New Mexico Tech Coordinating State-Funded Fossil Fuel Research inuolving Oil Gas CWl Enhanced Oil Recovery New Mexico Energy Institute at New Mexico Institute of Mining & Technology Socorro, New Mexico 87801 (505)835-5545 e 0 0 0 FOSSL I FUEL RESEARCH FINAL REPORT COAL, URANIUM, OIL & GAS POTENTIAL OF THE RILEY-PUERTECITO AREA, SOCORRO COUNTY, NEW MEXICO Charles E. Chapin, Principal Investigator Glenn R. Osbum, Co-Investigator Stephen C. Hook, Co-Investigator Gary L. Massingill, Co-lnvestigator Stephen J. Frost, Co-Investigator COAL, URANIUM, RILEY-PUERTECITO New OIL AND AREA, GAS SOCORRO POTENTIAL OF THE COUNTY, Principal Investigator: Charles E. Chapin, Ph.D. of Mines and Mineral Mexico Bureau NEW MEXICO Resources Technical Report by New Charles E. Chapin, Ph.D. Glenn R. Osburn Stephen C. Hook, Ph.D. Gary L. Massingill Stephen J. Frost Mexico Bureau of Mines and Mineral Resources March 1979 This project was conducted under the auspices of the NEW MEXICO ENERGY INSTITUTE of New Mexico Instituteof Mining and Technology. The research project was supported by the New as Mexico Energy and Minerals Department Project No.ERB 77-3302 and by the New Mexico Bureau of Mines and Mineral Resources., ABSTRACT .: The Riley-Puertecito area is located on the southeastern . : margin of the Colorado beltof gently northwest-trending Cenozoic Coal rocks beds . Plateau cut occur by near is dipping numerous the ,.. and underlain a west-by Cretaceous kaulks and igneous intrusions. . . ,. ana top Mesaverde Forof the .. . base and .(. , .. .. mation of Uppel cretaceous age. C o i l s in the lower Mesaverde .. were deposited on a coastal or . . :, . I , . delta plain a mixed in brackish , . .. . ., , . . . :, . . ,. and fresh water environment. Analyses of three samples from '_ ~ ... beds 13 inches to 5 feet thick yielded vaiues (as received) , .. of"5137 to 9083 BTU/lb, 13.2 to 39.0% ash, and 0.5 to 0.9% I . .. . , , sulfur; They range in thickness from one $0 five feet, but I , ' may aggregateas much as .8 feet of coal . . . coal seams. Coal: . .. . in areas ... of stacked i in the upper Mesaverde were'deposited in iiesh-water 'swanips further inland. Analyseso f ~ O i rsamples . from beds11 inches " to3.2 feet thick yielded values (as received) of 6083 to 11,555 BTU/lb, 6 . 4 to 40.3% ash, and 0.3 to 0.5% sulfur. Upper Mesaverde coals occuras isolated, lenticular beds that change thickness rapidly. Inferred resources were not calculated of lack of subsurface because of data and str'uctural complexities. Indicated resources lower Mesaverde coals southwest of * t o n ~of bituminous and subbituminous Riley are coal which about 1,000,000 could mined with a maximum stxipping ratioof 1O:l. The best use of the coal would probably a be cement plant that could utilize the abundant Limestone, travertine, and shale found in this area. ii be Small, scattered occurrences of uranium are present in terrestrial sandstonesof the Baca FormatiohoE Eocene age. A fluvial sandstone facies,0 to 176 feet thick, crops out over a distance of about fivemiles along the northeastern edge of the Bear Mountains, southwesto f Riley. The sandstone i s bleached, contains abundant carbonaceous material, and could contain commexcial uranium deposits where downfaulting has protected it from leaching. The oil and gas potential of Cretaceous rocks in the Riley-Puextecito area is negligible because of shallow depth of burial, low degree of thermal.ma&ration, and probable flushing by groundwater. However, structural information developea during this study maybe helpful in evaluating deeper formations. .. TABLE OF CONTENTS ............. Abstract. . . . . . . . . . . . . . . . . . . . . . . . Contents. . . . . . . . . . . . . . . . . . . . . . . . . Figures . . . . . . . . . . . . . . . . . . . . . . . . Tables. . . . . . . . . . . . . . .......... Acknowledgement and Disclaimer . . .. . . Page i ii iv V vi . , SECTION ................... I1 Geologic Setting ................. I11 Coal Potential . . . . . . . . . . . . . . . . . . . Stratigraphy, Distribution, Thickness . . . . . . . MiningHistory .................. Composition . . . . . . . . . . . . . . . . . . . . . ResourcePotential ................ ResourceUtilization ................. IV Uranium Potential . . . . . . . . . . . ; . . . . . ; . . .V Oil and Gas Potential . . . . . . . . . . . .i . . . . . 1 Introduction 1 5 9 9 12 15 18 19 21 29 .. Plates (availableas open-file of Mines and Mineral maps from Resources) the New Mexico Bureau 1. Geologic mapof the Riley area (1:24,000), G.L. Massingill, 1979. 2. Geologic mapof the Corkscrew Canyon-Abbe SpELng area 41:24,000); D.L. Mayerson, 1979. 3 . . ''Geologic map of the Puertecito-La Cruz Peak area (1:24,00 , R.A. Jackson, 1979. 4. Pebble compositions and transport directions in the Popotosa Formation, Abbe Springs area (plotted on 1:24,000 geologic map), G.R. Osburn, 1979. iv FIGURES Figures 2-1 - Page Generalized GeOlOgiC Map of the Ril0y-PWrteCitO Ana...................... 2-2 - Igneous Intrusions in the Riley-Puertecito Area 3-1 3-2 - - 7 ....................... a Composite Stratigraphic Column of the RileyPuertecito M e a . . . . . . . . . . . . . . . . 10 Favorable Areas for Coal and Uranium Explora- TABLES Tabla 3-1. Page malysae. o f ooala from the.lower Mesaverde . . . . . . '. . - Analysslpl coala €rom the upper Meaavsrde Foamation, 'Rllsy-Pusr4xmito area . . . . . . . . - 1 Poxmatian, Riley-Puerteclto area 3-2 16 of 17 .... . . . . V I. The INTRODUCTION purposeof this report is to present a concise summary of the coal, uranium, and oil and gas potential of the Riley-Puertecito stratigraphic area framework along with the geologic maps and essential to mineral exploration. .. are available in the theses and + Details of the . geology 1:24,000 geologic maps all of which available as open-file New are Mexico The north Bureau of completed Mines Magdalena in and part.of the reports from Mineral is located area Riley-Puertecito of as northwestern project, the Resources. about20 miles Socorro County, New Mexico. The area lies along the southeastern margin of the Colorado sedimentary tary Plateau rocks rocks, all of Cretaceous consists and overlain dipping by Cenozoic gently and Eocene volcanic southwestward and away sedimenfrom Colorado Plateau. Attention has been focused on the area in recent Cretaceous of the because years rocks, uranium occurrenceof coal prospects in beds Eocene in rocks, a and geologic setting favorable€or hydrocarbon exploration. In May 1976, the New begana detailed Resources Puertecito area in Mexico Bureau of Mines geologic study anticipation of probable of and the Mineral Ril'ey- exploration for energy fuels. The project began as an extension of geologic mapping conducted in the Socorro-Magdalena area since 1970 by the senior author and several graduate students. Detailed mapping and subdivision of the Cretaceous 'the rocks was made possible by paleontological and stratigraphic studies begun in 1976 by S.C. Hook and conducted in collaboration with W.A. Cobban of the U.S. Geological Survey. Since : 1977 , the September. project ; from the,NewMexico Energy Institute has Energy at been 5 0 % funded Resources New Mexico by Board a,'grant through Institute of Mining the and Technology. The project has been a team effort with overall direction S.C. by Hook in the the supported by author and areas of paleontology our stratigraphy. senior the with and major assistance Cretaceous thesis and dissertation projects were grant provided ofmost the and data on which this,report is based. These projects axe:I) RileyPuertecito area,Ph.D. dissertation, G.L. Massingili, El Paso; 2) Puertecito-La Crnz Peak Uiriversity of Texas at area, M.S. thesis,, R.A. Jackson, New Mexico Tech; 3 ) Corkscrew Canyon-Abbe Springs area, M.S. thesis, D.L. Mayerson, New Mexico,Tech; and 4) Palynology and thermal maturation of Ph.D. organjrc matter in Cretaceous and Eocene rocks, dissertation, M.S. Chaiffetz, Universityof Texas atEl: Paso. Pebble compositions and transport directions in . . the Miocene Osburn of Resources. were. White, Popotosa the . New Chemical determined €or Formation were Bureau of Mines Mexico compositions and determined and by G.R. Mineral Sra7/SrB6' ratios of the intrusive rocks by D.L. some whilea post-doctoral fellow with the New Mexico Bureau of Mines and Mineral Resources. K-Ar dating of .. . . igneous rocks was performed by Geochron Laboratories and and A.L. Odom of Florida State 2 University. by Three additional currently underway thesis and the west of the to dissertation projects are Riley-Puertecito area. The,se are: 1) D-Cross Mountain 7-1/2 minute quadrangle, Ph.D. dissertation, B.R. Robinson, University 2) Gallinas Peak area, M.S. thesis, of Texas at El Paso; 3) a sedimentologic study T.M. Laroche, New Mexico Tech; and of the Baca Formation in the Jaralosa Creek area, M.S. thesis, S.M. Cather, University of Texas at Austin. The details of these reports but studies they perspective they will be published are acknowledged have contributed here to in for the subsequent the regiona.1 Riley-Puertecito project. In addition, G.L. Massingill is completing a geologic map of the while a post-doctoral Mines and Mineral Several Mexico Puertecito fellow at 7-1/2 minute New Mexico the quadrangle Bureauof Resources. projects of the Bureauof Mines and Coal Mineral Research Resources Group have of the also helped in the preparationof this report. These include historical data and S . J . Frost, U.S. Geological and an on coal chemical Survey exploratory mining compiled analyses of under a grant hole by H.B. Nichelson coa1:performed by toF.E. Xottlowski, drilled as part of the Datil: Mountain Project o f D.E. Tabet and S.J. Frost. Several members of the U.S. Geological Survey have also contributed.to the project. We especially acknowledge the assistance given by W.A. . . Hook Cobbanto S C stratigraphy of the Cretaceous on the units, 3 paieontology the and cooperation of New C.H. Maxwell and S.L. units to Moore on the'correlationof stratigraphic thenorth; the assistance of M.N. Machette on Quaternary stratigraphy, and the funas contributed by the Branch .of Central Environmental Geology to subsiiize mapping for the Socorro 2-degree sheet. ,. . 0 11. GEOLOGIC SETTING The Riley-Puertecito eastern margin of the Rio of the Grande area is Colorado rift, and located Plateau, the along the the south- western northeastern edge marginrof the Datil-Mogollon volcanic field (Fig. 2-1). Neogene up1i.ft of the Colorado 15 degrees strata 10 to subsequent has erosion by Plateau to tilted the the Rio Miocene and south and southwest; Salado and its outcrop belt exposeda west-northwest-trending tributaries of Triassic, Upper Cretaceous, and Cenozoic strata. The .Upper and Cretaceous the Eocene Mesaverde Baca Formation Formation older contains contains ' coal beds uraniferous sand- stones. Four holes have recently been drilled for oil and gas exploration. Surface structures in the Riley-Puertecito area are of four types: 1) broad, gentle, north- to northwest-trending anticlines and synclines that developed during Laramide compression; 2) north- to north-northwest-trending normal faults of small early stages injected by displacement of opening magmas to that of form developed the an Rio during Grande extensive rift swarm the and of were mafic dikes (Fig. 2-2);3 ) north-trending normal faults of.major displacement tilted that faultblock bound the Mulligan uplifts of the Gallinas Gulch and graben and Bear Mountains; and 4 ) northeast-trending faults and flexures that formed at various times 5 by reactivation of the the Tijeras lineament, a major northeast-trending basement fault zone of Precambrian ancestry. !.. . . 6 '\ / I 1 COAL POTENTIAL 1x1. Stratigraphy, Distribution, Thickness Coal occurs in both the iower and upper portions of the Mesaverde Formation of Upper Cretaceous age (Fig. 3-1). The lower coal-bearing interval begins about 60 feet the base of the formation and contains above numerous thin coal seams ina 200-foot sequenceof shales containing thin interbeds of sandstone and siltstone. This lower coal-bearing interval is believed to be stratigraphically equivalent to the Dilco Coal Member of the Crevasse Canyon Formation (Molenaar, 1974); the sandstone underlying the coal-bearing interval is marine and correlative with the Gallup Sandstone (Molenaar, 1974). By agreement with United States Geological in ,the,area,the in future Coal 100 term reports beds in Survey Mesaverde personnel Formation and.Crevasse the upper and will other be workers abandoned Canyon Formation adopted. Mesaverde Formation occur to300 feet below the top of the unit. They tend to be isolated, lenticular coal seams that change thickness abruptly. Changes in depositional environment account for differences in composition and continuity of coals in the upper and lower Mesaverde Formation. Coals in the basal interval brackish are water marine to contain baltisphaerid environments, and transitional marine 9 algae the typical of enclosing and contain shales at least five dinoflagellate or planktonic algal morphologic types (M.S. Chaiffetz, 1978, written commun.). These coals apparently formed near mangrove or Cyprus swamps. on a coastal or delta plain. In contrast, coals in the upper Mesaverde contain abundant angiosperm pollen and lack marine or brackish water palynological indicators (M.S. Chaiffetz, 1978, written commun.). These coals apparently formed in isolated swamps.on the upper coastal plain. They are often associated with fluvial sandstones (Massingill, 1979). Coal beds in the lower from a few inchesto 5 feet. Mesaverde range in thickness At some localities,a series of thin coal seams occurring through a stratigraphic interval o f 20 to 40 feet will aggregate5 to 8 feet of coal. For example, a hole mile of drilled about one southwest Riley (SE-1/4, SW-1/4, Sec. 26, T.2N., R.4W.) by the New Mexico Bureau of Mines and Mineral Resources intersected five 2.5 to feet, with coal seams ranging in thickness from 1.0 an aggregate thickness of 8.0 feet ina stratigraphic interval of 28 feet. Such multiple, thin seams may merge laterally of commercial thickness. Coal into one or more coal beds beds in the upper Mesaverde have known thicknesses that range froma few inches to5 feet. These beds tend to be less continuous laterally than the coals in the lower Mesaverde and change thickness abruptly. They also tend to occur' as single beds in a stratigraphic sequence. rather than multiple seams stacked Coals west of in the Riley, lower south of coal by appears to allowing are Puertecito, most and abundant in the south- Corkscrew The northeast-trending Tijeras Canyon area (Fig. 3 - 2 ) . lineament Mesaverde have influenced different rates the of distribution of subsidence and sedimen- tation on opposite sidesof the lineament. Coal beds are abundant Riley on area, the southeast where the side marine of the and lineament brackish in water the sediments of the lower Mesaverde 'are relatively thick. This favorable stratigraphic interval thins to the northwest across the lineament,and coal outcrops disappear. However, coal is again At present in least8 coal this beds interval a Eew in the miles lower 'to Mesaverde the southwest. Formation are .' 1979). exposed in the Corkscrew Canyon area (Mayerson, near the southwest corner of the map area 3-2). (Fig. They range in thickness from 1 to 2 feet .' The abuqdance'of 'these coals may also be due to a favorable r a t e of subsidence on the southeast side of the lineament. Mining History ,Coal was mined Forfnation aboutone mile and 21, T.2N., R.4W. at various southwest of times Riley from in the lower sections 26 No records of these operations have been fouad. Several small 'excavations and two adits exist. Most of the production. apparently ?2 came from an adit in Mesav L Puertecito Figure 3-2 FAVORABLE AREAS FORCOALANDURANIUMEXPLORATlON R I L E Y -P U E R T E C I T OA R E A LEGEND Scale B N Coal outcmp outcrop of lower Mesoverde b D Fm. intervol.pmbobly eprivolent to Dilco Cool Member of CrevossBConmn Fm. outcrop of cool-bearing ~ntewolof upper Mesoverde / Fm. Outcrop of middle member of Boco Fm. Outcrop of umniferous channel of Boco Fm. undifferentiated Oppmximotelimits of Tijems lmeoment I C Cool mine Cool prospect R41 IW xu &onium mine or pmspect ‘x Copper prospect + Oil or gos test / / J Pinch-out line Helk Meso foult s e c t i o n 26 t h a t was d r i v e n on a c o a l bed 4 f e e t 8 i n c h e s was probably a few hundredtons. t h i c k .T o t a lp r o d u c t i o n was p r o b a b l y u s e d i n Most of the coal produced smelters and homes i n t h e Magdalena a r e a a n d ' b y r e s i d e n t s o f t h e R i l e y area. mined from t h e u p p e r Mesaverde at t h e Coal has been E l Cerro mine southwest betweenCorkscrew E l Cerro mine of Riley and a t t h e Hot'Spot mine Canyon and Abbe Springs(Fig.3-2). The is l o c a t e d i n Caiion d e l Tanque Hondo about 3 miles southwest of R i l e y (SE-1/4, Sec. 3 3 , T.2N., R.4W.). T h i s p r o p e r t y is a l s o known a s t h e Sanchez-Romero p r o s p e c t . The following data hwe been abstracted - Coal History of from - Mexico by Nichelson and Frost (in prep.). New I Mr. Gxegorio Romero and o t h e r s f i l e d a c o a l claim i n 1917 on t h e E-1/2, E-1,!2, Sec. 3 3 , T. 2N., R.4W. about 300 feet long from rooms. anddroveaninclinedadit which t h e y o p e n e d t h r e e s h o r t were d r i v e n a l o n g the S e v e r a lo t h e rs h o r to p e n i n g s o u t c r o p t o test t h ec o a l bed. I n 1 9 3 7 ,a n o t h e ri n c l i n e was d r i v e n . a b o u t 100 f e e t and a 30-foot entry opened right. Here, t h e c o a l to t h e bed was 2 1 i n c h e s t o 27 i n c h e st h i c k w i t h a s h a l e . r o o fa n df l o o r . As the minedeveloped, a , roll was h i t , a c r o s s which t h e coal was o n l y 1 8 i n c h e s t h i c k andwater was encountered. Cerro CoalMining The Treasurex o'f t h e E l Company was M r . R.H. r e s i d e n t of Socorro. He diedin company was renamed t h e RileyCoal S t a p l e t o n , a prominent 1939, a f t e r which t h e Company.Work had ceased a t t h e . m i n e by October 1 9 4 0 b e c a u s e o f t h e t h i n 14 c o a l andlong,roughroad t o market. canceLledJuly 1 7 , 1953 r e t r o a c t i v e t o The property produced Romero l e a s e . R.5W.) The lease was November 1 5 , 1 9 4 3 . 788 t o n s of coal under The Hot Spotmine t h e Sanchez- Sec. 18, T . l N . , (NW-1/4, strata produced 85 t o n s of c o a l fromupperMesaverde between 1 9 2 7 a n d1 9 3 1( N i c h e l s o na n & . F r o s t ,i np r e p . ) . was i s s u e d t o F.L. miningpermit Dugger on J u l y 1 5 , A 1927. Mr. Dugger drove a 90-foot a d i t on a 46-inch c o a l bed b e f o r e h i t t i n g a r o l l across which t h e c o a l t h i n n e d 1 2 inches. The permit expired June30,1931. a d i t s axe p r e s e n t o n t h e a v a i l a b l e €or t h e s e . to Three o t h e r same c o a l seam b u t no r e c o r d s a r e Mr. Dugger r e p o r t e d t h a t oneofthese i n c l i n e s w a s d r i v e n 115 f e e t w i t h o u t h i t t i n g t h e c o a l The t h i c k e s t c o a l bedobservedhere Mayersonc1979). bed. i s 5 f e e t t h i c k (D.L. The c o a 2 s . g r a d el a t e r a l l y i n t o s i l t y shale and sandstone. Composition Analysesof 7 coal samples from the Riley-Puertecito a r e a are l i s t e d i n T a b l e s lignite to high-volatile classes (ASTM, 1 9 6 7 ) . Mesaverderangefrom 3-1and3-2. The c o a l sr a n g e from C bituminousandsub-bituminous The three samplesfrom B t h e lower, 5137 t o 9083 BTU/lb as r e c e i v e d . The Q s h c o n t e n t r a n g e s f r o m 1 3 . 2 . t o 3 9 . 0 % ; s u l f u r c o n t e n t i s low andranges from 0.5 t o 0.9% ( a s ' r e c e i v e d ) . foursamplesfrom the upper Mesaverde (Table 3-2) range from 6,083 t o 11,555 B T U / l b , a s r e c e i v e d . 15 The Ash c o n t e n t so ft h e Table 3-1 Analyses of coals from the lower Mesaverde Formation, Riley-Puertecito area, Socorro County, New.Mexico. All analyses by United States Geological Survey, Branch of Coal Resources, Denver, Colorado. USGS Sample Dl99359 ID Lab No. Location D192387-89 D192390, H84794 SE,26,2N,4W SE,27,2NI4W 1 mi SW. of Riley Thickness/sample type Collected by SS. Height above Gallup Air dry loss Moisture Volatile matter Fixed carbon Ash Hydrogen 4.3 3.7 Carbon Nitrogen Sulfur Oxygen (Ind) Sulfur-sulfate 0.31 -pyrite -organic Ash-Initial Deform. -softening T. -fluid T. 2800F Heating Value BTU/lb 1 mi S. of Riley 3 channel samples 1'8", 1'2", 1'1" G.L. Massingill 40'47' 17' -6.0 Rec 'd -M -M&A 11.9 28.432.257.8 20.7 23.5 42.2 39.0 44.3 3.9 3.2 4.7 4.3 2.4 3.4 5 ft/channel G.L. Massingill -0.2 Rec'd -M "&A 8.9 41.3 35.3 32.2 45.7 50.2 58.7 14.5 13.2 4.3 66.2 56.036.9 61.5 32.5 71.9 1.1 1.5 1.2 0.80.71.4 0-9 1.0 1.2 24.4 18.1 21.1 0.40 0.34 0.08 0.09 0.11 0.540.600.70 2455F 2370F 2410F 2560F 2470F 9083997511667 - - - - - . 91 0.6 0.6 1.1 23.8 15.0 26.9 0.02 0.02 0.04 0.20 0.220.40 0.34 0.38 0.69 2755F 2800F X82071 SEI26,2N,4W 1 mi S. of Rifey 2 channel samples 1'5", 2'6" G.L. Massingill 12', 11.2 Rec'd -M "&A 19.0 30.938.146.2 35.944.453.8 14.2 17.5 - - 46.156.868.9 1.0 1.2 1.5 0.5 0.70.6 25.0 33.620.6 0.02 0.02 0..03 0.180.22 0.27 0.270.330.40 26551" 51375831 16 ' 1046771798858 10740 Table 3-2 Analyses of coals from the upper Mesaverde Formation, Riley-Puertecito area, Socorro County, New Mexico. All analyses by United States Geological Survey, Branch of CoalResources, Denver,Colorado. USGS Dl92395 Sample ID Dl79837 Dl92394 D192392-93 K82074 X82073 Lab No. K82072 Location NW3,1N,4W SE,33,2N,4W SE33,2N,4W 2.5 mi SW. of 2.5 mi SW. of 3 mi SW. of Riley Riley Thickness/sample 2 channel samples channel sample channel sample 1x1~ 1r211, 1'4" 11" type Collected by G.L. .Massingill G.L. Massingill G.L. Massingill Distance below top of Mesaverde -200 ft -250 ft -100 ft 2.2 Air dry loss 3.2. 6.6 Rec 'd -M "&A Rec 'd -M -M&A Rec 'd -M "&ARec 7 . 6 13.6 Moisture 9.1 Volatile matter 35.3 38.9 45.3 25.9 28.0 49.7 35.1 40.7 45.9 Fixed carbon 42.7 46.9 54.7 26.2 28.4 50.3 41.5 48.0 54.1 Ash 40.3 43.6 12.9 14.2 9.8 11.3 Hydrogen 4.1 4.7 4.7 5.4 3.7 3.1 4.8 3.8 4.3 Carbon 56.9 62.6 73.0 36.9 39.9 70.7 54.7 63.3 71.4 Nitrogen 1.1 1.2 1.4 0.8 0.8 1.5 1.1 1.5 1.3 Sulfur 0.5 0.8 0.4 0.4 0.4 0.5 0.3 0.4 0.4 Oxygen (Indf 24.0 17.4 20.3 17.9 12.1 21.5 29.2 19.8 22.4 SuTfur-sulfate 0.01 0.01 0.01 0.01 0.01 0.02 0.01 0.01 0.01 -pyritic 0.24 0.27 0.31 0.17 0.19 0.33 0.19 0.22 0.24 -organic 0.11 0.12 0.14 0.23 0.25 0.45 0.11 0.13 0.15 Ash-Initial Deform. 2105F 2800F 2210F -softening T. 2205F 2310F 2800F. -fluid T. 2305 2405F 2405F 2800F Heating value BTU/lb 9315 10253 11951 6083 6580 11672 8876 10276 11591 Riley - - - - - - - ' L a 0 0 0 0 a - 0 0 K67549 NW,18,1NI5W Hot SpotMine - 9 channel sample 3 t " -2 f - ._ D.E. Tabet ~ ? 1.6 'd -M 6.6 32.8 35.1 54.2 58.1 6.4 6.8 4.5 5.0 67.2 71.9 1.3 1.4 0.5 0.6 19.6 '14.7 - "&A - 37.6 62.4 - '4.9 77.2 1.5 0.6 15.8 0.1 0.1 0.1 0 0 0 0.4 0.4 218 5F 2290F 0.4 1155.5 12374 13279 0 0 0 upper Mesaverde samples ranged from 6.440.3% to (as received) with 3 out of the 4 samples being lower in ash than the samples from the lower Mesaverde. The sulfur contents of samples from upper Mesaverde coals ranged from 0.3 to 0.5% (as received) ; this is approximately one-half These the sulfur differences environments of content of lower in Mesaverde composition deposition for reflect lower coals. the and different upper Mesaverde coals as discussed earlier in this section. The coals of the lower Mesaverde,deposited under mixed brackish, and fresh-water conditions, tend to be higher.in ash and sulfur and lower in BTU values than the fresh-water . ..... . coals of the upper Resource Mesaverde. Potential . . The tonnage of coal area is subsurf difficult ace nature"of data, the ._ to estimate the coal available poor beds, in the because surface and the Riley-Puertecito of the exposures, structural scarcity.of the lenticular complexity of the area. Dataare too sparse in the western half of the area to attempt a resource calculation. Inferred' resources were not subsurface . calculated data 'Indicated and for any areas structuxal resource inile southwest of complexities'. computations of'sections 26 and 27, T.2N., R.4W. Riley, using, because a lackof of were'niade , located the system about for one described 'in U.S. Geological Survey Bulletin 1450-B. (1976). In this area, 18 parts two coal beds, which out continuously for are three to about.4000 four feet feet,and at coal beds are present (G.L. Massinqill, 1979). Mexico Bureau of Mines and Mineral thick, least crop two other The New Resources recently drilled a hole in SE-1/4,SW-1/4, Sec. 26, T.2N., R.4W. to aid in resource estimation. This.'hole intersected five 2.5 to feet, with coal seams ranging in thickness from 1.0 an'aggreqate thickness of 8.0 feet ina stratigraphic interval of 28 feet. The beds dip southeastward at about 15 degrees. The indic,ated resource is about 1,000,000 tons of coal that could be mineda maximum using field is 30 miles by poorly about . stripping ratio of 1O:l. Resource Utilization The Riley maintained coal dirt roads from the railroad siding at Bernardo, on the Santa Fe Railroad Albuquerque-El Paso line. The lack ofa bridge pose a problem over to the trucks, Rio Salado especially at Riley during would the summer 20 miles thunderstorm season. The Riley area is about by dirt roads by highway from from Maqdalena Maqdalena to and the an additional 26 miles Santa Fe Railroad siding at Sgcorro. The old Santa Fe line from Socorro to Magdalena was abandoned several years ago. The combination of transportation problems, a relatively small of the resource San potential Juan and compared Raton to basins, 19 the the large coal relatively low fields heating values, and conclusion the that moderately high ash the coal could Riley content best leads be to the utilized at the site. Abundant limestone, travertine, and shale deposits in the area and the Rio Salado suggests Riley-Bernard0 road the availability of water along that a cement plant might abe feasible way along to the utilize the coal. The labor force could be drawn from Belen, Magdalena, and .the A l a m o lndian Reservation, a11 of which have chronic unemployment problems. The very sparsely populated nature o'f the Riley mental problems. 20 area would minimize environ- URANIUM POTENTIAL IV. Known are 3-1). uranium restricted occurrences to the Baca in the Riley-Puertecito Formation of Eocene age area (Fig. The Baca is a terrestrial sedimentary unit that consists mainlyof reddish siltstones,and^ mudstones, fine-grained. sandstones but also contains light-gray to pale-yellow, coarser sandstones. The lighter colored sandstones are often material, and appear channel-shaped, to have been contain bleached carbonaceous by the passage of ground waters. These characteristics are typical of sandstones containing uranium deposits elsewhere in New Mexico and the Intermountain West. In this section, we will not delve history of the out where guidelines The deeply Baca Baca the Formation, favorable for into long but lithologies and will exist controversial attempt and to give point some general exploration. Formation unconformably overlies the Upper Cretaceous Mesaverde Formation (Fig. 3-1) and contains much material reworked from Cretaceous units. The RileyPuertecito area is located within the central portion of the Eocene basin in which the Baca accumulated. Consequently, the with Baca in this area a has gradational, volcaniclastic sedimentary rocks conformable of the contact overlying Spears Formation of earliest Oligocene (37 agem.y., Burke and others, 1963). Tres Montosas To the south, in the Magdalena and areas, the Spears 21 rests upon the Abo Formation of Permian the age,and entire Mesozoic Somewhere~between Tres Montosas and units along The to the Fo'rmation is section and ofmost the Permian Riley-Puertecito the Permian north Baca outcrop Baca the area, of the the through flank of Formation belt that Joyita regional is extends Hills and and the southward dip must age Laramide exposed from Carthage section. area Eocene the missing, as is be Magdalena along near must an reverse truncated uplift. east-trending Springerville, areas, a few Magdalena- miles Arizona east of the Rio Grande. This outcrop belt is partly due to southward Neogene tiltingof Oligocene and older rocks during upliftof the Formation the is north Colorado exposed and the between overlying Plateau, so that the an eroded upwarped, blanket of Baca younger edge to volcanic and volcaniclastic rocks to the south. Little is known of the original extent and configuration of the Eocene basin in which the Baca accumulated. Regional studies of the Baca Formation by Snyder (1971) and Johnson (1978) have addressed gathering data this on problem clast by measuring compositions, sections transport and by directions, sedimentary structures, and the sequence and geometry of sedimentary units. However, the data areso spar,se and detailed mappingso limited thata reconstruction of the Baca basin (or basins) is not yet possible. Little is known about the age range of the Baca Formation. The top of the Baca in the Riley-Puertecito area isof latest - Eocene earliest 22 Oligocene age because of the gradational Formation whose contact age has with been the well overlying established dating (37-33 m.y., Chapin and others,1978). mammal tooth from the Baca Spears Formation by radiometric A fossil in the Carthage area suggests a middle Eocene age (Gardner, 1910); a partial section of a jawbone with4 teeth from the the Riley-Puertecito area suggests a late (Snyder, 1970): between the Baca west of Eoceneage, However, the duration of the hiatus close of Mesaverde deposition in Late Cretaceous (Conia.cian) time and the beginning of Baca deposition is unknown. In the Red Basin area, north of riatil, a sequence of channel sandstones and interbedded carbonaceous shales occurs beneath typical reddish Baca beds and above the Point Lookout(?) Sandstone of Cretaceous age (Anonymous, Shale beds in this transitional sequence are mostly 1959). gray with only a few red lenses; the sandstones are gray to tan and differ from the underlying Point Lookout(?) in being lenticular, relatively friable sands with a coarser grain size anda higher percentage of angular fragments and heavy minerals (Anonymous,1959). sequence is This transitional 100 feet thick and. apparently fills a about north-northwest-trending paleochannel cut into the lying Point Lookout(?) Sandstone (Anonymous,1959). age of these important transitional because uranium deposition whether there of might their and be the beds is unknown, favorable question similar 23 under- The but they characteristics they raise transitional beds as are for to elsewhere along the outcrop belt. Uranium deposits were discovered in the transitional sequence of the Red Basin area in the early 1950's (Griggs,1954; Bachman, Baltz, and Griggs, 1957; Anonymous, 1959). Unconfirmed reports suggest that Gulf Mineral Resources has extended these discoveries in recent years. No outcrops of beds transitional between Cretaceous and Eocene rocks were found during mapping of the Riley-Puerkecito area. However, Tonking (1957,p. 25) states feet that, of "In Baca several beds outcrops are similar the basal few lithologically tens to of Mesaverde strata." Ln logging drill holes, the Baca-Mesaverde contact may be difficult to pick in some localities. Along the eastern and northern edges of the Bear . Mountains, the Baca members (Fig. 3-1). lower red unit, Formation can be divided into three Potter (1970) called these the middle sandstone unit, and upper red unit. Massingill (1979) also divided the Baca into three members in this gray area, but sandstone, and used red the informal mudstone terms for the conglomeratic, lower, middle, and upper members, respectively. Both schemes emphasize that the middle member a is light-colored sandstone unit that is different from typical Baca lithologies. Outcrops 3-2. West of the of the middle member are shown on Figure Bear' Mountains, subdivision of the the Baca middle is member not is missing a three-fold and possible. Massingill (1979) measureda complete reference section f o r the Baca at the north ofend the 24 Bear. Mountains in I I : W-1/2, Sec. 29, T.2N., R.4W. Here, the lower conglomeratic ! : member is 319 feet thick and consists of reddish-brown mudstone with numerous lenticular, 10to 30-foot beds of coarse, grayish, arkosic sandstone and conglomerate. . . The middle gray sandstone member 176is feet thick and consists of light-greenish-gray to yellowish-gray, friable, clayey, sandstones and siltstones. The upper red mudstone member is244 feet thick and consists mainly of grayish-red to reddish-brown silty mudstone. The total thickness of the Bacaat the reference section is 753 feet (Massingill, 1979). T,he which The middle are unit member favorable crops of to out the the Baca has occurrence over a distance of at. .several of characteristi uranium least deposits. five miles and is thick enough (176 feet) to contain orebodieso f commercial size. It may extend to the southeast beneath the piedmont gravels that mask bedrock along the east side .I of the Bear Mountains and it may extend to the southwest . . beneath the Bear Mountains. The geometry of the middle member is poorly known. Itmaybe a north-northwest-trending -3 channel-shaped fluvial deposit a ofmajor streamor a wedge- shaped body related toa fluvial fan. Detailed sedimentological studies are presently underway (S.M. Cather, in prep.) to determine of the transport directions and the environment deposition. Lithologically, the similar to terrestrial middle sandstones 25 member of elsewhere the that Baca is contain 'uranium mineralization. The sands are bleached and contain abundant carbonized wood fragments that could provide a reducing environment for precipitation of uranium. The sands are clayey but are friable and moderately permeable to the passage of ground water. The existence aofthick section of silicic ash-flow tuffs overlying the Baca Formation (Fig. 3-1) could provide an ample source of uranium. Studies of the uranium content of these tuffs and the systems mobility affecting Uranium middle of uranium the occurrences members of the tuffs in ground-water are currently were Baca discovered Formation and in in hydrothermal progress. the lower and southwest of Riley in the early 1950's (Collins, 1954; Collins and Smith, 1956; Potter, 1970). Several bulldozer cuts were made in gray sandstones of the middle Baca along the 15, R.4W.). south of Baca, Canyon (N-1/2., Sec. T.lN., anomalous minerals radioactivity occur in and of yellow traces limonitic halos escarpment Here, uranium around pieces of'carbonizea logs (Potter, 1970). Similar carbonized logs surrounded by limonitic halos are conspicuous in the middle member near Fall Spring (SE-1/4, Sec. 5 , T.lN., R.4W.I and appear to have been prospected in a minor way. One drill site was observed .' along a road bulldozed up the side of the escar*pment southof Fall Spring. These minor occurrences of uranium in highlyoxidized and leached outcrops of the middle member of the Baca are encouraging. The key to exploration of this unit is to find 26 areas where the middle member has been downfaulted and protected from leaching. One such area exists northwest of Fall Spring on ' the downthrown, (Fig. 3-2). west side of the Hells Mesa fault Displacement on the Hells Mesa fault is 'about 800 feet at Fall Spring and decreases to the north (Massingill, 1979). The middle member can be inferred to be present 1100 feet in the over subsurface pattersoni 0 to depths from drilling of about 2 square area an 29, 30, 31 and'32, T.2N., R.4W., T.lN., R.4W. at miles in sections and sections 5 and 6 , The selenium indicator plant Astragalus grows on outcrops of the middle member where it comes to the surface in sections 29 and 30, T.2N.,R.4W. (Massingill, 1979). Here, the Baca dips about 7 degrees to the southeast. Potter (1970) reportsa minor uranium occurrence in the lower memberof the Baca in Baca Canyon. The reported location isNW-1/4, Sec. 15, T.lN., R.4W., probably section 10, because the but this is lower Baca is not exposed in section.15. According to Potter, the radioactivity is associated <:wo small with piecesof carbonaceous material at the base of a 5-foot .lenticular sandstone bed. The sandstone red is mudstone pale red to is bleached gray light gray. and fora distance 1970). below the sandstone (Potter, the underlying ofi.5 feet Such minor occurrences of.uranium in the lower Baca probably have little or no commercial potential because of the host sandstone lenses. 27 small volume of the , Uranium occurrences were also discovered in the early 1950's at several localities along Jaralosa Canyon, between Corkscrew Canyon and Abbe Spring. Summaries of uranium investigations in this area have been published by.Griggs (1954), Bachman, Baltz, and Griggs (1957), and Anonymous The prospects are smal1,open cuts in thin, light- (1959). gray, lenticular sandstones containing carbonaceous material. Chemical analyses of samples from these prospects range U308 and from 0.1 to 9.21% V205 (Anonymous, fromQ.036 to 3;27% 1959). Mineralized zones range from one to two feet in thickness. The richest of these samples (3.27% U308, 9.21% V205) came from the Kook prospect (Fig. 3-2) in the 5-1/2, Sec. 13, T.lN.,R.6W. considerable drilling and This prospect has had surface trenching over the years but has produced little ore. In recent years, it was the site of an ill-fated leaching experiment and is again inactive. These thin, lenticular sandstones have little commercial potential, even though selected samples may yield high assay values. The main value of these scattered, minor occurrences is the indication that the area a as whole has uranium potential. The key is to find favorable host rocksof sizeable thickness and lateral extent. The middle member of the offas such a target for Baca Formation southwest of uranium discovery of.commercia1 size. 28 of deposits Riley OIL AND GAS POTENTIAL V. The combination degree of ground water gas thermal of shallow maturation, depth and of probable indicates a very low potential production from Cretaceous burial, flushing by oil or for rocks.in low the Riley-Puertecito area. However, the Cretaceous rocks may have potential to the northeast downfaulted and southwest grabens of the beneath where Rio they Grande have and been San Augustin rifts. The low degree of thermal maturation of organic area, dike matter in and several in Cretaceous spite of the sill major rocks of existenceof the swarm in cauldron New most Mexico structures the in Riley-Puertecito spectacular and the existence the Magdalena of area (Chapin and others, 1978); indicates that thermal effects from a major volcanic production beneath fielddo not its outflow preclude oil and gas apron,and may enhance it. M.S. Chaiffetz (in prep.) collected125 samples from Cretaceous units, Formation, and and pollen and Dakota processed for Sandstone through them identification for determination of Mesaverde thermal of spores maturation. Vitrinite reflectance values for shales and coals, not near ,igneous intrusions, average about 0.5%. the.peak oil generation stage and well This is below below the peak dry gas generation. Within1 to 2 feet of a dike, vitrinite reflectance values 1.3 to 1.4&, which approach is slightly above the peak of dry gas generation. Within 1 to 6 inches 29 of of a dike margin, vitrinite reflectance values for organic matter in shales are as high2.5% as and in coalsa s high as 4.5%. These values are near, or above, the dry gas preservation limit. In other words, thermal effects from 2-2) in the Riley-Puertecito the numerous mafic dikes (Fig. area are restricted to the ,vicinity of dike immediate margins. The bulk of the Cretaceous rocks have been very little There affected may be by intrusion of' mafic dikes and sills. some oil and gas potential in Paleozoic rocks beneath the Riley-Puertecito area, bu-t: these rocks do not crop out within the area mapped and we have nothing new to report on them. However, the structural framework outlined during this project should be helpful in evaluating the potential of these deeper formations. For example, differential influenced vertical movements sedimentation rates across during the ehe Tijeras lineament Cretaceous and may have during the Paleozoic as well. The Twowells Sandstone and the pinches Gallego out to the Sandstone southeast thins across markedly in the the lineament, same location. During deposition of basal Mesaverde strata, subsidence on the southeast'side at a more favorable of rate the for lineament coal apparently accumulation than occurred on the gorthwest side. If such differential movements . . occ,urred caused during facies Paleozoic changes and sedimentation, may theyhave thickness to entrapment of hydrocarbons. 30 variations conducive REFERENCES 1. Anonymous, 1959, Uranium deposits in the Datil Mountains-Bear Mountains region, New Mexico: New Mexico Geological Society, Guidebook 10th field conference,p. 135-143. 2. American Society for Testing and Materials, 1967, Standard specifications for. classification of D 388-66) in coals by rank (ASTM Designation Gaseous fuels; coal and coke, Philadelphia: 1967 Bookof ASTM Standards, Pt. 19, p. 73-78. 3. Burke, W.H;, Kenny, G.S., Otto, J.E., and Walker, R.D., 1963, Potassium-Argon dates, Socorro and Sierra Counties, New Mexico: New Mexico Geological Society, Guidebook 14th field conference, p. 224. 4. Bachman, G . O : , Baltz, E.H., and Griggs, R.L., 1957, Reconnalssance of geology and uranium occurrences of the upper Alamosa Creek valley, Catron County, New Mexico: U.S. Geological Survey TEI Report 521. 5. Cather, S.M., in preparation, Sedimentologic study of the Baca Formation, Jaralosa Creek area, Socorro County, New Mexico: University of Texas, Austin, unpub. K.S. thesis. 6. Chaiffetz, M.S., in preparation, Palynostratigraphic and thermal maturation studies from west-central and southwestern New Mexico and far-west Texas: University of Texas, El Paso, unpub. Ph.D. Dissertation. 7. Chapin, C.E., Chamberlin, R.M., Osburn, G.R., Sanford, A.R., and White, D.W.I 1978, Exploration Framework of the Socorro geothermal area, New MexicoI in Chapin, C.E., and Elston, W.E., eds., Field guide to selected cauldrons and.mining districts of the Datil-Mogollon volcanic field, New Mexico: New Mexico Geological Society, Spec. Pub. No. 7, p. 115-130. " a. .Collins, G.E.,195'4, Preliminary reconnaissance report DEB-RFU3-1413: U.S. Atomic Energy Corn. 9. Collins, G.E., and Smith, B.C., 1956, Airborne radiometric survey in the Lemitar-Ladron area, New Mexico: United States Atomic Energy Commission RME-1073 (Rev.) 10 p. 31 1 10. Gardner, J.H., 1910, The Carthage coal field, New Mexico: U.S. Geological Survey Bull. 381-C, p. 452-460. 11. Griggs, R.L., 1954,A Reconnaissance for uranium in New Mexico, 1953: U.S. Geological Survey, Circ. 354, 9 p. 12. Hook, S.C., and Cobban, W.A., 1979, Prinocyclus novimexicanus (Marcou) .Common Upper Cretaceous guide fossils in New Nexico: New Mexico Bureau of Mines and Mineral Resources, Ann. Rept. 1977 to 1978. 13. Jackson, R.A., in preparation, The geology of the Puertecito-La C r u z Peak area, Socorro County, New Mexico: New Mexico Institute of Mining and Technology, unpub. M.S..thesis. -- 14. Johnson, B.D., 1978, Genetic stratigraphy and provenance of the Baca Formation, New Mexico and the Eagar Formation, Arizona: University of Texas, Austin, unpub. M.S. Thesis, 150p. 15. Machette, M.N., 1978, Geologic map of the San Acacia quadrangle, Socorro County, New Mexico: U . S . Geological Survey, Map GQ-1415. 16. Massingill, G.L., 1979, Geology of the Riley-Puertecito area, southeastern margin of the Colorado plateau, Socorro County, New Mexico: University of Texas, El Paso, unpub. Ph.D. Dissertation, 272 p. 17. Corkscrew Mayerson, D.L., 1979, Geology of New Mexico: Canyon-Abbe Spring area, Socorro County, New Mexico Institute of Mining and.Technology, unpub. M.S. Thesis. 18. Molenaar, C.M., 1974, Correlation of the Gallup Sandstone and associated formations, Upper Cretaceous, eastern San Juan and Acoma basins, New Mexico: New Mexico ,Geological Society, Guidebook 25th. field conference, p. 251-258. 19. ,liichelson, H.B., and Frost,S . J., in prepar.ation, Coal history of New Mexico: New Mexico Bureau of Mines and Mineral Resources, Mem. 20. Osburn, G.R., in preparation, Pebble compositions and , transport directions in the Popotosa Formation, Abbe Spring area, Socorro County, New Mexico: New Mexico Bureauof Mines and Mineral Resources, Open File Report. 32 21. Potter, S.C., 1970, Geology of Baca Canyon, Socorro County, New Mexico:University of Arizona, unpub. M.S. Thesis, 54 p. 22. Snyder, D.O., 1971, Stratigraphic analysis of the Baca Formation, west-central New Mexico: Ph.D. University of New Mexico, unpub, Dissertation, 158 p. 23. Tonking, W.H., 1957, Geology of Puertecito Quadrangle, Socorro County, New Mexico: New MexicoBureau of Mines and Mineral Resources Bull. 41, 67 p. 24. United States Geological Survey,1976, Coal resources U . S . Bureau o f classification system of the Mines and U.S. Geological Survey: U . S . Geological Survey Bull. 1450-B, 7 p. 33