New Mexico Bureau of Mines and Mineral Resources Open File Report No. O F 200 HYDROCARBON SOURCE-ROCK EVALUATION STUDY, CITIES S E R V I P NO. 1 CORRALITOS FEDERAL A WELL1 DONA ANA COUNTY, NEW MEXICO by. Douglas A. Muckelroy GeoChem Laboratoriesr Inc. Houston, Texas November 2gr 1982 QEoCHEMICAL SOURCE ROCK EVALUATION CRUDE OIL-SOURCE ROCK CORRELATION CRUDE OIL CHARACTERIZATION pRospEcTING November 2 9 , 1982 Clayton S. Valder Marshall R. Young O i l Co. 750 West F i f t h S t r e e t Fort Worth, Texas 76102 Dear Mr. Valder: E n c l o s e dp l e a s ef i n dt h er e s u l t s of theorganicgeochemicalanalysesperformed on a s u i t e of f o r t y (40) drywellcuttingssamples from t h e Cities S e r v i c e s No.1 DonaAna County (22s-2W-61, New Mexico. Corralitos Federal A Well,locatedin Upon a r r i v a l a t GeoChem these samples were assigned the GeoChem Job Number 2371 and were submittedtothefollowingorganicgeochemicalanalyses: Table - Type of Analyses Totalorganiccarbonanalyses and brief lithological descriptions...... Organiccarbonanalyses and gross l i t h o l o g i c a l descriptions............... Rock-Eva1 p y r o l y s i s ...........I' .......I1 ............................. I11 Summary of C15+ s o x h l e t e x t r a c t i o n deasphaltening and l i q u i d chromatography ......................................... I V S a t u r a t e h y d r o c a r b o n a n a l y s i s ..................V; chromatograms Visual kerogen assessment......................VI V i t r i n i t e reflectance..........................VII; histograms Clayton S . Valder -2- November 1982 29, RESULTS AND INTERPRETATIONS A. Thermal M a t u r i t y The thermal maturity of the sediments penetrated by t h e Cities S e r v i c e No.1 I+ C o r r a l i t o s F e d e r a l A Well range from animmatureMaturationIndexStage t o 2- a t 1120+ f e e t (UpperHuecoFormation) t o a mature Maturation Index Stage 3 t o 3+-at 5130+ f e e t T.D., (Bliss Formation). - - The sediments of t h e UpperHueco Formation (1060+ f e e t t o 1230+ f e e t ) have experienced a f a i r l y low g e o t h e r m a l h i s t o r y and 'Fan be r a t e d a; immature (mean Stage 1+ t o 2-; T a b l eV I ) .T h i sr a t i n g i s based on theyellow-orange c o l o r a t i o no ft h er e c o g n i z a b l e amorphous, herbaceousand woody o r g a n i c matter t y p e s i s o l a t e d i n t h e visual k e r o g e n a n a l y s i s ( T a b l e V I ) . A t t h i s level ofthermalmaturitythesesedimentsareconsideredto beabove t h e o i l - g e n e r a t i n g window, wherein biogenic gas and immature o i l c o u l d have been.generated. The sediments from thePermian(EpitahFormation; 1300+ f e e t ) down through the Pennsylvanian (MagdalenaFormation; 2986+ f e e t ) a r e r a t e d a s m o d e r a t e l y T h i s s t a t e ofthermalmaturity is mature (mean Stage 2 t o 2+; Table V I ) . based on t h e orange-brown t o l i g h t brown c o l o r a t i o n of the recognizable amorphousand secondarywoody-structureddebriscontainedinthekerogen i s o l a t e d from t h ec u t t i n g ss a m p l e s( T a b l e VI). T h i sr a t i n g is supportedby themoderatelymatureratingsdetected from t h e v i t r i n i t e r e f l e c t a n c e a n a l y s i s on samples 2371-013, -016, -016 and -021 (0.64% Ro avg.;Table VII; chromatograms). A t a moderately mature Yaturation Index these sediments are located in the upper portion of t h e o i l - g e n e r a t i n g window, whereinanimmatureheavy and associatedgascouldhavebeengenerated. oil The M i s s i s s i p p i a n (Lake V a l l e y ) andDevonian (Percha) sediments were n o t a thermalmaturityranging from a a v a i l a b l ef o ra n a l y s e s ,b u ts h o u l dh a v e t o a mature moderately mature Maturation Index Stage (approximately Maturation Index Stage (approximately 3-). L+) The remainingsediments,Silurian(Fusselman) down throughthe Cambrian ( B l i s s )a r er a t e da st h e r m a l l ym a t u r e (mean Stage 3- t o 3 ; TableVI).This r a t i n g is based on the l i g h t brown t o brown c o l o r a t i o n of the r e c o g n i z a b l e amorphous d e b r i s c o n t a i n e d i n the k e r o g e n i s o l a t e d from t h e c u t t i n g s s a m p l e s (Table V I ) . Clayton S . Valder B. -3- November 29, 1982 S o u r c eC h a r a c t e r i z a t i o n The Pennsylvanian (Magdalena Formation) sediments have a moderately mature, poor t o p o s s i b l y f a i r o i l and a s s o c i a t e dg a ss o u r c ec h a r a c t e r .T h i s amountsof organic matter (0.22% avg. i n t e r p r e t a t i o n i s basedonthefair I ) analyzed,which i s comprised of t h e c a r b o n a t et o t a lo r g a n i cc a r b o n ;T a b l e o i l - p r o n e amorphous and secondary gas-prone woody m a t t e r t y p e s ( T a b l e V I ) . Thisfairrating i s supported by t h e good amountsof t o t a l h y d r o c a r b o n (262 ppm; TableIV)detected i n t h e C15+ s o x h l e t e x t r a c t i o n , d e a s p h a l t e n i n g and liquid chromatography analyses. from t h e C i t i e s S e r v i c e No.1 C o r r a l i t o s The remainingsedimentsanalyzed o r g a n i c m a t t e r (0.07% avg.carbonate F e d e r a l A Well contain poor amountsof I) t o t a lo r g a n i cc a r b o n and 0.22% avg. c l a s t i c t o t a l o r g a n i c c a r b o n ; T a b l e and a r e c o n s i d e r e d t o have a poorhydrocarbonsourcecharacter. Should we beofany furtherassistanceconcerningthisstudyor m a t t e r , p l e a s e do n o t h e s i t a t e t o c a l l upon US. any o t h e r Yours t r u l y , Dougla&A. Muckelroy GECCHEM LABORATORIES, st Enclosures # INC. I Sumnary Table 1 Cities Sewice NO. 1 Corralitor Fed. A .............................................. hssibly "_""""""""""""""" EP u iPh I 1" MOO Culmite. pinkish gray; shale. u1 gray. m e d i (2) 0.07 Odcrataly mtYr8, n.a. n.a. 0Olai.tlc. b m i s h 14W gray; shale. and (5) C d M i 1740 chert. 0.08 n.a. n.a. ---------------------""-.""""""""""""""""""""""~"""""""""",~ .. Shale, greenish n.a. n.r. n.a. n.a. W,U ('),- (2) 0.15 0.02 0.06 n.a. n... &&A 2230 gray. 0.37 0.02 0.07 n.a. n.a. kkk- 11) (1) 0.63 lbdsntely swm. pwr 011 and associated ws s o u m ChaNcter. 2 &t n.a. W e r a t e l y slum. pwr oil and1SsOCiated gas source character. 2 toz, 0.62 elated *as source cbractar. .. 21W (1) 11) 2 to 2 t 72 to 2t7 M;&(I) red: siltstone. grayish red; dolonfte. branfsh gray. 1740- ' ..a. pmr oil m b associated gas source character. (1) ' ......................................................... Shale. =dim dark gray;~dolmite and mdcraiely amre. pwr to Lwer 21W- linestone. bmmish (2) (2) possibly f a i r (2) and HlRO Oil ISSO- Sumnary Table 1 Cities Service 110. 1 Corralitos Fed. A 0EVONlP.N - Porcha 32603580 No sanple available - 3580- Oolalte, light 3890 brmmish gray. 0.06 n.a. n.a. (1) 177 (1) 86 (1) ti%-;- %Po4240 Dolmite, brmmish gray. 0.12 (4) (2) 0.08 (2) 0.08 n.8. n.a. (1) h*-;- for analyses. SlLuRIM Fusselnn (4) (1) 3- 0.69 (11 poor Mature. 011 and associated gas swne character. (1) 3- t o 3 0.75 (1) Ilature. poor o i l and associated gas swne character. oRwYICIu( )IntOya ............................................... E l Paro 62405060 . Dolomite. bWmish gray; linestone. bmmish gray. 0.07 Dolomite. bruwnish gray. 0.04 (8) (1) 0.04 . (1) (1) 0.06 n.a. n.a. An;-;- n.a. n.a. n.a. (1) kn,-;- (; 1 n.a. Mature.poor o i l and assoclated gas source character. n.a. Mature. p O O r o i l and assoclated gas source character. ORMJVICIP.N/CAPBRlAN 5060- 8111s 5129 1.0. (1) n.a. -3 (1) t o 3t fable I SCREEN ANALYSIS S W R Y GeoChem Sample Number We11 Interval (Feet) Brief Lithological Description Total O r m a = Carbon (%of RsdkJ) 2371-001 1060-1070 60% Shale, grayish red and greenish gray. 40% Anhydrite, white. Traces o f tourmaline and b i o t i t e . 0.07 2371-002 1090-1100 60% Shale, grayish red and greenish gray. 40% Anhydrite, white. 0.08 - Traces o f tourmaline and biotite. 2371-003 1120-1130 70% Shale, greenish gray and grayish red. 30% Anhydrite, white. Traces o f tourmaline and biotite. 0.20 2371-004 1150-1160 80% Shale, greenish gray and grayish red. 20% Anhydrite, white. Traces o f tourmaline and biotite. 0.17 :2371-005 1180-1190 85% Shale,greenish gray. 15%Anhydrite, white. Trace of tourmaline and b i o t i t e . 0.17&..U 2371-006 1210-1220 80% Shale, greenish gray. 15% Chert, pinkish gray:, 5% Anhydrite, white. 0.10 2371-007 1300-1310 80% Dolomite, pinkish gray. 15% Shale, medium gray. 5% Chert, white. Trace o f anhydrite. 0.08 2371-008 1350-1360 65% 15% 10% 10% 2371-009 1400-1410 100% Dol omi te , brownish gray. Trace o f shale. 0.06 2371410 1420-1430 80% Dolomite, brownish gray. 10% Chert, white. 10% Shale, medium gray. 0.06 23il-011 1520-1530 110% Dolomite, brownish gray. 10% Chert, white. 10% Shale, mediun gray. 0.05 Dolomite, p i n k i s h gray. Shale, medium gray. Anhydrite, white.', ., Chert, white. 0.06 7 SCREEN ANALYSIS SUMMARY Geothem Sample We11 Interval 2371-012 1620-1630 Number TotalOrganic Carbon (X of Rock) BriefDescription Lithological (Feet) 8oZ Dolomite grading t o limestone, brownish 0.09 gray. 10% Shale. 10% Chert. to grayish red. 0.12/0.12 2371-013 1720-1730 95% Dolomite,brownishgray 5% Shale,darkgray. 2371-014 1840-1850 60% Shale, grayish red and nedim gray. 40% Dolomite,brownishgray. 0.17 2371-015 2040-2050 70"A Siltstone, dolomitic, grayish red. 30% Dolomite, l i g h t brownish gray. Trace o f shale. 0.12 2371-016 2120-2130 70% Shale, medium dark gray. 30% Dolomite, brownish gray. Trace o f s i l t s t o n e . 0.52 2371-017 2220-2230 65% Limestone, l i g h t brownishgray. 25% Shale, medium dark gray. 10% Chert,verypaleorange. 0.21 2371-018 2320-2330 90% Limestone grading t o dolomite. l i g h t brownish gray. 10% Shale, grayish red andmedium dark gray. 0.34 2371-019 2420-2430 90% Limestone grading t o dolomite, .l i g. h t brownishgray. 10% Shale, grayish red and medium dark gray. 0.12 2371-020 2520-2530 70% Limestone, l i g h t brownish gray. 30% Shale, grayish red and medium dark gray. 0.30 2371-021 2620-2630 60% Limestone, l i g h t brownish gray. 40% Shale, medim dark gray. 0.20/0.26 2371-022 2720-2730 75% Limestone, l i g h t brownish gray. 25% Shale, medium dark gray and grayish red. 0.11 2371-023 2820-2830 85% Limestone, l i g h t brownish gray. 15% Shale, medim dark gray and grayish red. 0. OC 1371-024 2920-2930 90% Limestone, l i g h t brownishgray. 10% Shale, medium dark gray. 0.11 .. .. Table I SCREEN ANALYSSISUMMARY Total Organic Carbon (%o f Rock) Sample Number We11 Interval (Feet) Brief Lithological Description 2371-025 3620-3630 100% Dolomite, l i g h t brownish gray. 0.05 2371-026 3720-3730 100% Dolomite, l i g h t brownish gray. 0.04 2371-027 3az0-3a30 100% Dolomite, l i g h t brownish gray. Trace o f anhydrite. 0.04 2371-028 3920-3930 100% Dolomite, l i g h t brownish gray. Trace of anhydrite. 0.04 2371-029 4020-4030 100% Dolomite, l i g h t brownish gray. Trace o f anhydrite. 0.05/0.05 2371-030 4120-4130 l0OZ Dolomite, cherty, brownish gray. 0.24 2371-031 4220-4230 100% Dolomite, brownish gray and dark gray. 0.13 2371-032 4320-4330 100% Dolomite, l i g h t brownish i r a y t o brownish gray. 0.05 2371-033 4420-4430 100% Dolomite, l i g h t brownish gray t o brownish gray. 0.08 2371-034 4520-4530 100% Dolomite, l i g h t brownish gray to brownish gray. 0.03 2371-035 4620-4630 100% Dolomite, l i g h t brownish gray t o brownish gray. 0.09 2371-036 4720-4730 100% Limestone grading t o dolomite, l i g h t brownish gray t o brownish gray. 0.11 2371-037 4820-4830 100% Limestone grading ' t o dolomite, l i g h t brownish gray t o brownishgray. 0.01)/0.08 2371-038 4920-4930 100% Limestone grading t o dolomite, l i g h t brownish gray t o brownish gray. 0.06 2371-039 5020-5030 100% Limestone grading t o dolomite, l i g h t brownish gray t o brownish gray. 0.06 2371-040 5120-5130 100% Dolomite , browni sh gray. Traces of shale and sandstone. 0.04 GeoChem 8 , * - Magnetitepresentbut removed. . . .. . .. .. . . .. Table I1 ORGANIC CARBON ANALYSIS AND GROSS LITHOLOGICAL DESCRIPTION GeoChem Sample Number We11 Interval (Feet) 2371-018 -A 2230-2400 40% -B -C Gross Litholigical Description GSA Color Code Limestone, micrite, chunky, moderately hard, pinkish gray. 40% Dolomite, cryptocrystalline. argillaceous. chunky, moderately hard, medium dark gray. 20% Shale,slightlycalcareous, chunky, moderately hard, medium dark gray. 0.42 5YR 8/1 5YR 4/1 2371-025 -A TotalOrganic Carbon 0.09/0.09 3580-3780 100% Dolomite, microcrystalline, chunky, moderatelyhard, byownish gray. Trace of quartz fragments. ' 5YR 4/1 PAOE 1 OF 1 PAOB T.O.C. Sl s2 s3 * = i = Hydrogen Index Oxvnen Index carbon _ - ~== ~HC/8 organic omanic carbon TABLE 1x1 RESULTS OF ROCK-EVAL ffRDLISIS 1120-11302371-003 -. .2371-005 2371-014 '. 2371-016 2220-2230 2371-017 2371-018 2520-2530 2371-020 2371-021 4120-4130 2371-030 2371-031 426 4720-4730 2371-036 0.11180-1190 4 0.37 1840-1850 0.12120-2130 9 0.25 I 431 2320-2330 0.02 2620-2630 4220-4230 418 334 0.06 430 0.14 247 442 0.17 439 0.02 0.02 0.03 0.01 0. 00 .36 440 437 .: 0.03 0.101.30 0.04 0.04 . 0.12 0.33 0.25 0.18 0.01 0.15 0.13 0.14 0.08 0.23 0.06 0.23 0.25 0.14 0.19 0.61 0.33 0.40 0.00 0.08 0.36 Residual hydrocarbon potential (mg HC/g OF rock1 C M produced from kerogen pyrolyaia (.B C02/g of rock) 0.083 (€4 92) + PC* 424 Total organic carbon, ut. II Free hydrocarbons. mg HClg of rock 0.02 0.01 ~sg mg CO2/g PI t Tmx = SIISl+S2 Tesperatum Index, desrcea C. 0.01 0.20 0.17 0.17 0.52 0.21 0.34 14 105 0.01 0.30 43 0.01 0.01 0.01 0.27 0.24 0.13 0.11 51 33 76 133 125 176 227 0.00 0.01 0.00 0.00 95 95 70 35 26 217 0 85 61 54 190 98 Table IV Summaw of C15+ Soxhlet Extraction, Deasphaltening and Liquid Chromtography A. Weights of E x t r a c t s and Chmmatographic Fractions CeoCheD Rock Sample Number 231-018 2371-025 Well I n t e r v a l 2230-2400 Weight P rof e c i p iTt aotteadl Extd. Extract (gram) (gram) 100.0 N-C5 Asphaltenss Soluble Sulfur 0.0464 (grams) (grams). ( g r a m ) 0.0118 0.0346 0.0120 3580-37800.0057 0.0177 100.0 N.D. N.D. ParaffinsEluted Noneluted Naphthenes Amuatica NSO'S NSO'S (gram) (grams) (grama) (grams) 0.0076 0.0094 0.0168 0.0069 0.0011 0.0032 0.0008 0.0002 B. Concentratlw of Extracted Faterials i n Rock Hydrocarbons-------- -----------Nonhydmoarbons------------ " " " " GeoChea ParaffinSample Number W e l Interval (ppn) 2371-018 2371-025 Total Extract 2230-2400 464 3580-3780 177 Preciptd. Eluted Naphthene (ppm) (ppm) Aroaatic Total Sulfur Asphaltone (PP~) 168 69 262 86 94 11 . (ppm) -- #SO'S (PPd (ppm) 118 57 8 Noneluted NS'S (PPD)(PPD) ' 16 32 e 2 Total 202 91 ~~ C. Conpoaitlon of' E x t r a c t s ceochea Naphthene Sample Number 2311-018 231-025 Well I n t e r v a l 2230-2400 35853780 -------H,dmcarbons-------------------Nonh,drarbws----------ParafrinEluted Noneluted Precipitd. Amtic HC'S Sulfur NSO'S NSO'S Asphaltens I I PNlAmm Z ? I s AsphlNSD S 36.2 39.0 20.3 9.6 1.79 5.06 -- 16.4 18.1 1.1 1.1 25.5 32.2 1.3056.51.80 1.68 48.6 NWNw HC 0.95 Table V-A S a t u r a t e Hydrocarbon Analyses of Parafrin-Naphthene Distribution S-ry GeoChem Sample Number S S S c-P Naphthene Index A Well Interval Paraffin Isoprenoid 2371-018 23ll-025 2230-2400 3580-3780 23.2 20.2 1.03 1.9 1.15 0.81.02 14.9 19.0 C-P Index B ip19Iip20 1.04 0.99 0.52 Table V-B Saturate Hydrocarbon Analyses ~ Normalized Paraffin Distribution GeoChem Sample NIIBbar s Y e l Il n t e r v a l s nC15 nC16 nC17 s s s s s s s s s ip19 nC18 ip20 nCl9 nC20 nC21 nC22 nC23 nC24 nC25 s s s s s s s nG% nC2l nC28 nC29 nC30 s s s s s nC31 nCY nC33 nC3e nC35 TABLE VI Table VI1 VITRINITE REFLECTANCE SUMMARY GEOCHEM SAMPLE NUMBER DEPTH ("") 2371-003 1150 0.36 0.62 0-55 1.43 0.45 1.01 2371-005 1210 0.44 1.25 0.44 1.25 0.44 1.25 2371-007 1330 2371-013 1730 0.02.729 0.63 0.77 0.31 0.63 1.42 rYPE POPULATION OF READINGS SAMPLE NUMBER OF MEAN MINIMUM MAXIMUM REFLECTANCE REFLECTANCE REFLECTANCE ( Yo Ro) Re) ( Ro) (Yo Yo 0.63 1.07 .. 2371-014 1870 0.81 1.05 2371-016 2150 0.03.030 0.52 0.77 0.30 0.73 1.75 0.62 1.12 0.52 0-58 0.90 0.52 0.81 1.93 0.52 0.68 1.U 00 .. 2266 0.50 1.10.936 0.26 0.75 1.80 2371-018 2371-021 2350 2650 0.93 STD. ( DEV. VORo) 0.076 0.356 - -0.304 0.071 0.255 0.071 0.308 0.62 0.084 0.217 0.091 0.258 2371-025 3650 0.58 1.12.667 0.80 2.02 0.69 2371-030 4150 0.37 0.72 19 .1 29 0. 0.37 0.79 1.61 0.37 0.75 0.038 0.353 REMARKS Table VI1 VlTRlNlTE MAXIMUM GEOCHEM NUMBER SAMPLE NUMBER 2371-036 2371-040 5129 DEPTH I."., ll..l) 4750 REFLECTANCE TYPE OF POPULATION ~ ~ SAMPLE OF READINGS ClG (1) 1.49 1 1.49 cn; m VImNIm SUMMARY MINIMUM REFLECTANCE REFLECTANCE REFLECTANCE % Ro) ('3'0 RO) I% ~ 1.49 ~~~ Rei- STD. DEW ( Vo Rol REMARKS - IiEmRmo ~~ 2371-003 CLIENT'S NAME "SHALL XUG OIL (ND.CP READINSS = I l l POPULATION NO. 0.42 0.36 (1) 5 6 0.42 0.36 0.62 .. /SAMPLE DEPTH am= =a NAME WELL 0.500.55 MIN Ro ( % ) OF READINGS (2) m TYPE OF SAMPLE: GEOCHEM NO. .- 0.62 MAX. RO ( %) 0.55 1.430.356 0.66 NO. U.50 #l aRmLrms m. A 0.821.141.371.43 MEAN Ro( %) 0.45 1.01 STD. OEV. ( %) 0.076 REMARKS GEOCHEM NO. 2371-005 CLIENT'S NAME lwfsmu YOUNG o z POPULATION a u. NO. OF READINGS 1 1 TYPE OF SAMPLE: Cm DEPTH / SAMPLE NO. NAMEWELL MIN Ro ( % ) MAX. Ro ( %) 0.44 1.25 0.44 1.25 ' 1s VlTRlNlTE ~ ~ ~ ~ # l a X R A U l W F E D MEAN Ro( %I 0 REFLECTANCE HISTOGRAM 1210 0.44 1.25 STD. OEV.(%) -- REMARKS GEOCHEM NO. CLIENT'S NAME aG 7) OF 0.27 READINGS 0.31 /SAMPLE DEPTH 0.63 0.77 0.871.231.42 MIN Ro ( % ) MAX. Ro ( %) 0.31 0.63 1.42 t 1) 2 0 -27 (2) 1 0.63 (3) 4 1.07 0.77 NO. 1730 urn=SWVICE c103RRALmtXs Em. A WELL NAME YWNG OIL, (NO.CF ReADINGs = POPULATION NO. TYPE OF SAMPLE: 2371-013 . MEAN Ro( %) 0.29 0.63 C x STD. DEV. ( %) 0.304 REMARKS -- CAVE o3tmMlmTIoN Pomrnm INDIGENcm O-llBXCUD NO. GEOCHEM CLIENT'S NAME POPULATION !i I0 L IS NO. 1870 WELL NAME "G NO. OF READINGS 2 K TYPE OF/SAMPLE DEPTH SAMPLE: 2371-014 MIN Ro ( % 1 0.81 MAX. Ro 1.05 %I MEAN Ro I %I 0.93 m a #I STD. DEV. (%I REMARKS m. A GEOCHEM NO. 2371-016 (NO.OF READRK;s = 60) 0.30 0.52 0.54 0.57 0.79 0.80 0.830.84 0.85 0.85 0.86 0.87 1.021.031.041.05 1.11 1.12 1.12 1.15 1.351.391.421.45 1.49 1.49 1.50 1.53 POPULATION NO. OF READINGS MIN Ro ( % ) ' 0.77 3 !i (L 0 I* (1) 1 (2) ll (3) 48 a TYPE SAMPLE1 OF 0.30 0.52 /SAMPLE DEPTH NO. 2150 0.57 0.60 0.60 0.62 0.66 0.70 o.n 0.730.770.78 0.90 0.910.920.930.970.971.001.00 0.890.90 1.17 1.21 1.241.261.271.281.291.301.331.34 1.60 1.75 MAX. R o ( % ) 'MEAN R o ( % ) SlD.OEV.f%1 REMARKS 0.30 0.73 1.75 0.30 0.62 1.12 - 0.071 0.255 GEOCHEM NO. 2371-018 TYPE OF SAMPLE: CLIENT'S NAME MARSHALL "G OIL m DEPTH /SAMPLE NO. 2350 NAMEWELL C f T I E S ~ ~ I 1 ~ P B b . (NO.(IF READINGS = 44)0.520.580.610.620.620.630.630.640.640.650.670.680.720.73 0.80 0.810.900.900.920.930.940.960.960.971.001.021.071.091.101.10 0.750.78 1.121.151.221.241.291.341.381.581.621.791.841.93 NO. OF POPULATION MIN Ro ( % ) 0.512 17 261.93 0.52(1) (2) (3)1.21 0.308 READINGS MAX. 0.52 0.58 0.90 Ro ( %) MEAN 0.810.071 Rol%) STD. DEV. (%) REMARKS - 0.68 r4 -- CAVE o3@mmm!rIm m1RJFtlIATIa? O-REXXCI5) )I c x rn - W t 0 I. a k! .. (I (r 0 K w m =. . 5 X s 0 ,, ,, , ,' , ,, , , , ,, 0.0 oJ 0.2 0.9 0.4 I xx xx x x c xxxxxxxxxx ob T II##(,Vrn 0,s 0 0 oooO00ax)(30 000 00000 00 ~ ~ " ~ " " ~ " " ~ " 1 1 1 " 1 " " , " ' ) 1 , 1 1 ( , 1 0.8 a) 1.0 1.1 1.2 1,s 1 1 1 1 ~ 1 1 1 ' 1 1 1 ' 1 ) 1 1 1 ' 1.4 VlTRlNlTE 'REFLECTANCE HISTOGRAM 1,s 1.s 1.7 I.0 1.9 t.0 2.1 8.2 zs GEOCHEM NO. 2371-021 CLIENT'S NAME M A R S W YWNG OIL (No.ctr READIN33 = 27) 1.10 1.151.23 POPULATION NO. 1.25 0.26 1.27 OF READINGS cm TYPE OF SAMPLE: 0.50 1.30 /SAMPLE DEPTH WELL NAME 0.51 1.30 0.55 1.35 0.55 1.39 0.58 1.49 MIN Ro ( % ) MAX. Ro ( %) 0.26 0.50 1.09 0.26 0.75 1.08.0217 VlTRlNlfE 0.59 1.51 0.60 1.75 MEAN Ro( 0.26 0.62 1.36 REFLECTANCE HISTOGRAM NO. 2650 SBWKE #1 "IO5 ~~ 0.72 0.680.680.69 1.80 %) STD. DEK( %I - 0.004 0.75 1.09 REMARKS PB).A GEOCHEM NO. (M).OF READPOPULATION NO. (1) (2) 2371-025 TYPE = 1 2 ) 0.58 OF READINGS 5 7 0.64 cro OF SAMPLE: 0.67 0.77 0.80 1.26 MIN Ro ( % ) MAX. Ro ( %) 0.58 1.26 0.80 2.02 /SAMPLE DEPTH 1.41 1.64 .MEAN Ro( .. .. VITRINITE REFLECTANCE HISTOGRAM 0.69 1.67 1.73 1.78 %d NO. 3650 1.83 2.02 STD. 0EV.t %) 0.091 0.258 REMARKS 3 GEOCHEM NO. CLIENT'S NAME POPULATION 0.37 (1) (2) (3) TYPE OF SAMPLE: 2371-030 1.29 memu YUWG NO. OF READINGS 0.371 3 4 m /SAMPLE DEPTH NAME WELL OIL MIN Ro ( % 0.37 0-72 0.91 MAX. Rot 0.79 1.61 %) CITIES SERVICE MEAN Ro( %) STD. DEV.(%] 0.75 0.038 - NO. 4150 #1 (XRRAuIIOs REMARKS FED. A GEOCHEM NO. POPULATION (1) 2371-036 NO. OF READINGS 1 TYPE OF SAMPLE: MIH RO ( % ) 1.49 VITRINITE ' MAX. Ro DEPTH I SAMPLE NO. 4750 CIG yo) MEAN 1.49 REFLECTANCE HISTOGRAM Rot o/o) 1.49 STD. DEY( %) - REMARKS I Standard No.DENOTES a Ip-cfg = ISOPRENOID PRISTANE b = I P - C ~ ~ I S O P R E N O I DPHYTANE 19 I p C n PARAFFIN 20 21 a 22 23 24 i i t 13.. NAPHTHENES Ir 30 I . I 0 . In N 0 I ;I I') N D 0 i