New Mexico Bureauof Mines and Mineral Resources Open File Report No. OF-236 ORGANIC GEOCJBMICAL ANALYSIS, GULF OIL CORF'. NO. 1 SIERRA STATE K WELL, SIERRA COUNTY, N E W MEXICO By Stephen R. Jacobson, James S. Rankiri, and James D. Saxton Chevron U.S.A., Inc. Denver, Colorado and Gary W. Ruth Brown and Ruth Laboratories, Inc. Houston, Texas May 11, 1984 Chevron Chevron U.S.A. Inc. U 700 South Colorado Blvd., P. 0. Box 599,Denver, CO 80201 May 11, 1984 M r . S. Thompson 111 New Mexico Bureau of , Mines and Mineral Resources Socorro, NM 87801 Dear Mr. Thompson: E n c l o s e dp l e a s ef i n dt h ec o m p l e t e dr e s u l t s of theorganicgeochemicalanalyses 411 S i e r r a S t a t e "K", 35-12S-lW, S i e r r s . Co., and performed on samples from the Gulf the Plymouth #I F e d e r a l , 15-20S-9E, Otero Co. Enclosed also i s t h ec o r r e c t e d r e p o r t f o r t h e H o u s t o n O i l and Minerals well. As you may r e c a l l t h e r e was a mix-up we a c t u a l l y a n a l y z e d t h e #2 Lewelling (10-12S-9E, O t e r o C o . ) , with the samples, and rather than the #1 Lewelling (12-12S-9E). D i s t r iG c te o l o g i s t Enclosures . 0 0 + i '1 .* I. ,. :I .. , 2 " fa 5 i: if' I -1. . - - - - . ..-.. -_ " ,"" *r .. . . . GEOCHEMICAL REPORT TOC & Rock-Eva1 P y r o l y s i s R e s u l t s Gulf Oil Sierra S t a t e "K" Sierrfl INC. BROWN & RUTHLABORATORIES, 10690 Shadow Wood, S u i t e 130 Houston, T e x a s 77043 7131464-3284 .... . .. . ~ .. September 22, 1983 Chevron U.S.A. Inc. Central Region P. 0. Box 599 Denver, CO 80201 Attention: S . R. Jacobson Gentlemen: Attached are the results of our analysis of the 25 samples from Gulf Oil Sierra State "Kt',SierraCounty, New Mexico, The workwas authorized by y?ur Work No. CMEN2100. All unused sample is being returned under separate cover. We appreciate the opportunity to be questions regarding these data, then of service to Chevron. pleasecontact us. If you have any Very truly yours, BROWN B RUTH LABORATORIES, INC. Gary GWRlkrll9 Enclosures x. Ruth GEOCHEMICAL REPORT - 746 CLIENT: CHEVRON U.S.A. INC. P. 0. Box 599 Denver. Colorado 80201 WELL: Gulf Sierra State "K" LOCATION: Sierra County, NewMexico 35-125-1W SAMPLEMATERIAL: A total of 25 samples ofwell cuttings were received. Each appeared i l reasonably good condition, and no evidence ofmajor contamination was apparent. SAMPLEPREPARATION: Eachsamplewas visually examined for contaminants and cleaned where necessary.Splits of the samples were taken,groundtoafinepowder,and then analyzed. D A T A EVALUATION: The results of the analyses are presented in the attached criteria are suggested for interpreting the pyrolysis data: SOURCE POTENTIAL s2 4 PETROLEUM TYPE HYDROGEN INDEX DRY GAS MARGINAL 200-300 MIXED 2.5-5.0 WET GAS GOOD >5.O OIL POOR 2D-5.0 >5.0 e200 GASPRONE ~ 3 0 0OILPRONE The following THERMAL MATURITY s2Is3 e25 e2.0 Table. Tmax e440 WMATU3E 440-470 >470 OIL GAS .I TABLE I Gulf Oil Sierra State "K" Sierra County. New Mexico File No. 746 1983September 21, I Results of OrganicCarbon Analysis and Rock-Eva1 Pyrolysis Client Sample Number 746-001 I 746-004 746-005 1 I 746-006 746-007 i 746-009 746-010 746-011 I.D. P4256-1 900-960' T.O.C. (%Wt.) s1 (mglg) s2 (mglg) . GmD. S3 Tmax ( m g l g ) (OC) Production Index S2 53 i Hydrogen Index 24 2.00 48 38 1.34 51 Oxygen Index 1.30 0.19 0.62 ' 0.31 P4256-2 980-1000' 0.99 0.22 0.50 0.38 458 0.31 P4256-3 1000-1040' 1.03 0.25 0.53 0.37 458 0.32 1.44 52 36 P4256-4 1040-1070' 1.02 0.22 0.63 0.39 452 0.26 1.62 61 38 P4256-5 1070-1100' 0.84 0.21 0.47 0.37 458 0.31 44 1.27 56 P4256-6 1100-1160' 1.03 0.35 0.75 0.28 456 0.32 28 2.66 73 P4256-7 1170-1200' 0.88 0.25 0.53 0.22 455 0.32 2.39 60 25 P4256-8 1290-1350' 0.68 0.17 0.34 0.25 456 0.34 1.38 50 36 P4256-9 1350-1400' 0.76 0.15 0.24 0.31 465 0.39 41 0.76 31 P4256-10 1400-1450' 0.87 0.24 0.75 0.32 37 2.34 86 P4256-11 1560-1600' 0.94 0.32 0.59 0.38 40 1.55 63 464 0.23 i 1 ' - TABLE I Gulf Oil Sierra State "K" File N o . 746 September 21. 1983 Sierra County, N e w Mexico Results of OrganicCarbon Analysis andRock-Eva1 Sample Number Client I.D. 746-012 P4256-12 1640-1680' T.O.C. (%Wt.) 1.09 s1 (mglg) 52 (mglg) S3 Tmax (mglg) ( O C ) 0.29 465 Pyrolysis Production Index s3 S2 Hydrogen Index 29 1.78 52 P4ld tf 746-013 746-014 746-015 746-016 746-017 746-018 746-019 746-020 Oxygen Index 0.79 0.14 (0.10 ** "- "_ 42 P4256-I4 5510-5540' 1.51 0.26 (0.10 ** "- -" 33 P4256-15 5580-5620' 0.82 0.14 (0.10 0.40 ** "- "_ 49 P4256-16 5620-5660' 0.84 0.13 (0.10 0.42 ** -" "_ 50 P4256-17 6000-6030' 1.53 0.38 (0.10 0.53 ** "_ "_ 35 0.35 (0.10 0.23 ** "_ "- 11 0.95 < 0.10 (0.10 0.21 ** "- "_ 22 7120-7200' 1.40 0.11 (0.10 0.28 ** "- _" 20 P4256-21 7290-7350' 1.28 0.12 (0.10 0.33 ** P4256-22 7380-7450' 1.10 < 0.10 (0.10 0.29 ** "_ "_ "_ _" P4256-13 5480-5510' P4256-18 6030-6080 P4256-19 6230-6270' G@13 > $:( P4256-20 26 26 TABLE I File No. 746 September 21, 1983 Gulf Oil Sierra State "K" Sierra County, NewMexico Results of Organic Carbon Analysis andRock-Eval Sample Number bpi. Client I.D. fl/" 746-023P4256-23 7450-7500' nl,5" 746-024 P4256-24 1.27 7550-7600' T.O.C. (%Wt.) s1 (mglg) s2 S3 (mglg) (mglg) 1.08 (0.10 (0.10 0.36 . (0.10 c . 1 0 Tmax (OC) Production Index "_ ** !-J, .-"-/ _I 0.39 I 414 i- Pyrolysis G P'",,, \P' fl --5% S2 53 -" 0.27 Hydrogen Index "- Oxygen Index 34 8 30 p 2r' 0. ri.',f-+ 746-025P4256-25 7600-7700' 1.25 (0.10 **Unable to determine duetoinsufficient (0.10 0.38 ** S2 yield, multiple peaks, etc. --- "- -" 31