Physics 2D Quiz #4 Department of Physics, UCSD Summer Session II - 2009 Prof. Pathria 28 August 2009 Some Useful Data Speed of light: c = 2.998 ×108 m/s Planck’s constant: h = 6.626 ×10−34 J·s Rest mass of an electron: me = 9.109 ×10−31 kg = 0.511M eV /c2 1 eV = 1.602 ×10−19 J Schrödinger wave equation: 2 2 h̄ d ψ − 2m dx2 + U (x)ψ = Eψ Potential energy of a simple U (x) = 21 Kx2 = 12 mω 2 x2 harmonic oscillator: Some Useful Formulae sin2 x = 12 (1 − cos 2x) R∞ 0 2 e−ax dx = 1 2 pπ a cos2 x = 12 (1 + cos 2x) R∞ 0 2 x2 e−ax dx = 1 4 pπ a3 R∞ 0 2 x4 e−ax dx = 3 8 pπ a5 Instructions Please write your answers in your blue book, and make sure your secret code number is written on all pages in indelible ink. 1 1. An electron is contained in a one-dimensional box of width 0.1 nm. (a) Draw an energy level diagram for the electron for states up to n = 3, and show all the transitions that would eventually get the electron from the n = 3 state to the n = 1 state. (b) Find the wavelengths of the photons emitted during these transtions. 2. An electron is trapped in a one-dimensional rigid-walled box of width 1.0 nm. (a) Sketch the wavefunctions and the probability densities for the n = 1 and the n = 2 states. (b) For the n = 1 state, calculate the probability of finding the electron between x = 0.15 nm and x = 0.35 nm, where x = 0 is at the left end of the box. (c) Repeat the calculation in (b) for the n = 2 state. (d) If the electron absorbs a photon and, as a result, makes a transition from the n = 1 state to the n = 2 state, what would the wavelength of the photon have to be? 3. The wavefunction: 2 ψ(x) = Cxe−ax describes one of the eigenstates of the simple harmonic oscillator, provided that the constant α is chosen appropriately. (a) Using the Schrödinger wave equation for the oscillator, obtain an expression for α in terms of the oscillator mass m and the angular frequency ω. (b) What is the energy associated with this state? (c) Determine the root-mean-square values of the deviations ∆x and ∆px for the oscillator in this state, and verify that they are consistent with Heisenberg’s uncertainty principle. 2