Marine and Petroleum Geology 26 (2009) 1866–1878 Contents lists available at ScienceDirect Marine and Petroleum Geology journal homepage: www.elsevier.com/locate/marpetgeo Martian mud volcanism: Terrestrial analogs and implications for formational scenarios James A. Skinner, Jr. a * , Adriano Mazzini b a b U.S. Geological Survey, Astrogeology Team, 2255 North Gemini Drive, Flagstaff, AZ 86001, USA Physics of Geological Processes, University of Oslo, Box 1048, 0316 Oslo, Norway a r t i c l e i n f o a b s t r a c t Article history: Received 26 June 2008 Received in revised form 23 January 2009 Accepted 14 February 2009 Available online 28 February 2009 The geology of Mars and the stratigraphic characteristics of its uppermost crust (mega-regolith) suggest that some of the pervasively-occurring pitted cones, mounds, and flows may have formed through processes akin to terrestrial mud volcanism. A comparison of terrestrial mud volcanism suggests that equivalent Martian processes likely required discrete sedimentary depocenters, volatile-enriched strata, buried rheological instabilities, and a mechanism of destabilization to initiate subsurface flow. We outline five formational scenarios whereby Martian mud volcanism might have occurred: (A) rapid deposition of sediments, (B) volcano-induced destabilization, (C) tectonic shortening, (D) long-term, load-induced subsidence, and (E) seismic shaking. We describe locations within and around the Martian northern plains that broadly fit the geological context of these scenarios and which contain mud volcano-like landforms. We compare terrestrial and Martian satellite images and examine the geological settings of mud volcano provinces on Earth in order to describe potential target areas for piercement structures on Mars. Our comparisons help to evaluate not only the role of water as a functional component of geological processes on Mars but also how Martian mud volcanoes could provide samples of otherwise inaccessible strata, some of which could contain astrobiological evidence. Published by Elsevier Ltd. Keywords: Mars Mud volcano Analogs Surface processes Astrobiology 1. Introduction Pitted cones, mounds, and lobate flows are common landforms on the Martian surface and are most generally interpreted as having formed through an array of overlapping volcanic, glacial, periglacial, and/or impact processes (e.g., Frey et al., 1979; Lucchitta, 1981; Garvin et al., 2000; Dickson et al., 2008; Burr et al., 2008). Other researchers have used terrestrial mud volcanism as an analog for the formation of many of these features, primarily as an alternative to magmatic volcanism (Komar, 1990; Davis and Tanaka, 1995; Tanaka, 1997; Tanaka et al., 2003a,b, 2005; Farrand et al., 2005; Kite et al., 2007; Skinner and Tanaka, 2007; Skinner et al., 2007). However, dissimilar geologic processes commonly result in landforms of broadly-similar shape (the geomorphological concept of ‘‘equifinality’’). Inferring geologic processes based strictly on geomorphology can implicate, both directly and indirectly, very specific and often unintentional formational characteristics and conditions. It is unclear whether the current understanding of Mars’ geologic evolution reasonably supports the geologic conditions implied by a mud volcano analogy. Terrestrial studies reveal that mud volcanoes are geomorphologically variable and are subtly affected by many overlapping processes and conditions. For extraterrestrial studies, we are forced to rely heavily on remotebased geomorphological observations to interpret geologic processes and history. Though mud volcanism may be a plausible Martian geologic process based on gross morphologic similarities of terrestrial and Martian landforms, the geologic implications of the analogy have not yet been fully assessed. Herein, we summarize the components of terrestrial mud volcanoes and use these as a framework to examine the physical characteristics whereby mud volcanoes may form on Mars. Because a comprehensive summary of Mars’ exploration, datasets, and geologic setting is not tractable in the following text, further information is included as an Appendix. 2. Framework for terrestrial mud volcanism * Corresponding author. Tel.: þ1 928 556 7043; fax: þ1 928 556 7019. E-mail addresses: jskinner@usgs.gov (J.A. Skinner Jr.), adriano.mazzini@ fys.uio.no (A. Mazzini). 0264-8172/$ – see front matter Published by Elsevier Ltd. doi:10.1016/j.marpetgeo.2009.02.006 The terminology that is used to describe the surface and subsurface movements of large masses of sediments and fluids is broad and sometimes misleading. For terrestrial studies, these terms include J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 1867 diapirs, diatremes, domes, mud intrusions, chimneys, pockmarks, piercement structures, and mud volcanoes. Though such terms are descriptive, they are often confusingly applied, resulting in an unintended divergence of consistent scientific discussion. Herein, we apply a simplified definition of mud volcanoes as ‘‘geological phenomena made manifest through the sudden eruption or quiescent extrusion of sediment, rock, and fluid from deeper strata’’. On Earth, the occurrence of a mud volcano implies not only a suite of geologic conditions but also a sequence of events that result from these conditions. Processes and conditions that can lead to the growth of a mud volcano include (1) high rates of basin sedimentation and/or subsidence, (2) illitization of clay minerals, (3) expansion of pore fluids, (4) generation of hydrocarbon-rich fluids at depth, (5) presence of impermeable (or low permeability) strata as capping rock for pressurized units, (6) vertical or lateral compression of basin sediments, and (7) seismicity. When these conditions are achieved, mud volcanism may occur through a sequence of events that includes the build-up of pressure at depth (generally driven by gas (methane) production), the brecciation of sedimentary strata along a vertical conduit, and the eruption or extrusion of mud (mud breccia) with water, oil, and/or gas. The geomorphic result is generally a crater-shaped vent, perhaps located on a topographic cone, mound, or ridge of various size and shape, that is composed and surrounded by mud (mud breccia) flows (e.g., Khalilov and Kerimov, 1981; Kholodov, 2002; Kopf, 2002). Most terrestrial mud volcanoes form proximal to paleo-depocenters within structurally-controlled sedimentary basins that are experiencing active tectonic deformation. As a result, mud volcanoes are frequently located along major geologic structures such as faults and fold axes related to deformation of the sedimentary sequence. Terrestrial mud volcanoes can occur both offshore (e.g., Black Sea, Gulf of Cadiz, Caspian Sea, and Mediterranean Sea) and onshore (e.g., Azerbaijan, Indonesia, Trinidad), just to name the best known and characterized fields (e.g., Jakubov et al., 1971; Barber et al., 1986; Cita et al., 1996; Ivanov et al., 1996; Dia et al., 1999; Pinheiro et al., 2003; Isaksen et al., 2007). The most spectacular terrestrial mud volcanoes have a conical shape with a summit crater, similar to magmatic equivalents. Some mud volcanoes reach up to 5 km in diameter and 500 m in height. The total volume of erupted mud breccia can be >12 km3 for single volcanoes and up to 250 km3 for mud volcano complexes. Mud volcano flows can cover areas as large as 100 km2 (e.g., Dimitrov, 2002). One of the most spectacular terrestrial eruptions occurs on the Java Island at the Lusi mud volcano, which has erupted continuously for more than two years (at the time of this writing) covering >7 km2 (Mazzini et al., 2007). A critical element of the extraterrestrial analogy for mud volcanoes is what the morphology/morphometry of a potential Martian mud volcano indicates about the underlying formational conditions (e.g., Skinner and Tanaka, 2007). Such conditions include tapping depth, fluid content, stratigraphic architecture, and triggering mechanism. Size and morphology of terrestrial mud volcanoes vary widely depending on factors such as eruption frequency and vigor, lithology and water content of the erupted mud breccia, type of meteoric erosion (e.g., wind, rain, bottom currents), rates of basin subsidence, thickness of the affected sequence, and character of the confining strata or structure. The characteristics of these analogies and their known geologic settings provide the framework for describing formational contexts and scenarios of Martian mud volcanism. Global physiography provides the most broad and basic framework for understanding a planet’s evolutionary processes. The form and arrangement of large-scale Martian surface features provide a record of the planet’s geologic history. This record includes impact, volcanic, fluvial, periglacial, and eolian resurfacing processes, all of which variously overlap and intercalate with one another through time (Appendix A3). One of the most dominant Martian physiographic features is the highland–lowland boundary (HLB) scarp, a globe-encircling feature that elevates more ancient, higher-standing and densely-cratered terrains by 1–5 km above younger, lower-lying and sparsely-cratered terrains (Fig. 1). The Martian HLB establishes a globally-occurring topographic basin within which geologic processes can be examined and analyzed. The cratered highlands dominate the southern two-thirds of the Martian surface and are chiefly composed of very ancient (older than 3.5 Gyr; Tanaka, 1986; Hartmann and Neukum, 2001) impact crater and basin lithologies that are intercalated, onlapped, and buried by volcanic and sedimentary deposits (e.g., Scott and Carr, 1978; Scott and Tanaka, 1986; Greeley and Guest, 1987). By contrast, the Martian lowlands dominate the northern one-third of the Martian surface and are chiefly composed of (relatively) younger (younger than 2.5 Gyr) sedimentary and volcanic deposits (e.g., Tanaka et al., 2005). These units fill and bury ancient topographic and structural basins, which likely formed through both endogenic and exogenic processes very early in Mars’ evolution (e.g., Nimmo and Tanaka, 2005). The lowland basins appear to be temporally equivalent to the oldest exposed highlands (Frey, 2006). However, the ancient lowland surfaces are thoroughly buried by thick sequences (Buczkowski, 2007) of impact ejecta, erosional detritus, and volcanic rocks and sediment (Tanaka et al., 2003a, 2005), forming the low-relief topographic undulations that characterize the lowland plains (Fig. 1). An important step toward evaluating Mars’ geologic history includes framing the lowlands as a global-scale depocenter that consists of multiple overlapping, albeit unique, topographic and stratigraphic basins. This inherently implies that lowland processes were spatially partitioned, an assertion at least partly supported by recent geological maps (Tanaka et al., 2005). We suggest that these physiographic characteristics helped to establish accommodation space for the accumulation of sediments and development of a stratigraphic framework for the potential growth of mud volcanoes. 3. Framework for Martian mud volcanism 3.2. Stratigraphy In the absence of field-based data, terrestrial analogs provide the basis for deciphering the geologic history of extraterrestrial surfaces The lowlands represent Mars’ largest and longest-lived depocenter for the accumulation of sediments eroded from adjacent and inferring the conditions through which they form. For Mars, orbiting spacecrafts have historically provided the most fundamental datasets for investigating global and regional geologic characteristics (Appendix A1). Herein, we summarize geomorphological characteristics of Martian features as they appear in selected topographic and image datasets. For our characterizations, we viewed relevant Martian datasets (Appendix A2) as spatially-registered layers in a geographic information system (GIS). For morphological analogy, we note that many of the imaging instruments orbiting Mars were adapted from Earth-orbiting imaging instrument parameters, including spectral range, band-pass, and resolution. As such, we use terrestrial satellite images of Earth (supplemented by field-based images) as comparative examples to Martian mud volcanoes (see Fig. 6 caption for details on comparative images). 3.1. Global physiography 1868 J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 Fig. 1. Global context maps of Mars. (A) Color shaded-relief image showing major topographic features. The lowlands (purple and blue hues) represent Mars’ preeminent depocenter for the long-lived accumulation of diverse material sequences. White circles and connecting white line denote generalized locations of conceptual stratigraphic columns (Fig. 2). White boxes denote the locations of landforms described herein (Fig. 6). Stars denote recent surface lander locations: Mars Exploration Rovers (MER) A (‘‘Spirit’’) and B (‘‘Opportunity’’) and Phoenix (PHX). (B) Generalized geologic map of Mars indicating key physiographic regions, lithotypes, and surface ages. The yellow hachured line identifies the HLB, where exposed. Mollweide projection centered at 0 E longitude with a MOLA topographic base, artificially-illuminated from the northwest. Adapted from Nimmo and Tanaka (2005). highland (and lowland) outcrops (Appendix A4). Though internal stratigraphy cannot be confidently resolved within the lowland deposits, depth–diameter relationships of buried impact crater populations suggest that they vary laterally in both thickness and rheology (Buczkowski, 2007). Internal stratigraphy must be inferred by observing outcrops of the uppermost exposures of Martian rock and sedimentary deposits (i.e., Walther’s Law applied in reverse fashion; Middleton, 1973) and then accounting for variations based on a working knowledge of the geologic history of spatially-separated locations. In general, the Martian uppermost crust (mega-regolith) can be interpreted as vertically-gradational stratigraphic zones that consist of fractured crystalline basement rock overlain by a mélange of impact breccias overlain by (and intercalated with) erosional detritus and volcanic rocks and sediments (Clifford, 1993; MacKinnon and Tanaka, 1989; Appendix A4). These sequences presumably have differing proportions and lateral extents due to regional variations in topographic relief, latitude, material provenance, and proximity to geologic activity (Fig. 2). Surface impacts are interpreted to be (mostly) random, resulting in a global J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 1869 Fig. 2. Perceived variations in the Martian mega-regolith that constitute basin-related sequences and assist in partitioning geologic processes. The Martian highlands are dominated by uplifted crustal massifs (A) that grade laterally into high-standing cratered plains composed of intercalated sedimentary and volcanic units (B). With increased distance from high-standing regions, the thicknesses of the ejecta and detrital zones increase with the thickest mega-regolith in depocenters (C and D). Idealized global locations are denoted in Fig. 1. thickness of impact breccia that is maximum where there is an overall absence of long-term denudation (such as in topographic lows). By contrast, the thickness of erosional detritus is likely to increase as long as there are erosional processes, transport mechanisms, and a common base-level with sufficient accommodation space. These considerations are important because each zone within the mega-regolith is likely to have different and perhaps contrasting physical and hydrogeologic properties (e.g., MacKinnon and Tanaka, 1989; Skinner, 2005). We suggest that the stratigraphic architecture of the Martian lowland deposits established a spatially-variable hydrogeologic framework that assisted the formation of Martian mud volcanoes. control the stability of volatiles in the Martian mega-regolith are latitude and elevation: low-elevation and high latitude regions (such as the Martian lowlands) are more apt to have had stable volatile reservoirs than high elevations and low latitudes. These assertions are supported by recent observations of widespread near-surface ice inventories by NASA’s Mars Phoenix Lander in the northern lowlands (e.g., Mitrofanov et al., 2007; Mellon et al., 2008; see PHX location in Fig. 1). We suggest that these hydrogeologic characteristics and their associated processes transported and sequestered fluids in the subsurface, providing a key component for the growth of Martian mud volcanoes. 3.4. The Martian rock cycle 3.3. Hydrogeology Physical, rheological, and spatial properties of terrestrial strata direct migratory pathways for subsurface fluids and there is no plausible reason to expect fundamentally discrepant behavior on Mars. For example, thick and horizontally continuous layers of buried impact breccia are interpreted to be low-permeability, highporosity (due to high clay content), and mechanically-weak subsurface regions that help to partition Martian aquifers (MacKinnon and Tanaka, 1989). Subsurface fluids are critical components for the initiation of terrestrial mud volcanism and similar components should be anticipated in order to reasonably apply the process to Mars. There is abundant morphological evidence (channels, stream-lined islands, and lobate flows; Carr, 1996) and spectroscopic evidence (aqueous alteration mineralogies; Wyatt et al., 2004; Poulet et al., 2005) that show water was at the very least episodically present on the Martian surface (Appendix A5). The presence of fluids in the Martian mega-regolith is expected to have occurred through multiple processes (e.g., Clifford, 1993), including overland flow and aquifer recharge, direct condensation and/or precipitation, and atmospheric vapor diffusion (Fig. 3). A critical element for understanding the geologic effects of the Martian hydrogeologic cycle is the persistence and stability of water and/or ice within the mega-regolith. Pressure and temperature relationships imply that the two most critical factors that The transition from one major rock type to another is conceptually represented by the rock cycle. However, the familiar Fig. 3. Conceptual mechanisms of enrichment and migration of water within the Martian mega-regolith. These include: overland flow (1), supra-cryospheric groundwater flow (2), direct precipitation and/or condensation (3), atmospheric vapor diffusion (4), polar ice layers (5), impact (6), cryospheric vapor diffusion (7), and a leaking cryosphere (8). Locations of conceptual stratigraphic sections described in Fig. 2 are indicated by arrows. Low-lying regions provide a sink for the accumulation of subsurface volatiles and for volatile-assisted geologic processes. 1870 J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 terrestrial rock cycle significantly contrasts with the Martian rock cycle for several reasons. For example, on Mars, crustal materials are interpreted to have thickened very early in the planet’s formation, precluding the development of plate-driven processes of any notable longevity or overt geologic significance (Sleep, 2000; Nimmo and Tanaka, 2005; Appendix A5). As a result, one of the key ingredients for crustal recycling on Earth (i.e., plate-driven tectonism; Sleep, 2000) may have been inconsequential on Mars for much of its geologic history. A fundamental lack of crustal recycling through tectonic processes may have been substituted by recycling through surface impacts (e.g., Melosh, 1989) and diagenesis through compaction, volcanic heating, and aqueous alteration (e.g., McLennan et al., 2007). It is well understood from surface observations of the terrestrial planets as well as numerical modeling that impacts onto planetary surfaces are capable of simultaneously redistributing crustal outcrops, transforming target rocks and sediments, and forming regional-scale topographic basins (see summaries by Melosh, 1989 and Spudis, 1993). On Mars, for example, Argyre, Isidis, Utopia, and Hellas basins (see Fig. 1) formed from separate impact events (e.g., Schultz et al., 1982), resulting in the uplift of basement rocks and the formation of topographic basins thousands of kilometers in diameter. Subsurface and near-surface diagenesis likely occurred episodically on Mars through various processes, resulting in the weak induration of sediments (e.g., Wyatt et al., 2004). Impact-based recycling and low-grade diagenesis, in addition to atmospherically-driven surface erosion, may be the most significant components of the Martian rock cycle since early in Mars’ evolution (Fig. 4). The reduced gravitational field of Mars (relative to Earth) is likely to have had a demonstrable effect on Martian depthdependent diagenetic processes. Diminished gravitational effects on the compaction or lithification of Martian sediments may have resulted in long-lived instabilities in the Martian mega-regolith. Fig. 4. Conceptual representation of the Martian rock cycle. Non-essential or ‘‘inactive’’ processes are denoted by dotted lines and include tectonic recycling of the Martian crust and mega-regolith. The bulk of Mars’ evolutionary history has been dominated by the creation of sediments through the uplift and exposure by surface impacts. Topographic equilibrium can be theoretically achieved through erosion and infill. The depths and lateral continuity of these buried zones may be indirectly observed through the development and clustering of surface landforms. We suspect that the described Martian rock cycle was responsible for establishing instabilities in the megaregolith, resulting in upper-crustal sequences that were predisposed to compaction, mobilization, and ascent given certain mechanical controls (Skinner and Tanaka, 2007). 4. Potential scenarios for growth of Martian mud volcanoes Using broad-brush characteristics of the terrestrial mud volcano process and perceived Earth–Mars parallels, we suggest five geologically-plausible scenarios whereby mud volcanism (or mud volcano-like) processes could occur on Mars. The intent of the following sections is to provide an interpretive classification scheme for previously-identified landforms based on inferred geologic context and formational scenario. We present schematic diagrams in Fig. 5 and correlative terrestrial analogs in Fig. 6. 4.1. Scenario A – Rapid sedimentation This scenario of Martian mud volcanism entails the compaction and de-volatization of volumetrically-massive flood deposits (e.g., Davis and Tanaka, 1995; Fig. 5A). Mud volcanoes of this formational class may form preferentially where there are variations in the deposit thickness (perhaps due to variations in the pre-existing topography) and/or at the deposit margin where the sediments are likely to be fine-grained, water-enriched, and relatively thin. We interpret these units as rheologically homogenous and relatively thin (tens of meters?) (Table 1). Furthermore, the inferred particle sizes and pore space volumes of emplaced materials suggest that erupted mud and mud breccia may have had a low viscosity. Though mass flow deposits are inherently devoid of significant confining layers, internal heterogeneities may develop within rapidly-deposited sequences due to repeated outburst floods and/ or rheological layering due to deposition of contrasting units (e.g., flood deposits and lava flows). On Mars, the low-lying plains of Isidis, Chryse, and Acidalia Planitiae are interpreted to have formed through the catastrophic deposition of sediments related to fluvial and volcanic events (Baker and Milton, 1974; Christiansen, 1989; Tanaka, 1997). Isidis Planitia is located within the floor of an ancient impact basin and is surrounded by high-standing impact massifs and a large volcanic province (Fig. 1). Chryse and Acidalia Planitiae are located at the margins of the northern plains and proximal to the mouths of massive fluvial outflow channels. Each of these regions contains a high density (358 per 103 km2) of pitted cones and mounds (Fig. 6A, Table 2) that have been interpreted as Martian mud volcanoes that formed through the compaction of rapidly-deposited sediments (Davis and Tanaka, 1995; Tanaka, 1997; Tanaka et al., 2003a). The Isidis features are generally cone- or mound-shaped landforms that are a few hundreds of meters wide and tens of meters tall (Fig. 6A). The pitted cones are often aligned into arcuate ridges several to tens of kilometers in length, suggesting some association with buried structures. Mound-shaped features are common in Acidalia Planitia, some with subtle topographic depressions that may be eruptive vents (Fig. 6B). Though most mud volcano-like features in Chryse Planitia are similar to those described above, the region also includes pancake-like landforms that are several kilometers in diameter with shallow, ovoid central craters (Fig. 6C). None of these features are overtly associated with well-defined flows. The Isidis, Chryse, and Acidalia features are morphologically akin to terrestrial subaerial mud volcanoes and gryphons as well as J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 1871 Fig. 5. Formational scenarios through which mud volcanoes may form. In each case, we assume that affected sequences were volatile enriched and that instabilities were either inherent within and/or induced upon the sequences through various mechanism or processes. Martian mud volcanoes may have formed due to overlapping scenario characteristics. Table 1 describes our inferred physical characteristics of affected lithotypes for each scenario. (A) Scenario A – vertical compaction of rapidly-deposited sediments, such as catastrophic flood deposits. (B) Scenario B – vertical compaction of subsurface units through volcano-related heating through the intrusion of magmatic dikes and sills. (C) Scenario C – lateral compaction through tectonic shortening. (D) Scenario D – vertical compaction through long-term, load-induced subsidence. Mud volcanism due to the intrusion of magmatic dikes and sills may provide an alternative or supplemental condition. (D) Scenario E – vertical compaction through seismic shaking. dewatering features (e.g., Jakubov et al., 1971). Terrestrial gryphons may not be associated with abundant mud flows but, rather, form vertical vents for subsurface de-volatilization through smallvolume fluid extrusion and/or outgassing (Fig. 6D). The pitted cones that form inside eruptive mud volcano craters result from continued fluid and mud seepage after periodic eruptions. Moundshaped mud volcanoes form on Earth through repeated eruption of mud breccia from a central vent (Fig. 6E) and multiple summit depressions in Martian features may allude to multiple eruptions (e.g, Fig. 6B). Landforms similar to the elongate, pancake-like features of Chryse Planitia are also observed on Earth (Fig. 6F). Their shape and/or location are usually controlled by tectonic features such as shallow or deep faults or by large-scale anticlines. After large-scale eruptions, the crater may collapse and subsequently be affected by localized seepage (e.g., Hovland et al., 1997; Planke et al., 2003; Mazzini et al., 2009). Table 1 Formational scenarios, inferred characteristics, and potential locations of Martian mud volcanoes. Scenario Internal character of affected materials Viscosity of erupted material Thickness of affected materials Martian locations, landforms observed Martian locations, landforms not observed Rapid sedimentation Volcanic/geothermal destabilization Tectonic shortening Homogenous Homogeneous or heterogeneous Heterogeneous Low Low to moderate 10’s meters 100’s meters Isidis, Chryse, Acidalia Galaxias Fossae Hellas, central Utopia Cerberus Fossae, Alba Patera Low to high Utopia HLB Long-term, load-induced subsidence Seismic shaking Homogenous or heterogeneous Homogenous or heterogeneous (?) 100’s of meters to kilometers Kilometers On most globally-occurring tectonic ridges Other large basin centers (Utopia, Isidis, Hellas, Argyre) ? High Low to high (?) Meters to kilometers (?) Scandia Utopia HLB (?) 1872 J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 Fig. 6. Examples of Martian mud volcano-like features formed through formational scenarios proposed herein (see Fig. 1 for locations). Panels are excerpts from Mars Orbiter Camera narrow-angle images (w3 m/px resolution), Thermal Emission Imaging System (visible, 36 m/px and infrared, 100 m/px), and Mars Orbiter Laser Altimeter (MOLA) digital elevation models (231 m/px) (image number noted on each panel). Each Mars image is aligned above morphologically-equivalent terrestrial mud volcanoes (see Section 3 for summary). North is toward the top. Earth images are from Google Earth, unless otherwise noted. (A) Pitted cones of Isidis Planitia. Note partial alignment indicating some structural or topographic control. (B) Typical mound-shaped landform in Acidalia Planitia. Note small depressions at summit that may be overlapping vents. (C) Pancake-shaped mound in Chryse Planitia. Features form in channel floors and pre-date linear (desiccation?) fractures. (D) Field of seeping gryphons in Dashgil mud volcano crater, Azerbaijan. Fluid seepage is ongoing, forming mud flows that spread inside the crater. (E) Circular crater of Bledug Kuwu mud volcano (Java, Indonesia) showing three main active vents where gas and mud vigorously erupt. Size of the crater is w650 m. (F) Elongated and collapsed crater with concentric mud breccia flows and fluidized mud locally erupting inside the crater, east Azerbaijan. Size of the crater w1.5 km. (G) Pitted cones, flows, and ridges in Galaxias Fossae. Smooth, light-toned flows flood irregularly-shaped depression. (H) Eastern Utopia Planitia HLB. Mounds (arrows), some superposed with small pitted cones, form proximal to tectonic ridges. (I) Eastern Utopia Planitia HLB. Broad, low-slope mounds (arrows) superposed by smooth plains materials. (J) Lusi mud volcano (Java, Indonesia), oblique aerial view during August 2006. Note the area covered by the low-viscosity, water-rich mud. (K) Pitted cones of erupting gryphons at Dashgil mud volcano, Azerbaijan. Gryphon heights are w4 m. (L) Tang mud volcano, southeastern Iran. Mud flows radiate from a central pit. Fig. 6. (continued). Image size 2 km. (M) Falsely-illuminated hillshade of MOLA topography depicting mounds of the Scandia region (arrows). Note scale bar relative to other panels. (N) Scandia mound (outlined). Note high-standing central peak (arrow). (O) Western Utopia Planitia HLB pitted cones. Note morphologic difference between pitted cones (outlined) and impact crater. (P) Mud volcano in eastern Azerbaijan. Long axis of the crater is w3 km. (Q) Paint Hill, TX, which formed as a piercement structure above an ascending column of breccia that tapped Tertiary strata. Note boulders on the crowning diapir. (R) Quickbird image of Bahar satellite mud volcano, Azerbaijan. Size of the crater is w100 m. Note morphologic similarity to impact crater (c.f. Fig. 6O). (S) Western Utopia Planitia HLB pitted cones and rugged lobate features (flows?). Cross-cutting relationships indicate both features formed concurrently. (T) Western Utopia Planitia HLB cone and smooth flows. Note association with narrow fractures (arrow). (U) Western Utopia Planitia. Pitted cones and lobate features. (V) Quickbird image of Kotturdag mud volcano, Azerbaijan. Size of the crater is w200 m. The circular crater was breached by a large tongue of mud breccia. (W) Oblique Quickbird image of Lokbatan mud volcano, Azerbaijan. Width of image is w3 km. Graben collapse controls mud flows and coincides with the direction of the anticline axis that hosts Lokbatan mud volcano. (X) Photograph of edge of mud breccia flow from Lokbatan mud volcano, Azerbaijan. See oil wells in the background for scale. 1874 J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 4.2. Scenario B – Volcano-induced destabilization This scenario of Martian mud volcanism entails the thermal and/ or mechanical destabilization of volatile-enriched units through volcanic activity, mostly likely through the intrusion of dikes and sills (Fig. 5B). Models of volcano-ice interactions on Mars indicate that the thickness of affected units may be hundreds of meters thick (e.g., Wilson and Mouginis-Mark, 2003). The inferred tapping depth and conduit stratigraphy lead us to speculate that the erupted sediments in this formational scenario are low- to moderate-viscosity mud (Table 1). Preferential mobilization of mud and mud breccia along structural weaknesses may result in alignment of mud volcanoes and elongated depressions related to surface subsidence. The inferred variability in the affected units may result in diverse mud volcano morphologies and localized deposition of mud flows. Spatial distributions and alignments may reflect buried structural weaknesses that mimic regional stresses associated with the growth of the adjacent volcanic province (Appendix A5). On Mars, several locations are likely to have evolved partly through volcano–ice interactions. Galaxias Fossae is a fissure system located in the lowlands along the eastern margin of Utopia Planitia and adjacent to the Elysium volcanic province (Fig. 1). The region contains a relatively moderate density (90 per 103 km2) of mud volcano-like landforms including small pitted cones and domes, lineaments, and flows. However, the features occur as highdensity clusters, particularly when they are located marginal to bright, lobate deposits that fill shallow depressions (Fig. 6G). Segmented, positive- and negative-relief lineaments occur within and may be the source of the high-albedo surface units. The Galaxias landforms are aligned in the northwest–southeast direction, parallel to regional fracture patterns (Hall et al., 1986; Tanaka et al., 2005). They are a few hundred meters in diameter, often contain central pits, and extend tens of meters above adjacent terrains (Table 2). Mud volcanoes similar to the features observed in Galaxias Fossae are also observed on Earth. These ‘‘swamp-like’’ features are characterized by low-elevation and water-rich mud, which erupt for extended periods of time from a central vent. Erupted lowviscosity mud easily migrates away from the main crater and can cover significant areas (depending on the original morphology of the terrain). Some examples of this type of terrestrial mud volcanoes occur in Trinidad and Malaysia. Perhaps the best terrestrial analog is the Lusi mud volcano in northeast Java (Fig. 6J), a waterdominated eruption that has been ongoing since May 2006, which covers >7 km2. Similar to the hypothesized low-viscosity flows and edifices of Galaxias Fossae, Lusi is located proximal to a magmatic complex (Mazzini et al., 2007), which may provide a mechanism for the initiation and longevity of the eruption. Lineated ridges observed in the Galaxias region (Fig. 6G) may be similar to terrestrial sinter ridges produced by frictional heating of mud breccia during eruption. 4.3. Scenario C – Tectonic shortening This scenario of Martian mud volcanism entails the eruption of mud and mud breccia along buried faults due to the compression of volatile-enriched strata (Fig. 5C). We interpret the units affected by this Martian mud volcano scenario to have been rheologically heterogeneous due to the inferred high density of emergent faults and the potential existence of heterogeneous layers to confine subsurface pressures (Table 1). The source strata that produce mud volcanoes through tectonic shortening are not required to be rheologically layered. However, the presence of capping strata may promote the growth of mud volcano-like landforms due to increased subsurface pressures. Furthermore, compression ridges may provide more pathways for the ascent of buoyant sediments. Because Martian wrinkle ridges likely deform lithologic sequences of significant thickness (Watters, 1993), we suggest that the tapping sources for the growth of mud volcanoes in this scenario may be hundreds of meters to several kilometers thick (Table 1). These assessments are correlative to thickness estimates from depth– diameter relationships of buried impact crater populations (Buczkowski, 2007) as well as gravitational assessments of basin infill (Banerdt, 2004). On Mars, the southern margin of Utopia Planitia is defined by alluvial and colluvial plains related to the erosion of the ancient highlands located to the south (Tanaka et al., 2003; Skinner and Tanaka, 2007; Fig. 1). These sediments may be intercalated with Elysium-derived volcanic rocks and sediments, particularly along their eastern margins. The eastern Utopia Planitia HLB contains several large tectonic ridges which are buttressed and superposed by mounds that we interpret as having formed as mud volcanoes due to tectonic shortening (Fig. 6H). The mounds have a low spatial density within the region (1.04 per 103 km2), are circular to ovoid in planform shape, and are between 2 and 12 km wide (Table 2). Several have small (tens of meters wide) pitted cones located near their center (Fig. 6H). Others are partly buried by smooth materials of apparent similar origin (Fig. 6I), suggesting concurrent formation of mounds and surrounding plains. However, lobate features that are indicative of thick, widely-occurring mud flows are not observed in current datasets. The mounds that occur in the eastern Utopia HLB (as well as some of those described in Section 4.1) are morphologically akin to terrestrial subaerial mud volcanoes and gryphons where ‘‘pieshaped’’ features develop (Fig. 6K). On Earth, the latter can form as the result of episodic eruption of water-rich mud breccia from a central crater. Compared to the explosive eruptions that define other mud volcanoes, ‘‘pie-shaped’’ mud volcanoes on Earth erupt quiescently. The high fluid content (and resultant low viscosity) of mud in these instances allows for significant lateral propagation of mud flows with low-elevation lobate margins. This type of terrestrial mud volcano is common in mud volcano provinces; Dashgil (see Fig. 2 of Mazzini et al., 2009) and Tang mud volcanoes (Fig. 6L) are some of the examples observed in these regions. 4.4. Scenario D – Long-term, load-induced subsidence This scenario of Martian mud volcanism entails the growth of diapiric masses and piercement structures as the result of longterm compaction of thick, volatile-enriched sediments (Fig. 5D). We interpret the subsurface units affected by this Martian mud volcano scenario as rheologically homogenous or heterogeneous due to the diverse (and generally unknown) nature of the affected material as well as the diversity in size and geologic character of the erosional watersheds that feed these large basins (Table 1). Extreme depths of the source strata (kilometers?) can result in a lengthy vertical conduit along which ascending sediment mass can entrain rocks and sediment, resulting in the eruption of high viscosity mud breccia. The resultant mud volcano may be formed through violent eruptions (pitted cones or mounds) or passive extrusion (un-pitted domes). On Mars, the Scandia region occupies the lowest portions of the lowland plains (Fig. 1). This region is characterized by large ovoid and knobby mountains (termed ‘‘tholi’’) which may have formed through mud volcano-like processes related to long-term, loadinduced subsidence (Fig. 6M and N; Tanaka et al., 2003a; Kite et al., 2007). The Scandia Tholi are dissimilar to other mud volcano-like landforms described herein because they are not cone or mound shaped and they contain no obvious central vent or collapse J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 1875 Table 2 Morphological characteristics of potential Martian mud volcanoes. Martian location Postulated formational scenario Density (#/103 km2) Diameter Height Cone or mound morphologies? Associated with flow materials or morphologies? Associated with tectonic features? (type) Isidis, Chryse, Acidalia Galaxias Fossae Rapid sedimentation Volcanic/geotherm al destabilization Tectonic shortening Long-term, load-induced subsidence Seismic shaking 358 90 400–600 m 400–800 w10–20 m w10–20 m Both Cones No Yes No Yes (fractures) 1.04 0.13 2–12 km 22–40 km 10–200 m 100–500 m Mounds Mounds No No Yes (ridges) Maybea (fractures) 0.76 4–8 km 100–300 m Cones Yes No Eastern Utopia HLB Scandia Western Utopia HLB a Though their extents in Scandia are not observed, graben from Alba Patera may focus the growth of the Scandia mounds; see text for discussion. caldera. Rather, the Scandia features are large-diameter rugged mountains and hillocks (Table 2). If vents existed, they have been eroded or buried. Proximity to higher-standing regions, including Alba Patera and Planum Boreum (Fig. 1) suggests contributions from hydraulic pressuring through groundwater movement from higher areas (e.g., Tanaka, 2005). Increased subsurface pressures resulting from hydraulic forcing may have contributed to the buoyancy of buried deposits at the lowest point within the lowlands, supplementing subsidence-related pressures. Increased subsurface pressure may also have been generated by episodic inundation by flood deposits (Fairén et al., 2003). The Scandia Tholi are similar in shape to some terrestrial subaerial mud volcanoes (Fig. 6P) and piercement structures. Piercement structures are emergent sedimentary diapirs that pierce the land surface as the result of the long-term buoyant ascent of low-density sediments. Several of these structures are located above thick sedimentary sequences of the eastern Rio Grande embayment in McMullen County, Texas (Freeman, 1968). These mud volcanoes form circular to elongate domes that tend to parallel major northeast–southwest-trending geologic contacts and buried subsurface structures (Fig. 6Q). The resultant domes are comprised of breccia and sediment and are commonly topped and surrounded by meter-sized blocks (Freeman, 1968). An additional or alternative interpretation regarding the Scandia Tholi is their growth in response to magmatic intrusions in the form of dikes and sills, perhaps related to the Alba Patera shield volcano located to the south (Tanaka et al., 2005; Fig. 1). Such intrusions may have triggered metamorphic reactions and hydrothermal activity that resulted in violent eruptions. A similar scenario was suggested by Svensen et al. (2004) to explain the large craters observed on seismic images offshore Norway. This mechanism may explain the lack of clearly-defined craters associated with each of the Scandia mounds as well as the presence of blocky features observed across large areas (Fig. 6N). The past presence of water at or near the Scandia surface is evidenced through anomalous concentrations of hydrated sulfides and gypsum in adjacent regions (Langevin et al., 2005), which may further support the presence of hydrothermal activity in case of magmatic intrusions (e.g., Tanaka et al., 2008). A magmatic intrusion component for the growth of the Scandia features would be similar to the formational scenario described for the Galaxias Fossae features (Section 4.2), with the key discrepancy being the inferred thickness of affected units (see Table 1). 4.5. Scenario E – Seismic shaking This scenario of Martian mud volcanism entails the fluidization and buoyant ascent of volatile-enriched sediments due to seismically-induced destabilization and compaction (Fig. 5E). Mars is predicted to be seismically active based on length and offset measurements of tectonic graben, with Mars quakes of magnitude >4 occurring at rates of >500/year (Knapmeyer et al., 2006). Seismic energy can also be emitted by large impacts on adjacent and antipodal surfaces (Melosh, 1989). As such, the internal rheological character, viscosity, and thickness of the subsurface units feasibly extend the gamut of consideration (Table 1). This type of scenario can be used to account for the formation of multiple features on the surface of Mars, including irregularly-shaped depressions and mass movements as well as the pitted cone, mound, and flow morphologies of potential mud volcano origin. On Mars, we identify mud volcano-like landforms in the western Utopia Planitia HLB as potentially forming through seismically-induced mud volcanism (Tanaka et al. 2003b; Skinner and Tanaka, 2007). This assertion is based on a lack of characteristics that confidently place these materials in any of the aforementioned formational scenarios. The western Utopia HLB features include low-angle cones (with lobate flows) and mounds (Fig. 6O and S). The conical features are 4–8 km in diameter and 100–300 m in height (Table 2). The pitted cones are often associated with topographically-subdued fractures (Fig. 6T) and the surrounding plains consist of overlapping, rugged, lobate flows (Fig. 6U). The features that we observe in the southern Utopia HLB have similar morphologies to terrestrial mud volcanoes. Similar largescale edifice and crater mud volcanoes are observed in Azerbaijan such as Bahar satellite (Fig. 6R), Kotturdag (Fig. 6V), and Lokbatan (Fig. 6W). These classic morphology examples of terrestrial mud volcanoes form through periodic violent eruption of mud and mud breccia and resultant collapse of the upper plumbing conduits. They are oriented along subsurface anticline axes related to the lateral compression of underlying sedimentary sequences. These mud volcanoes are also associated with mud flows with lobate margins (Fig. 6X), the surface texture of which can vary from smooth to rugged similar to terrestrial lava flows. 5. Implications of Martian mud volcanism We acknowledge that the formational scenarios and morphologic comparisons outlined herein are speculative. However, they represent an improvement over past characterizations of mud volcano-like landforms on Mars because they provide some weight to formational specifics and geologic context. It is important to bear in mind that Mars–Earth analogs require careful adaptation in order to fully account for the implied geologic contexts and conditions. We identify several key implications of using mud volcanism as a viable Martian geologic process. If proven to exist, an analysis of the origin and character of Martian mud volcanoes can provide an improved understanding of the history of water on Mars and the potential for the development of life on that planet. For instance, basinscale impacts such as those that form the Martian lowlands form concentric basins separated by uplifted crustal massifs (Spudis, 1993; Schultz et al., 1982). Both terrestrial impact 1876 J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 studies and numerical modeling indicate that the bounding systems of impact-related extensional faults are long-lived focal points of hydrothermal activity. Though hydrothermal settings on Mars may have been conducive to the development of autotrophic life, their associated rock record is likely buried deep within the stratigraphic succession. The unique ability of mud volcanoes to transport rocks and sediments to the surface from great depths implies that erupted mud and mud breccia on Mars may contain ancient materials. Such deposits could provide not only a survey of past depositional environments but also astrobiological evidence that would otherwise be inaccessible for exploration. Terrestrial mud volcanoes are commonly associated with hydrocarbon reservoirs and mud eruptions contain not only rocks and sediment but also fluid, aqueous vapor, and gas (e.g., Ivanov and Guliev, 1988; Mazzini et al., 2007, 2009). Carbon dioxide and mainly methane production from terrestrial mud volcanoes may provide significant volumes of fossil hydrocarbon gas to Earth’s atmosphere and oceans (Etiope and Milkov, 2004). Recent details of methane plumes on Mars by Mumma et al. (2009) similarly indicate modern episodic release of methane and water vapor from discrete regions. Though the age of the Martian methane plumes is unknown, it is possible that they formed through the modern release of anciently-sequestered gas, perhaps as the result of the dissociation of gas-clathrate hydrate reservoirs (e.g., Kargel and Lunine, 1998). Even though the modern methane plumes do not directly coincide with the locations of postulated lowland mud volcanoes, the parallel between methane production from terrestrial mud volcanoes and potential production from Martian mud volcanoes is compelling. A concerted examination of Martian mud volcanism as a geologically feasible process that may contain geochemical evidence of fossil life can assist in identifying candidate landing sites for future Mars missions. Identifying a range of formational scenarios for the formation of Martian mud volcanoes helps underscore the concept that Martian basins contain complex stratigraphic architectures that both resulted from and subsequently controlled regionally-focused geologic activities. The idea that the younger and better-preserved Martian lowlands consist of multiple sedimentary deposits provides an understanding of the history of those deposits (e.g., Tanaka et al., 2003a). If mud volcanism is appropriately interpreted and applied, it serves to illustrate the stratigraphic and hydrogeologic character of those basins. For example, a complete stratigraphic reconstruction has been successfully complete on Mediterranean mud volcanoes using a collection of surface mud breccia clasts (Akhmanov, 1996; Akhmanov et al., 2003). Targeted analysis of potential Martian mud volcanoes using high-resolution surface and subsurface imaging instruments (Appendix A2) may provide a comprehensive approach to reconstructing Mars’ subsurface stratigraphy at specific locations. We note that the terrestrial mud volcanoes that we identify as morphologic analogies only partly satisfy the formational scenario with which they are identified. Our hypotheses implicate an overlap of scenarios that need to be more robustly explored. We identify only those regions within and adjacent to the Martian lowland plains because they represent the longest-lived depocenters on the surface of Mars. However, there are other locations that may potentially satisfy the formational characteristics proposed herein (e.g., Table 1). We are compelled to study these regions to identify whether our formational scenarios are realistically applicable. In addition, we need to establish scientific confidence beyond geomorphic analogy in order to develop the mud volcano hypotheses for Mars, using geochemical analyses and numerical modeling. There are significant questions that are unresolved (yet tractable for further research) that can firm our suggestive characterizations and scenarios. What is the full suite of formational processes that could produce mud volcano-like edifices on both Earth and Mars? Is there a discernible relationship between morphology/ morphometry and tapping depth, sediment-fluid ratios, subsurface structures, geologic unit, and formational age? Why are equivalent landforms not everywhere observed in ‘‘predicted’’ regions, based on the proposed formational scenarios? Numerical models can significantly assist in reconstructing the mud volcano-like processes and conditions through which the observed Martian landforms may have formed. Can the formational scenarios presented herein be reasonably buttressed by numerical modeling? Svensen et al. (2007) and Gisler et al. (2008) made an initial step in this direction when they compared terrestrial piercement features with numerical modeling of such eruptions on Mars. The results revealed comparable morphologies between the simulated terrestrial and Martian mud volcano-like features, with the exception that the latter were of much larger dimension. This effect is the result of the lower atmospheric pressure on Mars, which allows for more violent eruptions to manifest, fitting with the results described in our article. We not only expect but encourage improvements and corrections to the characterizations described herein. 6. Summary We find that the physical components that contribute to the growth of mud volcanoes on Earth have substantive parallels on Mars that warrant further consideration of mud volcanism as a viable Martian geologic process. We suggest: The physiographic, stratigraphic, hydrogeologic, and diagenetic character of Mars implicates five geologically-plausible formational scenarios through which mud volcanoes may form. These occur in regions that have undergone rapid sedimentation, volcano-induced destabilization, tectonic shortening, long-term, load-induced subsidence, and/or seismic shaking. We perceive these scenarios as end-members for the characterization of Martian mud volcanism and anticipate substantial overlap in geologic context and process. Mud volcano-like landforms exist in regions of the Martian lowlands that at least partly satisfy the aforementioned formational scenarios: (1) Isidis, Chryse, and Acidalia Planitiae (rapid sedimentation), (2) Galaxias Fossae (volcano-induced destabilization), (3) the eastern Utopia Planitia highland– lowland boundary (tectonic shortening), (4) the Scandia region (long-term, load-induced subsidence), and (5) the western Utopia Planitia highland–lowland boundary (seismic shaking). The pitted cones, mounds, and flows observed within regions within and marginal to the Martian northern plains are generally consistent with the morphological and geological criteria for terrestrial mud volcanoes. Martian mud volcanoes, if proven present, may provide ideal locations for surface exploration and sampling due to their point-source gathering of a vertical section of geologic units. The co-existence of water and past hydrothermal activity peripheral to lowland impact basins suggests that Martian mud volcanoes could provide evidence of past fossil life that would normally be inaccessible to robotic or human explorers. Acknowledgements We are grateful to the editors M. Ivanov and O. Catuneaunu for their support. We acknowledge the input of G. Akhmanov and one J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 anonymous reviewer who helped tighten the focus of this paper. Thanks to C. Fortezzo (USGS), G. Gisler (PGP), H. Svensen (PGP) and K. Tanaka (USGS) who each provided helpful discussions and reviews. We gratefully acknowledge the instrument teams that provided datasets used herein, including THEMIS (http://themis. asu.edu/), MOC (http://www.msss.com/), and MOLA (http://mola. gsfc.nasa.gov/). This work was supported, in part, by a grant from NASA’s Planetary Geology and Geophysics program. Appendix. Supplementary information Supplementary information associated with this article can be found, in the online version, at doi:10.1016/j.marpetgeo.2009.02.006 References Akhmanov, G.G., 1996. Lithology of mud breccia clasts from the Mediterranean Ridge. Mar. Geol., 151–164. Akhmanov, G.G., Premoli Silva, I., Erba, E., Cita, M.B., 2003. Sedimentary succession and evolution of the Mediterranean Ridge western sector as derived from lithology of mud breccia clasts. Mar. Geol. 195 (1–4), 277–299. Baker, V.R., Milton, D.J., 1974. Erosion by catastrophic floods on Mars and Earth. Icarus 23, 27–41. Banerdt, W.B., 2004. A gravity analysis of the subsurface structure of the Utopia impact basin. Lunar Planet. Sci. XXXV abstract #2043. Barber, A.J., Tjokosapoetro, S., Charlton, T.R., 1986. Mud volcanoes, shale diapirs, wrench faults and melanges in accretionary complexes, eastern Indonesia. Amer. Assoc. Petrol. Geol. Bull. 70, 1729–1741. Buczkowski, D.L., 2007. Stealth quasi-circular depressions (sQCDs) in the northern lowlands of Mars. J. Geophys. Res. 112, E09002, doi:10.1029/2006JE002836. Burr, B.M., Bruno, B.C., Lanagan, P.D., Glaze, L.S., Jaeger, W.L., Soare, R.J., Wan Bun Tseung, J.-M., Skinner Jr., J.A., Baloga, S.M., 2008. Meso-scale raised rim depressions (MRRDs) on earth: a review of the characteristics, processes, and spatial distributions of analogs for Mars. Planet. Space Sci., doi:10.1016/j.pss.2008.11.011. Carr, M.H., 1996. Water on Mars. Oxford University Press, New York, 229 pp. Christiansen, E.H., 1989. Lahars in the Elysium region of Mars. Geology 17, 203–206. Cita, M.B., Ivanov, M.K., Woodside, J.M., 1996. The Mediterranean Ridge Diapiric Belt. Mar. Geol. 132 (Special issue), 273 pp. Clifford, S.M., 1993. A model for the hydrologic and climatic behavior of water on Mars. J. Geophys. Res. 98, 10,973–11,103. Davis, P.A., Tanaka, K.L., 1995. Curvilinear ridges in Isidis Planitia, Mars – the result of mud volcanism? Proc. Lunar Planet. Sci. Conf. XXIV, 321–322. Dia, A.N., Castrec-Rouelle, M., Boulegue, J., Comeau, P., 1999. Trinidad mud volcanoes: where do the expelled fluids come from? Geochim. Cosmochim. Acta 63 (7–8), 1023–1038. Dickson, J.L., Head III, J.W., Marchant, D.R., 2008. Late Amazonian glaciation at the dichotomy boundary Mars: evidence for glacial thickness maxima and multiple glacial phases. Geology 36, 411–414. Dimitrov, L.I., 2002. Mud volcanoes – the most important pathway for degassing deeply buried sediments. Earth-Sci. Rev. 59 (1–4), 49–76. Etiope, G., Milkov, A., 2004. A new estimate of global methane flux from onshore and shallow submarine mud volcanoes to the atmosphere. Environ. Geol. 46, 997–1002. Fairén, A.G., Dohm, J.M., Baker, V.R., de Pablo, M.A., Ruiz, J., Ferris, J.C., Anderson, R.C., 2003. Episodic flood inundations of the northern plains, Mars. Icarus 165, 53–67. Farrand, W.H., Gaddis, L.R., Keszthelyi, L., 2005. Pitted cones and domes on Mars: observations in Acidalia and Cydonia Mensae using MOC, THEMIS, and TES data. J. Geophys. Res. 110, doi:10.1029/2004JE002297. Freeman, P.S., 1968. Exposed Middle Tertiary mud diapirs and related features in south Texas. AAPG Memoir 8, 162–182. Frey, H.V., 2006. Impact constraints on, and a chronology for, major events in early Mars. J. Geophys. Res. 111, E08591, doi:10/1029/2005JE002449. Frey, H., Lowry, B.L., Chase, S.A., 1979. Pseudocraters on Mars. J. Geophys. Res. 84 (B14), 8075–8086. Garvin, J.B., Sakimoto, S.E.H., Frawley, J.J., Schnetzler, C.C., Write, H.M., 2000. Topographic evidence for geologically recent near-polar volcanism on Mars. Icarus 145, 648–652, doi:10.1006/icar.2000.6409. Gisler, G., Svensen, H., Mazzini, A., Polteau, S., Galland, O., Planke, S., 2008. Simulations of the Explosive Eruption of Supercritical Fluids through Porous Media. EGU, Vienna. Greeley, R., Guest, J.E., 1987. Geologic map of the eastern equatorial region of Mars. USGS Misc. Inv. Ser. Map I-1802-B scale 1, 15M. Hall, J.L., Solomon, S.C., Head III, J.W., 1986. Elysium region, Mars: test of lithospheric loading models for the formation of tectonic features. J. Geophys. Res. 91, 11377–11392. Hartmann, W.K., Neukum, G., 2001. Cratering chronology and the evolution of Mars. In: Kallenback, R., Geiss, J., Hartmann, W.K. (Eds.), Chronology and Evolution of Mars. Kluwer Academic Publishers, London, pp. 165–194. 1877 Hovland, M., Hill, A., Stokes, D., 1997. The structure and geomorphology of the Dashgil mud volcano, Azerbaijan. Geomorphology 21, 1–15. Isaksen, G.H., Aliyev, A., Barboza, S.A., Plus, D., Guliev, I.S., 2007. Regional evaluation of source rock in Azerbaijan from the geochemistry of organic-rich rocks in mud-volcano ejecta. In: Yilmaz, P.O., Isaksen, G.H. (Eds.), Oil and Gas of the Greater Caspian Area. AAPG Studies in Geology, vol. 5, pp. 51–64. Ivanov, V.V., Guliev, I.S., 1988. A physio-chemical model of mud volcanism. In: Problems in the Oil and Gas Content of the Caucasus. Ivanov, M.K., Limonov, A.F., van Weering, T.C.E., 1996. Comparative characteristics of the Black Sea and Mediterranean Ridge mud volcanoes. Mar. Geol. 132 (1–4), 253–271. Jakubov, A.A., AliZade, A.A., Zeinalov, M.M., 1971. Mud Volcanoes of the Azerbaijan SSR. In: Atlas. Azerbaijan Academy of Sciences, Baku (in Russian). Kargel, J.S., Lunine, J.I., 1998. Clathrate hydrates on Earth and in the Solar System. In: Schmitt, B., de Bergh, C., Festou, M. (Eds.), Solar System Ices. Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 97–117. Khalilov, N.Y., Kerimov, A.A., 1981. Origin of mud volcanism and diapirism. Int. Geol. Rev. 25 (8), 877–881. Kholodov, V.N., 2002. Mud volcanoes, their distribution regularities and genesis: Communication 1. Mud volcanic provinces and morphology of mud volcanoes. Lithology and Mineral Resources, 37 (3): 197-209. Kite, E.S., Hovius, N., Hiller, J.K., Besserer, J., 2007. Candidate mud volcanoes in the northern plains of Mars. Eos Trans. AGU 88 (52) Fall Meet. Suppl., Abstract V13B-1346. Knapmeyer, M., Oberst, J., Hauber, E., Waehlisch, M., Deuchler, C., Wagner, R., 2006. Working models for spatial distribution and level of Mars’ seismicity. J. Geophys. Res. 111, E11006. Komar, P.D., 1990. Mud volcanoes on Mars. NASA Tech. Memo. 4300, 539–541. Kopf, A.J., 2002. Significance of mud volcanism. Rev. Geophys. 40 (2). Langevin, Y., Poulet, F., Bibring, J., Gondet, B., 2005. Sulfates in the north polar region of Mars detected by OMEGA/Mars Express. Science 307, 1584–1586. Lucchitta, B.K., 1981. Mars and Earth: comparison of cold-climate features. Icarus 45, 264–303. MacKinnon, D.J., Tanaka, K.L., 1989. The impacted Martian crust: structure, hydrology, and some geologic implications. J. Geophys. Res. 94, 17,359– 17,370. Mazzini, A., Svensen, H., Planke, S., Guliyev, I., Akhmanov, G.G., Fallik, T., Banks, D., 2009. When mud volcanoes sleep: insight from seep geochemistry at the Dashgil mud volcano, Azerbaijan. Mar. Petrol. Geol., doi:10.1016/ j.marpetgeo.2008.11.003. Mazzini, A., Svensen, H., Akhmanov, G.G., Aloisi, G., Planke, S., Malthe-Sørenssen, A., Istadi, B., 2007. Triggering and dynamic evolution of LUIS mud volcano, Indonesia. Earth Planet. Sci. Lett., doi:10.1016/j.epsl.2007.07.01. McLennan, S.M., Arvidson, R.E., Clark, B.C., Golombeck, M.P., Grotzinger, J.P., Jolliff, B.L., Knoll, A.H., Squyres, S.W., Tosca, N.J., 2007. LPI Contr., Report 1353, abstract #3231. Mellon, M.T., Arvidson, R.E., Marlow, J.J., Phillips, R.J., Asphaug, E., Searls, M.L., Martinez-Alonso, S.E., the HiRISE Team, 2008. Polygonally patterned ground and sorted rocks on Mars as seen by HiRISE: the Phoenix landing site, northern plains, and beyond. Lunar Planet. Sci. XXXIX abstract #1770. Melosh, H.J., 1989. Impact Cratering: A Geologic Process. Oxford University Press, New York, 245 pp. Middleton, G.V., 1973. Johannes Walther’s Law of the correlation of facies. AAPG Bull. 84, 979–988. Mitrofanov, I.G., et al., 2007. Water ice permafrost on Mars: layering structure and subsurface distribution according to HEND/Odyssey and MOLA/MGS data. Geophys. Res. Lett. 34, L18202. Mumma, M.J., Villanueva, G.L., Novak, R.E., Hewagama, T., Bonev, B.P., DiSanti, M.A., Mandell, A.M., Smith, M.D., 2009. Strong release of methane on Mars in northern summer 2003. Sci. Exp. January, doi:10.1126/science/1165243. Nimmo, F., Tanaka, K., 2005. Early crustal evolution of Mars. Annu. Rev. Earth Planet Sci. 33, 133–161, doi:10.1146/annurev.earth.33.092203.122637. Pinheiro, L.M., Ivanov, M.K., Sautkin, A., Akhmanov, G., Magalhães, V.H., Volkonskaya, A., Monteiro, J.H., Somoza, L., Gardner, J., Hamouni, N., Cunha, M.R., 2003. Mud volcanism in the Gulf of Cadiz: results from the TTR-10 cruise. Mar. Geol. 195 (1–4), 131–151. Planke, S., Svensen, H., Hovland, M., Banks, D.A., Jamteit, B., 2003. Mud and fluid migration in active mud volcanoes in Azerbaijan. Geo-Mar. Lett. 23, 258–268. Poulet, F., Bibring, J.P., Mustard, J.F., Gendrin, A., Mangold, N., Langevin, Y., Arvidson, R.E., Gondet, B., Gomez, C., the OMEGA Team, 2005. Phyllosilicates on Mars and implications for early Martian climate. Nature 438, doi:10.1038/ nature04274. Schultz, P.H., Schultz, R.A., Rogers, J., 1982. The structure and evolution of ancient impact basins on Mars. J. Geophys. Res. 87, 9803–9820. Scott, D.H., Carr, M.H., 1978. Geologic map of Mars. USGS Misc. Inv. Ser. Map I-1083 scale 1, 25M. Scott, D.H., Tanaka, K.L., 1986. Geologic map of the western equatorial region of Mars. USGS I-1802-A scale 1, 15M. Skinner Jr., J.A., 2005. Hydraulically-distinct, stratigraphic horizons in the southern margin of the Utopia impact basin, Mars. Eos Trans. AGU 86 (52) Fall Meet. Suppl., Abstract P23A-0180. Skinner Jr., J.A., Tanaka, K.L., 2007. Evidence for and implications of sedimentary diapirism and mud volcanism in the southern Utopia highland–lowland boundary plain, Mars. Icarus 186, 41–47, doi:10.1016/j.icarus.2006.08.013. 1878 J.A. Skinner Jr., A. Mazzini / Marine and Petroleum Geology 26 (2009) 1866–1878 Skinner Jr., J.A., Skinner, L.A., Kargel, J.S., 2007. Re-assessment of hydrovolcanismbased resurfacing within the Galaxias Fossae region of Mars. Lunar Planet. Sci. XXXVIII abstract #1998. Sleep, N.H., 2000. Evolution of the mode of convection within terrestrial planets. J. Geophys. Res. 105, 17,563–17,578. Spudis, P.D., 1993. The Geology of Multi-Ring Impact Basins. Cambridge University Press. Svensen, H., Planke, S., Malthe-Sørenssen, A., Jamtveit, B., Myklebust, R., Eidem, T., Rey, S.S., 2004. Release of methane from a volcanic basin as a mechanism for initial Eocene global warming. Nature 429, 542–545. Svensen, H., Gisler, G., Polteau, S., Mazzini, A., Planke, S., 2007. Hydrothermal vent complexes and the search of extra-terrestrial water. Lunar Planet. Sci. XXXVIII abstract #2268. Tanaka, K.L., 1986. The stratigraphy of Mars. J. Geophys. Res. 91, E139–E158. Tanaka, K.L., 1997. Sedimentary history and mass flow structures of Chryse and Acidalia Planitiae. Mars J. Geophys. Res. 102, 4131–4150. Tanaka, K.L., 2005. Geology and insolation-driven climatic history of Amazonian north polar materials on Mars. Nature 437, 991–994. Tanaka, K.L., Rodriguez, J.A.P., Skinner Jr., J.A., Bourke, M.C., Fortezzo, C.M., Herkenhoff, K.E., Kolb, E.J., Okubo, C.H., 2008. North polar region of Mars: advances in stratigraphy, structure, and erosional modification. Icarus 196, 318–358. Tanaka, K.L., Skinner Jr., J.A., Hare, T.M., Joyal, T., Wenker, A., 2003a. Resurfacing history of the northern plains of Mars based on geologic mapping of Mars Global Surveyor data. J. Geophys. Res. 108 (E4), doi:10.1029/2002JE001908. Tanaka, K.L., Carr, M.H., Skinner Jr., J.A., Gilmore, M.S., 2003b. Geology of the MER 2003 ‘‘Elysium’’ candidate landing site in southeastern Utopia Planitia, Mars. J. Geophys. Res. 108 (E12), doi:10.1029/2003JE002054. Tanaka, K.L., Skinner Jr., J.A., Hare, T.M., 2005. Geologic map of the northern plains of Mars. USGS Sci. Inv. Map 2888 scale 1 15,000,000. Wilson, L., Mouginis-Mark, P.J., 2003. Phreatomagmatic explosive origin of Hrad Vallis, Mars. J. Geophys. Res. 108 (E8). Watters, T.R., 1993. Compressional tectonism on Mars. J. Geophys. Res. 98, 17,049–17,060. Wyatt, M.B., McSween, H.Y., Tanaka, K.L., Head III, J.W., 2004. Global geologic context for subsurface alteration on Mars. Geology 32 (8), 645–648.