NORWEGIAN JOURNAL OF GEOLOGY Geology of the Hortavær Igneous Complex 187 Geology of a magma transfer zone: the Hortavær Igneous Complex, north-central Norway Calvin G. Barnes, Tore Prestvik, Melanie A. W. Barnes, Elizabeth Y. Anthony & Charlotte M. Allen Barnes, C.G., Prestvik, T., Barnes, M.A.W., Anthony, E.Y. & Allen, C.M.: Geology of a magma transfer zone: the Hortavær Igneous Complex, northcentral Norway. Norwegian Journal of Geology, Vol. 83, pp. 187-208. Trondheim 2003. ISSN 029-196X. The Hortavær intrusive complex consists of a wide range of plutonic rocks, from gabbro (calcic) to alkali feldspar syenite (alkalic). Emplacement at 456 ± 8 Ma (U-Pb, titanite) was primarily as a series of dikes that range from tens of cm to many meters in width. Magma mingling structures are ubiquitous and magma mixing occurred locally. Therefore, the intrusive complex can be considered to be a zone of magma transfer and storage rather than a single pool of magma. The complex is characterized by CaO-rich rock compositions and by the presence of minerals typical of assimilation of carbonate-rich metasedimentary rocks, such as calcite, titanite, scapolite, nepheline, Ca-garnet, and idocrase. These features have been interpreted as the result of intense assimilation of host calc-silicate rocks. However, major and trace element compositions show inflections in the magmatic trend, which argues for crystal-liquid separation processes. Furthermore, some syenites are quartz bearing, which suggests a quartzofeldspathic component in the contaminant. When combined, these observations suggest that the Hortavær magmas evolved by assimilation-fractional crystallization of parental gabbroic magmas to evolved syenitic ones. Fractionation was initially dominated by separation of clinopyroxene, which was stabilized at the expense of olivine because of assimilation of carbonate components of the host rocks. The excessive fractionation of clinopyroxene forced melt compositions to alkali-rich, silica-undersaturated compositions, rather than SiO2-rich ones expected with olivine fractionation. Such assimilation was possible because of the open-system behavior of the intrusive complex (magma transfer zone) such that CO2 was lost before it could stop assimilation reactions. Development of evolved quartz syenitic magmas required a shift to assimilation of the quartzofeldspathic component of the host rocks, which occurred because carbonates are insoluble in such evolved magmas. Calvin G. Barnes*, Department of Geosciences, Texas Tech University, Lubbock, TX 79409-1053, USA; Tore Prestvik, Department of Geology and Mineral Resources Engineering, Norwegian University of Science and Technology, N-7491 Trondheim, Norway; Melanie A. W. Barnes, Department of Geosciences, Texas Tech University, Lubbock, TX 79409-1053, USA; Elizabeth Y. Anthony, Department of Geological Sciences, University of Texas at El Paso, El Paso, TX 79902, USA; Charlotte M. Allen, Research School of Earth Sciences, The Australian National University, Canberra ACT 0200, Australia; * corresponding author, e-mail: Cal.Barnes@ttu.edu. Introduction The Hortavær intrusive complex is exposed on small islands and skerries northwest of the island of Leka (Fig. 1). Its intrusive relationships and generally nontectonized nature have been interpreted to indicate that it is of broadly Caledonian age. The intrusion has long been recognized for its unusual mineralogy and geochemistry: augite-rich rocks from Burøya and Vågøya were named "hortite" by Vogt (1916), a name subsequently abandoned by the IUGS. More detailed studies (Gustavson & Prestvik 1979) emphasized the complexity of the intrusive relationships and the mineralogy of the pluton. Both of these studies concluded that the calcium-rich igneous rocks in the complex were the result of assimilation of carbonate-rich metasedimentary rocks. Present studies have focused on obtaining a more complete geologic map, gaining a better understanding of intrusive relationships, and using geochemical and isotopic data to interpret the petrologic history of the complex. We found that the intrusion consists of gabbroic, dioritic, monzodioritic, monzonitic, syenitic and granitic magma types. In all cases except the granites and gabbro, each rock type shows mutually-intrusive contacts with the others, such that magma mingling is commonplace. We visited most of the islands and accessible skerries of the archipelago in order to document the intrusive relations, compositional diversity, and petrologic history of the intrusive rocks. In this contribution, the field relationships and overall chemical and mineralogical features of the pluton are presented. We conclude that the Hortavær igneous complex represents a zone of intense magma transfer, as well as a location in which batches of magma were stored and fractionated. In this sense, it is distinct from the traditional view of a magma chamber formed by one or a few pulses of magma. This 188 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. Fig. 1. Geologic map of Hortavær. The Hortavær igneous complex is outlined by the dashed contact. The granitic gneiss that underlies Kvingra is interpreted as a separate intrusion, not part of the Hortavær igneous complex (see text). NORWEGIAN JOURNAL OF GEOLOGY Geology of the Hortavær Igneous Complex 189 Fig. 2. a. Diatexitic host-rock migmatite from Måsøya with blocks of migmatite enclosed in granitic leucosome. b. Folded, banded calc-silicate screen from eastern Skarvflesa (southern part of central zone). Width of banded zone is approximately 5 meters. c. Garnet-rich banded melasyenite from Lågøyskjæret (northern part of western zone). d. Banded melasyenite from eastern Skarvflesa with residual clots of incompletelyreacted calc-silicate rock (adjacent to flowers on the left). conclusion has interesting implications for the magmatic evolution of the complex, particularly its ability to assimilate calcareous rocks. Field setting Host rocks of the intrusion are migmatitic gneiss, quartzofeldspathic gneiss, and quartzite, which crop out in the southwest and northwest, and marble, which crops out northeast of the complex (Fig. 1). The quartzites are white, fine- to medium-grained and have interlayers of medium-grained pelitic schist and gneiss. The migmatites vary from layered, relatively quartzrich types to diatexitic types, herein referred to as "anatectic granite" (Fig. 1). This latter type typically forms pods or intrusive masses that disrupt layered migmatite (Fig. 2a) and on Fuholmen folds in layered migmatite are surrounded by granitic matrix. Similar diatexitic rocks underlie much of the Vega massif (~40 km NNE; Nordgulen, 1993); anatexis has been dated at ~477 to 469 Ma (Yoshinobu et al. 2002). Metamorphic assemblages in semipelitic rocks are biotite + muscovite(?) + sillimanite + feldspars ± cordierite ± garnet. Such assemblages are indicative of moderate-pressure migmatization due to muscovite-dehydration melting, and possible incipient biotite-dehydration melting (e.g., Spear et al. 1999). Quartzitic and migmatitic units are intruded by dioritic and tonalitic dikes, and locally by composite dioritetonalite dikes. On the basis of geochemical data presented below, these dikes are thought to be distinct from diorites in the Hortavær complex. The migmatitic rocks are locally in sharp contact with the dikes, especially where the dikes were intruded parallel to foliation in the migmatite. Elsewhere, the dikes are intruded by leucosome material and are broken into boudins or schollen in the migmatite. 190 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. Fig. 3. Photos from the central zone. a. Melasyenitic clots on diorite on Vågøya. b. Garnet-bearing melasyenitic clots with dark, amphibole-rich reaction rinds in diorite on Vågøya. c. Dioritic pillows in coarse-grained syenite on Vågøya. d. Synplutonic dioritic dikes in syenite on Storfornøyta. Metasedimentary screens and/or xenoliths throughout the complex encompass the same lithologies as in the host rocks. However, in spite of the relative abundance of anatectic granite in the northwestern host rocks, it was rarely observed, for example west of Kvåholmen (613930, 7233420), where sheared dike-like bodies of garnet two-mica granite are present in a syenitic host. Screens and xenoliths of calcitic and dolomitic marble are present throughout the intrusion and calcareous, stretched-pebble conglomerate crops out on Lågøyskjæret. In addition to obvious metasedimentary screens, the complex also contains zones of rock banded on the centimeter scale in a manner reminiscent of schlieren banding. Banded zones range from a few square meters in outcrop to several hundred square meters (e.g., northern Lågøyskjæret and western Kvåholmen), and some are folded (e.g., eastern Skarvflesa; Fig. 2b). The origin of such rocks is apparent on eastern Skarvflesa. In this location, layered calc-silicate screens were intruded by dioritic magma, which reacted with them (in the magmatic state) to form melanocratic syenite and monzonite. Where this process went to completion, the resultant rocks contain clinopyroxene ± amphibole + poikilitic to megacrystic garnet (Fig. 2c) + calcite ± scapolite ± wollastonite. Locally, the banded melasyenite zones enclose less-reacted blocks of layered, calcite-rich calcsilicate rocks (Fig. 2d). Where these relationships are observed, the banding is parallel to layering in the calcsilicates, a relationship that provides important evidence of the assimilative origin of the banded melasyenites/melamonzonites. Similar assemblages and relationships are present where melasyenitic zones are enclosed in syenitic host rocks. The granitic and syenitic rocks that underlie Kvingra were mapped by Gustavson & Prestvik (1979) as part of the intrusive complex. However, this is not clear from field relations or geochemical data. No masses of granite as large as Kvingra crop out within the rest of the intrusive complex and Kvingra granites are compositionally distinct from granitic dikes that cut the rest of the complex (see below). Therefore, we suggest that Kvingra be treated as a separate intrusive body. Intrusive relationships within the Hortavær complex At any given outcrop, it is possible to determine the cross-cutting sequence. However, it proved difficult to export such sequences from one island to another, let NORWEGIAN JOURNAL OF GEOLOGY Geology of the Hortavær Igneous Complex 191 western syenitic part, the contact between these two zones, and the broad, dike-like bodies of monzonite in the eastern and west-central parts of the intrusion. Central dioritic zone. - On Burøya and Vågøya, the oldest intrusive rocks are (1) coarse-grained, massive to foliated diorite and monzodiorite and (2) heterogeneous variably hybridized diorite/monzodiorite, with probable end members of diorite and coarse-grained syenite. The heterogeneous diorites typically consist of cm- to dm-scale ovoid syenitic pods with indistinct margins in a melanocratic matrix (Fig. 3a). Dark, mmto cm-wide mafic reaction (?) zones commonly surround these syenitic pods (Figs. 3a, b). In some places, the diorite lacks syenitic pods but contains abundant stringers of mafic minerals similar to the reaction zones. Titanite is typically more abundant in heterogeneous diorite than in massive diorite, and garnet that ranges from interstitial to six cm in diameter is sparsely present; it typically occurs in the ovoid pods (Fig. 3b). Many of these early dioritic rocks are pyroxene- ± amphibole-rich and contain magmatic calcite and scapolite; they are the "hortite" of Vogt (1916). Locally, the dioritic dikes are appinitic, with equant amphibole phenocrysts and interstitial feldspars. (Note that the term "amphibole" is used for convenience; the range of calcic amphibole in the complex is discussed below). Younger rocks in the central zone are predominantly dikes. These encompass coarse- to medium-grained syenite, composite and pillowed (Fig. 3c) dikes with fine-grained diorite in syenitic host, and synplutonic dioritic dikes in both dioritic and syenitic (Fig. 3d) hosts. It is noteworthy that diorite in the composite dikes contains enclaves of more mafic diorite, and that some composite dikes contain hybrid monzonite. Fig. 4. Photos from the western zone. a. Monzonitic synplutonic dikes in syenite from Grøningen. b. A composite dike containing a swarm of dioritic enclaves in a syenitic host cuts medium-grained monzonite, Kvåholmen. c. Garnet rosettes in a mafic syenitic host on Ørnholmen. Width of field of view is approximately 25 cm. alone across the entire complex. The common exception to this is that granitic dikes (fine-grained to pegmatitic) were the last to be emplaced. Even this generalization is uncertain, because on southern Langdraget granitic dikes contain dioritic enclaves, which suggests the presence of mafic magmas throughout the history of the intrusive complex. Therefore, we present intrusive relations (prior to the granitic dikes) for four distinct areas in the complex: the central dioritic part, the Foliation is defined by alignment of pyroxene, plagioclase, and, where present, medium- to fine-grained, angular to rounded mafic microgranular dioritic enclaves. Where present, compositional banding is parallel to foliation. In the heterogeneous diorite/monzodiorite, felsic zones may be randomly oriented or flattened to form a foliation with approximately the same orientation as that in the foliated diorite. An island at the northwestern end of Burøya (Fig. 1) is underlain by coarse-grained biotite amphibole olivine augite gabbro that contains veins and pods of pegmatoidal olivine gabbro with glassy amphibole and feldspar. No contacts between this gabbro and adjacent dioritic rocks are exposed. However, in view of the location of the olivine gabbro in the central part of the pluton, we interpret it to be part of the Hortavær intrusive complex. Western syenite zone. - In this region, the oldest intrusive rocks are typically coarse-grained syenite. The lar- 192 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. Fig. 5. Photos from the sheeted zone. a. Alternating intrusive sheets of diorite and syenite on Kleppan, view to the north. b. Thin sheets of diorite intruding syenite northeast of Andersøya, view to the northeast. c. Banded and mingled diorite, monzonite, and syenite, northeastern Ørnholmen, view to the south. d. Dioritic dike cutting a composite diorite/syenite dike on Kleppan. gest exposures of banded screens are present in this zone (e.g., Kvåholmen, Lågøyskjæret, Sylskjæret). On the basis of mineral assemblage, they range from medium- to coarse-grained garnet melasyenite (Fig. 2c) to nepheline- and scapolite-bearing amphibole pyroxene diorite. The largest of the melasyenite units are shown in Figure 1. It is rare to find an outcrop of syenite in this zone that does not contain fine- to medium-grained enclaves and/or synplutonic dikes (Figs. 4a). The enclaves and dikes vary in composition from syenitic through monzonitic to dioritic. In some cases, the enclaves and synplutonic dikes also contain enclaves of more melanocratic rock (Fig. 4b). Some enclaves are blocky and appear to result from brittle disruption of synplutonic dikes (e.g., Barnes et al. 1986), others are fusiform to ovoid (10 to 30 cm long) and still others have bulbous pillow-like shapes. For many examples of such mingling relationships, see Didier & Barbarin (1991). Enclave abundances can reach as much as 70%, for example in outcrops on the Båsen island group (Fig. 1). The sheeted zone: the contact between central and western zones. - The transition from central diorite zone to western syenite zone is at least 500 m wide (Fig. 1). It is characterized by coarse-grained syenitic host rock with screens of diorite; all intruded by sub-parallel swarms of fine- to medium-grained dioritic dikes (Fig. 5a, b) and composite dikes of fine- to medium-grained diorite and syenite/monzonite. The composite dikes range from one meter to tens of meters in width and generally consist of fine- to medium-grained dioritic enclaves in coarse-grained syenite. They also vary in degree of disruption from uniform, straight-walled dikes (Fig. 5a) to broken and hybridized (Fig. 5c). Mafic enclaves range in size from one cm to many meters and can be angular, tabular, ovoid, or bulbous. Some composite dikes display hybrid zones whose color index is intermediate between the enclaves and the host syenite. These hybrid zones commonly contain mafic enclaves whose color index is somewhat lower than mafic enclaves enclosed in syenite. Two additional points are of note. First, composite dikes are not necessarily the youngest dikes in the sheeted zone. Figure 5d shows a massive dioritic dike cutting a composite dike. Second, the sheeted zone is not sharply bounded, particularly on the western side. Instead, it is gradational, with a westward decrease in the number of dioritic dikes and an increase in the amount of disruption of these dikes. NORWEGIAN JOURNAL OF GEOLOGY Geology of the Hortavær Igneous Complex 193 Fig. 6. Structural data. a. Poles to planes of magmatic foliation, orientation of host-rock screens, and sheet-like intrusions in the sheeted zone. Lower hemisphere equal-area plot. b. Rose diagram of dike orientations. See text for discussion. The strike of the sheeted zone changes along its length (Fig. 1) from about 010 and moderate westward dip in the Kleppan group to about 060 and moderate northwesterly dip further north (Fig. 6a). This change in orientation is also reflected in the attitudes of the dioritic and composite dikes elsewhere in the complex, as shown in a rose diagram of dike orientations (Fig. 6b). Maxima from 010 to 050 are reflective of dikes from the northern half of the complex, whereas the 155 maximum is reflective of the southern half. The E-W maximum represents orientations of late-stage syenitic, composite, and granitic dikes. This group is underrepresented because many late-stage dikes with this orientation were not measured. Dike-like monzonitic bodies. - Dike-like zones of monzonitic rock crop out in at least two parts of the complex. The largest of these is a 3 km-long, 500 m-wide body east of Vågøya. A similar body may underlie Småfornøyta (Fig. 1), but contact relations are not exposed. Finally, in the contact zone between the syenitic and dioritic zones (east of Ørnholmen; Fig. 1), a 100 mwide dike cuts dioritic host rocks. Typical cross-cutting relations in the monzonitic zones are well exposed on southern Langdraget (Fig. 1) where monzonite cuts the diorite, but "pods" or "pillows" of fine-grained diorite are present in adjacent coarse-grained monzonite and the grain size of the diorite coarsens away from the contact. As elsewhere, these mutu- ally intrusive contact relations are taken to indicate intrusion of the monzonitic unit while the diorite was still in a magmatic state. Late-stage dikes. - Late stage syenitic, granitic, and dioritic dikes are present throughout the intrusion. The syenitic dikes are generally coarse- or very coarse-grained, but white, fine-grained dikes are also present. The granitic dikes are commonly fine-grained and have accessory fluorite. The dioritic dikes are equigranular and fine-grained. Although the late stage dikes display a range of orientations, they most commonly have approximately E-W strike, whereas dike swarms in the contact zone between western and central parts of the intrusion strike N-S (in the south) or ENE (in the north; Fig. 6). Orientation of magmatic foliation and metasedimentary screens. Figure 6 also shows the orientation of magmatic foliation. Foliation in the east-central and southwestern parts of the intrusion is oriented NNE, whereas foliation in the western and northwestern parts of the intrusion is typically oriented ENE. Qualitative observations indicate that foliation in metasedimentary screens is generally parallel to magmatic foliation. In many cases the long dimensions of these screens share this orientation. 194 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. Lithology and Petrography Detailed petrographic descriptions of many of the rocks types were presented by Vogt (1916) and Gustavson & Prestvik (1979). Rather than repeat their work, we provide descriptions of samples that contain as-yet undescribed assemblages and summaries of rock types described previously. Mineral compositions are summarized in Tables 2, and 3. Olivine gabbro Fig. 7. Concordia plot of results of laser-ablation ICP-MS dating of titanite, plotted using the program ISOPLOT of Ludwig (2002). The upper intercept represents common Pb composition, the lower intercept the crystallization age of the titanite. Note intercept ages are inherently less precise than those derived from concordant minerals which is why zircon (when available) is the mineral of choice for dating intrusive ages. These rocks crop out on one island at the north end of Burøya (Fig. 1). They are medium- to coarse-grained amphibole olivine gabbro with subophitic texture. Olivine (Fo66 to Fo55) is rounded and commonly enclosed by augite, amphibole, or plagioclase. The augite is poikilitic, pale pink, and color zoned, with Mg# (=Mg/(Mg+Fetot) from 0.83 to 0.73. Brown to olive pargasitic amphibole is poikilitic, reaches at least 1 cm in diameter, and has Mg# of ~0.65. Plagioclase shows normal zoning from An77 to An45. Accessory minerals are pyrrhotite, pyrite, calcite, and biotite. Geochronology Diorite and monzodiorite Gustavson & Prestvik (1979) reported an Rb–Sr isochron age for the Hortavær complex of 471 ± 5 Ma. Further attempts at isochron dating using either the Rb–Sr or the Sm–Nd isotope data (data presented in Barnes et al., in review), failed to obtain consistent results. This is largely a function of the isotopic variability in the complex (op. cit.). Titanite from sample 91.32H, a biotite amphibole alkali feldspar syenite from Flatskjæret was dated by laser ablation ICP-MS at Australia National University. Nineteen 54µ-diameter spots were used to construct a substitute concordia plot (Figure 7). The data (Table 1) define a chord with an upper intercept approximating the composition of common Pb (207Pb/206Pb=0.691±0.07) and a lower intercept corresponding to an age of 455.7 ± 8.4 Ma, with an MSWD of 1.05. The goodness of fit of the chord suggests that what was measured is a mixture of a single common Pb component, and radiogenic Pb that has grown since crystallization of the syenite. These rocks show a wide range of grain size, texture, and degree of homogeneity. Detailed descriptions are presented in Vogt (1916) and Gustavson & Prestvik (1979). They range from fine- to coarse-grained and their mafic assemblage varies from pyroxene ± amphibole, to biotite + pyroxene + amphibole, to biotite + amphibole. Clinopyroxene is either pale violet or pale green; its Mg# varies within the group from 0.65 to 0.25. In some samples clinopyroxene occurs as granular aggregates surrounded by amphibole. The Al2O3 content of clinopyroxene is rather high compared to typical medium- to low-pressure pyroxene (Al reaches 0.4 atoms per formula unit). Amphibole habit and color vary widely; it is chemically classified as ferropargasite. It occurs as 1 to 3 mm diameter ragged prisms with reddish brown to olive pleochroism, as equant, deep olive to deep green, subhedral prisms, and as yellowgreen to olive, subhedral to anhedral grains. Amphibole Mg# varies from 0.47 to 0.24. Biotite occurs as sparse flakes. Zoned plagioclase has cores of An53-24 to rims of An28-20. K-feldspar (microcline) is poikilitic to interstitial. Accessory minerals are titanite, apatite, calcite, minor magnetite and pyrite, and, in some samples, scapolite. Late-stage epidote locally replaces plagioclase. This result is, within analytical uncertainty, similar to U-Pb (zircon) ages of mafic plutons of the Velfjord massif, e.g., 448 ± 2 Ma for the Akset-Drevli pluton and 447 ±2 for the Hillstadfjellet pluton (Yoshinobu et al, 2002) and the Andalshatten pluton (447 ± 7 Ma; Nordgulen et al., 1993). All of these plutons contain volumetrically significant mafic components. The possibility exists, therefore, that the Hortavær complex is a slightly older part of this pulse of mafic magmatism in the Bindal Batholith. Appinitic diorites grade into amphibole pegmatoids. The typical appinitic diorite has mafic phases in subequal proportions: clinopyroxene forms pale green to pale olive granular to prismatic crystals that reach 1mm in length and amphibole (ferropargasite with Mg# 0.33 to 0.24) forms equant, subhedral prisms 1 to 2 mm Geology of the Hortavær Igneous Complex 195 NORWEGIAN JOURNAL OF GEOLOGY Table 1. U-Pb-Th isotope composition of Titanite from 91.32H Anal No notes 1 excl. 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 610 238U/206Pb 11.227 10.473 11.263 11.742 12.221 12.068 12.207 10.974 12.108 11.892 11.690 12.473 11.067 12.119 12.539 11.913 10.978 10.887 11.213 11.197 4.0005 +1σ 207Pb/206Pb 0.161 0.138 0.175 0.152 0.159 0.150 0.157 0.144 0.154 0.154 0.149 0.151 0.140 0.148 0.155 0.148 0.147 0.136 0.140 0.144 0.17640 0.20212 0.16812 0.14440 0.12270 0.13471 0.14781 0.19466 0.12660 0.14873 0.16647 0.11429 0.18807 0.12146 0.11765 0.14211 0.19114 0.19340 0.17484 0.17207 0.909779 Pbtot +1σ U (ppm) atomic (ppm) 0.00286 0.00312 0.00339 0.00209 0.00185 0.00199 0.00196 0.00324 0.00185 0.00188 0.00259 0.00195 0.00306 0.00175 0.00191 0.00217 0.00297 0.00258 0.00250 0.00286 11.22 6.41 8.19 10.00 8.91 7.35 6.61 7.37 10.49 8.02 6.74 9.85 8.70 16.00 10.68 9.18 8.59 14.84 13.29 7.92 423.0 44.5 25.7 38.5 46.1 44.6 35.3 33.5 32.0 48.5 40.7 30.6 53.0 36.3 69.2 56.7 43.4 35.5 54.8 51.4 34.6 471.7 Th/U 6.635 5.608 4.696 5.561 5.247 5.486 4.795 5.186 5.917 4.680 5.470 4.765 5.752 6.750 4.918 5.408 5.802 7.205 6.916 5.558 1.01874 207Pb/235U +1σ 2.166 2.661 2.058 1.696 1.384 1.539 1.669 2.446 1.442 1.724 1.963 1.263 2.343 1.382 1.294 1.645 2.401 2.449 2.150 2.119 31.356 0.046 0.053 0.043 0.032 0.027 0.029 0.030 0.051 0.027 0.031 0.039 0.026 0.047 0.026 0.026 0.032 0.048 0.044 0.040 0.044 208Pb/232Th 0.02710 0.02975 0.02911 0.02655 0.02559 0.02582 0.02693 0.02929 0.02559 0.02703 0.02735 0.02538 0.02844 0.02496 0.02521 0.02650 0.02844 0.02727 0.02708 0.02775 0.528333 +1σ 0.00034 0.00036 0.00037 0.00034 0.00031 0.00033 0.00033 0.00039 0.00031 0.00033 0.00035 0.00030 0.00032 0.00029 0.00030 0.00032 0.00036 0.00031 0.00029 0.00034 The ANU’s LA-ICPMS facility comprises a Lambda-Physik LPX120i excimer laser and Agilent 7500S quadrupo ICP. A 54 µ beam was used to ablate 20 spots in 18 grains for 60 seconds to a depth of about 25 µ: 20 s of background, 10s of laser-on stabilization time, and 30 seconds of laser-on "peak" time. A mass sweep took 0.382 s. Zr and P were measured to check for inclusions, and none was identified. In only one case did uncertainty in 206Pb/238U exceed twice that expected for counting statistics, and no. 1 was excluded from the intercept calculation. NIST 610 glass was used as the standard with Pb isotope composition determined by Woodhead and Hergt (2000). For the titanite, isotope counts were background subtracted, ratioed to another isotope, and then on a mass-sweep by mass-sweep (depth) basis, a fractionation factor determined from the average of 11 ablations of the 610 glass was applied to the corresponding mass sweep in the unknown. Uncertainties quoted here include uncertainty in the measured average of the standard (1% for 206Pb/238U and 0.5% for 207Pb/235U). Concentration data assume CaO=26wt%. Fish Canyon Tuff (USGS-FC3) titanite was used as a monitoring standard and twenty analyses yielded a lower intercept age of 27.8 Ma+2.2 Ma (MSWD=2.0). The fine details of emplacement age of the tuff are in debate but probably the best emplacement age is from U-Pb single crystal TIMS work on zircon which yielded an age of 28.48 + 0.06 Ma (Schmitz et al., 2003). across; it is deep olive to deep green. Plagioclase (An53 to An26) and perthitic K-feldspar are poikilitic, with inclusions of clinopyroxene ± amphibole. Some plagioclase was prismatic, primary crystals were originally ~5mm across; they now consist of ~1mm-diameter subgrains. Accessory phases are titanite (euhedral, to 1 mm long), elongate apatite, and minor magnetite and pyrite. In pegmatoidal varieties, elongate amphibole reaches 15 cm in length. Nepheline-bearing monzodiorite is medium- to finegrained and hypidiomorphic-granular. It is texturally similar to monzodiorite described above, with granular to poikilitic plagioclase, poikilitic K-feldspar, and as much as 10% nepheline, which forms cores of some plagioclase crystals and is also interstitial to poikilitic. Where plagioclase rims nepheline, amphibole and pyroxene are inclusions at the crystal boundaries. The nepheline typically has ratios of Na/(Na+K+Ca) of 0.82 to 0.76. Accessory minerals are scapolite, calcite, stubby to prismatic apatite, titanite, biotite, pyrrhotite, and pyrite, and in one sample, idocrase. Monzonite Monzonites in the Hortavær complex are medium- to fine-grained, have hypidiomorphic granular texture, and contain pyroxene, biotite, and amphibole. Clinopyroxene is pale green and partly replaced by pale brown to olive ferropargasite; biotite occurs as yellow-brown flakes. These samples have variable proportions of plagioclase and K-feldspar. Furthermore, some samples contain andesine (An36-33) and others oligoclase (An2520), and a single sample (93.45H) contains nepheline. Accessory phases are fine apatite, pyrite, and zircon (?). Late, fine-grained epidote replaces some plagioclase. 196 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. Table 2. Summary of plagioclase, scapolite, and nepheline compositions. rock mg# olivine gabbro 91.49H 0.73 91.51H 0.74 93.49H 0.67 diorite/monzodiorite 93.44H 0.33 93.46H 0.34 93.52H 0.49 93.56H 0.39 93.62H 0.39 93.63H 0.44 93.72H 0.40 monzonite/syenite 93.45H 0.078 93.57H 0.370 93.76H 0.156 93.02H 0.100 melasyenite/melamonzonite 91.06H 0.084 91.20H 0.180 93.06H n.a. plagioclase Ca/(Ca+Na) max min scapolite Ca/Ca+Na) max min nepheline Na/(Na+K+Ca) max min 76.6 76.2 76.8 53.0 64.1 45.0 ---------- ---------- ---------- ---------- 23.7 36.0 31.1 40.5 52.8 47.8 32.7 20.4 32.8 23.6 24.4 26.3 27.9 ---- 63.2 74.8 ------------61.5 52.4 72.4 ---------------- ------81.3 ---------79.6 ------76.0 ---------65.0 ---25.0 8.8 5.5 ---19.7 5.3 1.5 ------------- ------------- 81.5 ---------- 79.9 ---------- 28.0 29.3 36.7 21.8 17.1 27.8 ---------- ---------- ---------- ---------- Syenite The syenitic rocks are typically coarse-grained, but range from fine-grained to very coarse-grained. The felsic assemblage varies, from plagioclase (oligoclase) syenite to plagioclase-free alkali feldspar syenite, to alkali feldspar quartz syenite. In all samples, the original alkali feldspar has undergone intense exsolution and consequent recrystallization. A few elongate, relict crystals (to several millimeters long; now microcline) are preserved in a matrix of ragged grains that range from < 1 mm to 2-3 mm in diameter. Granular, patchy, and lamellar exsolution are ubiquitous; it is common to observe bead-like albite surrounding blocky microcline. As a result of this extensive recrystallization, the nature of the primary alkali feldspar cannot be determined petrographically. Clinopyroxene and amphibole are the principal mafic minerals and dark brown biotite is present in some samples. Stubby hedenbergitic clinopyroxene (Mg# from 0.21 to 0.05) is the most common mafic phase. It is typically green, with weak pleochroism, but varies from yellow green to green to dark green. In some syenites, clinopyroxene is rimmed and partly replaced by ferropargasitic amphibole (Mg# from 0.10 to 0.05), with typical pleochroism from bluegreen to dark green. Still other syenites lack clinopyroxene and contain ferropargasite and brown biotite. Accessory minerals are titanite, zircon, calcite, and apatite. Quartz is either absent or present in abundances > 5% (quartz syenite). Melasyenite and melamonzonite (banded zones) These rocks are remarkably heterogeneous at outcrop, hand sample, and thin section scales. Grain size is medium to very coarse. Orange, color-mottled garnet varies from equant (Fig. 2c), to interstitial, to rosettelike (Fig 4c). Garnet compositions (mole fractions) are in the range grossular (0.773-0.700), pyrope (<0.005), almandine (0.001-0.097), spessartine (<0.013), andradite (0.248-0.148). Clinopyroxene is yellow-to-green pleochroic (Mg# 0.40 to 0.05); some samples also contain large (to 3 mm in diameter) grains with olive cores (Mg# 0.44 to 0.40). Ferropargasitic amphibole (Mg# 0.25 to 0.10) ranges from nearly opaque deep green to pleochroic bluish-green to yellow. K-feldspar (microcline) is prismatic, with original crystals ≥ 3 mm long. Both granular and lamellar exsolution has occurred. In addition, K-feldspar commonly surrounds garnet, although many clinopyroxene-garnet contacts are in textural equilibrium. Where present, plagioclase ranges from An37 to An17 and is riddled with fine inclusions of epidote. Common accessory minerals are interstitial 0.020 0.055 ----0.014 0.007 0.027 0.050 0.019 0.009 --- 0.25-0.33 0.48-0.64 ----0.40-0.44 0.36-0.40 0.05-0.15 0.10-0.24 0.13-0.21 0.10-0.13 --- 0.019 0.011 --0.58-0.65 --0.061 0.011 0.019 0.37-0.41 0.44-0.51 0.57-0.77 --- 0.033 0.016 --- s.d. 0.73-0.83 0.78-0.83 n.d. range * clinopyroxene core compositions. **clinopyroxene rim compositions gabbro 91.49H 0.677 0.787 91.51H 0.712 0.801 93.49H 0.672 n.d. diorite 93.46H 0.339 0.391 93.62H 0.387 0.464 monzodiorite 93.56H 0.391 --93.63H 0.439 0.622 93.57H 0.370 0.532 nepheline diorite 93.52H 0.487 0.667 93.58H 0.316 --nepheline monzodiorite 93.44H 0.291 0.300 93.72H 0.404 0.515 monzonite 93.02H 0.100 --93.45H 0.078 0.115 melasyenite/melamonzonite 89.02H* 0.199 0.421 89.02H** 0.199 0.370 91.06H 0.066 0.070 91.20H 0.180 0.154 93.06H n.d. 0.177 93.78H 0.098 0.109 garnet-bearing biotite granite dike 93.84H 0.320 --- bulk rockclinopyroxene ave. Mg# Mg# Table 3. Representative compositions of mafic minerals. --- ------------- ----- ----- ----- ----- ----- 0.61 0.67 0.58 olivine ave. Mg# --- ------------- ----- ----- ----- ----- ----- 0.63-0.60 0.69-0.65 0.62-0.55 range --- ------------- --- ----- --- ----- ----- 0.15 0.01 0.027 s.d. --- --------0.105 0.060 0.089 0.092 0.243 0.386 0.424 0.305 0.395 0.419 0.355 0.255 0.290 0.651 n.d. n.d. amphibole ave. Mg# --- --------0.005 0.004 0.013 0.009 0.005 0.007 0.025 0.026 0.006 0.013 0.016 0.003 0.018 0.009 ----- s.d. 0.052 0.632 --0.713 0.787 0.772 0.718 ----- ----- ----- ------- ----- ------- 0.718 0.021 --0.079 0.045 0.075 0.064 ----- ----- ----- ------- ----- ------- 0.028 0.337 --0.199 0.161 0.142 0.209 ----- ----- ----- ------- ----- ------- grossular almandine andradite garnet (mole fractions) NORWEGIAN JOURNAL OF GEOLOGY Geology of the Hortavær Igneous Complex 197 198 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. Monzogranite is most common, but a few alkali-feldspar granite and one biotite trondhjemite were collected. Most of the granitic dikes are leucocratic, with biotite (Mg# 0.11 to 0.07) as the common mafic mineral. However, a few samples also contain blue-green amphibole and a few contain hedenbergitic clinopyroxene. Accessory minerals are apatite, Fe-Ti oxides, tourmaline, fluorite, calcite, pyrite, and rare titanite and muscovite. Granitic dikes in the host rocks northwest of the intrusive complex consist of two-mica trondhjemite, biotite tonalite, muscovite alkali-feldspar granite, and garnet two-mica granite. These dikes are typically hypidiomorphic granular and show little evidence of deformation. Biotite in the garnet-bearing sample has much higher Mg# (0.31) than biotite in granitic dikes within the intrusive complex. Garnet in this sample is almandine-rich, with average composition (mole fractions) of grossular, 0.052; pyrope, 0.107; almandine, 0.718; spessartine, 0.095; andradite, 0.028. The Kvingra granite ranges from sub-mylonitic to intensely mylonitized (Gustavson & Prestvik, 1979). Some samples preserve relict K-feldspar phenocrysts. Biotite was probably the varietal phase; it is replaced by chlorite. Accessory minerals are epidote, fluorite, Fe-Ti oxides, pyrite, calcite, and muscovite. Geochemistry Analytical methods Fig. 8. Geochemical classification according to Frost et al. (2001). The proposed magmatic trend is shown by the dashed gray line. Samples labeled with and ‘N’ contain nepheline. a. The FeO/(FeO+MgO) ratio is calculated using measured FeO contents, therefore not all samples are plotted. The proposed magmatic trend crosses the boundary between magnesian and ferroan suites. b. The proposed magmatic trend begins in the calcic field and crosses boundaries into the alkalic field. The compositions of granitic dikes in the Hortavær complex then cross the boundary from alkaline to alkali-calcic. Note the dissimilar compositions of granitic dikes from the Hortavær complex and anatectic granites from the western host rocks. calcite (as much as 6% of the rock), titanite, apatite, and epidote; some samples contain wollastonite, pyrrhotite (?) or pyrite, and zircon (?) as inclusions in Kfeldspar, and magnetite. Granitic rocks Granitic dikes in the intrusive complex are generally medium- to fine-grained and hypidiomorphic granular. Mineral analyses were made on a JEOL-JXA733 Superprobe at the University of Wyoming using natural and synthetic standards and ZAF corrections. Analytical conditions were 15kV accelerating voltage and 10 na beam current. Analytical spots were ~1µm diameter except for plagioclase, nepheline, and scapolite (10 µm). Major oxides and Rb, Sr, Zr, Y, Ba, V, Cu, and Zn were analyzed by XRF at the Institute for Geology and Mineral Resources Engineering at the Norwegian University of Science and Technology or by ICP-AES at Texas Tech University. The rare earth elements (REE), Cs, Ta, Th, Hf, and U were analyzed by INAA in three different labs, as noted in Table 4. Classification According to the classification scheme of Frost et al. (2001), the gabbroic and dioritic rocks range from calcic to alkaline and from magnesian to ferroan (Fig. 8), with monzonitic and syenitic rocks virtually entirely alkaline and ferroan. This transition involves enrichment in total Fe and the alkalis within the dioritic group of rocks to nearly 12% Fe (as FeO) and 8% total NORWEGIAN JOURNAL OF GEOLOGY Geology of the Hortavær Igneous Complex 199 Fig. 9. Major element and Sr variation. The shaded field represents the compositional range of clinopyroxene. Samples labeled with and ‘N’ contain nepheline. a. Na2O + K2O versus CaO. Dioritic dikes that intrude host rock migmatites and anatectic granites plot in a trend parallel to, but offset from the proposed magmatic trend of the Hortavær complex. b. CaO versus Mg/(Mg+Fet) showing locations of dioritic samples. The field outlined with a dashed line is the compositional range of dioritic and gabbroic rocks from the central zone. The field outlined with a solid line encompasses diorite compositions from the sheeted zone. c. CaO versus K2O showing the curvilinear magmatic trend and particularly the decrease in K2O among the most evolved syenites. d. Inset of Na2O + K2O versus CaO for syenitic and granitic compositions. Compositional fields for cumulate syenites and for quartz-bearing syenites are shown. e. CaO versus TiO2 showing curvilinear magmatic trend. f. Sr versus CaO showing the curvilinear magmatic trend. Sr-rich samples labeled with a ‘d’ are dikes. Fig. 10. Chondrite-normalized REE plots. a. Gabbroic and dioritic rocks that are part of the proposed magmatic trend. Values of Mg/(Mg+Fe) are listed after the sample number. b. Diorite and calciumrich diorite ("hortite"; shown with shaded symbols). Values of Mg/(Mg+Fe) listed after sample numbers. c. Monzonitic rocks (unfilled symbols) and melasyenite and melamonzonite (filled symbols). d. REE patterns for syenites with Sr > 500 ppm. e. REE patterns of syenites with Sr < 500 ppm. f. REE patterns of syenites interpreted to be alkali-feldspar cumulates. Note change in scale. g. REE patterns of granitic dikes that intrude the intrusive complex. h. REE patterns of granitic rocks from Kvingra and dikes of residue-poor, peraluminous, anatectic granite (diatexite) from the western host rocks. The shaded field shows that range of the latter samples except for probable feldspar cumulate, sample 91.24H. 200 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. NORWEGIAN JOURNAL OF GEOLOGY alkalis (Na2O + K2O). Most granitic dike compositions plot in the ferroan field and range from alkaline to alkali-calcic (Fig. 8). Compositional variation Figures 8 and 9 exemplify the wide compositional range of the complex. When granitic dikes are included, SiO2 contents range from 43% to 77%, CaO contents from 24% to 0.4%, and total alkalis from 13.8% to 0.8%. Figure 8 permits identification of a number of compositional groups; data from the intrusive complex, the granitic rocks from Kvingra, and granitic and dioritic dike samples from the western host rocks are plotted. In Figure 9a, a linear relationship can be defined among samples of olivine gabbro, diorite and monzodiorite, monzonite, and syenite. Melasyenitic samples plot to the right of this line, as do many samples from the dioritic zone. Granitic dikes in the intrusive complex and Kvingra granites plot to the left of the line; they generally have low CaO contents and total alkalis somewhat less than the syenites. In contrast, diatexitic granite samples from the western host rocks have much lower alkali contents. Although not apparent in this plot, a compositional gap exists between the dioritic and syenitic rocks. This gap is filled by data from eight monzonitic samples. However, as is apparent from Figure 1, monzonites constitute a small percentage of the complex and are thus overrepresented in the diagram. Dioritic dikes that intrude and co-mingle with migmatites in the western host rocks plot in a linear array that is parallel to, but offset from the trend of diorites from the intrusive complex. We interpret this latter relationship to indicate that the two sets of diorites are unrelated and therefore do not further consider this group of dioritic dikes. Figure 9b shows the range of Mg/(Mg+Fe) values compared to CaO. In particular, it shows the wide range of CaO contents among the dioritic and melasyenitic rocks. However, despite this range of CaO values, a group of diorite analyses plot in a sub-linear array that extends from olivine gabbro compositions to syenite compositions. We suggest that if a magmatic trend exists for the intrusive complex, this array is its closest approximation. Figure 9b also shows that most of the diorites that are enriched in CaO relative to the proposed magmatic trend were collected from the central zone of the intrusion, whereas most diorites from the sheeted zone plot along the magmatic trend. Mg/(Mg+Fe) values of the granitic dikes within the intrusive complex overlap with those of the syenites, but most are lower than Mg/(Mg+Fe) values of diatexitic granites from the host rocks. Although this overlap Geology of the Hortavær Igneous Complex 201 of Mg/(Mg+Fe) is interesting, it is noteworthy that the granitic dike compositions do not plot along the proposed magmatic trend as shown in Figures 9b and 9d. This suggests that a simple crystal–liquid separation process cannot relate the granitic dike magmas and the syenitic magmas. The range of Mg/(Mg+Fe) among the syenites is also essentially identical to that of the melasyenitic rocks. This is consistent with the fact that mafic minerals in the syenites and melasyenites are compositionally similar. K2O variation is shown in Figure 9c. Previously identified compositional groups are apparent in this plot. Variation of K2O is noteworthy for two reasons. First, the proposed magmatic trend is not linear: K2O is enriched to values of about 8% (at approximately 2% CaO), and then decreases in the most evolved syenites. Samples in the K2O enrichment part of the trend also have Sr contents >500 ppm, whereas samples in the K2O depletion part have Sr contents <500 ppm. Additional distinctions among the syenites can be seen in a plot of CaO versus total alkalis (Fig. 9d). In this plot, the group of Sr-rich syenites shows negative correlation between CaO and total alkalis and a group of Sr-poor, quartz-bearing syenites show nearly constant total alkali content over a range of CaO contents. A third syenite group (labeled "cumulate") is characterized by high total alkalis at low CaO contents (Fig. 9d), high Al2O3 values (most >18.5%), and positive Eu anomalies (see below). TiO2 contents in the suite increase from the olivine gabbro to the most evolved dioritic rocks and then decrease Fig. 9e). In contrast, the compositional array of the melasyenitic samples crosses the inferred magmatic trend. Strontium abundances increase from olivine gabbro to evolved dioritic compositions (Fig. 9f), then decrease among the monzonites and syenites. It appears that the magmatic trend splits at this point, with a branch that extends to the Sr-rich syenite group and a branch that encompasses monzonitic compositions. Two distinct groups exist among Ca-rich diorites. One group contains the most Ca-rich diorites, which have Sr <1000 ppm; the second group with CaO from 10 to 16 wt% contains Sr contents from 900 to 1500 ppm (Fig. 9f). Rare earth element data The rare earth element plot of an olivine gabbro (91.49H) shows the most primitive pattern of all samples (Fig. 10a) with a negligible negative Eu anomaly, a shallow negative slope, and minor enrichment of the light REE. Dioritic samples from the proposed magmatic trend have higher REE abundances, show light REE enrichment, and small negative Eu anomalies. Rare earth element abundances are anticorrelated with bulk 202 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. Fig. 11. Multielement variation diagrams normalized to the primitive composition of Sun and McDonough, 1989). a. Olivine gabbro and dioritic rocks that are part of the proposed magmatic trend. Samples are listed in order of decreasing CaO content. b. Ca-rich dioritic rocks. Samples 70.24 and 91.44H are the "hortites" of Vogt (1916). Sample 93.44H is a nepheline-rich monzodiorite. CaO contents are listed next to sample numbers. c. Syenitic rocks, distinguished according to Sr content. The shaded field represents the range of gabbroic and syenitic samples of the magmatic trend. d. Monzonitic patterns are shown with solid lines, whereas patterns for melasyenite and melamonzonite are shown with dashed lines. The shaded field represents the range of gabbroic and syenitic samples of the magmatic trend. rock Mg/(Mg+Fe) and CaO content. Other dioritic samples show similar REE patterns (Fig. 10b); the samples richest in CaO content have the lowest REE abundances. These samples (70.27 and 91.44H) correspond to the "hortite" of Vogt (1916). concentrations and positive Eu anomalies. Three of these samples are dikes (89.08H, 89.14H, and 93.66H) and the latter sample is fine-grained. This suggests that residual magma was able to escape from alkali-feldspar-rich mushes. The transition from dioritic to monzonitic samples (Fig. 10c) involves an increase in total REE contents and generally deeper Eu anomalies. In contrast, the transition from monzonite to syenite (Figs. 10d and e) shows variable enrichment of light REE but depletion of heavy REE. Eu anomalies in the Sr-rich syenites are similar to those of the monzonites, but many of the syenites with Sr < 500 ppm (Fig. 10e) have deeper negative anomalies. Four syenite samples have patterns consistent with feldspar accumulation (Fig. 10f): low REE Granitic dikes from the intrusive complex display a range of REE patterns and abundances (Fig. 10g). Most samples have cup-shaped patterns and deep negative Eu anomalies. Light REE abundances are generally lower than those of the syenites but heavy REE abundances are similar (~10x chondrites). Granitic rocks from Kvingra show similar variability in REE abundances (Fig. 10h) but the cup-shaped pattern is absent; instead the middle and heavy REE show a flat pattern. With one exception, granitic dikes from the western Geology of the Hortavær Igneous Complex 203 NORWEGIAN JOURNAL OF GEOLOGY migmatitic host rocks have patterns similar to Kvingra samples, but with smaller Eu anomalies. The exception is a two-mica trondhjemite (sample 91.24H), which has low REE abundances and a positive Eu anomaly, suggestive of feldspar accumulation. Multi-element diagrams Primitive-mantle-normalized multi-element patterns are shown in Figure 11. Patterns for the olivine gabbro and dioritic samples that lie on the magmatic trend (Fig. 11a) show the most consistent patterns, in which Th, Nb, Ta, REE and K abundances increase with decreasing CaO content. The patterns are characterized by negative anomalies for Nb, Ta, P, and Ti, and positive anomalies for K and Sr, and arguably for Cs and Rb. Such patterns are characteristic of magmas erupted in supra-subduction zone environments, which is consistent with proposed tectonic setting for the Bindal Batholith (e.g., Stephens et al. 1985, Grenne et al. 1999, Yoshinobu et al. 2002). Dioritic samples that do not plot on the inferred magma lineage (Fig. 11b) show patterns similar to those in Figure 11a but with considerably more scatter. The patterns of syenitic rocks (Fig. 11c) are characteristic of highly fractionated magmas (e.g., Thompson et al. 1984, Thompson & Fowler 1986), with peaks at Cs, Rb, Th, and K and negative anomalies at Ba, Nb, Ta, P, and Ti. The monzonites have patterns intermediate between the syenites and diorites (Fig. 11d). Nb and Ta abundances in the monzonites are the same as, or slightly higher than those in the diorites and are tightly clustered compared to the syenites, in which Nb and Ta abundances vary by an order of magnitude. Discussion Style of intrusion of the Hortavær complex Although it is common practice to think of plutons as congealed pools of magma in the crust, the Hortavær complex cannot be viewed in this way. Field relationships clearly show that the complex was emplaced as a series of thousands of magma batches, many of which had sheet-like dimensions. Some of these magma batches were emplaced as dikes, but where they encountered older unsolidified magma batches, they mingled and locally mixed. In other words, there is little evidence for giant, homogeneous masses of magma. Instead the complex was emplaced as small-volume pulses that varied in composition from dioritic to syenitic throughout the history of the complex. Finally, in its late stage, magma compositions were predominantly granitic. In light of this style of emplacement, we consider the Hortavær complex to represent a zone of magma transfer rather than a simple pluton. Intrusive complexes with this geometry should result in significant subvertical thermal anomalies. In fact, such anomalies should be larger than thermal aureoles associated with singlepulse plutons because magma that passes through the system provides more heat than a single magma pulse (Annen & Sparks 2002, Dufek & Bergantz 2002). In addition, processes that can be observed at the level of exposure clearly provide only part of the entire magmatic history, because each magma pulse conceivably carries its own petrologic history. An example of this problem at Hortavær concerns the relative proportions of rocks that represent differentiated magmas (those belonging to the magma lineage) versus cumulate rocks. If our interpretation of the magma lineage is correct, then on a volumetric basis, the system lacks the abundant cumulate rocks necessary to explain the volume of differentiated rocks. This issue is "solved", i.e., moved to greater depth, by recognition of the complex as a zone of magma transfer. Tectonic setting Trace element patterns (Fig. 11) are consistent with emplacement of the complex in an arc setting. The 456 Ma titanite age suggests that the Hortavær complex represents the oldest post-migmatization magmatic activity in the HNC, followed by 448 to 445 Ma (U-Pb, zircon) mafic to intermediate plutons in the Velfjord region (Nordgulen et al. 1993, Yoshinobu et al. 2002). The tectonic setting of the Velfjord massif and related plutons was interpreted to be a continental-margin arc formed near Laurentia during the Taconic orogeny (e.g. Yoshinobu et al. 2002, Roberts 2003). The Hortavær complex may be associated with this burst of mafic magmatism. Arcs are commonly zones of local extension because of trench rollback (Hamilton, 1988; Hawkins, in press). This also fits the Hortavær complex, which consists of swarms of dikes of locally uniform orientation. For these reasons, we currently favor the interpretation that Hortavær magmatism is part of the Taconic episode. Magmatic processes Although the complex shows wide geochemical scatter, there is a discernible, consistent, magmatic trend. If one considers the previous discussion concerning mode of emplacement, it should be clear that "line of descent" does not imply evolution of a single magma body. Instead, it implies similar, coincident or parallel lines of evolution of numerous magma batches in a thick, complex, crustal column. However, the observation of a magmatic trend, the regular variations in plagioclase, clinopyroxene, and amphibole compositions, and regular enrichment patters of the incompatible elements suggests that crystal-liquid separation processes may have influenced evolution of the magma. Sample 89.08H 89.14H 91.12H 91.34H 64.29 64.68 62.83 63.22 SiO2 0.02 0.11 0.40 0.24 TiO2 19.76 18.91 16.90 17.00 Al2O3 0.45 0.49 0.38 0.85 Fe2O3 FeO n.d. n.d. 3.23 2.01 MnO 0.00 0.01 0.07 0.06 MgO 0.07 0.10 0.16 0.09 CaO 1.82 1.06 3.43 2.88 7.25 4.88 3.82 4.91 Na2O 5.15 8.55 7.87 6.33 K2O 0.01 0.09 0.08 0.02 P2O5 LOI 1.00 0.38 0.35 1.42 Total 99.81 99.26 99.52 99.04 Mg/(Mg+Fet) 0.225 0.291 0.074 0.056 A/CNK 0.95 0.98 0.80 0.84 trace element concentrations in parts per million Rb 160 361 178 297 Sr 132 210 690 377 Zr 18 54 n.d. 124 Y 0.4 4.0 n.d. 34.0 Nb b.d. 3 n.d. 9 Ba 152 160 342 477 Sc 0.2 0.8 1.4 0.2 V n.d. b.d. n.d. b.d. Cr b.d. n.d. b.d. b.d. Ni n.d. n.d. n.d. n.d. Cu b.d. b.d. n.d. b.d. Zn 4 6 57 54 La 3.2 6.82 31.80 31.64 Ce 3.8 9.28 73.30 61.46 Nd 1.5 3.67 38.80 25.60 Sm 0.25 0.86 6.82 5.59 Eu 0.16 0.65 0.98 1.10 Tb 0.02 0.12 0.64 0.79 Yb 0.07 0.49 1.56 3.40 Lu b.d. 0.06 0.23 0.52 Co 0.4 0.2 2.8 2.0 Cs 1.13 4.80 0.73 8.87 Hf 0.07 1.25 1.71 3.69 U b.d. 0.8 b.d. n.d. Th 0.40 2.29 3.80 n.d. Ta 0.02 0.09 1.11 0.38 Pb n.d. n.d. n.d. n.d. Eu/Eu* 1.49 1.49 0.32 0.38 REE lab Imperial OSU OSU UTEP major element oxide weight percent 93.67H 63.96 0.04 17.84 0.67 1.72 0.05 0.12 1.84 6.18 6.67 0.03 0.46 99.59 0.086 0.86 146 113 31 6.8 2 43 0.9 b.d. b.d. b.d. b.d. 27 13.20 25.00 11.90 2.27 1.12 0.28 1.20 0.16 1.0 0.66 1.00 b.d. 0.95 0.05 n.d. 0.99 UTEP 93.66H 65.32 0.02 19.51 0.37 n.d. 0.00 0.03 1.15 7.01 5.98 0.01 0.21 99.61 0.122 0.97 117 580 6 1.2 3 203 0.2 b.d. b.d. b.d. b.d. 5 4.40 6.20 2.80 0.44 0.75 0.04 0.18 0.03 0.2 0.26 0.18 b.d. 0.39 0.06 n.d. 3.79 UTEP syenite Table 4. Representative major and trace element analyses. 139 113 681 26.8 19 213 5.1 5 b.d. b.d. 2 56 142.00 254.00 85.80 14.50 1.08 1.09 3.50 0.48 2.4 0.83 14.30 4.4 24.60 0.52 n.d. 0.18 UTEP 93.75H 64.88 0.33 16.78 1.48 2.58 0.08 0.35 1.62 4.27 7.3 0.10 0.19 99.97 0.139 0.94 92 663 119 33.0 23 424 1.7 9 b.d. b.d. 3 82 41.30 96.30 45.70 9.34 1.41 1.09 2.90 0.39 4.4 0.70 3.44 b.d. 5.40 1.40 n.d. 0.31 UTEP 93.76H 62.01 0.57 17.16 1.45 3.27 0.09 0.34 4.97 5.49 4.41 0.10 0.45 100.31 0.117 0.75 260 275 40 8.0 n.d. 192 n.d. 15 b.d. b.d. b.d. 48 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. b.d. n.d. n.d. n.d. 2.60 n.d. 17.9 n.d. 02.16H 63.50 0.09 17.07 2.88 n.d. 0.06 0.22 2.27 4.46 8.51 0.06 0.40 99.52 0.131 0.83 88 2718 265 65.5 26 1666 0.5 15 11 7 b.d. 130 64.50 122.00 63.80 14.70 3.02 1.83 5.70 0.75 12.0 0.42 6.79 1.1 6.60 1.86 n.d. 0.41 UTEP 91.06H 50.94 1.61 12.75 2.87 8.67 0.21 0.45 14.02 2.78 3.60 0.27 1.39 99.56 0.066 0.38 28 1935 215 34.7 32 384 1.0 19 b.d. b.d. b.d. 129 60.90 137.00 68.90 13.10 2.31 1.25 3.20 0.38 10.9 0.33 6.18 b.d. 5.70 1.65 n.d. 0.39 UTEP 91.10H 51.52 1.39 15.26 2.71 7.41 0.17 0.54 13.08 4.33 1.15 0.25 1.13 98.95 0.089 0.47 19 794 286 48.0 n.d. 390 n.d. 33 b.d. b.d. 12 124 6.40 13.90 5.70 1.75 1.26 0.51 2.30 0.38 5.2 2.32 4.63 3.5 1.00 0.69 n.d. 1.09 UTEP 91.20H 45.48 2.99 7.08 16.28 n.d. 0.27 1.72 23.18 1.88 0.88 0.57 2.43 100.33 0.173 0.15 107 1910 216 36.2 32 1968 0.7 21 b.d. b.d. 5 104 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. UTEP 91.21H 51.14 1.98 10.96 2.15 8.51 0.20 1.05 14.49 2.45 4.33 0.32 1.91 99.50 0.152 0.31 melasyenite/melamonzonite 169 464 226 29.1 23 887 2.7 13 n.d. n.d. b.d. 73 33.80 65.10 36.20 7.62 1.71 0.91 2.10 0.31 7.8 0.59 5.28 1.8 3.90 0.89 n.d. 0.46 UTEP 91.45H 59.60 1.12 17.28 1.05 3.74 0.08 0.76 4.06 4.45 6.22 0.15 0.19 98.70 0.224 0.81 196 1275 227 19.0 n.d. 507 n.d. 12 b.d. b.d. 6 123 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 13.0 n.d. n.d. n.d. 7.00 n.d. n.d. n.d. 93.45H 52.89 0.60 20.75 7.21 n.d. 0.15 0.31 5.28 7.79 4.94 0.12 1.90 100.04 0.078 0.75 154 863 77 34.9 18 770 2.8 13 14 28 b.d. 89 42.30 83.60 35.70 7.39 1.32 1.01 3.20 0.44 7.7 0.47 2.13 b.d. 3.70 1.15 n.d. 0.35 UTEP 93.70H 57.74 0.56 17.13 2.82 4.31 0.14 1.10 4.26 4.91 5.78 0.32 0.35 99.41 0.222 0.78 monzonite 74 522 237 42.0 n.d. 362 n.d. 58 25 13 7 136 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 37.8 n.d. n.d. n.d. 4.80 n.d. 10.4 n.d. 02.11H 47.80 1.86 15.98 13.43 n.d. 0.20 4.09 8.58 3.43 3.45 0.43 0.82 100.07 0.376 0.64 204 NORWEGIAN JOURNAL OF GEOLOGY C. G. Barnes et al. 93.52H 48.59 1.13 17.82 9.99 n.d. 0.18 4.78 10.98 5.09 1.34 0.21 0.92 100.11 0.487 0.60 68 548 307 44.0 n.d. 169 n.d. 62 8 32 16 149 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 33.0 n.d. n.d. n.d. 20.00 n.d. n.d. n.d. 93.44H 43.04 1.04 17.02 1.71 7.59 0.19 2.10 15.64 6.03 1.93 0.40 3.61 100.30 0.291 0.42 93 1100 258 45.4 24 134 1.3 20 26 138 8 134 44.03 78.60 34.90 8.14 1.67 1.16 4.55 0.69 22.0 7.13 4.59 n.d. n.d. 1.51 n.d. 0.39 UTEP 97 720 196 42.8 14 361 3.0 32 b.d. 144 5 127 39.78 74.73 34.80 7.90 1.71 1.09 3.97 0.60 27.0 2.05 4.41 n.d. n.d. 1.00 n.d. 0.42 UTEP 93.58H 50.59 1.44 18.16 1.51 9.90 0.19 2.92 6.87 5.14 2.23 0.36 0.55 99.86 0.316 0.78 67 1284 225 26.0 n.d. 443 n.d. 29 b.d. 3 12 101 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 33.0 n.d. n.d. n.d. 7.00 n.d. n.d. n.d. 93.72H 44.63 1.08 18.89 11.66 n.d. 0.18 3.99 10.93 5.41 2.1 0.34 1.57 99.21 0.404 0.61 8 1073 237 42.0 n.d. 213 n.d. 18 b.d. b.d. b.d. 116 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 16.1 n.d. n.d. n.d. 14.90 n.d. 12.3 n.d. 02.14H 53.02 1.31 16.86 9.01 n.d. 0.15 0.88 12.55 4.72 0.77 0.38 0.17 99.82 0.162 0.54 69 448 138 26.0 n.d. b.d. n.d. 107 45 75 14 93 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 36.8 n.d. n.d. n.d. 10.10 n.d. 13.8 n.d. 02.32H 48.52 1.11 17.03 9.85 n.d. 0.16 6.50 11.09 3.67 1.54 0.16 1.42 101.05 0.567 0.61 97 752 189 26.0 n.d. 319 n.d. 54 b.d. 38 9 93 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 34.5 n.d. n.d. n.d. 12.30 n.d. 14.5 n.d. 02.45H 50.88 0.93 18.04 9.40 n.d. 0.14 4.86 9.23 4.49 2.04 0.19 0.70 100.90 0.506 0.68 47 1345 195 38.0 n.d. 506 n.d. 19 b.d. b.d. 6 82 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. 21.2 n.d. n.d. n.d. 11.00 n.d. 12.4 n.d. 02.57H 52.73 1.81 15.25 8.55 n.d. 0.15 1.58 12.82 3.60 1.92 0.39 1.25 100.05 0.268 0.49 69 223 223 15.6 11 255 4.6 19 b.d. n.d. b.d. 38 6.40 13.90 5.70 1.75 1.26 0.51 2.30 0.38 5.2 2.32 4.63 3.5 1.00 0.69 n.d. 1.09 UTEP 91.24H 72.68 0.43 14.33 0.58 2.17 0.03 0.77 2.76 3.59 1.85 0.11 1.00 100.32 0.336 1.11 Notes: b.d., below detection limits. n.d., not determined. REE lab: Imperial College, London, OSU: Oregon State Univ.; UTEP: Univ. of Texas-El Paso. Sample 91.48H 91.49H 93.39H 93.40H 48.90 47.94 49.59 49.73 SiO2 0.51 1.03 1.42 1.46 TiO2 25.01 16.20 17.64 16.94 Al2O3 3.66 1.73 2.23 2.24 Fe2O3 FeO n.d. 5.80 8.30 8.20 MnO 0.06 0.13 0.20 0.18 MgO 2.38 8.67 4.18 3.42 CaO 14.52 15.33 8.71 7.81 2.89 2.38 4.99 4.89 Na2O 1.06 0.38 1.93 2.57 K2O 0.11 0.08 0.26 0.32 P2O5 LOI 0.98 0.51 0.88 0.80 Total 100.08 100.18 100.33 98.56 Mg/(Mg+Fet) 0.563 0.677 0.420 0.374 A/CNK 0.77 0.50 0.67 0.68 trace element concentrations in parts per million Rb 37 15 120 124 Sr 1536 479 603 600 Zr 87 105 230 258 Y 17.3 29.6 43.5 44.5 Nb 5 b.d. 14 17 Ba 159 112 340 423 Sc 5.0 19.7 6.4 5.0 V 32 97 49 40 Cr 9 36 b.d. b.d. Ni 59 118 26 8 Cu 17 21 19 12 Zn 25 55 113 115 La n.d. 8.18 29.65 36.13 Ce n.d. 24.10 56.86 69.76 Nd n.d. 14.40 28.40 34.00 Sm n.d. 3.83 7.11 8.08 Eu n.d. 1.20 1.65 1.79 Tb n.d. 0.65 1.11 1.18 Yb n.d. 2.23 4.22 4.44 Lu n.d. 0.34 0.64 0.68 Co n.d. 37.3 32.0 28.0 Cs n.d. 0.57 8.44 4.83 Hf n.d. 3.36 4.99 5.83 U n.d. b.d. n.d. n.d. Th n.d. 1.57 n.d. n.d. Ta n.d. 0.19 1.03 1.13 Pb n.d. n.d. n.d. n.d. Eu/Eu* n.d. 0.57 0.43 0.42 REE lab OSU UTEP UTEP gabbro, diorite, monzodiorite major element oxide weight percent Table 4. Continued Representative major and trace element analyses. 412 15 163 22.9 13 8 0.1 n.d. b.d. n.d. b.d. 44 8.50 21.00 7.60 1.88 0.09 0.36 2.80 0.64 0.2 12.70 7.53 15.5 50.90 0.50 n.d. 0.08 UTEP 91.59H 76.39 0.04 13.30 0.36 0.60 0.03 0.05 0.27 4.74 4.44 0.00 0.17 100.39 0.090 1.02 469 38 277 22.7 26 65 0.5 b.d. b.d. 3 b.d. 115 31.57 56.69 16.60 3.31 0.30 0.34 2.19 0.37 1.1 26.90 7.36 n.d. n.d. 0.58 n.d. 0.19 UTEP 93.43H 73.11 0.06 14.20 0.41 0.88 0.02 0.06 0.41 5.55 4.59 0.03 0.32 99.62 0.074 0.96 granitic rocks 134 120 407 67.0 21 404 10.7 49 28 35 b.d. 62 47.74 100.50 49.50 10.67 1.76 1.54 5.53 0.85 9.5 4.38 10.40 n.d. n.d. 1.30 n.d. 0.31 UTEP 93.84H 69.38 0.81 14.77 0.77 4.00 0.07 1.24 2.00 3.49 3.08 0.11 0.85 100.57 0.320 1.16 255 43 74 9.0 n.d. b.d. n.d. 14 b.d. b.d. b.d. 40 n.d. n.d. n.d. n.d. n.d. n.d. n.d. n.d. b.d. n.d. n.d. n.d. 25.80 n.d. 30.2 n.d. 02.54H 75.52 0.04 13.28 1.00 n.d. 0.02 0.04 0.65 5.08 3.57 0.01 0.17 99.38 0.073 0.99 293 218 246 30.5 22 287 2.0 12 b.d. b.d. b.d. 61 42.97 80.44 33.10 6.90 0.87 0.82 2.75 0.44 5.8 7.84 6.08 n.d. n.d. 1.54 n.d. 0.26 UTEP 93.31H 64.43 0.53 16.24 1.42 2.30 0.10 0.69 2.03 4.98 5.1 0.15 1.81 99.78 0.255 0.93 Kvingra NORWEGIAN JOURNAL OF GEOLOGY Geology of the Hortavær Igneous Complex 205 206 NORWEGIAN JOURNAL OF GEOLOGY Furthermore, the effects of assimilation of carbonate rocks in the magmas are undeniable. This conclusion arises from a number of observations. For our purposes the first is the presence of minerals commonly associated with carbonate assimilation, such as calcite, scapolite, nepheline, grossular-andradite garnet, and idocrase. Not only do these minerals display igneous textures, they exist in medium- to fine-grained dikes, which must represent, at the very least, melt-rich magmas. The second observation is that layered calc-silicate rocks have been completely "made over" into rocks that have igneous assemblages, minerals with igneous compositions, and igneous textures (e.g. the melasyenitic rocks). These conclusions do not imply that assimilation was a simple process of dissolution of carbonate or calc-silicate minerals into the magmas. It is well known that assimilation of pure calcite in closed systems is of limited extent (e.g. Tilley 1949, 1952), primarily due to low solubility of CO2 (e.g. Watkinson & Wyllie 1969). Even if such assimilation were possible, there is no reason to think that assimilation of calcite should result in a Carich magma. In fact, the opposite might be true. A simple reaction that could characterize assimilation in the Hortavær complex in dioritic magmas might be: olivine + calcite + melt 1 = clinopyroxene + melt 2 +CO2. In this reaction, calcium provided by the assimilated carbonate phase is taken up in a solid silicate phase (clinopyroxene). This differentiation process is not a cotectic one, but rather a peritectic one in which the magma is modified by dissolution of one or more minerals as others precipitate (much like the olivine-enstatite reaction in basaltic magmas). Thus assimilation will not raise the Ca content of the melt, instead it will have the effect of depletion of the melt in elements necessary for crystallization of clinopyroxene.We suggest that in the dioritic magmas of the Hortavær complex, a principal and early major-element effect of carbonate assimilation was enrichment of alkalis, such that rocks in the suite range from calcic to alkaline. This process would suppress fractionation of olivine (consumed in the assimilation reaction) and probably of plagioclase (because Ca is sequestered in clinopyroxene). Therefore, clinopyroxene-dominated alkali enrichment would be accompanied by limited silica enrichment, as recognized by Meen (1990). Assimilation of carbonates would result in cumulate rocks with excess clinopyroxene, interstitial plagioclase, and accessory Ca-rich phases such as scapolite, titanite, and calcite. Such cumulate rocks are the "hortites" of Vogt (1916). This type of reaction cannot explain the transition from nepheline normative and nepheline-bearing mafic and intermediate compositions to the evolved C. G. Barnes et al. quartz syenitic compositions observed at Hortavær. Direct evolution by fractional crystallization and/or carbonate assimilation is not possible because of the low-P thermal divide between silica under- and oversaturated magmas. Thus, the presence of quartz-bearing syenites suggests either that the quartz syenites are unrelated to the rest of the Hortavær complex or that quartz is present due to assimilation of quartzofeldspathic metasedimentary material (e.g. Foland et al. 1993, Landoll et al. 1994). We find the former unlikely because quartz-bearing syenites do not occur in a geographically restricted part of the complex. Instead, we suggest that the principal assimilate in many Hortavær magmas was not pure carbonate, but instead was calcsilicate rock with both carbonate and quartzofeldspathic components. This would explain the observed decrease in silica activity from gabbroic to monzonitic compositions followed by an increase in silica activity from monzonite to syenite. In the mafic magmas, the abundance of Mg and Fe allowed the carbonate component of calc-silicate rocks to be consumed (to form clinopyroxene: see reaction above). In contrast, the evolved magmas lacked sufficient Mg and Fe to form significant clinopyroxene and therefore could not assimilate much carbonate component. Instead, these evolved magmas assimilated silicate components of the calcsilicate contaminants. This is certainly consistent with the abundance of layered calc-silicate rocks as screens in the Hortavær complex. It is also consistent with the observation that marble screens at Hortavær are essentially untouched by reaction with host magmas, whereas calc-silicate screens are nearly completely converted to layered melasyenite/melamonzonite. Finally, assimilation of calc-silicate rocks is consistent with Nd, oxygen, and carbon isotope ratios, which are documented in Barnes et al. (2002 and in review). It is unlikely that the widespread granitic dikes that make up the youngest parts of the complex are directly related to the syenites, because of the lower alkali contents of the granites. It is possible that the granites represent magmas that experienced less carbonate assimilation than those of the Hortavær trend, although assimilation of carbonate in granitic magma is unlikely owing to the limited solubility of CaO (e.g. Tilley 1949). It is also possible that the granites originated by partial melting of the host rocks. If so, the compositions of the granitic dikes are quite distinct from those of granites in the host rocks (Figs. 8 and 9). Alternatively, the granites are petrologically unrelated either to the Hortavær syenites or to the migmatitic host rocks. One of the interesting and unanswered questions concerning the Hortavær complex is the site of differentiation of the magmas. We argue for emplacement in a transfer zone, yet also show evidence for seemingly in situ assimilation, fractionation, and crystal accumulation. The former implies long-term magma storage Geology of the Hortavær Igneous Complex 207 NORWEGIAN JOURNAL OF GEOLOGY deeper in the crust, the latter implies that magmas remained chemically reactive for long periods at the level of emplacement. Final resolution of this problem awaits further research. However, we note that isotopic variation within the complex is consistent with in situ assimilation of host calc-silicates (Barnes et al. in review). We take this to suggest either that similar calcsilicate rocks exist at depth or that the collection of dikes in the Hortavær transfer zone retained enough heat to permit local, commonly extensive, host-rock assimilation. As noted above, closed-system assimilation of carbonate rocks is limited by the small solubility of CO2. This constraint is removed if CO2-rich fluid escapes from the site of assimilation. The fact that assimilation was occurring in a magma transfer zone, and probably in a zone of extension, suggests a resolution of this problem. As CO2 was enriched to the point of saturation, it exsolved as a separate fluid phases (very probably with H2O), and migrated upward, away from the magma system. As long as the system remained open to loss of CO2, and contained enough latent heat to promote chemical reactions, assimilation could proceed. Conclusions The Hortavær intrusive complex represents a Caledonian-age (456 Ma) intrusion that evolved from calcic to alkalic compositions (gabbro to alkali feldspar syenite). The complex was emplaced as thousands of dikes and dike-like bodies into a sequence of metasedimentary rocks characteristic of the Helgeland Nappe Complex. Magma mingling was widespread and magma mixing occurred locally. Trace element patterns indicate an arc setting for the complex. Magma evolution was dominated by crystal-liquid separation processes and heavily overprinted by assimilation of calc-silicate host rocks. We interpret differentiation to alkalic (nepheline-bearing) compositions as the result of carbonate-dominated assimilation in a magma system open to loss of CO2. Peritectic assimilation of carbonate phases resulted in stabilization of clinopyroxene relative to olivine and plagioclase. This resulted in enrichment of the alkalis over a small range of SiO2. As a CO2-rich fluid phase formed in the system, it was lost upward. This fluid loss, combined with episodic emplacement of new, hot magma batches, permitting continued assimilation. Further magma evolution to quartz syenite requires assimilation of the quartzofeldspathic component of the host rocks. Acknowledgements: - We are grateful to Øystein Nordgulen for his interest and input during all stages of this project, to J. G. deHaas and Ingrid Vokes for XRF analyses, and to Susan Swapp for assistance with microprobe analysis. Field work was ably assisted by Jostein Hiller, Reidar Berg, and Arne Lysø. We thank Bernard Barbarin, Jean-Paul Liegois, and Øystein Nordgulen for thoughtful reviews. This research was initially funded by a grant from Nansenfondet to Prestvik and received partial support from National Science Foundation grant EAR-9814280. References Annen, C. & Sparks, R.S.J. 2002: Effects of repetitive emplacement of basaltic intrusions on thermal evolution and melt generation in the crust. Earth and Planetary Science Letters 203, 937-955. Barnes, C.G., Allen, C.M. & Saleeby, J.B. 1986: Open- and closed-system characteristics of a tilted plutonic system, Klamath Mountains, California. Journal of Geophysical Research 91, 6073-6090. Barnes, C.G., Prestvik, T., Sundvoll, B., and Surratt, D. in review: Pervasive assimilation of carbonate and silicate rocks in the Hortavær Igneous Complex, north-central Norway. Lithos. Barnes, C.G., Presvik, T. & Barnes, M.A. 2002: Open-system alkaline magmatism in the Caledonides of north-central Norway. EOS, Trans. AGU 83, #47, Abstract V62A-1390. Didier, J. & Barbarin, B. (eds) 1991: Enclaves and Granite Petrology, Elsevier, 625p. Dufek, J.D. & Bergantz, G.W. 2002: A stochastic evaluation of the dynamical and thermal response of the lower crust to progressive basaltic input: Applications to MASH zone dynamics. Eos Trans. AGU, 83 (47), Fall Meet. Suppl., Abstract V61A-1346. Foland, K.A., Landoll, J.D., Henderson, C.M.B. & Jiangfeng, C. 1993: Formation of cogenetic quartz and nepheline syenites. Geochimica et Cosmochimica Acta 57, 697-704. Frost, B.R., Barnes, C.G., Collins, W.J., Arculus, R.J., Ellis, D.J. & Frost, C.D. 2001: A geochemical classification for granitic rocks. Journal of Petrology 42, 2033-2048. Grenne, T., Ihlen, P. & Vokes, F.M. 1999: Scandinavian Caledonide metallogeny in a plate tectonic perspective. Mineralium Deposita 34, 422-471. Gustavson, M. & Prestvik, T. 1979: The igneous complex of Hortavær, Nord-Trøndelag, central Norway. Norges geologiske undersøkelse 348, 73-92. Hamilton, W.B. 1988: Plate tectonics and island arcs. Geological Society of America Bulletin 100, 1503-1527. Hawkins, J.W. 2002: Geology of supra-subduction zones – Implications for the origin of ophiolites. Geological Society of America Special Paper: (in press). Landoll, J.D., Foland, K.A. & Henderson, C.M.B. 1994: Nd isotopes demonstrate the role of contamination in the formation of coexisting quartz and nepheline syenites at the Abu Khruq Complex, Egypt. Contributions to Mineralogy and Petrology 117, 305-329. Ludwig, K. 2002: Isoplot/Ex version 2.49. A geochronological toolkit for Microsoft Excel. Berkeley Geochronological Centre Special Publication. Meen, J.K. 1990: Elevation of potassium content of basaltic magma by fractional crystallization: the effect of pressure. Contributions to Mineralogy and Petrology 104, 309-331. Nordgulen, Ø. 1993: A summary of the petrography and geochemistry of the Bindal Batholith. Geological Survey of Norway, Report 92.111. Nordgulen, Ø. & Mitchell, J.G. 1988: Kentallenite (olivine-monzonite) in Bindal, central Norwegian Caledonides. Norges geologiske undersøkelse Bulletin 413, 51-60. Nordgulen, Ø., Bickford, M., Nissen, A.L. & Wortman G.L. 1993: U-Pb zircon ages from the Bindal Batholith, and the tectonic history of 208 NORWEGIAN JOURNAL OF GEOLOGY the Helgeland Nappe Complex, Scandinavian Caledonides. Journal of the Geological Society, London 150, 771-783. Roberts, D. 2003: The Scandinavian Caledonides: event chronology, palaeogeographic settings and likely modern analogues. Tectonophysics 365, 283-299. Schmitz, M.D., Bowring, S.A., Ludwig, K.R.& Renne, P.R. 2003: Comment on "Precise K-Ar, 40Ar-39Ar, Rb-Sr, and U-Pb mineral ages from the 27.5 Ma Fish Canyon Tuff reference standard: by M.A. Lanphere and H Baadsgaard. Chemical Geology electronic version, in press. Spear, F., Kohn, M. & Cheney, J. 1999: P-T paths from anatectic pelites. Contributions to Mineralogy and Petrology 134, 17-32. Stephens, M.B., Gustavson, M., Ramberg, I.B. & Zachrisson, E. 1985: The Caledonides of central-north Scandinavia–a tectonostratigraphic overview. In Gee, D.G. & Sturt, B.A. (eds): The Caledonide Orogen–Scandinavia and Related Areas, 135-162. John Wiley & Sons Ltd. Sun, S.-s. & McDonough, W.F. 1989: Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. In Saunders, A.D. & Norry, M.J. (eds): Magmatism in the ocean basins, 313-345. Geological Society London Special Publication 42, Oxford. Thompson, R.N. & Fowler, M.B. 1986: Subduction-related shoshonitic and ultrapotassic magmatism: a study of Siluro-Ordovician syenites from the Scottish Caledonides. Contributions to Mineralogy and Petrology 94, 507-522. Thompson, R.N., Morrison, M.A., Hendry, G.L. & Parry, S.J. 1984: An assessment of the relative roles of crust and mantle in magma genesis: an elemental approach. Philosophical Transactions of the Royal Society of London A 310, 459-590. Tilley, C.E. 1949: An alkali facies of granite at granite-dolomite contacts in Skye: Geological Magazine 86, 81-93. Tilley, C.E. 1952: Some trends of basaltic magma in limestone syntexis: American Journal of Science, Bowen Volume 529-545. Vogt, T. 1916: Petrographisch-chemische Studien an einigen Assimilations-Gesteinen der Nord-Norwegichen Gebirgskette. Vid. Selsk. Kristiania, Skr. I, Mat.-Nat. Klasse 1915 No 8, 33pp. Watkinson, D.H. & Wyllie, P.J. 1969: Phase equilibrium studies bearing on the limestone-assimilation hypotheses. Geological Society of America Bulletin 80, 1565-1576. Woodhead, J. & Hergt, J. 2000: Pb-isotope analyses of USGS Reference Materials. Geostandards Newsletter 24, 33-38. Yoshinobu, A.S., Barnes, C.G., Nordgulen, Ø., Prestvik, T., Fanning, M. & Pedersen, R-B. 2002: Ordovician magmatism, deformation, and exhumation in the Caledonides of central Norway: An orphan of the Taconic orogeny? Geology 30, 883-886. C. G. Barnes et al.