12.2 12.0 10.7 9.2 11.4 11.7 11.3 11.3 PPT in. 0.43 0.2 0.7 0.98 0.78 0.72 2.9 501 April PPT cm DO 100 DO 75 DO 35 1.09 0.51 1.78 476 573 13.1 12.8 12.7 12.5 17.2 15.1 13.7 14.7 14.8 18.7 0.06 0.17 1.63 2.04 0.15 0.43 4.14 5.18 May 2.49 1.98 1.83 7.37 5.7 5.1 227 WITHAM HILL DATA 3/15/96 3/23/96 Site 1 3/30/96 4/04/96 4/11/96 DO 20 Benton County 4/18/96 4/25196 5/04/96 5/09/96 5/16/96 5/24/96 350 200 350 200 5 1.5 5 1.5 Saturation (gn 20 cm 35 cm 75 cm Data Lines (graphing) 1 350 200 350 200 5 5 1.5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 350 200 350 200 5 1.5 5 1.5 5 350 200 5 1.5 1.5 Solution pH 75 cm 35 cm 20 cm A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 113.5 105 99.5 97 228 Benton County Site 1 WITHAM HILL DATA 5/30/96 6/14/96 6/21/96 E-50-1 361 322 380 365 325 383 311 E-50-2 E-50-3 E-30-1 168 369 E-10-3 216 369 320 302 389 378 TC-50 TC-30 TC-10 AMBIENT 14.2 14.6 14.4 16.2 15.5 16.2 18.7 25.9 16.8 21.3 5/30/96 6/14196 6/21/96 491 460 526 495 439 432 470 442 TC-50 TC-30 TC-10 AMBIENT 14.2 14.6 14.4 16.2 15.5 16.2 18.7 25.9 15.2 16.8 21.3 PPT in. 0.11 0 0.1 6/28/96 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-30-2 E-30-3 E-10-1 E-10-2 307 308 193 287 332 357 169 382 301 298 264 343 355 347 396 358 350 402 352 346 403 140 375 347 136 381 349 362 370 287 403 184 375 353 334 291 394 15.2 242 389 176 297 346 341 273 366 291 393 16.6 16.7 16.9 25.6 16.1 331 12.8 12.3 11.4 12.0 14.6 13.2 10.8 12.1 DO-W100 0075-1 0075-2 0075-3 0035-1 0035-2 D035-3 D020-1 0020-2 0020-3 Corrected Average 6/28/96 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 W-100 P-75 P-35 P-20 E-50 E-30 E-10 503 445 518 471 16.1 0.75 507 447 523 504 462 509 16.6 16.7 16.9 25.6 14.6 13.2 10.8 0 DO 100 DO 75 DO 35 0.28 0.25 1.91 431 496 12.1 0.39 1.37 June PPT cm 458 0.99 3.48 2.17 Oct 1.39 5.51 3.53 0.45 Nov 1.14 229 WITHAM HILL DATA Benton County Site 1 5/30/96 6/14/96 6/21/96 6/28/96 350 200 5 1.5 350 200 350 200 5 1.5 1.5 350 200 5 1.5 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 DO 20 Saturation (gri 20 cm 35 cm 75 cm Data Lines (graphing) Solution pH 75 cm 35 cm 20 cm A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data w-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 230 WITHAM HILL DATA Field Data Benton County Site 1 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 W-100 -34.5 -18.5 -14.5 -22.5 -34.5 -19.5 -13.5 -19.5 -60.0 -43.0 -37.0 -43.0 -21.0 -9.0 -4.5 -23.0 -7.0 -6.0 -30.0 -23.5 -13.0 -11.5 -11.5 -12.5 -11.5 -12.0 306 278 291 361 327 325 399 294 292 373 313 314 341 306 290 364 193 325 334 356 323 312 209 348 369 390 338 372 173 279 338 340 284 336 8.6 7.5 5.5 6.5 8.0 7.5 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-50-1 E-50-2 E-50-3 323 230 373 320 332 356 E-30-1 150 266 341 348 269 348 163 314 329 335 338 297 11.5 10.8 10.1 10.1 8.1 10.0 5.5 316 1/11/97 -22.0 -2.0 1/20/97 -10.5 -61.5 -38.5 -33.5 -29.5 -8.0 0.0 4.0 -23.5 -15.5 1.0 -2.0 -3.5 -6.0 -21.5 337 352 386 351 240 317 395 342 289 324 215 318 362 354 353 201 9.5 9.4 9.4 10.7 8.7 8.6 8.6 9.5 351 350 395 161 186 289 310 313 319 288 345 329 350 9.5 8.9 9.3 11.6 9.7 9.4 9.3 11.8 10.3 10.2 9.9 DO-W100 8.6 7.2 9.3 9.7 D075-1 D075-2 D075-3 8.2 7.1 8.1 8.2 6.6 5.7 8.4 8.8 8.2 9.9 9.5 9.4 D035-1 D035-2 D035-3 8.9 7.8 7.7 6.8 6.2 6.7 7.1 8.1 9.5 8.8 9.1 D020-1 D020-2 D020-3 7.7 7.6 6.7 4.3 2.8 4.4 5.7 5.3 7.7 9.0 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT Corrected Average 9.0 321 332 8.1 7.1 9.6 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 W-100 P-75 P-35 P-20 E-50 E-30 E-10 446 410 TC-50 TC-30 TC-10 AMBIENT PPT in. -34.5 -18.5 -11.5 -12.0 -34.5 -17.5 -12.0 -12.0 457 442 500 495 456 515 502 460 527 518 464 522 8.0 7.5 8.7 8.6 8.6 9.5 8.1 9.6 9,5 9.4 9.4 10.7 8.0 8.3 10.2 7.9 7.0 5.8 2.3 4.43 6.8 0.52 2.25 0.8 1.32 5.72 2.03 11.5 10.8 10.1 10.1 8.1 5.5 9.7 9.4 9.3 11.8 10.3 10.2 9.9 10.0 9.5 8.9 9.3 11.6 8.1 8.6 7.5 5.5 6.5 0.57 6.58 2.46 3.08 5.02 0.69 DO 100 DO 75 DO 35 16.71 6.25 1/25/97 463 475 488 476 1.45 1/20/97 7.9 7.0 5.8 2.3 457 421 489 7.1 Dec PPT cm 8.0 8.3 10.2 487 467 536 460 445 504 9.0 1/11/97 8.1 212 318 388 378 327 353 -22.0 -3.8 -1.3 -3.8 445 491 331 336 369 382 329 363 373 363 408 -60.0 -41.0 -26.8 473 427 493 411 1/25/97 -61.5 -33.8 -19.5 -21.5 Jan 7.82 12.75 8.6 8.2 7.2 6.5 6.6 8.1 1.75 11.25 17.27 9.3 8.5 8.0 9.7 9.6 9.3 231 WITHAM HILL DATA DO 20 Site 1 Benton County 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 7.3 3.8 6.2 1/11/97 1/20/97 9.0 1/25/97 Saturation (gri 20 cm 35 cm 75 cm Data Lines (graphing) 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 3 3 3 3 2 2 2 2 2 1 1 1 1 1 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 Solution pH 75 cm 35 cm 20 cm 5.78 5.87 6.12 4.54 5.55 5.81 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 no no no no no no 60 58.5 55.5 60 59.5 54.5 61 58 P-35-1 P-35-2 P-35-3 51 53 40 33.5 38 35 P-20-1 31 P-20-2 P-20-3 30 30.5 30.5 30 31 85.5 83 78 81.5 47.5 42 40 49 87 78.5 74.5 68 38 61 31 52.5 25 20 22 25 54.5 44.5 40 350 200 5 1.5 232 WITHAM HILL DATA 2/01/97 Benton County Site 1 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 341 341 310 325 369 314 306 314 300 336 366 297 397 323 371 323 307 386 201 204 211 341 373 365 356 199 373 207 319 352 348 289 347 Field Data W-100 P-75-1 P-75-2 P-75-3 -48.5 -26.5 -19.5 -21.0 P-35-1 P-35-2 P-35-3 -28.5 -8.5 -4.0 P-20-1 P-20-2 P-20-3 -13.0 -11.0 -12.5 E-50-1 E-50-2 E-50-3 345 343 387 353 347 395 350 338 384 347 340 388 E-30-1 203 E-30-2 E-30-3 311 202 339 364 370 195 356 359 358 198 369 381 346 321 374 314 372 282 368 8.0 7.4 6.8 7.5 7.8 7.9 7.7 15.5 8.7 8.5 6.9 7.2 8.2 8.2 7.6 8.4 8.7 8.1 2/08/97 2/15/97 2/22/97 461 495 474 E-10-2 E-10-3 359 386 322 339 TC-50 TC-30 TC-10 AMBIENT 8.0 8.6 8.6 9.9 E-10-1 DO-W100 10.5 D075-1 10.6 10.3 9.3 D075-2 D075-3 D035-1 D035-2 D035-3 7.4 D020-2 D020-3 10.1 7.1 W-100 P-75 P-35 P-20 388 344 389 200 364 367 318 355 398 10.2 10.7 9.7 14.6 10.4 10.6 9.5 13.2 10.3 10.3 9.3 17.3 10.2 10.3 10.3 11.8 8.7 8.8 9.4 14.2 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 494 462 503 472 449 497 467 455 506 476 474 538 454 468 517 490 468 526 482 8.4 8.7 9.1 11.8 8.7 8.8 9.4 14.2 10.2 10.7 9.7 14.6 10.4 10.6 9.5 13.2 10.3 10.3 9.3 17.3 10.2 10.3 10.3 2.45 2.11 1.22 0.23 0.45 April 0.35 6.22 5.36 3.10 0.58 1.14 0.89 194 343 375 336 293 371 2/01/97 9.1 346 348 309 353 361 359 311 391 370 316 364 400 13.1 -48.5 -22.3 -13.7 -12.2 E-50 E-30 E-10 495 449 518 502 460 524 494 517 501 TC-50 TC-30 TC-10 AMBIENT 8.0 8.6 8.6 9.9 8.0 7.4 6.8 7.5 7.8 7.9 7.7 15.5 8.7 8.5 6.9 7.2 8.2 8.2 7.6 PPT in. 3.31 0.24 Feb 0.41 0.75 PPT cm 8.41 0.61 1.04 1.91 0.35 Mar 0.89 DO 100 DO 75 DO 35 311 401 10.3 9.0 9.4 D020-1 Corrected Average 388 10.5 10.1 9.6 8.1 481 529 13.1 233 WITHAM HILL DATA 2/01197 DO 20 Site 1 Benton County 2108197 2115/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 350 200 5 1.5 350 200 5 1.5 350 200 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 8.2 Saturation (gn 20 cm 35 cm 75 cm Data Lines (graphing) 3 2 1 350 200 5 1.5 5 1.5 Solution pH 75 cm 35 cm 20 cm A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 no no no 74 66.5 60.5 59.5 58.5 39.5 33 P-20-1 31 P-20-2 P-20-3 29.5 31.5 no no no 234 WITHAM HILL DATA Site 1 Benton County 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 E-50-1 E-50-2 E-50-3 326 327 406 301 327 382 305 308 384 316 330 402 327 336 419 331 E-30-1 E-30-2 E-30-3 217 360 380 326 357 396 34 360 196 356 342 314 357 211 378 371 162 219 312 142 133 297 287 348 324 270 354 204 336 360 329 362 390 11.7 12.3 12.8 17.0 12.2 12.8 14.4 25.4 12.3 12.6 13.0 14.2 13.7 14.9 16.8 27.4 15.2 16.7 19.5 29.8 15.2 15.3 15.4 11.8 16.2 16.9 17.3 21.1 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 6/01/97 E-50 E-30 E-10 490 477 529 474 346 523 469 456 517 486 470 481 389 552 514 485 498 458 530 360 561 TC-50 TC-30 TC-10 12.2 12.8 14.4 25.4 12.3 12.6 13.0 14.2 13.7 14.9 16.8 27.4 15.2 16.7 19.5 29.8 15.2 15.3 15.4 16.2 16.9 17.3 AMBIENT 11.7 12.3 12.8 17.0 11.8 21.1 PPT in. 0.68 1.88 0.68 0.11 0 0.37 Field Data 5/24/97 6/01/97 316 402 335 507 6107/97 W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT 171 317 357 387 386 331 449 395 359 421 DO-W100 0075-1 D075-2 D075-3 D035-1 D035-2 D035-3 0020-1 0020-2 0020-3 Corrected Average W-100 P-75 P-35 P-20 May PPT cm DO 100 DO 75 DO 35 1.73 4.78 1.73 1.58 6/07/97 1.09 June 0.28 0.94 4.01 2.77 235 WITHAM HILL DATA Site 1 Benton County 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 6/01/97 6/07/97 350 200 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 350 200 350 200 350 200 5 1.5 5 1.5 5 1.5 DO 20 Saturation (gr 20 cm 35 cm 75 cm Data Lines (graphing) 5 1.5 1.5 Solution pH 75 cm 35 cm 20 cm A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 no no no no no no 236 WITHAM HILL DATA Field Data Site 2 Benton County 10\10\95 10/17/95 10/24/95 10\31\95 11\07195 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 W-100 -94.1 -94.8 -88.3 -60.5 -72.8 -60.8 -68.9 -66.9 -63.2 -14.0 -14.7 -10.9 -19.0 -13.2 -13.8 -9.4 -18.7 -13.2 P-35-1 P-35-2 P-35-3 -13.9 -10.2 -6.5 -13.1 -11.4 -9.0 -10.6 -6.1 -6.5 -12.6 -9.4 -12.2 P-20-1 P-20-2 P-20-3 -16.7 -12.2 -9.7 -18.3 -12.2 -8.4 -15.7 -11.8 -4.5 -17.8 -14.0 -7.8 384 163 379 264 216 299 266 174 -153 177 34 94 P-75-1 P-75-2 P-75-3 332 364 E-50-1 E-50-2 E-50-3 341 248 280 328 E-30-1 E-30-2 E-30-3 E-10-1 60 35 59 E-10-2 E-10-3 306 326 324 240 285 302 232 83 116 265 291 286 257 263 266 132 84 62 305 87 333 46 -151 53 4 21 -1 15 -1 11 8 -5 18 10 -2 -4 349 315 -11 -51 353 215 223 262 334 303 308 285 342 254 144 180 111 TC-50 TC-30 TC-10 AMBIENT 59 -36.2 -16.5 -20.7 -10.0 -37.9 13 -9 -83 -16 213 72 124 -73 -7 46 49 -3 148 25 25 148 158 267 -18.1 -9.1 9 11 -2 160 16 33 11.5 10.3 8 11.9 11.4 11.3 13.5 10.9 10.2 10.3 9.9 10.0 9.6 9.2 10.1 9.1 1.5 11.8 9.2 5.1 8.1 8.2 5.2 6.0 0075-1 D075-2 D075-3 4.5 4.3 9.0 4.4 2.2 4.0 5.4 1.8 2.0 3.8 1.7 0035-1 D035-2 0035-3 4.7 6.9 9.6 2.4 2.6 5.3 2.3 2.2 2.3 2.0 2.0 0020-1 D020-2 D020-3 7.2 8.3 4.9 3.8 4.0 2.8 12.1 DO-W100 Corrected Average -94.1 530 463 226 503 453 318 465 440 267 -94.8 -88.3 167 178 175 426 193 183 -60.5 -66.8 -68.9 415 374 489 316 411 394 TC-50 TC-30 TC-10 AMBIENT 0.06 2.26 0.55 0.82 Oct D075 DO 35 DO 20 -14.0 -14.9 -10.2 -12.9 493 437 405 -13.2 -14.0 -10.9 -13.0 -13.2 -21.2 -8.0 -10.7 -16.5 -22.9 -11.4 -13.2 251 270 162 208 149 184 311 241 244 11.5 10.3 8.0 11.9 11.4 11.3 13.5 10.9 10.2 9.2 1.5 10.3 9.9 10.0 9.6 10.1 9.1 11.8 9.2 0.26 2.96 3.38 3.74 2.71 -65.1 12.1 PPT in. DO 100 1.6 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 W-100 P-75 P-35 P-20 E-50 E-30 E-10 PPT cm 2.1 0.7 2.51 Nov 0.15 5.74 1.40 2.08 Dec 1.78 6.38 0.66 7.52 8.59 9.50 6.88 5.1 8.1 8.2 3.5 3.4 4.9 5.2 6.0 2.5 1.9 5.9 7.1 7.8 3.1 2.3 3.8 3.4 237 WITHAM HILL DATA Site 2 Benton County 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 Saturation (graphing) 20 cm 35 cm 75 cm Data Lines (graphing) 1 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 6.3 5.5 12.4 1.5 1 3 3 3 2 2 2 3 2 1 1 1 1 350 200 5 1.5 350 200 5 1.5 350 200 350 200 350 200 350 200 5 1.5 5 1.5 5 1.5 5 1.5 41.9 2.5 17.5 33.0 9.4 14.5 91.2 70.0 78.8 65.0 92.0 71.0 80.7 65.3 92.0 66.0 81.0 45.0 88.5 63.0 80.0 43.0 26.0 30.5 35.0 26.9 32.0 30.0 29.0 35.5 35.0 27.5 31.5 28.0 3.8 9.0 12.0 2.0 9.0 13.5 5.0 9.5 18.0 2.6 7.0 14.2 Solution pH pH 75 pH 35 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 238 WITHAM HILL DATA Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-50-1 E-50-2 E-50-3 E-30-1 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 Site 2 Benton County 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2/17/96 2/23/96 3/01/96 3/08/96 -15.1 -15.1 -10.4 -42.7 -14.5 -18.5 -18.0 -76.5 -13.0 -17.0 -13.0 -8.5 -15.5 -8.0 -10.5 -15.0 -11.5 -13.0 -18.5 -13.0 -0.5 -3.0 -5.0 -12.5 -17.0 -12.0 -0.5 -15.5 -5.0 -12.5 -18.5 -14.0 -11.5 -18.5 -13.5 -13.5 -10.6 -15.5 -14.5 -12.0 -10.0 -14.0 -11.0 -9.5 -11.0 -7.0 -3.5 -12.5 -9.5 -6.0 -13.5 -11.0 -10.0 0.5 -2.0 -1.5 -12.5 -10.0 -6.5 -7.5 -2.0 -3.0 -13.0 -11.0 -12.0 -12.5 -11.0 -11.0 -18.3 -14.8 -12.7 -20.0 -15.0 -10.5 -19.0 -15.0 -10.0 -15.0 -12.0 -4.5 -17.5 -14.0 -7.5 -18.5 -14.5 -10.0 -6.0 -2.0 -1.5 -19.0 -14.5 -8.5 -13.5 -7.0 -3.5 -18.5 -15.0 -12.0 -18.5 -15.5 -11.0 34 -166 -53 27 64 -27 209 22 -150 -14 -9 53 -23 -97 7 9 -116 -39 -125 -155 -77 -265 -67 -86 -64 130 -43 -113 -65 -329 -66 -153 -93 -302 82 -35 -121 23 77 -59 -100 -284 -4 29 19 210 113 96 9 130 0 3 -320 -57 -3 63 -16 117 48 11 -5 -104 -45 0 -146 -93 -27 75 -29 27 260 -3 9.2 8.5 7.9 7.5 8.2 7.2 5.9 6.8 5.0 2.8 6.1 2.3 8.6 8.6 9.2 10.4 -1 -38 -23 48 -15 -29 -1 67 0 15 5 83 -127 -48 -110 60 -59 7 -41 110 8.2 8.5 9.0 12.7 8.8 8.3 7.6 7.4 3.6 6.4 13.9 8.8 9.2 10.9 17.4 291 -153 293 -15 89 282 -129 TC-50 TC-30 TC-10 AMBIENT 8.7 9.1 7.1 4.8 3.6 9.0 8.9 15.1 9.7 9.3 8.6 8.0 DO-W100 7.3 2.5 2.7 7.7 9.0 5.3 8.0 2.0 5.4 1.9 1.3 D075-1 D075-2 D075-3 8.4 2.3 6.3 5.9 2.0 6.8 2.4 9.6 1.8 5.7 2.9 4.5 5.3 6.3 7.1 5.1 4.1 1.9 2.0 2.3 1.9 4.7 1.9 0035-1 D035-2 D035-3 2.9 2.5 2.4 1.8 2.3 2.3 1.3 1.3 2.0 2.2 1.8 3.6 1.4 1.5 2.5 2.5 1.7 1.6 1.7 2.4 2.6 4.6 1.2 1.1 1.0 1.9 1.5 2.4 1.8 1.6 2.0 6.5 3.8 4.8 4.2 2.5 3.7 2.3 2.0 4.0 3.7 3.5 4.4 3.1 4.2 2.3 3.7 2.5 2.8 4.6 D020-1 D020-2 D020-3 Corrected Average W-100 P-75 P-35 P-20 E-50 E-30 E-10 1.8 3.1 7.4 4.7 4.4 5.8 4.5 5.5 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2/17/96 2/23/96 3/01/96 3/08/96 -15.1 -22.7 -13.2 -15.3 -14.5 -37.7 -12.2 -15.2 -8.5 -11.8 -7.2 -10.5 -10.5 -13.3 -9.3 -13.0 -13.0 -15.8 -11.5 -14.3 -0.5 -10.3 -4.2 -8.0 -12.5 -16.3 -12.0 -15.2 -11.5 -16.0 -11.5 -15.0 137 192 216 132 135 200 208 108 184 269 -0.5 -4.0 -1.0 -3.2 37 -12.5 -14.5 -9.7 -14.0 123 199 251 -13.0 -15.0 -11.5 -14.7 60 112 186 177 111 81 314 66 52 205 82 304 93 255 6.8 5.0 2.8 2.3 8.6 8.2 8.5 9.0 12.7 8.8 8.3 7.4 3.6 7.6 8.6 9.2 10.4 8.8 9.2 10.9 17.4 1.27 6.5 0.04 4.48 0.55 March 1.73 TC-50 TC-30 TC-10 AMBIENT 8.7 9.1 7.1 9.0 8.9 PPT in. 0.08 4.8 3.6 192 195 181 9.7 9.3 8.2 7.2 5.9 4.09 110 15.1 8.6 8.0 9.2 8.5 7.9 7.5 1.5 1.75 3.26 6.1 Jan PPT cm DO 100 DO 75 DO 35 DO 20 7.1 192 Feb 7.1 6.4 13.9 0.20 3.81 4.45 8.28 10.39 3.23 16.51 0.10 11.38 1.40 4.39 7.3 2.5 5.1 4.1 2.1 2.7 4.0 1.5 4.4 7.7 4.6 2.5 5.3 9.0 5.7 5.3 4.3 2.2 4.0 8.0 5.4 1.7 3.9 2.0 4.6 3.2 3.5 5.4 3.7 1.3 2.5 1.9 3.0 1.3 3.3 1.8 2.7 2.6 7.4 4.7 2.1 5.0 1.8 3.4 239 WITHAM HILL DATA Site 2 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2/17/96 2/23/96 3/01/96 3/08/96 3 2 3 2 3 3 2 3 3 2 2 3 2 3 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 1 350 200 350 200 5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 26.0 68.0 61.5 Saturation (gi 20 cm 35 cm 75 cm Data Lines (graphing) Benton County 12/26/95 350 200 5 1.5 5 1.5 1.5 350 200 5 350 200 5 1.5 1.5 350 200 5 1.5 2 1.5 Solution pH pH 75 pH 35 pH 20 5.70 5.38 5.53 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 90.0 69.5 79.5 37.5 29.0 68.0 66.0 122.5 27.5 66.5 61.0 23.0 65.0 56.0 25.0 64.5 59.5 27.5 68.0 61.0 15 52.5 53 27.0 66.5 60.0 15.0 65.0 53.0 27.0 68.0 62.0 26.5 30.0 24.0 55.0 51.0 41.0 54.5 50.0 40.5 51.5 46.0 34.5 53.0 48.5 37.0 54.0 50.0 41.0 40 41 53.0 49.0 37.5 48.0 41.0 34.0 53.5 50.0 43.0 53.0 50.0 42.0 2.0 6.0 8.5 48.0 44.0 41.5 47.0 44.0 41.0 43.0 41.0 35.5 45.5 43.0 38.5 46.5 43.5 41.0 47.0 43.5 39.5 41.5 36.0 34.5 46.5 44.0 43.0 46.5 44.5 42.0 32.5 34 31 32.5 240 WITHAM HILL DATA Benton County Site 2 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 -16.0 -19.5 -5.5 -17.5 -20.0 -6.0 -26.5 -24.5 -24.5 -26.0 -20.5 -24.0 -47.0 -44.5 -48.5 -12.5 -22.0 -11.0 -3.5 -11.5 -5.0 -20.5 -20.5 -19.0 -41.5 -40.5 -44.0 -17.5 -28.0 -15.0 -16.0 -14.0 -12.0 P-35-2 P-35-3 -14.5 -12.0 -15.5 -13.5 -13.0 -14.5 -20.0 -21.0 -24.0 -20.0 -21.0 -23.5 -12.5 -10.0 -8.0 2.0 -5.0 -2.5 -14.5 -16.0 -22.0 -14.0 -14.0 -14.0 -12.0 -10.0 -13.0 P-20-1 P-20-2 P-20-3 -19.5 -16.0 -14.0 -18.5 -16.0 -14.0 -18.5 -14.0 -8.5 -8.5 -7.0 -4.0 -21.0 -19.0 -19.5 -16.5 -14.0 -14.0 -11.0 -12.0 E-50-1 -91 -171 -335 -160 -150 -283 -193 -273 -254 -357 -289 -201 -181 -323 50 -50 -275 -357 -250 -185 -276 62 -40 117 288 -162 -137 -250 74 -33 93 310 -332 -170 -272 -199 -10 -205 -213 -381 -204 180 76 -325 -242 -164 -217 -46 -204 -136 248 -43 -341 -154 -126 -319 87 -45 98 -136 -171 -143 -224 85 -35 125 321 -3 -141 E-50-2 E-50-3 9.7 9.5 10.2 14.2 10.3 10.8 10.9 21.1 Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 E-30-1 E-30-2 E-30-3 E-10-1 -114 21 369 286 12.3 12.7 12.0 10.2 11.8 12.0 10.7 7.9 11.4 11.6 11.0 13.2 1.3 1.9 1.2 3.9 1.5 5.2 2.3 4.0 2.7 1.5 1.6 2.2 1.5 1.5 1.9 1.9 1.9 2.9 2.2 2.5 1.5 2.7 3/15/96 3/23/96 3/30/96 4/04/96 -16.0 -12.5 -14.0 -16.5 -17.5 -13.0 -13.7 -16.2 35 -26.5 -24.5 -21.7 13 120 88 370 7C-50 TC-30 TC-10 AMBIENT 9.8 10.3 11.3 14.9 10.2 10.0 DO-W100 1.2 0.8 D075-1 5.3 1.8 D035-1 D035-2 D035-3 D020-1 D020-2 D020-3 W-100 P-75 P-35 P-20 E-50 E-30 E-10 -221 171 -152 Corrected Average -285 74 -58 74 -25 202 -30 E-10-2 E-10-3 D075-2 D075-3 -171 341 61 85 270 10.1 13.4 322 TC-50 TC-30 TC-10 AMBIENT 9.8 10.3 11.3 14.9 10.2 10.0 13.4 9.7 9.5 10.2 14.2 PPT in. 0.43 0.2 0.7 10.1 214 69 -35 109 308 -7 13.2 13.5 12.8 17.5 12.3 12.4 12.5 17.2 13.5 14.5 14.5 18.7 13.5 13.7 16.0 23.8 1.9 2.0 1.7 1.2 1.2 4.2 2.2 3.8 1.2 5.7 2.6 5.0 2.3 4.8 2.1 5.1 2.1 2.3 1.3 2.5 1.9 1.4 1.9 2.3 2.3 2.7 2.2 2.2 4.8 1.7 1.5 2.4 2.6 2.4 2.0 1.8 1.6 4/11/96 4/18/96 4/25/96 5/04/96 -26.0 -22.3 -21.5 -47.0 -46.5 28 108 -3.5 -8.3 -1.8 -6.5 -30 334 -59 22 198 -12.5 -16.5 -10.2 -13.7 -73 40 10.3 10.8 10.9 21.1 0.98 DO 100 DO 75 DO 35 DO 20 1.09 0.51 1.2 3.6 1.8 2.4 0.8 2.7 1.6 2.1 1.78 -31 129 121 341 176 322 -109 2.0 3.0 3.2 2.4 2.3 5/09/96 5/16/96 5/24/96 -41.5 -42.3 -17.5 -21.5 -14.0 -16.7 123 -94 70 400 -91 120 239 -20.5 -19.8 -17.5 -20.0 -88 102 436 311 -16.0 -13.0 -11.7 -12.3 -79 93 304 12.3 12.7 12.0 10.2 11.8 12.0 10.7 7.9 11.4 11.6 11.0 13.2 13.2 13.5 12.8 17.5 12.3 12.4 12.5 17.2 13.5 14.5 14.5 18.7 23.8 0.78 0.72 2.9 0.06 0.17 1.63 2.04 April PPT cm 76 97 13.5 13.7 16.0 May 2.49 1.98 1.83 7.37 0.15 0.43 4.14 5.18 1.3 3.8 2.2 1.9 1.2 1.9 1.2 3.2 2.0 2.5 2.5 1.7 1.8 2.0 4.2 2.4 1.7 3.4 3.7 3.5 1.2 3.6 1.9 2.2 3.1 3.1 241 WITHAM HILL DATA Saturation (g1 20 cm 35 cm 75 cm Data Lines (graphing) Site 2 3/15/96 3/23/96 3/30/96 4/04/96 3 2 3 2 2 2 1 1 1 1 350 200 5 1.5 350 200 350 200 350 200 5 1.5 5 1.5 5 1.5 4/11/96 Benton County 4/18/96 4/25/96 5/04/96 3 3 3 2 2 2 1 1 1 1 350 200 5 1.5 350 200 350 200 350 200 5 1.5 5 1.5 5 1.5 61.5 94 96.5 27 71.5 59 18 61 53 35 70 67 53 49 39 38.5 44 33.5 46.5 43 39.5 36.5 36 35 5/09/96 1 5/16/96 5/24/96 3 2 3 2 1 1 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 56 90 32 77.5 63 30.5 63.5 60 55 55 53 54.5 53 45 52.5 49 44 49 48 47.5 45.5 45 42 40 43 Solution pH pH 75 pH 35 pH 20 5.85 5.92 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 30.5 69.0 53.5 32.0 69.5 54.0 74 72.5 40.5 70 72 P-35-2 P-35-3 55.0 51.0 46.5 54,0 52.0 45.5 60.5 60 55 60.5 60 54.5 P-20-1 P-20-2 P-20-3 47.5 45.0 45.0 46.5 45.0 45.0 P-75-1 P-75-2 P-75-3 P-35-1 41 92 242 Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 5/30/96 6/14/96 -30.5 -28.5 -30.0 -88.5 Benton County Site 2 WITHAM HILL DATA 6/21/96 6/28/96 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 -24.0 -27.0 -29.5 P-20-1 P-20-2 P-20-3 -322 E-30-2 E-30-3 -353 -283 -309 -305 62 -40 E-10-1 161 E-10-2 E-10-3 343 197 234 333 224 156 291 62 TC-50 TC-30 TC-10 AMBIENT 14.2 14.5 14.9 15.1 15.7 16.3 19.0 23.9 15.7 16.2 17.3 22.2 DO-W100 1.2 2.0 D075-1 D075-2 2.4 E-50-1 E-50-2 E-50-3 E-30-1 -341 -342 -108 76 316 52 -42 155 98 338 320 376 343 32 342 380 328 330 378 345 216 356 30 110 351 194 354 108 353 218 110 131 345 234 15.6 15.5 16.6 27.9 13.9 12.6 10.5 11.9 106 148 101 301 352 333 40 31 110 346 238 323 224 12.5 12.1 10.9 11.9 D075-3 D035-1 2.2 D035-2 D035-3 2.1 3.7 D020-1 D020-2 D020-3 Corrected Average 5/30/96 6/14/96 -30.5 -29.3 -26.8 -88.5 -130 83 408 -150 272 438 240 357 344 TC-50 TC-30 TC-10 AMBIENT 14.2 14.5 14.9 15.7 16.3 19.0 23.9 15.7 16.2 17.3 22.2 PPT in. 0.11 0 0.1 W-100 P-75 P-35 P-20 E-50 E-30 E-10 15.1 6/21/96 6/28/96 DO 100 DO 75 DO 35 DO 20 1.2 535 273 402 341 401 536 342 440 15.6 15.5 16.6 27.9 13.9 12.6 10.5 11.9 0 0.39 1.37 Oct 0.25 0.28 2.4 2.7 531 0.75 June PPT cm 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 2.0 1.91 0.99 3.48 513 343 436 2.17 Oct 1.39 5.51 3.53 0.45 Nov 1.14 243 WITHAM HILL DATA 5/30/96 Site 2 6/21/96 6/28/96 350 200 350 200 350 200 350 200 350 200 350 200 350 200 350 200 350 200 5 1.5 5 1.5 350 200 5 5 1.5 5 1.5 5 1.5 5 1.5 5 1.5 5 1.5 5 1.5 45 103 Saturation (gt 20 cm 35 cm 75 cm Data Lines (graphing) 1 pH 75 pH 35 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm P-75-1 78 P-75-2 P-75-3 78 P-35-1 64.5 66 60.5 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 2 Solution pH Raw PZ Data W-100 Benton County 6/14/96 1.5 350 200 5 1.5 244 WITHAM HILL DATA Field Data Site 2 Benton County 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 W-100 1/11/97 1/20/97 1/25/97 P-75-1 P-75-2 P-75-3 -15.0 -63.5 -15.5 -49.0 -18.5 -23.5 -18.5 -60.0 -13.5 -12.5 -11.0 -71.0 -11.5 -11.5 -10.0 -51.5 -18.0 -16.5 -17.0 -71.0 -8.0 -15.5 -12.0 -75.5 -0.5 -3.0 -5.0 -48.5 -17.0 -17.0 -16.0 -49.5 -6.0 -16.0 -10.0 -69.5 -10.5 -15.5 -13.0 -64.5 P-35-1 P-35-2 P-35-3 -12.5 -5.0 -5.0 -15.0 -14.5 -13.5 -13.0 -8.5 -8.0 -11.0 -8.5 -6.5 -14.5 -14.5 -13.5 -12.5 -11.0 -9.0 0.5 -2.0 -1.5 -15.0 -14.0 -13.5 -12.5 -10.5 -8.0 -12.5 -11.0 -7.0 P-20-1 P-20-2 P-20-3 -8.5 -3.5 -6.5 -18.5 -15.0 -13.5 -14.5 -9.0 -9.0 -12.0 -7.5 -8.0 -19.5 -15.5 -14.0 -17.5 -11.0 -9.5 -6.0 -2.0 -1.5 -19.0 -15.5 -14.5 -15.0 -11.0 -9.5 -16.5 -10.5 -9.0 269 313 306 90 127 307 238 287 212 284 283 277 129 112 -10 7 -43 -319 -75 -35 -80 -309 -68 -52 -144 148 200 -59 -100 -284 -4 29 13 -15 -9 -360 -102 47 -3 265 237 49 -13 160 294 160 48 37 -25 59 85 85 220 280 172 9.9 9.3 10.1 10.0 5.1 8.6 8.8 11.7 9.7 9.4 9.3 11.8 9.5 9.0 8.6 7.3 8.0 8.6 7.7 DO-W100 8.3 4.6 3.0 3.3 0075-1 D075-2 D075-3 9.5 9.2 8.5 5.3 5.8 7.0 6.2 5.2 D035-1 D035-2 8.3 7.8 9.5 3.5 1.8 5.0 8.5 7.8 7.6 6.8 4.3 6.3 E-50-1 E-50-2 E-50-3 E-30-1 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT 309 262 310 55 111 312 256 266 138 11.0 10.6 61 19 122 302 175 19 210 81 113 96 7.6 6.9 6.8 9.7 8.6 8.6 9.2 10.4 8.7 8.2 1.9 6.5 4.5 7.7 158 10.1 8.0 1.7 6.1 5.5 5.7 4.9 6.0 4.5 5.3 6.3 6.8 4.6 4.3 3.7 4.1 2.1 2.4 5.2 5.3 2.0 2.1 2.1 1.7 1.6 1.7 2.1 1.5 1.5 4.5 1.7 1.5 1.8 0.5 1.4 1.8 1.6 5.8 5.0 4.9 4.0 4.2 4.9 3.7 4.6 8.3 3.7 3.5 4.4 5.6 3.0 5.4 4.2 2.6 3.9 4.8 4.3 6.6 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 1/25/97 -6.0 -31.8 -10.3 -11.8 57 158 358 -10.5 -31.0 -10.2 -12.0 54 8.1 7.3 7.2 7.2 9.2 10.1 7.5 6.5 5.7 2.0 0.52 2.25 0.8 17.27 1.32 5.72 2.03 8.0 5.4 1.7 3.9 1.7 6.1 5.2 1.7 3.7 2.4 5.5 3.9 1.6 4.7 3.6 5.2 -15.0 -42.7 -7.5 -6.2 1.6 1.1 4.9 7.6 -13.5 -31.5 -9.8 -10.8 205 254 399 -11.5 -24.3 -8.7 -9.2 95 216 403 -18.0 -34.8 -14.2 -16.3 9.7 9,4 9.3 8.0 11.8 9.5 9.0 8.6 7.3 3.08 5.02 TC-50 TC-30 TC-10 AMBIENT 11.0 10.6 10.1 9.9 8.6 7.7 10.0 5.1 9.3 8.6 8.8 11.7 PPT in. 0.57 6.58 2.46 352 420 9.0 7.1 -18.5 -34.0 -14.3 -15.7 466 355 379 481 -8.0 -34.3 -10.8 -12.7 43 90 318 -0.5 -18.8 -1.0 -3.2 37 192 314 -17.0 -27.5 -14.2 -16.3 8.6 8.6 9.2 10.4 8.7 8.2 4.9 7.6 7.6 6.9 6.8 9.7 0.69 4.43 6.8 66 179 374 7.1 Dec DO 100 DO 75 DO 35 DO 20 -5 156 194 32 9.2 478 337 395 PPT cm 21 8.1 0020-2 0020-3 E-30 E-10 1 77 36 240 286 -31 -349 -57 7.5 6.5 5.7 2.0 D020-1 W-100 P-75 P-35 P-20 E-50 -264 -22 -353 -95 27 40 80 268 60 7.3 7.2 7.2 0035-3 Corrected Average 291 5 1.45 6.25 7.82 12.75 1.75 8.3 4.6 6.0 3.4 5.8 3.0 6.8 1.5 5.2 3.3 6.2 1.3 1.9 5.5 4.4 5.5 8.5 8.0 164 302 Jan 16.71 9.1 64 168 311 1.5 1.3 2.1 11.25 245 WITHAM HILL DATA Saturation (gi Benton County 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 20 cm 35 cm 75 cm Data Lines (graphing) Site 2 350 200 5 1.5 1/11/97 1/20/97 1/25/97 3 2 3 3 3 3 3 2 2 2 2 3 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 1 350 200 5 1.5 350 200 350 200 5 1.5 350 200 5 350 200 5 350 200 5 350 200 350 200 350 200 350 200 5 1.5 1.5 1.5 5 1.5 5 1.5 1.5 5 1.5 5 1.5 2 Solution pH pH 75 pH 35 pH 20 6.10 6.22 6.18 6.09 5.86 5.76 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 no no no 29.5 113 63.5 95 33 73 66.5 106 28 62 59 117 58 97.5 53 44 36 55.5 53.5 44.5 53.5 47.5 39 36.5 32.5 37.5 46.5 44 44.5 42.5 38 40 32.5 66 65 no no no 117 22.5 65 60 121.5 51.5 47.5 37.5 55 53.5 44.5 53 50 40 40 36.5 39 47.5 44.5 45 45.5 40 40.5 26 61 15 52.5 53 94.5 40 41 32.5 34 31 32.5 31.5 66.5 64 95.5 20.5 65.5 58 115.5 110.5 55.5 53 44.5 53 49.5 39 53 50 38 47 44.5 45.5 43 40 40.5 44.5 39.5 40 25 65 61 246 WITHAM HILL DATA Site 2 Benton County 2101/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 -2.5 -10.5 -9.0 -69.0 -16.0 -16.0 -16.0 -73.0 -18.0 -16.5 -18.0 -75.5 -18.5 -17.5 -18.0 -73.5 -6.5 -18.0 -12.5 -64.5 -9.5 -16.0 -12.0 -71.0 -13.0 -14.5 -11.0 -75.0 -14.5 -16.5 -15.5 -72.5 -19.5 -17.0 -17.5 -61.0 -26.0 -20.0 -25.0 -73.5 -35.5 -28.5 -33.0 -10.0 -7.5 -5.5 -15.5 -14.0 -13.0 -15.5 -14.5 -15.5 -15.0 -14.0 -15.0 -13.0 -6.0 -4.5 -13.0 -8.0 -4.5 -14.5 -9.5 -9.5 -15.0 -14.0 -13.0 -15.5 -15.0 -16.0 -20.5 -22.0 -24.0 -29.5 -31.5 -32.5 P-20-2 P-20-3 -13.0 -8.0 -6.0 -18.0 -13.5 -13.0 -19.0 -14.5 -15.0 -18.0 -14.5 -15.0 -14.5 -8.0 -4.0 -16.5 -9.5 -6.0 -17.0 -12.5 -9.5 -18.5 -13.5 -13.0 -19.0 -15.5 -16.0 E-50-1 -32 0 -70 -35 -367 -204 43 -37 -29 -373 -203 48 -28 55 -95 -55 -366 -318 55 -40 132 -110 -14 -347 -74 -3 -26 48 -70 -38 -406 -195 -73 -52 -399 -246 -111 E-50-2 E-50-3 E-30-1 E-30-2 E-30-3 16 -31 -157 -74 -272 -339 99 -32 -33 191 0 -8 -37 128 18 65 -61 -27 188 14 22 -166 -15 -383 -324 -57 -47 112 32 -51 -92 -263 -78 -206 -340 42 -42 37 122 102 8.2 8.4 14.0 9.6 9.5 8.9 16.6 9.6 9.4 9.2 9.7 17.1 9.4 9.5 9.5 14.3 Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 -337 -88 53 10 -45 -355 -182 151 190 143 -31 170 121 37 85 112 173 127 TC-50 TC-30 TC-10 AMBIENT 8.0 8.2 8.4 9.7 7.3 6.9 6.0 9.2 7.2 7.2 7.2 14.8 7.9 7.5 6.6 8.5 7.8 7.6 8.2 8.0 7.6 8.3 12.4 DO-W100 7.7 1.9 0.8 1.2 4.3 2.0 1.2 0.8 0.9 0.9 1.0 0075-1 0075-2 0075-3 3.1 3.9 2.3 7.8 4.2 2.5 10.3 4.8 1.8 5.4 2.0 3.9 4.8 2.7 9.5 5.1 5.7 5.1 2.1 9.6 2.5 9.6 2.5 10.6 5.4 2.4 9.2 6.1 2.4 D035-1 1.3 1.4 1.4 2.6 1.8 1.0 3.4 2.1 2.8 2.0 1.7 2.0 1.0 1.7 2.1 2.2 1.2 1.2 1.9 1.3 1.1 1.5 1.2 1.6 1.1 0035-2 0035-3 2.0 2.8 4.3 0020-1 D020-2 D020-3 2.8 2.5 3.4 2.7 4.5 4.0 2.6 4.4 2.3 3.9 1.9 1.9 3.2 1.9 2.0 2.0 2.1 2.5 3.5 3.7 5.3 5.2 3.3 2.2 2.4 2.4 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 -2.5 -29.5 -7.7 -9.0 62 -18.0 -36.7 -15.2 -16.2 38 117 294 -18.5 -36.3 -14.7 -15.8 -6.5 -31.7 -7.8 -8.8 -14.5 -34.8 -14.0 -15.0 -19.5 -31.8 -15.5 -16.8 -26.0 -39.5 -22.2 -35.5 -30.8 -31.2 13 28 143 212 -9.5 -33.0 -8.5 -10.7 13 108 -13.0 -33.5 -11.2 -13.0 166 298 -16.0 -35.0 -14.2 -14.8 27 114 300 2 64 262 8.0 8.2 8.4 9.7 7.3 6.9 6.0 9.2 7.2 7.2 7.2 7.8 7.6 14.8 7.9 7.5 6.6 8.5 PPT in. 3.31 0.41 0.75 PPT cm 8.41 0.24 Feb 0.61 1.04 7.7 1.9 4.7 1.3 2.6 4.7 1.4 E-10-1 E-10-2 E-10-3 Corrected Average W-100 P-75 P-35 P-20 E-50 E-30 E-10 TC-50 TC-30 TC-10 AMBIENT DO 100 DO 75 DO 35 DO 20 -1 2.0 9.0 1.4 4.2 1.1 8.1 77 319 7.1 1.1 139 8.1 9.4 9.6 8.9 1.0 2.1 -61 24 62 1.9 10 14 -3 17 88 214 156 249 35 206 77 173 8.2 9.6 9.4 9.2 9.7 9.6 8.0 7.6 8.3 12.4 14.0 9.4 9.6 8.9 16.6 0.35 Mar 2.45 2.11 1.22 0.23 1.91 0.89 6.22 5.36 3.10 0.58 0.8 1.2 1.4 3.7 1.4 3.8 0.8 5.8 1.7 0.9 5.7 1.5 3.5 2.0 5.7 1.6 2.4 0.9 4.9 4.3 3.8 1.2 5.7 1.6 2.1 2.8 7.1 8.2 8.1 8.4 6.0 1.8 2.5 2.1 9.4 9.5 9.5 9.5 14.3 8.9 17.1 0.35 0.45 April 1.14 6.1 0.89 1.0 . 3.8 3.0 247 WITHAM HILL DATA 2/01/97 Site 2 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 3 Saturation (gi 20 cm 35 cm 75 cm Data Lines (graphing) Benton County 2/08/97 3 3 3 2 3 2 3 2 2 2 3 2 2 3 2 3 2 2 2 1 1 1 1 1 1 1 1 1 1 1 350 200 350 200 350 200 350 200 350 200 5 1.5 5 1.5 5 1.5 5 1.5 5 1.5 350 200 5 350 200 5 350 200 5 1.5 1.5 350 200 5 1.5 350 200 5 1.5 350 200 5 1.5 1.5 Solution pH pH 75 pH 35 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 yes yes yes 17 yes yes no 30.5 65.5 64 119 32.5 66 66 121.5 33 67 66 119.5 67.5 60.5 110.5 55.5 53 46 46 43.5 46 P-75-3 60 57 115 P-35-1 P-35-2 P-35-3 50.5 46.5 36.5 56 53 44 56 53.5 46.5 P-20-1 41 P-20-2 P-20-3 37 37 46 42.5 44 47 43.5 46 24 65.5 60 27.5 64 59 117 53.5 45 35.5 42.5 37 21 35 34 66.5 65.5 107 40.5 69.5 73 119.5 50 78 121 29 66 63.5 118.5 53.5 47 35.5 55 48.5 40.5 55.5 53 44 56 54 47 61 70 70.5 63.5 44.5 38.5 37 45 41.5 40.5 46.5 42.5 44 47 44.5 47 61 55 81 248 WITHAM HILL DATA Site 2 Benton County 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 6/01/97 -38.0 -33.5 -37.0 -17.5 -16.0 -16.0 -70.5 -18.5 -17.5 -18.5 -67.5 -53.0 -42.0 -49.5 -74.5 -66.0 -71.0 -99.5 -60.5 P-35-1 P-35-2 P-35-3 -12.0 -14.0 -16.0 -16.0 -10.5 -17.0 P-20-1 P-20-2 P-20-3 -18.0 -14.5 -15.5 -19.0 -16.0 -17.0 -300 -89 -185 -343 -12 -53 -313 -97 -382 -383 -53 -62 137 -303 -109 342 321 248 -330 110 32 68 133 -341 177 -60 390 256 124 Field Data W-100 P-75-1 P-75-2 P-75-3 E-50-1 E-50-2 E-50-3 E-30-1 E-30-2 -274 -66 -182 -349 -311 -66 -365 -366 49 E-30-3 -41 153 168 118 49 -65 E-10-1 E-10-2 E-10-3 163 168 -113 TC-50 TC-30 TC-10 AMBIENT 10.7 11.6 11.9 15.3 11.4 DO-W100 0075-1 0075-2 0075-3 3.1 168 -56 118 12.1 11.5 11.8 12.8 22.6 12.1 14.1 0.9 0.8 4.8 92 13.2 14.3 15.5 -381 -353 -163 265 141 15.1 -65.0 41 15.1 15.1 120 201 347 251 82 119 16.4 16.8 17.4 20.6 28.2 16.2 17.9 27.7 1.2 1.9 2.0 6.7 5.3 2.8 7.2 5.3 1.8 5.6 6.1 3.7 5.6 4.3 7.3 0035-2 0035-3 1.3 1.5 2.2 1.4 1.3 1.5 0020-1 2.1 0020-2 1.5 2.6 2.2 1.6 4.0 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 6/01/97 W-100 P-75 P-35 P-20 E-50 E-30 E-10 -38.0 -35.3 -17.5 -34.2 -14.0 -16.0 -63 50 247 -18.5 -34.5 -14.5 -17.3 -7 42 -53.0 -45.8 -74.5 -68.5 -99.5 -60.5 -65.0 -79 251 288 -80 94 255 229 347 315 264 400 325 TC-50 TC-30 TC-10 AMBIENT 10.7 11.6 11.9 15.3 11.4 11.5 11.8 13.2 14.3 15.5 28.2 15.1 15.1 15.1 16.4 16.8 17.4 PPT in. 0.68 1.88 PPT cm 1.73 4.78 0.9 4.0 0.8 D035-1 D020-3 Corrected Average DO 100 DO 75 DO 35 DO 20 11 64 321 12.1 12.8 22.6 5.1 1.7 2.1 12.1 14.1 0.68 May 1.73 1.2 4.2 1.4 2.6 12 0.11 16.2 17.9 27.7 0 0.28 1.9 4.9 2.0 5.0 6/07/97 15.2 12.3 15.2 12.3 6/07/97 20.6 0.37 1.58 June 1.09 0.94 4.01 2.77 6.7 7.3 249 WITHAM HILL DATA 4/18/97 Site 2 4/26/97 5/03/97 3 3 2 2 1 1 5/10/97 5/16/97 5/24/97 6/01/97 6/07/97 350 200 5 1.5 350 200 350 200 350 200 5 1.5 5 1.5 5 1.5 Saturation (gi 20 cm 35 cm 75 cm Data Lines (graphing) 1 350 200 5 1.5 350 200 350 200 Benton County 1 350 200 5 5 5 1.5 1.5 1.5 Solution pH pH 75 pH 35 pH 20 6.24 6.01 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 yes yes yes 52.5 83 85 no yes yes 32 65.5 64 116.5 33 67 66.5 113.5 52.5 53 47 56.5 49.5 48 46 43.5 46.5 47 45 48 67.5 91.5 97.5 89 115.5 119 114 75 113 250 WITHAM HILL DATA Field Data W-100 Site 3 Benton County 10 \ 10 95 10/17/95 10/24/95 10 \ 31\95 11\07 95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 -49.1 P-75-1 -59.2 -72.8 P-75-2 P-75-3 P-35-1 -5.7 -34.1 -3.8 -23.7 -63.4 -72.8 -2.8 -29.3 -44.0 -56.5 -4.7 -28.4 -43.1 -55.2 P-35-2 P-35-3 -9.6 -4.0 -8.3 -5.9 -0.3 -6.6 -5,7 -0.5 -4.0 -10.9 -4.8 -7.8 P-20-1 -1.9 -0.3 -1.0 -6.2 -0.6 -0.2 -3.6 -3.6 -7.9 P-20-2 P-20-3 -2.1 -7.1 E-50-1 376 349 53 38 221 16 E-30-1 335 46 E-30-2 E-30-3 331 31 329 335 338 333 46 55 29 E-50-2 E-50-3 319 269 232 50 63 326 293 255 5 2 321 319 279 -18 419 376 476 339 370 331 4 93 35 260 -97 19 -6 -59 87 220 8 -8 -3 521 343 -11 -19 291 5 2 66 81 18 391 -1 21 13.1 208 -33 23 39 11.8 11.4 11.5 14.2 -16 -13 -1 -1 484 406 10.8 9.6 8.6 1.6 9.3 10.8 12 8 -4.1 -7 -8 0 11.1 -40 -10 -29 -9 15 -8 9.8 9.3 9.0 9.7 7.0 5.5 5.6 9.9 10.9 9.3 9.3 8.4 8.6 D035-1 D035-2 D035-3 8.3 9.8 9.4 3.2 4.0 1.8 1.8 2.1 1.6 1.5 1.5 0020-1 D020-2 0020-3 5.7 2.8 4.0 2.5 4.7 2.1 2.9 2.0 3.8 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT 19 -1 256 266 258 243 -23 8 11.8 11.2 9.7 DO-W100 0075-1 0075-2 16 28 14 D075-3 Corrected Average 10 \ 10 95 10/17/95 10/24/95 10 \ 31 \ 95 11 \ 07 \ 95 W-100 -49.1 472 493 503 192 202 202 430 452 474 198 163 167 551 631 563 365 458 423 TC-50 TC-30 TC-10 AMBI ENT PPT in. 0.06 2.26 0.55 0.82 Oct PPT cm DO W100 DO 75 DO 35 DO 20 0.7 2.51 -59.2 -72.8 -5.7 -7.3 -3.7 -3.8 -53.3 -4.2 -2.5 -2.8 -43.2 -3.4 -1.5 -4.7 -42.2 -7.8 -5.2 154 163 170 267 279 177 137 148 187 155 143 104 151 11.8 11.2 9.7 10.8 9.6 8.6 1.6 10.0 9.8 10.5 13.1 11.8 11.4 11.5 14.2 11.1 9.8 9.3 9.0 9.7 0.26 2.96 3.38 3.74 2.71 -34.1 Nov 0.15 5.74 1.40 2.08 1.7 2.5 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 P-75 P-35 P-20 E-50 E-30 E-10 5.1 -33 -37 -55 -98 10.0 9.8 10.5 135 167 Dec 1.78 6.38 0.66 7.52 8.59 9.50 6.88 9.3 10.8 9.9 7.0 10.9 9.2 4.3 4.1 5.5 9.3 1.9 3.7 2.1 5.6 8.5 1.5 2.9 251 WITHAM HILL DATA Benton County Site 3 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 Saturation (graphing) 20 cm 35 cm 75 cm Data Lines (graphing) 3 1 350 200 5 350 200 5 350 200 5 350 200 350 200 5 5 3 2 3 2 3 2 1 1 1 1 2 350 200 5 350 200 5 350 200 350 200 350 200 5 5 5 350 200 5 54.0 43.2 2.5 100.0 102.0 59.5 13.5 2.5 103.0 53.0 36.0 21.5 101.0 54.0 37.0 23.0 29.5 36.0 31.0 33.8 40.3 33.0 34.0 40.0 36.0 28.0 35.0 31.5 21.0 20.8 15.0 22.8 22.0 16.0 22.5 23.0 19.0 18.5 19.0 14.0 Solution pH pH 75 pH 35 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 47.4 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 252 WITHAM HILL DATA Site 3 Benton County 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2/17/96 2/23/96 3/01/96 3/08/96 -13.7 -37.9 -47.4 -51.7 -9.0 -37.0 -46.0 -57.5 -8.0 -33.5 -43.0 -55.0 -1.0 -39.5 -49.5 -58.0 -1.0 -39.0 -50.0 -57.0 -13.5 -42.0 -51.0 -59.0 1.0 -24.0 -34.0 -46.0 -3.0 -30.0 -39.0 -51.5 1.0 -44.5 -52.5 -60.0 -15.0 -47.0 -54.0 -62.5 -10.0 -46.0 -55.0 -62.0 -17.8 -14.3 -17.8 -16.0 0.0 -9.5 -15.5 -8.0 -9.5 -9.5 -1.0 -3.5 -10.5 -3.0 -5.5 -19.5 -14.5 -12.5 -5.5 0.0 -1.5 -12.0 -3.5 -6.5 -7.5 -1.0 -2.5 -20.0 -15.0 -14.5 -17.0 -11.0 -11.5 -13.5 -12.2 -14.0 -7.0 -8.5 -11.0 -7.0 -8.5 -10.5 -1.0 -2.0 -5.0 -2.0 -3.0 -6.5 -11.5 -14.5 -12.5 1.0 -1.0 -2.5 -4.0 -4.5 -8.5 0.0 -1.5 -4.0 -13.5 -16.5 -14.0 -9.5 -12.0 -11.5 -18 -23 4 -9 -15 -7 -21 -20 -36 -22 -26 -43 -30 -31 -37 -18 -27 13 -14 -145 -53 -76 -23 -58 -39 -40 -46 -54 -38 -40 -50 E-30-1 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 -50 -72 -17 -34 -73 -68 -39 -159 -34 -249 -285 -93 -344 -307 -238 -112 -98 -53 -364 -41 -133 8.0 6.4 3.5 4.3 8.1 8.1 -103 -86 -56 -354 -153 -120 8.3 -99 -88 -52 -351 -202 8.6 4.5 2.2 3.4 8.3 8.9 10.5 7.9 7.2 6.7 6.5 6.1 -102 8.6 8.0 7.7 7.4 -47 -63 -43 -236 -67 -70 7.5 6.9 5.7 6.2 -45 -17 -44 -45 -54 -63 TC-50 TC-30 TC-10 AMBIENT -20 -5 36 -3 8.6 8.6 8.9 13.8 -74 -345 -32 -89 DO-W100 7.9 4.6 4.2 7.7 5.5 7.1 8.7 8.7 8.6 12.0 10.5 10.9 6.6 8.3 8.6 7.1 3.5 3.3 Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-50-1 E-50-2 E-50-3 -41 7 31 16 -22 5 -221 -93 9.3 8.9 8.5 -55 -61 -33 -281 -58 -31 6.1 13.0 8.0 7.2 4.8 13.9 8.7 11.0 17.6 3.1 2.4 2.2 3.6 4.4 9.4 8.3 9.4 7.3 7.5 7.7 6.7 6.0 6.4 1.2 1.9 1.4 2.5 3.9 2.6 2.1 2.1 2.1 1.9 2.5 2.5 D075-1 11.1 D075-2 D075-3 10.7 10.6 D035-1 D035-2 D035-3 2.6 3.4 3.3 2.4 2.9 3.3 1.8 3.4 2.6 6.0 5.2 5.2 2.4 3.5 3.2 D020-1 D020-2 D020-3 3.6 3.1 4.2 4.7 3.3 3.6 3.7 3.7 3.7 3.6 5.5 5.5 2.6 2.2 2.5 3.6 4.2 3.1 2.4 2.2 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 -13.7 -45.7 -16.6 -13.2 -9.0 -46.8 -8.5 -8.8 -8.0 -43.8 -11.0 -8.7 -1.0 -49.0 -4.7 -2.7 -1.0 -48.7 -6.3 -3.8 -13.5 -50.7 -15.5 -12.8 1.0 E-50 E-30 E-10 144 115 186 146 129 177 144 130 101 33 69 123 110 43 128 11 TC-50 TC-30 TC-10 AMBIENT 8.0 6.4 3.5 8.6 8.6 8.9 13.8 9.3 8.9 8.5 6.1 8.6 8.0 7.7 7.4 7.5 6.9 5.7 6.2 1.5 1.75 3.26 4.09 Corrected Average W-100 P-75 P-35 P-20 PPT in. 4.3 0.08 Jan 9.0 9.3 8.5 2.4 2.5 2.8 4.0 3.6 2.5 2.3 2.4 2/17/96 2/23/96 3/01/96 3/08/96 -3.0 -40.2 -7.3 -5.7 1.0 -34.7 -2.3 -0.8 -52.3 -3.7 -1.8 -15.0 -54.5 -16.5 -14.7 -10.0 -54.3 -13.2 -11.0 65 -48 -129 116 79 110 44 147 126 114 -41 -30 114 73 -78 6.1 8.1 8.1 4.5 2.2 3.4 8.3 8.9 10.5 7.9 8.5 13.0 8.3 8.0 7.2 4.8 7.2 6.7 6.5 13.9 1.27 6.5 0.04 4.48 3.1 111 0.20 3.81 4.45 8.28 10.39 3.23 16.51 0.10 DO W100 DO 75 DO 35 DO 20 7.9 10.8 3.1 4.6 4.2 8.7 7.7 5.5 7.8 3.0 2.4 7.1 3.1 11.1 8.5 3.3 3.6 9.0 1.5 2.2 2.4 7.5 3.0 2.4 2.6 3.7 5.5 4.9 5.3 5.5 3.5 Feb 2.9 3.3 5.5 2.0 3.0 2.4 PPT cm 4.2 -241 2.2 2.5 81 0.55 March 11.38 1.40 2.2 6.4 2.3 2.3 3.6 6.0 2.5 3.5 1.6 1.6 8.6 8.7 11.0 17.6 1.73 4.39 4.4 5.4 2.2 . 2.4 253 Site 3 WITHAM HILL DATA Benton County 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2117/96 2/23196 3101/96 3 2 3 2 3 3 3 2 3 2 3 2 3 2 3 2 3 2 3 2 2 2 1 1 1 1 1 1 1 1 1 1 1 350 200 5 350 200 350 200 350 200 350 200 350 200 350 200 5 350 200 5 5 5 5 5 350 200 5 25.0 92.5 103.5 105.0 41.0 95.0 105.0 107.5 36.0 94.0 106.0 107.0 3/08/96 Saturation (gr.; 20 cm 35 cm 75 cm Data Lines (graphing) 350 200 5 5 350 200 5 Solution pH pH 75 pH 35 pH 20 5.45 5.41 5.5 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-2 P-75-3 91.5 43.0 32.0 27.0 35.0 85.0 97.0 102.5 34.0 81.5 94.0 100.0 27.0 87.5 100.5 103.0 27.0 87.0 101.0 102.0 39.5 90.0 102.0 104.0 25 72 85 91 29.0 78.0 90.0 96.5 P-35-1 P-35-2 P-35-3 20.0 24.0 20.0 54.5 40.0 50.0 54.0 48.0 50.0 48.0 41.0 44.0 49.0 43.0 46.0 58.0 54.5 53.0 44 40 42 50.5 43.5 47.0 46.0 41.0 43.0 58.5 55.0 55.0 55.5 51.0 52.0 P-20-1 7.5 9.0 7.0 37.5 36.5 39.0 37.5 36.5 38.5 31.5 30.0 33.0 32.5 31.0 34.5 42.0 42.5 40.5 29.5 29 30.5 34.5 32.5 36.5 30.5 29.5 32.0 44.0 44.5 42.0 40.0 40.0 39.5 P-75-1 P-20-2 P-20-3 254 WITHAM HILL DATA Site 3 Benton County 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 P-75-2 P-75-3 -22.0 -50.0 -56.5 -64.0 -14.0 -56.0 -61.5 -68.0 -24.0 -58.5 -62.0 -69.0 -21.0 -47.0 -55.0 -64.5 -42.0 -63.0 -64.5 -72.5 -2.0 -52.0 -57.5 -67.5 -3.0 -47.0 -56.5 -65.0 -40.0 -56.0 -60.0 -68.0 -58.0 -72.5 -71.0 -78.0 -11.0 -68.0 -70.5 -76.5 -11.0 -47.0 -56.5 -62.5 P-35-1 P-35-2 P-35-3 -26.5 -22.0 -22.0 -19.5 -15.5 -17.0 -28.5 -25.0 -27.5 -26.5 -23.0 -25.0 -8.5 -3.5 -8.5 -7.0 -2.5 -7.5 -18.5 -11.5 -13.5 -16.5 -10.0 -14.5 P-20-1 -18.5 -20.0 -21.0 -12.5 -18.5 -17.0 -3.5 -5.5 -9.0 -3.5 -5.0 -8.5 -8.5 -10.0 -16.0 -7.5 -10.0 -16.5 -42 -34 -43 -38 -47 -47 -45 -50 -57 -33 -32 -35 -176 -44 -232 -63 -29 -38 -39 -44 -40 -41 6 -66 -43 -8 -19 -138 -123 -120 -111 -62 -102 -86 -49 -270 -258 -263 -149 -115 -72 -81 -91 -291 -6 -269 -262 -69 9.4 -59 -50 -26 -16 -22 12.1 -112 -69 -49 -97 -38 -233 11.7 -104 -76 -372 -85 -139 9.8 10.0 11.5 15.1 12.1 -86 -80 -36 -27 -153 -109 10.3 10.3 10.7 21.0 12.3 11.4 9.9 DO-W100 2.0 2.4 1.6 D075-1 D075-2 D075-3 5.2 5.4 4.8 4.7 5.5 5.2 5.0 D035-1 2.5 3.7 2.5 1.4 3.1 1.9 1.4 2.8 2.7 2.9 1.7 1.5 4.6 1.4 1.7 1.5 1.7 2.5 2.3 3.0 4.3 3.6 2.6 Field Data W-100 P-75-1 P-20-2 P-20-3 E-50-1 E-50-2 E-50-3 E-30-1 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT 0035-2 D035-3 -91 -151 10.2 9.8 10.0 9.8 12.5 3.7 D020-1 1.9 0020-2 0020-3 4.9 Corrected Average 9.1 -54 131 -41 147 -19 -21 -41 -45 -23 171 12.4 16.9 189 99 177 12.6 12.6 12.8 18.9 14.1 11.6 10.4 10.0 -25 -48 -123 11.4 11.5 11.2 13.2 14.8 15.0 18.3 -99 -98 -78 -39 -55 -53 13.5 13.4 16.4 23.6 1.9 2.0 1.5 2.7 1.4 2.9 1.8 4.7 4.8 4.0 3.9 3.8 5.4 4.9 6.0 6.2 6.9 1.2 2.6 2.7 5.1 2.4 4.1 2.9 -71 80 -338 183 109 13.1 13.1 4.1 4.1 1.9 1.9 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 -22.0 -56.8 -23.5 -19.8 -14.0 -61.8 -17.3 -16.0 -24.0 -63.2 -27.0 -21.0 -55.5 -24.8 -42.0 -66.7 -2.0 -59.0 -6.8 -6.0 -3.0 -56.2 -5.7 -5.7 -40.0 -61.3 -58.0 -73.8 -11.0 -71.7 -14.5 -11.5 -11.0 -55.3 -13.7 -11.3 117 106 82 123 94 45 243 99 323 142 98 146 121 71 .115 87 102 110 58 55 6 -103 58 113 84 -31 112 63 -69 TC-50 TC-30 TC-10 AMBIENT 9.8 10.0 11.5 10.2 9.8 10.0 9.4 12.1 12.1 9.8 12.5 12.3 11.4 9.9 11.7 11.6 10.4 10.0 11.4 11.5 11.2 13.2 12.4 16.9 12.6 12.6 12.8 18.9 14.1 14.8 15.1 10.3 10.3 10.7 21.0 15.0 18.3 13.5 13.4 16.4 23.6 PPT in. 0.43 0.2 0.7 0.98 0.78 0.72 2.9 0.06 0.17 1.63 2.04 7.37 0.15 0.43 4.14 5.18 1.5 2.7 1.4 W-100 P-75 P-35 P-20 E-50 E-30 E-10 44 9.1 April PPT cm DO W100 DO 75 DO 35 DO 20 1.09 0.51 2.0 2.4 5.0 2.7 3.6 5.2 2.9 1.78 322 13.1 13.1 69 119 May 2.49 1.98 1.83 1.6 1.9 5.2 2.5 4.8 2.0 4.5 2.0 1.5 2.9 1.8 3.9 5.4 6.4 1.8 2.0 4.1 3.1 3.2 2.7 255 WITHAM HILL DATA Benton County Site 3 3/15/96 3/23/96 3/30/96 4/04/96 3 2 3 2 2 2 1 1 1 1 350 200 5 350 200 5 350 200 5 4/11/96 4/18/96 4/25/96 3 2 1 1 5/04/96 5/09/96 5/16/96 5/24/96 3 3 2 2 3 2 1 1 Saturation (gr: 20 cm 35 cm 75 cm Data Lines (graphing) 350 200 5 1 350 200 350 200 350 200 5 5 5 68 28 100 108.5 112.5 29 95 107.5 110 47 43.5 49 34 33.5 37 1 1 350 200 5 350 200 5 66 104 84 120.5 122 123 350 200 5 350 200 37 121.5 121.5 37 95 107.5 107.5 45.5 42.5 48 57 51.5 54 55 50 55 34 33 36.5 39 38 38 38 44 44.5 5 Solution pH pH 75 pH 35 pH 20 5.23 6.03 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 48.0 98.0 107.5 109.0 40.0 104.0 112.5 113.0 50 106.5 113 114 65.0 62.0 62.5 58.0 55.5 57.5 67 65 49.0 48.0 49.0 43.0 46.5 45.0 68 47 95 111 106 109.5 115.5 117.5 65 63 65.5 111 113 116 256 WITHAM HILL DATA 5/30/96 Site 3 6/14/96 6/21/96 275 129 202 6/28/96 Field Data W-100 P-75-1 P-75-2 P-75-3 Benton County 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 -45.5 -63.5 -66.5 -72.5 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-50-1 -41 E-50-2 E-50-3 -25 -7 E-30-1 -74 -89 251 119 219 385 60 306 253 117 335 15.8 16.3 19.3 150 256 15.6 15.8 17.3 24.1 20.5 6/14/96 6/21/96 132 96 375 310 403 336 420 399 TC-50 TC-30 TC-10 AMBIENT 14.3 14.3 14.4 15.6 15.8 16.3 19.3 24.1 15.6 15.8 17.3 PPT in. 0.11 0 0.1 E-30-2 E-30-3 E-10-1 -31 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT 198 160 68 14.3 14.3 14.4 15.6 DO-W100 1.4 D075-1 D075-2 D075-3 6.8 5.5 6.2 357 160 260 289 374 137 315 370 398 314 375 286 175 336 390 315 360 148 316 386 132 328 361 381 352 309 326 217 189 319 120 311 314 359 250 291 172 184 318 13.9 12.4 10.4 11.2 344 15.5 15.6 17.4 27.9 12.6 12.2 10.6 11.9 D035-1 D035-2 D035-3 D020-1 D020-2 D020-3 Corrected Average W-100 P-75 P-35 P-20 E-50 E-30 E-10 5/30/96 6/28/96 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 -45.5 -67.5 411 432 523 433 20.5 0.75 434 516 437 438 512 418 420 490 409 15.5 15.6 17.4 27.9 13.9 12.4 10.4 11.2 12.6 12.2 10.6 11.9 0 0.39 1.37 June PPT cm DO W100 DO 75 DO 35 DO 20 0.28 1.4 6.2 117 0.25 1.91 0.99 3.48 5.51 045 1.39 Oct Nov 3.53 1.14 257 5/30/96 Benton County Site 3 WITHAM HILL DATA 6/14/96 6/21/96 6/28/96 350 200 5 350 200 5 350 200 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 Saturation (gr.: 20 cm 35 cm 75 cm Data Lines (graphing) 1 350 200 5 Solution pH pH 75 pH 35 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 71.5 111.5 117.5 117.5 5 350 200 5 350 200 350 200 350 200 350 200 350 200 350 200 5 5 5 5 5 5 258 WITHAM HILL DATA Field Data W-100 Site 3 Benton County 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 -2.0 P-75-1 -38.5 -48.0 -57.0 P-75-2 P-75-3 P-35-1 1/11/97 1/20/97 1/25/97 -6.5 -67.0 -1.0 -53.0 -64.0 -0.5 -56.0 -57.0 -77.0 -9.0 -49.5 -54.0 -72.5 -2.0 -52.5 -53.5 -70.0 -37.0 -42.0 -59.5 -9.5 -38.0 -45.0 -59.5 -2.5 -42.5 -48.5 -62.0 -1.0 -49.0 -52.0 -64.5 1.0 P-35-2 P-35-3 -7.0 -1.0 -8.5 -10.5 -5.0 -11.5 -5.5 -0.5 -6.5 -6.5 0.5 -5.5 -14.5 -8.5 -12.5 -7.5 -2.5 -7.0 -5.5 0.0 -1.5 -15.0 -9.0 -13.0 -11.0 -2.0 -6.5 -7.5 -2.5 -6.0 P-20-1 P-20-2 P-20-3 -3.5 -3.0 -7.0 -6.0 -7.0 -12.0 -1.5 -2.5 -6.0 -1.5 -2.0 -5.5 -8.0 -10.5 -12.5 -2.5 -2.5 -8.0 1.0 -1.0 -2.5 -8.5 -11.5 -12.0 -3.5 -3,5 -6.0 -2.0 -3.5 -6.0 5 -14 -33 -113 -27 -28 21 8 13 -1 -23 -1 15 -115 -321 9 -17 -100 32 -25 -48 -40 -9 -37 -111 8.9 8.4 7.8 -28 -10 -19 20 -20 -17 2 -3 9 7.3 6.2 3.9 7.2 -45 -17 -44 -45 -54 -63 -25 -30 -30 8.1 8.1 8.3 7.9 8.9 10.5 E-50-1 349 276 E-50-2 E-50-3 111 30 254 126 37 162 E-30-1 336 306 309 175 214 325 10.7 295 272 279 40 25 -13 10.1 8.6 7.0 5.4 11.9 9.1 -37 -49 8.8 8.6 8.3 6.2 DO-W100 7.5 3.9 1.4 1.7 3.4 D075-1 D075-2 D075-3 9.2 9.9 9.4 6.8 6.7 8.7 7.6 8.6 8.4 7.6 D035-1 D035-2 D035-3 6.1 2.4 0.9 9.0 6.7 1.3 1.6 D020-1 6.1 2.1 D020-2 D020-3 4.5 1.6 1.8 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT Corrected Average 9 21 -10 -10 8.0 -32 -43 -48 -57 -123 -78 6.8 7.0 7.7 -45 -100 -28 -48 -126 -48 6.6 6.2 4.8 9.0 10.1 2.1 3.1 2.2 1.3 3.6 8.2 7.5 7.4 6.6 5.9 6.9 5.0 6.2 9.6 9.4 8.3 9.4 1.7 2.2 1.7 1.2 1.9 1.4 1.2 1.4 1.5 1.3 1.3 1.3 0.7 2.5 2.8 3.3 2.1 1.2 2.2 3.2 1.6 1.9 1.6 1.6 2.4 2.2 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 1/25/97 -46.2 -2.3 -0.8 -9.5 -47.5 -12.3 -10.7 -2.5 -51.0 -6.5 -4.3 -1.0 -55.2 -5.3 -3.8 147 126 114 47 123 120 82 151 133 115 6.8 7.0 6.6 6.2 8.0 7.7 4.8 9.0 10.1 2.1 0.52 2.25 0.8 17.27 1.32 5.72 2.03 3.1 2.2 7.7 1.4 2.2 1.3 6.5 1.3 1.7 3.6 5.8 1.2 1.8 291 9.8 10.0 138 154 272 9.1 6.4 W-100 P-75 P-35 P-20 11 37 139 8.8 8.5 8.9 0.7 1.3 1.1 1.6 1.5 1.8 -11 1.4 1.6 1.6 1.3 1.7 -136 -121 -141 -113 -84 -128 6.9 6.6 6.8 9.9 8.4 -2.0 -47.8 -5.5 -4.5 -6.5 -67.0 -9.0 -8.3 -1.0 -58.5 -4.2 -3.3 -0.5 -63.3 -3.8 -3.0 -9.0 -58.7 -11.8 -10.3 -2.0 -58.7 -5.7 -4.3 -14 -41 -91 -25 1.0 E-50 E-30 E-10 407 478 406 343 443 356 265 178 230 168 123 115 151 148 155 170 85 142 135 TC-50 TC-30 TC-10 AMBIENT 10.7 9.1 8.9 8.4 9.1 7.3 6.2 3.9 7.2 6.9 6.6 6.8 9.9 8.3 8.9 10.5 7.9 10.0 8.8 8.6 8.3 6.2 8.1 8.6 7.0 5.4 8.8 8.5 8.9 11.9 8.1 10.1 PPT in. 0.57 6.58 2.46 3.08 5.02 0.69 4.43 6.8 9.8 7.8 28 59 Dec PPT cm DO W100 DO 75 DO 35 DO 20 1.45 1.3 1.6 2.2 1.5 103 94 Jan 16.71 6.25 7.82 12.75 1.75 7.5 9.5 7.3 5.7 3.9 6.8 1.8 1.4 7.7 1.0 1.6 1.7 3.4 8.5 1.8 6.1 8.2 1.3 1.5 1.9 2.9 11.25 9.0 1.5 2.2 259 Benton County Site 3 WITHAM HILL DATA 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 1/25/97 3 2 Saturation (gr 20 cm 35 cm 75 cm Data Lines (graphing) 3 2 3 2 3 2 3 2 3 2 3 2 3 2 2 3 2 1 1 1 1 1 1 1 1 1 350 200 350 200 5 350 200 350 200 5 5 350 200 5 3 350 200 5 5 350 200 350 200 350 200 350 200 350 200 5 5 5 5 5 Solution pH pH 75 pH 35 pH 20 5.32 6.05 5.96 6.02 5.01 5.67 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 27 26.5 101 115 104 108 122 35 97.5 105 117.5 28 100.5 104.5 115 25 85 93 104.5 35.5 86 96 104.5 28.5 90.5 99.5 107 27 97 103 109.5 49 45 52 44 40.5 47 45 39.5 46 53 48.5 53 46 42.5 47.5 44 40 42 53.5 49 53.5 49.5 42 47 46 42.5 46.5 36.5 35 40 32 30.5 34 32 30 33.5 38.5 38.5 40.5 33 30.5 36 29.5 29 30.5 39 39.5 40 34 31.5 34 32.5 31.5 34 32.5 115 P-75-2 P-75-3 28 86.5 99 102 P-35-1 45.5 P-35-2 P-35-3 41 P-20-1 P-20-2 P-20-3 34 P-75-1 no no no no no no 49 31 35 260 WITHAM HILL DATA Benton County Site 3 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 -2.5 -43.0 -49.0 -60.5 -9.5 -44.0 -50.0 -61.0 -13.0 -46.0 -52.0 -63.0 -11.5 -47.5 -53.5 -64.0 -1.5 -48.5 -53.5 -63.0 -2.5 -42.0 -48.0 -60.0 -3.5 -48.0 -50.0 -60.0 -10.5 -46.0 -50.0 -59.5 -13.5 -48.5 -51.0 -61.0 -23.0 -53.0 -58.0 -67.0 -25.0 -54.0 -60.0 -66.5 -8.0 -2.0 -5.5 -15.0 -9.0 -13.0 -19.0 -12.5 -16.5 -19.0 -12.0 -16.0 -ro -1.5 -5.5 -8.0 -2.5 -6.0 -11.5 -2.5 -7.5 -15.0 -10.0 -13.0 -20.5 -14.5 -18.0 -27.0 -22.0 -26.0 -29.5 -25.0 -28.0 -4.0 -4.0 -5.5 -9.5 -13.0 -11.5 -13.5 -16.0 -14.5 -13.5 -15.0 -14.5 -4.0 -4.0 -5.5 -2.5 -4.0 -7.0 -6.5 -5.0 -7.0 -10.5 -13.0 -11.5 -14.5 -17.0 -15.0 -104 -66 -17 -7 -52 -15 -7 -50 -51 -4 -18 -23 -17 -24 -4 -10 -40 0 -3 3 -43 -3 -74 -8 -44 -12 -7 3 6 6 -47 -29 -30 -53 -51 -54 -13 -50 -84 -38 -16 -33 -231 -216 -83 8.4 8.2 9.4 -96 -52 -95 -363 -234 -68 10.0 9.7 13.1 -75 -29 -44 -355 -254 -65 9.6 9.9 8.7 15.6 9.5 -75 -42 -82 -320 -252 -85 9.8 9.5 9.9 16.8 -78 -33 -79 -365 -187 -100 10.0 9.8 10.7 14.2 Field Data W-100 P-75-1 P-75-2 P-75-3 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 E-50-1 E-50-2 E-50-3 E-30-1 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT 6 -28 -22 -30 -40 -77 -109 -60 7.9 8.2 8.3 10.0 9.1 15.0 -52 -36 -43 -79 -286 -52 8.0 7.5 5.6 8.2 -191 -40 6.3 6.3 6.3 -38 -36 -76 -244 -49 7.1 7.1 8.1 1 -42 -54 8 7.3 7.3 8.0 -148 -200 -107 7.9 7.9 8.8 12.5 -221 -83 7.7 9.1 DO-W100 1.6 2.3 2.4 2.2 4.1 2.0 2.4 0.8 1.3 1.8 1.4 0075-1 0075-2 0075-3 6.3 7.0 5.7 6.6 7.3 6.3 6.3 7.3 6.2 7.7 7.6 6.2 5.3 7.8 6.9 6.7 7.8 8.3 6.1 7.2 7.4 6.3 7.7 7.3 4.1 8.1 5.9 7.6 8.5 D035-1 D035-2 D035-3 1.1 0.9 1.6 1.6 1.6 1.6 1.3 1.6 1.0 1.7 1.5 0.9 1.5 1.1 1.3 1.4 1.2 1.6 2.2 1.3 1.4 1.6 1.2 1.6 1.7 0020-1 D020-2 D020-3 1.4 1.3 1.6 1.7 1.3 2.2 1.5 1.9 2.2 1.5 1.8 2.0 1.6 1.7 1.3 1.7 1.7 1.2 1.3 1.4 2.1 2.1 1.9 1.8 1.6 2.0 1.6 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 -2.5 -50.8 -5.2 -4.5 -9.5 -51.7 -12.3 -11.3 -13.0 -53.7 -16.0 -14.7 -11.5 -55.0 -15.7 -14.3 -1.5 -55.0 -4.7 -4.5 -2.5 -50.0 -5.5 -4.5 -3.5 -52.7 -7.2 -6.2 114 130 86 126 126 73 132 119 45 139 117 29 132 122 38 143 132 TC-50 TC-30 TC-10 AMBIENT 7.9 8.2 8.3 10.0 6.3 6.3 6.3 7.1 7.1 8.1 9.1 15.0 8.0 7.5 5.6 8.2 7.7 7.3 7.3 8.0 7.9 7.9 8.8 12.5 PPT in. 3.31 0.24 Feb 0.41 0.75 PPT cm 8.41 0.61 1.04 1.91 0.35 Mar 0.89 1.6 6.3 1.3 1.4 2.3 6.7 1.4 1.7 2.4 6.6 1.3 1.9 2.2 7.2 1.4 1.8 4.1 7.1 1.5 1.5 Corrected Average W-100 P-75 P-35 P-20 E-50 E-30 E-10 DO W100 DO 75 DO 35 DO 20 6.1 7.8 7.3 8.7 1.8 9.7 2.2 1.8 3.3 2.5 3/30/97 4/05/97 4/12/97 -10.5 -51.8 -12.7 -11.7 -13.5 -53.5 -17.7 -15.5 -23.0 -59.3 -25.0 -25.0 -60.2 -27.5 144 132 -9 142 112 -57 142 80 -54 131 -51 140 98 -50 8.4 8.2 9.4 9.6 9.9 8.7 10.0 9.7 13.1 15.6 9.5 9.8 9.5 9.9 16.8 10.0 9.8 10.7 14.2 2.45 2.11 1.22 0.23 0.35 6.22 5.36 3.10 0.58 0.45 April 1.14 2.0 6.7 1.2 1.5 2.4 7.6 1.7 1.8 0.8 6.9 1.4 1.8 1.3 1.8 7.0 4.6 1.4 1.1 1.5 16 9.1 7.1 1.5 1.7 95 0.89 7.3 2.5 261 WITHAM HILL DATA 2/01/97 2/08/97 Site 3 Benton County 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 Saturation (gri 20 cm 35 cm 75 cm Data Lines (graphing) 3 3 3 2 3 2 3 2 3 2 3 2 2 2 2 2 2 1 1 1 1 1 1 1 1 1 1 1 350 200 5 350 200 5 350 200 5 350 200 5 350 200 350 200 5 350 200 350 200 350 200 5 5 5 350 200 5 350 200 5 5 Solution pH pH 75 pH 35 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 yes yes yes 28.5 35.5 92 37.5 95.5 104.5 109 27.5 96.5 104.5 108 28.5 90 99 105 29.5 96 106 39 94 103 108 46.5 42 46 53.5 49 53.5 57.5 52.5 57 57.5 52 56.5 45.5 41.5 46 46.5 42.5 46.5 50 42.5 48 34.5 32 33.5 40 44 44 42.5 44 43 42.5 34.5 32 33.5 33 32 35 37 33 35 P-75-1 91 P-75-2 P-75-3 100 105.5 101 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 yes yes no 41 39.5 36.5 94 39.5 96.5 101 101 101 105 104.5 102 106 109 112 53.5 50 53.5 59 54.5 58.5 65.5 62 66.5 41 41 39.5 45 45 43 49 51 102 111 111.5 68 65 68.5 262 Benton County Site 3 WITHAM HILL DATA 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 -17.0 -48.5 -54.5 -63.0 -12.5 -50.5 -56.0 -63.0 -42.0 -61.5 -67.5 -70.5 -76.5 -72.0 P-75-2 P-75-3 -17.5 -57.0 -60.0 -69.0 P-35-1 P-35-2 P-35-3 -24.5 -19.0 -22.5 -22.0 -16.5 -16.5 -18.0 -13.0 -15.0 -16.0 -20.0 -16.0 -11.5 -16.5 -15.0 -52 -39 2 -20 48 188 82 6 231 123 -63 -68 350 108 270 16.3 17.2 20.9 18.5 349 209 230 243 172 229 234 15.8 15.7 16.3 15.8 17.1 12.2 13.0 14.4 -112 -70 -125 253 132 -212 14.5 15.4 18.2 29.3 5/24/97 6/01/97 6/07197 Field Data W-100 P-75-1 P-20-1 P-20-2 P-20-3 E-50-1 E-50-2 E-50-3 -40 -16 -2 -44 -16 -2 -36 E-30-1 -69 -74 -63 -307 166 -122 11.4 11.9 13.3 16.4 -88 -74 -92 -243 -50 -22 -47 -103 46 37 DO-W100 1.7 1.4 1.2 2.3 2.0 D075-1 5.3 6.5 7.2 5.0 7.4 3.8 5.4 8.1 8.0 5.2 7.0 7.6 2.0 3.0 1.5 2.7 1.5 1.2 2.0 1.5 1.3 3.3 1.0 2.0 2.0 2.4 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 -17.5 -62.0 -22.0 -17.0 -55.3 -18.3 -17.3 -12,5 -56.5 -15.3 -14.3 -42.0 -66.5 -76.5 -72.0 137 92 80 136 76 90 152 127 59 225 168 158 TC-50 TC-30 TC-10 AMBIENT 11.4 11.9 13.3 16.4 12.2 12.6 15.3 22.6 12.1 PPT in. 0.68 1.88 PPT cm 1.73 DO W100 DO 75 DO 35 DO 20 1.7 6.3 2.4 E-30-2 E-30-3 E-10-1 E-10-2 E-10-3 TC-50 TC-30 TC-10 AMBIENT D075-2 D075-3 D035-1 D035-2 D035-3 2.1 D020-1 D020-2 D020-3 Corrected Average W-100 P-75 P-35 P-20 E-50 E-30 E-10 166 -156 12.2 12.6 15.3 22.6 21 1 12.1 6.1 -20.5 112 68 214 143 286 245 176 286 17.3 18.1 18.5 7.2 5/24/97 6/01/97 6/07/97 -20.5 410 323 424 382 288 382 403 14.5 15.4 18.2 29.3 16.3 17.2 20.9 18.5 15.8 15.7 16.3 15.8 17.1 0.11 0 0.37 1.58 June 1.09 4.78 0.68 May 1.73 0.94 4.01 2.77 1.4 6.8 1.9 2.2 1.2 6.0 1.6 1.8 2.3 6.6 121 161 12.2 13.0 14.4 0.28 2.0 5.4 17.3 18.1 18.5 7.2 263 WITHAM HILL DATA Site 3 4/18/97 4/26/97 5/03/97 2 3 2 2 1 1 1 350 200 5 350 200 5 5/10/97 5/16/97 Benton County 5/24/97 6101/97 6107(97 350 200 5 350 200 350 200 5 Saturation (gr: 20 cm 35 cm 75 cm Data Lines (graphing) 350 200 5 3 1 350 200 5 1 350 200 5 5 Solution pH pH 75 pH 35 pH 20 5.56 5.63 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 yes yes yes 43.5 38.5 98.5 114 43 96.5 105.5 108 63 59 63 60.5 56.5 57 56.5 53 55.5 46.5 48 44 42 44.5 43 P-75-1 105 P-75-2 P-75-3 111 P-35-1 P-35-2 P-35-3 P-20-1 P-20-2 P-20-3 no yes no 107 108 68 109.5 118.5 115.5 102.5 120 46.5 264 WITHAM HILL DATA Field Data Site 4 Benton County 10\ 10\95 10/17/95 10/24/95 10 \ 31 \95 11 \07\95 95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 W-100 -27.4 -44.0 P-100-1 P-100-2 P-100-3 P-50-1 P-50-2 P-50-3 -22.2 -19.4 P-25-1 -23.3 -23.3 -20.3 -33.1 P-25-2 P-25-3 -40.9 -37.8 -35.3 E-100-1 E-100-2 E-100-3 192 206 194 211 199 131 195 166 123 201 185 153 452 442 439 131 121 128 106 154 E-50-1 246 153 271 180 E-25-1 232 264 340 416 522 424 474 503 607 -81 261 185 187 252 112 245 297 333 172 E-50-2 E-50-3 -46 -10 42 -297 172 E-25-2 E-25-3 TC-100 TC-50 TC-25 AMBIENT 241 129 164 210 250 254 266 341 78 104 -96 96 25 131 31 13.2 12.6 11.4 11.8 D0-W100 1.9 -5.7 -2.8 -1.9 -95.9 -64.2 -36.6 -31.9 -18.5 -4.7 -78.9 -31.0 -19.0 -2.6 -17.7 -5.2 -1.7 -4.3 -8.6 -0.9 -1.7 -3.4 -5.2 -3.4 -3.4 -3.4 -6.0 -3.7 -2.6 -5.2 -0.7 -2.6 -4.3 -0.9 -3.4 -5.2 -1.3 55 49 78 -5 32 -24 -43 -13 -253 -235 -207 -383 16 -12 -393 -415 -318 -193 -372 7 12.1 11.1 11.4 13.7 9.4 1.8 5.8 10.0 7.0 7.5 10.6 10.3 6.8 6.2 8.0 6.5 4.8 2.6 5.4 10.6 2.5 2.9 2.3 3.4 4.6 3.0 4.4 3.1 -373 -3 -46 12.9 34 -45 12.7 00100-2 00100-3 9.3 7.7 Corrected Average 7.0 4.9 3.5 10 \ 10 \ 95 W-100 P-100 P-50 P-25 E-100 447 417 453 E-50 E-25 PPT in. 0.06 430 370 466 411 367 382 429 388 694 461 702 2.26 0.55 641 0.82 Oct DO 100 DO 100 DO 50 DO 25 -114 11.5 9.8 9.1 8.8 7.6 2.8 3.4 2.3 2.1 3.1 0.7 -5.7 -95.9 -8.5 -4.4 310 45 34 -2.8 -50.4 -4.9 -2.8 5 -1.9 -25.2 -2.0 -2.6 223 -39 40 189 13.2 12.6 11.4 11.8 12.9 12.7 12.1 11.1 11.5 9.8 11.4 13.7 9.4 1.8 11.8 10.2 9.4 10.9 0.26 2.96 3.38 3.74 2.71 -27.4 -44.0 -24.9 -22.3 -38.0 371 220 183 385 2.51 182 143 Nov 0.15 -261 10/17/95 10/24/95 1O\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 TC-100 TC-50 TC-25 AMBIENT PPT cm 3.2 3.7 0025-1 0025-2 D025-3 -112 -413 -166 -97 273 -95 -133 11.8 10.2 9.4 10.9 -151 D0100-1 0050-1 0050-2 D050-3 -281 5.74 1.40 2.08 261 -4.7 -43.0 -4.0 -3.3 34 -122 -75 9.1 8.8 Dec 1.78 6.38 0.66 7.52 8.59 9.50 6.88 1.9 5.8 10.0 10.5 8.5 3.5 6.2 4.0 7.0 6.5 2.7 2.7 7.5 6.4 4.4 2.9 5.1 265 WITHAM HILL DATA Site 4 Benton County 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 Saturation (graphing) 25 cm 50 cm 100 cm Data Lines (graphing) 3 2 350 200 5 350 200 350 200 5 5 350 200 5 2 350 200 350 200 350 200 5 5 77.0 3 3 3 3 2 2 2 2 1 1 1 1 350 200 5 350 200 5 350 200 5 5 350 200 5 59.4 100.0 103.0 104.0 4.8 41.5 73.5 79.0 94.5 101.0 24.5 80.0 94.0 55.0 37.5 52.0 56.0 53.0 48.0 57.0 56.0 54.0 52.0 54.0 54.0 25.0 22.0 24.7 26.0 23.0 28.2 26.0 24.0 28.0 25.0 23.0 27.5 Solution pH pH 100 pH 50 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 C P-100-1 C P-100-2C P-100-3C P-50-1C P-50-2C P-50-3C 32.2 35.5 19.6 P-25-1C P-25-2C P-25-3C 2.0 2.0 5.5 10.5 14.2 17.0 266 WITHAM HILL DATA Site 4 Benton County 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2/17/96 2/23/96 3/01/96 3/08/96 -10.4 -66.8 -16.4 -6.0 -5.0 -64.5 -17.0 -9.0 -4.0 -56.0 -9.0 -5.0 -3.0 -62.0 -9.5 -4.5 -3.5 -62.5 -11.0 -7.0 -5.5 -62.0 -11.5 -8.0 -3.5 -28.5 -7.0 -4.5 -2.5 -35.0 -5.5 -3.0 -1.0 -61.0 -11.0 -6.5 -4.0 -60.0 -12.5 -10.0 -4.0 -56.0 -8.0 -5.0 -5.2 -0.9 -2.2 -3.5 -1.0 -3.5 -3.5 -0.5 -2.0 -1.5 P-50-2 P-50-3 -2.5 -3.0 0.0 -3.0 -3.0 -0.5 -5.0 -2.5 0.5 0.5 -4.0 -0.5 -2.5 -2.5 0.5 -5.0 -4.5 -2.0 -4.5 -3.5 -1.5 -3.5 P-25-1 P-25-2 P-25-3 -3.4 -4.3 -0.9 -5.5 -4.0 -3.5 -5.0 -4.0 -8.5 -3.5 -1.5 -1.5 -4.5 -3.0 -2.5 -5.0 -3.5 -2.5 -3.5 -2.5 -1.5 -4.5 -3.5 -2.5 -3.5 -1.5 -2.0 -6.0 -4.5 -4.5 -5.0 -3.5 -3.5 E-100-1 E-100-2 E-100-3 -112 -78 -298 -93 -471 -107 -225 -140 -107 -225 -140 -68 -226 -83 -155 -358 -120 -83 -287 -71 -82 -319 -66 -77 -224 -125 -76 -242 -133 E-50-1 -421 -133 -182 -353 -423 -386 -148 -244 -220 -436 -124 -99 -366 25 -191 -81 9.3 8.6 8.5 13.4 9.7 7.9 6.4 5.8 -382 -20 -136 9.5 8.8 -385 9 -437 -333 -136 -372 -196 -114 8.6 8.4 -428 -143 -6 8.1 13.1 8.1 2.6 -437 -333 -136 -372 -196 -114 8.9 7.4 7.8 10.5 -436 -140 -384 -318 -20 10.4 9.3 9.0 5.4 -424 -237 -306 -287 -142 -24 10.2 9.0 7.7 7.6 -431 E-50-2 E-50-3 E-25-1 E-25-2 E-25-3 TC-100 TC-50 TC-25 AMBIENT Field Data W-100 P-100-1 P-100-2 P-100-3 P-50-1 -267 -82 -429 -150 -232 -389 29 38 27 11.0 8.2 5.2 3.7 31 9.9 -431 -385 -351 1.0 -131 6.6 4.1 -101 -184 12 -361 -381 12 4.9 -85 9.2 7.7 6.4 15.4 -188 9.0 9.0 9.7 17.2 4.1 2.6 6.1 4.7 3.0 4.3 4.5 1.9 1.8 1.7 2.4 3.2 DO-W100 5.9 3.3 3.7 9.2 7.7 6.3 3.5 2.0 00100-1 D0100-2 D0100-3 6.0 9.6 11.0 8.5 6.5 9.1 8.9 9.3 7.6 8.7 5.8 5.4 8.7 7.1 8.9 8.9 6.9 5.6 6.9 8.1 4.1 0050-1 3.2 5.9 2.0 3.3 9.1 8.4 2.3 2.7 7.2 1.7 2.3 1.2 2.3 5.1 5.1 7.9 2.1 2.9 7.6 4.3 3.6 2.5 6.0 2.3 1.5 2.5 1.2 1.9 3.3 2.1 5.1 2.3 2.4 2.0 2.7 2.0 1.9 3.2 3.4 0050-2 0050-3 0025-1 8.8 10.3 0025-2 3.0 2.8 D025-3 2.1 2.9 3.3 2.6 12/26/95 1/02/96 -10.4 -29.7 -2.7 -2.9 96 -59 -5.0 -30.2 -2.7 -4.3 Corrected Average W-100 P-100 P-50 P-25 E-100 E-50 E-25 TC-100 TC-50 TC-25 AMBIENT 11.0 PPT in. 0.08 3.3 7.0 DO 100 DO 100 DO 50 DO 25 5.6 1.8 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2/17/96 2/23/96 3/01/96 3/08/96 -4.0 -23.3 -2.0 -5.8 34 -202 -3.5 -26.8 -2.0 -3.3 38 -132 -5.5 -27.2 -2.8 -3.7 82 -33 64 -3.5 -13.3 -0.5 -2.5 92 -115 -53 -2.5 -14.5 -2.3 -3.5 92 -115 -53 -1.0 -26.2 -2.3 -2.3 -4.0 -27.5 -3.7 -5.0 107 -32 22 -4.0 -23.0 -2.8 -4.0 99 -124 -66 -3.0 -25.3 -1.0 -2.2 94 -136 23 9.9 8.6 8.5 13.4 10.4 9.3 9.0 5.4 10.2 9.0 7.7 7.6 9.7 7.9 6.4 5.8 9.3 6.6 8.6 9.5 8.8 2.6 8.9 7.4 7.8 10.5 8.1 13.1 9.2 7.7 6.4 15.4 9.0 9.0 9.7 17.2 1.5 1.75 3.26 4.09 1.27 6.5 0.04 0.55 March 11.38 1.40 1.73 18 4.1 8.4 Feb 0.20 3.81 4.45 8.28 10.39 3.23 16.51 0.10 5.9 3.3 8.7 4.2 3.7 7.7 5.8 3.5 9.2 8.6 7.7 6.6 6.3 7.6 7.1 4.1 2.1 4.1 3.5 8.6 1.7 1.7 2.0 5.5 2.7 8.1 6.5 2.6 3.9 4.0 2.9 2.9 Jan PPT cm 3.1 5.0 2.5 1.9 -84 65 8.2 5.2 3.7 7.6 4.6 4.4 5.1 100 78 6.5 2.9 5.6 2.7 2.1 118 -82 -5 8.1 4.9 4.48 3.9 2.6 4.4 1.9 2.7 2.1 2.1 4.1 -11 4.39 6.1 4.7 3.7 3.9 267 WITHAM HILL DATA Site 4 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 2/17/96 2/23/96 3/01/96 3/08/96 3 2 3 2 3 3 2 3 3 2 3 2 3 2 2 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 1 1 350 200 350 200 350 200 350 200 350 200 350 200 5 5 350 200 5 5 5 5 5 350 200 5 350 200 5 Saturation (gr 25 cm 50 cm 100 cm Data Lines (graphing) Benton County 350 200 5 350 200 5 Solution pH pH 100 pH 50 pH 20 6.95 5.7 5.52 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 C P-100-1C P-100-2C P-100-3C 95.0 38.5 97.0 109.0 30.0 89.5 42.0 34.0 29.0 81.0 34.0 30.0 28.0 87.0 34.5 29.5 28.5 87.5 36.0 32.0 30.5 87.0 36.5 33.0 28.5 53.5 32 29.5 27.5 60.0 30.5 28.0 26.0 86.0 36.0 31.5 29.0 85.0 37.5 35.0 29.0 81.0 33.0 30.0 P-50-1C P-50-2C P-50-3C 52.0 57.0 55.5 29.0 27.5 27.0 29.0 27.0 25.5 27.0 25.5 26.0 28.5 26.5 26.5 28.5 27.0 28.5 28 26 23 29.5 27.0 26.0 28.0 26.0 28.5 30.0 28.5 28.0 29.0 28.0 27.0 P-25-1 C 25.0 24.0 28.0 29.5 30.5 28.0 29.0 30.5 33.0 27.5 28.0 26.0 28.5 29.5 27.0 29.0 30.0 27.0 27.5 29 26 28.5 30.0 27.0 27.5 28.0 26.5 30.0 31.0 29.0 29.0 30.0 28.0 P-25-2C P-25-3C 268 WITHAM HILL DATA Site 4 Benton County 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 -5.0 -55.5 -9.0 -6.0 -4.0 -53.0 -7.5 -5.0 -6.0 -57.5 -11.5 -8.5 -7.0 -41.0 -11.5 -8.0 -17.0 -59.0 -17.0 -14.0 -2.0 -61.0 -9.0 -6.5 -3.5 -57,0 -8.5 -6.0 -17.0 -50.0 -13.0 -12.0 -35.0 -73.0 -30.0 -26.0 -8.0 -69.0 -19.0 -17.0 -6.5 -54.0 -9.0 -6.0 P-50-2 P-50-3 -5.0 -2.0 -4.5 -4.0 -1.0 -5.0 -5.5 -3.0 -6.0 -6.0 -4.0 -3.5 -15.5 -12.5 -14.5 -3.0 -0.5 -3.5 -3.5 -1.0 -3.0 -13.5 -9.5 -8.5 -32.5 -29.5 -27.0 -5.5 -3.5 -12.5 -5.0 -2.5 -3.5 P-25-1 P-25-2 P-25-3 -6.0 -4.5 -4.0 -5.5 -4.5 -4.0 -8.0 -5.5 -5.5 -8.0 -6.5 -6.5 -18.5 -17.0 -15.0 -4.5 -3.5 -3.5 -5.0 -3.5 -3.5 -16.0 -13.5 -15.5 -8.0 -4.5 -7.0 -7.5 -5.0 -5.5 E-100-1 E-100-2 E-100-3 -389 -89 -244 -44 -82 -387 -102 -362 -17 -67 -159 -312 -33 -123 -194 -137 -56 -253 -32 -171 8 -380 -86 -164 -117 -251 -31 -131 E-50-1 -432 -428 -119 -402 -389 -407 -353 -358 -359 -392 -138 -316 -359 -380 -131 -410 -109 -385 -364 26 -95 10.4 10.0 9.3 12.2 -429 E-50-2 E-50-3 13.8 14.8 19.7 -370 -122 -410 -373 -149 -172 13.2 13.7 13.2 21.2 Field Data W-100 P-100-1 P-100-2 P-100-3 P-50-1 6 -157 E-25-1 -345 -389 E-25-2 E-25-3 TC-100 TC-50 TC-25 AMBIENT 6 -171 9.8 10.1 10.4 15.3 -434 -132 -391 -389 14 -122 10.4 10.5 9.8 13.7 6 -241 -78 10.7 11.0 10.9 18.5 -250 11.3 12.4 12.9 9.9 -408 -126 -347 -312 -18 -87 12.0 12.7 12.2 11.3 -251 -36 12.1 -389 -397 -164 -110 12.6 13.3 12.2 16.0 12.6 17.0 -408 -93 -286 -387 -180 -105 12.5 12.6 12.0 18.8 -141 -21 -73 11.9 -121 -404 -89 -149 -368 13.0 -169 DO-W100 1.5 1.1 1.1 1.0 1.0 0.9 1.3 1.3 1.3 1.3 D0100-1 D0100-2 D0100-3 4.5 3.4 2.9 4.6 4.3 4.6 4.5 3.6 3.2 4.0 2.3 1.7 2.4 10.5 11.3 6.4 6.0 6.5 4.5 3.9 4.6 2.6 4.0 3.9 3.0 2.6 1.1 2.0 1.5 4.6 1.0 1.0 3.3 0.9 1.4 0.8 1.8 2.1 3.4 2.1 1.3 1.0 2.0 1.3 3.1 3.1 1.7 2.0 2.3 2.5 1.4 1.8 3.0 1.4 2.0 2.8 1.4 1.2 1.6 1.2 4.8 5.6 2.8 D050-1 D050-2 D050-3 D025-1 D025-2 D025-3 Corrected Average W-100 P-100 P-50 P-25 E-100 E-50 E-25 TC-100 TC-50 TC-25 AMBIENT PPT in. 1.8 1.2 1.4 1.3 4.4 1.8 1.3 2.7 2.4 2.1 1.5 1.1 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 -5.0 -23.5 -3.8 -4.8 69 -116 -10 -4.0 -21.8 -3.3 -4.7 -7.0 -20.2 -4.5 -7.0 -17.0 -30.0 -14.2 -16.8 -2.0 -25.5 -2.3 -3.8 -3.5 -23.8 -2.5 -4.0 -17.0 -25.0 -10.5 -15.0 9 -6.0 -25.8 -4.8 -6.3 93 -115 30 9.8 10.4 15.3 10.4 10.5 9.8 13.7 10.4 10.0 9.3 12.2 0.43 0.2 0.7 10.1 2.7 124 -132 DO 100 DO 100 DO 50 DO 25 1.09 0.51 1.5 2.9 1.3 2.2 1.78 2.0 1.8 2.3 5/09/96 5/16/96 5/24/96 -35.0 -43.0 -29.7 -8.0 -35.0 -7.2 -6.5 39 136 101 115 133 21 -186 -109 -107 35 -95 23 -133 -49 -76 -50 -115 -28 10.7 11.0 10.9 18.5 11.3 12.4 12.9 9.9 12.0 12.7 12.2 11.3 11.9 12.6 13.3 12.6 17.0 12.5 12.6 12.0 18.8 13.0 13.8 14.8 19.7 13.2 13.7 13.2 21.2 0.98 0.78 0.72 2.9 0.06 0.17 1.63 2.04 0.15 0.43 4.14 5.18 1.3 1.3 5.7 2.8 1.3 1.3 3.2 1.7 2.0 89 -130 81 12.1 12.2 16.0 May 2.49 1.98 1.83 7.37 1.1 1.1 3.6 4.5 2.7 1.0 3.8 1.8 1.0 2.7 2.1 2.1 2.1 0.9 1.8 1.9 1.3 2.3 2.0 3.6 3.5 2.2 -6.5 -23.0 -3.7 -6.0 92 -114 -57 April PPT cm 4.5 1.8 9.4 1.9 4.4 3.7 2.3 3.1 269 Benton County Site 4 WITHAM HILL DATA 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 3 2 3 3 2 3 2 3 2 3 2 3 2 3 2 2 2 1 1 1 1 1 1 1 1 1 5/09/96 5/16/96 5/24/96 3 2 3 2 1 1 Saturation (gr 25 cm 50 cm 100 cm Data Lines (graphing) 350 200 5 350 200 5 350 200 5 350 200 5 350 200 5 350 200 5 350 200 5 350 200 350 200 5 5 32 66 36.5 33 42 84 42 39 27 86 34 31.5 28.5 82 33.5 42 60 98 55 31 75 38 37 31.5 30.5 27 41 28.5 27 27 29 27.5 26.5 39 36 32 32 33 42.5 43.5 39.5 28.5 30 29 30 28 40 40 40 350 200 5 350 200 33 94 44 42 31.5 79 34 31 30.5 29 27 5 Solution pH pH 100 pH 50 pH 20 7.58 6.39 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 C P-100-1C P-100-2C P-100-3C 30.0 80.5 34.0 31.0 29.0 78.0 32.5 30.0 82.5 36.5 33.5 P-50-1C P-50-2C P-50-3C 30.5 28.5 28.0 29.5 27.5 28.5 29.5 29.5 P-25-1C P-25-2C P-25-3C 30.0 31.0 28.5 29.5 31.0 28.5 32 32 30 31 31 31 39 38 28 51 58 56 50.5 30 36 32 31 31.5 31 31.5 31.5 30 270 WITHAM HILL DATA Field Data W-100 P-100-1 P-100-2 P-100-3 P-50-1 6/14/96 6/21/96 -20.0 -63.5 -15.5 -13.0 -81.0 -70.0 -83.0 -76.0 -96.0 63 -52 -201 48 124 138 -205 -29 74 -68 76 -48 64 -87 138 18 119 79 70 248 -371 -155 152 9 156 23 239 123 139 115 269 -18.0 -14.5 -13.5 P-25-1 P-25-2 P-25-3 -20.5 -16.5 -18.0 E-100-1 E-100-2 E-100-3 -324 -86 -378 E-50-1 -327 -82 -378 -353 -250 -75 13.4 14.2 14.2 18.6 E-25-1 E-25-2 E-25-3 TC-100 TC-50 TC-25 AMBIENT 14.1 15.2 15.5 20.4 DO-W100 1.3 1.6 4.6 4.3 5.2 D0100-1 5.5 D0100-2 D0100-3 5.1 D050-1 D050-2 D050-3 2.3 1.2 4.7 D025-1 D025-2 D025-3 2.7 3.6 2.0 Corrected Average W-100 P-100 P-50 P-25 E-100 E-50 E-25 TC-100 TC-50 TC-25 AMBIENT PPT in. Benton County 5/30/96 P-50-2 P-50-3 E-50-2 E-50-3 Site 4 4.5 224 21.3 6/14/96 6/21/96 -20.0 -30.7 -15.3 -18.3 -13 -76 -52 -81.0 -76.3 -96.0 299 225 104 104 259 249 13.4 14.2 14.2 18.6 14.1 14.3 14.9 15.0 21.3 0.11 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 14.3 14.9 15.0 5/30/96 15.2 15.5 20.4 6/28/96 0.1 6/28196 269 115 238 14.6 14.7 14.9 20.0 68 249 173 75 270 154 275 14.4 13.7 110 177 97 273 155 278 13.0 12.3 11.9 11.6 12.1 11.9 300 343 382 291 14.6 14.7 14.9 20.0 14.4 13.7 DO 100 DO 100 DO 50 DO 25 12.1 11.9 0.39 1.37 2.17 0.25 1.6 4.7 1.91 0.99 3.48 0.45 1.39 Nov Oct 0.28 1.3 5.0 2.7 2.8 280 315 410 352 407 June PPT cm 12 13 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 267 315 349 0.75 151 65 -33 92 5.51 3.53 1.14 271 WITHAM HILL DATA 5/30/96 6/14/96 Site 4 6/21/96 6/28/96 Saturation (gr 25 cm 50 cm 100 cm Data Lines (graphing) 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 3 2 1 1 350 200 5 350 200 350 200 350 200 5 5 5 45 88.5 40.5 38 106 95 108 121 Solution pH pH 100 pH 50 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 C P-100-1C P-100-2C P-100-3C Benton County P-50-1C P-50-2C P-50-3C 43.5 P-25-1C P-25-2C P-25-3C 44.5 43 42.5 41 37 101 350 200 5 350 200 5 350 200 5 350 200 350 200 350 200 5 5 5 350 200 5 272 WITHAM HILL DATA Field Data W-100 -38.0 -6.0 -34.0 -29.5 -32.0 P-25-1 P-25-2 P-25-3 E-100-2 E-100-3 E-50-1 E-50-2 E-50-3 E-25-1 E-25-2 E-25-3 TC-100 TC-50 TC-25 AMBIENT DO-W100 69 43 -24 36 188 146 275 157 284 11.5 10.7 10.1 10.0 9.0 9.5 9.9 10.0 P-100 P-50 P-25 E-100 E-50 E-25 -4.5 -55.0 -17.0 -14.5 -3.5 -28.5 -7.0 -4.5 -5.5 -26.5 -5.0 -4.0 -32.5 -6.5 -5.0 -3.5 -49.0 -6.5 -8.5 -4.0 -1.5 -2.0 -4.5 -1.5 -2.5 -3.5 -0.5 -1.5 -3.5 -0.5 -1.5 -4.5 -1.5 -2.5 -3.5 0.5 -4.0 -2.5 0.5 0.5 -4.0 -1.0 -2.0 -3.5 -1.5 -2.0 -2.5 0.0 -0.5 -5.5 -4.0 -4.0 -6.0 -4.0 -5.0 -3.0 -2.5 -5.0 -3.0 -2.5 -6.5 -4.0 -3.5 -5.0 -3.0 -2.5 -3.5 -2.5 -1.5 -5.5 -3.5 -3.0 -4.5 -2.5 -5.0 -3.5 -2.0 -1.5 40 9 -160 -63 -82 -60 19 12 -34 -25 7 -53 41 3 28 6 52 54 14 31 1 -3 -42 -52 -24 -10 7 2 -74 -35 -45 -16 -87 10.3 -13 -12 -90 -105 -115 -77 -29 -82 9.0 9 -7 -53 -40 2 -50 8.9 7.4 7.8 10.5 -50 -19 -235 -17 4.0 55 43 171 118 156 113 207 12.0 10.0 8.0 5.4 108 48 -56 -86 -90 11.0 9.3 8.3 12.0 6.1 4 11 -29 11 -2 10.9 9.0 7.3 18 24 47 2 13 27 -6 -1 -127 -12 -94 -42 -16 -144 8.3 6.7 6.6 -106 -43 -158 10.4 2.5 -79 -32 -145 8.4 6.6 8.3 6.9 -14 9.8 7.5 4.6 7.3 5.4 5.7 3.2 2.9 3.5 4.4 4.5 4.5 10.4 7.7 6.5 8.7 9.2 8.7 8.9 7.3 7.2 7.4 8.9 8.9 6.3 6.6 8.1 7.6 6.3 6.5 3.1 4.4 3.0 2.8 6.4 4.0 5.5 2.9 0.9 1.8 0.8 1.3 1.6 1.0 1.5 1.0 1.6 1.6 1.6 1.7 2.3 1.2 1.4 1.2 1.2 3.1 1.2 2.0 1.4 1.7 2.3 1.4 1.2 1.6 1.8 1.5 2.3 1.7 1.5 2.5 9.1 8.1 7.1 5.9 10.0 -89 9.2 8.0 7.4 7.9 5.1 1.3 1.3 0.9 1.6 1.5 1.1 1.2 1.2 1.9 1.2 1.1 1.5 1.2 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 1/25/97 4.5 4.0 -3.5 -21.3 -1.0 -2.3 217 109 107 238 84 89 5.0 3.4 -38.0 -31.8 -6.0 -2.5 -6.0 -55.0 -2.8 4.5 170 145 9.0 7.1 5.9 10.0 8.9 7.4 7.8 10.5 9.2 8.0 7.4 7.9 8.3 6.7 6.6 10.4 8.4 6.6 6.9 9.8 7.5 4.6 7.3 5.02 0.69 4.43 6.8 0.52 2.25 0.8 17.27 1.32 5.72 2.03 3.5 8.6 1.7 1.7 4.4 4.5 5.3 4.5 3.4 1.0 1.4 1.1 168 125 10.3 9.1 TC-100 TC-50 TC-25 AMBIENT 11.5 10.7 11.0 10.9 9.3 10.0 12.0 10.0 8.0 5.4 9.0 7.3 8.3 PPT in. 0.57 6.58 2.46 10.1 83 112 151 200 253 97 333 181 191 4,7 301 281 163 175 -5.5 -11.8 -2.3 -4.0 260 85 137 -5.0 -41.5 -1.8 -3.5 226 256 8.3 12.0 3.08 4.5 8.1 -6.0 -22.7 -2.8 -4.7 -28.8 -2.3 -3.5 Dec 16.71 6.25 7.82 12.75 1.75 9.0 6.1 5.4 5.7 7.6 1.2 1.8 3.2 8.9 1.2 1.5 2.9 7.3 1.6 1.8 9.8 5.3 3.8 1.9 1.5 -14.7 -2.3 5.1 2.5 Jan 1.45 9,1 1.0 -3.5 -13.3 -0.5 -2.5 282 -20.5 -1.8 -3.5 278 4.5 DO 100 DO 100 DO 50 DO 25 4.5 -6.0 -49.5 -10.0 -8.5 -21.0 -20.0 279 310 413 PPT cm 1/25/97 0.8 0.8 D025-1 D025-2 D025-3 Corrected Average W-100 -4.5 1/20/97 -52.0 -58.0 D0100-1 D0100-2 D0100-3 D050-1 D050-2 D050-3 -6.0 1/11/97 -5.0 -82.5 -21.0 -21.0 P-100-3 E-100-1 Benton County 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 P-100-1 P-100-2 P-50-1 P-50-2 P-50-3 Site 4 11.25 6.8 1.3 1.4 1.3 273 WITHAM HILL DATA Site 4 Benton County 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 1/25/97 Saturation (gr 25 cm 50 cm 100 cm Data Lines (graphing) 2 350 200 5 3 2 350 200 5 3 3 2 3 2 3 2 3 2 2 3 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 350 200 5 350 200 5 350 200 5 350 200 350 200 5 5 350 200 5 350 200 5 350 200 5 350 200 5 Solution pH pH 100 pH 50 pH 20 6.81 6.62 5.74 5.67 6.35 6.09 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 C P-100-1C P-100-2C P-100-3C P-50-1C P-50-2C P-50-3C P-25-1C P-25-2C P-25-3C no no no 63 59.5 56 55.5 31 31 29.5 30 107.5 46 46 74.5 35 33.5 29.5 80 42 39.5 28.5 53.5 32 29.5 30.5 51.5 30 29 29.5 57.5 31.5 30 28.5 74 31.5 33.5 29 26 27.5 28 26 23 29.5 27.5 25.5 29 28 25.5 28 26.5 24 29 29.5 27 27.5 29 26 29.5 30 27.5 28.5 29 29.5 27.5 28.5 26 31 77 83 46 45 25.5 30 28 26 29 27 25 25 30 28 26 29.5 30.5 28.5 30 30.5 28.5 29 29.5 27 29 29.5 27 30.5 30.5 28 29.5 28 29 27 no no no 274 WITHAM HILL DATA Site 4 Benton County 2/01/97 2108/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4112/97 -4.0 -38.0 -13.0 -5.0 -6.0 -35.0 -9.0 -6.0 -6.0 -36.5 -8.0 -6.5 -5.5 -34.5 -8.0 -6.5 -4.0 -31.5 -4.5 -5.5 -5.5 -30.5 -7.0 -5.0 -5.5 -37.5 -3.0 -3.5 -7.0 -32.5 -5.5 -5.5 -5.5 -27.5 -3.5 -2.5 -8.0 -37.0 -6.0 -4.5 -7.5 -35.0 -7.0 -6.0 P-50-1 P-50-2 P-50-3 -5.0 -1.0 -1.0 -5.5 -3.5 -2.0 -5.0 -1.5 -2.5 -4.5 -2.5 -2.0 -3.0 0.0 0.0 -3.5 -0.5 -1.5 -5.0 -2.0 -2.5 -5.5 -3.0 -2.5 -6.5 -3.0 -4.5 -6.0 -3.0 -4.0 -5.5 -4.5 -3.5 P-25-1 -6.0 -3.0 -2.5 -7.0 -4.0 -4.5 -6.5 -4.0 -5.0 -8.0 -5.5 -5.5 -6.5 -4.5 -1.5 -4.5 -4.5 -3.5 -5.0 -6.5 -4.5 -6.5 -4.0 -6.5 -7.0 -4.5 -5.0 -7.5 -5.5 -5.5 -6.0 -5.5 -4.5 E-100-1 15 43 -7 -87 -5 -9 -65 -25 16 11 6 -41 -9 -108 32 -3 -212 3 -57 -29 24 -36 -10 44 E-100-2 E-100-3 -5 8 -211 -215 2 -406 -270 -28 -193 -294 -181 -326 -34 -229 -359 -194 -208 9.2 9.6 9.5 15.3 -324 -44 -240 -345 11.6 -262 -59 -196 -220 -158 -196 8.7 8.6 8.5 13.3 10.3 10.0 9.9 -333 -50 -228 -109 -193 -235 10.7 10.2 9.5 18.9 -346 -72 -137 -197 -198 -178 8.5 8.4 8.4 Field Data W-100 P-100-1 P-100-2 P-100-3 P-25-2 P-25-3 E-50-1 -169 E-50-2 E-50-3 -131 9 -14 -79 -204 -18 -154 -144 -74 -240 8.2 -231 -19 7.1 6.1 7.1 8.1 8.1 7.5 10.0 5.8 6.9 14.0 9.7 -193 -18 -207 -196 -133 -205 8.3 7.9 7.4 6.9 DO-W100 2.8 2.0 3.6 2.9 3.0 2.2 2.1 1.3 1.8 2.0 1.4 00100-1 00100-2 D0100-3 6.1 5.7 3.3 2.7 6.5 1.0 3.5 6.6 3.0 3.5 6.0 2.5 3.3 6.5 1.2 2.2 6.1 3.3 3.7 6.3 4.9 4.2 6.4 3.6 3.7 7.4 3.2 3.7 4.5 3.0 3.7 0050-1 D050-2 0050-3 1.3 1.6 0.8 2.0 0.8 0.9 1.5 1.0 1.2 1.3 0.9 1.2 0.8 1.1 1.1 1.4 0.6 0.5 0.9 1.0 1.2 0.9 0.8 1.1 1.1 1.2 0.9 0.9 0.8 0.5 D025-1 1.6 1.8 1.2 1.6 1.7 1.1 1.5 1.9 1.3 1.1 1.4 2.4 1.2 1.4 2.0 1.1 1.8 2.7 1.6 2.0 2.2 1.1 1.4 1.6 1.2 2.1 1.1 1.5 1.3 1.1 1.1 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 -4.0 -18.7 -2.3 -3.8 226 49 73 -6.0 -16.7 -3.7 -5.2 242 -5.5 -16.3 -3.0 -6.3 232 23 -60 -4.0 -13.8 -1.0 -4.2 223 47 -4 -5.5 -14.2 -1.8 -4.2 -5.5 -11.2 -4.7 -5.5 188 178 57 -17 -5.5 -14.7 -3.2 -5.3 216 14 -17 -7.0 -14.5 -3.7 -5.7 22 -6.0 -17.0 -3.0 -5.2 262 45 7 -10 -79 -16 -82 -8.0 -15.8 -4.3 -6.2 184 -17 -5 -7.5 -16.0 -4.5 -5.3 117 -29 -46 8.0 8.2 8.0 8.2 7.1 6.1 5.8 7.1 8.1 6.9 14.0 7.5 9.7 8.3 7.9 7.4 6.9 8.5 8.4 8.4 11.6 8.7 8.6 8.5 13.3 9.2 9.6 9.5 15.3 10.0 10.3 10.0 9.9 10.7 10.2 9.5 18.9 10.2 7.5 0.24 Feb 0.61 0.41 0.75 2.45 2.11 1.22 0.23 0.45 April 0.35 1.04 1.91 0.35 Mar 0.89 6.22 5.36 3.10 0.58 1.14 0.89 2.0 3.9 1.2 1.5 3.6 3.7 1.2 1.3 2.9 4.4 1.2 1.5 3.0 3.9 2.2 3.3 0.8 1.4 2.1 1.3 4.4 1.0 1.5 5.1 1.8 4.6 1.0 1.7 2.0 4.8 1.4 3.7 0.7 1.5 E-25-1 E-25-2 E-25-3 TC-100 TC-50 TC-25 AMBIENT 0025-2 0025-3 Corrected Average W-100 P-100 P-50 P-25 E-100 E-50 E-25 -114 -102 -57 -145 8.0 7.5 2.6 3.6 1.0 0.9 TC-100 TC-50 TC-25 AMBIENT 10.0 PPT in. 3.31 PPT cm 8.41 DO 100 DO 100 DO 50 DO 25 8.1 2.8 4.1 1.1 1.5 1.1 61 -175 -172 -99 -232 8.0 -121 -289 8.2 1.7 1.1 1.4 201 1.4 1.0 2.0 -191 -232 10.0 1.1 1.8 -61 -239 -213 -204 -245 10.2 10.1 9.6 14.0 10.1 9.6 14.0 275 WITHAM HILL DATA Site 4 Benton County 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 3 2 3 3 2 3 2 3 2 3 2 3 2 2 3 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 1 1 350 200 5 350 200 5 350 200 5 350 200 5 350 200 5 350 200 5 350 200 5 350 200 5 350 200 350 200 5 Saturation (gr 25 cm 50 cm 100 cm Data Lines (graphing) 350 200 5 5 Solution pH pH 100 pH 50 pH 20 A-A-Dip Test 40-60 cm 20-40 cm 0-20 cm Raw PZ Data W-100 C P-100-1C P-100-2C P-100-3C yes no no 29 63 38 30 31 31 60 34 31 61.5 33 31.5 P-50-1C P-50-2C P-50-3C 30.5 27.5 24.5 31 30.5 30 25.5 P-25-1C P-25-2C P-25-3C 30 29.5 27 31 30.5 29 30.5 59.5 yes no no 33 31.5 29 56.5 29.5 30.5 30.5 55.5 32 30 30.5 62.5 28 28.5 32 57.5 30.5 30.5 30.5 52.5 28.5 27.5 31 32.5 60 32 29.5 31 30 29 25.5 28.5 26.5 23.5 29 27 25 30.5 28.5 31 29.5 26 26 32 29.5 28 31.5 29.5 27.5 31 28 26 30.5 30.5 29.5 32 32 30 30.5 28.5 29 33 29 30.5 30.5 31 31 30 31 29.5 31.5 32 30 31 31 26 28 33 62 31 27 32 29 276 WITHAM HILL DATA Site 4 Benton County 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 6/01/97 -3.0 -38.5 -6.0 -8.0 -8.5 -32.0 -7.0 -5.0 -5.5 -33.0 -6.5 -4.0 -21.0 -39.5 -13.5 -11.5 -53.0 -56.5 -40.0 -37.5 -79.0 -77.0 -77.0 -69.0 -22.0 -82.0 -59.5 -56.5 P-50-2 P-50-3 -4.5 -2.5 -3.5 -6.0 -2.5 -5.0 -4.0 -1.0 -2.5 -17.5 -14.5 -15.0 -46.0 -47.5 P-25-1 P-25-2 P-25-3 -6.0 -4.5 -3.0 -6.5 -6.5 -6.0 -5.5 -3.5 -2.0 -19.5 -16.5 -16.5 E-100-1 E-100-2 E-100-3 7 -38 -388 29 23 -368 11 -36 -388 57 3 -382 46 3 -382 E-50-1 E-50-2 E-50-3 E-25-1 E-25-2 E-25-3 -350 -44 -250 -193 -212 -365 -124 -63 -374 -261 -362 -360 -370 -55 -329 Field Data W-100 P-100-1 P-100-2 P-100-3 P-50-1 TC-100 TC-50 TC-25 AMBIENT -251 10.3 11.2 11.8 17.2 -61 -284 -163 -207 -262 11.4 -276 -230 -269 12.5 19.8 11.6 12.4 12.3 14.2 12.1 -1 -11 -268 12.2 13.5 -20.5 -15.5 -17.5 -20.0 -17.5 -19.0 -367 -369 28.8 -307 12.8 14.7 15.8 27.4 14.1 6/07/97 -360 55 -97 16 -45 47 -114 -216 -333 13.4 14.7 0 -67 -362 -22 0 24 -357 10 -234 13.5 15.1 15.4 16.0 22.4 2.4 1.5 4.8 3.8 3.8 15.1 DO-W100 1.4 1.4 1.3 1.2 0.4 D0100-1 4.0 3.8 3.3 2.7 4.5 2.3 3.7 4.7 6.0 4.1 D0100-3 2.2 4.8 4.9 5.5 5.7 0050-1 0.9 0.7 0050-2 0050-3 1.1 1.0 2.1 1.1 0.8 0.9 1.0 0.9 1.4 0.8 D025-1 1.7 1.2 1.2 1.1 1.1 2.3 1.6 1.2 0.7 0.9 2.1 1.7 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 6/01/97 -3.0 -17.5 -3.5 -4.5 -8.5 -14.7 -4.5 -6.3 -5.5 -14.5 -21.0 -21.5 -15.7 -17.5 -53.0 -44.7 -46.8 -79.0 -74.3 -22.0 -66.0 -17.8 -18.8 110 144 -50 -36 142 -59 -39 138 -65 -173 115 193 -47 106 187 -19 13.4 14.7 15.1 15.4 13.5 0.37 1.58 June 1.09 0.94 4.01 2.77 2.4 5.7 1.5 00100-2 0025-2 D025-3 Corrected Average W-100 P-100 P-50 P-25 E-100 E-50 E-25 -28 -44 3.1 2.8 TC-100 TC-50 TC-25 AMBIENT 10.3 11.2 11.8 17.2 11.4 PPT in. 0.68 1.88 PPT cm 1.73 1.4 4.0 1.4 1.4 DO 100 DO 100 DO 50 DO 25 -2.5 -3.7 112 37 -84 3.9 4.1 4.0 1.4 3.1 35 3.1 3.9 2.9 11.6 12.4 12.3 14.2 12.2 13.5 28.8 12.8 14.7 15.8 27.4 0.11 0 4.78 0.68 May 1.73 1.4 3.3 0.9 1.3 1.3 3.3 0.9 0.9 1.2 3.5 1.0 2.0 12.1 12.5 19.8 14.1 0.28 0.4 4.2 3.6 6/07/97 15.1 16.0 22.4 4.1 3.0 3.3 Benton County Site A WITHAM HILL DATA 10\10\95 10/17/95 10/24/95 10\31195 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 -90.0 -94.5 -48.0 -35.0 -74.0 -65.0 -26.5 -29.0 -28.0 13.0 10.8 9.8 10.7 10.0 10.6 3.26 4.09 2/02/96 2/09/96 Field Data W-100 P-75-1 -75.9 -60.8 -46.2 -30.2 -32.6 -87.2 13.4 13.6 12.5 9.8 10.4 3.38 3.74 2.71 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 0.06 PPT in. 2.26 0.55 PPT cm 0.7 0.82 2.51 0.26 2.96 Nov Oct 0.15 5.74 1.40 2.08 0.08 Dec 1.78 6.38 0.66 7.52 1.5 1.75 Jan 8.59 9.50 6.88 0.20 1.27 6.5 3.23 16.51 Feb 3.81 4.45 8.28 10.39 Saturation (graphing) 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 1 25.5 16.5 1 -57.0 52.0 3.0 1 13.6 116.0 120.5 74.0 85.0 1 100.0 115.0 52.5 79 67 2/17/96 2/23/96 3/01/96 Benton County Site A WITHAM HILL DATA 3/08/96 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 5/30/96 0.06 0.17 1.63 2.04 0.11 6/14/96 6/21/96 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm 0.04 0.10 -36.5 -32.5 -81.0 10.8 9.8 5.9 0.55 March 11.38 1.40 4.48 1.73 0.43 0.2 0.7 0.98 0.78 0.72 2.9 April 4.39 1.09 0.51 1.78 May 2.49 1.98 1.83 7.37 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 62.5 82.5 107 0 0.1 June 0.15 0.43 4.14 5.18 0.28 0.25 6/28/96 Benton County Site A WITHAM HILL DATA 9/24196 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm 0.75 1.91 0 0.39 0.99 1.37 3.48 2.17 Oct 1.39 5.51 3.53 0.45 0.57 6.58 2.46 Nov -46.5 -35.5 -54.5 -45.0 7.9 8.1 6.1 8.1 3.08 5.02 -66.5 -61.0 0.69 4.43 -26.5 -29.0 -28.0 -75.5 -67.5 10.7 10.0 10.6 9.6 9.7 6.8 Dec 1.14 1.45 16.71 6.25 0.52 2.25 1.32 5.72 Jan 7.82 12.75 1.75 11.25 17.27 Saturation (gr 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 2 1 72.5 85.5 1 1 80.5 95 92.5 111 1 52.5 79 67 1 101.5 117.5 1/25/97 2/01/97 Benton County Site A WITHAM HILL DATA 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 0,35 Mar 0.89 2.45 2.11 1.22 0.23 0.35 0.68 1.88 0 0.37 5.36 3.10 0.58 0.89 1.73 4.78 0.68 May 1.73 0.11 6.22 0.45 April 1.14 Field Data -49.0 -38.0 W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 9.3 10.0 0035-1 D020-1 PPT in. 0.8 3.31 0.24 Feb 0.41 0.75 PPT cm 2.03 8.41 0.61 1.04 1.91 Saturation (g o 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 1 75 88 0.28 0.94 WITHAM HILL DATA 6/01/97 6/07/97 1.58 June 1.09 4.01 2.77 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 0035-1 0020-1 PPT in. PPT cm Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 Site A Benton County Benton County Site B WITHAM HILL DATA 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 -23.3 -17.3 12.0 13.9 9.3 7.4 -14.1 9.9 PPT in. 0.06 2.26 0.55 0.7 0.82 2.51 0.26 2.96 Nov Oct PPT cm -46.2 -22.4 -31.9 0.15 5.74 1.40 2.08 3.38 -9.8 -15.5 -11.7 -8.6 -20.8 -12.9 -15.2 -68.9 -48.7 -18.5 -16.0 -17.0 -18.5 -22.5 -17.0 -19.5 -7.5 -11.0 -10.5 -13.5 -9.0 -13.0 -12.5 -14.0 -30.5 -22.5 -27.5 -11.5 -12.5 -12.5 -11.0 8.3 4.0 5.7 9.0 5.8 1.6 2.9 5.8 7.0 1.4 7.1 11.9 2.8 7.3 3.6 6.0 1.6 4.0 6.2 3.4 3.2 6.9 3.4 4.6 3.74 2.71 0.08 3.26 4.09 2.7 Dec 1.78 6.38 0.66 9.9 1.6 3.9 1.5 1.75 Jan 7.52 8.59 9.50 6.88 2 2 3 2 2 1 1 1 1 0.20 4.4 6.0 1.27 6.5 Feb 3.81 4.45 8.28 10.39 3.23 16.51 47.0 66.0 49.5 32.0 60.0 40.5 42.5 33.5 82.0 42.5 43.0 55.0 71.5 57.5 36 61.5 42.5 40 Saturation (graphing) 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 57.0 61.0 3.6 81.3 70.6 20.5 95.6 69.0 27.0 13.2 3 84.0 72.0 23.0 2 1 1 33.0 30.5 43.0 65.0 47.0 47.5 Site B WITHAM HILL DATA 2/17/96 2/23/96 3/01/96 3/08/96 3/15/96 3/23/96 3/30/96 4/04/96 -42.5 -30.0 -8.0 -11.0 -12.0 -13.5 -40.5 -31.0 -26.5 -16.5 -22.5 -59.5 -45.5 -82.0 -63.0 -99.0 -97.0 4.3 3.4 7.5 2.3 3.5 1.8 4.8 1.4 2.3 1.0 1.4 2.2 0.55 March 11.38 1.40 1.73 0.43 0.2 4/11/96 Benton County 4/18/96 4/25/96 5/04/96 -96.0 -74.5 -10.5 -16.0 -13.0 -14.0 4.3 2.9 2.3 2.6 2.2 5/09/96 5/16/96 5/24/96 5/30/96 -75.5 -58.0 -95.5 -43.0 -40.0 -89.0 -77.0 2.3 6.4 1.2 2.3 1.7 3.4 1.63 2.04 0.11 6/14/96 6/21/96 0 0.1 Field Data W-100 P-75-1 P-35-1 P-20-1 D0 -W100 0075-1 2.7 2.6 D035-1 0020-1 PPT in. PPT cm 0.04 0.10 4.48 2.0 0.7 0.98 0.78 0.72 1.09 0.51 1.78 0.06 2.9 April 4.39 3.1 0.17 May 2.49 1.98 1.83 7.37 June 0.15 0.43 4.14 5.18 0.28 Saturation (gr 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 3 2 1 1 67.0 79.0 32.5 60.0 42.0 42.5 3 2 1 65.0 80.0 1 51.0 65.5 52.5 2 1 84.0 94.5 1 106.5 112.0 123.5 121.5 1 1 1 120.5 123.5 35 65 43 43 100 107 1 120 67.5 89 1 113.5 126 0.25 6/28/96 Benton County Site B WITHAM HILL DATA 9/24/96 10/03196 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 -11.5 -12.5 -12.5 -11.0 -66.0 -52.5 -13.0 -15.5 -14.5 -14.0 6.0 2.5 1.6 1.8 5.9 1.2 8.5 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT In. PPT cm -30.5 -21.5 -24.0 -48.0 -34.5 -17.0 -15.0 -14.5 -17.0 -16.0 -15.0 -15.0 -16.5 -59.5 -46.5 10.2 9.0 6.7 5.1 5.1 2.0 5.5 8.3 5.2 1.0 4.7 6.7 2.6 2.7 3.08 5.02 0.69 9.1 0.75 1.91 0 0.39 0.99 1.37 3.48 2.17 Oct 1.39 5.51 3.53 0.45 0.57 6.58 2.46 Nov -17.0 -17.0 -16.0 -16.5 4.4 6.0 4.43 6.8 Dec 1.14 1.45 16.71 6.25 8.1 0.52 2.25 1.32 5.72 Jan 7.82 12.75 3 2 1 1 11.25 17.27 3 3 3 2 2 2 1.75 Saturation WI 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 2 1 55 70.5 54 1 72.5 83.5 41.5 64 44.5 46 40.5 64 45 45.5 1 84 95.5 1 41.5 66 46 45.5 1 36 61.5 42.5 40 2 1 1 90.5 101.5 37.5 64.5 44.5 43 Benton County Site B WITHAM HILL DATA 1/25/97 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 4/26/97 5/03/97 -18.0 -17.5 -17.5 -18.0 -11.5 -15.0 -16.0 -13.5 -40.5 -32.0 -58.0 -47.5 -47.5 -36.5 -31.0 -21.5 -23.5 -22.5 -18.5 -19.0 -23.5 -18.0 -20.0 -33.5 -23.0 -29.0 -67.0 -52.0 -86.0 -68.5 -99.5 -25.5 -22.0 -23.0 -59.0 -47.0 6.5 1.2 8.1 1.0 3.9 2.3 1.3 2.6 1.2 2.9 4.3 4.8 0075-1 1.0 1.1 2.0 0.8 3.2 0.9 2.7 2.9 D035-1 D020-1 7.1 7.1 3.7 11.1 4.5 1.2 2.6 5.1 2.8 0.8 1.1 1.2 3.1 PPT in. 0.8 3.31 2.45 2.11 1.22 0.23 PPT cm 2.03 8.41 0.35 Mar 0.89 6.22 5.36 3.10 0.58 4/18/97 5/10/97 5/16/97 5/24/97 0 0.37 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 1.1 0.24 Feb 0.61 0.41 0.75 1.04 1.91 4.5 1.9 0.45 April 1.14 0.35 0.68 1.88 0.89 1.73 4.78 0.68 May 1.73 Saturation (gr 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 3 2 2 2 2 1 1 1 1 42.5 66.5 47.5 47 36 65 64 81 46 42.5 82.5 96.5 72 85.5 55.5 70.5 53.5 47 67.5 49 48 67 50 58 72 59 2 1 91.5 101 1 110.5 117.5 1 124 50 71 53 1 83.5 96 0.11 0.28 0.94 WITHAM HILL DATA 6/01/97 6/07/97 1.58 1.09 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT In. June PPT cm Saturation (gr 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 4.01 2.77 Site B Benton County Site C WITHAM HILL DATA 10 \ 10 \ 95 10/17/95 10/24/95 Field Data W-100 10 \ 31 \ 95 11 \ 07 \ 95 -95.3 -96.7 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 12/26/95 -77.1 -64.2 P-75-1 P-35-1 P-20-1 -79.5 -69.0 8.3 0.06 2.26 0.55 0.7 0.82 2.51 0.26 0.15 5.74 1.40 2.08 6.38 0.66 1/26/96 2/02/96 2/09/96 -7.5 -7.5 -5.5 -7.5 -6.0 -4.5 -4.5 -6.5 -1.0 -1.5 0.0 -2.5 -1.0 -1.5 -1.0 -2.5 -6.5 -3.0 -4.0 -5.5 -3.0 -3.0 -1.5 -4.5 2.3 1.6 7.2 3.1 4.8 2.5 3.5 3.3 4.1 4.4 4.09 1.27 6.5 -28.3 9.5 8.1 2.6 4.6 2.0 2.7 3.7 1.1 3.1 1.8 1.7 2.8 1.3 1.7 5.9 5.1 2.1 2.0 1.6 1.9 2.4 3.7 7.8 2.4 2.5 4.2 3.38 3.74 2.71 1.5 1.75 3.26 2.96 -24.1 -25.9 0.08 Dec 1.78 1/19/96 -5.7 -1.7 -4.0 -5.3 Nov Oct 1/12/96 -4.7 -4.3 -2.7 -3.2 8.6 0035-1 0020-1 1/02/96 -9.0 -3.4 -7.4 -7.9 -12.2 DO-W100 D075-1 PPT cm -15.5 -10.3 -10.1 PPT in. Benton County 4.2 3.8 Jan 7.52 8.59 9.50 6.88 3 2 3 3 3 2 2 2 2 1 1 1 1 1 89.6 75.0 28.9 9.0 96.5 83.0 32.0 14.0 0.20 1.1 1.1 Feb 3.81 4.45 8.28 10.39 3.23 16.51 3 3 2 3 3 2 2 3 2 3 2 1 1 1 1 1 1 Saturation (graphing) 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 1 3.5 5.0 24.3 12.5 21.7 7.0 101.0 82.0 37.5 19.5 100.0 85.0 36.0 17.0 76.0 59.0 10.5 31.5 56.0 45.0 37.0 30.0 53.0 44.0 36.0 25.0 50.0 39.5 32.0 25.0 50.0 40.5 32.0 30.5 51.5 43.5 35.0 27 51.5 41 34 Benton County Site C WITHAM HILL DATA 2/17/96 2/23/96 3/01/96 3/08/96 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 5/30/96 6/14/96 -12.5 -9.5 -8.0 -8.5 -1.0 -0.5 -0.5 -2.5 -10.0 -6.0 -3.5 -4.5 -4.5 -24.5 -25.0 -26.5 -34.0 -33.5 -33.5 -45.5 -43.5 -44.5 -43.0 -65.0 -62.5 -37.5 -32.5 -29.0 -5.0 -4.5 -4.0 -6.0 -27.0 -32.5 -35.5 -55.0 -51.5 -37.5 -32.5 -30.0 -22.0 -18.0 -17.5 -19.0 -46.0 -41.5 -98.5 1.7 2.5 4.5 1.2 1.2 2.9 1.5 2.0 1.6 1.2 1.4 2.3 1.2 1.2 1.2 1.5 1.2 2 1.7 2.3 1.6 1.6 3.6 1.0 1.3 1.4 1.3 3.1 1.8 1.5 1.9 1.3 1.3 3.6 1.3 1.5 1.6 1.2 1.2 1.73 0.43 0.72 2.9 0.17 1.63 2.04 0.11 6/21/96 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm 3.1 3.5 0.04 0.10 -9.0 -10.0 -8.5 1.9 3.2 2.1 0.2 0.55 March 1.40 11.38 4.39 1.09 0.51 4.48 0.7 0.98 0.78 April 1.78 4.5 0.06 May 2.49 1.98 0.1 June 1.83 7.37 0.15 2 3 2 2 1 1 1 1 51 79 100 0.43 4.14 5.18 0.28 0.25 Saturation (g 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 3 2 3 2 3 2 3 2 2 2 1 1 1 1 1 1 36.5 58.0 47.5 38.0 25.0 49.0 40.0 32.0 34.0 57.5 49.5 38.0 30.0 52.0 44.0 34.0 48.5 73.5 66.0 58.0 82.0 73.0 1 1 1 69.5 92 68.5 91.5 89 61.5 111 81 68.5 29 53 43.5 35.5 81 75 2 1 61.5 81 69.5 46 66.5 57 48.5 1 70 90 122.5 6/28/96 Benton County Site C WITHAM HILL DATA 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 -3.0 -3.0 -1.5 -4.5 -30.0 -30.0 -30.0 -9.0 -19.0 -6.5 -8.5 4.1 0.9 1.8 5.3 2.3 0.9 1.0 3.8 0.52 2.25 1.32 5.72 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm -13.5 -11.5 -9.5 -13.5 -25.0 -21.5 -18.5 -10.5 -8.0 -7.0 -10.5 -8.5 -6.5 -5.5 -9.5 -28.5 -27.0 -27.0 10.8 5.8 5.6 4.5 3.6 1.2 3.0 1.5 1.5 1.7 4.2 9.1 7.7 8.5 0.75 1.91 0 0.39 0.99 1.37 3.48 2.17 Oct 1.39 5.51 3.53 0.45 0.57 6.58 2.46 Nov 1.1 1.1 5.6 4.9 3.08 5.02 -8.0 -7.5 -6.0 -7.5 1.1 1.1 4.4 0.69 4.43 6.8 Dec 1.14 1.45 16.71 6.25 Jan 7.82 12.75 1.75 11.25 17.27 Saturation (g 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 3 3 2 2 2 2 3 2 3 2 2 2 2 1 1 1 1 1 1 1 1 1 27 51.5 54 78.5 69.5 3 37.5 60 49 43 49 70 58 34.5 56.5 46.5 40 32.5 55 45 39 52.5 75.5 66.5 32 56 45.5 37 41 34 3 33 67.5 46 38 Site C WITHAM HILL DATA Benton County 1/25/97 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 -9.5 -8.5 -7.5 -7.5 -7.5 -6.0 -3.5 -7.0 -50.0 -18.5 -18.5 -29.5 -30.0 -29.5 -25.0 -25.5 -25.5 -4.5 -6.5 -4.5 -6.5 -8.5 -5.5 -6.5 -7.0 -9.5 -8.5 -8.0 -8.5 -13.0 -12.5 -11.5 -14.0 -30.5 -35.0 -33.5 -46.0 -46.5 -57.0 -54.0 -63.0 -59.5 -10.5 -12.5 -11.5 -14.5 -32.0 -27.0 -25.0 -65.0 -60.0 -89.0 DO-W100 D075-1 D035-1 D020-1 3.6 0.7 2.5 1.6 1.3 1.8 0.7 0.7 1.3 1.9 6.1 1.0 1.3 1.9 1.0 1.2 1.9 1.0 1.0 1.5 1.1 1.1 1.1 1.8 0.9 0.8 1.0 1.6 1.5 0.7 1.0 2.2 1.0 2.0 3.1 1.4 4.9 2.9 1.0 1.7 2.5 2.1 1.0 1.2 1.6 PPT in. 0.8 3.31 0.24 0.41 0.75 2.11 1.22 0.23 0.45 April 0.35 0.68 1.88 0 8.41 1.04 1.91 6.22 5.36 3.10 0.58 1.14 0.89 1:73 4.78 0.68 May 1.73 0.11 2.03 0.35 Mar 0.89 2.45 Feb 0.61 3 3 2 2 2 2 3 2 3 2 3 2 2 3 2 2 1 1 1 1 1 1 1 1 1 1 37 54.5 83.5 73 5/24/97 Field Data W-100 P-75-1 P-35-1 P-20-1 PPT cm 1.3 1.1 3.4 8.9 0.8 1.3 1.7 0.28 0.94 Saturation (g 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 33.5 57 47 37 31.5 54.5 43 36.5 74 67 58 53.5 78.5 69 49 74 65 28.5 55 44 36 32.5 54 46 36.5 33.5 57 47.5 38 61 51 43.5 3 1 70 95 2 2 1 1 1 1 81 87 108 34.5 56 75.5 64.5 102.5 61 51 44 1 89 108.5 0.37 113 WITHAM HILL DATA 6/01/97 6/07/97 1.58 June 4.01 1.09 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 0075-1 D035-1 0020-1 PPT in. PPT cm Saturation (g 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 2.77 Site C Benton County Site D WITHAM HILL DATA 10 \ 10 \ 95 10/17/95 10/24/95 10 \ 31 \95 11 \ 07 \ 95 Benton County 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 6.9 6.4 2/02/96 2/09/96 1.0 0.0 -58.0 -5.5 -3.0 -58.0 -6.0 -4.0 0.0 -62.5 -4.5 -0.5 Field Data -85.8 W-100 P-75-1 P-35-1 P-20-1 -76.9 -84.2 -34.3 -74.2 8.0 DO-W100 D075-1 D035-1 D020-1 -3.8 -70.9 -6.6 -2.8 -0.9 0.06 2.26 0.55 0.82 7.4 0.7 2.51 0.26 2.96 Nov 0.15 5.74 1.40 2.08 -2.8 -53.0 -5.7 -0.2 -6.6 -49.8 -10.9 -6.6 -3.0 -55.0 -8.0 -7.0 -1.0 -51.0 -6.0 -5.0 0.0 -55.0 -4.0 -3.0 8.3 7.0 3.9 2.7 6.5 4.8 7.9 6.9 3.5 6.1 9.1 7.1 1.8 3.8 1.5 2.7 4.8 2.0 2.9 7.9 2.8 3.4 5.0 6.8 7.4 8.3 2.6 3.3 3.38 3.74 2.71 1.5 1.75 3.26 4.09 -5.7 -1.9 7.8 Oct 0.0 -49.0 -5.3 -1.0 -55.1 10.1 PPT in. PPT cm -47.2 6.1 3.4 0.08 Dec 1.78 6.38 0.66 Jan 3.2 2.7 6.4 1.9 7.9 1.27 6.5 3.1 Feb 7.52 8.59 9.50 6.88 0.20 3.81 4.45 8.28 10.39 3.23 16.51 3 2 3 2 3 2 3 3 2 3 2 3 2 3 2 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 1 1 106.0 32.0 34.5 22.0 103.0 27.0 34.0 23.0 Saturation (graphing) 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 1 15.0 24.5 16.8 69.6 1.0 56.0 102.0 5.0 33.0 20.0 105.0 24.5 34.0 21.0 99.0 31.0 28.0 15.5 17.0 104.0 48.0 36.0 15.0 100.0 46.0 34.0 14.0 104.0 44.0 32.0 13.0 107.0 45.5 32.0 14.0 107.0 46.0 33.0 14 111.5 44.5 29.5 Site D WITHAM HILL DATA Benton County 2/17/96 2/23/96 3/01/96 3/08/96 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 5/30/96 6/14/96 6/21/96 -1.0 -43.5 -7.5 -5.5 0.0 -58.5 -5.0 -3.0 -1.0 -60.0 -7.5 -6.0 -1.0 -61.0 -6.0 -4.0 -7.0 -59.5 -13.5 -11.5 -5.0 -61.0 -13.5 -10.0 -17.0 -65.0 -13.5 -19.5 -16.0 -58.5 -22.5 -17.5 -39.0 -71.0 -2.5 -66.0 -10.5 -6.0 0.5 -61.0 -6.0 -3.0 -23.0 -64.0 -29.0 -45.0 -60.0 -7.0 -69.0 -15.0 -11.0 -5.0 -60.0 -11.0 -7.5 -32.5 -66.0 -84.5 -97.5 3.3 7.3 3.3 2.3 5.6 5.5 3.4 2.3 4.8 4.5 2.2 3.5 1.5 5.5 1.8 3.8 1.7 4.8 4.7 3.9 1.5 1.7 2.2 4.4 2.0 2.3 1.2 3.2 1.7 1.4 2.7 2.3 1.4 5.2 2.0 1.9 0.55 March 11.38 1.40 1.73 0.43 0.72 2.9 1.63 2.04 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm 0.04 0.10 4.48 1.9 1.4 1.6 1.7 1.3 4.3 4.3 2.3 4.3 4.3 1.4 1.9 0.2 0.7 0.98 2.1 0.78 April 2.1 4.3 0.06 0.17 1.8 0.11 May 4.39 1.09 0.51 1.78 2.49 1.98 0 0.1 June 1.83 7.37 0.15 3 2 3 2 2 1 1 1 0.43 4.14 5.18 3 2 3 2 1 1 0.28 0.25 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 3 2 3 2 3 2 3 2 3 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 15.0 92.5 47.5 34.5 14.0 107.5 45.0 32.0 15.0 109.0 47.5 35.0 15.0 110.0 46.0 33.0 21.0 108.5 53.5 40.5 19.0 110.0 53.5 39.0 31 114 53.5 48.5 30 107.5 62.5 46.5 1 53 120 16.5 115 50.5 35 13.5 110 46 32 37 113 69 1 59 109 21 118 55 40 19 109 51 36.5 1 46.5 115 98.5 111.5 Site D WITHAM HILL DATA 6/28/96 Benton County 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 0.0 -62.5 -4.5 -0.5 -6.0 -61.0 -13.5 -8.0 -1.0 -68.5 -6.5 -4.5 2.7 6.4 1.9 7.9 1.7 7.4 2.0 1.9 1.9 8.2 1.5 3.0 0.52 2.25 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm 0.75 1.91 0 0.39 0.99 1.37 3.48 2.17 Oct 1.39 5.51 3.53 0.45 0.57 -2.0 -23.0 -8.0 -4.0 -5.0 -64.5 -13.5 -9.5 -1.0 -74.0 -6.5 -4.0 -1.0 -72.0 -6.5 -2.5 -5.5 -69.5 -14.0 -9.0 8.8 8.6 8.9 5.6 1.8 9.0 1.5 6.1 3.1 2.6 8.4 1.3 3.6 4.7 3.6 7.8 2.2 2.7 6.58 2.46 3.08 5.02 0.69 5.3 3.6 Nov -1.0 -70.5 -7.0 -3.0 4.43 6.8 Dec 1.14 1.45 Jan 16.71 6.25 7.82 12.75 1.75 11.25 17.27 1.32 5.72 3 2 3 2 3 3 3 2 2 3 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 15 19.5 118.5 54 38 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 16 19 72 48 33 113.5 53.5 38.5 15 123 46.5 33 121 46.5 31.5 15 119.5 47 32 14 111.5 44.5 29.5 20 110 53.5 37 2 15 117.5 46.5 33.5 Site D WITHAM HILL DATA Benton County 1/25/97 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 5/24/97 -1.5 -70.5 -7.0 -5.0 -1.0 -69.0 -7.0 -3.0 -3.5 -68.5 -12.0 -6.5 -6.5 -69.5 -14.0 -10.0 -6.0 -69.5 -13.0 -8.5 -1.0 -69.5 -9.0 -3.0 -2.0 -67.0 -7.5 -2.5 -2.5 -70.0 -8.0 -7.0 -4.0 -70.0 -10.0 -6.5 -6.5 -70.0 -14.0 -10.5 -14.5 -72.0 -20.5 -17.0 -20.0 -70.0 -25.5 -16.0 -71.0 -24.0 -7.5 -71.0 -14.0 -10.5 -7.0 -71.0 -15.0 -10.0 -38.0 -72.5 -68.0 -92.5 DO-W100 D075-1 D035-1 D020-1 3.3 9.2 1.6 1.6 1.5 8.3 8.7 2.8 2.8 10.2 1.8 1.4 1.3 8.2 1.7 1.3 1.0 8.9 2.0 2.0 7.0 2.6 1.8 1.0 5.0 1.5 1.2 1.9 1.6 3.5 3.2 1.5 6.1 1.7 1.2 PPT in. 0.8 3.31 0.41 0.75 0.35 0.68 1.88 0.37 2.03 8.41 1.04 0.89 1.73 4.78 0.68 May 1.73 0 PPT cm 0.24 Feb 0.61 3 2 3 3 2 2 1 1 1 Field Data W-100 P-75-1 P-35-1 P-20-1 1.1 1.1 1.1 1.0 1.1 2.1 8.3 1.8 1.4 8.6 1.7 1.7 9.0 1.9 1.2 7.5 2.1 8.3 2.0 1.3 1.5 6.7 3.5 2.3 2.45 2.11 1.22 0.23 1.91 0.35 Mar 0.89 6.22 5.36 3.10 0.58 3 2 3 2 3 2 3 2 3 2 3 2 3 2 3 2 2 3 2 3 2 1 1 1 1 1 1 1 1 1 1 1 1 1 30 120 64 21.5 21 120 54 39.5 120 55 39 52 121.5 1.1 0.45 April 1.14 6.1 5.9 0.11 0.28 0.94 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 15.5 119.5 47 34 15 118 47 32 17.5 117.5 52 35.5 20.5 118.5 54 39 20 118.5 53 37.5 15 118.5 49 32 16 116 47.5 31.5 16.5 119 48 36 18 20.5 28.5 119 50 119 54 121 35.5 39.5 60.5 46 34 119 65.5 2 82 106.5 WITHAM HILL DATA 6/01/97 6/07/97 Field Data W-100 P-75-1 -24.0 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm 4.7 1.58 June 1.09 4.01 2.77 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 38 Site D Benton County Site E WITHAM HILL DATA Benton County 10\10\95 10/17/95 10/24/95 10\31\95 11\07\95 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 -11.0 -6.5 -7.5 -2.5 -8.5 -4.5 -6.0 -1.0 -3.0 -2.5 -3.0 0.0 -2.0 -3.0 -3.0 -0.5 -11.0 -5.5 -7.5 -2.0 -2.0 -1.5 -2.5 2.5 6.5 5.5 2.4 14.2 9.5 3.3 5.5 10.6 4.9 2.4 3.9 4.8 5.7 3.3 3.2 7.2 1.5 7.3 7.3 2.9 3.2 1.5 1.75 3.26 4.09 1.27 6.5 Field Data W-100 -72.6 P-75-1 P-35-1 P-20-1 -49.1 11.3 DO-W100 D075-1 D035-1 D020-1 -8.2 -1.4 -2.0 0.6 -4.7 -2.2 -2.9 2.6 -3.8 -3.0 -2.0 -8.5 -6.9 -3.9 1.7 1.7 6.8 4.8 9.5 4.9 1.7 3.7 9.4 5.0 1.6 3.5 6.9 5.4 1.9 3.4 5.1 3.38 3.74 2.71 0.08 3.1 2.8 PPT in. 0.06 2.26 0.55 0.7 0.82 2.51 0.26 2.96 0.15 5.74 1.40 2.08 -15.1 -10.3 -11.4 -9.2 6.9 2.3 4.7 Dec Nov Oct PPT cm -70.8 -52.8 1.78 6.38 0.66 Jan 3.1 1.2 1.6 Feb 7.52 8.59 9.50 6.88 0.20 3.81 4.45 8.28 10.39 3.23 16.51 Saturation (graphing) 20 cm 35 cm 75 cm 1 Raw PZ Data W-100 29.0 30.0 P-75-1 P-35-1 P-20-1 1.06 1 31.0 25.8 3 3 3 2 2 3 2 3 2 3 2 3 2 2 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 1 1 36.0 55.0 48.5 33.5 33.5 53.0 47.0 32.0 27.0 51.5 44.0 31.5 36.0 54.0 48.5 33.0 97.3 85.4 35.0 21.8 101.0 84.5 34.0 24.0 102.0 83.5 35.0 23.0 97.0 79.0 33.0 23.0 90.0 75.0 25.0 11.5 28.0 51.0 44.0 31.0 27 50 43.5 28.5 Site E WITHAM HILL DATA Benton County 2/17/96 2/23/96 3/01/96 3/08/96 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 5/30/96 -5.5 -5.0 -5.0 -2.5 -1.0 -2.5 -2.0 -13.0 -8.0 -10.0 -6.0 -9.5 -4.5 -6.5 -2.5 -19.0 -14.0 -17.0 -15.0 -17.0 -20.5 -16.0 -14.0 -30.0 -23.0 -29.0 -27.0 -19.5 -25.0 -50.5 -49.5 -7.0 -11.0 -8.5 -3.5 -13.5 -4.5 -4.0 -1.0 -30.0 -34.5 -58.5 -55.5 -12.5 -18.5 -8.5 -9.0 -13.0 -8.0 -12.5 -8.0 -45.5 -35.5 DO-W100 D075-1 D035-1 D020-1 4.3 4.9 3.3 3.5 7.6 3.9 1.6 2.5 4.8 3.4 2.0 3.1 1.2 1.9 1.3 1.6 3.0 1.4 4.1 4.0 4.0 2.9 1.5 3.6 2.0 5.8 1.5 2.6 2.2 3.8 2.3 4.8 1.6 4.8 1.4 2.1 3.5 1.7 1.4 2.2 1.3 5.8 1.7 2.9 4.3 2.3 1.9 14.2 1.8 3.7 PPT in. 0.04 0.55 March 11.38 1.40 1.73 0.43 0.2 0.72 2.9 1.63 2.04 6/14/96 6/21/96 0 0.1 Field Data W-100 P-75-1 P-35-1 P-20-1 PPT cm Saturation (En 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 0.10 1.0 4.48 0.7 0.98 4.39 1.09 0.51 1.78 2.49 3 2 3 2 3 3 2 2 3 2 2 2 1 1 1 1 1 1 1 1 42.0 69.0 57.0 45.0 55 71.5 70 26.0 51.0 43.0 30.0 38.0 56.5 51.0 37.0 34.5 53.0 47.5 33.5 44.0 62.5 58.0 46.0 0.06 0.17 0.11 May 3 2 30.5 53.5 46.0 33.5 0.78 April 1.0 52 68 66 1.98 1 75.5 98 1.83 7.37 3 2 3 2 1 1 32 59.5 49.5 34.5 38.5 53 45 32 June 0.15 1 55 83 0.43 1 83.5 104 4.14 5.18 3 2 3 1 1 1 38 70.5 84 37.5 67 49.5 40 0.28 2 56.5 53.5 39 0.25 Site E WITHAM HILL DATA 6/28/96 Benton County 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10/31/96 11/07/96 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1111197 1/20/97 -2.0 -1.5 -2.5 2.5 -13.0 -11.0 -12.5 -7.5 -4.5 -5.0 -5.0 -12.5 3.9 Field Data -3.5 -11.0 -5.5 W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm 0.75 1.91 0 0.39 0.99 1.37 3.48 2.17 Oct 1.39 5.51 3.53 0.45 0.57 -4.0 -3.5 -5.0 1.0 -3.5 -3.0 -4.5 1.0 -11.5 -9.5 -11.5 -7.0 1.0 -13.0 -10.5 -12.0 -8.0 8.9 8.3 5.2 4.8 3.8 3.9 1.5 1.6 4.8 3.8 4.9 3.0 7.2 4.9 3.1 2.7 2.5 1.1 4.1 1.0 1.8 1.4 2.1 1.2 1.6 1.2 1.2 1.6 0.9 1.8 6.58 2.46 3.08 5.02 0.69 0.52 2.25 Nov 1.1 -4.5 -4.0 -5.0 -1.0 4.43 6.8 Dec 1.14 1.45 Jan 16.71 6.25 7.82 12.75 1.75 11.25 17.27 1.32 5.72 3 3 2 3 2 3 2 3 3 2 2 2 3 2 3 2 3 2 1 1 1 1 1 1 1 1 1 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 28.5 59.5 46.5 30 36.5 58 52.5 38 29 52 46 30 28.5 51.5 45.5 30 38 59 53 39 29.5 52.5 46 32 27 50 43.5 28.5 38 59.5 53.5 38.5 29.5 53.5 46 43.5 Site E WITHAM HILL DATA Benton County 1/25/97 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 -4.0 -7.0 -3.5 -0.5 -5.0 -3.0 -5.0 -0.5 -13.0 -10.5 -12.0 -6.5 -18.0 -13.5 -16.0 -11.0 -17.0 -12.5 -15.5 -10.0 -2.5 -6.0 -6.5 -2.0 -3.5 5.0 -5.0 -0.5 -8.0 -6.0 -10.0 -1.0 -15.5 -10.0 -13.0 -8.5 -20.0 -14.5 -19.0 -12.5 -30.0 -22.5 -28.0 -35.0 -27.0 -31.5 -30.0 -25.0 -28.5 -21.5 -13.0 -20.0 -13.0 -21.5 -15.5 -18.0 -13.0 -53.5 -46.0 -77.0 -75.0 DO-W100 D075-1 6.9 1.5 4.5 1.9 1.6 2.0 7.0 2.6 1.5 1.9 0.8 3.2 6.2 2.3 1.1 1.1 2.0 1.0 0.9 1.5 1.7 2.2 0.8 2.3 1.3 1.0 1.2 2.4 1.2 1.0 1.2 1.3 1.2 1.0 1.3 2.4 1.7 1.0. 1.0 7.7 1.3 0.7 1.0 4.2 1.1 1.7 1.5 1.0 1.0 4.4 0035-1 0020-1 2.1 1.6 1.1 0.41 0.75 2.45 2.11 1.22 0.23 0.68 1.88 0 6.22 5.36 3.10 0.58 0.89 1.73 4.78 0.68 May 1.73 0.11 1.91 0.45 April 1.14 0.35 1.04 0.35 Mar 0.89 3 5/24/97 Field Data W-100 P-75-1 P-35-1 P-20-1 1.4 1.6 1.0 1.2 PPT in. 0.8 3.31 PPT cm 2.03 8.41 0.24 Feb 0.61 3 2 3 2 3 2 3 2 3 2 3 2 3 2 3 2 3 2 2 2 2 2 2 3 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0.9 1.1 1.5 1.7 0.28 0.94 Saturation (gr 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 29 55.5 44.5 31.5 30 51.5 46 31.5 38 59 53 37.5 43 62 57 42 42 61 56.5 41 27.5 54.5 47.5 33 28.5 43.5 33 54.5 40.5 58.5 46 31.5 51 54 39.5 32 45 63 60 43.5 3 55 71 69 60 75.5 72.5 55 73.5 69.5 46.5 61.5 61 44 46.5 64 59 44 1 78.5 94.5 0.37 1 102 123.5 WITHAM HILL DATA 6/01/97 6/07/97 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. PPT cm -63.5 -61.0 4.7 6.6 1.58 June 1.09 4.01 2.77 Saturation (9, 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 1 88.5 109.5 Site E Benton County Site F WITHAM HILL DATA 10 \ 10 \ 95 10/17/95 10/24/95 10 \ 31 \ 95 11 \ 07 \ 95 Benton County 11/14/95 11/21/95 11/28/95 12/05/95 12/12/95 12/19/95 12/26/95 1/02/96 1/12/96 1/19/96 1/26/96 2/02/96 2/09/96 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 0075-1 -55.7 -54.9 -6.6 -4.9 -6.5 -4.7 -4.2 -2.2 -1.3 -3.6 -4.7 -5.2 -0.0 -1.9 -12.3 -12.9 -5.7 -8.8 -23.6 -23.3 -22.8 -17.5 -17.0 -15.0 -17.0 -16.5 -16.0 -13.0 -16.0 -4.5 -3.0 -0.5 -3.0 -8.0 -7.5 -5.0 -7.0 -26.5 -28.0 -25.0 -4.5 -4.0 -1.5 -3.5 8.9 12.3 9.5 5.5 4.1 3.8 2.9 2.3 2.5 3.5 4.6 4.6 3.7 3.0 3.3 4.3 5.3 3.0 3.0 3.6 3.8 3.6 5.3 1.7 1.4 0.26 2.96 3,38 3.74 2.71 0.08 1.5 1.75 3.26 4.09 5.1 D035-1 0020-1 0.06 PPT in. 2.26 0.55 0.82 PPT cm 0.7 2.51 Nov Oct 0.15 5.74 1.40 2.08 Dec 1.78 6.38 0.66 Jan 7.52 8.59 9.50 6.88 3 2 3 2 3 2 3 1 1 1 99.0 81.3 35.0 17.8 101.5 84.5 41.5 19.0 1.27 6.5 Feb 0.20 3.81 4.45 8.28 10.39 3.23 16.51 2 2 3 2 3 2 3 2 3 2 2 3 2 1 1 1 1 1 1 1 1 50.0 78.0 65.0 28 54 41.5 33.5 Saturation (graphing) 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 1 47.0 23.3 101.0 81.0 43.0 21.0 93.0 72.0 36.0 13.0 81.0 60.0 15.0 41.0 67.0 55.0 47.0 40.0 66.0 53.0 46.0 28.0 53.0 40.5 33.0 31.5 57.5 45.0 37.0 Site F WITHAM HILL DATA Benton County 2/17/96 2/23/96 3/01/96 3/08/96 3/15/96 3/23/96 3/30/96 4/04/96 4/11/96 4/18/96 4/25/96 5/04/96 5/09/96 5/16/96 5/24/96 5/30/96 -8.5 -8.0 -4.0 -8.0 -4.5 -3.0 -2.0 -3.5 -25.5 -27.0 -24.5 -14.5 -15.0 -12.5 -15.0 -30.5 -33.5 -31.0 -31.5 -33.5 -30.0 -40.0 -42.0 -34.0 -34.0 -32.0 -54.0 -58.0 -7.5 -8.0 -5.5 -8.5 -8.5 -11.0 -7.5 -10.0 -51.5 -55.0 -65.5 -70.0 -21.5 -23.0 -21.0 -15.5 -17.5 -15.0 -18.0 -49.0 -53.5 DO-W100 D075-1 D035-1 D020-1 3.3 2.5 2.0 2.4 2.5 3.3 2.7 4.5 2.1 2.0 2.7 1.9 1.8 2.8 5.1 2.0 4.2 1.9 2.3 1.9 1.7 1.8 2.9 PPT in. 0.04 0.55 March 11.38 1.40 1.73 0.43 0.2 0.06 0.17 1.63 2,04 0.11 6/14/96 6/21/96 0 0.1 Field Data W-100 P-75-1 P-35-1 P-20-1 PPT cm 0.10 4.48 0.7 2.0 2.5 3.1 2.2 1.7 1.9 1.6 0.98 0.78 0.72 2.9 April 4.39 1.09 0.51 1.78 May 2.49 1.98 1.83 7.37 3 2 3 1 1 31 32 58 45.5 38.5 61 June 0.15 0.43 4.14 5.18 0.28 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 3 3 2 2 2 3 2 2 2 1 1 1 1 1 1 32.0 58.0 44.0 38.0 28.0 53.0 42.0 33.5 49.0 77.0 64.5 38.0 65.0 52.5 45.0 54.0 83.5 71.0 55.0 83.5 70.0 2 1 63.5 92 1 57.5 84 72 1 77.5 108 3 2 47.5 40 1 75 105 2 2 1 1 1 89 120 45 73 61 39 67.5 55 48 1 72.5 103.5 0.25 Site F WITHAM HILL DATA 6/28/96 Benton County 9/24/96 10/03/96 10/10/96 10/17/96 10/24/96 10131/96 11/07/96 11/17/96 11/21/96 11/27/96 12/05/96 12/10/96 12/19/96 12/24/96 12/31/96 1/11/97 1/20/97 -4.5 -4.0 -1.5 -3.5 -24.5 -27.5 -24,0 -7.5 -11.5 -7.0 -8.0 3.6 2.7 2.7 3.0 1.8 1.0 1.5 2.8 0.52 2.25 Field Data W-100 -90.0 -5.0 -6.0 -3.0 -6.0 -10.5 -12.5 -9.5 -19.5 -5.5 -6.5 -3.5 -5.0 -5.5 -6.5 -3.0 -5.0 -25.5 -29.0 -26.0 8.5 8.5 8.6 7.7 8.7 4.5 2.5 5.8 1.4 2.0 3.2 5.0 1.4 2.4 4.6 4.0 6.58 2.46 3.08 5.02 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 D035-1 D020-1 PPT in. 0.75 0 0.39 1.37 2.17 1.91 0.99 3.48 0.57 2.4 4.3 Nov Oct PPT cm 0.45 1.39 8.1 5.51 3.53 -6.5 -7.5 -5.0 -6.5 5.3 1.7 1.4 2.1 0.69 4.43 6.8 Dec 1.14 1.45 Jan 16.71 6.25 7.82 12.75 1.75 11.25 17.27 1.32 5.72 3 3 2 2 3 2 3 2 2 3 2 3 2 2 3 2 1 1 1 1 1 1 1 1 1 Saturation (gs 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 113.5 28.5 56 43 36 34 29 62.5 49.5 49.5 56.5 43.5 35 29 56.5 43 35 49 79 66 30 57.5 45 36.5 28 54 41.5 33.5 48 77.5 64 31 61.5 47 38 Site F WITHAM HILL DATA Benton County 1/25/97 2/01/97 2/08/97 2/15/97 2/22/97 3/01/97 3/08/97 3/15/97 3/22/97 3/30/97 4/05/97 4/12/97 4/18/97 4/26/97 5/03/97 5/10/97 5/16/97 -7.0 -7.5 -6.0 -4.5 -12.5 -15.5 -13.0 -13.0 -19.0 -20.5 -18.5 -22.0 -24.5 -22.5 -22.5 -25.0 -23.0 -3.5 -3.0 -2.0 -2.5 -7.5 -6.0 -3.0 -4.0 -11.0 -11.0 -9.5 -9.0 -21.0 -24.0 -20.0 -25.0 -29.0 -25.0 -34.0 -37.5 -33.5 -36.5 -41.0 -32.5 -37.0 -34.0 -30.5 -34.0 -31.0 -28.5 -32.0 -28.0 -52.5 -58.5 -79.0 2.5 1.4 1.6 3.4 2.0 2.8 1.4 2:8 1.0 1.9 1.4 3.0 1.2 1.7 2.6 2.6 1.7 2.2 2.8 1.6 1.9 2.5 2.6 5.7 1.7 3.8 2.8 2.0 4.0 1.3 3.3 1.2 2.1 2.4 0.9 1.5 2.6 2.3 2.0 2.8 1.6 1.9 3.1 1.6 D020-1 3.0 1.5 0.7 2.4 PPT in. 0.8 3.31 0.41 0.75 2.11 1.22 0.23 0.68 1.88 8.41 1.04 1.91 6.22 5.36 3.10 0.58 0.45 April 1.14 0.35 2.03 0.35 Mar 0.89 2.45 PPT cm 0.24 Feb 0.61 0.89 1.73 4.78 0.68 May 1.73 3 2 3 3 3 2 2 2 2 2 2 2 2 2 2 2 2 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 46 75 63 27 53 42 32.5 31 34.5 56 61 91 43 49.5 39 57.5 87.5 73.5 5/24/97 Field Data W-100 P-75-1 P-35-1 P-20-1 DO-W100 D075-1 0035-1 5.1 1.9 2.9 0.11 0 0.28 0.94 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 30.5 57.5 46 34.5 3 36 65.5 53 43 42.5 70.5 58.5 45.5 74.5 62.5 34 44.5 74 60 48.5 79 65 60 56 87 74 54 84 71 52 82 68 1 76 108.5 0.37 102.5 WITHAM HILL DATA 6/01/97 6/07/97 Field Data W-100 -64.5 P-75-1 P-35-1 P-20-1 D0 -W100 5.8 0075-1 D035-1 0020-1 PPT in. PPT cm 1.58 June 1.09 4.01 2.77 Saturation (gi 20 cm 35 cm 75 cm Raw PZ Data W-100 P-75-1 P-35-1 P-20-1 88 Site F Benton County 307 Appendix D Vegetation Characterization Data Vegetation Characterization of Site l SPECIES AGST AGTE ALPR AREL BRCO BRHY BRCO BRMO CADE CALE CAOL CATU CAUN CEVI CIVU DACA SCIENTIFIC NAME Agrostis stolonifera L. Agrostis tenuis Sibth. Alopecurus pratensis L Arrhenatherum elatus (L.) J. & K. Presl Brodiaea coronaria (Salisb.] Engl. Brodiaea hyacinthina (Lindl.) Baker 1.3 1.4 Plot Number 1.1 1.2 1.5 Mean % Quadrat 4/0 C 0/3 B 0/ 1 A 4/ 1 D 5/ 1 E areal Date 5/15 6/06 Avg. 5/15 6/06 Avg. 5/15 6/06 Avg. 5/15 6/06 Avg. 5/15 6/06 Avg. cover COMMON NAME Creeping Bentgrass Colonial Bentgrass 10 15 12.5 20 40 30.0 15 20 17.5 25 30 27.5 30 80 70 75.0 18 40 29.0 45 50 47.5 35 35 35.0 42 1 1 1 1 1.0 1.0 1 1.0 35 32.5 24.0 53.5 48.0 Meadow Foxtail Tall Oatgrass Hairy Chess Soft Brome Dense Sedge Carex densa (L.H. Bailey) L.H. Bailey Hare's-foot Sedge Carex leporina L. Few-seed Bitter-cress Cardamine oligosperma Nutt. Foothill Sedge Carex tumulicola Mackenzie One-sided Sedge Carex unilateralis Mackenzie Chickweed 1 Cerastium viscosum L. Bull Thistle Cirsium vulgare (Savi) Ten. Queen Anne's Lace Daucus carota L. Eleocharis palustris (L.) Roem. & J.A. Schultes Common Spikerush ELPA Epilobium glandulosum Lehm. EPGL Festuca dertonensis (All.) (F. bromoides) FEDE Meadow Fescue FEPR Festuca pratensis Huds. Red Fescue FERU Festuca rubra L. Tall Fescue Festuca arundinacea Schreb. FEAR Catchweed Bedstraw 1 Galium aparine L. GAAP Geranium Geranium dissectum L. GEDI Velvet Grass HOLA Holcus lanatus L. Soft Rush JUEF Juncus effusus L. Slender Rush Juncus tenuis Willd. JUTE Birds-foot Trefoil Lotus corniculatus L. LOCO Fountain Miner's-Lettuc MOFO Montia fontana L. Montia linearis (Dougl.] Greene MOLI 1 Blue Forget-Me-Not MYDI Myosotis discolor Pers. Yellow Parentucellia Parentucellia viscosa (L.) Caruel PAVI 20 Kentucky Bluegrass Poa pratensis L. POPR Straight-beak Butter-cu Ranunculus orthorhynchus Hook. RAOR Sheep Sorrel Rumex acetosella L. RUAC Suckling Clover TRDU Trifolium dubium Sibth. Clover Trifolium Trifolium spp. Corn Speedwell Veronica arvensis L. VEAR Common Vetch VISA Vicia sativa L. Bromus commutatus Schrad. Bromus mollis Schrad. 1 1.0 1 _, 65 0.2 0.2 1 1 1.0 0.6 0.4 15.0 15.0 1.5 2.2 0.6 1.0 1.0 1 1 20 25 10 3 6.5 1 1 1.0 1 1 -, 3 1 10 2.0 1.0 15.0 25 15 1 1 1 1 1 1 25 10 1 1 2 2 20.0 20 15 1.0 1.0 1 I 1.0 1.0 1 1 1.0 35 20 1.0 1 1 1.0 2.0 1 1 1.0 17.5 17.5 27.5 22.5 15 15 1 2 0.6 30 5 17.5 35 5 20.0 19.5 1 1 1.0 0.6 0.6 Ve:etation Characterization of Site2 Plot Number 2.1 2.2 I uadrat EN 1 Date SPECIES AGST AGTE ALPR AREL BRCO BRHY BRCO BRMO CADE CALE CAOL CATU CAUN CEVI C1VU DACA ELPA EPGL FEDE FEPR FERU FEAR GAAP GEDI HOLA JUEF JUTE LOCO MOFO MOLI MYDI PAVI POPR RAOR RUAC TRDU Cree in Bent:rass Colonial Bent:rass Alo.ecurus .ratensis L Arrhenatherum elatus L. J. & K. Presl Brodiaea coronaria Salisb. En:l. Brodiaea h acinthina Lindl. Baker Bromus commutatus Schrad. Bromus mollis Schrad. Carex densa L.H. Baffle Carex le .orina L. L.H. Baffle Cardamine olios.erma Nutt. Carex tumulicola Mackenzie Carex unilateralis Mackenzie Cerastium viscosum L. Cirsium vul:are Savi Ten. Daucus carota L. Eleocharis .alustris L. Roem. & J.A. Schultes E.ilobium Ilandulosum Lehm. Festuca dertonensis All. F. bromoides Festuca ratensis Huds. Festuca rubra L. Festuca arundinacea Schreb. Galium a.arine L. Geranium dissectum L. Holcus lanatus L. Juncus effusus L. Juncus tenuis Willd. Lotus corniculatus L. Montia fontana L. MIMI 6 06 MI WI B IMMO 2.5 C 6 06 areal E 6 06 12111 cover 40 25 32.5 25 30 10 10 10.0 2 2 27.5 2.0 40 50 2 3 45.0 2.5 1 1 1.0 25 20 2 2 22.5 2.0 20 2 50 35.0 2 2.0 32.5 3.7 Meadow Foxtail Tall Oat:rass Chess Soft Brome Hai 0.2 Dense Sed:e Hare's-foot Sed:e Few-seed Bitter-cress Foothill Sed:e One-sided Sed:e Chickweed Bull Thistle 1 1 1.0 0.2 ueen Anne's Lace Common S.ikerush Meadow Fescue Red Fescue Tall Fescue Catchweed Bedstraw Geranium Velvet Grass Soft Rush Slender Rush Birds-foot Trefoil Fountain Miner's-Lettuce Montia linearis Dou:I. Greene M osotis discolor Pers. Parentucellia viscosa L. Caruel Poa ratensis L. Ranunculus orthorh nchus Hook. Yellow Parentucellia Rumex acetosella L. Trifolium dubium Sibth. Shee. Sorrel Sucklin: Clover Trifolium Trifolium s... Veronica arvensis L. VEAR VISA Vicia sativa L. ME 6 06 El En= rffilltini 6 06 MIMI 2.4 2.3 D COMMON NAME SCIENTIFIC NAME A rostis stolonifera L. A:rostis tenuis Sibth. MI A Blue For:et -Me -Not Kentuck Blue rass Strai ht-beak Butter-cu 5 8 6.5 14 36 29 25.0 20.0 11 39 31 40 30 3 3 39.5 30.5 3.0 1 1 1.0 3 3 3.0 3 3 3.0 19 16 2 25 20 22.0 44 36 44 36 2 8 44.0 36.0 5.0 5 18.0 3.5 2.5 47 38 33 27 1 5 40.0 32.5 3.0 34.1 27.4 2.9 0.2 2 3 2.5 1 1 1.0 1 1 1.0 10 4 7.0 5 5 5.0 8 1 4.5 1 1 1.0 1 1 1.0 1 1 2 3 2.5 5 5 5.0 2 1 1.0 1.1 5 3.5 5.0 0.4 Clover Corn S.eedwell Common Vetch 1 1 1.0 1 5 3.0 2 1 1.5 1.6 Ve:etation Characterization of Site 3 Plot Number 3.1 uadrat 4 1 3.2 D Date 5 15 6 06 SPECIES AGST AGTE ALPR AREL BRCO BRHY BRCO BRMO CADE X 1 3.5 Mean % areal A Av: cover COMMON NAME SCIENTIFIC NAME A rostis stolonifera L. A. rostis tenuis Sibth. Cree.in: Bent:rass 35 45 Colonial Bent:rass 2 2 40.0 2.0 Alo.ecu us . a ensis L Arrhenatherum elatus L. J. & K. Presl Brodiaea coronar a Salisb. En:!. Brodiaea h acinthina Lindl. Baker Meadow Foxtail Tall Oa ass 2 1 1.5 1 1 1.0 Chess Soft Brome Dense Sed:e Hare's-foot Sed:e Carex le .orma L. CALE Few-seed Bitter-cress Cardamine or:os. rma Nutt. CAOL Foothill Sed:e Carex tumulicola Mackenzie CATU One -sided Sed:e Carex unilateralis Mackenzie CAUN Chickweed Cerastium v scosum L. CEVI Bull Thistle Cirsium vulgare (Savi) Ten. CIVU Queen Anne's Lace DACA Daucus carota L. Eleocharis palustris (L.) Roem. & J.A. Schu Common Spikerush ELPA EPGL Epilobium glandulosum Lehm. Festuca dertonensis (All.) (F. bromoides) FEDE Meadow Fescue Festuca pratensis Huds. FEPR Red Fescue FERU Festuca rubra L. Tall Fescue FEAR Festuca arundinacea Schreb. Catchweed Bedstraw Galium aparine L. GAAP Geranium Geranium dissectum L. GEDI Velvet Grass HOLA Holcus lanatus L. Soft Rush JUEF Juncus effusus L. Slender Rush Juncus tenuis Willd. JUTE Birds-foot Trefoil Lotus corniculatus L. LOCO Fountain Miner's-Lettuce MOFO Montia fontana L. Montia linearis (Doug!.) Greene MOLI Blue Forget-Me-Not Myosotis discolor Pers. MYDI Yellow Parentucellia Parentucellia viscosa (L.) Caruel PAVI Kentucky Bluegrass Poa pratensis L. POPR Straight-beak Butter-cup Ranunculus orthorhynchus Hook. RAOR Sheep Sorrel Rumex acetosella L. RUAC Suckling Clover Trifolium dubium Sibth. TRDU Clover Trifolium Trifolium spp. Corn Speedwell Veronica arvensis L. YEAR Common Vetch VISA Vicia sativa L. Bromus commutatus Schrad. Bromus mollis Schrad. Carex densa L.H. Baile L.H. Baile 3.4 3.3 44 E 20 B 2 1 C 5 15 6 06 Av:. 5 15 6 06 Av:. 5 15 6 06 Av:. 5 15 6 06 1 Hai 10 7 40 3 25.0 5.0 45 15 30 20 20 30 25.0 60 50 5 5 5.0 5 5 55.0 5.0 1 1 1.0 5 5 5.0 12.5 1 39 16 1 1 1 1.0 2 8 5.0 1 1 1 21 9 14 6 17.5 7 7.5 3 21 9 1 1 1.0 1 1 10 10.0 18 30 1 1 2 1 2.0 1.0 3 1 2.0 2 1 1.5 1 1 1.0 1 1 5 15 2 1 0.3 0.4 0.2 1.0 35 42.0 11 20 15.5 28.0 15 5 2 8 6.5 11.9 1 18.0 1.0 1 1.5 1 1 1.0 0.9' 0.4 10 10 10.0 9.8 14.0 49 6.0 21 1.0 1 24.0 I 2 0.4 4.5 1.0 1.5 1.0 51.0 21.5 36.0 2.4 0.3 0.2 5.0 25.0 2 63 27 10 35.0 1.0 1 1 25 1.0 1 1 1.0 15 10 1 1 12.5 1.0 1.4 2.0 10.0 1.5 2.5 1 1 1.0 4 2 3.0) 1.4 0.4 Vegetation Characterization of Site 4 Plot Number 4.1 4.2 4.4 4.3 A 3/2 C 5/3 D Quadrat 0/1 Date 5)15 6/06 Avg. 5/15 6/06 Avg. 5/15 6/06 SPECIES AGST AGTE ALPR AREL BRCO BRHY BRCO BRMO CADE CALE CAOL CATU CAUN CEVI CIVU DACA ELPA EPGL SCIENTIFIC NAME Agrostis stolonifera L. Agrostis tenuis Sibth. Alopecurus pratensis L Arrhenatherum elatus (L.) J. & K. Presl Brodiaea coronaria (Salisb.) Engl. Brodiaea hyacinthina (Lindl.) Baker Avg. Mean % 3/0 B 5/15 6/06 Avg. 10 5.5 10.9 35.0 30.5 areal cover COMMON NAME Creeping_Bentgrass Colonial Bentgrass Meadow Foxtail Tall Oatgrass Hairy Chess Soft Brome Dense Sedge Carex densa (L.H. Bailey) L.H. Bailey Hare's-foot Sedge Carex leporina L. Few-seed Bitter-cress Cardamine ol gosperma Nutt. Foothill Sedge Carex tumulicola Mackenzie One-sided Sedge Carex unilateralis Mackenzie Chickweed Cerastium viscosum L. Bull Thistle Cirsium vulgare (Savi) Ten. Queen Anne's Lace Daucus carota L. Eleocharis palustris (L.) Roem. & J.A. Scht Common Spikerush Epilobium glandulosum Lehm. Festuca dertonensis (All.) (F. bromoides) FEDE Meadow Fescue Festuca pratensis Buds. FEPR Red Fescue Festuca rubra L. FERU Tall Fescue FEAR Festuca arundinacea Schreb. Catchweed Bedstraw Galium aparine L. GAAP Geranium Geranium dissectum L. GEDI Velvet Grass HOLA Holcus lanatus L. Soft Rush JUEF Juncus effusus L. Slender Rush Juncus tenuis Willd. JUTE Birds-foot Trefoil Lotus corniculatus L. LOCO Fountain Miner's-Lettui Montia fontana L. MOFO Montia linearis (Dougl.) Greene MOLI Blue Forget-Me-Not MYDI Myosotis discolor Pers. Yellow Parentucellia Parentucellia viscosa (L.) Caruel PAVI Kentucky Bluegrass Poa pratensis L. POPR Straight-beak Butter-cu RAOR Ranunculus orthorhynchus Hook. Sheep Sorrel Rumex acetosella L. RUAC Suckling_ Clover Trifolium dubium Sibth. TRDU Clover Trifolium Trifolium spp. Corn Speedwell Veronica arvensis L. VEAR Common Vetch Vicia saliva L. VISA Bromus commutatus Schrad. Bromus mollis Schrad. Avg,, 4.5 5/4 E 5/15 6/06 5 30 17.5 10 20 15.0 18 15 16.5 40 25 32.5 50 15 32.5 40 25 32.5 40 15 17.5 25 18 21.5 20 20 20.0 10 8 9.0 3 3 3.0 10 20 10 10 10.0 15.0 7 5 7 5 7.0 5.0 3 3 3.0 18 20 19.0 3 3 3.0 1 1 1.0 12 3 12 3 12.0 3.0 5 5 4 5.0 4.0 2 2 2.0 4 1 1 1.0 5 10 7.5 15 10 10 5 12.5 5 15 10 15 75 80 60 80 3 3 7.5 77.5 3.0 20 3 3 3.0 2 2 2.0 15.0 15 15 15.0 70.0 50 75 62.5 1 30 15 20 17.5 13.7 5 5 5 5 5.0 5.0 4.4 5.0 10 5 7.5 7.1 0.2 5 5 5.0 1 1 1.0 4.8 2.2 7.5 3.0 8.5 1.5 65 80 3 2 3 2 5 5 72.5 3.0 2.0 5.0 68 85 76.5 2 3 3 3.0 3 3 3.0 15 2 15 2.0 71.8 0.6 0.8 15.0 5.8 1 312 Appendix E Mineralogy Laboratory Procedures 313 MINERALOGICAL ANALYSIS A. Procedure for bulk random powder mounts 1. Preparation of the sample. A small soil sample was ground into powder in a mortal and pestle. 2. Slide preparation. The powder was gently tampered into a bulk slide holder and pressed to create a flat surface. B. Procedure for film slide mounts 1. Preparation of the samples. The air-dried samples were gently crushed with a rolling pin and a mortal and pestle. Crushed material was placed in 1-liter beakers. No pretreatments were done to remove organic matter or Fe-Al. 2. Dispersion of the samples. Samples were dispersed in 500-m1 distilled water with 5 ml of NaHMP (sodium hexametaphosphate) and shaken overnight. 3. Separation of the fractions. The samples were removed from the shaker and allowed to settle for 5 minutes to remove the sand and coarse silt. Subsamples of the decanted suspended materials were used for the <15 gm fraction. The main samples of the suspended materials were centrifuged at 650 rpm for 6 minutes and the decanted supernatant used for the < 2 gm fraction. The <15 f1111 was concentrated by squirting 5 ml of 1N MgC12 into the suspended materials, centrifuged at 5,000 rpm for 5 minutes, and pouring off the clear liquid. 4. Sample treatments. Both the < 2 fiM and < 15 gm fractions were Mg+2- saturated by washing three times with 20-30 ml of 1N MgC12 followed by three washings with distilled water. 5. Slide preparation. Oriented film slides were prepared by taking a small amount of sediment from the centrifuge tube with a microspatula and smearing it on a glass slide until a thin smooth surface was obtained for both the <2 fiM fraction and <15 p.m fraction. 6. Further sample treatments. After the slides were made from the <2 p.m Mg+2-saturated samples, the remaining < 2 gm separates were then K +saturated by washing three times with 20-30 ml of 1N KC1 followed by three washings with distilled water. Slides were prepared for analysis the same as in Step A.5 above. 7. Slide treatments. The Mg+2 saturated slides were prepared for XRD analysis using three treatments. The Mg+2 54% relative humidity slides were prepared by placing the Mg+2 saturated slides in a hydrator for 1224 hours. Once the XRD was run, the MgE2-glycol slides were made by lying the Mg+2-saturated slides in a ethylene glycol hydrator, heating 2-3 hours in a 650C oven, and letting them equilibrate for 12-24 hours. 314 Mineralogical Analysis, Continued Following the XRD on glycolated slides, the slides were set aside to allow the glycol to evaporate. Then the Mg+2-glycerol slides were made by lying the slides in a glycerol hydrator, heating 3 hours in a 1100C oven, and allowing them to equilibrate for 24 hours. The K +- saturated slides were prepared with two treatments. K+ 54% relative humidity slides were run after they were equilibrated for 12-24 hours. Once the XRD was run, the slides were placed in an oven at 1100C for 2 hours and analyzed immediately while hot.