MATERIAL
SAFETY
DATA
SHEET
P a ge 1 of 5
I. PRODUCT INFORMATION
MANUFACTURER'S NAME:
ADDRESS:
TRADE NAME:
REGULAR TELEPHONE NO.
EMERGENCY TELEPHONE NO.
Elk Corporation of Texas
(9 7 2 ) 8 7 5 -9 6 1 1
(9 7 2 ) 8 7 5 -9 6 1 1
202 Cedar Road, Ennis, Texas 75119
VERSASHIELD®
Prestique Grande Interply,
VERSASHIELD®
Domain W inslow Interply
SYNONYMS:
Shingle Interply
SHIPPING NAME:
DOT: Mineral-Coated Chopped Strand Glass Mat (not restricted)
II. HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT
CAS NO.
%
HAZARD DATA
Limestone
1 3 1 7 -6 5 -3
5 0 -6 0
Slag, Coal
6 8 4 7 6 -9 6 -0
1 0 -1 5
Glass, Fibrous (diameter > 13 micron)
6 5 9 9 7 -1 7 -3
5 -1 0
ACGIH(TLV-TW A)=10 mg/m3
OSHA(PEL-TW A)=15 mg/m3 Total Dust
= 5 mg/m3 Respirable Fraction
Calcium Hydroxide
1 3 0 5 -6 2 -0
0.1-0.2
ACGIH(TLV-TW A)= 5 mg/m3
OSHA(PEL-TW A)=15 mg/m3 Total Dust
= 5 mg/m3 Respirable Fraction
ACGIH(TLV-TW A)=10 mg/m3
*
OSHA(PEL-TW A)=15 mg/m3 Total Dust
= 5 mg/m3 Respirable Fraction
ACGIH(TLV-TW A)=10 mg/m3
= 5 mg/m3 Respirable Fraction
OSHA(PEL-TW A)=15 mg/m3 Total Dust
= 5 mg/m3 Respirable Fraction
* This value is for total dus t containing no as bes tos .
Fibrous Glas s Inhalation
Acute: Mechanical irritation of the m outh, nos e and throat.
Chronic: Many s tudies have been conducted to determ ine the potential long term effects of fibrous glas s inhalation. Although inconclus ive, s om e res earch s upported by the indus try indicates that m anufacturing plant em ployees , who were firs t em ployed m ore than 30
years ago in factories that m anufactured glas s wool and m ineral wool, have an increas ed rate of lung cancer as com pared to certain
other reference populations . Further third party s tudy is planned to identify thos e factors as s ociated with the reported increas ed rate.
Sim ilar findings were not reported regarding em ployees in textile fiber m anufacturing plants . Anim al s tudies have not dem ons trated an
increas ed rate of lung cancer when the anim als breathed large quantities of glas s fibers . Artifical im plantation or injection of fine glas s
fibers into the ches t, abdom inal cavity or trachea of laboratory anim als has produced cancer.
III. PHYSICAL DATA
BOILING POINT, 760 MM HG
NA
MELTING POINT
NA
SPECIFIC GRAVITY (H2O=1)
NA
VAPOR PRESSURE
NA
VAPOR DENSITY (AIR=1)
NA
SOLUBILITY IN H2O % BY W T
% VOLATILES BY VOL.
NA
EVAPORATION RATE (BUTYL ACETATE-1)
NA
pH (AS IS)
pH (1% SOLN.)
NA
APPEARANCE AND ODOR
BlackColor,
Mineral-filled
Mat w ith laminated plastic filmOdorless
Insoluble
MATERIAL
SAFETY
DATA
SHEET
P a ge 2 of 5
IV. FIRE AND EXPLOSION DATA
FLASH POINT
(TEST METHOD)
NA
AUTOIGNITION TEMPERATURE
FLAMMABLE LIMITS IN AIR, % BY VOL.
NA
LOW ER
NA
Non-Flammable
UPPER
NA
EXTINGUISHING MEDIA
W ATER, FOAM, DRY CHEMICAL, SAND AND CO2
SPECIAL FIRE FIGHTING PROCEDURES
NONE-Treat w ith generally accepted practices for combusible product.
UNUSUAL FIRE AND EXPLOSION HAZARD
NA
V. HEALTH HAZARD INFORMATION
HEALTH HAZARD DATA
ROUTES OF EXPOSURE
HAZARD CLASSIFICATION
NUISANCE DUST
INHALATION
SKIN CONTACT
SKIN ABSORPTION
EYE CONTACT
INGESTION
NUISANCE DUST
BASIS FOR CLASSIFICATION
SOURCE
"Industrial Exposures and
Control Technologies for OSHA
Regulated Hazardous
Substances"
"
"
1 -1 9 -8 9
Federal Register
"
"
NA
NUISANCE DUST
NA
"Industrial Exposures and
Control Technologies for OSHA
Regulated Hazardous
Substances"
1 -1 9 -8 9
Federal Register
"
"
EFFECTS OF OVEREXPOSURE:
Use of this product is not anticipated to result in employee overexposure during normal conditions
of use that are in accordance w ith the manufacturer's specified applications. How ever, use of this
product in other applications not specified by the manufacturer could potentially result in eye, skin
and/or respiratory irritation.
_____________________________________________________________________________________________________________
ACUTE OVEREXPOSURE:
Excessive grinding or abrasion of this product may create airborne dust and fiber concentrations in
excess of state and Federal OSHA permissible exposure limits. Exposure to concentrations in
excess of these PELs may cause severe respiratory irritation, skin irritation and/or eye irritation.
_____________________________________________________________________________________________________________
CHRONIC OVEREXPOSURE:
Repeated and/or prolonged exposure to dust and fibers at concentrations in excess of state and
Federal OSHA permissible exposure limits may result in respiratory damage, chronic skin irritation
and/or eye injury.
MATERIAL
SAFETY
DATA
SHEET
P a ge 3 of 5
EMERGENCY AND FIRST AID PROCEDURES
EYES:
Flush w ith clean w ater for at least 15 minutes. Seek medical attention if irritation persists.
_____________________________________________________________________________________________________________
SKIN:
Flush w ith clean w ater for at least 15 minutes. Seek medical attention if irritation persists.
INHALATION:
Remove afffected persons from source of exposure. Seek medical attention if irritation persists or
if affected persons develop breathing difficulties.
_____________________________________________________________________________________________________________
INGESTION:
This product is not intended for consumption or direct contact w ith any type of food or beverage. Seek medical attention if this product is ingested.
_____________________________________________________________________________________________________________
NOTES TO PHYSICIAN:
_____________________________________________________________________________________________________________
_____________________________________________________________________________________________________________
VI. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY:
NA
_____________________________________________________________________________________________________________
INCOMPATIBILITY:
Strong acids w ill react w ith the limestone component releasing CO2 gas.
_____________________________________________________________________________________________________________
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide, Carbon Dioxide and Hydrocarbons w ill result from incomplete
combustion of the organic binder if involved in a fire.
_____________________________________________________________________________________________________________
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: W ill not occur
_____________________________________________________________________________________________________________
VII. DISPOSAL, SPILL OR LEAK PROCEDURES
AQUATIC TOXICITY:
NA
_____________________________________________________________________________________________________________
W ASTE DISPOSAL METHOD:
Dispose of w aste in accordance w ith local, state, and Federal law s and regulations pertaining to
material of this type of composition.
_____________________________________________________________________________________________________________
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Collect spilled material in appropriate containers for reuse or disposal.
Avoid dry sw eeping and other spill removal procedures that may create airborne dust and fibers.
NEUTRALIZING CHEMICALS
NA
MATERIAL
SAFETY
DATA
SHEET
P a ge 4 of 5
VIII. SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS: Use of this product is not anticipated to require more than general room ventilation during normal
conditions of use that are in accordance w ith the manufacturer's specified applications. How ever,
use of this product in other applications not specified by the manufacturer could potentially
generate airborne dust and fibers that may require additional mechanical exhaust to prevent
employee overexposures. Excessive grinding or abrasion of this product may create airborne dust
and fiber concentrations in excess of state and Federal OSHA permissible exposure limits. If
employee exposures exceed these PELs, local exhaust ventilation or other mechanical ventilation
systems may be required to reduce such exposures to concentrations below the PELs. If
mechanical exhaust ventilation is necessary, exhaust air should be appropriately filtered or
otherw ise controlled to meet local, state and Federal air pollution and air quality law s and
standards.
_____________________________________________________________________________________________________________
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT:
W here respiratory protection is used, such use must comply w ith state and
Federal OSHA standards. Only respirators approved by the National Institute
for Occupational and Health (NIOSH) should be used.
EYES:
W ear safety glasses w ith sideshields or safety goggles. Selection and use of all eye protection
should meet applicable standards set by the American National Standards Institute (ANSI)
and state and Federal OSHA standards.
_____________________________________________________________________________________________________________
SKIN:
W ear sturdy w ork gloves and intact clothing w ith long sleeves and long pants.
____________________________________________________________________________________________________________
FEET:
W ear socks and appropriate, closed-toe shoes or boots. Selection and use of all foot protection
should meet applicable standards set by the American National Standards Institute (ANSI) and state
and Federal OSHA standards.
_____________________________________________________________________________________________________________
HEAD:
W ear a hard hat, bump cap or other head covering appropriate for the specific w ork areas and
activities to be performed. Selection and use of all head protection should meet applicable
standards set by the American National Standards Institute (ANSI) and state and Federal OSHA
standards
___________________________________________________________________________________________________________
RESPIRATORY:
If employee exposures exceed state or or Federal OSHA permissible exposure limits, respiratory
protection should be w orn until and unless such exposures are reduced to concentrations below
these PELs. Only NIOSH-approved respirators should be w orn. Selection and use of specific
respirators should meet applicable standards set by state and Federal OSHA standards for
repiratory protection and for the specific substances and concentrations to w hich employees are
exposed.
_____________________________________________________________________________________________________________
W ORK PRACTICES:
Employees should avoid eating, drinking, chew ing, smoking, taking medication and applying
cosmetics in w ork areas w here this product is being installed or removed. Employees should w ash
their hands and other exposed areas of skin after handling this product and before smoking or
consuming anything. Employees should show er at the end of each w ork shift after installing or
removing this product. W ork clothing should be w ashed separately and the w ashing machine
should be w iped out at the end of the w ashing cycle.
IX. SPECIAL PRECAUTIONS
STATE:
This product contains chemicals know n to the State of California to cause cancer and/or repro- ductive
toxicity, as defined by Title 22 California Code of Regulations Section 12000. For additional
information on this content, contact the product manufacturer.
_____________________________________________________________________________________________________________
MATERIAL
SAFETY
DATA
SHEET
P a ge 5 of 5
ADDITIONAL REGULATORY CONCERNS:
FEDERAL-
NA
FDA-
NA
USDA-
NA
TSCA
CARCINOGENICITY IARC -
NA
NO
OSHA - NO
IS THIS PRODUCT, OR ALL ITS INGREDIENTS, BEING CERTIFIED FOR INCLUSION ON THE TOXIC SUBSTANCES
CONTROL ACT INVENTORY OF CHEMICAL SUBSTANCES?
Yes_____
_____________________________________________________________________________________________________________
OTHER HANDLING AND STORAGE REQUIREMENTS:
NONE
_____________________________________________________________________________________________________________
OTHER:
W hile Elk Corporation of Texas, Inc. believes the data set forth herein is accurate as of the date hereof, Elk makes
no w arranty, express or implied, regarding its correctness w ith respect thereto and expressly disclaims all liability
for reliance thereon. The conditions and methods of handling, storage, use and disposal of the product are beyond
our control. For this and other reasons, w e do not assume responsibility and expressly disclaim liability for loss,
damage, or expense arising out of or in any w ay connected w ith the handling, storage, use or disposal of the
product.
_____________________________________________________________________________________________________________
DATE:
September 19, 2002