Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:26 PM Page 120 WELDING RESEARCH Cold Metal Transfer (CMT) GMAW of Zinc­Coated Steel Welding conditions for quality welding were obtained based on understanding the porosity formation mechanism and mechanical strength evaluation BY M D. R. U. AHSAN, Y. R. KIM, R. ASHIRI, Y. J. CHO, C. JEONG, AND Y. D. PARK ABSTRACT This paper investigates the feasibility of cold metal transfer (CMT) gas metal arc (GMA) welding of zinc­coated steel in a lap­joint configuration with no root opening over a wide range of heat inputs from 150 to 550 J/mm in terms of porosity formation and mechanical performance. The quantitative analysis of porosity by x­ray radiographic test­ ing shows the heat input conditions below 250 J/mm and above 350 J/mm cause the least amount of porosity. The temperature­dependent properties of the weld pool vis­ cosity and vapor pressure of zinc determine the porosity formation, growth, and escape mechanisms at different heat inputs. These factors were characterized by using high­ speed imaging analysis and infrared (IR) thermography of the weld pool. Secondly, to en­ sure joint integrity, samples welded at different heat input conditions were mechanically tested to identify the minimum required penetration depth leading to base metal failure. It was found that a minimum heat input of 200 J/mm is required for ensuring that mini­ mum penetration. Finally, the heat input criteria achieved from the porosity analysis and mechanical testing were combined and two sets of optimized welding conditions — one set is in the low heat inputs, ranging from 200 to 250 J/mm, and another set is in the high heat inputs, ranging from 350 to 550 J/mm — were derived. The guideline proposed by this work can be used for selecting suitable welding conditions based on the require­ ments, which can ensure low porosity in the weldments and adequate mechanical strength of the joints. KEYWORDS • Zinc­Coated Steels • Cold Metal Transfer (CMT) • Gas Metal Arc Welding (GMAW) • Porosity • Mechanical Properties Introduction In order to improve fuel efficiency and reduce CO2 emissions by reducing vehicle weight, without compromising safety, leading automakers are extensively using thinner sheets of highstrength steels (Ref. 1). These steels are often coated with zinc-based coatings as they protect the steel compo- nents from aqueous corrosion by offering barrier protection and galvanic protection (Ref. 2). Gas metal arc welding (GMAW) is a commonly used method for joining plastically deformed and closed structural components for the automotive industry (Refs. 3, 4). In order to achieve high productivity and avoid melt-through in thin sheet materials, welding conditions with fast welding speeds ensuring low heat input are required. Cold metal transfer (CMT) is a recently developed automated GMAW process associating short circuit transfer as the droplet transfer method (Ref. 5). The CMT process engages with the mechanically controlled retraction of the wire to assist the droplet transfer during short circuiting without aid from the electromagnetic force, which allows reducing the current without affecting the material transfer and thus creates a lower heat input for the same amount of deposition compared to other GMAW processes (Ref. 6). The controlled method of material deposition and higher melting coefficient compared to conventional welding processes make CMT a suitable choice for joining steel sheet materials with a higher productivity (Ref. 7). However, the melting temperature of steels is about 1500°C, which is significantly higher than the boiling temperature of zinc (906°C) (Ref. 8). This situation causes formation of highpressure zinc vapor at the interface of zinc-coated sheets during welding (Ref. 9). If this high-pressure zinc vapor is not vented out properly, it will be trapped in the weld pool and form weld discontinuities in the form of porosities (Refs. 10–13), which is severe, especially in the lap-joint weld geometry with no root opening (Ref. MD. R. U. AHSAN and Y. D. PARK (corresponding author, ypark@deu.ac.kr) are, respectively, student and professor of the Dept. of Advanced Materials Engi­ neering, Dong­Eui University, Busan, Korea. Y. R. KIM is with the Hyundai Motor Co., Gyeonggi­do, Korea. R. ASHIRI is a visiting researcher with the Department of Advanced Materials Engineering, Dong­Eui University, Busan, Korea, invited from the Dept. of Materials Engineering, Isfahan University of Technology, Is­ fahan, Iran. Y. J. CHO is with the Ship Infrared Signature Research Center, Dept. of Naval Architecture and Ocean Engineering, Dong­Eui University, Busan, Korea. C. JEONG is with the Dept. of Mechanical Engineering, Stevens Institute of Technology, Castle Point on Hudson, Hoboken, N.J. 120-s WELDING JOURNAL / APRIL 2016, VOL. 95 Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 121 WELDING RESEARCH Fig. 1 — A — Stress vs. time curves at different heat input condi­ tions; B — image from x­ray RT test of the respective weldments with the exact location of tensile test sample on weld bead marked. 1). The presence of porosities in the weld bead severely affects the joint integrity in terms of both strength and fatigue performance (Ref. 14). Existing works show entrapment of zinc vapor in the weld pool can be avoided if the solidification is delayed enough to allow time for the zinc vapor to escape from the weld pool (Ref. 15). This requires high heat input. However, high heat input in fusion welding processes gives rise to the chance of meltthrough, hence it is undesirable (Refs. 12, 13, 16). Existing works focusing on mitigating porosity discontinuities in the weld bead include removal of the zinc coating as the simplest approach as suggested by AWS (Ref. 17). Other researchers also looked for an alternate to zinc as a coating material, such as nickel, which has a higher boiling point and hence does not evaporate during welding (Refs. 18, 19). The porosity issue has also been dealt with by using metal cored wires (Refs. 13, 16), flux cored wires (Ref. 20), or changing the composition of solid wires (Refs. 21, 22). Significant efforts are also made by modifying the process parameters in order to attain a better control over the process and increase the heat input to reduce porosities in the weld bead (Refs. 20, 21). In the works of Matsui et al. (Refs. 23, 24), the effect of the root opening between specimens, welding position, tilt angle of the torch, contact tip-toworkpiece distance (CTWD), and base plate angle on porosity formation were extensively studied. The effects of Table 1 — Welding Conditions Experienced for Understanding the Porosity Formation Behavior in CMT­GMAW 19.7 18.5 18.4 18.3 18.2 17.6 16.9 16.2 15.5 14.9 14.6 13.9 13.1 12.7 12.4 40 50 60 Constant Speed 263 252 241 231 220 211 200 190 180 170 161 150 141 130 120 Voltage (V) Welding Speed (cm/min) 70 80 90 100 110 120 Melt-Through Current (A) Constant Current and Voltage Incomplete Fusion APRIL 2016 / WELDING JOURNAL 121-s Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 122 WELDING RESEARCH A B Fig. 2 — Porosity analysis data as function of the following: A — Welding current (with corresponding voltage) at a constant welding speed [60 cm/min (15.75 in./min)]; B — welding speed at a constant welding current and voltage (200 A and 16.9 V). welding speed and welding voltage on porosity formation were also studied in their work. However, these specific studies have been conducted in the bead-on-plate condition, which is far from a real weld used in the automotive industry. Although extensive research has been conducted on fusion welding of zinc-coated steels, all these prior studies focused on mitigating porosity discontinuities without any in-depth study to disclose the mechanisms and phenomena involved in the porosity formation in relation to a wide range of welding parameters. Moreover, none of the existing works involve the CMT process. In this work, a systematic study is performed on porosity formation, growth, and escape phenomena in CMT-GMA welding of zinc-coated steels over a wide range of welding parameters (welding current, voltage, and welding speed) consisting of low, medium, and high-heat-input conditions. The weld pool behavior during welding and the quality of welds depend largely on weld pool temperature. Infrared (IR) thermography using an infrared camera can detect the IR energy emitted from the surface and convert it into a two-dimensional image of temperature distribution showing real-time weld pool temperature during the process (Ref. 25). Insitu study of the weld pool using highspeed camera and infrared camera were performed in order to support the experimental data and to explain the mechanisms involved in porosity formation, growth, and escape phenomena in CMT-GMA welding of zinccoated steel. With the understanding of the mechanism, a set of welding conditions were derived that ensure the least possible amount of porosity. In order to obtain welds with reliable mechanical responses (static and dynamic) in the arc welding process, adequate penetration and a discontinuity-free weld are needed. Therefore, CMT-GMA weld joints were also put through a tensile test to determine a critical penetration depth to ensure adequate mechanical properties and sort out a range of welding conditions that ensure adequate strength of the weld joint. Finally, the outcome of the study on porosity and the mechanical properties were combined to yield optimized welding conditions with adequate penetration and less porosity, ensuring the integrity of the welds. Experimental Procedure Experiments on porosity were conducted using hot-rolled steel sheets of 440 MPa ultimate tensile strength and 2.3 mm thickness with a galvannealed coating thickness of 10 μm. The samples were welded using ER 70S-3 solid welding wires 1.2 mm in diameter. As single lap-joint geometry is the most susceptible one to porosity formation, this geometry with a 25-mm overlap was selected for the current study. Throughout the study, a constant welding length of 100 mm was used. As was found in the study by Matsui et al. Table 2 — Tensile Test Results Showing the Strength and Failure Modes of the Joints with Different Penetrations Heat Input (J/mm) Penetration (mm) Sample 1 152 167 185 203 223 0.01 0.10 0.20 0.28 0.38 122-s WELDING JOURNAL / APRIL 2016, VOL. 95 331 382 337 447 451 UTS (MPa) Sample 2 Sample 3 311 292 359 443 455 313 376 384 441 445 Sample 1 Mode1 Mode 1 Mode 1 Mode 2 Mode 2 Failure Mode Sample 2 Mode 1 Mode 1 Mode 1 Mode 2 Mode 2 Sample 3 Mode 1 Mode 1 Mode 1 Mode 2 Mode 2 Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 123 WELDING RESEARCH Fig. 3 — Porosity analysis data as a function of heat input for CMT­GMAW (Ref. 28). Fig. 4 — Porosity analysis data as a function of heat input for the stan­ dard short circuit GMAW process. B A C Fig. 5 — Analysis at high­heat­input condition: A — Frames from high­speed camera movie showing porosity escape phe­ nomenon; B — weld pool temperature distribution obtained by infrared camera; C — schematic illustrating the steps of zinc vapor bubble formation, growth, and escape; D — x­ray RT film and bead cross section of the sample welded at a high­ heat­input condition. (Refs. 23, 24), a root opening of 0.2 mm between the sheets in lap-joint geometry can provide a passage for high-pressure zinc vapor to escape and thus can significantly affect the amount of porosity in the weld bead. Therefore, specimens were spot welded prior to the experiments in order to ensure zero root opening and avoid ambiguity of data. The drag technique with a drag angle of 80 deg and torch angle of 60 deg was used throughout the study. In this current work, wide ranges of welding parameters, including welding current, welding voltage, and welding speed, were considered to study porosity formation mechanism and behav- ior. The CMT process works based on a synergic program, allowing the user to only modify wire feed speed. The machine itself selects the suitable welding current and voltage based on the synergic program. In this work, wire feed speed was used ranging from 3 to 11 m/min, which varied the welding current and welding voltage in the ranges of 120 to 263 A and 12 to 20 V, respectively. The welding speeds used ranged from 40 to 120 centimeters per minute (cm/min) (15.75–47.25 in./min) with an interval of 10 cm/min (4 in./min). To quantify the amount of porosity in the weld bead, welded samples were D put through x-ray radiographic testing (RT) with a Rigaku 250EGS industrial x-ray system. X-ray RT results were obtained in films, which were digitalized for the analysis of porosity. Commercially available image analysis software, Image-Pro Plus®, was used for quantification of porosity. For the quantification of porosities in weldments, previous researchers have followed two approaches: The first approach involves measuring the summation of the area of all the porosities in the x-ray RT image and quantifying it as the percentage of the total area of the weld bead in the x-ray RT image (Ref. 14). The second apAPRIL 2016 / WELDING JOURNAL 123-s Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 124 WELDING RESEARCH B C A Fig. 6 — Analysis at medium­heat­input condition: A — Frames from high­speed camera movie showing porosity escape phenomenon; B — weld pool temperature distribution obtained by infrared camera; C — schematic illustrating the steps of zinc vapor bubble formation, growth, and escape; D — x­ray RT film and bead cross section of the sample welded at a medium­heat­input condition. proach considers counting the number of porosities from the x-ray RT results (Refs. 21, 23, 24). As the latter approach does not consider the size of porosities, in this study the first approach was followed and porosities were quantified as area percentage. However, x-ray RT results were obtained in two-dimensional plane and can reveal the size of porosities without disclosing their positions. The welded samples were cross sectioned, polished, and etched with 2% picral solution. The subsequent macroscopic analyses were performed with an Olympus SZ61 macroscope at 10 magnification to find out the location for porosity formation. Moreover, a high-speed imaging technique was engaged to study the weld pool surface to visualize the zinc vapor escape phenomenon and its frequency. A collimated monochromatic LED light source was used to illuminate the weld pool for high-speed imaging at 4000 frames per second with a Photron MC2-type high-speed video camera. The high-speed camera was set up parallel to the welding gun focusing on the weld pool right behind the arc. To study the weld pool temperature at different heat input conditions, a FLIR A655sc infrared camera was used. Data from infrared imaging were used for comparing the differences in weld pool temperature at different welding conditions. For the study of mechanical properties, hotrolled steel sheets of 440 MPa ultimate tensile strength and 2.3 mm thickness were used. As the presence of porosity can lead to irregular and fluctuating results in the tensile test and prevent the selection of critical condition, uncoated samples were used for the tensile test with the KSU-10M tensile testing machine. Other welding conditions were kept constant. Results and Discussion Porosity in GMAW of Zinc­ Coated Steel Effect of Porosity on the Mechanical Properties In a sound welding condition, the mechanical properties of weld joints of zinc-coated steels usually match those 124-s WELDING JOURNAL / APRIL 2016, VOL. 95 D of uncoated steels (Ref. 27). Data from tensile tests performed on weld joints at different welding conditions are presented in Fig. 1. As the ultimate tensile strength (UTS) of base metal and welding wire are 440 and 540 MPa, respectively, failure is more likely to occur at base metal with an UTS of about 440 MPa. However, the stress vs. strain curves produced from the tensile test data presented in Fig. 1A show a scattered behavior and failures were found in weld zones as well as base metal for different welding conditions. X-ray RT analysis of samples presented in Fig. 1B shows that the sample, which failed through the weld zone at a lower stress, has a large amount of porosity in the weld bead. The presence of weld discontinuities like porosity degrades the weld quality as the cracks initiate along the edge of the pores (Ref. 1). Moreover, the stress vs. strain curves presented in Fig. 1A show a sig- Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 125 WELDING RESEARCH B C A Fig. 7 — Analysis at low­heat­input condition: A — Frames from high­speed camera movie showing porosity escape phe­ nomenon; B — weld pool temperature distribution obtained by infrared camera; C — schematic diagram illustrating the steps of zinc vapor bubble formation, growth, and escape; D — x­ray RT film and bead cross section of the sample welded at a low­ heat­input condition. nificant difference in the failure strain of samples with and without porosities in the weld bead. The sample with a large amount of porosity had a very low failure strain (2.82%) compared to the weld joints with little or no porosity (17.72 and 19.92%, respectively). Hence, the presence of porosity in the weld bead greatly reduced the energy absorption capacity of the joint, which is a significant requirement for ensuring vehicle safety. On a similar study conducted by Joaquin et al. (Ref. 14) on the mechanical properties of GMAW lap-joint geometry of zinccoated steel, fluctuating results in the tensile strength were observed due to the presence of porosity in weldments. Porosity Formation Behavior in GMAW To understand the porosity formation mechanism and behavior in CMTGMAW of zinc-coated steels, a wide range of welding conditions were studied as presented in Table 1. The CMT process functions based on a synergic program, which allows the user to only change wire feed speed, and the CMT machine chooses the suitable current and voltage. Therefore, in this work, at the fixed welding speed, wire feed speed was changed in a way that the D current changed by 10 A (from 120 to 263 A), letting the machine choose the respective voltage. In addition, at the fixed welding current and voltage, welding speed was varied at an interval of 10 cm/min (4 in./min) in the range of 40 to 120 cm/min (15.75 to 47.25 in./min). Samples prepared according to the experiment plan presented in Table 1 were put through an x-ray RT test for the purpose of porosity evaluation. The amount of porosity in area percent as function of welding current, voltage, and welding speed are presented in the graphs in Fig. 2. All the graphs in Fig. 2 have similar trends for the porosity amount. At the lower ends, the amount of porosity is low, which then shows a rapid increment in the medium ranges of the parameters and again decreases at the higher ends. In order to compare both data sets as a function of one parameter, the calculated heat inputs were used. The amount of heat input was calculated using Rosenthal’s simplified approach. When the amount of porosity is plotted as a function of heat input, both data sets yield an identical trend: having a lesser amount of porosity in low and high heat inputs and a relatively higher amount of porosity in the medium-heat-input range, as shown in Fig. 3 (Ref. 28). According to the ISO standard for porosity, the critical amount of porosity is equal to 2% of the total bead area in weld joints (Ref. 29). The porosity analysis data in Fig. 3 indicates the amount of porosity in the weldment was lower than the critical value in low heat inputs ranging from 150 to 250 J/mm. As the heat input rose beyond 250 J/mm, the amount of porosity rapidly increased and reached its maximum at around 300 J/mm heat input. Further increment in the heat input showed a decreasing trend of porosity, which fell below the critical once again beyond the heat input of 350 J/mm. Based on the described trend of porosity accumulation in the weld bead, the whole heat input range was divided into three distinguished sections as low, medium, and high heat input for the present study. Based on this, welding conditions resulting in heat inputs less than 250 J/mm were considered as low-heat-input conditions. Heat inputs between 250 and 350 J/mm, which are susceptible to porosity accumulation, were marked as mediumheat-input conditions. Heat inputs beyond 350 J/mm were considered highheat-input conditions. The lesser amount of porosity at high heat inputs attributed to the slow solidification APRIL 2016 / WELDING JOURNAL 125-s Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 126 WELDING RESEARCH A B Fig. 8 — A — Amount of porosity as function of heat input (verification of the proposed mechanism); B — contour plotting for choosing suitable CMT­GMAW conditions with less porosity. A B Fig. 9 — A — Three­dimensional schematic illustrating the prepa­ ration of the tensile test specimens; B — bead cross sections at different heat inputs with different penetration depths. rate, which provided a longer time for the zinc vapor to escape from the weld pool compared to other heat inputs (Refs. 12, 15). As explained by Ribic et al. (Ref. 15), the thermophysical properties of the material, power density of the heat source, and the heat input per unit length govern the solidification rate of the weld pool. As the material and heat source were fixed throughout this study, heat input per unit length was the factor determining the solidification rate. At high heat inputs, the solidification rate is slow enough to allow the zinc vapor to escape the weld pool, causing less porosity. This phenomenon is supported by other published research regarding the porosity issue in fusion welding of zinc-coated steels (Refs. 13, 16, 30). As the heat input decreases up to the medium range, the amount of porosity starts to rise, which is also supported by the previous works (Refs. 12, 15, 20). However, all the previous works have used the terms “high heat input” and “low heat input” without indicating the exact range in actual values (Refs. 12, 13, 20). Beside, the weldable heat input range changes depending on the materials’ thermophysical properties and thickness for the same welding process. Hence, in order to compare CMT-GMAW process with other processes and to explain less porosity in low heat inputs, a better understanding on the weldable heat input 126-s WELDING JOURNAL / APRIL 2016, VOL. 95 range of conventional short-circuit process and porosity formation behavior over that range are required. To achieve that understanding, a set of samples were welded using the same shielding gas over a wide range of heat inputs, which showed that at heat inputs less than approximately 250 J/mm, conventional GMAW cannot produce adequate deposition to Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 127 WELDING RESEARCH A B Porosity Formation Mech­ anisms at Differ­ ent Heat Input Conditions As zinc has a boiling temperature that is much lower than the melting temperature of iron, the zinc coating present on the surface of specimens evaporates when exposed to the C arc. In the lap joint configuration, a high-pressure zinc vapor Fig. 10 — A — Typical failure mode at penetration < 10% of base metal thickness; B — typical failure mode at penetration >10% of starts to form at base metal thickness; C — tensile strength as a function of pene­ the faying intertration depth. face of the specimens (Ref. 21). The amount of create a sound weld joint. Weldability zinc vapor formation depends on the of the CMT process at heat inputs less extent of the region over the boiling than 250 J/mm is the result of the point of zinc, which is proportional to controlled method of metal transfer the amount of heat input (Ref. 1). In and its higher melting efficiency comthe absence of a root opening in the pared to conventional arc welding lap-joint configuration, zinc vapor has processes, as explained by Pickin et only one way to be vented out and that al. (Ref. 7). The obtained conventionis through the weld pool (Refs. 1, 21). al GMA welded samples were put The attempts made by Masaharu Sato through an x-ray RT test and the reto identify critical locations of zinc sults of porosity evaluation were plotcoating for porosity formation by placted as the function of heat input in ing a thin zinc leaf on different locathe graph shown in Fig. 4. Within the tions of the lap-joint geometry to simweldable range starting from approxiulate the zinc coating (Ref. 31) conmately 250 J/mm, the amount of cluded that the zinc present at the fayporosity is similarly high as in CMTing interface of the specimens is reGMA welded samples up to 350 sponsible for porosity formation in J/mm, which decrease sharply at the weldments of zinc-coated steels. Once high heat inputs beyond 350 J/mm. the zinc vapor enters the weld pool, it takes the form of a bubble. This bubble contains a high-pressure zinc vapor, which lets it grow in size and then rise up due to buoyancy. Like all gaseous matter, the vapor pressure of zinc also has strong temperature dependency and shows higher vapor pressure at higher temperatures, which is governed by the ClausiusClapeyron equation (Refs. 8, 9). Weld pool temperature depends on the amount of heat input causing a higher temperature weld pool at higher heat inputs (Ref. 26). The maximum temperature of CMT-GMAW was measured within 1650° to 2700°C with different heat input conditions, which is close to the measurement made by Kozakov et al. (Ref. 32). From this measured temperature range, the approximate range of vapor pressure can be calculated within 63 to 125 MPa. While vapor pressure affects the growth and rising up of the zinc vapor bubble by assisting in the process, viscosity of molten metal affects the process by acting as the resisting force (Ref. 21). The viscosity of molten metal is also temperature dependent. The Arrhenius equation shows this dependency as follows: Eμ μ = μo e RT (1) where is the viscosity at the studied temperature, ois the viscosity at the reference temperature, E is the temperature coefficient of viscosity, R is the universal gas constant, and T is the study temperature in Kelvin (Ref. 33). From the stated equation, it can be said that the viscosity of molten APRIL 2016 / WELDING JOURNAL 127-s Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 128 WELDING RESEARCH A B Fig. 11 — A — Penetration depth as function of heat input; B — contour plot for choosing a suitable CMT­GMA welding condition ensuring adequate penetration. metal decreases with the increase in temperature. The weld pool temperature depends on the welding parameters or heat input (Ref. 33). Within the measured range of weld pool temperature, the calculated viscosity using the provided equation varies from 4.00 10–3 to 1.62 10–3 kg/ms. Therefore, at higher heat inputs, weld pool temperature is higher, resulting in a less viscous weld pool and vice versa. The zinc vapor bubble’s growth and rise due to vapor pressure and buoyancy depends on the viscosity and the time required to reach solidification temperature of the weld pool (Ref. 15). The size and location of pores are the results of the competition of viscosity against buoyancy and vapor pressure within the time required to reach solidification temperature. Based on this concept, schematic diagrams of zinc vapor behavior with respect to different heat input conditions are presented in Figs. 5–7 along with corresponding x-ray RT results, bead cross sections, and in-situ study evidence from high-speed camera (to study the zinc vapor bubble escape behavior) and infrared camera (to measure the weld pool temperature) in order to explain the porosity formation and growth behaviors in CMT-GMAW of the studied zinc-coated steel at different heat input conditions. The in-situ high-speed imaging study of the weld pool gives out the zinc vapor escape phenomenon from the weld pool. Frames from the study conducted at a high-heat-input condi- tion are presented in Fig. 5A, which shows the zinc vapor escape phenomena from the large-sized weld pool. In the high-heat-input conditions, the frequency of zinc vapor escaping from the weld pool was counted to be about 25 times per second. The temperature measurement of the weld pool surface using the infrared camera (Fig. 5B) shows the peak temperature of the weld pool was about 2700°C and the arc and the region just behind the arc were at maximum temperature. A schematic representation of zinc vapor formation, growth, and escape mechanism is presented in Fig. 5C. The weld pool temperature was highest in the high inputs within the experimental range. This induced a less viscous weld pool with a viscosity of about 1.62 10–3 kg/ms, less than the half of the viscosity in the low-heat-input cases (4.00 10–3 kg/ms). Moreover, as calculated, the vapor pressure of zinc in high heat inputs was about 125 MPa, which is also about twice the vapor pressure at low-heat-input conditions. Because of high vapor pressure inside the zinc vapor bubble in a less viscous weld pool, the zinc vapor bubbles rapidly grew in size and rose up faster. Beside, due to the high temperature of the weld pool, it needed a longer time to reach its solidification temperature. Due to these facts, even though zinc vapor bubbles cross a longer distance to reach the surface, they can escape the weld pool before solidification. This is claimed because the high-speed camera recorded the highest zinc va- 128-s WELDING JOURNAL / APRIL 2016, VOL. 95 por bubble escape frequency at this condition. As a result, a porosity-free weld bead can be obtained at high inputs as evident from the x-ray RT image and bead cross section shown in Fig. 5D. Frames from a similar high-speed camera study of the weld pool with medium-heat-input conditions are presented in Fig. 6A. From the highspeed camera frames, zinc vapor escape behavior is also evident in medium heat inputs, although the zinc vapor escape location is far from the arcing location compared to the high heat inputs. The zinc vapor escape initiation (at 3.5 ms) was also delayed compared to the high-heat-input case (at 3.0 ms) indicating a longer time was required for the zinc vapor bubble to rise to the surface. Moreover, the frequency of zinc vapor escaping was much lower than that of the highheat-input condition (5 times per second). The weld pool surface temperature measurement data obtained by the IR camera in Fig. 6B shows the highest temperature was about 2100°C, which is significantly lower than the highheat-input case. Hence, the weld pool is more viscous with an approximate viscosity of 2.6 10–3 kg/ms. At this weld pool temperature, the vapor pressure of zinc was calculated to be about 91 MPa, significantly lower than the high-heat-input case. A zinc vapor bubble with lower vapor pressure in a more viscous weld pool takes longer to rise to the weld pool surface and es- Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 129 WELDING RESEARCH Fig. 12 — Weldability envelope diagram presenting different zones in the whole experi­ mental range. cape. This explains the delayed escape of the zinc vapor bubble from the weld pool at a location far behind the arc compared to that of the high-heatinput case. Based on this evidence, the mechanisms for zinc vapor formation and growth in medium-heat-input conditions are explained in the schematic representation of Fig. 6C. In medium heat inputs, the zinc vapor bubble formation starts in a similar manner as in high heat inputs. However, due to the significantly lower weld pool temperature compared to the high-heat-input condition, the viscosity of the weld pool was higher and the vapor pressure was lower than the high-heatinput case as calculated. Therefore, the zinc vapor bubble faced more resistance and needed a longer time to reach the weld pool surface, even though it had to cross a shorter distance due to a lower amount of deposition compared to high-heat-input conditions. Hence, the zinc vapor bubble could rise up and grow in size; however, the weld pool temperature was not high enough to delay the solidification initiation until the zinc vapor bubble reached the surface and completely vented out from the weld pool and the molten pool again filled the void the escaped zinc vapor left behind. When solidification starts before the zinc vapor bubble reaches the surface, it produces discontinuities in the form of internal porosities (Ref. 21), which are not seen from the surface. As a result, large-sized porosities (about 750 m in diameter) are evident in the x-ray RT images in Fig. 6D. However, some irregular escaping of zinc vapor bubbles was observed in high-speed camera analysis. In such cases, if the solidification starts before the weld pool closes down, there will be pits (porosities open to the surface) (Ref. 21). The bead cross sections in Fig. 6D show the presence of large porosity right below the surface in the first one and the presence of pit in the second one, as explained. The heat input range specified as low-heat-input conditions in the current work was unexplored in earlier studies (Refs. 9–14) as the standard short-circuit arc welding process is unable to produce adequate deposition required for making a weld joint possible at this heat input range. The porosity evaluation results show (Fig. 3) that the amount of porosity is less than the critical value in this range. However, the high-speed camera study of the weld pool presented in Fig. 7A showed no porosity escape phenomenon in this condition. Infrared temperature measurement of the weld pool surface reveals its maximum temperature is about 1650°C, which is relatively close to the solidification temperature. The infrared image in Fig. 7B also shows a small region over the solidification temperature of molten steel, and images from the high-speed camera in Fig. 7A also show a smaller-sized weld pool at this heat input condition. Yet the lower amount of porosity is the subject of the small size of porosity as evident in x-ray RT image of Fig. 7D. The bead cross section in Fig. 7D reveals the porosity formation location is near the root of the weld bead, far away from the weld bead surface. The mechanisms involved in porosity formation in low heat inputs are explained with a schematic in Fig. 7C. As illustrated in the schematic, in the low heat inputs, the zinc vapor bubble formation initiates in a similar manner as in the high- and medium-heat-input conditions. However, due to low heat input, the amount of zinc evaporation is lower. The weld pool temperature is lower than in the medium- and highheat-input conditions. The low temperature of the weld pool causes less vapor pressure inside the zinc vapor bubble, which is about 62 MPa, about half of the vapor pressure exerted at the high-heat-input conditions. Beside, at the low-temperature weld pool, the viscosity of the molten metal (approximately 4.00 10–3 kg/ms) is more than twice the viscosity at high heat inputs. The lower vapor pressure of zinc in a high-viscosity weld pool results in slower growth of the zinc vapor bubble. The small-sized bubbles need a longer time to rise to the surface due to weaker buoyancy than the larger-size zinc vapor bubbles formed in medium- and high-heat-input conditions and higher viscosity of the weld pool (Ref. 34). Moreover, the low temperature of the weld pool also leads to its early solidification. As a result of these, smallsized porosities with an average diameter of 250 m are formed near the root of the weld bead as evident in the bead cross section shown in Fig. 7D. APRIL 2016 / WELDING JOURNAL 129-s Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 130 WELDING RESEARCH Beside, as the porosities cannot rise to the surface, no porosity escape phenomena are observed at these heat inputs. In the quantitative characterization of porosity in laser welding of stainless steel performed by Madison et al. (Ref. 35), a similar behavior in porosity formation location and size was observed. In that work, smallsized pores were evident at a location far away from the weld bead surface. As the heat input gradually increases, larger-sized pores start to appear at a gradually closer position to the weld bead surface. Optimized Welding Conditions for Porosity As discussed in the previous section, the heat inputs ranging from 250 to 350 J/mm, which are marked as medium heat inputs, are susceptible to porosity formation. The low-heatinput (below 250 J/mm) and highheat-input (over 350 J/mm) conditions have significantly less porosity. To perform a validation test on this range, all welding conditions yielding heat inputs within 250 to 350 J/mm along with one condition in the highheat-input range and one condition in the low-heat-input range at each welding speed within the range were evaluated for porosity. The porosity evaluation results were accumulated in the graph in Fig. 8A. The graph shows the porosity evaluation data agree well with the proposed mechanism and behavior discussed in the previous section. All the porosity evaluation data of welds performed at heat inputs within 250 to 350 J/mm show a porosity amount of more than 2% of the total bead area, whereas other conditions (low- and high-heat-input conditions) always show an amount of porosity less than the critical amount (2% of bead area). Based on this validation study, it can be concluded the proposed mechanisms are sound. However, the synergic program in the CMT-GMAW process increases the amount of deposition along with the welding current and voltage. As a result, the welding conditions with high heat inputs can lead to overdesigning the weld joint, exceeding the actual requirements. An independent control over current and voltage apart from the wire feed rate as found in double-electrode GMAW (Refs. 36-42) would have allowed changing the heat input without increasing the amount of deposition, hence avoiding overdesigning the weld joint. With the porosity evaluation data, a contour mapping was prepared and is presented in Fig. 8B. By following the color coding in the contour plot, welding conditions susceptible to porosity formation can be identified. Moreover, using this diagram as a guideline, suitable welding conditions causing less porosity can be selected based on the requirement. In the contour map, the welding conditions falling from the yellow to red color regions must be avoided due to the high amount of porosity, whereas the ash-colored regions do not have weldability due either to incomplete fusion or meltthough. Welding conditions in the ashcolored region of the low heat inputs do not produce adequate deposition to produce a weld joint. On the other hand, the welding conditions in the ash-colored region at the high-heatinput side produce too high a heat input and cause melt-through. The welding conditions leading to any other color in the map will produce a weld joint with porosity less than 2% of total bead area and are hence acceptable. Mechanical Properties In the previous section, a range of optimized welding conditions was derived based on the porosity analysis results. However, a weld joint must ensure adequate mechanical strength as well. To achieve a guideline for acceptable welding conditions for adequate mechanical strength, tensile testing was performed in the current work. As shown in Fig. 1, tensile testing with zinc-coated samples can lead to ambiguous results due to the presence of porosity, hence prohibiting researchers from deriving any practical useful guideline. To overcome this difficulty, tensile tests were performed using uncoated materials with the same mechanical properties and composition. For the tensile strength test, tensile samples were prepared with the dimensions presented in Fig. 9A, according to the ASTM E8M-03 standard (Ref. 43). A set of samples with different heat inputs and hence different leg lengths 130-s WELDING JOURNAL / APRIL 2016, VOL. 95 and penetration depths as shown in Fig. 9B were put through a tensileshear test at a constant testing speed of 5 mm/min. The samples at all the welding conditions had a leg length more than 90% of base metal thickness, which is the minimum leg length requirement as specified by the AWS D8.8 standard (Ref. 44). For each welding condition, three tensile samples were machined from the same weldment. The results from the tensile-shear tests are presented in Table 2, which shows two types of failure mode. The first type of failure mode is referred to as “mode 1,” which is shown in Fig. 10A. The penetration depth was less and under tensile loading, the weld bead separated from the lower sheet. As the leg length fulfilled the minimum requirement, this kind of failure was attributed to inadequate joint penetration (Refs. 7, 45). Beside, as mentioned by Lawrence and Cox (Ref. 46), a significant drop in the tensile strength and fracture strain is seen in the samples with inadequate penetration. Moreover, in CMT-GMAW, the leg length and penetration increase simultaneously as the amount of deposition increases with the amount of heat input. Hence, in this work, penetration depth was considered as the critical parameter for a weld to ensure adequate mechanical strength. From the data in Table 2, it is evident that “mode 1” is the usual failure mode at penetration depths less than 0.20 mm. In the case of the samples with higher penetration depths, the failure location moves toward the base metal as a shown in Fig. 10B. In this work, failure at the base metal was classified as “mode 2.” The tensile test data from Table 2 are plotted as a function of penetration depth in order to relate the tensile strength with penetration depth in the graph of Fig. 10C. The graph shows gradual increments in the tensile strength with increasing penetration depth until the penetration depth is less than 0.23 mm. However, as the penetration depth increases beyond 0.23 mm, which is 10% of the base metal thickness, the ultimate tensile strength stops increasing as the failure location shifts toward the base metal. Hence, the penetration depth equal to 10% of the base metal thickness was considered the minimum re- Ahsan Paper 201590 April 2016_Layout 1 3/10/16 4:27 PM Page 131 WELDING RESEARCH quirement to ensure adequate mechanical strength in a CMT-GMA weld joint. A similar guideline (10% of base metal thickness) as minimum requirement for penetration depth was also used by O. Schwedler et al. (Ref. 47) to set acceptance criterion for sound welding in CMT-GMAW. Based on the criteria set for minimum penetration depth ensuring adequate mechanical strength, a range of bead cross sections were checked for penetration depth. In the graph presented in Fig. 11A, penetration depth was plotted as a function of heat input, which shows an increasing trend in penetration depth with heat input and a heat input of 200 J/mm was considered to be the critical value to yield a penetration greater than 10% of base metal thickness. To verify this condition, all the welding conditions right above 200 J/mm within the total welding range shown in Table 1 were checked for penetration depth. The results of the verification study is accumulated in the contour plot in Fig. 11B. The contour plot shows the whole weldable range that has been divided into three distinguished zones with black lines: welding conditions that had inadequate heat input to produce sufficient penetration, welding conditions with adequate penetration, and extremely high heat inputs that will lead to melt-through. Using this contour plot, suitable welding conditions can be chosen to ensure minimum adequate penetration and, hence, joint strength. Optimized Welding Conditions From the study conducted on porosity formation, growth, and escape mechanisms in CMT-GMAW of zinc-coated steels, heat inputs below 250 J/mm (low heat inputs) or above 350 J/mm (high heat inputs) had the amount of porosity less than the critical amount of 2% of total bead area. However, not all the welding conditions in these ranges might be suitable from the mechanical performance standpoint due to inadequate joint strength. To ensure joint efficiency and optimized welding conditions, tensile tests on samples with different heat input conditions, and hence, different penetration depths, were carried out. The tensile testing results show a minimum penetration equivalent to 10% of base metal thickness is enough to ensure mechanical efficiency (see Fig. 10C). The relationship between heat input and penetration depth shows that heat inputs equal to or above 200 J/mm always yields a penetration equal or higher than the set critical condition (10% of base metal thickness). The conditions derived from the individual studies performed on porosity and mechanical porosity evaluation are plotted in contours in Figs. 8B and 11B. Both contours show optimum weldable regions considering either porosity or mechanical joint efficiency. Both of the mentioned contours are plotted within the same range of welding parameters, hence, their optimum weldable ranges are super positioned to derive the common weldable region, which is presented as the weldability envelope diagram shown in Fig. 12. The envelope diagram shows two regions, one ranging from 200 to 250 J/mm heat input, falling into the lowheat-input conditions (lower enclosed section by green line). The other region ranges from 350 to 550 J/mm, falling into the high-heat-input conditions (upper enclosed section by green line). Both regions ensure adequate penetration depth to ensure joint efficiency and a less-than-critical amount of porosity, which are recommended for next experiences. Conclusions This paper explains a study on the porosity formation, growth, and escape behavior, and the mechanical properties of weld joints in CMTGMAW over a wide range of heat inputs (150–550 J/mm). At the three distinctive heat input regions, [low (below 250 J/mm), medium (250–350 J/mm), and high (over 350 J/mm)], the maximum weld pool temperatures were found to be approximately 1650°, 2100°, and 2700°C. In this work, porosity formation, growth, and escape mechanisms were explained using the viscosity of the weld pool and the vapor pressure of zinc. With the low heat inputs, due to the lower temperature of the weld pool within the range, low vapor pressure of zinc, and high viscosity of the weld pool, the zinc vapor bubble could not grow and rise. As a result, small-sized pores were formed near the weld root and the total amount of porosity was less. With the high heat inputs, the high temperature of the weld pool assisted the zinc vapor bubble to grow in size, rise up, and escape by creating the least viscous weld pool, maintaining high vapor pressure of zinc, and delaying the solidification. With the medium heat inputs, the weld pool temperature was proved not to be high enough to delay solidification until the zinc, vapor could escape. However, it was high enough to maintain a low viscosity and high vapor pressure of zinc to let the zinc vapor bubble grow and rise. The combination of these factors led to a high amount of porosity accumulation in the weldment in this range. 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