MODELING AND COMPARISON OF TRANSIENT EMISSIONS BEHAVIOR OF HYBRID AND CONVENTIONAL VEHICLES by Martin Edward Kosto Bachelor of Science, Mechanical Engineering Rensselaer Polytechnic Institute (1999) Bachelor of Science, Economics Rensselaer Polytechnic Institute (1999) SUBMITTED TO THE DEPARTMENT OF MECHANICAL ENGINEERING IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE IN MECHANICAL ENGINEERING at the MASSACHUSETTS INSTITUTE OF TECHNOLOGY February 2001 BARKER MASSACHUSTTf INSTITUTE OF TECHNOLOGY © 2001 Massachusetts Institute of Technology All Rights Reserved JUL 16 2001 LIBRARIES Signature of Author Martin E. Kosto 9 January 2001 Certified by John B. Heywood of Mechanical Engineering Sun Jae Professor Thesis Supervisor Accepted by. Ain A. Sonin Chairman, Department Graduate Committee I $ N 4 iS' 2 '' A TO MY FATHER, Timothy J. Kosto: An Engineer'sEngineer. 3 4 MODELING AND COMPARISON OF TRANSIENT EMISSIONS BEHAVIOR OF HYBRID AND CONVENTIONAL VEHICLES by Martin Edward Kosto Submitted to the Department of Mechanical Engineering on January 9, 2001 in partial fulfillment of the requirements for the Degree of Master of Science in Mechanical Engineering ABSTRACT: Due to increasing emissions and fuel economy legislation, both in the United States and globally, the search for alternative propulsion systems is escalating. Electric, hybrid gas-electric, fuel cell, and other possible automotive propulsion technologies are continually being evaluated for their merit in a more "environmental society". Investigating these technologies requires both specific evaluation and broad comparative techniques. Currently, most codes associated with hybrid vehicle technology focus on fuel economy, this being the economic driver in the market. Its brother variable, emissions, has been investigated to a lesser degree. Hence, this study will focus on hybrid gasolineelectric system emissions and will examine what determines the magnitude of hybrid emissions and compare these to the emissions of a conventional vehicle of similar scope. Several varieties of emissions estimation methods exist. Many attempt to forecast such levels using a quasi steady-state approach; looking at each time-step independently with no memory of previous results. However, engine transient behavior has a large impact on emissions production. The highest engine-out emissions result from the severe changes in the engine power the vehicle-driving pattern requires. Additional transients occur by a gas-electric hybrid's vehicle constant state of change; turning the engine on and off when necessary. Thus, it is imperative when modeling hybrid vehicle emissions to use a "transient" investigation method. In addition to modeling transient engine (emissions) behavior (modeled as a function of the propellant mixture's air-fuel ratio), a transient catalyst model is included. This allows different control methodologies and improvements in current automobile catalytic converters to be assessed. Such technology is only beginning to be studied and modeled. Yet, it is important to do so, as hybrid technologies will seek to use the best new products available. In conclusion, it is shown that hybrid technology is superior to its conventional counterparts in the emissions arena. Doing so will substantiate criticism of current transportation technologies in favor of new hybrid technology. Modeling results, coupled with real data will substantiate the code and methodology used. Finally, this study gives the reader an improved understanding of the issues associated with hybrid vehicle emissions. Thesis Advisor: Professor John B. Heywood Title: Sun Jae Professor of Mechanical Engineering 5 6 ACKNOWLEDGEMENTS Scientifically, this document is a culmination of one-and-a-half years of work. Philanthropically, however, it is a representation of my life, which has been touched by so many. These souls are those, who in my time of need, were there for me, whether it was encouragement, comfort, help or just pure revelry. My deepest and most sincere thanks go to them, accompanied with best wishes for future success. Thanks go to the members and faculty at the Sloan Automotive Lab, without whom this would have been less of an experience. The day-to-day chatter with Kelly Canales, Brigitte Castaing, loannis Kitsopanidis, Gary Lansdberg, Susan Lutin, Anuscheh Nawaz, Chad Smutzer, and Shigeyuki Tanaka gave my brain some much-needed rest from time-to-time. Brian Hallgren deserves my appreciation for never throwing me out of his office (unless Meredith called). I'd like to thank Professor John B. Heywood, whose direction and suggestions have led to the discovery of knowledge and the successful completion of this project. Thank you Karla (Stryker) for always telling me when my appointments were, no matter how many times I forgot. I also thank Bruce Tobis, Andy Adamczyk and Rod Tabaczynski at Ford, who supplied data and made this project possible. Huxian Shen also deserves a great deal of gratitude for giving me his code when no others were available. Additionally, I'd like to thank all my Chemical Engineering (and other) friends who made weekends (and lunchtime) a lot of fun: Jim Bielenberg, Michael Buchanan, Kevin Dorfman, Jeb Keiper, Tom Lancaster, John Lock, LaRuth Mcafee, Jason Raff, Ley (Llewellyn Bentley the third) Richardson, April Ross, Patty Sullivan, Paul Yelvington, Ian Zacharia, and all those others we often forgot on email lists! I'd especially like to thank Greg Pollock, whose tastes for fine scotch, symphonic bands, late nights, and bar management made the past year a great ride. My gratitude is also deserved by those, who in my life's journey, have played key roles. Dr. Roberta Love, Principal at Lewiston-Porter High School, who had faith in me when few others did. Salvatore Paonessa, whose love for the trumpet and sincere dedication to teaching made me the musician I am today. John P. Cloninger, E. Benjamin Miller IV, Peter Crisman and Judy Muller, all of whom made my experience at RPI not just fun, but unforgettable. Furthermore, I thank my Brother Tim, whose hard work and dedication paved a road to success for me to follow. Without his experiences in hand, this journey would have proven much more difficult. To my Sister Sarah, her husband Chris and their Daughter (my Niece) Elizabeth, who have always been there when I needed help or someone to talk with. Most especially, I thank my parents. Thank you for the encouragement and upbringing that prepared me for life. Your insight and sacrifice have been the underlying basis for my success and I can only hope to provide for my children as you have for Tim, Sarah and myself. Dad, your competence as an engineer is unparalleled and Mom, your unselfishness will always be remembered. To both, your constant support and love have never failed me. 7 Most importantly, I thank Kim Bryan Kosto, my endearing wife, whose love for me, even with my imperfections, has no bounds. You have provided the unconditional love that makes our relationship so special. Only with you am I the happiest man in the world. Thank you. Martin E. Kosto 9 January 2001 8 TABLE OF CONTENTS ABSTRACT 5 ACKNOWLEDGEMENTS 7 TABLE OF CONTENTS 9 LIST OF TABLES 11 LIST OF FIGURES 12 NOMENCLATURE 14 Chapter 1: INTRODUCTION 1.1 Motivation 1.2 Hybrid Technologies Background 1.3 Objectives 17 18 20 Chapter 2: ADVISOR CODE 2.1 Background 2.2 Vehicle Performance Evaluations 2.2.1 Vehicle Calculations 2.2.2 Fuel Converter Calculations 2.2.3 Emissions Calculations 2.2.4 Hybrid Control Strategy 2.3 Limitations 23 24 24 25 25 27 28 Chapter 3: HYBRID/CONVENTIONAL QUASI-STEADY-STATE COMPARISONS 35 3.1 Background 36 3.2 Test Setup 37 3.2.1 Hybrid Configuration 38 3.2.2 Conventional Configuration 38 3.3 Results 39 3.3.1 Engine Operation 39 3.3.1.1 Engine Usage 39 3.3.1.2 More Efficient Operation 40 3.3.1.3 Transient Behavior 41 3.3.2 Engine Tuning 41 3.3.3 Catalyst Cool-Down 42 3.4 Conclusions Chapter 4: ADVISOR AND ADDITIONAL TRANSIENT MODELS 4.1 ADVISOR Emissions Model Limitations 4.1.1 Transient Operations 59 59 9 4.1.2 Chemical Reactions 4.2 Changes Made to ADVISOR 4.2.1 Air-Fuel Ratio 4.2.2 Emissions Calibration 4.3 NTWC Transient Modeling Program 4.3.1 Modeling Method 4.3.2 Integration with ADVISOR 4.3.3 Limitations 59 60 60 62 63 63 63 64 Chapter 5: ADVISOR-NTWC HYBRID/CONVENTIONAL TRANSIENT MODELING 5.1 Background 71 5.2 Comparison 71 5.2.1 CO Production 71 5.2.2 NO, Production 72 5.2.3 HC Production 72 5.3 Hybrid Configuration Results 73 5.4 Conventional Configuration Results 74 5.5 Hybrid and Conventional Comparison 74 5.5.1 Overall 74 5.5.2 Limitations - Startup and Shutdown 75 5.6 Conclusions 75 5.6.1 Transient Effect 75 5.6.2 Hybrid / Conventional Comparison 75 5.6.3 ADVISOR / NTWC Comparison 76 Chapter 6: CONCLUSIONS AND DISCUSSION 6 1 Conclusions 6.1.1 Steady-State Emissions 6.1.2 Transient Emissions 6.1.3 Overall 6.2 Future Technologies 81 81 83 83 84 REFERENCES 87 10 LIST OF TABLES Hybrid/ConventionalQuasi-Steady-State Comparisons Table 3.1: Vehicle Configuration 44 Table 3.2: Catalyst Temperature, Engine Off Time, NOx Conversion Efficiency 45 ADVISOR-NTWC Hybrid/ConventionalTransientModeling Table 5.1: Various Compensations - Hybrid & Conventional - Emissions 77 11 LIST OF FIGURES ADVISOR Code Figure 2.1: General ADVISOR Model 29 Figure 2.2: Conventional Vehicle Configuration 29 Figure 2.3: Series Hybrid Vehicle Configuration 30 Figure 2.4: Parallel Hybrid Vehicle Configuration 30 Figure 2.5: Previous Emissions Temperature Correction Factor 31 Figure 2.6: New Emissions Temperature Correction Factor 31 Figure 2.7: ADVISOR Catalyst Model 32 Figure 2.8: Lumped Capacitance Model 33 Figure 2.9 High SOC 34 Figure 2.10 Low SOC 34 Hybrid/ConventionalQuasi-Steady-StateComparisons Figure 3.1: General Engine Map (Torque vs. Speed) 46 Figure 3.2: Federal Urban Driving Schedule 46 Figure 3.3: Highway Fuel Economy Test 47 Figure 3.4: Binned bmep - Hybrid & Conventional - FUDS 48 Figure 3.5: Binned bmep - Hybrid & Conventional - HWFET 48 Figure 3.6: Engine Map - Conventional - FUDS 49 Figure 3.7: Engine Map - Hybrid - FUDS 49 Figure 3.8: Engine Map - Conventional - HWFET 50 Figure 3.9: Engine Map - Hybrid - HWFET 50 Figure 3.10: Brake Specific NO, Map - Conventional - FUDS 51 Figure 3.11: Brake Specific NO, Map - Hybrid - FUDS 51 Figure 3.12: Binned NO, BSE - Hybrid & Conventional - FUDS 52 Figure 3.13: Binned HC BSE - Hybrid & Conventional - FUDS 52 Figure 3.14: Binned CO BSE - Hybrid & Conventional - FUDS 53 Figure 3.15: Binned HC FSE - Hybrid & Conventional - FUDS 53 Figure 3.16: Binned d(bmep)/dt - Hybrid & Conventional - FUDS 54 12 Figure 3.17: Binned d(bmep)/dt - Hybrid & Conventional - HWFET Figure 3.18: d(bmep)/dt vs. Time - Severe - Hybrid & Conventional - FUDS Figure 3.19: d(bmep)/dt vs. Time - Minimal - Hybrid & Conventional - FUDS Figure 3.20: Difference in Engine-out Brake Specific NO, Emissions - FUDS Figure 3.21: bmep vs. Time - Hybrid & Conventional - FUDS Figure 3.22: Binned Time Hybrid Engine is Off Figure 3.23: Catalyst Efficiency, Temperature and Emissions for 32s Hybrid Engine Shutdown Figure 3.24: NOx Catalyst Conversion Efficiency - Hybrid & Conventional 54 ADVISOR and Additional Transient Models Figure 4.1: General X vs. bmep Figure 4.2: X vs. d(bmep)/dt - Data Figure 4.3: Different Compensations for ADVISOR - [X vs. d(bmep)/dt] Figure 4.4: General Engine-Out Emissions Characteristics vs. X Figure 4.5: Relative NO, emissions versus X Figure 4.6: Relative CO emissions versus X Figure 4.7: Relative HC emissions versus X Figure 4.8: X Based Emissions Adjustment Factor Simulink Model Figure 4.9: ADVISOR - NTWC Visual Connection ADVISOR-NTWC Hybrid/Conventional TransientModeling Figure 5.1: X vs. Time - Hybrid - Different Compensations Figure 5.2: X vs. Time - Conventional - Different Compensations Figure 5.3 General post-TWC Emission Levels (w/o 02 Storage) vs. X 13 NOMENCLATURE bmep Brake Mean Effective Pressure bse Brake Specific Emissions EAF Emissions Adjustment Factor EO Engine Out fse Fuel Specific Emissions FTP Federal Test Procedure FUDS Federal Urban Driving Cycle HWFET Highway Fuel Economy Test ICE Internal Combustion Engine x. Relative air-fuel ratio SOC State of Charge TWC Three-Way-Catalyst 14 15 16 CHAPTER 1 INTRODUCTION 1.1 MOTIVATION With the passage of the Clean Air Act of 1963 and subsequently the Motor Vehicles Air Pollution Control Act of 1965, the automobile and transportation industries embarked on a quest to reduce air pollution. Even prior to 1963 was the creation of the California Air Resources Board, whose task was the improvement of air quality, mainly in the Greater Los Angeles Metropolitan Area. Since then, the automobile industry, coupled with state, national and global governments have strived to reduce automobile emissions by various measures. Beginning with engine controls and simple catalytic converters, emissions improvement technologies now range to entirely new vehicle system designs. These new designs attempt to appease both societies' preceding need for a vehicle with proper speed and range limits in addition to the new necessities for emissions and fuel economy boundaries. To incorporate such diverse requirements, these new concepts often consist of both an electric power generation unit and an internal combustion engine together in a hybrid propulsion system. This new combination is on the verge of mass production. The Toyota Prius, one such gasoline-electric car, has been in production for about 2 years. It achieves a significant improvement in fuel economy and reduction of total tail-pipe emissions (as compared to a similar conventional model). Because of the substantial reduction of emissions (over 8x), the hybrid technology looks promising for the overall cutback of fleet emissions. Thus, with increasing legislation, automobile manufacturers are preparing concept hybrid vehicles as viable alternative to their conventional ICE driven counterparts. With more car manufacturers developing such hybrid automobiles, the need to examine such concepts in the pre-production is clear. To examine novel hybrid concepts, current methods must be revamped to account for the differences between hybrid vehicles and their conventional counterparts. For example, gasoline-electric hybrid vehicles run 17 the internal combustion engines in much less extreme ways, therefore incurring less severe transients because the electric component of the propulsion system can better provide for the rapid fluctuations in torque. While revamping current codes to apply to new hybrid vehicle technology, it is also important to account for improvements in catalytic converter technology, both associated with conventional vehicles and that design for the specific operation of hybrids. With options built-in for future advancements, a code will be much more robust for a far longer period of time than one capable of examining current technology only. 1.2 HYBRID TECHNOLOGIES BACKGROUND Attempts to design and produce vehicles that use less fuel and produce fewer emissions have surged and ebbed over the past 40 years. The fluctuations have previously correlated with the availability and price of oil. Only recently has the realization been made that a more efficient power source will be necessary in the not-sodistant future. The electric car gained popularity in the early 20 1h Century. It was much easier to start, ran quieter and was more reliable than its gasoline internal combustion engine counterpart. However, it ran into the same problems faced today. As the automobile infrastructure grew (roads, gasoline stations, etc.), so did the demand for performance (speed) and range. These two problems are still, by far, the biggest quandaries facing electric and hybrid electric vehicle designers. In 1990, the specific energy of gasoline was 3 orders of magnitude greater than that of batteries. Even with a correction factor for the electrical system's superior efficiency, gasoline was over 200 times more powerful per unit mass than batteries. However, by the year 2000, significant improvements in battery technology have improved the difference by a factor of 50% to a level of 100. Still, with current battery technology, it is not possible to build an electric car that seats five people, travels at speeds up to 100 miles per hour and can trek 300 miles before recharging (which would take only 5 minutes). To combat such a problem, the automobile industry has crossbred the electric car with the internal combustion engine. In addition, other technologies such as fuel cells are seriously being considered, but require further research to be feasible. 18 The gasoline- electric hybrid appears (currently) to be the best solution. Such a vehicle has an electric propulsion system, which is utilized at low speeds where high power is not necessary. At higher speeds and accelerations, the internal combustion engine either assists the motor, or provides all the torque to the powertrain. In addition, it may also recharge the batteries through the motor, which acts as a generator. There exist several variants in the gasoline-electric hybrid family. A series hybrid configuration uses the electric motor as the lone link to the powertrain. Any power supplied by the internal combustion engine will be routed through the motor, then moving along either to the batteries or driveshaft. A dual (or road-coupled) hybrid ties each component to one of the two pairs of wheels, where the electric motor would drive the front wheels and the engine would drive the back. Such an arrangement has rarely been used and is thought to be inefficient. The third (and most widely used) hybrid design is the parallel configuration, where the motor and engine are in parallel to the driveshaft. Unlike the series hybrid, the parallel hybrid's transmission derives power directly from both the internal combustion engine and the electric motor. Hybrids are an improvement over their conventional counterparts for several reasons. First, the fuel economy of a hybrid is significantly better than most other vehicles produced. Some smaller conventional (solely internal combustion engine driven) cars do come near hybrid numbers, but at the loss of utilization for things other than minimal human transport. Fuel economy, being the main driver behind hybrid development and production (in addition to government legislation), gets a major focus. This being true, many studies and codes predominately investigate it, leaving out the other major benefit, reduced emissions. Reduced emissions levels occur in hybrid vehicles for various reasons. First, the internal combustion engine, which produces all the emissions, is run significantly less because the electric motor is used. In addition, conventional vehicle internal combustion engines must be designed so they can endure severe transients. This transient behavior, such as hard accelerations and stops, is another significant contributor to high emissions levels. Hybrid vehicles do not incur such hard transients, for the electric motor contributes when such rapidly changing power quantities are called for. Also, the 19 hybrid's internal combustion engine can be tuned better for emissions at the more steady power levels. Current legislation imposes several levels for emissions reduction. The first level was Tier 1, imposed on all vehicles model year 1994 and newer2 . Tier 2 restrictions further reduced Tier 1 limitations. The Environmental Protection Agency is imposing these restrictions on 49 of the 50 states. California (the other state), abides by restrictions made by its own California Air Resources Board which classifies cars as transitional low emissions vehicle (TLEV), low emissions vehicle (LEV), ultra low emissions vehicle (ULEV) and zero emissions vehicle (ZEV). California also requires each auto manufacturer to sell a certain number of LEV's each year or face fines. The Toyota Prius, the first (and currently only) production hybrid vehicle has been proven in reducing tailpipe emissions and meeting these requirements. Its CO, HC and NO, emissions all meet the SULEV level (super ultra-low emissions vehicles) proposed by CARB. It does so as a hybrid vehicle, but has several novel catalytic converter improvements, such as a light-off catalyst, a HC-absorption catalyst and .3 advancements in air-fuel control strategies. 1.3 OBJECTIVES The foremost target of this study was creating a robust emissions model to allow for first-cut emissions analysis of various hybrid concepts. This model accounts for transient behavior through a catalyst oxygen storage mechanism and changes in internal combustion engine behavior. It also allows for improvements in the catalytic converter technologies represented as an improvement in converter efficiency with respect to temperature. Coupled with a pre-existing hybrid evaluation code, the total model provides for a wide variety of configurations and possibilities. Using this model, one could then pinpoint the "emissions-savings" of hybrid vehicles. This comes from the previously posed question: whether the hybrid is improved because of more stable and better-tuned engines or less ICE running time. The answer to such question provides insight into which areas need improvement. In addition, such information was used to prove the viability of hybrid vehicles in comparison to their conventional counterparts. For example, if the hybrid is better only 20 because it spends less time using an internal combustion engine, then simulations results will shows the ill importance of fine-tuning the hybrid engine, as doing so produces no fewer emissions. 21 22 CHAPTER 2 ADVISOR CODE 2.1 BACKGROUND Over the past several decades, automobile manufacturers, the government and research institutions have progressively developed computer codes to model vehicle systems behavior. These models vary from simple one-dimensional lumped-parameter block diagrams to intricate iterative programs containing many sub-models for various subsets of a vehicle. Currently, there exist two different types of vehicle modeling approaches: forward and backward. The forward approach, for example, determines the vehicle dynamics (i.e. speed) from the given engine output. A backwards approach is just the opposite, determining the engine output and emissions from a desired vehicle speed or other performance variable. When analyzing vehicles' emissions levels, a standard "driving cycle" has been used. This driving cycle concept requires the vehicle to perform at certain speeds and loads over a set period of time, thus creating an easy standard for which every vehicle can be compared. Thus, it is better to use a backward approach when modeling vehiclc emissions is important. Additionally, models may be purely theoretical or semi (or fully) empirical. Theoretical models often allow for a good understanding of the modeled subsection, but often do not allow for a large variation in dynamics or systems to provide feasible results. To model many different systems, a semi-empirical approach is superior. Such a setup allows the end-user to draw from known systems data to further validate a models' results. Yet another trait of modeling programs are their time-use and memory characteristics. Some codes are steady state, calculating one set of results independent time. These being the easiest of codes, some further developed programs are quasisteady-state, where results from previous time-steps are used, but their paths are assumed to be inconsequential. A fully transient model investigates, at all points in time, the effects of a variable. Pure transient models are often complex and unreliable, because 23 they must be purely theoretical or empirical. Hence, a model including some transient assumptions and other quasi-steady measures is often the best at predicting outcomes. ADVISOR (ADvanced VehIcle SimulatOR) is a vehicle modeling code produced by the Center for Transportation Technologies and Systems of the National Renewable Energies Laboratory, a federally funded research lab in Colorado. Running in a Matlab and Simulink environment, it uses a backward, semi-empirical, quasi-steady-state modeling approach. Comprehensively, the backward setup uses a required and achieved set of variables, determining what is needed to what could be produced so as to provide a results check. This project was originally started using version 2.2, but in its course converted over to version 3.0 (October 2000). 2.2 VEHICLE PERFORMANCE EVALUATIONS ADVISOR is a set of eight submodules : the desired Drive Cycle, vehicle, wheel and axle, final drive, gearbox, clutch, fuel converter and exhaust system (Figure 2.1). Using each model differently, configurations for conventional (Figure 2.2), electric, parallel and series hybrid gas-electric (Figure 2.3 and 2.4), fuel cell and customs vehicles can be created. Data files, created by the user using known figures, include generic information about the vehicle, such as mass, geometry, axle size, frontal area and other rudimentary values. In addition to the vehicle, information must be supplied about the powerplant (fuel converter). This may include engine maps for internal combustion engines or performance characteristics for a battery-generator-motor powerplant of an electric vehicle. 2.2.1 VEHICLE CALCULATIONS The vehicle calculations begin with the calculation of forces using a simple force balance: F, = ma (2.1) This includes the rolling resistance, aerodynamic drag and the force of gravity that must be overcome to climb a grade and the force required to achieve certain vehicle acceleration (determined from the drive cycle). The wheel/axle calculations use lookup 24 tables by vehicle mass to determine how much torque/speed is lost due to friction. In addition, it calculates the allowable and desired braking force of the vehicle. All the forces are then combined to determine the vehicle speed, which is then used to comply with the speed specified at time t of the driving cycle. 2.2.2 FUEL CONVERTER CALCULATIONS The fuel converter may be the internal combustion engine, motor, fuel cell or any other power-providing source. Using the required output as an input, it follows backwards to determine how much fuel (gasoline, electricity, etc.) is necessary to provide the requested power. The requested output comes from the transmission, which is linked to the vehicle force required. The torque available is calculated using the engine torque from which the accessories torque is subtracted. The accessories power (and thus torque) is determined using empirical data from vehicles, and is held constant throughout the cycle. The engine torque is the minimum of the requested engine torque or the fuel converters' maximum torque available. This value is computed from look up tables provided by the user. 2.2.3 EMISSIONS CALCULATIONS ADVISOR calculates emissions through a series of steps. Emission levels are evaluated at the engine, out of the engine, and after a catalytic converter. Included are Hydrocarbons, Nitric Oxide and Dioxide (NOx), Carbon Monoxide and Particulates. In the case of a non-diesel fuel converter, Particulates are ignored. Cold Engine-out emissions are first correlated from data supplied to the code. This data is indexed by engine torque and speed. ADVISOR then adjusts the cold emissions to account for engine warm-up using curve fits. These curve fits (Figure 2.5), being outdated, were replaced by new data5 (Figure 2.6). The correction uses a normalized engine temperature, which is a linear function of the difference between present and hot (maximum) engine coolant temperatures. The hot engine-out emissions then proceed through the manifold to a catalytic converter exhaust system sub-model. The top level of the exhaust system thermal model is shown in Figure 2.7. The converter thermal model uses two outputs from the fuel converter as its inputs: the 25 exhaust gas flow rate and engine-out temperature. The exhaust gas loses heat to the exhaust manifold and downpipe prior to reaching the catalytic converter (which in turn lose heat to the engine and ambient). The catalytic converter is modeled via a three-node lumped capacitance model including monoliths, inner steel shell, and outer steel shell. Heat exchange from the gas to the converter nodes, between converter (and pipe) nodes, and from the converter to the ambient is modeled using advection, conduction, convection, and radiation thermal resistances, as shown in Figure 2.8. It is composed of five subsystems. The first subsystem is a block model analyzing the heat loss from the exhaust gas as it flows from the engine, through the manifold, downpipe, and catalytic converter. For each part of the system (manifold, pipes, converter), the convective heat transfer is found using the surface area, a given heat transfer coefficient, and the temperature difference between the wall and gas temperatures. A thermal capacitance is determined using the mass flow and heat capacity of the gas. This is used, in addition to the heat transfer found, to find the gases temperature as it exits the specific system and enters the next. The next sub-model accounts for increases in gas temperature within the converter due to the catalysis of the emissions. First, the catalyzed emissions are broken down to their molar concentrations as a percentage of the total exhaust gas flow. Then, using the element's specific heat, a thermal power of the catalyzed is found. This is used later to determine the converter temperature. The calculation of heat loss in the entire catalyst system is the third sub-model. This includes heat exchanges between the manifold and ambient (convection and radiation), pipes and ambient (convection and radiation), pipes and converter interior and exterior shells (conduction), pipes and converter monolith (radiation), monolith and interior (conduction), interior and exterior (conduction and radiation), and exterior and ambient (convection and radiation). These values are all calculated using user supplied heat capacitances, thermal conductivities, convective heat transfer coefficients and emissivities. In addition, heat flows are based on temperatures from the previous time step. Next, a converter temperature is calculated to provide for the catalyst efficiency. This is assessed first by adding together the heat transfer from the exhaust gas to 26 converter, the total heat transfer from the monolith, and the heat released from the catalyzed emissions. The temperature change is found by dividing this heat transfer by the monolith's thermal capacitance. In addition, applying the same methodology, the other system's temperatures are calculated to be used in the next iteration. Finally, the monolith's temperature is used to find the converter's efficiency. Again, data supplied by the user, indexed by monolith temperature and specific emission (HC, NOX, CO, or PM) provide the emissions reduction percentage. This is then applied to the engine-out emissions to determine what the tail-pipe emissions will be. Additionally, a "break-through" limit is imposed. If the tail-pipe emissions exceed a certain level (ADVISOR suggests 5 times the federal Tier I regulations), then the pre-set number will be used in place of the calculated emissions level. This provides a "realitycheck" to the process. 2.2.4 HYBRID CONTROL STRATEGY ADVISOR has a control methodology to assess, in a gasoline-electric hybrid configuration, when the internal combustion engine and electric motor should operate (both independently and together for added output). ADVISOR provides for several different hybrid control strategies, ranging from series, to electric assist to fuel cell technology. Examining the parallel hybrid arrangement, the code operates as shown in Figures 2.9 and 2.10. When the batteries state-of-charge (SOC) is greater than the minimum allowed (Figure 2.9), the engine will only run above a certain engine speed (called the electric launch speed) and required torque (a constant fraction of the maximum torque). Below these levels, only the motor will provide power to the wheels. The user determines both the launch speed and the off torque envelope. If the SOC falls below the allowed minimum (Figure 2.10), the engine or motor must provide power to the generator to increase the SOC level. If the required torque (torque to wheels plus torque to generator) is below the off torque envelope, then the motor can supply enough power to increase the SOC. However, if the required torque falls above it, the engine must supply power in addition to the motor. 27 2.3 LIMITATIONS Advisor has several limitations to its users. First, the program was designed as a tool to aid in understanding hybrid fundamentals, rather than a reliable predictor of hybrid vehicle behavior. Additionally, the market focus for hybrid vehicles is their improved fuel economy rather than their reduced emissions levels. Hence, ADVISOR provides much more accurate results for fuel economy, where more time has been spent improving the code to reflect reality. Secondly, being quasi-steady state, it doesn't allow for a true transient analysis of vehicle performance; the foremost problem this study sought to tackle. Emissions are transient by nature and occur mostly (after catalyst light-off) during severe transient engine behavior. Thus, if engine behavior is smoother than reality suggests, the emissions data will be inaccurate. It is also true that transient emission modeling is still in an adolescence stage. Finally, ADVISOR is limited by the amount of data held by the user. Because it is an empirical code, specific vehicle configurations require large amounts of information, which may differ from those provided in the code. However, those provided allow for a "back-of-the-envelope" calculation. In all, these limitations may prove ADVISOR inefficient in the vehicle design area, but of exemplary value in an initial feasibility study. 28 total fuel used (gal) gal -- exscalc fc drive cycle <cyc> emis vehicle controls <vc> - AND ->Clutch ri fuelHCC, vehicle <veh> wheel and axle <wh> final drive <d> gearbox <gb> clth exhaust sys NOx, PM (g/s) <ex> f>cere Figure 2.1: The general ADVISOR model. This shows the different vehicle components of the model used. Wheel Gearb ox 'ftI :Final Dnive Cl itch J... Jfc: Fuel Converter Figure 2.2: Conventional vehicle configuration in ADVISOR. 29 Wheel Gearbox Jfa :Final D rive 61172...Energy Ja Converer Geerato -Mto Fuel Power ... KiStorage Bus N... System Figure 2.3: Series gasoline-electric hybrid vehicle configuration in ADVISOR. Wheel ...... Gearbox......... Torque Coupler J& J Final :Drive ......... ..... Motor .................................. Fuel Converter Energy Storage System Figure 2.4: Parallel gasoline-electric hybrid vehicle configuration in ADVISOR. 30 Hot Engine Out Emissions Correction Factor ADVISOR 20 18 16 14 12 H0 10wU 8 642 0 260 a Y '4 -- --- 280 % -- 30 0 320 340 360 380 Engine Coolant Temp [K] -- HC - - - CO NOx Figure 2.5: Previous ADVISOR hot engine-out emissions correction factor. (EO emis = Cold EO emis * CF) Hot Engine Out Emissions Correction Factor SAE Paper 971603 1.6 1.4 1.2 - 0 1 0.8 0.6 0.4 260 280 300 320 340 360 380 Engine Coolant Temp [K] -- HC - - - CO NOx Figure 2.6: Study updated hot engine-out correction factor. (From SAE 971603) Note the significant change from Figure 2.5 in both magnitude and deviation from unity. 31 OLD cat temp. OLD Temp Correction OLD tail pipe emis Trn- , EU Terminator ex-cat_ eff I ~ThFJ*E~sat~ Heat Transfer as ga s flows from engine to catalytic converter emisca'd i Tex,gas ex-gas-tmp Efficiency assigned using gas temperature ex gas flow creakthru Ocat EO emis info Tex,eo $ ex cat th_pwr - HC ncti temp eff Xmax ex-cat-tmp exoeem temp elf -K ex gas heat flow ............... Ocm m 1/Ccm Qcat-i + -- Ocat ex temp u)M c temp eff -..... -/ /c Enable 1Cp x Omni ex sys heat flow tailpipe emis (g/s) Max of breakthrough or catalyzed gas / -K Qcp catalyst using cond, cony & rad ... temp eff Qci Ocal-p Calculates HT in Ox T mN veh spdpc Tfc,x T '-U ....... Ocat . /Ccx m /C Figure 2.7: ADVISOR catalyst model. Emissions coming in are temperature corrected engine-out emissions with data such as temperature and mass flow rate. Temperatures are found using heat exchanges between the gas, the catalytic converter and the environment and thermal capacitances (shown in Figure 2.8). Conversion efficiency is found using the catalyst temperature and applied to the engine-out emissions entering. Cl . Inlet pipe .CLdulyIl wIwtILtn cor eter S Exhaust gas . ... .U ........ .... ........-_ --- hm- " ___W i. Exhaust gas ct Rc,2 Rd1 22 Tip dt Rcn1 R--2 'TdE R4 RAv R:v2 Rda2 Ren3 TdC Rd3 R>6s .. Rd4 - Amb ient Figure 2.8: Lumped Capacitance Thermal Network Model of Catalyst System, where: A - Monolith B - Interior C - Exterior 33 For SOC > cslo_soc j Engine Torque Maximum Torque Envelope Engine ON Off Torque Envelope Lcsoff trq fiac*(max torque ) ....... .... ...... ,4 Electric Launch Speed w Engine Speed Figure 2.9: When the SOC is high enough such that the batteries need not be recharged, the engine will commence operation only when the motor cannot fully provide the total torque required. For SOC < cslosoc Engine Torque Maxim iu Torque Envelope Aiditional Charge Torque cs_chargeftrq *(avg(cso _soc, cs_hi_soc)-SOC) *Case 1 (blue): Operation point isrequire d tor que plus charge torque * Engine ON " ... - - Minimum Torque Envelope cs_mintrcLfrac*(max torque) . ea Required Case 2 (red): Operation point lies along mniimum torque envelope because re quire d tor que plus char ge torque is too low Torque Ii Engine Speed Speed Figure 2.10: When the SOC is such that the batteries need recharged, the engine will commence operation when the motor cannot fully provide the total torque required (which is the vehicle torque + torque to charge the batteries to increase the SOC). 34 CHAPTER 3 HYBRID/CONVENTIONAL QUASI-STEADY-STATE COMPARISONS 3.1 BACKGROUND Fundamentally, a gasoline-electric hybrid vehicle (referred herein as hybrid) incurs fewer emissions because it operates the internal combustion engine less than a conventional vehicle under the same speed and range requirements. In addition to this simple proviso, it is important to note when the hybrid does not use its ICE. Most hybrid control strategies call for engine output only when the motor is not powerful enough to drive the vehicle at the requested speed (usually above 45 miles per hour). 70% of emissions come during the first few minutes of driving, before the catalyst system can warm-up. Thus, if the hybrid is not using its ICE during this time period, a substantial reduction in emissions occurs. Also, emissions systems improvements such as light-off and electrically heated catalysts and HC absorption chambers improve the time to lightoff and overall efficiency of the catalyst. With the hybrid control strategy, however, it is necessary to investigate catalyst cool-down. A hybrid vehicle may not use its ICE for large periods of time. In doing so, the catalyst temperature may fall to where it wields the system inefficient versus a continuous conventional system. In addition to the original proviso that hybrids emit less because they use the ICE less, the hybrid's engine performs in the more efficient portions of the engine map (at high engine speed and torque) as shown in Figure 3.1. Because the hybrid uses the electric motor below (approximately) 45 miles per hour, it operates the ICE not just less, but less in the more inefficient areas of the map. Furthermore, engines placed in hybrid vehicles can be better tuned for improved emissions output. Because hybrid vehicles only use their engine to provide power at high levels (save when the batteries need charged), the engine can be designed such that, the performance map for engine out emissions is centered about the average operating points. 35 Severe engine transients is yet another extensive contributor to engine-out emissions. When the catalyst is fully warmed up (usually by 1-2 minutes into a driving cycle), it reduces engine-out emissions between 90% and 98% except when there is a significant change in the engine-out emissions composition. The hybrid vehicle does not incur as many severe engine transients for several reasons. First, the foremost significant transient occurs from a stopped position. When the vehicle accelerates from 0-20 or 0-45 miles per hour (even 0-60), these transients are handled by the motor. Similarly, the hybrid's ICE operates between vehicle speeds of 40-85 miles per hour, a difference of 45 mph instead of an 85 mph spread (0-85 mph). Finally, the hybrid control strategy allows the motor to provide dampening to any unusual power requests to the engine, such that the engine has ample time to react and adjust. Thus, there are several investigations to be made using the simple quasi-steadystate approach built in to ADVISOR. First, determine why the hybrid produces fewer emissions than its conventional counterparts. This will show the relative advantages of fewer emissions (due to engine shut-off) versus the operation in a more efficient (less engine-out emissions) area of the engine map. In addition, it is necessary to test the long engine shut-off periods to ensure the catalytic converter temperature does not drop below an efficient level. Finally, a by mile-engine-on comparison will be made to determine if the hybrids engine is better or worse than its conventional counterpart. 3.2 TEST SETUP As prefaced, ADVISOR simulates vehicle performance according to specified conditions (driving cycles). To compare a conventional vehicle with a hybrid counterpart, two such configurations were created (see 3.2.1 and 3.2.2). Furthermore, a set driving cycle was needed to compare these vehicles; one which represented typical driving in the United States. Such a cycle exists, and is known as the Federal Test Procedure Cycle. This procedure is comprised of two driving cycles: the Federal Urban Driving Schedule (FUDS) (Figure 3.2) and the Highway Fuel Economy Test (HWFET) (Figure 3.3). The FUDS driving cycle is used to simulate city driving. It is comprised of several vehicle accelerations and decelerations of different amplitude, a rest period and 36 the same acceleration/deceleration levels repeated. These represent the start-and-stop nature of urban driving. The cycle is 1372 seconds long with a top speed of 56.7 miles per hour and an average speed of 19.5 mph. The total distance traveled is 7.5 miles. The HWFET driving cycle is used to simulate highway driving. This test consists of a warm-up phase followed by a test phase. The driver follows the same driving trace in both the warm-up and the test phase. However, since ADVISOR is coded to include hot starts, the first phase is redundant. The cycle (as used in ADVISOR) is 770 seconds long with a top speed of 59.9 miles per hour and an average speed of 47.6 mph. The distance traveled is 10.3 miles. Several simulations were run, changing the vehicle type, initial conditions (hot or cold start-up), physical and geometrical aspects of each vehicle configuration, and the driving cycles. A time-step of 0.1 seconds was used. To keep post-processing time to a minimum, only 35% (480 seconds) of the FUDS driving cycle and 65% (500 seconds) of the HWFET driving cycle were analyzed when comparing vehicles. The catalyst cooldown simulations used the entire cycles. A physical comparison of vehicles can be found in Table 3.1. 3.2.1 HYBRID CONFIGURATION The hybrid vehicle used for the simulations was created as something similar to the PNGV (Partnership for a New Generation of Vehicles) goals 6, being a mid-sized vehicle with enough power to perform as a typical conventional vehicle would. Using this as a baseline, a medium car frame (a 1998 Ford Taurus) was used. The internal combustion engine is an inline 4 cylinder engine, similar to one found in a Ford Contour. The engine's power output is 77 horsepower and emissions data was scaled from the 105 horsepower engine data received from the Ford Motor Company. The motor was selected to provide the hybrid vehicle with approximately the same maximum horsepower from an average car, such as the Taurus. Thus, a 90 horsepower motor was used, bringing the total vehicle power to 167 horsepower. Additionally, a manual shift transmission was selected from ADVISOR's set of data. This 5-speed model was edited to include gear ratios also supplied by Ford. 37 3.2.2 CONVENTIONAL CONFIGURATION A 2000 Ford Taurus was modeled as the "average" family vehicle built at the time of the study. Using the same frame as the hybrid vehicle, only the powerplant and transmission were changed. The internal combustion engine was a 153 horsepower Vulcan V-6 cylinder engine with a displaced volume of 3 liters. All data for this engine was, again, supplied by the Ford Motor Company. The transmission was modeled as a 4 speed automatic rather than a 5 speed due to judgments that it better suited a mid-size family car, whereas a 5 speed manual transmission would be used in a hybrid to increase efficiency. 3.3 RESULTS Upon running each scenario, a spreadsheet was created to view and analyze the data as prescribed above. Output variables from ADVISOR included (on a lo second basis): hot and cold start engine-out and tail-pipe emissions, internal combustion engine speed and torque, motor speed and torque (hybrid only) and vehicle speed. From this data, the brake mean effective pressure (bmep) was calculated using Formula 3.17: Bmep[kPa] = 6.28 x n, x Torque[Nm] (3.1) Vd [liters] In addition, the power produced by the internal combustion engine, was found using Formula 3.2: bmep[kPa] x Vd[liters] x N rev Power[kW] = x 1 (3.2) Total Torque = Engine Torque + Motor Torque (3.3) The total torque was calculated using Formula 3.3: The change in bmep with respect to time was calculated for each time step in addition to all three torques (engine, motor, and total). 38 Bmep is subsequently used as a comparison factor because of its good qualities. First, it compares the engines only and has no component for the hybrid vehicle's motor, which is unimportant because it produces no emissions. More importantly, it scales torque with respect to engine displacement (size), allowing for reasonable assessments between the 1.25-liter hybrid and 3-liter conventional engines. Furthermore, brake specific emissions (bse) were used, as opposed to normal emissions calculations that present emissions as a mass fraction of the total output. Bse data is formulated as mass per power output of the engine, which also normalize the results, so as not to mis-compare emission predictions from two different engines. 3.3.1 ENGINE OPERATION 3.3.1.1 ENGINE USAGE First examined were emissions savings due to less than whole engine usage for the hybrid vehicle. The engine runs only 21% of the total time in the hybrid vehicle as compared to 95% of the time in the conventional (an initial starting delay of -20 seconds occurs) over the first 480 seconds (35%) of the FUDS driving cycle (Figure 3.4). Summing the emissions produced by the conventional vehicle at times when the hybrid engine was off, a 72% reduction in engine out emissions occurs. Additionally, the hybrid runs its engine during only 40% of the first 475 seconds (65%) of the HWFET driving cycle (Figure 3.5) compared to the conventional engine running 98% of the time. A 50% reduction in engine-out emissions is seen by the hybrid from its conventional counterpart comparing engine-off emissions. 3.3.1.2 MORE EFFICIENT OPERATION The hybrid vehicle uses the engine at less polluting operating conditions. Comparing Figures 3.6 and 3.7, the conventional vehicle operates at all levels of the engine map, whereas the hybrid engine only performs at the more efficient points, nearer to the "center " of the map. This phenomenon is true for the HWFET driving cycle as well (Figures 3.8 and 3.9). For the conventional vehicle, only 30% of the engine 39 operating points are above 30% efficiency. On the other hand, the hybrid operates exclusively above the 30% mark. Furthermore, the effects of engine efficiency and emissions production are considerably similar. Looking at the bse maps for the FUDS cycle (Cold Start), the conventional vehicle (Figure 3.10) shows that only 36% of the NOx emissions are below 10g/kWh, whereas 80% of the hybrid vehicle's (Figure 3.11) NOx emissions are below 10g/kWh. Moreover, 20% of the conventional vehicle's NOx emissions lie outside 34 g/kWh as compared to only 18% of the hybrid. This trend can also be seen in Figure 3.12, where the hybrid has significantly less outliers. Changing the data to reflect only times when emissions are being produced, 51% of the hybrids occur below 10 g/kWh as compared to 40% of the conventional vehicle. Beyond 20 g/kWh, the vehicles produce nearly the same percentage of emissions when the engine is producing emissions. For HC (Figure 3.13) and CO emissions (Figure 3.14), the same, but more pronounced, phenomenon occurs. The no-emissions levels are much higher for the hybrid vehicle. Its emissions profile is similar to a "normal" distribution about the lower i. The profile for the conventional vehicle is also similar to a normal distribution, but has a higher offset and a significant tail that extends out past the hybrid's profile. A fuel-specific approach to tail-pipe emissions production shows the hybrid to produce similar (but reduced) amounts of HC, CO, and NO,. Figures 3.15 shows similar emission profiles when the HC emissions levels are divided by the fuel used. The center of the hybrid distribution is slightly smaller, which is to be expected for a slightly smaller engine. The profiles are not tremendously different because the engine technologies are similar. The offset is again attributed to the disproportionate engine use by the conventional vehicle. 3.3.1.3 TRANSIENT BEHAVIOR Reducing the transients of a vehicle greatly reduces the level of emissions produced. Figure 3.16 shows the change in bmep with respect to time for both the conventional and hybrid vehicles for the FUDS driving cycle. The hybrid vehicle has significantly fewer large (10-1000 kPa/s) transients because the motor aids to control such events. The HWFET driving cycle shows similar results, however, the hybrid incurs 40 more sizable positive torque (bmep) changes (Figure 3.17). There are fewer large negative torque changes, because the extra power is used to charge the hybrid's electrical system. Thus, there are fewer emissions and more available power. Additionally, Figures 3.18 and 3.19 show the difference in transient engine operation during the FUDS driving cycle. Figure 3.18 shows the difference in severe engine transients while Figure 3.19 shows the difference in smaller transients. The reduced transients transform into reduced emissions looking at the difference in engine-out emissions (Figure 3.20). Most of the differences are negative (difference = hybrid - conventional), thus there is a significant decrease of engine out emissions between the conventional and hybrid vehicles. The graph only accounts for those times when both engines are running and creating emissions. Over 70% of the time the hybrid engine generates less (normalized) emissions than the conventional vehicle's engine. Only 13% of the time does the hybrid produce significantly (>5g/kWh) more NO, emissions. 3.3.2 ENGINE TUNING The hybrid vehicle also incurs fewer emissions because it is not required to perform at such vastly different operating points. Figure 3.21 shows the difference between the bmep along the FUDS driving cycle for each vehicle configuration. The conventional vehicle must be able to vary between 0 and 900kPa. The hybrid must vary only between 400 and 800kPa with a few outliers at points where the program "hiccups". This alleviates the need design for power output at inefficient points (the phenomenon described in Section 3.3.1), and therefor the hybrid's internal combustion engine need not be as rigorous as its conventional counterpart. ADVISOR, however, only takes this into account only upon the user defined engine emissions output data. 3.3.3 CATALYST COOL-DOWN The temperature of the catalytic converter determines how efficiently the catalyst will perform its function. As the engine is run, hot gas warms the converter making it more efficient. Thus, it is important to see how the catalyst temperature and efficiency 41 vary both over the entire driving cycle and, more specifically, during periods when the hybrid does not run its internal combustion engine. Over the entire 1372 seconds of the FUDS driving cycle, ADVISOR shuts the hybrid's engine off 181 times. The length of shut off (shown in Figure 3.22) varies between 0.1 and 60 seconds. The shut-offs of length less than 2 seconds probably would not occur in real life and will be ignored. This assumption leaves 55 occurrences of average length 14.3 seconds. Although the catalyst temperature may not drop in an average stop, a 60 second (or longer) stop may prove detrimental to the catalyst temperature, thus efficiency, thus reduced emissions. For example, Table 3.2 shows a sampling of engine shutdown periods. The largest decrease in NO, catalytic efficiency occurs during a 57-second shutdown, where it drops by 5.3%. It is the largest because the catalyst has not been heated to its maximum efficiency. However, the shutdown is for a considerable amount of time, and those emissions not catalyzed are far more desirable than those produced by the conventional vehicle. Once the catalyst is warmed above -300'C, even a 60-second shutoff results in a loss in efficiency of only 2%. Figure 3.23 shows a typical 32-second shutoff profile. The catalyst temperature drops 16'C while the efficiency drops less than 3%. Figure 3.24 is a close-up look at the effect of catalyst cool-down. ADVISOR sets a maximum limit for NOx catalyst efficiency, which is 91% in this case. Once the conventional vehicle reaches 91%, it remains constant throughout the remainder of the driving cycle. The hybrid's catalyst, when the engine disengages, does lose some efficiency, albeit often less than 1%. This proves there is little or no effect (especially after catalyst light-off) of temperature loss affecting the catalyst efficiency. 3.4 CONCLUSIONS There is a considerable emission savings when comparing a hybrid vehicle to its conventional counterpart. From the data above, one can point to several reasons: reduced transients, less asked of the internal combustion engine, both overall and particularly in bad emissions areas, and the overall design and tuning of the powerplant itself. Clearly, emissions reductions will occur if the engine is better tuned to operate in a specific region of torque output, albeit a minimally. Furthermore, the reduction of engine transients 42 trims the engine-out emissions by 10-20%, thus creating a noticeable impact on the total emissions output. However, the engine operating procedure is the primary reason for decreased tail-pipe emission levels. Although the lack of emissions (due to engine shut-off) does provide for sizable decreases, the fact that the hybrid does not operate the engine in high emissions areas (low torque and low speed) is probably the most significant improvement in the vehicle design and control. If the engine operated at the low end of the engine map, a significant increase in emissions would occur (comparing just the hybrid to itself). Hence, it is of great importance to design the engine for minimum emissions output at high engine operating conditions. 43 Table 3.1: Vehicle configuration in ADVISOR for hybrid and conventional vehicles. venicle ueometry 1000 2.04 0.335 Mass [kg] (w/o engine) Frontal Area [mz] Cd Wheelbase [m] 2.6 Height [m] (Center of Gravity) Cargo Mass [kg] Transmission Speed Shift 0.5 140 4 Automatic 5 Manual Internal Combustion Engine Displacement [L] Valves [per cylinder] Maximum Torque [Nm] Maximum Power [kW] Mass [kg] Electric Motor Maximum Power [kW] Maximum Torque [Nm] Mass [kg] 44 1.25 3 4 4 300 @ 4500 rpm 110 @ 4300 rpm 58 130 186 416 75 273 @ 6000 rpm 91 Table 3.2: Sample Results for various engine off intervals. - I Citdty~t Ten1p~rature ILL. I~ 701.8 2 381.2 2.2 464.1 2.2 598.6 2.2 706.7 2.2 311.3 4.2 560.0 4.2 674.0 4.2 688.0 4.2 309.8 6.2 386.0 6.2 675.8 6.2 566.8 6.3 60.1 10.2 337.4 12.2 36.2 15.5 645.6 15.6 301.5 16.2 507.0 16.2 459.9 22.4 684.9 22.7 687.4 29.7 Engine Off Time I 31.6 479.6 33.1 36.9 529.9 691.7 442.5 394.3 659.7 452.7 249.0 323.7 615.3 39.1 39.3 40.2 49.1 57.3 59.2 60 I U -U- A'ncNO~ ATc -1.7 -1.9 -0.6 -1.8 -1.5 -1.2 -3.8 -2.4 -3.2 -2.8 -4.8 -3.2 -4.3 -2.5 -8.0 -0.4 -9.3 -12.4 -9.8 -7.7 -12.8 -15.7 I- -0.5% -0.2% 0.0% 0.0% -0.3% 0.0% 0.0% -0.1% -4.3% 0.0% -0.4% -0.1% -4.0% 0.0% 0.0% -0.5% -0.8% -3.4% 0.0% 0.0% -1.3% -1.4% -0.1% -2.8% -3.6% 0.0% -2.0% -5.3% -2.7% -14.6 -16.7 I -18.4 -9.8 -15.2 -19.3 -16.1 -8.3 -11.2 -9.5 0.0% -1.7% I- 45 Torque (bmep) Ak More Hybrid Speed Figure 3.1: Speed vs. T orque engine map - hybrid and conventional vehicles. The conventional vehicle operates in more regions while the hybrid's operation is more concentrated and in a more efficient region. Federal Urban Driving Schedule 30 25 20 0. E 15 10 5 0 0 200 400 800 600 1000 1200 1400 Time [s] This test protocol is for city Figure 3.2: Federal Urban Driving Schedule (FUDS). driving and includes 2 (identical) acceleration/deceleration periods in addition to a shut-off period. The red line shows the first 35% (480 seconds). 46 Highway Fuel Economy Test 30 25 20 , n 0. ' r F 15 10 5 0 0 200 400 600 800 Time [s] This test protocol is for Figure 3.3: Highway Fuel Economy Test (HWFET). highway driving. The red line shows the first 65% (476 seconds). 47 bmep vs. Binned Timesteps - 35% FUDS 10004 940 3922 900 741 800 700 574 600 595 458 500 412 4 400- 8 351 255 316 300 18 193 200 200- 125 57 100- 76 5 71 34 31 0 0 -4 0 0 8 8 CD S D 0 0 0 0 bmep [kPa] 13 3.OLEN 1.25L] Figure 3.4 (top) and 3.5 (bottom): Engine bmep output for the FUDS (3.4) and HWFET (3.5) Driving Cycles. In both, there is a significant amount of time the hybrid's engine is off (and not producing emissions) and the hybrid does not have negative bmep because the engine shuts off during such time periods. bmep vs. Binned Timesteps - 65% HWFET 2925 2000 1752 1600 0L 1200 979 800 656 655 E 762 448 420 400 289 263 180 151 0 21 47 0 0 31 0 0 0 0 cc CD [ 3.OL M 1.25L 48 C,) 0 0 0 0 0; 0 8 bmep [kPa] 0 40 A IC Engine Torque vs. Engine Speed Ford 3. OL 35% FUDS 351 301 251 z 201 0* 151 101 - - -2 ---- -_ - -- 51 +1 1 6000 5000 4000 3000 2000 1000 0 Engine Speed [rpm] *2.02% u 30.99% A 31.10% X 17.24% K 2.79% * 5.72% + 10.12% Figure 3.6 (top - Conventional) and 3.7 (bottom - Hybrid): Engine operating (efficiency as a decimal) points indexed with engine torque and speed for FUDS driving cycle. The hybrid operates solely within the 30% efficiency contour while the conventional vehicle operates only i of the time above 30% engine efficiency. IC Engine Torque vs. Engine Speed Ford 1.25L 35% FUDS 121 101 81 E z --3 61 0 41 + .02 21 0.15 -~~-0-I 0 2000 1000 4000 3000 6000 5000 7000 Engine Speed [rpm] + 6.32% m 47.30% A 33.44% X 12.95% - -0.00% 0 0.00% 49 IC Engine Torque vs. Engine Speed Ford 3.OL 60% HWFET 351 301 251 E z 201 U)P 151 101 0.26 X 51 1 5000 4000 3000 2000 1000 0 6000 Engine Speed [rpm] 0.41% U 24.94% A 52.77% x 16.85% x 0.21% * 3.51% + 1.31% Figure 3.8 (top - Conventional) and 3.9 (bottom - Hybrid): Engine operating (efficiency as a decimal) points indexed with engine torque and speed for HWFET driving cycle. The hybrid operates solely within the 30% efficiency contour while the conventional vehicle operates only i of the time above 30% engine efficiency. IC Engine Torque vs. Engine Speed Ford 1.25L 60% HWFET 121 - 101 81 E j~3 0) 61 41 - 21 0.2 ----- 1 101 0 1000 2000 3000 4000 6000 5000 Engine Speed [rpm] + 50 11.29% m 38.32% a 43.08% < 7.31% -0.00% * 0.00% 7000 ICE Torque vs. Engine Speed - NOx Map Ford 3.OL 35% FUDS 351 301-- are Brake -Contours 251 Specific Emissions [g/kWh] E 20X E 201- 51 Figure 3.10 (top - Conventional) and 3.11 (bottom - Hybrid): NOx emissions [g/kWh] points indexed with engine torque and speed for FUDS driving cycle. In addition to fewer points (less emissions), 80% of the hybrid's emissions are better than 15 g/kWh whereas only 55% of the conventional points are within that limit. ICE Torque vs. Engine Speed - NO. Map Ford 1.25L 35% FUDS 121 101 1P 81 -A E 61 ~' ~N 0 4IPf~ 4 .9' I 4 ~ 41 21 ~~4.9I N 7. i|I I 1 0 1000 -~ 2000 3000 4000 5000 6000 7000 Engine Speed [rpm] * 43.12% 0 12.44% 13.86% 9.17% X 2.75% 6.01% + 12.64% 51 brake specific NO, Emissions 1738 vs. Binned Timesteps - 35% FUDS - Cold Start 3822 1200 1040 1000 846 800 w 600 1384 343 400 26 200 200 j 192 23 200 1 136 116 165 110 0" 0 0m n ? r 7 0n 0 -0 i. Zo 0n 0 - .: bs emissions [g/kWh] 3 3.OL 0 1.25L Figure 3.12: Binned brake specific NO, emissions for hybrid and conventional vehicles. Note undefined brake specific emissions occur when the power is zero or negative. These emissions would be "idling" emissions and range between 0 and 5 g/kWh. Similar to the emissions maps above, there are fewer total occurences of emissions. brake specific HC Emissions vs. Binned Timesteps - 35% FUDS - Cold Start 3822 1738 800- 737 737 700 600 500 454 408 400 259 300 200 170 157 200 140 134 165 164 131 56 49 68 100 15 2 0 o3.OL l 1.25L - bs emissions [g/kWh] Figure 3.13: Binned brake specific HC emissions for hybrid and conventional vehicles. The hybrid's distribution is smaller in both offset (time) and width (severity) of emissions production. 52 brake specific CO Emissions vs. Binned Timesteps - 35% FUDS - Cold Start 1938 3822 10 00 00 - 900 808 8 00 - 7 0 DO 00 II 0 0. 0 500- 0 4 00 - 30 419 395 E p 331 346 47H 300 196 2 0 0 150 108 114 87 33 231 0 01870 .R 0 . 98 76 1 4 -4 -El -4 0 AL bs emissions [g/kWh] 1 0.LE 1.25L Figure 3.14: Binned brake specific CO emissions for hybrid and conventional vehicles. The hybrid's distribution is smaller in both offset (time) and width (severity) of emissions production. fuel specific HC Emissions vs. Binned Timesteps - 35% FUDS - Cold 3822 - 10 00 1429 9 00 8 00 750 663 7 00 6 00 521 482 5 00 469 437 CL I- - 4 00 298 A: 30 0-200 2( 174 4159 0- 101 10 17 1 19 2 12 18 5 21 1 10 111 0 -. 0 3.OL M 1.25L fs emissions [g/ ] 0 . A - Figure 3.15: Binned fuel specific HC emissions for hybrid and conventional vehicles. The hybrid's distribution is again smaller in both offset (time) and width (severity) of emissions production. The lack of large levels (100+ g/kg) is because the hybrid rarely uses small amounts of fuel. 53 Transient Behavior dbmep/dt vs. Binned Timesteps - 35% FUDS 1258 3792 600 584 5897 533 545 525 500- 400 296 ( - 300 246 197 200 - 134 114 110 95 100 - 75 67 43 31 52 7 3 2 5 9 13 4 6 2 2 0 n 0r\, - ~ Lnt o Cn - -LN ~dbmep/dt 13 0 3.0Luo1.25L N 0 51 A 0, 0 1 [k as]J -~- Figure 3.16 (top - FUDS) and Figure 3.17 (bottom - HWFET): Severity of Transients. Binned changes in bmep with respect to time for hybrid and conventional vehicles. This shows the hybrid has less severe changes in bmep over time, thus less severe and overall transients which leads to better emissions. Transient Behavior dbmep/dt vs. Binned Timesteps - 65% HWFET 3137 1392 1000 -r 901 900 - 836 800 - 732 700614 *. 600- ( 500 - 0 400- 566 413 E 300164 200 68 100- 7 8 54 8 102 219n28 12 7 8 7~ 7 8 0 7 0 '. 0 - ' II (7 151 98 3 [] 83 0 0 000 0 A S03.OL E 1.25L 3 2 50L 9 - - -N ? dbmep/dt [kPa/s] -. I 0 oo on o § t 525 dbmep/dt vs. Time Ford 3.OL & 1.25L 35% FUDS -- 500 400+ 300 - 200 Z! 100w50 -0. C0 -100No 0 -200 * -300* . 1! -400 -500 Time [s] + 3.OL a 1.25L Figure 3.18 (top - Severe) and Figure 3.19 (bottom - Minimal): Transient magnitude. Changes in bmep with respect to time for hybrid and conventional vehicles using different scales. The hybrid incurs fewer severe transients (top) and the magnitude of smaller changes in bmep are 50-75% less then those of the conventional vehicle (bottom). dbmep/dt vs. Time Ford 3.OL & 1.25L 35% FUDS 20 - * + **f++ - 15 + 10 40 1L *% +.iBL 5 E* -10- -15 -20 -* * 3OL 1 .25L U Time [s] 55 Difference of Engine Out brake specific NO, Emissions (When both engines are on - 35% FUDS) 160 Hybrid Emissions Better 140 123 139 H 100 H 80 H7 120 120 1] 120 143 Hybrid Emissions Worse 62 39 40 20 10 n I F 39 41 28 25 4 8 I 7 0 0 0 1 Occurences difference of bs emissions [g/kWh] Figure 3.20: Difference in engine-out brake specific NO, emissions for hybrid and conventional vehicles on the FUDS driving cycle. When both engines are running, the hybrid produces, most often, less brake specific emissions than the conventional vehicle. Only 13% does the hybrid produce significantly more emissions, thus, the hybrid calls on its engine in less polluting areas of operation. bmep vs. Time Ford 3.OL & 1.25L 35% FUDS - - - 1000 - 900 800 m- 700 MM , 600 C 500 .0 400 - 300 00 0 +3.OL m 1.25q 100 300 200 400 500 Time [s] Figure 3.21: Bmep vs. time for hybrid and conventional vehicles on the FUDS driving cycle. Again, the hybrid vehicle's engine concentrates on the larger power production requirements leaving smaller, more inefficient for the electric motor. 56 Time Hybrid Engine is Off vs. Binned Timesteps - 100% FUDS - Cold Start 88 25 19 20n 2S15 0 00 8 7 E 6 6 5 z5 4 4 3 0 -A.~. 0) - A U1 0 U.1 0 C) 0) -C - -4 - - - - o Time Engine Off [s] U1.25L Figure 3.22: Binned length of timesteps in which the hybrid vehicle is using only electric power. Those engine-off periods below 2 seconds exist only in simulations and would not occur in reality. There are however, significant lengths of time the engine is not running. Emissions & Catalyst Info vs. Time -32 second Engine Off Period - 380 1 92.7% 0.9 -. 375 89.9% 0.8 -- 370 369.9 0.7 365 0.6 0. E 360 1- 0.5 0.4- 355 352.5 0.3 350 0.2 345 0.1 0 806.6 340 II 810.6 --- 814.6 818.6 Cold HC Emis Cold NOx Emis 822.6 826.6 830.6 834.6 - Time [s] Catalyst Efficiency - Catalyst Temperature - 838.6 842.6 846.6 850.6 Cold CO Emis Figure 3.23: Catalysts efficiency, temperature, and tail-pipe emissions for hybrid vehicle during 32 second engine shut off period on FUDS driving cycle. This "average" shut-off shows the unimportance of catalyst cooldown and its affect on conversion efficiency. 57 NOx Catalyst Efficiency Hybrid and Conventional Vehicles - 35% FUDS (Small Scale) 92% 91% '-PIJ C I 1riv i, 0 uLJ 90%- 89% 0 - Conventional 200 400 Hybrid 600 800 1000 1200 1400 ime Figure 3.24: Catalyst efficiencies for hybrid and conventional vehicles on FUDS driving cycle. The graph shows there is little difference between the hybrid and conventional vehicles conversion efficiency even though the hybrids engine is turned off from time to time. 58 CHAPTER 4 ADVISOR AND ADDITIONAL TRANSIENT MODELS 4.1 ADVISOR EMISSIONS MODEL LIMITATIONS ADVISOR has several limitations that prevent it from producing results without qualifications. It is important to bolster ADVISOR where these faults exist to sustain and strengthen those conclusions. The two largest inadequacies are the (lack of) transient modeling of engine behavior and the rudimentary chemical reaction modeling of the catalytic converter. 4.1.1 TRANSIENT OPERATIONS As stated in Chapter 3, transient engine behavior is an important factor in postcatalyst-light-off emissions creation. ADVISOR does not provide for such behavior. For any given level of engine output (and speed), the emissions level is constant and the mix of air to fuel is always stoichiometric. Therefore, the engine-out emissions are only a function of torque (bmep) and engine speed whereas they should be a function of torque (bmep), engine speed and the change in torque (bmep) with respect to time (Formula 4.1). Engine out emissions = f(bmep, N, d(bmep)/dt) (4.1) Including the change in bmep will account for high level transients that account for a considerable share of engine-out emissions, and are the cause of a majority of the tail pipe emissions after the catalysts has fully warmed up. 4.1.2 CHEMICAL REACTIONS The three-way catalyst model ADVISOR uses does not account for chemical reactions between the exhaust gas (and contained emission compounds) and the catalytic converter. This interaction is non-essential for the quasi-steady-state engine out 59 emissions modeling currently used. However, to properly show the effects of transients, the model must account for air-to-fuel ratios other than stoichiometric (X =1). Furthermore, the conversion efficiency calculated in ADVISOR is only a function of catalyst temperature. Modem day catalytic conversion efficiencies are functions of several variables, including temperature, space velocity, age, and oxygen storage capability. Hence, it will be important to incorporate such parameters into the new model. 4.2 CHANGES MADE TO ADVISOR Several code modifications were made to the ADVISOR program. The following section (with supporting figures) is supplied for those who wish to modify ADVISOR in the same fashion. These revisions were done in the simple block diagram models, which are the underlying backbone of the ADVISOR code. 4.2.1 AIR-FUEL RATIO To account for transient engine behavior, it was necessary to use a parameter, which as a function of the change in bmep with respect to time, could be used to alter engine-out emissions. Creating new 3-dimensional matrices indexed by all three parameters in Formula 4.1 would be a sizable, if not impossible task for a simple initial investigation. ADVISOR calculates emissions based on a specified stoichiometric relative airfuel ratio (herein referred to as lambda or X). Ideally, when X=1, the fuel is completely converted to the oxidized byproducts of combustion. When the engine is called upon for more or less power, a small excursion away from stoichiometry occurs and the engine bums fuel-lean (X>1) or fuel-rich (k<1). Figure 4.1 shows the change in bmep with respect to time and its relationships to X. A perfect (ideal) engine would always operate at stoichiometry where emissions are minimized. However, due to engine transients, it is impossible to do so. For example, if a vehicle reduces its velocity (i.e. slows down), there is less demand from the engine. There is, however, a short (<1 second) lag time when there exists a "puddle" of fuel in the intake port even though the quantity of air is reduced, thus making the mixture fuel- 60 rich (X<1), when there is no compensation. The same reasoning applies to a positive engine transient, when the mixture, with no compensation, becomes is fuel-lean (X>1). Modem control systems, however, compensate these fluctuations of X thus requiring large transients to produce changes from stoichiometry. Data in Figure 4.2 relates d(bmep)/dt to X. from an uncompensated fuel metering Five separate curve fits were This represents the worst-case scenario. system. implemented into the fuel converter model of ADVISOR (Figure 4.3). They include uncompensated, 1 compensated, I compensated, full compensation and perfect compensation (stoichiometric). The worst case scenario (Figure 4.2) is considered the uncompensated curve fit. The the uncompensated. and - compensated conditions are simple scaled fits of For example, the 2 compensated scenario implies at any given bmep, the difference from stoichiometry (AX) will be half that of the uncompensated scenario. Additionally, the full compensation fit implies that for small changes in bmep, the fuel metering system will react in time to prevent any excursions from stoichiometry. However, as the magnitude of transients increase, changes in X will occur. Each of these compensations will be compared with the stoichiometric to see the effect of transients on emissions. Determining X from a 1 second time step change in bmep led to anomalies in the results due to simulation-related jumps in the d(bmep)/dt. To make corrections for this phenomenon, a time-averaged relative air-fuel ratio was found using the past three timestep values for changes in X, as shown in Formula 4.2: A 1A 1 2 4 (4.2) 3 14 where the change in X is not the change in time-step, but the change from stoichiometry. 61 4.2.2 EMISSIONS CALIBRATION Engine-out emissions vary with respect to changes in X. Figure 4.4 shows the general trend of the three emissions tested and simulated: NOx, HC, and CO. The first step was to create curve fits from general data for each emissions type with respect to X. Nitric oxide and nitrogen dioxide combined vary as a parabola with respect to X. Data taken8 provides Figure 4.5. From the two curve-fits (Formulas 4.3 and 4.4), a lambda based emissions adjustment factor (EAF) is found and the true transient emissions are found using Formula 4.5. If X < 1: EAF = 73.517X3 - 174.15X2 + 137.54X - 36.021 (4.3) EAF = -36.827X 2 + 81.928X - 44.089 (4.4) If X 1: E-O EmissionsTransient = EAF * E-O Emissionsoriginai (4.5) Similarly, the curve-fits (Formulas 4.6 and 4.7) for carbon monoxide are found using the data in Figure 4.69. There is a simple linear regression when the mixture is fuel-rich which tails off near stoichiometry. EAF = -31X + 31.8 (4.6) 1: EAF = 6.551E8e20 592 (4.7) If X < 1: If X Hydrocarbons behave in a linear fashion with respect to X as shown in Figure 4.71". The EAF for HC is shown below in Formula 4.8. For all X: EAF = -2.5X + 3.5 (4.8) Figure 4.8 shows the ADVISOR Simulink block diagram added to adjust hot engine-out emissions for transient behavior using the curve fits from above to find the EAF and thus the new emission levels. 62 4.3 NTWC TRANSIENT MODELING PROGRAM Although ADVISOR was configured to compute transient engine-out emissions, no provisions could easily be added for transient behavior in the catalytic converter. It was then essential to find a simulation code, which properly analyzed the transient emissions with consideration for the transient behavior of a catalyst. NTWC11 ' 12 was selected for its robust calculation of catalytic transient behavior. 4.3.1 MODELING METHOD The model, similar to ADVISOR, uses a transient heat transfer simulation technique with a transient catalyst chemical kinetic mechanism, which includes provisions for oxygen storage chemistry. Specifically, the governing equations provide for convective heat and mass transfer from the exhaust gas to the catalytic converter with heat conduction through the converter itself and losses to the surrounding environment, the reactions occurring on the converter's surface and the capacity to store oxygen under fuel-lean conditions and release it under fuel-rich conditions. From the temperature and species time derivatives come the reaction scheme, which, using those reactions, produce rates of catalysis for the system, thus providing the level of emission reduction. The oxygen storage model (See Chapter 5) allows for proper representation of the modern three-way catalyst. Excess oxygen increases the conversion efficiency for CO, which produces other elements, which in turn, increase the conversion efficiency for NOx. 4.3.2 INTEGRATION WITH ADVISOR NTWC uses engine-out emissions levels, exhaust gas flow rate and temperature and relative air-fuel ratio as inputs. This data is obtained through ADVISOR for a specific vehicle configuration per time-step. It is then fed into NTWC, which independently calculates transient tail-pipe emissions. Because NTWC does not calculate the heat and temperature losses between the catalytic converter and the engine exhaust manifold, the input temperature is that of the exhaust gas in the pipes, which is calculated by ADVISOR. Figure 4.9 shows the interaction between the two simulation codes as they apply to the actual vehicle setup. 63 4.3.3 LIMITATIONS Several limitations exist with the current modeling setup (of ADVISOR NTWC). - First, with all "corrected" programs, there are some integration issues, the largest of which is the actual temperature of the exhaust gas as it enters the catalytic converter. ADVISOR does not calculate this value, but rather estimates it using basic heat transfer principles. Furthermore, there is no feedback between ADVISOR and NTWC. Because of programming issues, the complete integration was not possible and the temperatures and mass flow rates coming from ADVISOR are not bounded by NTWC. Additionally, ADVISOR's calculations of transient emissions is merely a regression fit as opposed to an actual calculation. Unfortunately, transient engine-out emissions are significantly hard to model in a general sense, and require a great deal of insight into a particular engine-vehicle configuration - something this study aimed to prevent. Bmep, engine speed, and d(bmep)/dt are all factors in engine-out emissions levels, but other variables such as ambient temperature, fuel injection control logic and air quality also have an impact on emissions production. Although these (and other) limitations provide some uncertainty and error, they do not impede the general characteristics of the results nor reduce significantly the validity of the conclusions based on the results. 64 X=1 * "us,, / / / / / dbmep dt / / /, /6...-- / Ideal (Perfect) Compensation (X=1) - ------... Best Real Compensation - . - - No Compensation - Figure 4.1: Ideal X vs. change in bmep with respect to time. Ideally, X would never stray from stoichiometric. However, realistically, with no control compensation, the airfuel mixture will go lean when there is a request for power due to the slight time lag and "under-injection" of fuel. Optimal compensation reduces the excursions from X=1 for most transients except those too severe to offset. Transient Behavior as a function of uncompensated A 200150 100 50 ++ V~ 0 6 0.7 0.8 0.9 e 1.1 1.2 1.3 14 E 10 *-100 y = 592.02x - 590.53 R2 = 0.8672 -150 X (uncompensated) Figure 4.2: Real (data) X vs. change in bmep with respect to time. This shows the relationship between an uncompensated X and transient engine behavior. When the vehicle slows down, there is a "puddle" of excess fuel leading to a rich mixture. 65 Compensations 300 200 - 100 02 E -100 -200 -300 0.6 - 0.8 Stoichiometric - Uncorrpensated - 1.4 1.2 1 1/4 - 1/2 - Best Figure 4.3: Various compensations (lambda models) made in ADVISOR. The uncompensated model assumes no feedback loop alters the air-fuel ratio. The 25% and 50% models are simple slope changes to the uncompensated model whereas the best compensation assumes a feedback loop which can control X between certain transients (changes in tourque) Emissions Behavior 0.7 0.8 0.9 1 1.1 1.2 1.3 x NOx emis H emrs - -CO ems Figure 4.4: General characteristics of engine-out emissions with respect to X (note y-axis not to relative scale). 66 Relative NO. Emissions vs. ) 1.6 x 1.4 z0 1.2 1 0 0a 0 y = 73.517x 3 0.8 .0 a. ' 0 - y = -36.827x 2 + 81.928x - 44.089 R 2 = 0.9804 - 0.6 : N 174.15x 2 + 137.54x - 3 6.021 R 2 = 0.9797 04 0 0.2 0.9 0.8 0.7 0.6 1.3 x Lower End -u-- Upper End -+-- 1.2 1.1 1 Figure 4.5: Relative NO, emissions versus X with regression analysis. When runnning rich, the engine-out emissions will be reduced. When slightly lean, more NOx will be produced. Relative CO Emissions vs. X 8 7 0 6 0 5 0 0 0. E w 0 y = -31x + 31.8 R 2 =1 4 3 0 0 I.- 1x y = 6.55 1E+08e -2.059EO 2 R = 9.921E-01 2 1 0 I- 0.7 -- +- Lower End -=- 0.8 Upper End 0.9 1 1.1 1.2 x Figure 4.6: Relative CO emissions versus X with regression analysis. When runnning rich, the engine-out emissions will be significanlty more.. When lean, less CO will be produced. 67 Relative HC Emissions vs. X 1.6 1.4 1.2 1 0 y = -2.5x + 3.5 0 1 R2 =1 0.8 0 w 0 a0. 0.6 0.4 0.2 0 I0.7 0.8 0.9 1.1 1 1.2 1.3 Figure 4.7: Relative HC emissions versus X with regression analysis. The linear data shows there will be more HC engine-out emissions when the air-fuel mixture is rich (too much fuel to burn) and less when it is lean. h., \ lam hcremiscorr HC Lambda Corr lam-co-emis-corr CO Lambda Corr m-emiscorr am-noxemiscorr Lambda emis adj lambda N% NOx Lambda Corr F Mux PM Corr Figure 4.8: Lambda based emissions adjustment factor (EAF) Simulink model. Using lambda found based on chosen compensation, the engine-out emissions correction factor is calculated. 68 NTWC input: utput: Seissions ncxhaust Transient emissions levels Texhaust T Texhaust -T- -- - - - - - - - - - - Engine (Fuel Catoy, Pipes Converter) Engine-Out Data: Additional Data: (from ADVISOR) emissions Texhaust Muffler/ Tail-pipe (from ADVISOR) '------------------ nfexhaust Texhaust -l - - - - - - - - Figure 4.9: ADVIOSR - NTWC visual connection. ADVISOR's results at the catalytic converter's entrance are fed into NTWC and analyzed. 69 70 CHAPTER 5 ADVISOR-NTWC HYBRID/CONVENTIONAL TRANSIENT MODELING 5.1 BACKGROUND Using the "combination" ADVISOR-NTWC simulation code, the effect of transients can be seen using perfect compensation (stoichiometric) as the baseline (see Figure 4.3). Four test cases were made against the baseline as degrees of compensation. They include a worst-case (no compensation), Acompensation, 2 compensation, and full compensation. These were made for both the conventional vehicle and hybrid vehicle using the full 1400 seconds of the Federal Urban Driving Schedule (FUDS). Additionally, these results are compared to those provided by the ADVISOR model. 5.2 COMPARISON As stated in Chapter 4, two main factors affect the conversion efficiency and thus tail-pipe emissions during transients. These are the engine-out emissions, which are affected by X, and the reductions in emissions achieved through oxygen storage. Table 5.1 shows the emissions levels for each test in grams per mile, the difference between methods and vehicles and changes from stoichiometry modeling results. 5.2.1 CO PRODUCTION CO is a by-product of combustion and is thus closely related to the amount of excess fuel supplied to the engine. When the air-fuel mixture is lean, engine-out CO emissions are significantly less than at or above stoichiometry. Hence, again only positive transients harmfully affect the magnitude of engine-out CO emissions. While an engine is running lean, a ceria coated catalyst stores oxygen as per Formula 5.113: 02+ 2Ce 2 O 3 -+ 4CeO 2 (5.1) 71 While running lean, CO is completely oxidized by the oxygen present in the air. When the engine runs rich, excess CO is left unoxidized, thus the ceria (Formula 5.2) is reduced and releases oxygen which is used to oxidize the remaining CO. (5.2) CO + 2CeO 2 -+ CO 2 + Ce 2O 3 Additionally, a CeO 2 catalyst is a good steam reforming catalyst, and thus catalyzes the reactions of CO and HC with H2 0 during rich conditions (Formula 5.3).14 CO + H 2 0 -+ H 2 + CO 2 5.2.2 (5.3) NOx PRODUCTION NO, is an additional by-product of combustion. It has a unique relationship to changes in air-fuel mixtures. The stoichiometry point is just rich of the peak in the EAF (see Figure 4.5). Thus, under more rich conditions, fewer engine-out emissions will be produced, while slightly lean conditions will lead to an increase in NOx. Significantly lean conditions will also lead to a reduction in such emissions. When the engine runs lean and oxygen is being replenished, there is an increased availability of reactant sites, which allows for further reduction of excess NOx. Also, the H 2 produced (Formula 5.3) allows for additional reduction of NOx by producing N2 and H 20 from H 2 (Formula 5.4). NO, + xH 2 -- N 2 + xH 2O 5.2.3 (5.4) HC PRODUCTION HC production occurs when the fuel in the combustion chamber is not fully burnt. As air-fuel conditions go rich, HC emissions increase. Inversely, if less than stoichiometric fuel is available, it will all burn, leaving little or no remnants. Therefore, with increased positive transients come excursions into lean air-fuel mixtures and thus less HC emissions. 72 Excess oxygen does not affect the tail-pipe emissions. However, unburned hydrocarbons may react with water further reducing them the H2 gas (Formula 5.5). CxHy + 2H 20 -+ (2+y/2)H 2 + xCO 2 (5.5) 5.3 HYBRID CONFIGURATION RESULTS The hybrid vehicle's engine rarely slows down (negative d(bmep)/dt). Instead of reducing its speed (and thus output) during a decrease in vehicle speed, it shuts down. Therefore, there are more increases in bmep than decreases, thus it is most often lean (Figure 5.1). Consequently, according to Figures 4.5 - 4.7, the engine-out emissions will be greater for NOx and less for CO and HC for any of the compensation routines. Additionally, the oxygen storage capability increases the conversion efficiency for the unburned HC and CO produced (Table 5.1). As compensation level decreases, lean excursions by X become greater in magnitude. Thus, the amount of engine-out HC emissions diminishes. Oxygen storage, however, has little effect on such emissions as it is seen in Table 5.1. At stoichiometry, the hybrid vehicle produces .0796 grams per mile, whereas it produces 12% less during the no-compensation transient run. As the compensation increases, the vehicle performs closer to stoichiometry and has worse HC emissions (because there are fewer lean excursions). This would imply the hybrid vehicle, in terms of HC emissions, performs better during transient behavior because it rarely "overfuels" the engine which causes high HC emissions. Additionally, NTWC results compare closely to ADVISOR's outcomes implying little or no effect of oxygen storage on HC emissions. The hybrid's CO production also gets worse with better compensation, which is attributed to the same phenomenon as HC emissions. As X goes more lean (less compensation), there is a significant reduction in engine-out emissions. Additionally, the oxygen storage capacity decreases CO emissions as the compensation gets better. Because these two trends are opposite, it is necessary to determine which has the bigger effect. Although the difference between no compensation and best compensation is 7% or .12 grams per mile, the worst compensation is still 5% less than stoichiometry, 73 implying the reduction in engine out emissions wins over the oxygen storage capacity of the catalyst. NO, emissions become better as compensation improves. Because of lean conditions, engine-out emissions levels grow with decreasing compensation. compensation, there is -30% more emissions than at stoichiometry. At no As compensation improves, NTWC predicts better improvements in emission levels over ADVISOR due to the further reduction of NO, via the steam reformation and increased reaction sites. For example, NTWC predicts the no compensation levels to be 24% higher than stoichiometric as opposed to ADVISOR's 29% increase. 5.4 CONVENTIONAL CONFIGURATION RESULTS The conventional vehicle's performance over the driving cycle indicates an equal number of excursions from X, both rich and lean (Figure 5.2). Thus, the results from NTWC come closer to those of ADVISOR. Hydrocarbon emissions are worse stoichiometry, which should be expected. for all compensations compared to Best compensation emission levels are 6% higher than stoichiometric levels whereas no compensation is 13% higher. Again, since oxygen storage plays a relatively small role in HC emissions reduction, there is little difference between ADVISOR and NTWC. CO and NOx production for the conventional vehicle also improves with compensation. Oxygen storage capabilities of the catalyst are key in decreased tail-pipe emissions. The excursions away from X come close to canceling the effects of changes in engine-out emissions making the NTWC marginally (-5-10%) better across the board. 5.5 HYBRID AND CONVENTIONAL COMPARISON 5.5.1 OVERALL The hybrid vehicle produces fewer emissions. HC emissions levels are roughly 40% of conventional vehicles. CO emissions are between 20 and 30% better. There is a 5x reduction in NOx emissions. Although these are absolute levels (g/mile) and not normalized for engine size (brake specific emissions), the hybrid still offers a significant reduction in total vehicle emissions. 74 5.5.2 LIMITATIONS - STARTUP AND SHTDOWN The modeling methodology used does not necessarily account for the increase in HC emissions created during the significant number of engine starts the hybrid performs. The hybrid incurs 55 (Figure 3.22) hot engine restarts over the entire FUDS driving cycle. If the initial fuel injected into the combustion chamber is larger than necessary (by 10 mg), a total of 0.55 grams extra would be produced. Normalized by distance, an extra 0.73 grams/mile in engine-out emissions would occur. Although some may be catalyzed, more tailpipe emissions would occur. 5.6 CONCLUSIONS 5.6.1 TRANSIENT EFFECT Transient emissions do increase the levels for most of the scenarios (compensations) with the exception of HC and CO hybrid emissions. In these two cases, the reduced emissions levels are explainable. HC emissions are reduced in the hybrid because less fuel is being burned and thus, less fuel is left in crevices and the combustion chamber (which plays a role in the magnitude of HC emissions). Additionally, there is an excess amount of air (oxygen) which implies the HC's are fully burned and there is excess oxygen to further oxidize any additional CO emissions. Figure 5.315 shows the general characteristics of a TWC with respect to X (without oxygen storage). These curves agree with the findings in Table 5.1. The conventional configuration incurs minor increase in emissions levels when a best-fit compensation is applied. HC emissions are 6% higher than ideal compensation while NO, is a mere 4% greater. Additionally, the hybrid's NOx best-compensation levels are also only slightly greater than stoichiometry. This implies the transients incurred do provide additional emissions production, but not at an extreme level when compared to the simple stoichiometric case runs. 5.6.2 HYBRID/CONVENTIONAL COMPARISON The Hybrid configuration's emissions levels are within an ULEV rating for CO and NO, emissions and between ULEV and LEV for HC emissions. They range between 20 and 65% of their conventional counterparts. The hybrid has significant improvements 75 in NOx and HC emissions with smaller savings in CO levels. This provides the needed data to prove the less severe transient behavior of the hybrid provides the much-needed emissions savings to qualify as a LEV. 5.6.3 ADVISOR VERSUS NTWC ADVISOR and NTWC emissions predictions vary slightly. difference is the estimation of CO emissions levels. The only sizble Although ADVISOR lacks the oxygen storage model of NTWC, both use a similar approach to quantifying temperatures and heat transfers to and from the exhaust system. HC and NOx emission levels are forecasted within 15% of each other. Thus, using NTWC's oxygen storage model just adds more exoneration to an already robust emissions calculation code. 76 Table 5.1: Emissions results for various compensations and changes from stoichiometry. The difference in results between ADVISOR and NTWC is minimal, thus bolstering ADVISOR's methodology. Additionally, NTWC predicts decreasing emissions as compensation improves. Furthermore, the hybrid configuration has significantly fewer emissions than its conventional counterpart. HC emissions are less because the hybrid does not over-fuel when it slows down, rather it shuts the engine off. CO emissions experience the same phenomenon while NOx emissions methodically decrease. Compensation Stoichiometry None 25% 50% Best A% From Stoich None 25% 50% Best ADVISOR HC CO NOx [g/mile] 0.0728 1.080 0.032 0.0653 0.746 0.041 0.0690 0.794 0.040 0.0705 0.823 0.039 0.0720 0.893 0.037 Hybrid NTWC % Difference HC CO NOx HC CO NOx [g/mile] [%] 0.0796 1.689 0.031 9% 56% -5% 0.0701 1.599 0.038 7% 81% -1% 0.0728 1.672 0.036 6% 86% -8% 0.0747 1.714 0.034 6% 83% -12% 0.0751 1.721 0.032 4% 77% -12% -10% -5% -3% -31% -26% -24% 29% 26% 20% -12% -9% -6% -5% -1% 2% 24% 19% 11% -1% -17% 14% -6% 2% 5% ADVISOR HC CO NOx [g/mile] 0.1580 1.567 0.187 0.1812 2.034 0.239 0.1801 1.967 0.226 0.1793 1.917 0.211 0.1737 1.873 0.206 1 Conventional NTWC HC CO [g/mile] 0.1706 2.160 0.1934 2.609 0.1902 2.549 0.1855 2.451 0.1811 2.325 15% 14% 14% 30% 25% 22% 28% 21% 13% 13% 11% 9% 21% 18% 13% 10% 19% 10% 6% 8% % Difference NOx HC CO NOx [g/mile] 0.176 0.204 0.195 0.189 0.183 16% 11% 7% 4%1 8% 7% 6% 3% 4% 38% 28% 30% 28% 24% -6% -15% -14% -10% -11% I X vs. Time X vs. Time No Compensation 1/4 Compensation 1.2 1.2 1.1 ee 0.9 1 0.9 0.8- 0.8 0 200 400 600 800 1000 1200 1400 0 200 400 Time [s] 1.2- 600 Time 800 X vs. Time X vs. Time 1/2 Compensation Best Compensation 1.2 1.1 1000 1200 1400 1000 1200 1400 [s] 1.1 S1 0.9- 0.9 0.8- 0.8 0 200 400 600 800 Time [s] 1000 1200 1400 0 200 400 600 800 Time [s] Figure 5.1: Various X compensations for hybrid configuration for FUDS driving cycle. As compensation improves there are less excursions from X. Additionally, note excursions are centered near stoichiometry, but there are more significant lean excursions. 1.2 X vs. Time X vs. Time No Compensation 1/4 Compensation 1.2 1.1 er- 1.1 1 U S1 I ilir 1w rr Ill. 71 i di ,11IL Fi6L 111177 0.9 r 1111 7 0.9 0.8 0.8 0 200 400 600 800 1000 1200 1400 0 200 400 Time [s] 1.2 600 800 1000 1200 1400 1000 1200 1400 Time [s] ) vs. Time X vs. Time 1/2 Compensation Best Compensation 1.2- lia LALL i, ir * 1-1717Trif HO 0.9 0.9- 0.8 0.8 0 200 400 600 800 Time [s] 1000 1200 1400 0 200 400 600 800 Time [s] Figure 5.2: Various X compensations for hybrid configuration for FUDS driving cycle. As compensation improves there are less excursions from X. Additionally, excursions are centered about stoichiometry. Conversion Efficiency vs. X Typical TWC w/o 0 2 Storage 100 0 80 0 C 60 C: 0 40 0 20 0 ooo 0 0.98 0.97 - NOx - HC - 0.99 CO 1 1.01 1.02 1.03 Figure 5.3: Typical Conversion Efficiency for Three-Way Catalyst without oxygen storage capabilities. NTWC, showing the same general trends, predicts CO to be worse for the Conventional vehicle (which hovers about stoichiometry) and better for the hybrid (which stays to the lean side). HC and NOx also compare with NTWC results. 80 CHAPTER 6 CONCLUSIONS 6.1 CONCLUSIONS ADVISOR and NTWC, working separately and together, provide reasonable explanations to the phenomena tested. ADVISOR, which is under constant improvement by NREL, still needs additional work to provide unquestionable emission results, but performs well in general trend evaluation and initial back-of-the-envelope calculations. Although not a commercial code, NTWC does an excellent job predicting the effects of oxygen storage and three-way catalyst performance under various operating conditions. As shown in its supporting published documents, it forecasts transient emissions within a slim margin of error. Unfortunately, actual hybrid emissions data was not available at the time of this study to prove the validity of the ADVISOR/NTWC findings, but the author feels this should not have an impact on the trends found. 6.1.1 STEADY-STATE EMISSION LEVELS As stated in Chapter 3, the hybrid all-around outperforms its conventional counterpart in steady-state emissions analysis. The four main reasons: * The hybrid uses its engine for less time, thus producing less total emissions. " When the hybrid engine is producing emissions, it produces less because of its reduced engine size. * The hybrid's engine operates in more efficient areas of the engine map, both in terms of emissions and fuel economy. * Fewer and less severe transients are absorbed by the hybrid's engine. Because the hybrid has an electric motor, it uses the engine 4 times less often than its conventional counterpart. Thus, the hybrid produces emissions for only 15 seconds versus a conventional engine's minute. This alone provides for the much-needed reduction of emissions. It is not, however, the only reason for emissions reduction. 81 Additionally, most hybrid vehicles have comparatively small engines. For example, the standard family sedan's engine in 2000 was about 2.8L 6 . Most hybrid engines are ~to 3 the size. (The Toyota Prius, weighing in around 2800 pounds, has an undersized 1.5L engine). Hence, when the hybrid produces emissions, they are considerably less, for only half the conventional vehicle's amount of fuel is being burned. However, when hybrid emissions are investigated on a brake specific basis, they are found to be marginally less than their conventional counterparts. Again, a smaller powerplant accounts for emissions reductions, but is not the crucial piece. The crux to the hybrid vehicle's emissions savings is engine performance. The hybrid's engine only operates when the motor cannot provide the power necessary to achieve the requested speed. This occurs at higher vehicle speeds, where the engine is more efficient. Because it does not operate at low speeds and torque, it does not produce the high magnitude emissions that are created by conventional vehicles. For example, the conventional vehicle creates significant emissions when idling and starting from a stopped position. These two scenarios, which are not incurred by the hybrid, attribute a sizable chunk to vehicle emissions. Without them, there is a significant reduction in tailpipe emissions. A side-study was performed to investigate the possibility of catalyst cool-down as a complication of hybrid engine shut-off periods. The conversion efficiencies are significantly related to catalyst temperature, which is related to gas flow through the exhaust system. If the engine is off, then the catalyst temperature might fall and reduce its efficiency. This, however, does not play a key role, since even the longest shut-down periods (- 1 minute) result in minor (5*C) temperature changes in the catalytic converter. Finally, the two main causes for increase in engine-out emissions (other than normal driving) are the pre-light-off period where the catalyst has not fully warmed up and severe transients caused sizable changes in required torque (both positive and negative). Such transients are controlled by the hybrid, as it can allocate power from both its motor and internal combustion engines. Thus, the hybrid incurs less of these behavioral issues because the motor often damps such changes in requested torque. 82 6.1.2 TRANSIENT EMISSION LEVELS ADVISOR is a quasi-steady-state empirical emissions model. It does not take into account changes in air-fuel ratio nor is its catalyst model "chemically robust". It lacks any sort of oxygen storage capacity of the catalyst. These issues required an indepth look at other programs that predict transient emissions and have oxygen storage models. NTWC did an excellent job using data from ASDVISOR as input to further calculate and corroborate hybrid and conventional emission levels. Transient analysis of the hybrid vehicle showed improvements in HC and CO emissions. Because the hybrid rarely decelerates (it turns the engine off), its transient are often lean. Lean excursions provide a reduction in HC emissions because there exists more air than needed to completely bum the fuel. Additionally, under lean conditions, there is an excess of oxygen needed to oxidize CO further reducing the emissions. NO, emissions do increase, but only by 5% under a good air-fuel compensation regime. The conventional vehicle incurred an equal distribution of lean and rich excursions, and thus, increased emissions levels across the board. Although emissions improved with improved compensation, they still exceeded the stoichiometric levels. The analysis, however, did not include a specific investigation of the extensive startup and shutdown of the engine. Such an investigation may show the true extent of HC emissions. However, back of the envelope calculations show these emission levels may vary at most, 30-40%. Thus, to find general trends, it was not necessary to perform such an inquiry. 6.1.3 OVERALL Overall, there were not significant changes between a reasonable "worst-case" compensation level (50% compensation) and stoichiometry. At most, emissions were 15% higher using this transient analysis. This implies there is minimal benefit in considering transient behavior when performing basic initial feasibility calculations. Additionally, when performing back-of-the envelope calculations, it is important to properly size all vehicle components in ADVISOR, but it does not require actual data. Although it is beneficial to have raw engine and motor numbers, resizing current modules by power does not appreciably change results. 83 6.2 FUTURE TECHNOLOGIES Hybrid vehicles have a bright future. Current versions are providing the basis by which automotive makers will build upon. Although hybrids measure up to emissions and fuel savings standards, they still require a great deal of work. The "ideal" hybrid that can transport 6 people and their luggage is far off, but not unforeseeable. Additional technologies, such as light-off catalysts, HC absorption chambers, better controls will further the hybrid field. Improvements in catalyst technology are being made daily and allow for better conventional vehicle emissions, which will be used up until that day when the ideal hybrid is introduced. 84 85 86 REFERENCES 1. "Design of Hybrid Electric Vehicles", David A. Erb, SAE Seminar #94031, 1997. 2. http://www.epa.gov/ 3. "Toyota Prius Information Packet", Toyota Motor Corporation, 2001. 4. "Advisor Documentation", National Renewable Energy Laboratories Center for Transportation Technologies and Systems, 2000. 5. Shayler, P. J., Darnton, N. J., Ma, T.: "Factors Influencing Drive Cycle Emissions and Fuel Consumption", SAE Paper 971603, 1997. 6. "PNGV Program Plan", Partnership for a New Generation of Vehicles, 1995. 7. Heywood, J. B. 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