WATER QUALITY ASSESSMENT OF PRAIRIE CREEK RESERVOIR TRIBUTARIES IN DELAWARE COUNTY, INDIANA A THESIS SUBMITTED TO THE GRADUATE SCHOOL IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE MASTER OF SCIENCE BY JEREMY D. FERGUSON Committee Approval: ___________________________________________________ Committee Chairperson ____________ Date ___________________________________________________ Committee Member ____________ Date ___________________________________________________ Committee Member ____________ Date Departmental Approval: ___________________________________________________ Departmental Chairperson ____________ Date ___________________________________________________ Dean of Graduate School ____________ Date BALL STATE UNIVERSITY MUNCIE, INDIANA JULY 2015 WATER QUALITY ASSESSMENT OF PRAIRIE CREEK RESERVOIR TRIBUTARIES IN DELAWARE COUNTY, INDIANA A THESIS SUBMITTED TO THE GRADUATE SCHOOL IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE MASTER OF SCIENCE BY JEREMY D. FERGUSON DR. JOHN PICHTEL - ADVISOR BALL STATE UNIVERSITY MUNCIE, INDIANA JULY 2015 ABSTRACT THESIS: Water Quality Assessment of Prairie Creek Tributaries in Delaware County, Indiana STUDENT: Jeremy D. Ferguson DEGREE: Master of Science College: Sciences and Humanities Date: July 2015 PAGES: 247 Prairie Creek Reservoir was located in east-central Indiana within an agricultural watershed. The reservoir served as a secondary source of drinking water for the city of Muncie and provided various recreational amenities. Previous research had focused on water quality in the reservoir, and land management decisions were performed based on those studies. The current study was conducted to obtain baseline physical and chemical data on the five major tributaries of Prairie Creek Reservoir, and to determine how agricultural land use impacted water quality via tributary sub-watersheds. Water temperature, dissolved oxygen and pH were measured over the course of 133 days; additionally, concentrations of nitrate, ammonium, and phosphorus species were analyzed. Discharge was measured using a Flowtracker®. Dissolved oxygen concentrations were below Indiana Administrative Code (IAC) guidelines; total phosphorus and particulate phosphorus significantly differed between several tributaries; whereas total nitrogen and nitrate concentrations did not significantly differ, which indicated consistent nitrogen concentrations throughout the watershed. Shave Tail Creek produced the largest nutrient load per kg/km2/yr.; nevertheless, Carmichael Ditch was ranked the worst tributary among the other sampling locations in iii terms of overall water quality. Best management practices should be implemented at Carmichael Ditch and Shave Tail Creek to sustain reservoir water quality. ACKNOWLEDGEMENTS An overwhelming thanks goes out to my committee chair, Dr. John Pichtel, for his emotional, social, and academic support and his knowledge, inspiration, and his fervent supervision. It was a pleasure working with him on various challenges. Many thanks to my committee members, Drs. Amy Gregg and Dr. Lee Florea, for their guidance and creativity. I cannot express the importance of their involvement in my academic career. I also want to thank my advisor, Dr. Jarmila Popovicova for giving me the opportunity to work on this thesis. The Department of Natural Resources, Mr. Stan Ross, and Ms. Karee Buffin are acknowledged for their technical and administrative assistance. I also thank them for their moral support when things got rough. Thanks to my wife, Jessica, for her unwavering faith, unending courage, inspiration, and being there through the most difficult times in my life. There are no truer words to explain how grateful I am. Thanks to my parents, Daryl and Judy; brothers, Justin and Brandon; sister, Amanda; and my cousin and his wife, Kenneth and Erica Miller for all their support. Finally, I want to thank some great friends that were here emotionally and spiritually; Dr. Kiev Gracias, Dr. Chuck McKinney, Zoe Payne, and Chris Krieg. iv TABLE OF CONTENTS Final Approval Acceptance Form i ABSTRACT............................................................................................................... ii ACKNOWLEDGEMENTS……………………………………………………….. iii List of Tables……………………………………………………………………….. vi List of Figures………………………………………………………………………. vii List of Appendices………………………………………………………………….. viii EXPLANATION OF FORMAT…………………………………………………... xii CHAPTER 1: Review of Literature………………………………………………. 1 1.1 Introduction……………………………………………………………………… 1 1.2 Literature Review………………………………………………………………... 2 1.2.1 U.S. History and Policies Relating to Water Use…………………………………………………………………… 2 1.2.2 U.S. Surface Water Quality Status and Issues………………………… 3 1.2.3 Indiana Surface Water Quality Status and Issues……………………... 7 1.2.4 Eutrophication…………………………………………………………. 7 1.2.5 Nutrients……………………………………………………………….. 9 1.2.5.1 Nitrogen……………………………………………………... 9 1.2.5.1.1. Drinking Water Standards for Nitrogen and Human Health Concerns……………………….…….. 14 1.2.5.2 Phosphorus…………………………………………………... 15 1.2.6 Discharge……………………………………………………………… 17 1.2.7 Mass Balance……………………………………………………….…. 18 1.2.8 Previous Studies and the Current Study………………….................... 19 1.2.8.1 Prairie Creek Reservoir…………………………………..... 19 1.2.8.2 Project Over view…………………………………………... 24 1.2.8.1 Outfall…………………………………………………….... 26 v 1.2.8.2 Carmichael Ditch…………………………………………... 26 1.2.8.3 Shave Tail Creek…………………………………………… 26 1.2.8.4 Huffman Ditch……………………………………………… 27 1.2.8.5 Cemetery Run…………………………………….………… 27 1.2.8.6 Cecil Ditch…………………………………………………. 27 1.2.8.7 Field and Lab Procedures………………………………….. 28 1.2.8.8 Data………………………………………………………… 29 1.3 Literature Cited...………………………………………………………………… 30 CHAPTER 2: Technical Paper……………………………………………………. 38 2.1 ABSTRACT……………………………………………………………………... 38 2.2 Introduction……………………………………………………………………… 39 2.3 Experimental Methods…………………………………………………………… 44 2.3.1 Study Location…………………………………………………………. 44 2.3.2. Sampling and analysis…………………………………………………. 45 2.3.3 Ranking tributaries……………………………………………………... 46 2.4 Results and Discussion…………………………………………………………… 48 2.4.1 Discharge……………………………………………………………….. 48 2.4.2 Chemical Characteristics…………..……………………………………. 50 2.4.3 Nutrients………………………………………………………………... 55 2.4.4 Tributary Comparison………………………………………………….. 62 2.4.5 Correlations and Nutrient Loads……………………………………….. 65 2.4.6 Ranking and Best Management Practices……………………………... 66 2.5 Literature Cited ………………………………………………………………….. 68 CHAPTER 3: Management Recommendations and Suggestions for Future Research.................................……………………………………………….. 72 3.3 Literature Cited…………………………………………………………………… 77 ………………………………………………………………………… 78 Appendices vi LIST OF TABLES Table 1.1. Major crops growing in the United States ……………………………… 5 Table 2.1. Tributary sub-watershed characteristics of Prairie Creek Reservoir, IN.…………………………………………………………………………………… 41 Table 2.2. Discharge measured at Prairie Creek Reservoir tributaries in 2014 (June to October)……………………………………………………………. 49 Table 2.3. Chemical parameters measured at Prairie Creek Reservoir tributaries in 2014 (June through October)……………………………………………... 51 Table 2.4. Nutrient concentrations measured at Prairie Creek Reservoir Tributaries. 53 Table 2.5. Nutrient loads for each sampling location in Prairie Creek Watershed (kg/yr.)……………………………………………………………… 62 Table 2.6. Ranking of tributaries and outfall based on parameter results……………… 65 vii LIST OF FIGURES Figure 1.1. Nitrate ion concentrations………………………………………………... 12 Figure 1.2. Contamination risks of shallow ground water (< 100 ft. deep)…………… 13 Figure 1.3. Location for Prairie Creek Reservoir …………………………………...... 22 Figure 1.4. Illustrates sub-watersheds, and sampling locations……………………… 25 Figure 2.1 Prairie Creek Reservoir, Tributary sub-watershed, and sampling locations. 43 Figure 2.2 Concentrations for nitrogen species in the five tributaries and outfall. ‘+’ indicates a significant difference among paired tributaries………………….. 56 Figure 2.3 Concentrations of phosphorus species. ‘+’ and ‘++’ indicates significant differences among paired tributaries and “*” is for outliers………………….. viii 58 APPENDICES APPENDIX A……………………………………………………………………... . 79 Table 1A. Discharge Measurements for the outfall………………………………. . 79 Table 2A. Discharge Measurements for Carmichael Ditch………………………. . 110 Table 3A. Discharge Measurements for Shave Tail Creek………………………… 128 Table 4A. Discharge Measurements for Huffman Ditch…………………………... 144 Table 5A. Discharge Measurements for Cemetery Run……………………………. 158 Table 6A. Discharge Measurements for Cecil Ditch………………………………. 174 APPENDIX B Table 1B. Nitrate concentrations measured at all sampling locations…………………… 184 APPENDIX C Table 1C. Ammonia concentrations measured at all sampling locations………………. 188 APPENDIX D Table 1D. Total nitrogen concentrations measured for all sampling locations……… 189 APPENDIX E Table 1E. Particulate phosphorus measured for all sampling locations………………… 193 APPENDIX F Table 1F. Soluble orthophosphate measured for all sampling locations……………….. 197 APPENDIX G Table 1G. Total phosphorus measured for all sampling locations……………………. ix 199 APPENDIX H Table 1H. In-situ measurements for pH for all sampling locations…………………… 203 APPENDIX I Table 1I. In-situ measurements for dissolved oxygen for all sampling locations……. 207 APPENDIX J Table 1J. In-situ measurements for temperature for all sampling locations …………. 208 APPENDIX K Table 1K. In-situ measurements for turbidity for all sampling locations……………. 209 APPENDIX L Table 1L. In-situ measurements specific conductivity for all tributaries……………. 209 APPENDIX M Table 1M. Descriptive Statistics for water quality parameters for all tributaries……. 210 APPENDIX N Table 1N. Nutrient loads for all sampling location…………………………………… 216 APPENDIX O Table 1O. Ranking tributaries based on mean results……………………………….. 217 APPENDIX P Table 1P. Spearman’s rho correlation for concentrations of different parameters for each sampling location……………………………………………………….... x 219 APPENDIX Q Table 1Q. Kruskal Wallis ANOVA: comparing nitrate concentrations among sampling Locations………………………………………………………………………. 225 Table 2Q. Kruskal Wallis ANOVA: comparing ammonia concentrations among sampling locations………………………………………………………………………. 226 Table 3Q. Kruskal Wallis ANOVA: comparing discharge concentrations among sampling locations………………………………………………………………………. 227 Table 4Q. Kruskal Wallis ANOVA: comparing total nitrogen concentrations among sampling locations……………………………………………………………. 228 Table 5Q. Kruskal Wallis ANOVA: comparing nitrite concentrations among the sampling locations……………………………………………………………. 229 Table 6Q. Kruskal Wallis ANOVA: comparing particulate orthophosphate concentrations among sampling locations…………………………………………………… 230 Table 7Q. Kruskal Wallis ANOVA: comparing soluble orthophosphate concentrations among sampling locations……………………………………………………………. 231 Table 8Q. Kruskal Wallis ANOVA: comparing total phosphorus concentrations among sampling locations…………………………………………………………… Table 9Q. Kruskal Wallis ANOVA: comparing pH among sampling locations….. 232 233 Table 10Q. Kruskal Wallis ANOVA: comparing dissolved oxygen concentrations among sampling locations………………………………………………………….. 234 Table 11Q. Kruskal Wallis ANOVA: comparing temperature concentrations among sampling locations…………………………………………………………………….. 235 Table 12Q. Kruskal Wallis ANOVA: comparing specific conductivity among sampling locations……………………………………………………………………. 236 Table 13Q. Kruskal Wallis ANOVA: comparing turbidity concentrations among sampling locations……………………………………………………………………. 237 xi APPENDIX R Table 1R. Multiple comparison test for ammonia concentrations for the tributaries… 238 Table 2R. Multiple comparison test for discharge for the tributaries………………… 239 Table 3R. Multiple comparison test for particulate orthophosphate concentrations for the tributaries……………….……………………………………………………… 240 Table 4R. Multiple comparison test for soluble orthophosphate concentrations for the tributaries……………………………………………………………………… 241 Table 5R. Multiple comparison test for specific conductivity for the tributaries…… 242 Table 6R. Multiple comparison test for total phosphorus concentrations for the tributaries……………………………………………………………………… xii 244 EXPLANATION OF FORMAT This thesis consists of three chapters. The first chapter contains an introduction and literature review of the topic; Chapter Two is a technical paper; and Chapter Three includes supplementary information and recommendations for future research. Chapter One addresses surface water and groundwater contamination issues within agricultural systems in the U.S. and specifically in Indiana. It also describes the effects of eutrophication, the importance of nitrogen/phosphorus species, a description of sampling locations used in the reported study, and an overview of the project. Chapter Two has been drafted in the form of a manuscript to be submitted to a refereed scientific journal. An abstract, introduction, experimental methods, and results and discussion are incorporated in this chapter. Chapter Three provides additional information not reported in the technical paper. Management recommendations and future research suggestions for the watershed are included. xiii CHAPTER 1: Review of Literature 1.1 Introduction Lakes and reservoirs offer multiple uses and benefits to humans and the environment; they act as containment basins for drinking water, provide habitat for aquatic and terrestrial organisms, and offer recreational opportunities. It is anticipated that lakes and reservoirs will experience greater pressures in the future due to increasing water scarcity and continued population growth. In order to meet these needs, it is essential to maintain the health and proper function of aquatic ecosystems, which are adversely affected by improper land use and other environmental stresses (e.g., atmospheric deposition of pollutants), resulting in impaired water quality, limited fresh water supply, and restricted aquatic biodiversity. Best management practices (BMPs) must be implemented to sustain healthy aquatic ecosystems, ensure optimum drinking water quality, and provide safe recreational use. Streams and rivers replenish water supplies; however, they also transport nutrients, including those originally intended for agriculture, as well as sediment. By analyzing the chemical properties of water within watersheds, we can understand and evaluate the effects of specific land uses and derive useful information regarding water quality, which can aid in identifying atrisk areas within a watershed. For example, natural and anthropogenic activities in a specific region can contribute high concentrations of nutrients and sediments, thus triggering eutrophication of local water bodies. 1.2 Literature Review 1 Lakes and reservoirs provide numerous important uses such as replenishment of ground water supplies; they also serve as a source of drinking water; help control of flooding; preserve biodiversity; provided wildlife habitat, irrigation water, recreation, and tourism; and support residential living (New Brunswick, 2015; US Geological Survey, 2014). 1.2.1 U.S. History and Policies Relating to Water Use Streams are classified based on environmental niches and locations within a watershed -they may be classified as perennial, intermittent, or ephemeral (US Environmental Protection Agency [US EPA], 2013). Ephemeral streams flow only during precipitation events and lack biological, hydrological, and physical characteristics common to intermittent and perennial streams (North Carolina Department of Environment and Natural Resources [NC DENR], no date). Intermittent streams are characterized by a well-developed channel and flow only during certain periods of the year while perennial streams flow throughout the year (NC DENR, no date). Streams collect overland flow, recharge or discharge groundwater, provide habitat for aquatic organisms and wildlife, and sustain the health of influent water sources e.g., they remove nutrients and reduce suspended solids (US EPA, 2013). Furthermore, oxygenation of moving water may reduce biochemical oxygen demand (BOD). Of all the stream miles assessed by federal agencies, 53% are classified as headwaters, i.e., those located at the farthest distance from a confluence of another stream or a river. Nearly 60% of headwaters flow intermittently (US EPA, 2013). Anthropogenic activities have altered many natural streams and lakes in the United States. For example, agricultural activities, drainage of wetlands, pollutants, and exotic species impart adverse effects on water quality within watersheds (Meyer et al., 2003). In addition, 2 channeling streams can disrupt receiving water bodies, reduce groundwater recharge rates, alter evapotranspiration patterns and rates, displace riparian zones, destabilize extant water bodies, promote flooding in areas not originally prone to flooding, and increase susceptibility to algal blooms (MacKenzie et al., 2011; Meyer et al., 2003). Stream modifications may result in a range of biological impacts. For example, a study in Hawaii found that lower flow regimes restricted the growth of caddis flies and Atyid shrimp (MacKenzie et al., 2011; McIntosh et al., 2003). 1.2.2 U.S. Surface Water Quality Status and Issues In recent decades comprehensive data have been collected in efforts to assess the nation’s water quality (US EPA, 2014). The U.S. Environmental Protection Agency has assessed 43 percent of US lakes and reservoirs; 67.3% of the areas assessed, totaling close to 12 million acres, were found to be impaired for one or more designated uses. The major impairments were primarily due to the presence of mercury, excess nutrients, and polychlorinated biphenyls (PCBs); turbidity; and organic enrichment/oxygen depletion. The likely sources for these pollutants include agriculture, commercial forestry, improper use of lawn care products, and atmospheric deposition, among others (US EPA, 2014). A total of 29.6% of all U.S. rivers and streams have been assessed, of which 53.7%, totaling 560,411 miles, were designated as impaired. A total of 476,351 miles (45.6%) were considered to support designated uses, and 7,559 miles (0.7%) were considered to be at high risk for becoming impaired (US EPA, 2014). The main causes for these impairments are the presence of pathogens, sediment, and nutrients; organic enrichment/oxygen depletion; and contamination by PCBs. Likely contaminant sources included agriculture, channel modification, urban-related runoff/stormwater, atmospheric deposition, and others. 3 The United States has the largest agricultural capacity compared to any country in the world (US EPA, 2013). A total of 1.02 billion acres of land is devoted to agriculture (US EPA, 2013)—408 million acres are in crop production and 613 million acres are used for grazing livestock. U.S. agriculture generates $153 billion in revenue from livestock production and $143 billion worth of crops (corn, soybeans, hay, wheat, cotton, sorghum, and rice) per year (Table 1.1) (US EPA, 2013). The U.S. was the largest producer and exporter of corn and soybean (32% and 50%, respectively) in 2008 (US EPA, 2013; USDA, 2014; 2013). 4 Table 1.1. Major crops grown in the United States in 2011 (excluding root crops, citrus, and vegetables). Harvested Area (million acres) Cash Receipts from Sales ($ billion) 84 63.9 Soybeans 73.8 37.6 Hay 55.7 6.7 Wheat 45.7 14.6 Cotton 9.5 8.3 Sorghum (grain) 3.9 1.3 Rice 2.6 2.9 Crop Corn (grain) Source: US Environmental Protection Agency. 2015. Ag 101: Major Crops Grown in the United States. (Accessed 12 January 2015). 5 Agriculture is the largest consumer of water in the U.S. and accounts for 80% (90% in Western States) of all water usage (USDA, 2013). Water quality in irrigation systems varies greatly in terms of concentrations of trace elements and minerals which influence water conductivity (Fipps, 2013; UN FAO, n.d.). A primary concern regarding irrigation water quality is salinity, i.e., salt concentrations that can retard or prevent crop growth (Fipps, 2013; Ongley, 1996). Salinity originates from the weathering of rocks and soils over which water flows. As a result of using even slightly saline water for agricultural purposes, salt and other trace minerals accumulate at the surface (Fipps, 2013). A suite of well-established field and laboratory methods can provide data regarding the suitability of water for agriculture. Example methods include determination of total dissolved solids, electrical conductivity, and sodium adsorption ratio (SAR). Based on these criteria soil can be classified as normal, saline, sodic, or saline-sodic (Fipps, 2013). Saline soils have a pH < 8.5, low sodium concentrations and contain various species of sodium-, calcium-, and magnesium sulfates and chlorides. Sodic soils have a pH of 8.5-10, and sodium concentrations are sufficiently high to make soil surfaces impervious (Fipps, 2013). In intensive agriculture, fertilizer applications are necessary to replace macro- and micronutrients in agricultural fields. Modern agriculture is highly dependent on the use of commercial agricultural fertilizers. The most critical nutrient elements for generating high yields of agronomic and other crops are nitrogen, phosphorus and potassium. Many commercial fertilizer formulations are manufactured as salts, e.g., NH4NO3, K3(PO4), KCl. Should these materials enter waterways, they cause ecological damage via eutrophication (see below), as well as via salinity effects when these fertilizer salts dissolve in water (Dowling, 1998). 6 Excessive and/or poorly timed fertilizer application can result in groundwater and surface water pollution (US EPA, 2010). As much as 25% of nitrogen applied to fields is lost through leaching or denitrification (US EPA, 2010). To alleviate such losses, a portion of the required fertilizer rate should be applied during spring and subsequently in limited amounts throughout the growing season. Application of fertilizer during the Fall should be avoided to prevent nitrogen leaching and denitrification. This practice will optimize crop yields and reduce nitrogen losses. Fertilization should occur only after annual soil sampling has been conducted to determine current nutrient concentrations (US EPA, 2010). 1.2.3 Indiana Surface Water Quality Status and Issues Data on Indiana water quality has been compiled for 83.6% of all lakes, reservoirs, and ponds. A total of 95.6%, totaling 231,000 acres, are designated as impaired (US EPA, 2014). The major causes for impairment include the presence of mercury and PCBs, excess nutrients, and excessive algal growth. Sources of pollution include non-point sources, industrial resource extraction, and urban-related runoff/stormwater (US EPA, 2014). A total of 67.2 percent of Indiana streams and rivers have been assessed and 69.1 percent, totaling 16,554 river miles, are designated as impaired. The main causes for impairment include pathogens, PCBs, mercury, organic enrichment/oxygen depletion, and unknown causes. The major sources of these pollutants are animal feeding operations, municipal discharges/sewage and unspecified non-point sources (US EPA, 2014). 1.2.4 Eutrophication Eutrophication is defined as enrichment in the nutrient status of surface water bodies largely due to excessive nitrogen and phosphorous concentrations. These nutrients promote algal 7 and macrophyte production, resulting in an unpleasant odor and an ‘earthy’ taste in drinking water. The eutrophication process can occur naturally; it can occur due to climate change; or it can be a direct consequence of anthropogenic activities that drastically hasten the process (Chislock et al., 2013; USGS, 2013). Eutrophication gradually ‘ages’ water bodies as they become more biologically productive. Human activities accelerate this aging process exponentially (Schindler, 1974). Eutrophication promotes algal growth and anoxic conditions, raises pH levels, causes fish kills, and degrades overall water quality. In extreme cases, eutrophication kills livestock, causes public health risks, and decreases property values (Chislock et al., 2013). Eutrophication is categorized into four trophic states depending on the productivity of the water body: oligotrophic, mesotrophic, eutrophic, and hypereutrophic. Oligotrophic lakes have the lowest nutrient concentrations and experience the lowest biological productivity for algae, macrophytes, and biota higher in the food chain (Rawson, 1956; Lake Access, no date). Oligotrophic lakes tend to have the greatest depths, often greater than 30 meters. The hypolimnion, i.e., the coldest layer of water located at the bottom of the lake, may remain well-oxygenated compared to other classes of lakes (Rawson, 1956). Mesotrophic lakes have parameters similar to those of oligotrophic and eutrophic lakes; however, mesotrophic lakes have depths between 10 to 30 meters and experience nearly complete oxygen depletion of the hypolimnion (Lake Access, no date). Eutrophic and hypereutrophic lakes tend to have higher nutrient concentrations and biological productivity of algae and macrophytes and are shallower than the other classes of lakes (Rawson, 1956). Extensive research is required to categorize streams and rivers into trophic states (Dodds, 2006). A stream condition index is used to compare biological conditions of a stream to some 8 reference condition, for example a stream not impaired but occurring in a similar region (Green et al., 2000). Commercial fertilizers may impart a major effect on a stream or lake trophic states and are the largest source of nitrogen and phosphorus in freshwater ecosystems. Midwestern states input from 10,000 - 40,000 lbs/m2 of nitrogen and from 340 - 2,700 lbs/m2 phosphorus annually (Caskey et al., 2013). In the White River, Indiana, fertilizers contribute 57,000 tons of total nitrogen -- 1,200 tons of ammonia and 40,000 tons as nitrate; and 2,900 tons of phosphorus in streams annually (Martin, 1996). In 2010, Aaron Chalfant Farms (Randolph County, IN) was declared responsible for killing over 107,000 fish as a result of fertilizing fields during a wet season in June. The excessive nutrient runoff entered Bear Creek and the Mississenewa River and adversely affected downstream ecosystems (StarPress, 2012). Land use directly impacts concentrations of nutrients in rivers and streams. A watershed management plan was assembled to prioritize watershed concerns for Geist Reservoir and the Upper Fall Creek in Indianapolis (White River Watershed Alliance, 2011). A major concern for Geist Reservoir was the occurrence of blue-green algae due to excessive quantities of nutrients from runoff. The input streams, i.e., Honey Creek, Flatfork Creek, Sly Fork, and Thorpe Creek, contained higher than expected nutrient concentrations for nitrate + nitrite and total phosphorus, which promoted eutrophication within Eagle Creek and Geist Reservoir (IDEM, 2005). To improve water quality it was necessary to filter nutrients from runoff, construct stream buffers and artificial wetlands, remove debris, restrict livestock access to creeks and reservoirs, ban phosphorous from certain household products, and regulate nitrogen and phosphorus fertilizer usage (Upper White River Watershed Alliance, 2011; IDEM, 2005). 1.2.5 NUTRIENTS 9 1.2.5.1 Nitrogen Nitrogen is an essential macronutrient for plant and animal nutrition. Nitrogen forms that are readily used by plants include nitrate (NO3-), nitrite (NO2-), and ammonium (NH4+) (Ward, 1995). Nitrogen is an essential macronutrient for all biota – it is necessary for forming nucleotides, i.e., a constituent of the nucleic acids deoxyribonucleic acid (DNA) and ribonucleic acid (RNA), as well as proteins (Raven et al., 2008). Nitrogen in proteins occurs in amino groups where nitrogen is bonded with hydrogen as (-NH2). Proteins have major functions in organisms such as enzyme catalysis, immunity/defense, transport of biomolecules, support, motion, regulation, and storage (Raven et al., 2008). Nitrogen enrichment of soils and water bodies occurs from multiple sources and includes agricultural fertilizers, sewage, and animal manure (USGS, 2014). Improper usage of nitrogenrich fertilizer has increased significantly in the Mississippi River Basin over the past 25 years (Goolsby and Battaglin, 1995). The nitrogen concentration in the Mississippi River has increased four times over that of pre-industrial times (Anderson, 2012). The global nitrogen cycle is predominately controlled by bacteria that consume and produce nitrogen compounds via mineralization, ammonification, nitrification, denitrification, and nitrogen fixation (Ward, 1995). These organisms obtain nitrogen via atmospheric deposition of nitrite and nitrate, and also as N2 gas. The former N compounds contribute 3 million tons of nitrogen into U.S. water bodies annually (USGS, 2014). Figure 1.1 illustrates nitrate ion concentrations throughout the U.S. resulting from atmospheric deposition (USGS, 2014). 10 Nitrates are produced via nitrification. In this process, aerobic nitrifying bacteria convert ammonia to nitrite, and nitrite to nitrate (US EPA, 2002; Ward, 1995). The reactions are as follows: 1. 2 NH4+ + 3 O2 → 2 NO2− + 2 H2O + 4 H+ 2. 2 NO2− + O2 → 2 NO3− − 2 − 3. NH3 + O2 → NO2 + 3H + 2e − + − 1 3 − 4. NO2 + H2O → NO3 + 2H + 2e + 4 Nitrification can reduce pH and alkalinity, water’s ability to neutralize acids and resist pH change, thus affecting water quality. In drinking water, the nascent acids can cause corrosion of pipes and damage to concrete structures (US EPA, 2002). Denitrification is the process where, under anoxic conditions, nitrates are reduced to nitrites, and nitrites to ammonia and/or N2 gas (Ward, 1996): NO3− → NO2− → NO + N2O → N2 (g) 5 The complete denitrification process can be expressed as: 2 NO3− + 10 e− + 12 H+ → N2 + 6 H2O 6 Nitrogen compounds, specifically nitrates, are highly soluble and mobile in water; therefore, leaching is a critical problem for shallow groundwater wells (Naidenko et al., 2012). Nearly 50% of U.S. citizens obtain their drinking water from underground sources such as wells and aquifers (Bernard et al., 2014). Nearly 39% of U.S. public water supplies originate from underground sources. Nitrate levels in shallow wells in agricultural fields have the highest concentrations of nitrate compared to all other wells, with concentrations often exceeding drinking water 11 quality standards of 10 mg/L (Bernard et al., 2014; Naidenko et al., 2012). Figure 1.2 illustrates nitrate contamination risk in the U.S. 12 Figure 1.1. Nitrate ion concentrations in water caused by atmospheric deposition (National Atmospheric Deposition Program [NADP], 2014). 13 Figure 1.2. Contamination risks of shallow ground water (< 100 ft. deep). (Bernard et al,. 2014). 14 Ammonium, NH4+, is an inorganic nitrogen compound that is readily absorbed by plants and algae. Common chemical forms are the ammonium ion and un-ionized ammonia, NH3 (US EPA, 2013). Ammonia is rarely detected in non-polluted freshwater; however, it is introduced via nitrogen fixation, in rainfall, lightning strikes, from agricultural runoff, and by decomposition of proteins (US EPA, 2013; Oregon, 2000). The high solubility and mobility of ammonia allow it to percolate through soils and contaminate groundwater (Oregon, 2000). Ammonium is less toxic to biota compared with ammonia. The ammonium ion is positively correlated with photosynthesis and respiration rates in plants (Wurt, 2003). Ammonia (NH3) is positively correlated with water pH and temperature; a 10:1 ratio of ammonia to ammonium correlates to a one pH unit increase; ammonia concentrations double with an increase of 10oC (US EPA, 2013). The proportion of ammonia in water increases as pH increases: NH3 + H2O ↔ NH4+ + OH- 7 Ammonia is usually at its highest concentrations in late afternoon due to the consumption of carbon dioxide required for photosynthesis. Ammonia concentrations can be 63 times higher in late afternoon compared to early morning concentrations, and are > 90% positively correlated with rise in pH (Wurt, 2003). 1.2.5.1.1 Drinking Water Standards for Nitrogen and Human Health Concerns Municipal water treatment plants are required to comply with federal and state standards limiting the presence of various contaminants to ensure safe drinking water for customers (US EPA, 2013). The drinking water Maximum Contaminant Level (MCL) for nitrate is 10 mg/L and for nitrite 1 mg/L. MCLs for ammonia vary with temperature (US EPA, 2013; IAC, 2012). 15 High nitrate and ammonia concentrations in drinking water impart negative effects on human health. Pregnant women, babies, individuals suffering from methemoglobin reductase and gastric acidity issues are at risk (Self, 2014; US EPA, 2013; Benton Franklin, 2002). Methemoglobinemia, i.e., ‘blue baby syndrome’ is linked with high nitrate concentrations in water. Symptoms include shortness of breath, stomach aches, and possible death (Self, 2014; US EPA, 2013; Benton Franklin, 2002). 1.2.5.2. Phosphorus — Phosphorus is an essential macronutrient for plants and animals (US EPA, 2012; Raven et al., 2008). Nucleic acids (DNA, RNA) are composed of three specific compounds: a phosphate group, organic nitrogenous base, and a pentose group (Raven et al., 2008). The phosphate group binds with other nucleotides via phosphodiester bonds to construct DNA and RNA. In addition, phosphorus is essential in the structure of phospholipids; it furthermore aids in energy storage (as adenosine triphosphate, ATP) and photosynthesis (Mullins, 2009; Raven, 2008). Plants convert inorganic phosphorus (as the phosphate molecule, PO43-) into organic phosphorus (DNA, ATP, phospholipids, etc.), which is subsequently consumed by other organisms including decomposers (Oram, 2014; US EPA, 2012; Raven et al., 2008). Decomposition of animal and plant biomass by bacteria returns organic P to the inorganic PO43- form. Phosphorous is essential for supporting biological processes in aquatic ecosystems (US EPA, 2012). Natural (non-polluted) freshwater ecosystems are phosphorous-deficient and may experience algal blooms if phosphorous levels reach elevated concentrations (USGS, 2014; US EPA, 2012). Total phosphorus reference levels, i.e., total P concentrations considered the ‘breakpoint’ for algae to bloom, may range from 0.01 to 0.075 milligrams per liter (mg/L) depending on ecoregion (US EPA, 2012; 2002; Dodds and Welch, 2000). 16 Phosphorus is a common element in nature, derived from weathering of minerals such as fluorapatite, Ca5(PO4)3F. In the manufacture of commercial agricultural fertilizers, such minerals are physically and chemically converted to a soluble fertilizer material such as triple superphosphate, Ca(H2PO4)2.H2O (USGS, 2013; Raven et al., 2008). Phosphorus is frequently detected in runoff from agricultural sites affected by manures or fertilizers; in addition, it enters waterways in municipal, domestic, and industrial wastes in sewage (USGS, 2014). Decades ago in the United States, phosphorus entered waterways via domestic use of phosphate-containing detergents. Animal manures may contain several percent phosphorus, depending on the type of livestock being raised. Confined feeding operations (CFOs) which raise poultry or swine contain manure with greater phosphorus concentrations than do cattle operations. Such manures can be land-applied to serve as a fertilizer material on agricultural fields; however, intensive land application of manures must be carefully monitored. Excessive soil phosphorus concentrations can be carried to surface runoff. Furthermore, soil-bound phosphorus may be lost via erosion (Domagalski et al., 2013; Mullin, 2009). Phosphate adsorbs to sediment particulates and reacts with minerals such as iron, aluminum, and calcium to form insoluble compounds (US EPA, 2012; Mullins, 2009). Inorganic phosphorus may be recycled back into the water column due to anthropogenic activity or animal interaction with the environment (e.g., livestock churning the stream bed), wind action and/or due to acidic soil conditions (Domagalski et al., 2013; US EPA, 2012). When bound to iron, aluminum, and organic compounds, phosphorus is typically not mobile (Redmond et al., 2014); however, iron-, aluminum- and organic-bound phosphorus is sensitive to low dissolved oxygen levels and low pH (Redmond et al., 2014; Gray, 2008). Ferric 17 phosphate is insoluble under high dissolved oxygen levels but may be reduced to ferrous phosphate and released into the water column under conditions of low pH and reduced dissolved oxygen concentrations. These conditions can promote internal loading, i.e., reintroduction of nutrients that had previously adhered to sediments into the water column (Søndergaard et al. 2003). An effective means to combat internal phosphorus loading is via aeration, which increases dissolved oxygen concentration and pH while restricting release of phosphorus from sediment particles (Redmond et al. 2014). The reactions involved are as follows: 1. HCO3- → H+ + CO32- 8 2. HCO3- + H+ → H2CO3 9 3. H2CO3 → CO2 + H2O 10 Although phosphorus is an important nutrient in biological processes, it is detrimental to water quality when present in excess concentrations (USGS, 2014; USGS, 2013). Phosphorus has the potential to cause algal blooms and explosive growth of bacteria, and consequently poor water quality, eutrophication, poor aesthetic appeal and unpleasant odors (Redmond et al., 2014; USGS, 2013; US EPA, 2012). Eutrophication caused by excess P has the tendency to lower pH and reduce dissolved oxygen levels and redox potential, thus causing an unfavorable environment for fish and other aquatic biodiversity (Redmond et al. 2014; USGS 2014, 2013; US EPA 2012). 18 1.2.6. Discharge Discharge is defined as the volume of water passing over a designated location for a specified period of time, usually measured in cubic feet per second (ft3/sec) (US EPA, 2012). Discharge changes seasonally; summer months normally experience lower velocities and volumes of water due to lower rates of precipitation and greater evapotranspiration. The lowest flow months in North America are typically August and September (US EPA, 2012). Stream flow is affected by land use, precipitation, and other climatic factors (Ridgeway et al., no date). Stream flow can be used to identify flooding, sediment discharge and long-term trends in water movement, and can be used to indicate watershed changes, i.e., channelizing streams/ditches. Stormwater discharge and runoff can impart negative effects on water quality. These effects occur when precipitation, rain, or snowmelt flows over impervious surfaces (surface water runoff) collecting chemicals, debris, sediments, or other pollutants, and discharges them untreated into receiving bodies of water (US EPA, 2015). Stormwater discharge is harmful to receiving bodies of water due to buildup of solids, oxygen-demanding substances, nitrogen/phosphorus, pathogens, petroleum hydrocarbons, metals, and synthetic organic compounds (US EPA, 2006). These pollutants reduce water quality and adversely affect biological productivity, aesthetics and drinking water. 1.2.7 Mass Balance Calculating mass balance, whether of water volume or nutrient loads, helps to determine the magnitude that sources impart upon water quality in a watershed. Mass balance calculations also aid in empirical/mechanical modeling, provide a basis for tracking water distribution, and can evaluate lake/reservoir response to the contributing watershed (Fetter, 2001; Walker, 1999). 19 A mass balance requires a water budget that includes precipitation, surface water runoff, groundwater input, evapotranspiration rate, discharge inputs and losses, and groundwater outflow. Mass balance calculations may also be applied to nutrient loading in a watershed—the process includes measuring all nutrient load inputs, including sources such as atmospheric deposition (Jain et al., 2007; Fetter, 2001; Walker, 1999). Land use within a watershed has a major impact on mass balance (Jain et al., 2007). A mass balance study was conducted on Lake Michigan to determine spatial and temporal variability and atmospheric deposition of atrazine, total phosphorus and nitrogen (Miller et al., 2000). It was found that atrazine concentrations were significantly higher in atmospheric deposition during the months it was applied to fields, i.e., from April – June. Nutrient concentrations did not significantly differ spatially; however, total nutrient concentrations have decreased for the Lake Michigan watershed between the 1970s – 1990s. A nitrogen mass balance study was conducted on the Mississippi River (Blesh et al., 2013). Surface water leaching from small, but intensively cropped grain farms was found to be the primary cause for hypoxia in the Gulf of Mexico. It was observed that crop rotation and use of legumes as a source of nitrogen decreased nitrogen concentrations entering the Mississippi River compared to fertilizer-rich fields cultivated to corn and soybean (Blesh et al., 2013). Blesh et al. (2013) recommends that farmers reduce nitrogen inputs and increase carbon availability by cultivating and incorporating nitrogen-fixing crops, e.g., legumes, into the soil. 1.2.8 Previous Studies and the Current Study 1.2.8.1 Prairie Creek Reservoir—The Prairie Creek Reservoir is located in Delaware County, Indiana, and constitutes part of the northern watershed of the White River. The dam that created the reservoir was completed in 1959. The reservoir covers 1,252 acres of land; it has a 20 16-mile shoreline, contains 7.2 billion gallons of water, and is located 990 ft. above sea level (Haman, 1964). The reservoir is used as a secondary drinking water source for Muncie, Indiana. It is privately owned by the Indiana American Water Company and is leased and maintained by the Muncie Parks and Recreation Department (UMU, 2015). A 2,300-acre public park is available for recreational activities. The watershed is used for agriculture, residential dwellings and recreation (Figure 1.3). Haman (1964) conducted a study investigating various physical, chemical and biological characteristics of Prairie Creek Reservoir. Water quality parameters analyzed included temperature, secchi disk transparency, pH, dissolved oxygen levels, and plankton levels. The study concluded that the reservoir was a common eutrophic lake. Turnover occurred in the spring and fall, and vertical stratification occurred during summer. Cescon (1997) studied micro-crustacean zooplankton at the reservoir, and compared her findings to other published data for North American Lakes. Temperature, secchi disk transparency, and turbidity were measured. It was concluded that the reservoir was a typical North American eutrophic lake that contained a variety of zooplankton species common to Ecoregion 55. The White River Watershed Project (WRWP) (IDEM, 2004) studied the Prairie Creek Reservoir watershed to obtain baseline information so that informed decisions could be made to reduce pollutant concentrations and to conserve water quality for future generations. The Project monitored seven locations within the watershed; it was concluded that water quality at all locations did not significantly differ between 2005 and 2006. However, ammonia concentrations were the most problematic parameter throughout the Prairie Creek Reservoir watershed due to agricultural runoff and failing septic systems. Low dissolved oxygen concentrations were measured in Huffman Ditch, Cecil Ditch, and Carmichael Ditch (IDEM, 2004). 21 Goward (2004) studied the links between nutrients and pesticides to the land use in the Upper White River Watershed using three different subwatersheds, including Prairie Creek Reservoir Watershed. Samples were collected from 18 locations in three different subwatersheds. It was determined that Prairie Creek Watershed had the second highest ammonia concentration and the lowest nitrate and orthophosphate concentrations compared to Killbuck Creek and Buck Creek Subwatersheds. Prairie Creek Reservoir Watershed is less developed compared to the other two watersheds. It is expected that faulty septic systems and combined sewer overflows contributed to elevated nutrient concentrations in Killbuck and Buck Creek Watersheds. Barnard (2004) studied Escherichia coli in the same three sub-watersheds as part of the White River Watershed Project. Prairie Creek watershed was studied for spatial distribution of E. coli, temperature, dissolved oxygen, and pH. There were six sampling locations: two within the lake, three major tributaries, and the outfall. The study concluded that E. coli concentrations were strongly correlated with land use and tended to increase downstream. Septic systems, confined swine feeding operations, and combined sewer overflow contributed to high levels of E. coli. The highest concentrations of E. coli were found at the public boat launch on the east shore of the reservoir and at the outfall. 22 Figure 1.3. Location for Prairie Creek Reservoir, sub-watersheds, and sampling locations. 23 Matheny (2007) analyzed spatial and temporal variability in sediment interstitial water within Prairie Creek Reservoir. Excess phosphorus concentrations were detected in reservoir sediment, which was expected to contribute to internal loading during anoxic conditions. Nutrient concentrations varied in the hypolimnion due to organic matter decomposition during the sampling period. Total phosphorus concentrations were consistent throughout the reservoir and did not differ spatially; however, concentrations of ammonia, total nitrogen, and nitrates differed among sampling locations. It was concluded that external nutrient loads affected the southern portion of the reservoir more strongly than the central and northern zones. Celi (2008) conducted a water quality assessment of Prairie Creek Reservoir to determine how nutrient concentrations influenced eutrophication. The study also analyzed water quality parameters, determined trophic status, and identified limiting nutrients. Levels of dissolved oxygen, transparency, pH, temperature, chlorophyll a, and nutrients were analyzed. Vertical variations for pH, temperature, and dissolved oxygen were detected between the hypolimnion and epilimnion. It was found that the reservoir experienced anoxic conditions on multiple occasions for about 50% of its depth. Re-oxygenation of the reservoir occurred throughout the sampling period due to the action of strong winds mixing the water. Total nitrogen and total phosphorus concentrations did not significantly differ throughout the sampling period; however, P concentrations differed between the hypolimnion and epilimnion. The reservoir was horizontally homogenous. Internal loading of phosphorous was evident and correlated with anoxic conditions occurring in the hypolimnion. Popovicova (2008) studied Prairie Creek Reservoir from 2005-2006 in order to obtain baseline information for water quality parameters, observe temporal changes, and provide future researchers a basis to continue studies. The reservoir was analyzed for pH, dissolved oxygen, 24 temperature, conductivity, transparency, and concentrations of nitrates, orthophosphate, and chlorophyll a. Weak thermal stratification was observed in mid-June throughout the reservoir, thermal layering of the epilimion, thermocline, and hypolimnion was formed for a short period of time. Turnovers occurred during spring and Fall. Popovicova (2009) studied the effects of thermal and anoxic conditions on dispersal/variability of nutrients in Prairie Creek Reservoir and compared them to Ecoregion 55 reference guidelines. The analysis focused on pH, temperature, dissolved oxygen, alkalinity, transparency, chlorophyll a, and nutrient concentrations. It was concluded that anoxic conditions as well as re-oxygenation occurred in the hypolimnion due to water mixing from strong winds and boat traffic. Internal nutrient loading exacerbated the eutrophic state of the reservoir, causing it to change from eutrophic to hyper-eutrophic. Nitrogen was found to be the limiting nutrient, i.e., the nutrient required for algal blooms, due to high phosphorus loading within the watershed. Best management practices were proposed to reduce internal and external loads of nutrients and included buffer strips, livestock fencing, and constructed wetlands at the reservoir inlets to protect water quality. 1.2.8.2 Project Overview— The goals of the present study were to assess water quality for five major tributaries of Prairie Creek Reservoir and the outfall into the White River; compare tributaries and outflow for nutrients and other water quality parameters; and identify potential watershed risks which may promote eutrophication within the reservoir. The methodology includes: (1) providing baseline data regarding the physical-chemical properties of the tributaries and outfall; (2) quantifying discharge for tributaries and outflow; (3) determining nutrient loads for tributaries and outflow; and (4) identifying problematic areas within the watershed. 25 Figure 1.4. Sampling locations and tributary sub-watersheds for the reported study. 26 Prairie Creek Watershed includes the reservoir and five major tributaries that drain 17 square miles of New Castle Till Plains (IDEM, 2004). The watershed is composed mainly of Crosby and Miamian soil series. Both soils have poor drainage and the topography is classified as gently rolling, containing various small lakes, prairie pothole lakes, and wetlands (IDEM, 2004). Current land use is predominately agriculture (72.2%), green space (18.2%) and residential (6.3%) (IDEM, 2004). The five major tributaries of the watershed are James Huffman Ditch, Cemetery Run, Chalfant/Cecil Ditch, Shave Tail Creek, and Carmichael Ditch. In addition to the tributaries, the Prairie Creek Reservoir outfall was also monitored. Figure 1.4 illustrates the major tributary sub-watersheds. 1.2.8.1 The Outfall — The outfall is 6,133 ft. in length and located north of Prairie Creek Reservoir where it converges with the White River. The riparian area is dominated largely by woody and grassy vegetation providing cover throughout the site. The outfall discharge varies depending on the release of water as controlled by the Indiana American Water Company. 1.2.8.2 Carmichael Ditch — Carmichael Ditch is located northeast of the reservoir. It extends 9,348 ft. in length and drains approximately 1,270 acres of land. The sub-watershed comprises agricultural uses (99.8%), recreation and conservation (0.2%). The riparian zone consists mainly of woody and grassy vegetation. The nearest embankment to the road has been cleared of most woody vegetation, reducing cover and allowing direct sunlight to reach the ditch. This location is affected by algal growth throughout the growing season. During the assessment, discharge of the ditch was noticeably slow to almost nonexistent. 1.2.8.3 Shave Tail Creek — This creek is located due east of the reservoir and extends 24,630 ft. The watershed drains 1,975 acres of land which consists largely of agricultural fields 27 (88%), green space (10%), and residential (2%). The sampling site is west of C.R. 600 E and is located downstream of a cattle farm. During the assessment, cattle had access to the creek just upstream from the sampling point. This location encompasses woody and grassy vegetation downstream of the sampling site. The upstream area lacked riparian coverage. The flow of this creek was not always consistent and may experience backflow from the reservoir. 1. 2.8.4 James Huffman Ditch — This tributary is located southeast of the reservoir and extends 17,506 ft. This sub-watershed covers an area of 1893 acres and consists of agricultural (72%), residential (4%), green space (2%), and other (22%) land uses. The riparian zone is dominated by grassy vegetation with spotty coverage of woody vegetation throughout the ditch. The sampling site was south of C.R. 600 S and was accessible via private property. This stream is narrow, has a rocky bottom, and has a regular flow. 1. 2.8.5 Cemetery Run — This tributary is located south of C.R. 650 S, measures 7,880 ft. in length and drains 400 acres. Sub-watershed land use is largely agricultural (36%), green space (53%), and residential (11%). The riparian zone consists of woody vegetation, which serves to filter runoff from the road. Water tends to pool just before entering the reservoir via a four foot pipe. This tributary is exposed to direct sunlight and contains a muddy bottom. Discharge is inconsistent and is affected by both wind and water level of the reservoir. It has been observed that the reservoir will back flow into the tributary. During the sampling process, high turbidity was observed which may correlate to construction on the north side of the road. 1. 2.8.6 Cecil Ditch — This ditch is located southwest of the reservoir, intersecting a horse trail and the Cardinal Greenway. This tributary is 7,690 ft. in length and drains approximately 768 acres. Land use consists of agricultural (42%), green space (52%), and residential (6%). The sampling site was located north of C.R. 650 S and just north of the horse trail. The riparian zone 28 is largely wooded, providing coverage from direct exposure of sunlight. The tributary floor was largely silt and sand, of sufficient depth to make it difficult to traverse. The embankments had noticeable erosion, possibly contributing to the silty bottom of the stream. 1. 2.8.7 Field and Lab Procedures —Figure 1.4 shows locations which were sampled and monitored on a weekly basis from June 16 through October 26, 2014. Samples were collected from the center of the tributaries, which were accessible from public roads or private properties. A grab sample technique was used to collect water samples, following U.S. Geological Survey procedures (USGS, 2014). Glass containers were filled, sealed and transported on ice to the laboratory and analyzed within 24 hours of sampling. All instruments were calibrated according to manufacturers’ specifications. Laboratory glassware was dosed three times with 10% HCl and rinsed with deionized (DI) water to remove any contaminants that may have adhered to the container. Field rinsing was required when collecting multiple samples using the same instrument to avoid cross-contamination from one stream to the next. A trip blank, lab blank, a duplicate sample, and a standard served as QC samples. Temperature, turbidity, pH, specific conductivity, and dissolved oxygen concentrations were analyzed in-situ using a Hydrolab DS5 Sonde (HACH Hydromet 2011). The Sonde was calibrated according to manufacturer’s specifications every two weeks. Discharge data for all streams were collected from a SONTEK Flow Tracker (SONTEK, San Diego, CA). Discharge measurements were collected every half-foot to one-foot using a measuring tape; velocity was measured from right to left. The ‘60% rule’ was used to obtain maximum velocity measurements – the flow tracker accurately analyzes velocity at 60% of water depth. Total nitrogen concentration was analyzed using the Persulfate Digestion Method 10070; nitrate by the Cadmium Reduction Method 8039; and ammonia by the Salicylate Method 8155 29 (HACH Company, Loveland, CO). Total phosphorus was analyzed by the Acid Persulfate Digestion Method 8190 (HACH); and unfiltered and filtered orthophosphate was measured using the Ascorbic Acid Method 8048 (HACH). A DR/2400 spectrophotometer (HACH) was used to analyze nutrient concentrations in milligrams per liter (mg/L). All methods are either approved or equivalent to current US EPA standards (HACH; EPA Compliant Methods-EPA, no date). 1. 2.8.8 Data Analysis — Data were analyzed using Minitab® software on a Windowsbased PC. A normal probability plot was used to determine normal sampling distribution, which was not met. From there, the Kruskal-Wallis ANOVA test was performed on all parameters to determine significant differences among sampling locations. A multiple comparison analysis was used to determine where a significant difference occurred, i.e., whether it was between two tributaries or a tributary and outfall. A Spearman rho correlation analysis was conducted to determine whether nutrient levels had any correlation with any of the water quality parameters. All analyses were nonparametric due to an abnormal sampling distribution that violates parametric requirements. 30 1.3 Literature Cited Anderson, D., P. Glibert, and J. Burkholder. 2002 Harmful Algal Blooms and Eutrophication: Nutrient Sources, Composition, and Consequences. Estuaries. 25 (4): Pp. 704-726. <http://www.whoi.edu/cms/files/Anderson_etal_2002_Estuaries_29903.pdf>. (Accessed 4 April 2015) Barnard, A.R. 2004. 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(Accessed 9 January 2015). 38 Chapter 2: Technical Paper A WATER QUALITY ASSESSMENT OF FIVE MAJOR TRIBUTARIES AND OUTFALL WITHIN PRAIRIE CREEK WATERSHED IN DELAWARE COUNTY, INDIANA ABSTRACT. Water quality in agricultural watersheds tends to be more significantly impacted by nutrient loading than occurs for other watersheds. Eutrophication, often the consequence of excess nutrient loading, can produce hazardous algal blooms, degrade water quality for public use and for aquatic organisms, and impair various designated uses. The Prairie Creek Reservoir watershed is an agricultural watershed in east-central Indiana. The reservoir functions as a secondary drinking water supply for Muncie, IN, and offers numerous recreational activities. The reservoir is eutrophic and has five major tributaries that drain predominantly agricultural land. There are no published data concerning water quality and nutrient loads from the tributaries to the reservoir. The reported study assessed basic chemical parameters and established baseline information to support future management decisions. Sampling and monitoring occurred weekly from June through October 2014. USGS protocols were followed to obtain outfall/stream discharge data. Discharge, and ammonia and total P concentrations were significantly different (p = 0.05) among the tributaries; the outfall differed in terms of ammonia, particulate P, and total P concentrations. Shave Tail Creek had greatest contributions to the watershed of total N (1692 kg/yr.) and total P (601 kg/yr.). Based on nutrient data, Carmichael Ditch had poorest water quality within the Prairie Creek watershed. Total N contribution of these sub-watersheds to the White 39 River is estimated to be < 1%. It is recommended that future best management practices (BMPs) be implemented on multiple sub-watersheds in the region. Keywords. — Eutrophication, nutrients, monitoring, streams, reservoir INTRODUCTION As of 2014 a total of 43% of all U.S. lakes and reservoirs were classified as impaired for their designated uses; nutrients were listed as the primary factor, and agriculture as the primary source of these impairments (US EPA, 2014). Commercial agricultural fertilizers inadvertently promote biological productivity in water that drains agricultural lands. Fertilizers contribute nearly 57,000 tons of total nitrogen to the White River in Indiana annually (Martin, 1996), and nearly 90 percent of the total N and P loads from the Mississippi River Basin enter the Gulf of Mexico every year (USGS, 1997). Runoff from livestock feedlots also contribute substantial N and P to surface waters. Animal manures may contain 2 - 5% N and P, depending on the type of livestock being raised. Confined feeding operations (CFOs), which raise poultry or swine contain manure with greater N and P concentrations than do cattle operations. Such manures are often applied to serve as a fertilizer material on agricultural fields; however, intensive land application of manures must be carefully monitored. Excessive soil N and P concentrations can be carried to surface runoff. Furthermore, soil-bound P may be lost via erosion (Domagalski et al., 2013; Mullin, 2009). Eutrophication of water bodies, the result of a continuous supply of nutrients entering a body of water, restricts commercial and recreational uses of water sources, reduces drinking water quality due to poor taste and odor, increases sedimentation and algal blooms, lowers or depletes dissolved oxygen (DO) concentrations needed by aquatic species, reduces property values, 40 and increases costs of water treatment for domestic consumption (Redmond et al., 2014; USGS 2014, 2013; Chislock et al., 2013; U.S. EPA, 2012, 2002; Søndergaard et al., 2003; Carpenter, 2005; Dodds and Welch, 2000; Walker, 1983). Water quality in Indiana has degraded between 2002 and 2010; the US Environmental Protection Agency (2015) observed that 86 and 63% of assessed lakes/reservoirs and streams/rivers, respectively, support full body contact; however, only 81 and 79%, respectively, support use for a public water supply. Ecoregion 55, which extends across east-central Ohio through central Indiana, ranked among the worst water quality conditions and levels of eutrophication compared to any other Indiana ecoregion. The main sources of water quality degradation were agricultural and industrial runoff (US EPA, 2014). In those areas most affected by nutrient pollution, BMPs must be implemented to protect water quality (US EPA, 2010; 2006; 2002). 41 Table 2.1. — Tributary sub-watershed characteristics of Prairie Creek Reservoir, IN. Location Stream Length (ft.) Drainage Area (acres) Land Use Percentage of Land Use Outfall 6,133 n/a n/a n/a Carmichael Ditch 9,348 1,277.4 Agriculture 49% Commercial 46% Residential 5% Agriculture 53% Residential 41% Commercial 6% Agriculture 72% Commercial 16% Residential 12% Agriculture 98% Residential 2% Agriculture 100% Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch 24,633 17,506 7,879 7,694 1,975.2 1892.9 399.9 768 42 In Delaware County, Indiana, Prairie Creek Reservoir serves as a secondary source of drinking water for the City of Muncie and provides recreational activities such as boating, fishing, and camping. The reservoir and its surrounding riparian land are owned by the IndianaAmerican Water Company that leases it for recreational purposes to the Muncie Department of Parks and Recreation (Delaware Commission, 2007; Cescon, 1997). The Delaware MuncieMetropolitan Commission developed a Prairie Creek Reservoir Master Plan to address future land development within the watershed, enhance park and reservoir value, and protect water quality (Popovičová 2008; Delaware Commission 2007). In 2012, the City of Muncie renewed the reservoir lease for 100 years (Dick, 2012). The reservoir is significantly affected by agricultural land use and has shown signs of degradation (Popovičová, 2008; Delaware Commission, 2007). Recent studies (Popovičová, 2009; Celi 2008; Goward, 2004; Cescon, 1997) have recorded obvious signs of eutrophication and reduction in DO levels during summer. 43 Figure 2.1. Sampling locations and tributary sub-watersheds in the Prairie Creek Watershed. 44 To prevent further degradation of reservoir water quality, long-term monitoring and implementation of BMPs must be performed within the watershed to reduce non-point source pollution (IDEM, 2004). Previous studies, however, have not conducted monitoring and assessment of reservoir tributaries, which is essential for the implementation of BMPs. Analysis of reservoir tributaries and the reservoir outfall for nitrate, ammonia, total N, particulate P and total P, and chemical parameters such as temperature and DO levels can aid in implementing future land management practices to safeguard reservoir water quality. The reported study is the first to investigate water quality for all five tributaries of the Prairie Creek Reservoir watershed. The objective was to measure and compile current data regarding water quality of the major tributaries in order to support future management decisions. Specific objectives were to: (1) determine water quality of the tributaries and acquire baseline data; (2) determine nutrient loads for each tributary; and (3) determine spatial differences, if any, for nutrient concentrations among the tributaries. 45 EXPERIMENTAL METHODS Study location. — Prairie Creek Watershed, located in Delaware County, Indiana, is classified as gently rolling and contains small lakes, prairie pothole lakes, and wetlands. The watershed is composed mainly of Crosby and Miamian soil series; both soil series have poor drainage. The watershed is dominated by agricultural land use (72%), green space (18%), and residential (6%) (IDEM, 2004). The reservoir has five major tributaries, i.e., Carmichael Ditch, Shave Tail Creek, James Huffman Ditch, Cemetery Run, and Cecil Ditch, draining 17 mi2 of New Castle Till Plains (Table 2.1; Figure 2.1) (Popovičová, 2008; IDEM, 2004). These streams obtain water primarily from groundwater sources and precipitation. Riparian zones are dominated by woody to grassy vegetation. Stream bottoms consist primarily of a silt to gravel substrate; silty bottoms were located in multiple tributaries suggesting bank erosion with streams acting as sinks. Sampling and analysis. — Weekly sampling and monitoring was performed at each tributary and outfall from June through October 2014 (Fig. 2.1). A SONTEK Flow Tracker (SONTEK, San Diego, CA) measured discharge of each stream using US Geological Survey protocols (USGS, 2013). A Hydrolab DS5 Sonde (Hydrolab Inc., Austin, TX) was used to measure pH, temperature, DO, and turbidity in-situ. Water samples for nutrient determination were collected from the center of each tributary using a grab sample technique. Samples were collected in acid-washed glass containers, transported on ice and analyzed within 24 h of collection. Samples were analyzed for nitrate using the Cadmium Reduction Method 8039; ammonia by the Ammonia Salicylate Method 8155; total N by the Persulfate Digestion Method 10070; particulate and soluble orthophosphate by the Ascorbic Acid Method 8048 (Reactive Phos Ver3); and total P by the Acid Persulfate Digestion Method (Hach, 2015). A Hach DR/2400 Spectropho46 tometer (Hach, Inc., Loveland, CO) was used to determine concentrations of each analyte. One field duplicate, one lab blank, a field blank, and a laboratory fortified blank with deionized water were used to verify precision and accuracy of analytical procedures for each sampling event. All statistical analyses were performed using Minitab® 16.2.4 statistical software (Minitab Inc., State College, PA) on a Windows-based PC. The effects of location (fixed factors) for each water quality parameter (dependent variable) were determined by the use of nonparametric statistics including Spearman’s rho, Kruskal-Wallis, and multiple comparisons analysis. The level of statistical significance was set at α = 0.05. Ranking Tributaries. —A stream quality ranking system was established based on mean concentration of nutrient parameters, with scores from 1 (best) to 6 (worst). The final ranking was determined by adding the scores for each nutrient parameter; that tributary having the highest total value was designated as the poorest quality tributary. 47 RESULTS AND DISCUSSION Discharge. — The greatest discharge was measured at the outfall (6.89 ft3/s) (Table 2.2). The Indiana-American Water Company controls the release of water at this location. Discharge varied throughout the sampling period, from 0.42 to 6.89 ft3/sec. It is expected that ground water and precipitation contribute to all tributaries due to the high water table in this watershed (NRCS, 2013). Shave Tail Creek had the highest discharge rate compared to the other tributaries (1.58 ft3/sec) (Table 2.2). Carmichael Ditch had the second highest discharge (1.15 ft3/sec) (Table 2.2), and Cemetery Run had the lowest (0.36 ft3/sec). It was observed that the latter stream experienced reservoir backflow. 48 Table 2.2. — Discharge (CFS) measured at Prairie Creek Reservoir tributaries in 2014 (June to October). Location n Mean St. Dev. Min. Max. Outfall 13 6.89 15.47 0.03 56.65 Carmichael Ditch+ 18 1.15 1.11 0.05 4.2 Shave Tail+ Creek 8 1.58 0.88 1.11 3.74 Huffman Ditch 18 0.66 0.76 0.16 3.2 Cemetery Run+ 17 0.36 0.3 -0.1 0.96 Cecil Ditch+ 17 0.42 0.46 0.15 1.9 + = Significant difference at p < 0.05. 49 Discharge results were affected by rainfall events throughout the study period (Purdue University, 2015). Rainfall for the sampling period was within the second quartile for 1994 – 2014 (NWS, 2014). June was the only month that had a higher mean precipitation (0.23 in.) than average for 1994 – 2014 (0.16 in.). It was expected that nutrient concentrations were lower due to higher discharge rates for this month. July and September mean precipitation for 2014 was 0.10 and 0.08 in, respectively, and was slightly less than mean precipitation for 1994 – 2014 (0.12 and 0.11 in., respectively) and nutrient concentrations were expected to be higher than normal concentrations (NWS, 2014). Chemical Characteristics. —The reservoir outfall had the highest mean temperature (19.9oC) followed by Cemetery Run (17.2oC); the high temperature at the outfall was likely due to the reservoir was exposed to direct sunlight (Table 2.3). Specific conductivity at the outfall was lowest compared to all tributaries (324.4 uS/cm) (Table 2.3); the highest value (777.1 uS/cm) was measured at Cecil Ditch. This tributary, incidentally, had relatively high nitrate concentrations. The outfall had the highest pH (7.6) and DO concentrations (5.69 mg/L). The high DO concentration may be a result of agitation and subsequent aeration of water discharging directly from the reservoir. pH and DO concentrations for this location were lower than those measured by Goward (2004) (7.97 and 9.06 mg/L, respectively). The lower pH and DO concentration measured in 2014 are attributed to decomposition of organic matter that had increased CO2 concentration within the reservoir (Cooke et al., 2005; Jørgensen et al., 2005). 50 Table 2.3. – Chemical parameters measured at Prairie Creek Reservoir tributaries in 2014 (June through October, 2014). Parameter Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch pH 7.63 ± 0.53 6.68 ± 0.26 7.16 ± 0.34 7.42 ± 0.26 7.46 ± 0.33 7.12 ± 0.41 n 9 9 9 9 9 9 Median 7.53 6.69 7.22 7.47 7.51 7.23 Range 7.0 - 8.4 6.16 – 7.0 6.55 - 7.7 6.8 - 7.8 6.93 - 8.1 6.22 - 7.60 DO (mg/L) 5.69 ± 3.66 3.23 ± 2.54* 2.48 ± 2.36* 2.94 ± 1.66* 3.53 ± 3.21* 2.69 ± 2.34* n 9 9 9 9 9 9 Median 5.85 3.17 2.92 3.08 3.64 2.45 Range 0 - 11.22 0 - 6.65 0 - 5.91 0 - 5.23 0 - 10.98 0 - 5.55 Turbidity (NTU) 21.73 ± 12.67 28.28 ± 10.78 20.42 ± 7.4 38.24 ± 44.07 24.39 ± 8.14 20.32 ± 5.71 n 6 7 6 7 7 6 Median 16.35 24.7 22 19.3 28.4 19.2 Range 14.8 - 47.2 18.6 - 49.9 10.5 - 29.7 8.6 - 135.2 8 - 30.3 13.6 - 30 51 Table 2.3. – Continued. Parameter Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Temperature (oC) 19.92 ± 5.29 15.87 ± 3.95 15.73 ± 4.14 16.31 ± 3.19 17.24 ± 5.33 16.12 ± 4.49 n 9 9 9 9 9 9 Median 20.23 16.73 17.92 17.43 18.25 17.18 Range 12.1 - 25.85 10.07 - 20.96 9.8 - 20.12 10.22 - 19.25 8.81 - 25.74 9.37 - 21.29 Specific Conductivity (uS/cm) 324.4 ± 132.6 687.1 ± 116.5 647.4 ± 75.9 665.7 ± 60.0 577.8 ± 162.9 777.1 ± 32.2 n 8 9 8 9 8 7 Median 349.5 690.6 667.3 670.5 643.8 780.8 Range 0.1 - 471.9 410.2 - 814.9 460.8 - 685.5 532.6 - 766.5 339.5 - 754.9 738.7 - 833.6 * = Concentrations are below Indiana Administrative Code (IAC) Standards. 52 Table 2.4. —Nutrient concentrations for Prairie Creek Reservoir tributaries in 2014 (June through October, 2014). Parameters (mg/L) Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Nitrate 0.45 +/- 0.21 1.15 +/- 1.11 0.67 +/- 0.43 1.07 +/- 0.8 0.58 +/- 0.32 1.02 +/- 0.76 n= 15 15 15 15 4 15 Median 0.4 0.7 0.6 0.8 0.55 0.9 Range 0.2 - 0.9 0 - 4.2 0.2 - 1.6 0.2 - 3.2 0.1 - 1.4 0 - 2.7 Ammonia 0.04 +/- 0.05 0.05 +/- 0.02 0.04 +/- 0.06 0.01 +/- 0.02 0.02 +/- 0.02 0.04 +/- 0.03 n= 17 17 17 17 17 17 Median 0.03 0.05 0.02 0 0.03 0.03 Range 0 - 0.14 0 - 0.24 0 - 0.08 0.07 0 - 0.1 Total N 0.66 +/- 0.84 1.61 +/- 1.5 1.2 +/- 1.33 1.44 +/- 1.3 0.68 +/- 1.04 1.55 +/- 1.81 n= 15 15 15 15 14 15 Median 0.2 1.3 0.9 1 0.2 0.9 Range 0 - 2.3 0 - 4.7 0 - 4.4 0-4 0 - 3.6 0 - 5.4 0 - 0.07 53 Cecil Ditch Table 2.4. — Continue. Parameters (mg/L) Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Particulate P 0.01 +/- 0.02 0.03 +/- 0.06 0.01 +/- 0.02 0.02 +/- 0.04 0.00 +/- 0.00 0.01 +/- 0.00 n= 18 18 18 18 18 17 Median 0 0 0 0 0 0 Range 0 - 0.12 0 – 0.15 0 - 0.05 0 - 0.14 0 - 0.01 0 - 0.05 Total P 0.04 +/- 0.06 0.09 +/- 0.09 0.13 +/- 0.15 0.09 +/- 0.08 0.06 +/- 0.07 0.04 +/- 0.05 n= 18 18 18 18 18 18 Median 0 0.06 0.06 0.05 0.05 0.01 Range 0 - 0.19 0 - 0.28 0 - 0.60 0 - 0.22 0 - 0.22 0 - 0.16 54 Cecil Ditch Carmichael Ditch had lowest pH (6.68) and second-highest specific conductivity (687.1 uS/cm), possibly a result of algal productivity and decomposition, and mineralization of detritus; this was also evident for Cecil Ditch that had highest specific conductivity (780.8 uS/cm) (Table 2.3) (Matheny, 2007; Cooke et al., 2005; Jørgensen et al. 2005). Fertilizer runoff likely contributed to high conductivity readings. Water pH and DO concentrations at all locations were lower than those for the Geist Reservoir Watershed in Indianapolis (8.5 mg/L and 7.9 respectively), Buck Creek Watershed (9.85 mg/L and 7.6 respectively), and Killbuck Creek Watershed (7.72 mg/L and 7.2 respectively) (UWRWA, 2011; Goward, 2004). Huffman Ditch had the highest turbidity readings for all Prairie Creek Reservoir tributaries (38.2 NTU); this level was higher than that of the Honey Creek Watershed located east of Middletown (36.8 NTU) and lower than concentrations found in Thorpe Creek Watershed located northeast of McCordsville (43.4 NTU) (UWRWA, 2011). Cecil Ditch had the lowest turbidity (20.3 NTU), which was lower than that of Geist Reservoir Watershed (28.9 NTU); however, these concentrations were higher than those of Foster Branch Watershed located northwest of Pendleton (15.9 NTU) (UWRWA, 2011). Nutrient Concentrations. — Carmichael Ditch had the highest concentrations of total N (1.61 mg/L), nitrate (1.15 mg/L), and ammonia (0.05 mg/L) (Table 2.3); however, ammonia and nitrate concentrations for the sub-watershed (0.095 and 1.4 mg/L, respectively) were lower than concentrations measured a decade earlier (Goward, 2004). Nitrate + nitrite concentrations increased between 2004 – 2011 (1.4 mg/L) (UWRWA, 2011) and again from 2011 - 2014 (Table 2.4). Cecil Ditch had the highest mean concentrations of nitrite (0.78 mg/L) followed by Shave Tail Creek (0.68 mg/L). Atmospheric deposition via precipitation was found to contribute 0.8 55 mg/L of nitrate to the local watershed (NAPD, 2014). Concentrations for nitrate at multiple sampling locations were < 0.8 mg/L in the outfall, Shave Tail Creek, and Cemetery Run (Table 2.4). Nitrite concentrations were highest during warm summer months, generated in stream channels with sediments such as silt, or from nitrate-rich groundwater that discharges to the surface; alternatively, nitrites may be formed via denitrification (USGS, 2011; 2009). According to the Indiana Administrative Code (IAC), concentrations of N species were within acceptable limits; however, the presence of dense algal growth in Carmichael Ditch suggested that IAC limits may be too high. Leaching from surface soil, use of tile drains, bank erosion, and stormwater runoff may have contributed to elevated N and P concentrations (Domagalski et al., 2013; Mullin, 2009). Shave Tail Creek had the highest total P concentration (0.13 mg/L), which may be caused by fertilizer runoff, soil erosion, and agitation of the stream bed by cattle (Goward, 2004). This sub-watershed consisted largely of agricultural fields (88%). Multiple tributaries had similar total P concentrations compared to 2011 data (0.06 mg/L) (UWRWA, 2011). Soluble orthophosphate concentration was highest at Shave Tail Creek (0.1 mg/L) and particulate P was highest at Carmichael Ditch (0.03 mg/L) (Table 2.3). 56 Figure 2.2. Concentrations for N species in the five tributaries and outfall. ‘+’ indicates a significant difference among paired tributaries. 57 Total nitrogen concentrations for tributaries and outfall 0.7 Concentrations (mg/L) 0.6 0.5 0.4 0.3 0.2 0.1 0.0 tfa Ou ll r Ca m ae ich i tc lD h e av h S T re lC i a ek ffm Hu an h tc Di Figure 2.2. Continued. 58 m Ce y er et n Ru C h itc D il ec Figure 2.3. Concentrations of phosphorus species. ‘+’ and ‘++’ indicates significant differences among paired tributaries and “*” is for outliers. 59 Figure 2.3. Continued. 60 Table 2.4. —Nutrient loads for each sampling location in Prairie Creek watershed (kg/yr). Nutrients Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Outfall Tributary Sum Total Total nitrogen 940 1692 849 212 575 4056 4267 Total phosphorus 163 601 167 72 44 709 1046 61 Comparison of Tributary Properties and Indiana Watersheds. — Shave Tail Creek had significantly (p < 0.05) higher discharge, and total P, and NH3 concentrations compared to Carmichael Ditch, Cemetery Run, and Cecil Ditch (Table 2.2; Fig. 2.2). Total P concentrations significantly differed between Carmichael Ditch-Cecil Ditch, and Shave Tail Creek-Cemetery Run and Cecil Ditch (p = 0.01) (Fig. 2.2). Ammonia-N concentrations were significantly different between Carmichael Ditch and Huffman Ditch (p = 0.02) (Fig. 2.2); however, ammonia comprises only a fraction of total N, which did not significantly differ throughout the watershed (p = 0.13) (Fig. 2.2). Prairie Creek Reservoir Watershed had lower concentrations of ammonia and nitrate (0.05 and 1.15 mg/L) (Table 2.4) compared to Buck Creek (0.07 and 2.3 mg/L respectively) and Killbuck Creek (0.14 and 2.4 mg/L respectively) Watersheds (Goward, 2004). Likewise, PCRW tributaries had lower concentrations of nitrate + nitrite compared to the Geist Watershed (8.84 mg/L) (UWRWA, 2011). Soluble orthophosphate concentrations measured 0.08 mg/L each for Carmichael Ditch, Huffman Ditch, and Cecil Ditch in Prairie Creek Reservoir Watershed, which was twice the values of the nearby Buck Creek (0.04 mg/L) but an order of magnitude less than Killbuck Creek (0.75 mg/L) (Goward, 2004). Geist Watershed had higher concentrations of total P (0.2 mg/L) compared to all sub-watersheds in PCRW (Fig. 2.4) (UWRWA, 2011). The PCRW was less developed compared to Buck Creek, Killbuck Creek, and Geist Reservoir watersheds — residential use comprised 15.4, 12.9, and 16.5 %, respectively, compared to 6 % for PCRW (Goward, 2004; UWRWA 2011). Agricultural land use predominated in the PCRW (72%) (Goward, 2004; UWRWA, 2011). PCRW has the highest percentage of green space (19%) compared to the other watersheds (Buck Creek, 13%; Killbuck Creek, 7%; and 62 Geist, 9%). This may account for PCRW having better water quality than the other watersheds (UWRWA, 2011; Goward, 2004). 63 Table 2.5. —Ranking of tributaries and outfall based on parameter results. Parameters Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Nitrate 1 6 3 5 2 4 Ammonia 3 6 3 1 2 3 Total N 1 6 3 4 2 5 Particulate P 1 6 4 5 2 2 Total P 1 3 6 5 3 2 Total: 7 27 19 20 11 16 Rank 1 6 4 5 2 3 64 Correlations and Nutrient Loads. — Concentrations of nitrate-N were strongly correlated with discharge at Carmichael Ditch (r = 0.77). Total P had a moderately positive correlation with discharge at Carmichael Ditch (r = 0.66). Huffman Ditch had a moderate positive correlation for discharge and total P (r = 0.63). These correlations were expected, as nitrate-N is highly soluble in water; furthermore, particulate concentrations often increase in water when discharge increases. The outfall had a moderately negative correlation with ammonia concentration and pH (r = - 0.63) and a strong negative correlation with DO level (r = -0.83). This suggested that the dominant form of ammonia was ammonium (NH4+). Carmichael Ditch had a strongly negative correlation between ammonia and DO (r = - 0.75) which may have been caused by denitrification and respiration of algae throughout the sampling period (Cooke et al., 2005; Jørgensen et al., 2005). The outfall had a strongly positive correlation (r = 0.88) and Huffman Ditch a moderately positive correlation (r = 0.61) for pH and discharge. Higher rates of discharge could incorporate greater quantities of DO, have reduced concentrations of CO2, and increased pH levels and nutrient concentrations within the tributaries (Araoye, 2009). Higher discharge rates were capable of carrying greater quantities of particulates and ions, which resulted in a positive correlation between turbidity and specific conductivity. Comparing the sum total nutrient loads for the tributaries to the outfall, it is evident that Prairie Creek Reservoir is becoming more eutrophic due to influx of total N and P from the watershed (Table 2.6). This study did not establish a water budget for the watershed and cannot determine an accurate mass balance for the reservoir (Fetter, 2001; Walker, 1999); however, it is possible that the reservoir is acting as a nutrient sink for the watershed. The eutrophication of the reservoir could impair aquatic biodiversity and drinking water quality for Muncie. 65 The tributary that contributed the greatest annual nutrient loads was Shave Tail Creek (total N = 1692 kg/yr. and total P = 601 kg/yr.). It was recommended that BMPs be implemented in this sub-watershed (Table 2.4). Prairie Creek Reservoir Watershed contributes < 1% of the total nutrient load within the White River Basin (Martin, 1996). However, data obtained for the White River dates to 1995 and it was likely that nutrient loads have changed since then. Ranking Tributaries and Best Management Practices. — Carmichael Ditch was ranked the worst tributary within the watershed. This suggests that Carmichael Ditch obtained the greatest concentrations of nutrients compared to any other tributary. This effect was possibly due to more agricultural activities occurring in the sub-watershed, or fewer management practices implemented for this sub-watershed that allowed runoff and erosion of agricultural fertilizers to enter the ditch. BMPs that should be implemented in this sub-watershed include soil analysis pre-planting to determine soil N and P concentrations. This would allow for accurate determination of fertilizer application rates (Hartz, 2009; 2006). Another suggested BMP was to use a N fertilization template; monitoring N in soil could provide a basis for determining fertilizer application rates for a specific crop (Hartz, 2006). Given watershed data, a drip irrigation system was suggested to provide optimal results, i.e., uniform application of nutrients throughout the growing season (Hartz, 2009; 2006). The use of cover crops could reduce nutrient loss from soils by rotating shallow-rooted crops with deeprooted crops, which would allow nitrates to re-concentrate in shallower soils (Smuckler et al., 2012; Hartz, 2006). To increase irrigation efficiency, it could be wise to implement a catchment pond constructed with a pump to recycle runoff onto fields, as another option (Smukler et al., 2012). The installation of vegetative buffer strips and constructed wetlands could possibly be the 66 best option for future land management practices due to current bank instability, and having the capability to filter sediment/nutrients from entering the stream (DNR, 2007; US EPA, 2006). EPA (2006) recommended at least a 100-foot buffer strip to efficiently remove 50% of the nutrients that may enter a stream. For a buffer strip to be efficient, EPA (2006) advised an increase of at least 2 ft. of buffer width per 1% slope increase. 67 LITERATURE CITED Araoye, P. A. 2009. Seasonal variation of pH and Dissolved Oxygen Concentrations in Asa Lake Llorin, Nigeria. International Journal of Physical Sciences. 4(5): 271 - 274. http://www.academicjournals.org/article/article1380621785_Araoye.pdf. (Accessed 28 April 2015). Carpenter, S. R. 2005. Eutrophication of Aquatic Ecosystems: Bistability and Soil Phosphorus. PNAS, 102(29): 10002-10005. Madison Wisconsin. http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1177388/pdf/pnas-0503959102.pdf Celi, D. E. 2008. Water Quality Assessment of Prairie Creek Reservoir in Delaware County, Indiana. MS thesis, Ball State University. Muncie, IN. Chislock, M. F., E. Doster, R. A. Zitomer, and A. E. Wilson. 2013. Eutrophication: Causes, Consequences, and Controls in Aquatic Ecosystems. Nature Education Knowledge 4(4): 10. <http://www.nature.com/scitable/knowledge/library/eutrophication-causes-consequences-andcontrols-in-aquatic-102364466>. Cooke, G. D., E.B. Welch, S.A. Peterson, and P.R. Newroth. 2005. Restoration and management of lakes and reservoirs 3rd ed. Pp. 606. CRC Press. Boca Raton, Fl. Delaware Muncie-Metropolitan Plan Commision. 2007. Prairie Creek Reservoir Master Plan. <http://157.91.22.196/watershed/PC_master_plan_docs/Printable%20Versions/Prairie%20Creek %20Master%20Plan%20%28printable%29.pdf>. (Accessed 23 February, 2015) Dick, Gerry. 2012. Muncie Renews Reservoir Lease. Inside Indiana Business. <https://www.insideindianabusiness.com/newsitem.asp?ID=52466>. (Accesed 23 February, 2015) Dodds W.K. and E. B. Welch. 2000. Establishing nutrient criteria in streams. Final Report for The North American Benthological Society, 19(1): 186–196. Manhattan, KS; and Seattle, WA. <http://www.k-state.edu/doddslab/journalarts/dodds%20and%20welch%20jnabs%202000.pdf> Domaglski J. L. and H. Johnson. U.S. Geological Survey (USGS). 2013. Phosphorus and Ground Water: Establishing Links Between Agricultural Use and Transport to Streams. At: http://pubs.usgs.gov/fs/2012/3004/ (Accessed 6 January, 2015). Fetter C. W. 2001. Applied Hydrogeology. 4th ed. Pp. 444-445 Prentice Hall Inc. Upper Saddle River, NJ. Goward, K. J. 2004. Relationship of Nutrients and Pesticides to Landuse Characteristics in Three Subwatersheds of the Upper White River, Indiana. MS thesis, Ball State University. Muncie, IN. 68 Hargreaves, J. A. and C. S. Tucker. 2004. U.S. Department of Agriculture (USDA). Managing Ammonia in Fish Ponds. < http://www2.ca.uky.edu/wkrec/ManagingAmmonia.pdf>. (Accessed 2015 February 20). Hartz T.K. and R.F. Smith 2009. Controlled-release Fertilizer for Vegetable Production: The California Experience: HortTechnology 2022 (19). 20-22. <http://horttech.ashspublications.org/content/19/1/20.full>. Accessed (13 April 2015). Hartz, T.K. 2006. Vegetable Production Best Management Practices to Minimize Nutrient Loss: HortTechnology 16(3): 398-403 IDEM (Indiana Department of Environmental Management). 2004. White River Watershed Project. Indianapolis, Indiana. < http://www.in.gov/idem/nps/files/wmp_whiteriver-upperdelaware_co_00-206t.pdf.> (Accessed 2014 May 7). Jørgensen, S., Loffler, H., Rast, W., and M. Straskraba. 2005. Lake and reservoir Management. Vol. 54, Developments in Water Science, Elsevier Publishers. Pp. 502. Amsterdam. Minnesota Department of Natural Resources (MDNR). 2007. Vegetation Buffer Strips in Agricultural Areas. <http://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=2&ved= 0CCsQFjAB&url=http%3A%2F%2Ffiles.dnr.state.mn.us%2Fpublications%2Fwaters%2Fbuffer _strips.pdf&ei=SFz2VOW1NsyrgwTUyIHIAw&usg=AFQjCNFKDh-o9g288b54d3BZR8065 g3fg&bvm=bv.87269000,d.eXY> (Accessed 3 March 2015). Matheny, S. E. 2007. Nutrient Analysis of Sediment Interstitial Water of the Prairie Creek Reservoir, Indiana. MS thesis, Ball State University. Muncie, IN. Mullins G. 2009. Phosphorus, Agriculture & The Environment. At: https://pubs.ext.vt.edu/424/424-029/424-029_pdf.pdf (Accessed 6 January, 2015). National Atmospheric Deposition Program (NAPD). 2014. Annual NTN Maps by Year. At: http://nadp.sws.uiuc.edu/ntn/annualmapsByYear.aspx#2013. (Acccessed 23 April 2015). Natural Resources Conservation Service (NRCS). 2013. Web Soil Survey. Washington D.C. http://websoilsurvey.sc.egov.usda.gov/App/WebSoilSurvey.aspx (Accessed 13 April 2015). National Weather Service (NWS). 2014. NOWData – NOAA Online Weather Data. Indianapolis, IN. < http://www.weather.gov/climate/xmacis.php?wfo=ind> (Accessed 6 April 2015). Oram, B. 2014. Ammonia in Groundwater, Runoff, and Streams. Water Research Watershed Center. Dallas, PA. http://www.water-research.net/index.php/ammonia-in-groundwater-runoffand-streams. (Accessed 28 April 2015). Popovicova, J. 2008. Water Quality Assessment of Prairie Creek Reservoir in Delaware County, Indiana. Proceedings of the Indiana Academy of Science. 117(2): 124-135 69 Popovicova, J. 2006. Water Quality Assessment of the Prairie Creek Reservoir WRWP. <http://www.whiteriverwatershedproject.org/ PC_master_plan_docs/Printable%20Versions/Appendix%20A%20(printable).pdf>. (18 April 2014). Purdue Agriculture. 2015. National Weather Service Data. West Lafayette, IN. <https://ag.purdue.edu/arp/pac/Pages/DPAC-Weather-Service-Station-Data.aspx> (Accessed April 7, 2015). Redmond M., Dr. M. Schreiber, Z. Munger., and Dr. C Carey. 2014. Release Potential and Mobility of Sediment Phosphorus in a Periodically Oxygenated Reservoir. <http://agroecology.fiu.edu/students/current-students/fccage-fiu/mariah-redmond/redmondpaper-7-31-2014.pdf> Smukler S.M., A.T. O’Green, and L.E. Jackson. 2012. Assessment of best management practices for nutrient cycling: A case study on an organic farm in a Mediterranean-type climate: Journal of Soil and Water Conservation 67(1): 16-31. Søndergaard, M., J. P. Jensen, and E. Jeppesen. 2003. Role of sediment and internal loading of phosphorus in shallow lakes. Final Report for Hydrobiologia, 506-509: 135-145. Silkeborg, Denmark. <http://www.wwwalker.net/pdf/sondergaard_2003.pdf> Upper White River Watershed (UWRWA). 2011. Geist Reservoir/Upper Fall Creek Watershed Management Plan. http://www.in.gov/dnr/fishwild/files/fwGeist_Reservoir_Upper_Fall_Creek_Wtrshd_Mgmt_Plan_Del_Ham_Han_Hen_Mad_Mar_Coun ties_Feb_2011.pdf. (Accessed 28 April 2015). U.S. Environmental Protection Agency (US EPA). 2012a. 5.5 Turbidity. Washington D.C. http://water.epa.gov/type/rsl/monitoring/vms55.cfm US EPA. 2012b. Phosphorus. Washington, D.C. <http://water.epa.gov/type/rsl/monitoring/vms56.cfm>. US EPA. 2002a. Nitrification. Washington, D.C. <http://water.epa.gov/lawsregs/rulesregs/sdwa/tcr/upload/nitrification.pdf>. US EPA. 2002b. Watershed Assessment, Tracking & Environmental Results – U.S. Washington, D.C. <http://iaspub.epa.gov/waters10/attains_state.report_control?p_state=IN&p_cycle2002&p_report_type=A>. U.S. Geological Survey (USGS). 2009. Report as of FY2008 for 2008WI191B: “Occurrence and Generation of Nitrite in Ground and Surface Waters in an Agricultural Watershed”. Washington, D.C. http://water.usgs.gov/wrri/08grants/progress/2008WI191B.pdf > (Accessed 5 May 2015). Walker, W.W. Jr. 1983. Significance of Eutrophication in Water Supply Reservoirs. Journal of American Water Works Association: 38-42. <http://h2o.wwwalker.net/pdf/awwa.pdf>. 70 Walker W. 1997. Mass-Balance Modeling. At: <http://www.wwalker.net/onondaga/mass_bal_1998.pdf>. (Accessed 10 April, 2015). Ward, B. B. 1996. Nitrification and Denitrification: Probing the Nitrogen Cycle in Aquatic Environments. Pp 247-261. In Microbial Ecology. Springer, Verlag, New York. <https://www.princeton.edu/nitrogen/publications/pdfs/Ward_1996_Probing.pdf>. (Accessed 7 January, 2015) 71 CHAPTER 3: MANAGEMENT RECOMMENDATIONS AND SUGGESTIONS FOR FUTURE RESEARCH This thesis was the first to analyze water quality and nutrient loading of the five major tributaries of Prairie Creek Reservoir in order to determine the potential impact of each sub-watershed. This study assisted in identifying which BMPs should be implemented to improve water quality throughout the watershed to the reservoir. Based upon the reported results, it is considered particularly important to implement intensive practices on Shave Tail Creek, as it had the greatest nutrient loads; however, Carmichael Ditch should also be subject to BMPs due to having the highest nutrient concentrations compared to the other tributaries. It was expected that nutrient concentrations in these two sub-watersheds may be have been contributed by extensive agricultural activities drained via tile drainage, septic system failures, and bank erosion/instability due to the removal of riparian zones. Cecil Ditch had the highest specific conductivity and further research is needed to determine its source(s). It is unknown whether the high conductivity may have arisen from dissolved ions from nutrients, the presence of dissolved metals due to groundwater recharge, contamination of brine due to oil rigs (which occur nearby), or contamination caused by surface water runoff from Highway 35. To limit degradation of water quality, it will be necessary to determine the precise sources of pollution within each sub-watershed to better understand what management practices are need to be implemented. Such an analysis was not conducted during this study. However, 72 analyzing the confluences of each tributary can aid in identifying certain areas within the tributary sub-watersheds that contribute the largest nutrient concentrations so that BMPs can be better utilized. It is also important to conduct an analysis of Cecil Ditch to determine sources causing high specific conductivity levels. One suggested BMP involves using manure from selected livestock animals, e.g., cattle, as fertilizer; cattle can better metabolize N and P compared to poultry or swine thus reducing the amounts of nutrients lost via leaching and runoff from agricultural fields (Mullin, 2009). It is essential, however, that livestock and their manures be managed properly so as not to contribute to local water pollution. For example, access of livestock to water bodies must be controlled. One or more tributaries from the current study are affected by direct livestock traffic. In addition, it is necessary to control runoff from barnyards and feedlots. Clean runoff can be diverted to reduce the amount of water that runs through these areas. Some states suggest that roof runoff from barns be diverted away from barnyards and feedlots. This will minimize the volume of runoff enriched with nutrients. The manure-related pollutants that run off barnyards and feedlots can be controlled with filter strips, i.e., grass areas below the barnyards and feedlots, and/or settling basins. Vegetative buffer strips and constructed wetlands could possibly be the best option for future land management practices due to current bank instability; buffer strips have the capability to filter sediment/nutrients from entering the stream, thus reducing turbidity and increasing dissolved oxygen levels (DNR, 2007; US EPA, 2006). EPA (2006) recommends at least a 100-foot buffer strip to efficiently remove fifty percent of the nutrients that may enter the stream. For a buffer strip to be efficient, EPA (2006) advises an increase of at least 2 ft. of width per 1% in- 73 crease in slope. It is also beneficial to replace grassy riparian zones with woody ones to restrict sunlight exposure, thus reducing stream temperatures and increasing DO concentrations. Barnyards and feedlots can be also managed to minimize concentrations of manure. For example, timely cleaning and removal of manure will reduce buildup and retain nutrients. Likewise, pastures can be managed to reduce concentrations of manure. Careful placement of livestock watering facilities and herd management areas and paddock layout can reduce concentrations of manure and associated impact on water bodies. When practical, it is suggested that manures be composted. This will reduce the volume of material requiring land application. Composting converts nutrients into organic forms that are more slowly available to plants when incorporated into soil. The leaching potential of nutrients is reduced when using compost. Composted material has little odor and is suitable for use as a soil amendment in residential areas. Regarding application of commercial fertilizer, it is recommended that farmers within the watershed use soil tests to determine background levels of nutrients and soil pH. Knowing the amount of available nutrients in the soil reduces the need for applying extra nutrients for crop production. Over-application causes potential leaching into groundwater and added expense for crop production. Proper soil pH allows better utilization of soil nutrients. Nutrient application rates must be based on realistic yield goals. Landowners are urged to use crop yield and soil potential information from published county soil survey reports until yield experience data is compiled. Only realistic goals based on recent yield experience or published soil potential information will allow accurate determination of optimum nitrogen and phosphorus application rates for crop production. It is strongly recommended that growers develop and maintain accurate recording systems for crop yield. 74 Farmers and homeowners are encouraged to use split fertilizer applications where possible. Using smaller applications on a more frequent basis will decrease potential for nutrient loss to ground or surface waters. Home lawns, depending on the quality of turf desired, may receive between one and three applications of fertilizer annually with three applications being the maximum for most situations. A good guideline for a three application schedule includes use of a starter type fertilizer in May (1-2-1 ratio), a slow release high nitrogen fertilizer (having a 4-1-2 ratio) in July, and balanced fertilizer (1-1-1 ratio) in September. If a single application is to be applied, the September application is preferred (New Hampshire, 2011). Sources of fertilizer nitrogen can be either readily-available (i.e., water-soluble) or slowrelease. Fertilizer particles may also be coated to provide another means of controlled release of nutrients. Homeowners are encouraged to use slow-release nitrogen sources, which become available to plants gradually. As mentioned above, if highly soluble N sources are used they should be applied in several smaller split applications. Phosphate (P2O5) is not particularly soluble in the soil. Phosphate application on established lawns is usually only needed at low rates. Phosphate should be avoided entirely when soil test results for P are high or when steep slopes might carry particles to nearby surface water. Accurate fertilizer and manure application records and crop yield records should be maintained to help determine proper manure and fertilizer rates. Applying proper rates of manure and fertilizer can minimize risk of manure- and fertilizer-related pollutants to ground and surface waters. Using worksheets and keeping long-term records help predict realistic crop yield goals to plan nutrient application rates. Farmers should plant cover crops on fields after harvesting annual crops. This practice can be used in those situations where a crop is harvested early enough in the growing season to 75 establish a cover crop. The use of cover crops will reduce nutrient loss from soils by rotating shallow-rooted crops with deep-rooted crops; this will allow nitrates to re-concentrate in shallower soils and prevent soil erosion (Smuckler et al., 2012; Hartz, 2006). In addition, wind and water erosion rates are decreased by the cover crop, reducing the potential for nutrient transport to surface water bodies. Some BMPs are more subtle than those suggested above. For example, it is recommended to maintain good soil structure to reduce runoff from areas that receive manure. Maintaining good soil structure will reduce the amount of runoff by increasing infiltration. This will reduce the potential for off-site transport of manure-related contaminants. Aeration of water, although expensive, can aid in increasing DO levels, increase pH, and in turn, restrict P from reentering the water column (Redmond et al. 2014); it can also aid in regulating ammonia-ammonium concentrations that can trigger eutrophication in streams/rivers and lakes/reservoirs (Wurt, 2003). Irrigation using a catchment pond and a pump to recycle runoff onto fields is another possible BMP option (Smukler et al., 2012). Future studies to conduct in the watershed include formulation of a water budget to track water flow throughout the watershed and determine whether the watershed is gaining or losing water. Such data can help in designing a mass budget that can determine an increase/decrease in nutrient concentrations throughout the watershed. This can help determine if the reservoir is acting as a nutrient sink. A water budget can aid in tracking the movements of nutrients throughout the watershed. Thorough soil analysis can aid in determining how well soil retains N and P and whether it has an impact on ground water quality. 76 LITERATURE CITED Goward, K. J. 2004. Relationship of Nutrients and Pesticides to Landuse Characteristics in Three Subwatersheds of the Upper White River, Indiana. MS thesis, Ball State University. Muncie, IN. Hartz, T.K. 2006. Vegetable Production Best Management Practices to Minimize Nutrient Loss: HortTechnology 16(3): 398-403 Hartz T.K. and R.F. Smith 2009. Controlled-release Fertilizer for Vegetable Production: The California Experience: HortTechnology 2022 (19). 20-22. <http://horttech.ashspublications.org/content/19/1/20.full>. Accessed (13 April 2015). Minnesota Department of Natural Resources (MDNR). 2007. Vegetation Buffer Strips in Agricultural Areas. <http://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=2&ved=0CCsQFjAB& url=http%3A%2F%2Ffiles.dnr.state.mn.us%2Fpublications%2Fwaters%2Fbuffer_strips.pdf&ei =SFz2VOW1NsyrgwTUyIHIAw&usg=AFQjCNFKDho9g288bE54d3BZR8065g3fg&bvm=bv.87269000,d.eXY> (Accessed 3 March 2015). Mullins G. 2009. Phosphorus, Agriculture & The Environment. At: https://pubs.ext.vt.edu/424/424-029/424-029_pdf.pdf (Accessed 6 January, 2015). New Hampshire Department of Agriculture, Markets, and Food. 2011. Manual of Best Management Practices (BMPs) for Agriculture in New Hampshire. Concord, NH. Popovicova, J. 2009. Water quality assessment and ecoregional comparison of a reservoir in east central Indiana. Lake and Reservoir Management. 25(2): 155-166. Redmond M., Dr. M. Schreiber, Z. Munger., and Dr. C Carey. 2014. Release Potential and Mobility of Sediment Phosphorus in a Periodically Oxygenated Reservoir. <http://agroecology.fiu.edu/students/current-students/fccage-fiu/mariah-redmond/redmondpaper-7-31-2014.pdf> Smukler S.M., A.T. O’Green, and L.E. Jackson. 2012. Assessment of best management practices for nutrient cycling: A case study on an organic farm in a Mediterranean-type climate: Journal of Soil and Water Conservation 67(1): 16-31. U.S. Environmental Protection Agency (US EPA). 2006. Economic Benefits of Wetlands. <http://water.epa.gov/type/wetlands/outreach/upload/EconomicBenefits.pdf> (Accessed 3 March 2015). US EPA. 2012. Turbidity. Washington D.C. http://water.epa.gov/type/rsl/monitoring/vms55.cfm US EPA. 2012. Phosphorus. Washington, D.C. <http://water.epa.gov/type/rsl/monitoring/vms56.cfm>. 77 Wurt, W.A. 2003. Daily pH Cycle and Ammonia Toxicity. In World Aquaculture, 34 (2). Pp. 20-21. At: <http://www2.ca.uky.edu/wkrec/pH-Ammonia.htm>. (Accessed 9 January 2015). 78 APPENDICES APPENDIX A Table 1A. Discharge Calculations for Dam. Date Location Away from Shore (Ft) Depth Change in Depth Velocity 6/15/2014 ---- ---- ---- ------ 6/22/2014 ---- ---- ---- ------ 7/6/2014 ---- ---- ---- ------ 7/13/2014 ---- ---- ---- ------ 7/20/2014 ---- ---- ---- ------ 7/27/2014 1 0.5 0.3 -0.08 2 0.8 0.48 -0.2 3 1.02 0.61 0.08 4 1.2 0.72 0.09 5 1.3 0.78 0.08 6 1.42 0.85 0.07 7 1.52 1.22 0.16 0.3 0.07 1.26 0.09 0.31 0.12 1.3 0.11 0.32 0.16 1.52 0.1 0.38 0.1 1.52 0.04 0.38 0.1 1.46 0.09 8 1.55 9 1.63 10 1.9 11 1.9 12 1.82 79 13 1.75 0.37 0.07 1.4 0.08 0.35 0 14 1.49 0.88 0.08 15 1.37 0.82 0.09 16 1.3 0.78 0.08 17 1.37 0.82 0.07 18 1.44 0.86 0.06 19 1.49 0.88 0.07 20 1.49 0.88 0.07 24 1.1 0.66 0.08 25 0.98 0.58 0.06 26 0.65 0.39 0.02 1.99 CFS 0.78 ft/s “----“ = no data. 80 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/3/2014 1 0.4 0.24 -0.04 2 0.8 0.48 -0.02 3 0.95 0.57 0 4 1.03 0.62 -0.02 5 1.13 0.65 0 6 1.25 0.75 -0.01 7 1.28 0.77 -0.02 8 1.38 0.89 -0.01 9 1.6 1.28 0.02 0.32 -0.03 1.28 0.02 0.32 -0.03 1.24 0.03 0.31 -0.02 10 11 1.6 1.55 12 1.44 0.86 -0.01 13 1.1 0.66 0.02 14 1.17 0.7 0.01 15 1.05 0.63 0.01 16 1.15 0.69 0.01 17 1.17 0.7 0.02 18 1.3 0.78 0.01 19 1.2 0.72 0 20 1.2 0.72 0.01 21 1.1 0.66 0.01 22 1.1 0.66 0.01 81 23 1 0.6 0.01 24 1 0.6 0.01 25 0.82 0.49 0 26 0.49 0.29 -0.01 .0291 CFS 0.001 ft/s 82 Table 1A. continued Location Away from Date Shore (Ft) 8/10/2014 1 2 3 4 5 6 7 8 9 10 11 1.65 12 1.52 Change in Depth 0.312 0.432 0.54 0.59 0.66 0.72 0.75 0.96 0.99 1.26 0.314 1.32 0.33 1.22 1.4 1.15 1.03 1.03 1.03 1.1 1.1 1.2 1.1 1 0.98 0.8 0.7 0.304 0.84 0.69 0.62 0.62 0.62 0.66 0.66 0.72 0.66 0.6 0.59 0.48 0.42 13 14 15 16 17 18 19 20 21 22 23 24 25 Depth 0.52 0.72 0.9 0.98 1.1 1.2 1.25 1.3 1.35 1.57 0.082 cfs 0 ft/s 83 Velocity -0.01 -0.01 0 0.03 0.03 0 -0.01 0.01 0.03 0.03 -0.02 0.02 -0.02 0.02 -0.02 -0.01 0.01 0.03 0.01 0.01 0 0 0 -0.01 -0.01 -0.01 0 0.03 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/17/2014 1 0.4 0.24 0 2 0.8 0.48 -0.03 3 0.85 0.51 -0.01 4 0.9 0.54 -0.03 5 0.97 0.58 0 6 1.1 0.66 0 7 1.2 0.72 0 8 1.25 0.75 0 9 1.35 0.81 0 10 1.4 0.84 0 11 1.4 0.84 -0.01 12 1.52 1.216 0 0.3 0.03 0.912 0 1.28 -0.01 0.32 0.03 0.96 0 1.34 -0.01 0.33 0.04 1 -0.02 1.24 0 0.31 0.03 0.93 0 1.2 0 0.3 0.02 13 14 15 16 1.6 1.67 1.55 1.5 84 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 0.9 -0.01 17 1.4 0.84 0.01 18 1.2 0.72 0.02 19 1.2 0.72 0 20 1.15 0.69 0.01 21 1.2 0.72 0 22 1.2 0.72 0 23 1.2 0.72 0 24 1.02 0.61 0 25 1 0.6 0 0.156 CFS 0.0017 Ft/s 85 Table 1A. Continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/24/2014 1 0.7 0.42 0.02 2 2.05 1.64 0.24 0.4 0.08 1.23 0.28 1.84 0.53 0.47 0.32 1.4 0.28 2.04 0.65 0.51 0.53 1.53 0.59 2.2 0.72 0.55 0.6 1.65 0.81 2.3 0.91 0.57 0.74 1.72 1 2.36 1.07 1.77 1.15 3 4 5 6 7 2.33 2.55 2.75 2.87 2.95 0.59 8 9 10 3.05 2.15 3.27 86 2.44 1.29 0.61 0.59 1.83 1.07 2.52 1.25 0.62 0.64 1.89 1.15 2.62 1.17 0.065 11 12 13 3.3 3.4 3.45 87 1.96 1.15 2.64 1.04 0.66 0.79 2 0.96 2.72 0.97 0.68 0.72 2.04 0.81 2.76 0.8 0.7 0.65 2.07 0.69 Table 1A. continued Date Location Away from Shore (Ft) 8/24/2014 14 15 16 Depth Change in Depth Velocity 3.45 2.76 0.57 0.7 0.61 2.07 0.48 2.68 0.48 0.67 0.59 2.01 0.46 2.64 0.47 0.65 0.52 3.35 3.3 1.98 17 18 19 20 21 22 3.1 3 3 2.95 3 3 88 2.48 0.54 0.62 0.46 1.86 0.57 2.4 0.57 0.6 0.58 1.8 0.63 2.4 0.59 0.6 0.62 1.8 0.61 2.36 0.57 0.59 0.6 1.77 0.53 2.4 0.58 0.6 0.48 1.8 0.55 2.4 0.54 23 24 25 26 3 2.75 2.75 2.6 89 0.6 0.41 1.8 0.51 2.4 0.54 0.6 0.37 1.8 0.5 2.2 0.56 0.55 0.52 1.65 0.55 2.2 0.68 0.55 0.57 1.65 0.68 2.08 0.75 Table 1A. continued Date Location Away from Shore (Ft) Depth 8/24/2014 27 28 29 2.6 2.1 1.95 Change in Depth Velocity 0.52 0.56 1.56 0.77 2.08 0.8 0.52 0.35 1.56 0.79 1.68 0.81 0.42 0.56 1.26 0.76 1.56 0.94 0.39 0.63 1.17 0.65 30 1.1 0.66 0.88 31 1 0.6 0.31 56.645 CFS 0.68 ft/s 90 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/31/2014 1 0.75 0.45 0.06 2 0.95 0.57 0.14 3 1.25 0.75 0.21 4 1.45 0.87 0.26 5 1.6 1.28 0.47 0.32 0.36 0.96 0.49 1.4 0.52 0.35 0.43 1.05 0.57 1.44 0.54 0.36 0.31 1.08 0.45 1.54 0.63 0.384 0.28 1.15 0.51 1.6 0.51 0.4 0.35 1.2 0.55 1.68 0.55 0.42 0.33 1.26 0.55 1.76 0.44 0.44 0.34 1.32 0.5 6 7 8 9 10 11 1.75 1.8 1.92 2 2.1 2.2 91 12 13 14 15 2.3 2.3 2.3 2.2 92 1.84 0.36 0.46 0.34 1.38 0.39 1.38 0.26 1.38 0.28 1.38 0.28 1.38 0.29 1.38 0.32 1.38 0.26 1.76 0.25 0.44 0.25 1.32 0.27 Table 1A. continued Date Location Away from Shore (Ft) 8/31/2014 16 17 18 19 20 21 22 23 24 Depth Change in Depth Velocity 2.1 1.68 0.25 0.42 0.16 1.26 0.24 1.44 0.28 0.36 0.17 1.08 0.26 1.48 0.28 0.37 0.21 1.11 0.28 1.44 0.24 0.36 0.18 1.08 0.26 1.44 0.24 0.36 0.18 1.08 0.26 1.62 0.22 0.38 0.18 1.14 0.22 1.14 0.22 1.14 0.22 1.14 0.19 1.26 0.21 0.33 0.16 0.99 0.2 1.26 0.18 1.8 1.85 1.8 1.8 1.9 1.9 1.65 1.65 93 1.26 0.14 1.26 0.18 25 1.49 0.89 0.18 26 1.49 0.89 0.18 27 1.2 0.72 0.13 28 0.99 0.59 0.12 29 0.7 0.42 0.09 14.37 CFS 94 0.29 Ft/s Table 1A. continued Date 9/7/2014 Location Away from Shore (Ft) Depth Change in Depth Velocity 1 0.55 0.33 0.03 2 0.8 0.48 0.15 3 1 0.6 0.18 4 1.2 0.72 0.2 5 1.4 0.84 0.21 6 1.49 0.89 0.19 7 1.7 1.36 0.27 0.34 0.17 1.02 0.22 1.36 0.34 0.34 0.17 1.02 0.32 1.36 0.33 0.34 0.26 1.02 0.31 1.44 0.26 0.36 0.23 1.08 0.27 1.6 0.19 0.4 0.19 1.2 0.2 1.6 0.16 0.4 0.19 1.2 0.18 1.68 0.16 8 1.7 9 1.7 10 1.8 11 2 12 2 13 2.1 95 14 1.95 15 1.8 16 1.5 96 0.42 0.17 0.26 0.18 1.56 0.13 0.39 0.11 1.17 0.13 1.44 0.13 0.36 0.08 1.08 0.13 1.2 0.15 0.3 0.06 Table 1A. continued Date Location Away from Shore (Ft) Depth 9/7/2014 17 1.55 18 1.55 19 1.65 20 1.65 21 1.65 Change in Depth Velocity 0.9 0.12 1.24 0.14 0.31 0.04 0.93 0.12 1.24 0.15 0.31 0.06 0.93 0.14 1.32 0.13 0.33 0.05 0.99 0.09 1.32 0.12 0.33 0.08 0.99 0.11 1.32 0.12 0.33 0.07 0.99 0.12 22 1.49 0.89 0.12 23 1.49 0.89 0.13 24 1.4 0.84 0.11 25 1.25 0.75 0.08 26 1 0.6 0.08 27 0.7 0.42 0.06 6.34 CFS 97 0.16 Ft/s 98 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/14/2014 1 0.6 0.36 -0.02 2 0.9 0.54 0.07 3 1.1 0.66 0.12 4 1.25 0.75 0.11 5 1.35 0.79 0.11 6 1.49 0.87 0.09 7 1.49 0.87 0.13 8 1.65 1.32 0.24 0.33 0.12 0.99 0.21 1.36 0.18 0.34 0.17 1.02 0.23 1.44 0.17 0.36 0.18 1.08 0.22 1.44 0.16 0.39 0.15 1.17 0.19 1.6 0.14 0.4 0.14 1.2 0.15 1.6 0.12 0.4 0.14 1.2 0.14 9 1.7 10 1.8 11 1.95 12 2 13 2 99 14 1.85 15 1.7 1.48 0.13 0.37 0.11 1.11 0.1 1.36 0.11 0.34 0.09 1.02 0.12 16 1.48 0.89 0.1 17 1.48 0.89 0.11 18 1.45 0.87 0.11 19 1.6 1.28 0.13 0.32 0.04 0.96 0.11 100 Table 1A. continued Date Location Away from Shore (Ft) 9/14/2014 20 21 Depth Change in Depth Velocity 1.6 1.28 0.12 0.32 0.06 0.96 0.1 1.28 0.11 0.32 0 1.28 0.08 1.6 22 1.49 0.87 0.09 23 1.4 0.84 0.09 24 1.3 0.78 0.1 25 1.2 0.72 0.09 26 1.1 0.66 0.08 27 0.9 0.54 0.9 28 0.78 0.47 0.09 4.765 CFS 101 0.12 Ft/s Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/21/2014 1 0.45 0.27 0 2 0.9 0.54 -0.01 3 0.99 0.59 0.03 4 1.15 0.69 0.04 5 1.3 0.78 0.06 6 1.4 0.84 0.06 7 1.48 0.89 0.09 8 1.55 1.24 0.13 0.31 0.07 0.93 0.11 1.44 0.11 0.36 0.08 1.08 0.11 1.52 0.08 0.38 0.06 1.14 0.08 1.44 0.07 0.36 0.05 1.08 0.07 1.36 0.05 0.34 0.05 1.02 0.04 9 1.8 10 1.9 11 1.8 12 1.7 13 1.3 0.78 0.07 14 1.3 0.78 0.07 15 1.35 0.81 0.07 102 16 1.45 0.87 0.07 17 1.4 0.84 0.06 18 1.45 0.87 0.06 19 1.4 0.84 0.06 20 1.3 0.78 0.05 21 1.2 0.72 0.03 22 1.1 0.66 0.06 23 0.9 0.54 0.05 24 0.8 0.48 0.48 25 0.5 0.3 0.3 1.964 CFS 0.06 Ft/s 103 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/28/2014 1 0.5 0.3 -0.03 2 0.6 0.36 -0.01 3 0.85 0.51 0 4 0.98 0.59 0.02 5 1.1 0.66 0.01 6 1.2 0.72 0.03 7 1.3 0.78 0.02 8 1.4 0.84 0.01 9 1.4 0.84 0.02 10 1.55 1.24 0.03 0.31 -0.01 0.93 0.03 1.32 0 0.33 0 0.99 0 1.32 0.03 0.33 -0.01 0.99 0.02 1.24 0.03 0.31 -0.02 0.93 0.03 11 1.65 12 1.65 13 1.55 14 1.35 0.81 0.02 15 1.1 0.66 0.02 16 1.1 0.66 0.03 17 1.15 0.69 0.04 104 18 1.2 0.72 0 19 1.2 0.72 -0.02 20 1.3 0.78 0.04 21 1.2 0.72 0.04 22 1.1 0.66 0.02 23 1 0.6 0.02 24 1 0.6 0 25 0.9 0.54 -0.01 26 0.6 0.36 -0.02 0.385 CFS 0.01 ft/s 105 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 10/12/2014 1 0.4 0.24 0.01 2 0.6 0.36 -0.03 3 0.8 0.48 -0.04 4 1 0.6 -0.03 5 1.15 0.69 -0.03 6 1.3 0.78 0 7 1.35 0.81 0.03 8 1.4 0.84 0.02 9 1.49 0.89 0.03 10 1.73 1.38 0.03 0.35 0.01 1.04 0.02 1.38 0.02 0.35 0.02 1.04 0.02 1.38 0.03 0.35 -0.01 1.04 0.03 1.2 0.03 0.3 0.01 0.9 0.03 11 1.73 12 1.73 13 1.5 14 1.15 0.69 0.04 15 1.2 0.72 0.04 16 1.2 0.72 0.03 17 1.3 0.78 0.04 106 18 1.35 0.81 0.03 19 1.25 0.75 0.01 20 1.2 0.72 -0.02 21 1.05 0.63 -0.03 22 0.95 0.57 -0.03 23 0.7 0.42 -0.03 24 0.55 0.33 -0.05 0.385 CFS 10/19/2014 0.01 Ft/s 1 0.5 0.3 -0.03 2 0.9 0.54 -0.03 3 0.98 0.59 -0.05 107 Table 1A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 4 1.15 0.69 0.03 5 1.3 0.78 0.04 6 1.4 0.84 0.04 7 1.45 0.87 0.06 8 1.55 1.24 0.07 0.31 0.04 0.93 0.08 1.32 0.08 0.33 0.04 0.99 0.09 1.44 0.08 0.36 0.03 1.08 0.06 1.52 0.07 0.38 0.03 1.14 0.05 1.52 0.07 0.38 0.03 1.14 0.05 1.44 0.07 0.36 0.03 1.08 0.05 1.36 0.06 0.34 0.02 1.02 0.05 9 1.65 10 1.8 11 1.9 12 1.9 13 1.8 14 1.7 108 15 1.3 0.78 0.04 16 1.4 0.84 0.05 17 1.4 0.84 0.03 18 1.49 0.89 0.04 19 1.49 0.89 0.07 20 1.49 0.89 0.04 21 1.4 0.84 0.05 22 1.35 0.81 0.06 23 1.2 0.72 0.04 24 1.1 0.66 0 25 1 0.6 0.01 26 0.7 0.42 -0.03 1.40 CFS 10/26/2014 0.04 Ft/s 1 0.4 109 0.24 0 Table 2A. Discharge Calculations for Carmichael Ditch. Date Location Away from Shore (Ft) Depth Change in Depth Velocity 6/15/2014 0.5 0.65 0.39 0.1 1 0.65 0.39 0.23 1.5 0.6 0.36 0.31 2 0.6 0.36 0.48 2.5 0.65 0.39 0.6 3 0.7 0.42 0.68 3.5 0.7 0.42 0.46 4 0.7 0.42 0.28 4.5 0.7 0.42 0.56 5 0.7 0.42 0.48 5.5 0.6 0.46 0.29 6 0.65 0.39 0.29 6.5 0.55 0.33 0.04 7 0.55 0.33 -0.02 7.5 0.4 0.24 -0.05 1.52 CFS 6/22/2014 0.34 Ft/s 0.5 0.6 0.36 0.17 1 0.6 0.36 0.41 1.5 0.6 0.36 0.56 2 0.6 0.36 0.8 2.5 0.65 0.39 0.76 3 0.65 0.39 0.67 3.5 0.7 0.42 0.66 110 4 0.75 0.45 0.77 4.5 0.75 0.45 0.81 5 0.8 0.48 0.52 5.5 0.8 0.48 0.53 6 0.75 0.45 0.5 6.5 0.75 0.45 0.24 7 0.7 0.42 0.06 7.5 0.7 0.42 0.02 8 0.5 0.3 -0.03 2.573 CFS 0.45 Ft/s 111 Table 2A. Continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 7/6/2014 0.5 0.3 0.18 0.02 1 0.38 0.22 0.05 1.5 0.35 0.21 0.07 2 0.3 0.18 0.09 2.5 0.4 0.24 0.11 3 0.35 0.21 0.11 3.5 0.4 0.24 0.14 4 0.45 0.27 0.21 4.5 0.49 0.294 0.15 5 0.49 0.294 0.14 5.5 0.49 0.294 0.09 6 0.47 0.282 0.09 6.5 0.47 0.282 0.05 7 0.4 0.24 0.03 7.5 0.4 0.24 0.03 8 0.25 0.169 0.02 0.299 CFS 7/13/2014 0.09 ft/s 0.5 0.35 0.21 0 1 0.39 0.23 0.04 1.5 0.35 0.21 0.1 2 0.35 0.21 0.14 2.5 0.35 0.21 0.16 3 0.4 0.24 0.19 112 3.5 0.4 0.24 0.21 4 0.45 0.27 0.2 4.5 0.45 0.27 0.16 5 0.51 0.31 0.16 5.5 0.51 0.31 0.08 6 0.49 0.29 0.06 6.5 0.52 0.31 0.05 7 0.48 0.29 0.03 7.5 0.48 0.29 0.04 8 0.4 0.24 0 8.5 0.3 0.18 0 0.344 CFS 0.09 Ft/s 113 Table 2A. Continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 7/20/2014 1 0.37 0.22 0.05 1.5 0.37 0.22 0.07 2 0.32 0.19 0.09 2.5 0.32 0.19 0.11 3 0.339 0.23 0 3.5 0.4 0.24 0.09 4 0.4 0.24 0.06 4.5 0.45 0.27 0.05 5 0.5 0.3 0.04 5.5 0.48 0.29 0.04 6 0.48 0.29 0.01 6.5 0.48 0.29 0 7 0.48 0.29 0.02 7.5 0.4 0.24 0.1 8 0.4 0.24 0 8.5 0.3 0.18 0 0.128 CFS 7/27/2014 0.04 Ft/s 0.5 0.35 0.21 0.1 1 0.35 0.21 0.17 1.5 0.35 0.21 0.15 2 0.35 0.21 0.14 2.5 0.35 0.21 0.05 3 0.4 0.24 0.07 114 3.5 0.4 0.24 0 4 0.4 0.24 0.05 4.5 0.45 0.243 0 5 0.45 0.243 -0.01 5.5 0.45 0.243 0 6 0.49 0.29 0 6.5 0.49 0.29 0 7 0.49 0.29 0.01 7.5 0.45 0.243 0 8 0.3 0.18 0 0.13 CFS 0.05 Ft/s 115 Table 2A. Continued Date Location Away from Shore (Ft) 8/3/2014 Depth Velocity 0.5 0.4 0.24 0.11 1 0.4 0.24 0.07 1.5 0.4 0.24 0.05 2 0.4 0.24 0 2.5 0.4 0.24 0 3 0.4 0.24 0.01 3.5 0.4 0.24 0 4 0.45 0.27 0 4.5 0.45 0.27 0 5 0.5 0.3 0 5.5 0.5 0.3 0 6 0.5 0.3 0 6.5 0.5 0.3 0.01 7 0.5 0.3 0 7.5 0.5 0.3 0 8 0.4 0.24 0 0.048 CFS 8/10/2014 Change in Depth 0.01 Ft/s 0.5 0.4 0.24 0 1 0.4 0.24 0.02 1.5 0.4 0.24 0.03 2 0.4 0.24 0 2.5 0.4 0.24 0.01 3 0.4 0.24 0.01 3.5 0.4 0.24 0.04 116 4 0.4 0.24 0.02 4.5 0.5 0.3 0.01 5 0.5 0.3 0.01 5.5 0.5 0.3 0.01 6 0.5 0.3 0.01 6.5 0.5 0.3 0 7 0.5 0.3 0.01 7.5 0.4 0.24 0.01 0.4 cfs 117 0.01 ft/s Table 2A. Continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/172014 0.5 0.35 0.21 0 1 0.35 0.21 -0.01 1.5 0.35 0.21 -0.01 2 0.35 0.21 0 2.5 0.35 0.21 0.01 3 0.4 0.24 0.01 3.5 0.4 0.24 0.02 4 0.4 0.24 0.01 4.5 0.4 0.24 0.01 5 0.5 0.3 0.02 5.5 0.5 0.3 0.03 6 0.5 0.3 0.02 6.5 0.42 0.25 0.03 7 0.4 0.24 0.01 7.5 0.4 0.24 0 0.035 CFS 8/24/2014 0.01 Ft/s 1 0.9 0.54 0.63 1.5 0.9 0.54 0.47 2 0.9 0.54 0.52 2.5 0.9 0.54 0.66 3 0.9 0.54 0.87 3.5 0.9 0.54 0.999 4 1 0.6 0.94 118 4.5 1 0.6 1.14 5 1 0.6 0.96 5.5 1 0.6 0.83 6 1.05 0.63 0.85 6.5 1 0.6 0.74 7 1 0.6 0.52 7.5 0.95 0.57 0.31 8 0.9 0.54 0.09 8.5 0.8 0.48 0 5.066 CFS 0.658 Ft/s 119 Table 2A. Continued Date 8/31/2014 Location Away from Shore (Ft) Depth Change in Depth Velocity 0.5 0.3 0.18 0 1 0.3 0.18 0 1.5 0.3 0.18 0.04 2 0.3 0.18 0.03 2.5 0.4 0.24 0.04 3 0.4 0.24 0.05 3.5 0.4 0.24 0.08 4 0.4 0.24 0.09 4.5 0.4 0.24 0.07 5 0.4 0.24 0.07 5.5 0.4 0.24 0.07 6 0.4 0.24 0.04 6.5 0.4 0.24 0.01 7 0.4 0.24 0 0.115 CFS 9/7/2014 0.04 Ft/s 0.5 0.3 0.18 0 1 0.3 0.18 0.01 1.5 0.3 0.18 0.01 2 0.3 0.18 0.03 2.5 0.3 0.18 0.02 3 0.4 0.24 0.02 3.5 0.4 0.24 0.03 4 0.5 0.3 0.06 120 4.5 0.5 0.3 0.05 5 0.5 0.3 0.05 5.5 0.5 0.3 0.03 6 0.5 0.3 0.02 6.5 0.5 0.3 0 0.073 CFS 0.03 Ft/s 121 Table 2A. Continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/14/2014 0.5 0.4 0.24 0 1 0.4 0.24 0 1.5 0.4 0.24 0 2 0.4 0.24 0 2.5 0.45 0.27 0 3 0.45 0.27 0.08 3.5 0.5 0.3 0.24 4 0.5 0.3 0.24 4.5 0.55 0.33 0.24 5 0.55 0.33 0.14 5.5 0.55 0.33 0.03 6 0.5 0.3 0.01 6.5 0.5 0.3 0 0.253 CFS 9/21/2014 0.08 Ft/s 0.5 0.4 0.24 0 1 0.4 0.24 0 1.5 0.4 0.24 0 2 0.4 0.24 0.01 2.5 0.4 0.24 0 3 0.45 0.27 0.07 3.5 0.45 0.27 0.08 4 0.5 0.3 0.14 4.5 0.5 0.3 0.13 122 5 0.5 0.3 0.01 5.5 0.5 0.3 0 6 0.5 0.3 -0.01 0.101 CFS 0.03 Ft/s 123 Table 2A. Continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/28/2014 0.5 0.3 0.18 0.01 1 0.3 0.18 0.04 1.5 0.35 0.21 0.01 2 0.4 0.24 0.05 2.5 0.35 0.21 0.06 3 0.4 0.24 0 3.5 0.45 0.27 0.04 4 0.45 0.27 0.06 4.5 0.5 0.3 0.04 5 0.5 0.3 0.04 5.5 0.4 0.24 0 0.71 CFS 10/12/2014 0.03 Ft/s 0.5 0.35 0.21 0.02 1 0.35 0.21 0.07 1.5 0.4 0.24 -0.01 2 0.4 0.24 0.06 2.5 0.4 0.24 0.05 3 0.4 0.24 0.05 3.5 0.4 0.24 0.04 4 0.5 0.3 0.03 4.5 0.5 0.3 0.03 5 0.5 0.3 0 5.5 0.5 0.3 0 124 6 0.5 0.3 0 6.5 0.5 0.3 -0.03 0.059 CFS 0.02 Ft/s 125 Table 2A. Continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 10/19/2014 0.5 0.5 0.3 0 1 0.5 0.3 0.05 1.5 0.5 0.3 0.06 2 0.5 0.3 0.05 2.5 0.6 0.36 0.07 3 0.6 0.36 0.04 3.5 0.5 0.3 0.12 4 0.6 0.36 0.19 4.5 0.6 0.36 0.28 5 0.6 0.36 0.26 5.5 0.6 0.36 0.1 6 0.5 0.3 0.05 6.5 0.5 0.3 0.06 7 0.5 0.3 0.03 0.388 CFS 10/26/2014 0.1 Ft/s 0.5 0.4 0.24 0.01 1 0.4 0.24 0 1.5 0.4 0.24 0 2 0.4 0.24 0.05 2.5 0.5 0.3 0.04 3 0.5 0.3 0.01 3.5 0.5 0.3 -0.01 126 4 0.55 0.33 0.08 4.5 0.55 0.33 0.06 5 0.55 0.33 0.16 5.5 0.6 0.36 0.1 6 0.5 0.3 0.05 6.5 0.4 0.24 0 0.149 CFS 0.05 Ft/s 127 Table 3A. Discharge Calculations for Shave Tail Creek. Date Location Away from Shore (Ft) Depth Change in Depth Velocity 6/15/2014 ---- ---- ---- ---- 6/22/2014 ---- ---- ---- ---- 7/6/2014 ---- ---- ---- ---- 7/13/2014 ---- ---- ---- ---- 7/20/2014 ---- ---- ---- ---- 7/27/2014 ---- ---- ---- ---- 8/10/2014 0 2.4 1.92 0.09 0.48 0 2 0.01 0.5 -0.03 1.92 0.01 0.48 -0.03 1.92 0.13 0.48 0.01 1.92 0.13 0.48 0.02 2 0.12 0.5 0.04 2.16 0.11 0.54 0.01 2.32 0.03 0.58 0 2.32 0.1 0.58 -0.01 2.48 0.07 1 2 3 4 5 6 7 8 9 2.5 2.4 2.4 2.4 2.5 2.7 2.9 3.1 3.1 128 10 3 1.284 CFS 0.62 0.06 2.4 0.08 0.6 0.01 0.04 Ft/s “----“ not measured. 129 Table 3A. continued Date Location Away from Shore (Ft) 8/17/2014 0 1 2 3 4 5 6 7 8 Depth Change in Depth Velocity 2.33 1.86 0.07 0.47 0 1.38 0.02 2.04 0.02 0.51 0.02 1.53 0.05 2 0.13 0.5 0.05 1.5 0.14 1.92 0.08 0.48 -0.02 1.44 0.07 1.92 0.07 0.48 0 1.44 0.05 1.98 0.08 0.49 0.04 1.48 0.12 2.2 0.11 0.55 0 1.65 0.07 2.42 0.04 0.61 -0.01 1.82 0.07 2.54 0.1 2.55 2.5 2.4 2.4 2.47 2.75 3.03 3.17 130 9 10 3.01 2.55 3.739 CFS 0.62 -0.02 1.9 0.1 2.46 0.1 0.61 0 1.84 0.13 2 0.1 0.51 0.02 1.53 0.04 0.613 Ft/s 131 Table 3A. continued. Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/31/2014 ---- ---- ---- ---- 9/7/2014 0 1.85 1.48 0.01 0.37 0 1.11 -0.02 1.68 -0.01 0.42 0 1.26 0 1.68 0.06 0.42 -0.01 1.26 0.03 1.6 0.08 0.4 0.06 1.2 0.07 1.64 0.1 0.41 0.05 1.23 0.09 1.68 0.1 0.42 0.02 1.26 0.09 2.24 0.05 0.56 0 1.68 0.03 2.32 0.07 0.58 0.01 1.74 0.06 1 2.1 2 2.1 3 2 4 2.05 5 2.1 6 2.8 7 2.9 132 8 2.9 9 3 10 2.3 1.124 CFS 2.32 0.08 0.58 0.02 1.74 0.07 2.4 0.08 0.6 0.02 1.8 0.06 1.84 0.06 0.46 0 1.38 0.02 0.05 Ft/s “----“ not measured 133 Table 3A. continued Date Location Away from Shore (Ft) 9/14/2014 0 1 2 3 4 5 6 7 8 Depth Change in Depth Velocity 1.75 1.42 -0.01 0.35 -0.01 1.05 0.02 2 0.06 0.5 0.01 1.5 0.05 2 0.09 0.5 -0.01 1.5 0.11 2 0.08 0.5 0.01 1.5 0.07 2 0.04 0.5 0.03 1.5 0.06 2.08 0.04 0.52 0.04 1.56 0.05 2.22 0.09 0.55 0.05 1.65 0.1 2.3 0 0.57 0.03 1.71 0.08 2.38 0.05 2.5 2.5 2.5 2.5 2.6 2.75 2.85 2.95 134 9 10 3.3 2.65 1.341 CFS 0.59 -0.02 1.77 0.03 2.64 0.05 0.66 0 1.98 0.07 2.12 0.06 0.53 0 1.68 0.02 0.041 Ft/s 135 Table 3A. continued Date Location Away from Shore (Ft) 9/21/2014 0 1 2 3 4 5 6 7 8 Depth Change in Depth Velocity 2.2 1.76 -0.01 0.44 -0.01 1.32 0.02 2 -0.1 0.5 0.01 1.5 -0.04 2 0.05 0.5 0.04 1.5 0.05 2 0.1 0.5 0.03 1.5 0.05 2 0.12 0.5 0.09 1.5 0.12 2.08 0.08 0.53 0.06 1.56 0.1 2.44 0.03 0.56 0.04 1.68 0.04 2.44 0 0.56 0.01 1.68 0.06 2.32 -0.02 2.5 2.5 2.5 2.5 2.6 2.8 2.8 2.9 136 9 10 3.1 2.5 1.225 CFS 0.58 0.01 1.74 0.01 2.48 0.07 0.62 0 1.86 0.11 2 0.06 0.5 -0.02 1.5 0.05 0.04 Ft/s 137 Table 3A. continued Date Location Away from Shore (Ft) 10/12/2014 0 1 2 3 4 5 6 7 8 Depth Change in Depth Velocity 2.2 1.76 -0.01 0.44 -0.01 1.32 -0.01 1.96 0.03 0.49 -0.04 1.47 -0.02 1.92 0.09 0.48 0.05 1.44 0.06 1.92 0.06 0.48 0.08 1.44 0.07 1.96 0.07 0.49 0.05 1.47 0.09 2.04 0.07 0.51 0.05 1.53 0.08 2.12 0.08 0.53 0.03 1.59 0.04 2.16 0.05 0.54 0.01 1.62 0.04 2.24 0.03 2.45 2.4 2.4 2.45 2.55 2.65 2.7 2.8 138 9 10 2.8 2.85 1.106 CFS 0.56 0.02 1.68 0 2.24 0.04 0.56 0.03 1.68 0.04 2.28 0.07 0.57 -0.03 1.71 0.03 0.04 Ft/s 139 Table 3A. continued Date Location Away from Shore (Ft) 10/19/2014 0 1 2 3 4 5 6 7 8 Depth Change in Depth Velocity 2.25 1.8 0 0.45 0.02 1.35 -0.02 2.08 0.03 0.52 0 1.56 0.06 1.96 0.05 0.49 0.02 1.47 0.08 1.96 0.04 0.49 0.02 1.47 0.04 2 0.05 0.5 0.03 1.5 0.03 2.08 0.07 0.52 0.07 1.56 0.09 2.16 0.08 0.54 0.07 1.62 0.1 2.24 0.04 0.56 0.05 1.68 0.07 2.32 0.07 2.6 2.45 2.45 2.5 2.6 2.7 2.8 2.9 140 9 10 2.9 2.5 1.439 CFS 0.58 0.04 1.74 0.06 2.32 0.06 0.58 0.01 1.74 0.07 2 0.07 0.5 0 1.5 0.02 0.05 Ft/s 141 Table 3A. continued Date Location Away from Shore (Ft) 10/24/2014 0 1 2 3 4 5 6 7 8 Depth Change in Depth Velocity 2.35 1.88 -0.03 0.47 0.04 1.41 0.02 2.04 -0.03 0.51 0.01 1.53 -0.01 1.96 0.05 0.5 0.05 1.5 0.05 1.96 0.09 0.5 0.07 1.5 0.11 1.96 -0.02 0.5 0.06 1.5 0.08 2.04 0 0.51 0.04 1.53 -0.01 2.2 0.1 0.55 0.08 1.65 0.08 2.24 0.07 0.56 0.04 1.68 0.13 2.4 -0.01 2.55 2.5 2.5 2.5 2.55 2.75 2.8 3 142 9 10 3.1 2.7 1.392 CFS 0.6 0.03 1.8 0.05 2.48 0 0.62 0.05 1.86 0.03 2.16 0.18 0.54 0.03 1.72 0.07 0.05 Ft/s 143 Table 4A. Discharge Calculations for Huffman Ditch Date Location Away from Shore (Ft) 6/15/2014 Depth Velocity 0.5 0.75 0.45 0.32 1 1.1 0.68 0.36 1.5 1 0.6 0.38 2 0.85 0.51 0.38 2.5 1 0.6 0.37 3 0.95 0.57 0.44 3.5 0.8 0.48 0.4 4 0.75 0.45 0.33 4.5 0.7 0.42 0.3 5 0.7 0.42 0.26 5.5 0.5 0.3 0.23 6 0.45 0.27 0.24 1.69 CFS 6/22/2014 Change in Depth 0.35 Ft/s 0.5 0.85 0.51 0.58 1 1 0.6 0.52 1.5 1.1 0.66 0.6 2 1.1 0.66 0.54 2.5 1 0.6 0.55 3 0.95 0.57 0.51 3.5 0.95 0.57 0.47 4 0.85 0.51 0.43 4.5 0.8 0.48 0.45 5 0.8 0.48 0.42 144 5.5 0.45 0.27 0.37 6 0.4 0.24 0.35 2.57 CFS 0.56 Ft/s 145 Table 4A. continued Date Location Away from Shore (Ft) 7/6/2014 Depth Velocity 0.5 0.79 0.474 0.16 1 0.82 0.492 0.21 1.5 0.72 0.432 0.2 2 0.82 0.492 0.21 2.5 0.8 0.28 0.25 3 0.7 0.42 0.22 3.5 0.72 0.432 0.21 4 0.7 0.42 0.17 4.5 0.52 0.312 0.11 5 0.45 0.27 0.13 5.5 0.35 0.21 0.09 6 0.25 0.15 0.06 0.728 CFS 7/13/2014 Change in Depth 0.18 Ft/s 1 0.8 0.48 0.18 1.5 0.75 0.45 0.18 2 0.85 0.51 0.21 2.5 0.8 0.48 0.2 3 0.7 0.42 0.19 3.5 0.7 0.42 0.2 4 0.7 0.42 0.2 4.5 0.55 0.33 0.18 5 0.55 0.33 0.19 5.5 0.45 0.27 0.13 146 6 0.3 0.66 CFS 0.18 0.33 Ft/s 147 0.1 Table 4A.- continued Date Location Away from Shore (Ft) 7/20/2014 Depth Velocity 1 0.72 0.43 0.09 1.5 0.82 0.49 0.15 2 0.79 0.47 0.17 2.5 0.65 0.39 0.15 3 0.77 0.46 0.13 3.5 0.71 0.43 0.17 4 0.62 0.37 0.18 4.5 0.6 0.36 0.15 5 0.52 0.31 0.14 5.5 0.48 0.29 0.11 6 0.4 0.24 0.1 0.49 CFS 7/27/2014 Change in Depth 0.14 Ft/s 1/2 0.65 0.39 0.12 1 0.8 0.48 0.12 1.5 0.7 0.42 0.14 2 0.63 0.38 0.16 2.5 0.7 0.42 0.12 3 0.7 0.42 0.14 3.5 0.6 0.36 0.14 4 0.6 0.36 0.14 4.5 0.5 0.3 0.13 5 0.5 0.3 0.1 148 5.5 0.4 0.24 0.09 6 0.3 0.18 0.06 0.45 CFS 0.12 Ft/s 149 Table 4A. continued Date Location Away from Shore (Ft) 8/3/2014 Depth Velocity 1/2 0.4 0.24 0.06 1 0.6 0.36 0.07 1.5 0.65 0.39 0.11 2 0.65 0.39 0.1 2.5 0.6 0.36 0.1 3 0.7 0.42 0.13 3.5 0.6 0.36 0.12 4 0.55 0.33 0.11 4.5 0.49 0.29 0.1 5 0.49 0.29 0.08 5.5 0.35 0.21 0.07 0.30 cfs 8/10/2014 Change in Depth 0.1 ft/s 1/2 0.65 0.39 0.08 1 0.55 0.33 0.1 1.5 0.6 0.36 0.1 2 0.45 0.27 0.12 2.5 0.6 0.36 0.12 3 0.6 0.36 0.12 3.5 0.6 0.36 0.1 4 0.55 0.33 0.09 4.5 0.5 0.3 0.09 5 0.4 0.24 0.1 150 0.29 cfs 0.1 ft/s 151 Table 4A. continued Date Location Away from Shore (Ft) Depth Change in Depth 8/17/2014 1/2 0.6 0.36 1 0.6 0.36 1.5 0.65 0.39 2 0.6 0.36 2.5 0.6 0.36 3 0.65 0.39 3.5 0.55 0.33 4 0.47 0.28 4.5 0.4 0.24 5 0.3 0.18 0.23 CFS 8/24/2014 Velocity 0.08 Ft/s 1/2 0.9 0.54 0.59 1 1.1 0.66 0.55 1.5 1.1 0.66 0.54 2 1 0.6 0.55 2.5 1 0.6 0.46 3 1 0.6 0.52 3.5 0.9 0.54 0.52 4 0.8 0.48 0.47 4.5 0.7 0.42 0.45 5 0.7 0.42 0.46 5.5 0.6 0.36 0.38 152 2.48 CFS 0.50 Ft/s 153 Table 4A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/31/2014 1/2 0.8 0.48 0.11 1 0.7 0.42 0.08 1.5 0.7 0.42 0.12 2 0.7 0.42 0.15 2.5 0.7 0.42 0.13 3 0.7 0.42 0.12 3.5 0.7 0.42 0.11 4 0.5 0.3 0.12 4.5 0.4 0.24 0.07 5 0.4 0.24 0.04 0.35 CFS 9/7/2014 0.11 Ft/s 0.5 0.7 0.42 0.07 1 0.8 0.48 0.11 1.5 0.7 0.42 0.11 2 0.8 0.48 0.12 2.5 0.7 0.42 0.11 3 0.6 0.36 0.1 3.5 0.5 0.3 0.1 4 0.45 0.27 0.09 4.5 0.4 0.24 0.06 0.29 CFS 0.1 Ft/s 154 Table 4A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/14/2014 0.5 0.6 0.36 0.07 1 0.7 0.42 0.07 1.5 0.8 0.48 0.11 2 0.7 0.42 0.1 2.5 0.7 0.42 0.11 3 0.6 0.36 0.11 3.5 0.6 0.36 0.11 4 0.5 0.3 0.08 4.5 0.45 0.27 0.09 5 0.4 0.24 0.05 0.28 CFS 9/21/2014 0.09 Ft/s 0.5 0.4 0.24 0 1 0.7 0.42 0.05 1.5 0.8 0.48 0.09 2 0.75 0.45 0.1 2.5 0.5 0.3 0.12 3 0.6 0.36 0.1 3.5 0.6 0.36 0.09 4 0.5 0.3 0.08 4.5 0.45 0.27 0.08 5 0.4 0.24 0.08 0.23 CFS 0.08 Ft/s 155 Table 4A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/28/2014 0.5 0.6 0.36 0.04 1 0.6 0.36 0.08 1.5 0.6 0.36 0.08 2 0.7 0.42 0.09 2.5 0.55 0.33 0.07 3 0.5 0.3 0.08 3.5 0.45 0.27 0.06 4 0.4 0.24 0.05 4.5 0.35 0.21 0.04 0.16 CFS 10/12/2014 0.07 Ft/s 0.5 0.7 0.42 0.06 1 0.8 0.48 0.08 1.5 0.55 0.33 0.08 2 0.7 0.42 0.11 2.5 0.7 0.42 0.09 3 0.65 0.39 0.08 3.5 0.6 0.36 0.08 4 0.6 0.36 0.08 0.23 CFS 0.08 Ft/s 156 Table 4A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 10/19/2014 0.5 0.8 0.48 0.12 1 0.8 0.48 0.1 1.5 0.75 0.45 0.1 2 0.75 0.45 0.11 2.5 0.65 0.39 0.08 3 0.5 0.3 0.06 3.5 0.5 0.3 0.06 4 0.5 0.3 0.07 4.5 0.45 0.27 0.04 0.25 CFS 10/26/2014 0.09 Ft/s 0.5 0.75 0.45 1 0.8 0.48 1.5 0.7 0.42 2 0.7 0.42 2.5 0.65 0.39 3 0.6 0.36 3.5 0.5 0.3 4 0.45 0.27 0.21 CFS 0.08 Ft/s 157 Table 5A. Discharge Calculations for Cemetery Run Date Location Away from Shore (Ft) Depth Change in Depth Velocity 6/15/2014 ---- ---- ---- ---- 6/22/2014 0 2.45 1.96 -0.02 2.45 0.49 0.04 2.6 2.08 -0.02 2.6 0.52 0.1 3 2.4 0.07 3 0.6 0.12 2.8 2.24 -0.06 2.8 0.56 0.16 2.45 1.96 -0.02 2.45 0.49 0.18 2.8 2.24 0.08 2.8 0.56 0.08 1 2 3 4 5 0.73 CFS 7/6/2014 0 1 2 3 0.06 Ft/s 2.15 2.3 2.4 2.23 158 1.72 0.03 0.43 0.05 1.84 -0.09 0.46 0.03 1.92 -0.31 0.48 0.25 1.78 0.24 0.45 0.28 4 -0.1 2.3 CFS 159 2.04 -0.17 0.46 -0.09 -0.1 Ft/s Table 5A. continued Date Location Away from Shore (Ft) 7/13/2014 0 Depth Change in Depth Velocity 2.1 1.68 0 0.42 0.06 1.92 -0.29 0.48 0.19 1.92 -0.05 0.48 0.07 1.92 0.09 0.48 0.08 1.82 -0.11 0.45 0.13 1 2.4 2 2.4 3 4 2.4 2.27 0.18 CFS 0.02 Ft/s 7/20/2014 0 1.9 1.52 0.38 1 2.31 1.85 0.46 2 2.4 1.92 0.48 3 2.4 1.92 0.48 4 160 2.22 1.77 0.44 0.45 CFS 161 0.04 Ft/s Table 5A. continued Date Location Away from Shore (Ft) 7/27/2014 0 1 2 3 4 Depth Change in Depth Velocity 1.9 1.52 -0.05 0.38 0.08 1.68 -0.09 0.42 0.04 1.84 0.01 0.46 0 1.92 0.06 0.48 0.16 1.68 0.11 0.42 0.07 2.1 2.3 2.4 2.1 0.39 CFS 8/3/2014 0 1 2 3 4 0.04 Ft/s 1.85 2.2 2.28 2.2 2 .389 CFS 1.48 0.03 0.39 0.06 1.76 -0.05 0.44 0.03 1.84 -0.01 0.46 0.12 1.76 0.04 0.44 0.13 1.64 0 0.4 0.04 .04 ft/s 162 Table 5A. continued Date Location Away from Shore (Ft) 8/10/2014 0 1 2 3 4 Depth Change in Depth Velocity 1.8 1.44 0.01 0.36 -0.01 1.68 -0.09 0.42 0.01 1.68 0.02 0.42 0.08 1.68 -0.02 0.42 0.08 1.68 -0.04 0.42 0 2.1 2.1 2.1 2.1 0.03 CFS 8/17/2014 0 1 2 3 0 Ft/s 1.7 2 2.3 2.2 163 1.36 0 0.34 0.01 1.02 0.01 1.6 0.01 0.4 0.05 1.2 0.04 1.84 0.03 0.46 0.07 1.38 0.07 1.76 0.02 0.44 0.09 4 2.1 0.96 CFS 1.32 0.07 1.68 0.02 0.42 0.04 1.26 0.02 0.05 Ft/s 164 Table 5A. continued Date Location Away from Shore (Ft) 8/24/2014 0 1 2 3 4 Depth Change in Depth Velocity 2.4 1.92 0.02 0.48 0 2.32 0.04 0.58 0.06 2.32 0.01 0.58 0.17 1.74 0.02 2.4 0.04 0.6 0.08 1.8 0.08 1.84 0 0.52 0 1.56 -0.01 2.9 2.9 3 2.6 0.51 CFS 8/31/2014 0 1 2 0.04 Ft/s 1.6 2.3 2.6 165 1.6 0 0.4 0 1.2 0.03 1.84 0 0.46 0.07 1.38 0.03 2.08 -0.03 0.52 0.15 1.56 0.04 3 4 2.6 2.3 0.36 CFS 2.08 -0.05 0.52 0.06 1.56 0.15 1.84 -0.02 0.46 0.04 1.38 0.03 0.04 Ft/s 166 Table 5A. continued Date Location Away from Shore (Ft) 9/7/2014 0 1 2 3 4 Depth Change in Depth Velocity 1.95 1.56 0.01 0.39 -0.02 1.17 0 1.96 -0.01 0.49 0.06 1.47 0.02 2 -0.09 0.5 0.14 1.5 0.02 2 -0.03 0.5 0.15 1.5 0.08 1.52 -0.05 0.38 0.04 1.14 0.04 2.45 2.5 2.5 1.9 0.34 CFS 9/14/2014 0 1 0.03 Ft/s 2 2.2 167 1.6 0.01 0.05 -0.05 1.2 0.01 1.76 0.02 0.44 0.08 1.32 0.1 2 3 4 2.4 2.4 1.8 0.18 CFS 1.92 0.12 0.48 0.1 1.44 -0.1 1.92 -0.14 0.48 0.15 1.44 0.08 1.44 -0.02 0.36 0.04 1.08 -0.11 0 Ft/s 168 Table 5A. continued Date Location Away from Shore (Ft) 9/21/2014 0 1 2 3 4 Depth Change in Depth Velocity 1.9 1.52 0.06 0.38 0.01 1.14 0.12 1.88 0.01 0.47 -0.22 1.41 -0.18 1.96 0.14 0.49 0.12 1.47 0.36 1.92 -0.06 0.48 -0.25 1.44 -0.08 1.52 -0.11 0.38 0.13 1.14 0.17 2.35 2.45 2.4 1.9 0.30 CFS 9/28/2014 0 1 2 0.02 Ft/s 1.85 2.1 2.4 169 1.48 0 0.37 0.01 1.11 0 1.68 0 0.42 0.07 1.26 0.01 1.92 -0.02 3 4 2.2 1.7 0.28 CFS 0.48 0.08 1.44 0.02 1.76 0.04 0.44 0.01 1.32 0.07 1.36 0.01 0.34 -0.01 1.02 0.02 0.03 Ft/s 170 Table 5A. continued Date Location Away from Shore (Ft) 10/12/2014 0 1 2 3 4 Depth Change in Depth Velocity 1.9 1.52 -0.02 0.38 0.01 1.14 -0.01 1.64 0.07 0.41 -0.06 1.25 0.09 1.84 0.02 0.46 0.06 1.38 0.08 1.64 -0.04 0.41 0 1.25 -0.06 1.48 -0.03 0.87 0.11 1.11 0.07 2.05 2.3 2.05 1.85 0.96 CFS 10/19/2014 0 1 2 0.02 Ft/s 2.05 2.1 2.4 171 1.64 0.03 0.41 0.03 1.23 0.03 1.68 0 0.42 0.02 1.26 0.01 1.92 0.09 3 4 2.05 1.8 0.07 CFS 0.48 0.01 1.44 0.02 1.64 -0.05 0.41 0.04 1.23 0 1.44 -0.11 0.36 0.05 1.08 -0.01 0.01 Ft/s 172 Table 5A. continued Date Location Away from Shore (Ft) 10/26/2014 0 1 2 3 4 Depth Change in Depth Velocity 2 1.6 0.02 0.4 0.06 1.2 0.07 1.68 -0.12 0.42 -0.03 1.2 -0.12 1.88 0.14 0.47 0.09 1.41 0.14 1.68 -0.02 0.42 -0.06 1.26 -0.05 1.44 0.05 0.36 -0.01 1.08 0.01 2.1 2.35 2.1 1.8 0.1 CFS 0.01 Ft/s 173 Table 6A. Discharge Calculations for Cecil Ditch Date Location Away from Shore (Ft) Depth Change in Depth Velocity 6/15/2014 ---- ---- ---- ---- 6/22/2014 1 0.55 0.33 0.02 2 0.7 0.42 0.09 3 0.7 0.42 0.08 4 0.7 0.42 0.14 5 0.8 0.48 0.14 6 0.8 0.48 0.12 7 0.8 0.48 0.12 8 0.65 0.39 0.13 9 0.6 0.36 0.12 10 0.5 0.3 0.1 11 0.4 0.24 0.1 11.5 0.3 0.18 0.01 1.17 CFS 7/6/2007 0.11 Ft/s 1 0.25 0.15 0.05 2 0.25 0.15 0.02 3 0.3 0.18 0.01 4 0.39 0.23 0.06 5 0.45 0.27 0.12 6 0.48 0.288 0.11 7 0.48 0.288 0.15 8 0.45 0.27 0.12 9 0.35 0.21 0.1 174 10 0.28 0.208 0.07 11 0.2 0.12 0.03 1.69 CFS 0.08 Ft/s 175 Table 6A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 7/13/2014 1 0.25 0.15 0 2 0.25 0.15 0.02 3 0.25 0.15 0.1 4 0.4 0.24 0.13 5 0.4 0.24 0.04 6 0.5 0.3 0.13 7 0.47 0.28 0.1 8 0.41 0.25 0.07 9 0.32 0.19 0.04 10 0.28 0.17 0.11 0.296 cfs 0.08 ft/s 7/20/2014 1 0.3 0.18 0.02 2 0.3 0.18 0.05 3 0.25 0.15 0.1 4 0.37 0.22 0.12 5 0.39 0.23 0.13 6 0.39 0.23 0.1 7 0.39 0.23 0.11 8 0.35 0.21 0.1 9 0.28 0.17 0.1 1.43 CFS 0.16 Ft/s 176 Table 6A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 7/27/2014 1 0.2 0.12 0 2 0.2 0.12 0.02 3 0.2 0.12 0.05 4 0.3 0.18 0.08 5 0.4 0.24 0.11 6 0.4 0.24 0.14 7 0.4 0.24 0.07 8 0.4 0.24 0.01 9 0.3 0.18 0.13 10 0.2 0.12 0.06 0.192 CFS 8/3/2014 0.07 Ft/s 3 0.32 0.19 0 3.5 0.32 0.19 0.08 4 0.32 0.19 0.1 4.5 0.32 0.19 0.1 5 0.32 0.19 0.12 5.5 0.32 0.19 0.14 6 0.39 0.23 0.19 6.5 0.39 0.23 0.17 7 0.35 0.21 0.09 7.5 0.32 0.19 0.08 8 0.3 0.18 0.08 8.5 0.25 0.15 0 177 0.198 CFS 0.08 Ft/s 178 Table 6A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/10/2014 4 0.3 0.18 0.09 4.5 0.3 0.18 0.12 5 0.3 0.18 0.18 5.5 0.4 0.24 0.15 6 0.4 0.24 0.09 6.5 0.4 0.24 0.05 0.167 CFS 8/17/2014 0.1 Ft/s 1 0.3 0.18 0 2 0.4 0.24 0.01 3 0.5 0.3 0.05 4 0.45 0.27 0.06 5 0.55 0.33 0.04 6 0.55 0.33 0.04 7 0.6 0.36 0.03 8 0.65 0.39 0.03 9 0.55 0.33 0.03 10 0.35 0.21 0.05 0.18 CFS 0.03 Ft/s 179 Table 6A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 8/24/2014 1 0.9 0.54 0.06 2 1 0.6 0.07 3 1 0.6 0.07 4 1 0.6 0.08 5 1.1 0.66 0.08 6 1.1 0.66 0.09 7 1.1 0.66 0.07 8 1.2 0.72 0.05 9 1.2 0.72 0.07 10 1 0.6 0.04 0.754 CFS 8/31/2014 0.07 Ft/s 1 0.6 0.36 0.03 2 0.6 0.36 0.03 3 0.7 0.42 0.04 4 0.7 0.42 0.03 5 0.7 0.42 0.05 6 0.7 0.42 0.05 7 0.7 0.42 0.05 8 0.8 0.48 0.03 9 0.9 0.54 0.01 10 0.7 0.42 0.05 0.28 CFS 0.04 Ft/s 180 Table 6A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 9/21/2014 1 0.5 0.3 0.04 2 0.5 0.3 0.02 3 0.6 0.36 0.03 4 0.6 0.36 0.06 5 0.6 0.36 0 6 0.6 0.36 0.04 7 0.7 0.42 0.01 8 0.6 0.36 0.05 9 0.6 0.36 0.08 10 0.4 0.24 -0.01 0.19 CFS 9/28/2014 0.03 Ft/s 1 0.5 0.3 0 2 0.5 0.3 0.06 3 0.5 0.3 0.05 4 0.5 0.3 0.04 5 0.6 0.36 0.02 6 0.6 0.36 0.01 7 0.6 0.36 0.06 8 0.65 0.39 0.04 9 0.7 0.42 0.04 10 0.45 0.27 0.04 0.21 Ft/s 0.04 Ft/s 181 Table 6A. continued Date Location Away from Shore (Ft) Depth Change in Depth 10/12/2014 1 0.5 0.3 2 0.4 0.24 3 0.45 0.27 4 0.4 0.24 5 0.5 0.3 6 0.6 0.36 7 0.6 0.36 8 0.6 0.36 9 0.6 0.36 0.15 CFS 10/19/2014 Velocity 0.03 Ft/s 1 0.5 0.3 -0.02 2 0.5 0.3 0.05 3 0.5 0.3 0.04 4 0.5 0.3 0.03 5 0.5 0.3 0.04 6 0.5 0.3 0.06 7 0.65 0.39 0.06 8 0.65 0.39 0.05 9 0.65 0.39 0.03 10 0.5 0.3 0.04 0.21 CFS 0.04 Ft/s 182 Table 6A. continued Date Location Away from Shore (Ft) Depth Change in Depth Velocity 10/26/2014 1 0.55 0.33 0.04 2 0.55 0.33 0.06 3 0.55 0.33 0.05 4 0.55 0.33 0.04 5 0.55 0.33 0.04 6 0.6 0.36 0.06 7 0.6 0.36 0.05 8 0.6 0.36 0.06 9 0.6 0.36 0.06 10 0.6 0.36 0.02 0.28 CFS 0.05 Ft/s 183 APPENDIX B Table 1B. Nitrate Concentrations (mg/L) for Tributaries. Dates Outfall Duplicate Carmichael Ditch Duplicate Shave Tail Creek Duplicate Huffman Ditch Duplicate 6/15/2014 0.4 ---- 4.2 ---- 1.6 ---- 3.2 ---- 6/22/2014 0.2 ---- 2.8 2.9 1.4 ---- 2 ---- 7/6/2014 0.7 ---- 1.1 ---- 0.9 1 1.5 ---- 7/13/2014* 0.2 ---- 1.4 ---- 0.9 ---- 1 ---- 7/20/2014 0.3 ---- 1.5 ---- 0.9 ---- 0.8 ---- 7/27/2014 0.6 0.5 0 ---- 0.6 ---- 0.7 ---- 8/3/2014* 1 ---- 0.1 ---- 0.5 ---- 1.8 1.7 8/10/2014 0.9 ---- 0.7 ---- 1.1 ---- 2.1 ---- 8/17/2014* 0.5 ---- 0.9 ---- ---- ---- 1.7 ---- 184 8/24/2014 0.5 ---- 1.5 ---- 0.5 0.6 0.5 ---- 8/31/2014 0.4 ---- 0.7 0.7 0.4 ---- 0.7 ---- 9/7/2014 0.3 ---- 0.3 ---- 0.2 ---- 0.7 ---- 9/14/2014 0.5 ---- 0.8 ---- 0.3 ---- 0.8 0.8 9/21/2014 0.2 ---- 0.1 ---- 0.3 0.3 0.4 ---- 9/28/2014 0.3 ---- 0.6 ---- 0.6 ---- 0.8 ---- 10/12/2014 0.8 0.8 0.5 ---- 0.7 ---- 0.8 ---- 10/19/2014 0.4 ---- 1.8 ---- 0.4 ---- 0.8 ---- 10/26/2014 0.3 ---- 0.6 ---- 0.2 0.2 0.2 ---- “----“ signifies no data and “*” is for erroneous standards 185 Table 1B. continued Dates Cemetery Run Duplicate Cecil Ditch Duplicate Trip Blank Lab Blank 6/15/2014 0.7 ---- 2 ---- 0 0 9.1 6/22/2014 0.4 ---- 2.7 ---- 0 0 9.4 7/6/2014 0.7 ---- 0.8 ---- 0 0 9.1 7/13/2014* 0.3 ---- 0.9 1 0 0 0.48 7/20/2014 0.9 0.8 0.6 ---- 0 0 9.8 7/27/2014 0.6 ---- 1 ---- 0 0 9.3 8/3/2014* 0.6 ---- 1.3 ---- 0 0 7.1 8/10/2014 1.4 ---- 1.6 ---- 0 0 9.3 8/17/2014* 1.3 1.4 1.9 ---- 0 0 8.9 8/24/2014 0.3 ---- 0.7 ---- 0 0 9 186 Standard 8/31/2014 0.4 ---- 1.2 ---- 0 0 9 9/7/2014 0.7 ---- 0.3 0.2 0 0 9.1 9/14/2014 0.4 ---- 0.4 ---- 0 0 9.2 ---- 0.1 ---- 0 0 9.5 9/21/2014 9/28/2014 0.7 0.7 1.9 ---- 0 0 9 10/12/2014 0.5 ---- 1.1 ---- 0 0 10.7 10/19/2014 0.1 ---- 0.9 ---- 0 0 10.2 10/26/2014 0.3 ---- 0 ---- 0 0 9.3 187 Appendix C Table 1C. Nitrite Concentrations (mg/L) for tributaries. Date Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run 6/15/2014 0 0.03 0.44 0 0 0 7/6/2007 1.3 1.47 0.57 1.32 0 1.18 7/20/2014 0 0 0 0 0 0 8/10/2014 0 0.1 0 0 0 0 8/24/2014 0 0.86 0.35 0 0 2.45 8/31/2014 0 0.18 0 0 0 0 9/7/2014 2 2.37 4.2 1.5 2.89 2.73 9/14/2014 1.17 0.63 0 0 0 0 9/21/2014 0 0 0 0.58 0 0 9/28/2014 0.5 0.16 2.98 2.8 1.3 3.5 10/12/2014 0 0 0 0 0 0 10/19/2014 0 0 0 0 0 0 10/26/2014 0.24 1.33 1.15 0.8 0 0.86 188 Cecil Ditch APPENDIX D Table 1D. Ammonia Concentrations (mg/L) for Tributaries. Dates Outfall Duplicate Carmichael Ditch Duplicate Shave Tail Creek Duplicate Huffman Ditch Duplicate 0.06 ---- 0.02 ---- 6/15/2014 0 0 0.07 6/22/2014* 0 ---- 0.07 0.06 0.04 ---- 0.05 ---- 7/6/2014 0 ---- 0.03 ---- 0.03 0.03 0.08 ---- 7/13/2014 0 ---- 0.05 ---- 0.02 ---- 0.01 ---- 7/20/2014 0.03 ---- 0.07 ---- 0.24 ---- 0.06 ---- 7/27/2014 0 0.01 0.02 ---- 0 ---- 0 ---- 8/3/2014 0.1 ---- 0.04 ---- 0 ---- 0.02 0.01 8/10/2014 0.05 0.05 0 ---- 0 ---- 0 ---- 8/17/2014 0.08 ---- 0.04 ---- 0.05 ---- 0 ---- 189 8/24/2014 0 ---- 0.02 ---- 0.09 0.09 0.02 ---- 8/31/2014 0 ---- 0.03 0.01 0 ---- 0 ---- 9/7/2014 0.03 ---- 0.07 ---- 0.03 ---- 0 ---- 9/14/2014 0.13 ---- 0.05 ---- 0.02 ---- 0.02 ---- 9/21/2014 0 ---- 0.04 ---- 0.02 0.03 0 ---- 9/28/2014 0.14 ---- 0.07 ---- 0.08 ---- 0.01 ---- 10/12/2014 0.07 0.09 0.05 ---- 0.01 ---- 0 ---- 10/19/2014 0.06 ---- 0.07 ---- 0.05 ---- 0 ---- 10/26/2014 0.04 ---- 0.06 ---- 0.02 ---- 0 ---- “----“ signifies no data and “*” is for erroneous standards. 190 Table 1D. continued Dates Cemetery Run Duplicate Cecil Ditch Duplicate 6/15/2014 0.03 ---- 0.07 ---- 0 0 0.47 6/22/2014* 0.01 ---- 0.07 ---- 0 0 0.39 7/6/2014 0.06 ---- 0.02 ---- 0 0 0.46 7/13/2014 0.07 ---- 0.06 0.06 0 0 0.45 7/20/2014 0.03 0.04 0.1 ---- 0 0 0.49 7/27/2014 0 ---- 0 ---- 0 0 0.45 8/3/2014 0.05 ---- 0.03 ---- 0 0 0.5 8/10/2014 0 ---- 0 ---- 0 0 0.45 8/17/2014 0.02 0.01 0.05 ---- 0 0 0.45 8/24/2014 0.04 ---- 0.07 ---- 0 0 0.47 191 Trip Blank Lab Blank Standard 8/31/2014 0.01 ---- 0.07 ---- 0 0 0.48 9/7/2014 0 ---- 0 0 0 0 0.49 9/14/2014 0.01 ---- 0.02 ---- 0 0 0.48 9/21/2014 ---- ---- 0 ---- 0 0 0.46 9/28/2014 0.04 0.04 0.07 ---- 0 0 0.5 10/12/2014 0 ---- 0.02 ---- 0 0 0.45 10/19/2014 0.03 ---- 0.04 0.04 0 0 0.49 10/26/2014 0.01 ---- 0.01 ---- 0 0 0.47 “----“ signifies no data and “*” is for erroneous standards. 192 APPENDIX E Table 1E. Total Nitrogen Concentrations (mg/L) for Tributaries. Shave Tail Creek Duplicate Huffman Ditch Duplicate 2.1 ---- 2 ---- 4.9 1.7 ---- 4 ---- 2.6 ---- 1.5 1.4 2.9 ---- ---- ---- ---- ---- ---- ---- ---- 0 ---- 0.2 ---- 0.6 ---- 0.5 ---- 7/27/2014* 0 ---- 0 ---- 0 ---- 0 ---- 8/3/2014 1.7 ---- 1.3 ---- 0.9 ---- 1.9 2.1 8/10/2014 0.6 0.5 0.8 ---- 0.9 ---- 1.4 ---- Dates Outfall Duplicate Carmichael Ditch 6/15/2014 0 0 4.3 6/22/2014 0.2 ---- 4.7 7/6/2014 2 ---- 7/13/2014* ---- 7/20/2014 8/17/2014 ---- Duplicate ---- 193 ---- ---- 8/24/2014 0 ---- 2.4 ---- 0.9 0.8 0.3 ---- 8/31/2014 0 ---- 0.9 0 0 ---- 0 ---- 9/7/2014 2.3 ---- 2.7 ---- 4.4 ---- 2.2 ---- 9/14/2014 1.7 ---- 1.5 ---- 0 ---- 0.7 0.9 9/21/2014 0 ---- 0 ---- 0 0.2 1 9/28/2014 0.8 ---- 0.8 ---- 3.6 ---- 3.6 ---- 10/12/2014 0 0 0 ---- 0 ---- 0.1 ---- 10/19/2014 0 ---- 0 ---- 0 ---- 0 ---- 10/26/2014 0.6 ---- 2 ---- 1.4 1.6 1 ---- “----“ signifies no data and “*” is for erroneous standards. 194 Table 1E. continued Dates Cemetery Run Duplicate Cecil Ditch 6/15/2014 0 ---- 6/22/2014 1.3 7/6/2014 Duplicate Trip Blank Lab Blank Standard 0.9 0 0 9.1 ---- 4.9 0 0 9.5 0.6 ---- 2 0 0 9 7/13/2014 ---- ---- ---- ---- ---- ---- 7/20/2014 0.8 0.8 0.1 0 0 9.5 7/27/2014* 0 ---- 0 0 0 0 9.45 8/3/2014 0.8 ---- 1.3 ---- 0 0 9.6 8/10/2014 0.04 ---- 1.2 ---- 0 0 9 8/17/2014 ---- ---- ---- ---- ---- ---- ---- 8/24/2014 0 ---- 3.2 ---- 0 0 9.2 8/31/2014 0 ---- 0 0 0 10.2 9/7/2014 3.6 ---- 3.1 2.9 0 0 10.9 9/14/2014 0 ---- 0 ---- 0 0 9.5 9/21/2014 ---- ---- 0 ---- 0 0 9.8 9/28/2014 2 1.9 5.4 ---- 0 0 9.8 10/12/2014 0 ---- 0.2 ---- 0 0 10 ---- 195 10/19/2014 0 ---- 0 0 0 0 9.6 10/26/2014 0 ---- 0.9 ---- 0 0 10.3 “----“ signifies no data. 196 Appendix F Table 1F. Particulate phosphorus concentrations for the tributaries. “----“ result was out of range. Date Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch 6/15/2014 0 0.009783 0.143484 0 0 0 7/6/2007 0.42393 0.479367 0.185877 0.430452 0 0.384798 7/20/2014 0 0 0 0 0 0 8/10/2014 0.3261 0.410886 0.09783 0.384798 0.048915 0.088047 8/24/2014 0 0.03261 0 0 0 0 8/31/2014 0 0.280446 0.114135 0 0 0.798945 9/7/2014 0 0.058698 0 0 0 0 9/14/2014 0.6522 0.772857 1.36962 0.48915 0.942429 0.890253 9/21/2014 0.381537 0.205443 0 0 0 0 197 9/28/2014 0 0 0 0.189138 0 0 10/12/2014 0.16305 0.052176 0.971778 0.91308 0.42393 1.14135 10/19/2014 0 0 0 0 0 0 10/26/2014 0 0 0 0 0 -0.29349 198 APPENDIX G Table 1G. Soluble Orthophosphate Concentrations (mg/L) for Tributaries. “----“signifies no data. Dates Outfall Duplicate Carmichael Ditch Duplicate Shave Tail Creek Duplicate Huffman Ditch Duplicate ---- ---- ---- 0.51 ---- 6/15/2014 ---- ---- ---- ---- ---- 6/22/2014 0 ---- 0.63 0.68 0.29 7/6/2014 0.19 ---- 0.31 ---- 0.26 0.23 0.13 ---- 7/13/2014 0.32 ---- 0.24 ---- 0.29 ---- 0.29 ---- 7/20/2014 0.01 ---- 0.29 ---- 0.29 ---- 0.24 ---- 7/27/2014 0.07 0.06 0.06 ---- 0.25 ---- 0.17 ---- 8/3/2014 0.25 ---- 0.13 ---- 0.33 ---- 0.23 0.22 8/10/2014 0.06 0.07 0.04 ---- 0.18 ---- 0.06 ---- 8/17/2014 0.09 ---- 0.23 ---- 0.21 ---- 0.17 ---- 8/24/2014 0.22 ---- 0.99 ---- 1.87 1.87 0.75 ---- 199 8/31/2014 0.09 ---- 0.18 0.2 0.26 ---- 0.22 ---- 9/7/2014 0.08 ---- 0.11 ---- 0.18 ---- 0.67 ---- 9/14/2014 0.12 ---- 0.25 ---- 0.39 ---- 0.36 0.35 9/21/2014 ---- ---- ---- ---- ---- ---- ---- ---- 9/28/2014 0.26 ---- 0.57 ---- 0.33 ---- 0.42 ---- 10/12/2014 0.01 0 0.1 ---- 0.11 ---- 0.11 ---- 10/19/2014 0.05 ---- 0.28 ---- 0.24 ---- 0.29 ---- 10/26/2014 0.1 ---- 0.24 ---- 0.21 0.21 0.43 ---- “----“ signifies no data. 200 Table 1G. continued Dates Cemetery Run Duplicate Cecil Ditch Duplicate Trip Blank Lab Blank Standard 6/15/2014 ---- ---- ---- ---- ---- ---- ---- 6/22/2014 0.14 ---- 0.18 ---- 0 0 0.92 7/6/2014 0.06 ---- 0.04 ---- 0 0 0.98 7/13/2014 0.24 ---- 0.21 0.19 0 0 0.98 7/20/2014 0.17 0.16 OR ---- 0 0 1 7/27/2014 0.35 ---- 0.2 ---- 0 0 1.09 8/3/2014 0.14 ---- 0.17 ---- 0 0 1.02 8/10/2014 0.19 ---- 0.07 ---- 0 0 0.92 8/17/2014 0.1 0.09 0.47 ---- 0 0 1.05 8/24/2014 0.15 ---- 1.35 ---- 0 0 1 8/31/2014 0.33 ---- 0.21 ---- 0 0 1 9/7/2014 0.27 ---- 0.17 0.16 0 0 0.98 9/14/2014 0.23 ---- 0.39 ---- 0 0 1 9/21/2014 ---- ---- ---- ---- ---- ---- ---- 9/28/2014 0.18 ---- 0.48 ---- 0 0 0.99 10/12/2014 0.17 ---- 0.1 ---- 0 0 0.9 10/19/2014 0.13 ---- 0.17 0.17 0 0 1.01 201 10/26/2014 0.39 ---- 0.6 ---- “----“ signifies no data. 202 0 0 1.02 APPENDIX H Table 1H. Total Phosphorus Concentrations (mg/L) for Tributaries. “----“signifies no data. Dates Outfall Duplicate Carmichael Ditch Duplicate Shave Tail Creek Duplicate Huffman Ditch Duplicate ---- 0.68 ---- 0.68 ---- 6/15/2014 0 0.47 0.5 ---- 0.78 6/22/2014 0 ---- 0.54 0.68 1.83 7/6/2014 0.08 ---- 0.12 ---- 0.17 0.16 0.16 ---- 7/13/2014 ---- ---- ---- ---- ---- ---- ---- ---- 7/20/2014 0 ---- 0 ---- 0.02 ---- 0 ---- 7/27/2014 0.18 0.19 0.15 ---- 0.28 ---- 0.17 ---- 8/3/2014 0.11 ---- 0.27 ---- 0.12 ---- 0.15 0.15 8/10/2014 0.07 0.06 0 ---- 0.13 ---- 0.1 ---- 8/17/2014 0 ---- 0.2 ---- 0.1 ---- 0.13 ---- 8/24/2014 0 ---- 0.87 ---- 0.89 0.94 0.52 ---- 203 8/31/2014 0.19 ---- 0.12 0.11 0.64 ---- 0.62 ---- 9/7/2014 0.03 ---- 0.27 ---- 0.11 ---- 0.14 ---- 9/14/2014 0.46 ---- 0.52 ---- 0.68 ---- 0.46 0.46 9/21/2014 0 ---- 0 ---- 0.09 ---- 0 ---- 9/28/2014 0 ---- 0 ---- 0.14 ---- 0.23 ---- 10/12/2014 0 0.01 0.08 ---- 0.21 ---- 0.15 ---- 10/19/2014 0.59 ---- 0.87 ---- 0.6 ---- 0.45 ---- 10/26/2014 0.25 ---- 0.24 ---- 0.45 0.45 0.18 ---- 204 Table 1H. continued Dates Cemetery Run Duplicate Cecil Ditch Duplicate Trip Blank Lab Blank Standard 6/15/2014 0.66 ---- 0.48 ---- 0 0 1.39 6/22/2014 0.68 ---- 0.13 ---- 0 0 0.97 7/6/2014 0.14 ---- 0.28 ---- 0 0 1.06 7/13/2014 ---- ---- ---- ---- ---- ---- ---- 7/20/2014 0.04 0.05 0.03 ---- 0 0 1 7/27/2014 0.18 ---- 0.11 ---- 0 0 1.1 8/3/2014 0.09 ---- 0 ---- 0 0 1.03 8/10/2014 0.08 ---- 0.02 ---- 0 0 0.9 8/17/2014 0.19 0.18 0 ---- 0 0 1.03 8/24/2014 0.24 ---- 0.32 ---- 0 0 0.93 8/31/2014 0.15 ---- 0.01 ---- 0 0 0.9 9/7/2014 0.15 ---- 0.16 0.14 0 0 0.93 9/14/2014 0.25 ---- 0.04 ---- 0 0 1.02 9/21/2014 ---- ---- 0 ---- 0 0 0.92 9/28/2014 0 0 0 ---- 0 0 0.94 10/12/2014 0 ---- 0.07 ---- 0 0 0.98 10/19/2014 0.59 ---- 0.31 0.28 0 0 0.97 205 10/26/2014 0.13 ---- 0.04 ---- “----“ signifies no data. 206 0 0 0.94 APPENDIX I Table 1I. Results of in-situ measurements: pH Concentrations for Tributaries. Date Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch 7/13/2014 8.16 6.8 7.22 7.38 7.47 7.29 7/27/2014 7.54 6.99 7.33 7.56 7.54 7.42 8/3/2014 7.08 6.64 7.24 7.52 7.51 7.56 8/24/2014 8.36 6.6 7.4 7.5 7.53 7.23 8/31/2014 8.38 7.02 7.72 7.75 7.47 7.38 9/14/2014 7.53 6.69 7.2 7.46 8.11 7.23 9/21/2014* 7.5 6.62 7.2 7.47 7.48 7.26 9/28/2014 7 6.76 6.88 7.35 7.54 6.87 10/19/2014 7.28 6.48 6.87 7.47 7.07 6.86 10/26/2014 7.37 6.16 6.55 6.8 6.93 6.22 “*” Signifies erroneous reading. 207 APPENDIX J Table 4J. Results of in-situ measurements: Temperature for Tributaries. “*” signifies erroneous reading Date Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch 7/13/2014 24.92 18.22 17.92 18.09 19.07 21.29 7/27/2014 23.32 18.87 18.92 18.43 18.16 20.61 8/3/2014 17.97 16.73 18.1 17.43 20.21 17.18 8/24/2014 25.85 20.96 20.08 19.14 25.74 19.31 8/31/2014 25.25 19.36 20.12 19.25 19.07 19.66 9/14/2014 20.23 13.47 12.1 12.7 16.75 12.98 9/21/2014* 20.14 16.12 17.28 17.36 17.81 17.13 9/28/2014 16.55 14.88 14.05 14.2 18.25 14.21 10/19/2014 13.06 10.31 9.8 17.36 9.11 9.37 10/26/2014 12.1 10.07 10.49 10.22 8.81 10.51 208 APPENDIX K Table 1K. Results of in-situ measurements: Turbidity for Tributaries. "N/A" signifies no data. Date Dam Carmichael Shave Tail Huffman Cemetary Cecil 7/13/2014 14.8 20.3 29.7 19.3 30.3 N/A 8/24/2014 17.4 24.6 27.7 135.2 29.2 17.1 8/31/2014 20.6 18.6 16.4 8.6 30.3 17.7 9/14/2014 15.3 34.6 10.5 18.4 24.6 20.6 9/28/2014 47.2 49.8 489 27.1 28.4 30 10/19/2014 15.1 24.7 22 42.7 8 13.6 10/26/2014 N/A 25.3 16.2 16.4 19.9 22.9 APPENDIX L Table 1L. Results of in-situ measurements: Specific Conductivity for Tributaries. "N/A" signifies no data and "IE" signifies instrument error. Date 7/13/2014 7/27/2014 8/3/2014 8/24/2014 8/31/2014 9/14/2014 Dam 0.1 355.3 471.9 313 307 328.2 Carmichael 690.6 676.9 664.9 410.2 671.3 749.9 Shave Tail 677.3 660.8 665.5 460.8 0.6 667.3 Huffman 677 660.2 658.3 532.6 670.5 673 Cemetary 643.8 658.9 IE 409.1 643.8 339.5 Cecil N/A N/A 738.7 784.9 795.1 750 9/28/2014 10/19/2014 10/26/2014 420.2 349.5 374.6 720.2 814.9 785.4 676.2 685.4 685.5 662.5 766.5 691 422.3 749.7 754.9 756.4 833.6 780.8 209 Appendix M Table 1M. Surface water quality parameters measured for Prairie Creek Reservoir Tributaries in 2014 (June through October). Parameter Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch pH 7.63 6.68 7.16 7.42 7.46 7.12 ± 0.41 std. 0.53 0.26 0.34 0.26 0.33 0.41 n= 9 9 9 9 9 9 Median 7.53 6.69 7.22 7.47 7.51 7.23 Range 7 - 8.4 6.16 - 7 6.55 - 7.7 6.8 - 7.8 6.93 - 8.1 6.22 - 7.6 Dissolved Oxygen 5.69 3.23 2.48 2.94 3.53 2.69 std. 3.66 2.54 2.36 1.66 3.21 2.34 n= 9 9 9 9 9 9 Median 5.85 3.17 2.92 3.08 3.64 2.45 Range 0 - 11.22 0 - 6.65 0 - 5.91 0 - 5.23 0 - 10.98 0 - 5.55 Turbidity 21.73 28.28 20.42 38.24 24.39 20.32 std. 12.67 10.78 7.4 44.07 8.14 5.71 n= 6 7 6 7 7 6 210 Median 16.35 24.7 22 19.3 28.4 19.2 Range 14.8 - 47.2 18.6 - 49.9 10.5 - 29.7 8.6 - 135.2 8 - 30.3 13.6 - 30 Temperature 19.92 15.87 15.73 16.31 17.24 16.12 std. 5.29 3.95 4.14 3.19 5.33 4.49 n= 9 9 9 9 9 9 Median 20.23 16.73 17.92 17.43 18.25 17.18 Range 12.1 - 25.85 10.07 - 20.96 9.8 - 20.12 10.22 - 19.25 8.81 - 25.74 9.37 - 21.29 211 Table 1M. continued Parameter Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Specific Conductivity (uS/cm) 324.4 687.1 647.4 665.7 577.8 777.1 std. 132.6 116.49 75.92 60.02 162.85 32.22 n= 8 9 8 9 8 7 Median 349.5 690.6 667.3 670.5 643.8 780.8 Range 0.1 - 471.9 410.2 - 814.9 460.8 - 685.5 532.6 - 766.5 339.5 - 754.9 738.7 - 833.6 Table 2M. Tributary and outfall discharge characteristics from June to October 2014. Location n Mean St. Dev. Min. Max. Outfall 13 6.89 15.47 0.03 56.65 Carmichael Ditch 18 1.15 1.11 0.05 4.2 Shave Tail Creek 8 1.58 0.88 1.11 3.74 Huffman Ditch 18 0.66 0.76 0.16 3.2 Cemetery Ditch 17 0.36 0.3 -0.1 0.96 212 Cecil Ditch 17 0.42 0.46 0.15 1.9 Table 3M. Surface water nutrient concentration for Prairie Creek Reservoir Tributaries in 2014 (April through October). Parameters Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Nitrate 0.45 1.15 0.67 1.07 0.58 1.02 StDev 0.21 1.11 0.43 0.8 0.32 0.76 N 15 15 15 15 14 15 median 0.4 0.7 0.6 0.8 0.55 0.9 range 0.2 - 0.9 0 - 4.2 0.2 - 1.6 0.2 - 3.2 0.1 - 1.4 0 - 2.7 Ammonia 0.04 0.05 0.04 0.01 0.02 0.04 StDev 0.05 0.02 0.06 0.02 0.02 0.03 N 17 17 17 17 16 17 median 0.03 0.05 0.02 0 0.03 0.03 range 0 - 0.14 0 - 0.07 0 - 0.24 0 - 0.08 0.07 0 - 0.1 Total N 0.66 1.2 1.44 0.68 1.55 StDev 0.84 1.33 1.3 1.04 1.81 1.61 1.5 213 N 15 15 15 15 14 15 median 0.2 1.3 0.9 1 0.2 0.9 range 0 - 2.3 0 - 4.7 0 - 4.4 0-4 0 - 3.6 0 - 5.4 Particulate P 0.02 0.04 0.06 0.02 0.03 StDev 0.04 0.06 0.04 0.05 0.02 0.02 N 18 18 18 18 17 18 median 0 0.07 0.04 0.05 0.02 0.03 range 0 - 0.13 0.01 - 0.21 0 - 0.15 0 - 0.18 0 - 0.1 0 - 0.08 0.08 An abbreviation "ODL" signifies the level over detection limit 214 Table 3M. continued Parameters Outfall Carmichael Ditch Shave Tail Creek Soluble Orthophosphate 0.03 0.08 0.1 0.08 0.05 0.08 StDev 0.03 0.08 0.13 0.07 0.03 0.1 N 18 18 18 18 17 18 Median 0.02 0.07 0.08 0.07 0.05 0.06 Range 0 - 0.10 0 - 32 0 - 0.61 0 - 0.24 0 - 0.11 0 - ODL Total Phosphprus 0.04 0.09 0.13 0.09 0.06 0.04 StDev 0.06 0.09 0.15 0.08 0.07 0.05 N 18 18 18 18 17 18 Median 0 0.06 0.06 0.05 0.05 0.01 Range 0 - 0.19 0 - 0.28 0 - 0.60 0 - 0.22 0 - 0.22 0 - 0.16 215 Huffman Ditch Cemetery Run Cecil Ditch APPENDIX N Table 1N. Nutrient loads contributed by each tributary and exported to the White River Nutrient Loads (lbs/yr) Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Nitrate 6150 1470 2100 1390 414 838 Ammonia 584 590 132 183 178 304 Total Nitrogen 8964 2076 3744 1872 468 1272 Particulate Orthophosphate 905 316 412 256 54 78 Soluble Orthophosphate 136 31 92 34 12 22 Total Phosphorus 130 30 111 31 13 8 216 APPENDIX O Table 1O. Ranking Tributaries and outfall based on parameter results. Parameters Outfall Carmichael Ditch Shave Tail Creek Discharge 1 3 2 4 6 5 Nitrate 1 6 3 5 2 4 Ammonia 3 6 3 1 2 3 Total Nitrogen 1 6 3 4 2 5 Particulate Phosphorus 1 6 4 5 2 2 Soluble Orthophosphate 1 3 6 4 2 4 Total Phosphorus 1 3 6 5 3 2 pH 6 3 2 4 5 1 Dissolved Oxygen 1 3 6 4 2 5 Temp 6 2 1 4 5 3 Turbidity 3 5 2 6 4 1 Specific Conductivity 1 5 3 4 2 6 Total: 26 51 41 50 37 41 Rank 1 6 3 5 2 3 217 Huffman Ditch Cemetery Run Cecil Ditch Table 2O. Ranking Tributaries and outfall based on nutrient median concentrations. Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Nitrate 1 4 3 5 2 6 Ammonia 4 6 2 1 3 4 Total Nitrogen 1 6 3 5 1 3 Particulate Phosphorus 1 6 4 5 2 3 Soluble Orthophosphate 1 4 6 5 2 3 Total Phosphorus 1 5 6 4 3 2 Total 9 31 24 25 13 21 Rank 1 6 4 5 2 3 Parameters 218 APPENDIX P Table 1P. Spearman Correlations for tributary parameters (r). Parameters Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Nitrate vs. Discharge -0.64 0.77 -0.24 0.372 -0.10 0.00 Ammonia vs. Discharge -0.22 -0.13 0.56 0.59 -0.19 0.14 Total N vs. Discharge -0.22 0.43 -0.16 0.18 0.10 0.32 Particulate P. vs. Discharge -0.10 -0.02 -0.08 0.13 -0.25 -0.13 Soluble P vs. Discharge 0.37 0.76 0.20 0.44 -0.17 -0.09 Total P vs. Discharge -0.18 0.66 -0.23 0.63 0.02 0.06 219 Nitrate vs. pH -0.86 -0.52 0.47 -0.04 0.66 0.43 Ammonia vs. pH -0.63 -0.42 -0.34 -0.12 -0.13 -0.06 Total N vs. pH -0.63 -0.10 -0.28 -0.54 0.37 0 Particulate P vs pH -0.20 -0.22 -0.31 0.11 -0.45 -0.19 Soluble P vs. pH 0.12 -0.16 0.30 -0.30 -0.19 -0.22 Total P vs. pH -0.29 -0.41 0.22 0.45 -0.24 -0.05 Nitrate vs. Dissolved Oxygen -0.70 0.08 0.46 -0.03 0.36 0.45 Ammonia vs. Dissolved Oxygen -0.83 -0.75 -0.15 -0.13 0.58 0.49 220 Table 1P. continued Parameter Outfall Carmichael Ditch Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Total Nitrogen vs. Dissolved Oxygen -0.83 0.55 -0.23 -0.77 0.51 0.18 0.14 -0.41 -0.42 Particulate Orthophosphate vs Dissolved Oxygen -0.20 -0.38 0.49 Soluble Orthophosphate vs. Dissolved Oxygen 0.10 0.40 0.58 0.21 -0.38 0.18 Total Phosphorus vs. Dissolved Oxygen -0.19 0.17 0.36 0.61 -0.25 0.10 pH vs. Discharge 0.88 -0.33 -0.66 0.61 0.42 0.22 Dissolved Oxygen vs. Discharge 0.82 0.30 -0.66 0.73 0.75 0.39 221 Specific Conductivity vs. Discharge -0.09 0.11 0.72 -0.50 -0.38 0.63 Stream Turbidity vs. Discharge 0.73 -0.34 1.0 -0.58 0.62 -0.27 Temp vs. pH 0.83 0.6 0.97 0.8 0.24 0.73 Temp vs. Dissolved Oxygen 0.82 0.75 0.95 0.87 0.95 0.86 Nitrate vs. Turbidity 0.56 -0.36 0.74 0.04 0.71 0.38 Ammonia vs. Turbidity 0.15 0.51 0.54 -0.25 0.27 0.04 Total Nitrogen vs. Turbidity 0.15 -0.14 0.29 0.08 0.29 0.69 222 Table 1P. continued Parameter Outfall Carmichael Ditch Total Phosphorus vs. Turbidity -0.43 -0.20 -0.34 -0.16 -0.81 -0.70 Particulate Phosphorus vs. Turbidity -0.20 -0.24 -0.11 0.81 -0.89 -0.58 Soluble Orthophosphate vs. Turbidity 0.31 0.27 0.43 -0.37 0.21 0.02 Nitrite vs. Discharge -0.31 -0.05 -0.32 0.10 -0.37 0.30 Nitrite vs. Ph 0.53 0.41 0.92 0.62 -0.30 0.25 Nitrite vs. Dissolved oxygen 0.30 -0.62 0.55 0.70 -0.17 0.48 223 Shave Tail Creek Huffman Ditch Cemetery Run Cecil Ditch Nitrite vs. Turbidity -0.12 -0.48 -0.29 -0.87 0.48 -0.36 Nitrite vs. Total N. -0.29 0.01 -0.29 -0.21 -0.21 -0.17 224 APPENDIX Q Table 1Q Kruskal-Wallis Test: Comparing Nitrate concentration of the tributaries and the outfall. Locations N Median Ave. Rank Z-Score Carmichael Ditch 18 0.7 51.7 1.1 Cecil Ditch 18 0.9 53.7 1.43 Cemetery Run 17 0.55 37.4 -1.2 Huffman Ditch 18 0.8 56.4 1.88 Outfall 18 0.4 29.1 -2.61 Shave Tail Creek 18 0.6 41.2 -0.62 H = 12.95 DF = 5 p = 0.24 (adjusted for ties) 225 Table 2Q. Kruskal-Wallis Test: Comparing ammonia Concentrations of the tributaries and the outfall. Location N Median Ave. Rank Z-score Outfall 17 0.03 53.4 0.37 Carmichael Ditch 17 0.05 66.6 2.41 Shave Tail Creek 17 0.02 52.4 0.21 Huffman Ditch 17 0 32.2 -2.9 Cemetery Run 16 0.03 45.9 -0.76 Cecil Ditch 17 0.03 55.2 0.65 H = 13.23 DF = 5 p = 0.021 226 (adjusted for ties) Table 3Q. Kruskal-Wallis Test: Comparing Discharge Concentrations of the tributaries and the outfall. Location s N Median Ave. Rank Z-Score Carmichael Ditch 18 0.14 32.8 -2.36 Cecil Ditch 17 0.22 38.4 -1.32 Cemetery Run 17 0.34 39.8 -1.07 Huffman Ditch 18 0.30 49.3 0.59 Outfall 13 1.4 60.2 2.09 Shave Tail Creek 8 1.31 74.5 3.2 H = 20.19 DF = 5 p = 0.001 227 (adjusted for ties) Table 4Q. Kruskal-Wallis Test: Comparing Total Nitrogen concentrations of the tributaries and the outfall. Location s n Carmichael Ditch 15 1.3 53.4 1.38 Cecil Ditch 15 0.9 49 0.66 Cemetery Run 14 0.2 33.6 -1.79 Huffman Ditch 15 1 52.5 1.24 Outfall 15 0.2 35 -1.64 Shave Tail Creek 15 0.9 45.6 0.1 H = 8.43 DF = 5 Median Ave. Rank Z-Score (adjusted for ties) 0.134 228 Table 5Q. Kruskal-Wallis Test: Comparing nitrite concentrations of the tributaries and the outfall. Location n median ave. Rank Z Carmichael Ditch 13 0 46.5 1.21 Cecil Ditch 13 0 40 0.08 Cemetery Run 13 0 32.2 -1.27 Outfall 13 0 38.1 -0.24 Huffman Ditch 13 0 39.5 0 Shave Tail Creek 13 0 40.8 0.22 H = 2.67 P= 0.652 Df = 5 229 Table 6Q. Kruskal Wallis Test: comparing particulate P concentrations of the tributaries and outfall Location n median ave. Rank Z Carmichael Ditch 16 0 58.5 1.68 Cecil Ditch 16 0 46 -0.31 Cemetery Run 16 0 42.7 -0.85 Outfall 16 0 46.2 -0.29 Huffman Ditch 16 0 48.9 0.14 Shave Tail Creek 16 0 45.6 -0.38 H = 7.58 P= 0.181 DF = 5 230 Table 7Q. Kruskal-Wallis Test: Comparing Soluble P concentrations of the tributaries and the outfall. * signifies median value above actual median. Location n Carmichael Ditch 18 0.24 51.2 0.51 Cecil Ditch 18 0.2 49.6 0.24 Cemetery Run 17 0.18* 43.2 -0.77 Huffman Ditch 18 0.27* 58.3 1.64 Outfall 18 0.09 25.2 -3.62 Shave Tail Creek 18 0.26 60.7 2.01 DF = 5 p= 0.004 H = 17.32 Median Ave. Rank Z-Score (adjusted for ties) 231 Table 8Q. Kruskal-Wallis Test: Comparing Total P concentrations of the tributaries and the outfall. Locations n Carmichael Ditch 17 0.2 55.3 0.66 Cecil Ditch 17 0.04 37.9 -2.02 Cemetery Run 16 0.15 53.3 0.34 Huffman Ditch 17 0.17 60.2 1.42 Outfall 17 0.03 33.6 -2.68 Shave Tail Creek 17 0.21 65.8 2.29 DF = 5 p= 0.007 H = 15.99 Median Ave. Rank Z-Score (adjusted for ties) 232 Table 9Q. Kruskal-Wallis Test: Comparing pH of the tributaries and the outfall. Locations n Median Ave. Rank Z-Score SE MSD Conclusion Carmichael Ditch 9 6.69 8.2 -4.4 5.24 15.42 N.s. Cecil Ditch 9 7.23 23.6 -0.81 5.24 15.42 N.s. Cemetery Run 9 7.51 36.8 1.95 5.24 15.42 N.s. Huffman Ditch 9 7.47 35.5 1.67 5.24 15.42 N.s. Outfall 9 7.53 37.7 2.14 5.24 15.42 N.s. Shave Tail Creek 9 7.22 23.2 -0.91 5.24 15.42 N.s. H = 24.13 DF = 5 p=0 (adjusted for ties) “S.D." signifies a Significant Difference and "N.s." means no difference. 233 Table 10Q. Kruskal-Wallis Test: Comparing Dissolved Oxygen concentrations of the tributaries and the outfall. Locations n Carmichael Ditch 9 3.17 26.4 -0.12 Cecil Ditch 9 2.45 23.6 -0.73 Cemetery Run 9 3.64 26.4 -0.12 Huffman Ditch 9 3.08 24.5 -0.53 Outfall 9 5.85 36.7 2.07 Shave Tail Creek 9 2.96 24 -0.6 DF = 5 p= 0.466 H = 24.13 Median Ave. Rank Z-Score (adjusted for ties) 234 Table 11Q. Kruskal-Wallis Test: Comparing Temperature of the tributaries and the outfall. Locations n Median Ave. Rank Z-Score Carmichael Ditch 9 16.73 24.6 -0.62 Cecil Ditch 9 17.18 27.1 -0.08 Cemetery Run 9 18.25 28.7 0.24 Huffman Ditch 9 17.43 24.7 -0.59 Outfall 9 20.23 36.1 1.79 Shave Tail Creek 9 17.92 23.9 -0.74 H = 3.78 DF = 5 p= 0.581 (adjusted for ties) 235 Table 12Q. Kruskal-Wallis Test: Comparing Specific Conductivity of the tributaries and the outfall. Locations n Median Ave. Rank Z-Score SE MSD Carmichael Ditch 9 690.6 34.1 1.8 5.24 15.42 Cecil Ditch 9 780.8 45.4 3.72 5.24 15.42 Cemetery Run 9 643.8 20.9 -1.06 5.24 15.42 Huffman Ditch 9 670.5 27.7 0.37 5.24 15.42 Outfall 9 349.5 7.1 -4.2 5.24 15.42 Shave Tail Creek 9 667.3 24.6 -0.32 5.24 15.42 H = 24.13 DF = 5 p=0 (adjusted for ties) 236 Table 13Q. Kruskal-Wallis Test: Comparing Turbidity of the tributaries and the outfall. Locations n Carmichael Ditch 7 24.7 25.8 1.48 Cecil Ditch 6 19.15 16.9 -0.72 Cemetery Run 7 28.4 23.9 1.01 Huffman Ditch 7 19.3 20.5 0.13 Outfall 6 16.35 14.4 -1.3 Shave Tail Creek 6 19.2 16.8 -0.76 DF = 5 p= 0.414 H = 5.01 Median Ave. Rank Z-Score (adjusted for ties) 237 APPENDIX R Table 1R. Multiple comparison test for ammonia concentrations for the tributaries. Comparison (R1 - R2) n1 n2 SE MSD Conclusion Carmichael Ditch -outfall 13.2 17 17 10.05 29.55 N.s. Shave Tail Creek - outfall -1 17 17 10.05 29.55 N.s. Huffman Ditch - outfall -21.2 17 17 10.05 29.55 N.s. Cemetery Run -outfall -7.5 16 17 10.21 30.02 N.s. Cecil Ditch - outfall 1.8 17 17 10.05 29.55 N.s. Carmichael Ditch - Shave Tail Creek 14.2 17 17 10.05 29.55 N.s. Carmichael Ditch - Huffman Ditch 34.4 17 17 10.05 29.55 S.D. Carmichael Ditch - Cemetery Run 20.7 17 16 10.21 30.02 N.s. Carmichael Ditch - Cecil Ditch 11.4 17 17 10.05 29.55 N.s. Shave Tail Creek - Huffman Ditch 20.2 17 17 10.05 29.55 N.s. Shave Tail Creek - Cemetery Run 6.5 17 16 10.21 30.02 N.s. Shave Tail Creek - Cecil Ditch -2.8 17 17 10.05 29.55 N.s. Huffman Ditch - Cemetery Run -13.7 17 16 10.21 30.02 N.s. Huffman Ditch - Cecil Ditch -23 17 17 10.05 29.55 N.s. Cemetery Run - Cecil Ditch -9.3 16 17 10.21 30.02 N.s. "S.D." signifies a Significant Difference and "N.s." means no difference. 238 Table 2R. Multiple comparison test for discharge of the tributaries and outfall. Comparison (R1 - R2) n1 n2 SE MSD Conclusion outfall - Carmichael Ditch 27.4 13 18 9.61 28.25 N.s. outfall - Shave Tail Creek -14.3 13 8 11.87 34.9 N.s. outfall - Huffman Ditch 10.9 13 18 9.61 28.25 N.s. outfall - Cemetery Run 20.4 13 17 9.73 28.61 N.s. outfall - Cecil Ditch 21.8 13 17 9.73 28.61 N.s. Carmichael Ditch - Huffman Ditch -16.5 18 17 8.93 26.25 N.s. Carmichael Ditch - Cemetery Run -7 18 17 8.93 26.25 N.s. Carmichael Ditch - Cecil Ditch -5.6 18 17 8.93 26.25 N.s. Shave Tail Creek - Carmichael Ditch 41.7 18 8 11.87 34.9 S.D. Shave Tail Creek - Huffman Ditch 14.3 8 17 11.87 34.9 N.s. Shave Tail Creek - Cemetery Run 34.7 8 17 11.87 34.9 S.D. Shave Tail Creek - Cecil Ditch 36.1 8 17 11.87 34.9 S.D. Huffman Ditch - Cemetery Run 9.5 18 17 8.93 26.25 N.s. Huffman Ditch - Cecil Ditch 10.9 18 17 8.93 26.25 N.s. Cemetery Run - Cecil Ditch 1.4 17 17 9.06 26.64 N.s. "S.D." signifies a Significant Difference and "N.s." means no difference. 239 Table 3R. Multiple comparison test for particulate orthophosphate concentrations for the tributaries. Comparison (R1 - R2) n1 n2 SE MSD Conclusion Carmichael Ditch -outfall 43.8 18 18 10.34 30.4 S.D. Shave Tail Creek - outfall 25.2 18 18 10.34 30.4 N.s. Huffman Ditch - outfall 38.5 18 18 10.34 30.4 S.D. Cemetery Run -outfall 10 17 18 10.5 30.87 N.s. Cecil Ditch - outfall 19.2 18 18 10.34 30.4 N.s. Carmichael Ditch - Shave Tail Creek 18.6 18 18 10.34 30.4 N.s. Carmichael Ditch - Huffman Ditch 5.3 18 18 10.34 30.4 N.s. Carmichael Ditch - Cemetery Run 33.8 18 17 10.5 30.87 S.D. Carmichael Ditch - Cecil Ditch 24.6 18 18 10.34 30.4 N.s. Shave Tail Creek - Huffman Ditch -13.3 18 18 10.34 30.4 N.s. Shave Tail Creek - Cemetery Run 15.2 18 18 10.34 30.4 N.s. Shave Tail Creek - Cecil Ditch 6 18 18 10.34 30.4 N.s. Huffman Ditch - Cemetery Run 28.5 18 17 10.5 30.87 N.s. Huffman Ditch - Cecil Ditch 19.3 18 18 10.34 30.4 N.s. Cemetery Run - Cecil Ditch -9.2 17 18 10.5 30.87 N.s. "S.D." signifies a Significant Difference and "N.s." means no difference. 240 Table 4R. Multiple comparison test for soluble orthophosphate concentrations for the tributaries. Comparison (R1 - R2) n1 n2 SE MSD Conclusion Carmichael Ditch -outfall 26 18 18 10.34 30.4 N.s. Shave Tail Creek - outfall 35.5 18 18 10.34 30.4 S.D. Huffman Ditch - outfall 33.1 18 18 10.34 30.4 S.D. Cemetery Run -outfall 18 18 17 10.5 30.87 N.s. Cecil Ditch - outfall 24.4 18 18 10.34 30.4 N.s. Carmichael Ditch - Shave Tail Creek -9.5 18 18 10.34 30.4 N.s. Carmichael Ditch - Huffman Ditch -7.1 18 18 10.34 30.4 N.s. Carmichael Ditch - Cemetery Run 8 18 17 10.5 30.87 N.s. Carmichael Ditch - Cecil Ditch 1.6 18 18 10.34 30.4 N.s. Shave Tail Creek - Huffman Ditch 2.4 18 18 10.34 30.4 N.s. Shave Tail Creek - Cemetery Run 17.5 18 18 10.34 30.4 N.s. Shave Tail Creek - Cecil Ditch 17.5 18 18 10.34 30.4 N.s. Huffman Ditch - Cemetery Run 15.1 18 17 10.5 30.87 N.s. Huffman Ditch - Cecil Ditch 8.7 18 18 10.34 30.4 N.s. Cemetery Run - Cecil Ditch -6.4 17 18 10.5 30.87 N.s. “S.D." signifies a Significant Difference and "N.s." means no difference. 241 Table 5R. Multiple comparison test for Specific Conductivity concentrations for the tributaries. Comparison Conclusion Carmichael Ditch -outfall S.D. Shave Tail Creek - outfall S.D. Huffman Ditch - outfall S.D. Cemetery Run -outfall N.s. Cecil Ditch - outfall S.D. Carmichael Ditch - Shave Tail Creek N.s. Carmichael Ditch - Huffman Ditch N.s. Carmichael Ditch - Cemetery Run N.s. Carmichael Ditch - Cecil Ditch N.s. Shave Tail Creek - Huffman Ditch N.s. Shave Tail Creek - Cemetery Run N.s. Shave Tail Creek - Cecil Ditch N.s. Huffman Ditch - Cemetery Run N.s. Huffman Ditch - Cecil Ditch N.s. Cemetery Run - Cecil Ditch N.s. "S.D." signifies a Significant Difference and "N.s." means no difference. 242 Table 6R. Multiple comparison test for Total Phosphorus concentrations for the tributaries. Comparison (R1 - R2) n1 n2 SE MSD Conclusion Carmichael Ditch -outfall 21.7 17 17 10.05 29.55 N.s. Shave Tail Creek - outfall 32.2 17 17 10.05 29.55 S.D. Huffman Ditch - outfall 26.6 17 17 10.05 29.55 N.s. Cemetery Run -outfall 19.7 16 17 10.21 30.02 N.s. Cecil Ditch - outfall 4.3 17 17 10.05 29.55 N.s. Carmichael Ditch - Shave Tail Creek -10.5 17 17 10.05 29.55 N.s. Carmichael Ditch - Huffman Ditch -4.9 17 17 10.05 29.55 N.s. Carmichael Ditch - Cemetery Run 2 17 16 10.21 30.02 N.s. Carmichael Ditch - Cecil Ditch 17.4 17 17 10.05 29.55 N.s. Shave Tail Creek - Huffman Ditch 5.6 17 17 10.05 29.55 N.s. Shave Tail Creek - Cemetery Run 12.5 17 16 10.21 30.02 N.s. Shave Tail Creek - Cecil Ditch 27.9 17 17 10.05 29.55 N.s. Huffman Ditch - Cemetery Run 6.9 17 16 10.21 30.02 N.s. Huffman Ditch - Cecil Ditch 22.3 17 17 10.05 29.55 N.s. Cemetery Run - Cecil Ditch 15.4 16 17 10.21 30.02 N.s. "S.D." signifies a Significant Difference and "N.s." means no difference. 243