41st Lunar and Planetary Science Conference (2010) 2275.pdf ORBITAL SPECTRAL MAPPING OF SURFACE COMPOSITIONS IN THE ANTARCTIC DRY VALLEYS: REGIONAL DISTRIBUTIONS OF SECONDARY MINERAL-PHASES AS CLIMATE INDICATORS AND IMPLICATIONS FOR MARS. M. B. Wyatt1, J. W. Head1, D. R. Marchant2, R. P. Harvey3, P. R. Christensen4, M. R. Salvatore1, and U. N. Horodyskyj1, 1Dept. of Geological Sciences, Brown University, Providence, RI 02912, 2Dept. of Earth Sciences, Boston University, Boston, MA 02215 3Dept. of Geological Sciences, Case Western Reserve University, Cleveland, OH 44106, 4School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85287. Introduction: Physical weathering dominates over chemical weathering in the current environment of the Antarctic Dry Valleys (ADV) due to extremes of very low moisture availability and very low temperatures. Although chemical weathering is limited, the effects of aqueous alteration at the surface-atmosphere interface are evident in the production of a variety of secondary mineral-phases. Phyllosilicates [1, 2], carbonates [3], sulfate salts [4], amorphous silica [4], zeolites [5] and iron staining [6] are all found on stable, old surface materials. Characterizing compositions in the top hundred microns of ADV rocks and soils is thus fundamentally important towards understanding the alteration effects from past and present climate regimes. In the current martian environment, physical weathering also dominates over chemical weathering and a diversity of secondary mineral-phases similar to those found in the ADV have been identified using data from near infrared (NIR) and thermal infrared (TIR) orbiting spectrometers (OMEGA-CRISM and TESTHEMIS) [e.g. 7-10]. The aqueously derived mineralphases on Mars are thought to reflect an ancient, warmer and wetter environment compared to current martian climate conditions [e.g. 11]. A major outstanding question that remains, however, is how warm and how wet ancient Mars must have been for the observed diversity of secondary alteration mineral-phases to form. The ADV are an ideal natural laboratory for such an investigation. We are currently addressing this key question through a multidisciplinary investigation that combines ADV field work during the 2009-2010 summer season with NIR and TIR laboratory spectroscopy and orbital remote sensing. In this abstract, we provide context for our ongoing research, present preliminary field work results, and outline future studies that will begin upon returning from Antarctica. ADV Climate Background: The ADV are generally described as a hyper-arid, cold-polar desert [12]. New climate and geomorphic data show that the region can be subdivided into three narrow zones distinguished on the basis of varying elevation, temperature, and precipitation [13]. The microclimate zones include: 1) a seasonally dynamic coastal thaw zone (CTZ), 2) a transitional inland mixed zone (IMZ), and 3) a stable upland frozen zone (SUZ). Within micro- climate zones, subtle variations in temperature and soil-moisture are sufficient to produce variations in surface topography. Changes in relative humidity and soil-moisture content, both of which are strongly influenced by atmospheric temperature and wind speed/direction [14], regulate salt weathering, frost action, and soil development [15]. These processes in turn control rates of downslope movement, fan development, gullying, polygon morphology/evolution, and rock weathering. Each microclimate zone in the ADV thus features a unique assemblage of landforms [13]. ADV Compositional Investigations: Several previous studies have also examined secondary mineral‐phases in the ADV at local‐scales and associated compositional variations with changes in temperature, water chemistry, pH, water/rock ratio, and dissolution rates of primary minerals [e.g. 15 and references therein]. Correlations between secondary mineral‐phases and climate variables over regional‐scales, however, remain poorly constrained. This gap in scale and knowledge is largely due to the difficulty in accurately characterizing fine‐grained, poorly‐crystalline secondary mineral‐phases on exposed surfaces during field mapping. Nevertheless, it is important to understand the distribution of secondary mineral‐phases across the ADV because regional‐scale trends in surface compositions provide the best insight into regional‐scale changes in climate conditions. The major focus of our ADV work is to thus quantitatively evaluate the linkage between different regional microclimate environments and surface compositions. This is being pursued in three integrated studies: (1) Establishment of key NIR and TIR spectral indices for “ground-truth” identification of ADV surface compositions. (2) Mapping distributions of primary lithologies and secondary mineral-phases over the entire ADV region using multispectral Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) TIR data and hyperspectral Hyperion NIR data. (3) Determining if regional distributions of secondary mineral‐phases are linked to current climate variables as measured by Long Term Ecological Research Automatic Weather Network (LAWN) stations or instead provide insight to past climate conditions. (1) Ground Truth Field Spectroscopy. In a companion LPSC abstract by M. R. Salvatore, we present 41st Lunar and Planetary Science Conference (2010) Wright Upper Glacier N 2 km OL YM S PU GE RD GA AS N RA Mc Ke lve y NG RA Dais E Lake Vanda Wright Valley B 0.92 0.90 0.96 Emissivity Avg Scene Dolerite Emissivity 0.94 0.96 0.94 1 2 8.5 9.0 9.5 10.0 10.5 11.0 Wavelength (μm) A Avg Scene Granodiorite 0.92 0.96 Avg Scene Quartz/ Conglom 0.92 0.90 0.94 0.90 8.5 9.0 9.5 10.0 10.5 11.0 Wavelength (μm) Emissivity Emissivity 0.96 Va lley Bull Pas s Labyrinth 0.94 3 8.5 9.0 9.5 10.0 10.5 11.0 Wavelength (μm) Avg Scene Gneiss 0.92 0.90 4 8.5 9.0 9.5 10.0 10.5 11.0 Wavelength (μm) Figure 1: (A) ASTER VIS and atm. corrected TIR emissivity image showing compositional diversity of ADV lithologies. Dashed lines are IMZ 2009-2010 field location. (B) Average scene spectra taken from points 1-4 compared to lab measured rock spectra resampled to ASTER spectral resolution. Emissivity 0.97 0.96 Weathered Fresh 0.95 Β 0.94 0.93 0.96 Emissivity initial results of ongoing spectroscopic field measurements from the SUZ type locale of Beacon Valley. NIR spectra of the Ferrar Dolerite, which are compositionally analogous to basaltic martian meteorites [16], reveal variations in the type and extent of aqueous alteration minerals-phases (phyllosilicates) produced in one of the coldest (mean annual temperature of 22°C [13]), driest (mean annual relative humidity of 43% [13]), and thus Mars-like environments on Earth. These results illustrate the diversity of spectral features associated with a single lithology and will be used to constrain the diversity seen in orbital spectral datasets. (2) Orbital Mapping of Surface Compositions. ASTER and Hyperion data are analyzed to uniquely identify and map primary and secondary surface compositions at high-spatial resolutions (90 and 30 m/pixel respectively). Figures 1 and 2 show examples of ongoing spectroscopic mapping in the ADV and the effectiveness of using ASTER TIR data to map sediment pathways and mixing of surface materials in the IMZ. (3) Linking Climate and Compositions. Upcoming work will focus on measuring surface exposure ages to develop a spectral maturity index for different primary lithologies. The objective of this combined approach is to develop an understanding of how 2275.pdf 0.94 0.92 8.5 9.0 9.5 10.0 10.5 11.0 Wavelength (μm) Scene Ferrar Dolerite 0.90 0.88 C 8.5 9.0 9.5 10.0 10.5 11.0 Wavelength (μm) Α Figure 2: (A) High-resolution ASTER VIS-TIR map of Upper Wright Valley Dais. (B) Lab spectra of fresh and weathered Ferrar dolerite with spectral variation due to secondary silica phases. (C) ASTER spectra of Ferrar dolerite (white boxes in A). Spectral variations likely caused by variable secondary coatings and/or mixing of lithologies. surface exposure ages, secondary compositions, and climate are linked and expressed in the upper 100 μm of a surface. We will integrate environmental LAWN data to determine if surface compositions reflect current climate variables or instead provide insight into past climate conditions and alteration processes. Implications for Mars: The ADV microclimate zones serve as ideal locations for developing an understanding of the link between surface compositions and climate variables in a Mars-like, hyper-arid, cold-polar desert. NIR and TIR field and orbital data of the ADV are thus valuable for comparison to NIR and TIR data from OMEGA-CRISM and TES-THEMIS. Constraining the diversity of secondary alteration mineralphases in the ADV will directly influence interpretations of martian surface compositions and the search for evidence of climate variations over geologic time. 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