New Mexico Bureau of Mines and Mineral Open FileReport No. OF-237 Resources ORGANIC GEOCHEMICAL ANALYSIS, PLYMOUTH OIL CO. NO. 1 FEDERAL WELL, OTERO COUNTY, NEW MEXICO by Stephen R. Jacobson, JamesS . Rankin and James D. Saxton Chevron U.S.A., Inc. Denver, Colorado and GaryW. Ruth Brown and Ruth Laboratories, Inc. Houston, Texas May 11, 1984 . Mr. S. Thompson I11 New MexicoBureau of Minesand Mineral Resources S o c o r r o , NM 87801 . Dear Mr. Thompson: E n c l o s e dp l e a s ef i n dt h ec q m p l e t e dr e s u l t s of theorganicgeochemicalanalyses performed on samples from the Gulf #l S i e r r a S t a t e "K", 35-125-1W, S i e r r a Co., and t h e Plymouth #1 F e d e r a l , 15-20S-9E, Otero Co. Enclosed also i s t h ec o r r e c t e d r e p o r t for t h e H o u s t o n O i l and Minerals well. A s you may r e c a l l t h e r e w a s a mix-up with the samples, and we a c t u a l l y a n a l y z e d t h e #2 Lewelling (10-12S-9E, 0::ero C o . ) , r a t h e r t h a n t h e #l Lewelling (12-12S-9E)., Sincerely, pdk S. V i e t t i I District G e o l o g i s t Enclosures L IO I I 0 N Z 0 0 0 E n tI a t- %$ \ * * * I I I I I I ! .. GEOCHEMICAL REPORT December 30, 1983 Chevron U.S.A. Inc. Central Region P.O. Box 599 Denver. Colorado 80201 Attention: S. R. Jacobson Federal Well, Otero, New Mexico. The work was-authorized by Order No. CMEN 2100 of Decmeber 2 , 1983. your Work All unused sample material is being returned under separate cover. We appreciatetheopportunitytobe of service to Chevron. questions regarding these data, then please contact us. If you haveany Very truly yours, BROWN 8 RUTHLABORATORIES, Gary W. Ruth GWRlkrll Enclosures INC. QEOCHEMICAL REPORT CLIENT: CHEVRON U . S . A . , INC. P.O.Box 599 Denver, Colorado 80201 WELL: Plymouth #1 Federal LOCATION: Sec. 15-T20S-R9E OteroCounty, New Mexico - 934 SAMPLEMATERIAL: A total of 46 samples of cuttings werereceived. and no evidence Eachwas in good condition, of contamination was apparent. SAMPLEPREPARATION: Priortoanalysis, each sample was visually examined for contaminants. of the samples were taken, ground to a fine powder, and then analyzed. Splits DATAPRESENTATION: The results of the analyses are presented in the attached Table I. following criteria are suggested for interpreting the pyrolysis data: I SOURCE POTENTIAL I PETROLEUM TYPE c2.0 POOR 2.0-5.0 MARGINAL 200-500 MIXED s5.0 GOOD GAS PRONE <2.5 ( 2 0 0 5 ,0 0 OIL PRONE DRY GAS 2.5-5.0 WETGAS >s.o OIL e440 IMMATURF 440-410 I OIL s m GAS I The TABLE I Results of OrganicCarbon Analysis and Rock-Eva1 Pyrolysis ~~~~~ ~ Client I.D. Sample Number T.O.C. (% Wt.) 52 (mglg) Production Tmax S3 , Index (mglg) ("C) ,L:dc.n.!c ; a.10 0.15 0.46 422 "- 0.12 0.10 0.32 375 0.55 < 0.10 a.10 0.31 ** "- 0.15 0.43 372 0.53 (0.10 0.42 451 -" "- "- 46 s1 (mglg) rrc, -",P'? I"{ ,$,,J!, rp 934- 01 /3C /;I P4400-1 600- 0 $ 934-002 P4400-2 ,yb,~i;1200-1300 934-004 P4400-4 vJ.C. 2200-2300 934-005 P4400-5 2600-2700 LdJL 0.16 (0.10 40 s-3 Hydrogen Index 0.34 31 0.32 13 S2 "57 0.34 I "- Oxyger Index 94 33 19 934-006 P4400-6 v J C + 2800-2900 0.10 (0.10 0.44 ** "- -" "- 46 934-007 P4400-7 L.JL, 3100-3200 0.10 (0.10 0.48 ** "- "- "- 49 934-008 P4400-8 VJL 3240-3300 0.23 0.18 0.48 367 0.56 934-009 P4400-9 n~ 3300-3400 (0.10 (0.10 0.39 ** "- "- -" 40 0.12 (0.10 0.40 ** "- "- "- 42 (U.10 (0.10 0.48 ** "- "- -" 39 (0.10 (0.10 0.54 ** "- "- "- 58 40 0.37 15 I I 331-313 @rk' fts0 8,.fid i - 5.p 934-011 P1100-10 3500-3600 P4400-11 ,195, 3600-3700 934-012 P4400-12 3700-3800 ! ti TABLE I R e s u l t s of O r g a n i c C a r b o n A n a l y s i s s1 s2 (mglg) (mglg) Tmax S3 ( m g l g ) (OC) 0.25 0.14 0.49 ** 0.64 0.28 P4400-14 0.13 1.28 3850-3900 6 ' 9 LJ (0.10 0.42 ** "- --- -" 33 P4400-15 0.16 1.50 3900-3950 &man <o. 10 0.45 ** -" --- -" 30 0.26 0.53 351 0.60 0.49 (0.10 0.48 ** "- "- 0.19 0.55 367 0.58 0.34 14 39 0.32 0.43 359 0.64 0.73 18 25 0.14 0.49 376 0.66 0.29 11 40 0.23 0.49 343 0.68 0.48 15 31 0.31 0.41 353 0.81 0.75 20 21 0.24 0.34 357 0.68 0.69 12 18 0.21 0.56 351 0.69 0.37 10 27 Sample Number Client I.D. T.O.C. (%Wt.) 934-013 P4400-13 3800-3850 1.93 p,5 934-014 P3 934-015 ?. * 934-016 P4400-16 9.5. 934-018 P4400-18 0.26 1.39 4100-4150 RJ?; 5 , 4150-4200 934-020 P4400-20 Pfr. 934-021 P4400-21 0 , 4260-4320 ~ 934-022 P4400-22 p.3 ~ p,5 934-024 !1 dqIt1 - <&, 7.4 25 11 22 -" 36 0.27 GFOd 1.55 0.50 &.t:t? 0.49 1.54 4320-4370 6@* 4400-4460 0.50 1.92 f5dfl 934-023 P4400-23 7 Oxygen Index 46b0 1.23 4200-4250 Hydrogen Index 6a f9 0.55 1.76 934-019 P4400-19 52 3-3 , (*refi' P4400-17 0.13 1.34 4020-4100 p.5. Production Index &'a& 0.39 2.40 3950-4020 934-017 m d Rock-Eva1 Pyrolysis P4400-24 0.47 2.09 4460-4520 v. 6 4 f.. TABLE I R e s u l t s of O r g a n i c C a r b o n A n a l y s i s Client I.D. Sample Number T.O.C. (%Wt.) s1 s2 (mglg) (mglg) ( m g l g ) (OC) Index 0.17 0.41 0.42 354 0.72 0.43 1.92 934-025 P4400-25 w . 4520-4600 &-?# 934-026 P4400-26 4600-4700 LLM? 1.59 6;crbB 0.37 P4400-27 0.30 1.53 4700-4800 G/D4 934-027 and Rock-Eval Pyrolysis 53 Tmax Production S2 s3 Hydrogen Index Oxygen Index 21 (0.10 0.39 362 -" "- 25 (0.10 0.38 ** -" "_ 25 0.12 0.43 340 0.79 0.29 23 (0.10 0.27 346 "- "- 15 (0.10 0.28 368 -" -" 27 (0.10 0.28 357 -" -" 15 c4-4~ 934-028 r P4400-28 0.47 1.82 4800-4900 a- 934-029 P4400-29 L&7f, 4900-5000 1.02 934-030 P4400-30 M. 934-031 P4400-31 &V. 934632 C6-r 5000-5040 0.28 w& 0.46 1.84 cgod 5040-5100 P4400-32 5100-5200 934-033 P4400-33 C&?9 0.46 1.76 6,?& 5200-5260 1.58 G.cfld- 0.29 0.14 0.29 0.47 359 0.69 18 1.31 0.25 0.10 0.29 0.35362 0.71 22 * .::.+'@ ** "- 0.32 356 -" 0.27 ** "- - P4400-34 0.17 1.25 5?53-5333 66 0 4 (0.10 0.33 (0.10 57-4. P4400-35 0.22 1.19 ad) 5300-5400 - (0.10 934-034 P+l SA?& 934-035 934-036 . q. ,? P4400-36 0.15 0.97 5400-5500 Fd/Z , A d "- -" 26 27 -" 28 . TABLE I Results of OrganicCarbon Analysis andRock-Eva1 Sample Number Client I.D. s1 (mglg) T.O.C. (% Wt.) s2 (mg/g) Tmax S3 (mglg) (OC) Pyrolysis Production Index S2 s.3 Hydrogen Index Oxygen Index 934-037 P4400-37 5500-5600 0.19 (0.10 0.33 ** 30 934-038 P4400-38 5600-5700 0.28 0.12 0.39 366 34 934-039 P4400-39 fnz 5710-5800 0.22 (0.10 0.32 ** 36 934-040 P4400-40 / 5800-5860 0.12 (0.10 0.24 ** 27 934-041 P4400-41 &M46000-6070 0.14 (0.10 0.34 370 33 934-042 P4400-42 +,&'+?, 6150-6170 0.26 (0.10 0.42 ** 44 934-043 P4400-43 0.20 (0.10 0.35 350 48 934-044 P4400-44 0.19 (0.10 0.35 ** 44 934-045 P4400-45 - ,f3 6560-6590 0.12 (0.10 0.29 ** 90 0.49 360 24 532. $72 fa- q&', 934-046 P4400-46 Mj55 - . PF45 J,'/ 7 6700-6800 0.57 0.21 7 **Unable to determine due to insufficient S2 yicld. multiple peaks, etc.