MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Quantum Effects Lead to Phenomena such as: Ultra Thin Oxides – Observe: High Leakage Currents Through the Oxide - Tunneling Depletion in Poly-Si metal gate – capacitance effect Thickness of Inversion Layer – alters tox GIDL (Gate-Induced Drain Leakage) – High Doping - Leads to tunneling DIBL (Drain-Induced Barrier Lowering) – Short Channel - Leads to tunneling Take advantage of Quantum Effects Decrease effective mass Change E -vs- k energy band diagram by… Induce strain using lattice mismatch between S/Cs Quantum Confinement – Gain in Device Efficiency Band gap engineering – Use other S/Cs to decrease Eg Knowlton 1 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Ultrathin SiO2 – begin to observe quantum effects +V gate VSource M VDrain W + poly-crystalline Si O Source Contact Insulator S n++ Poly Si Gate Contact or Electrode Drain Contact Insulator SiO2 - Gate oxide n+source - - - - - - - - - - - - - - n+drain channel p-Si Wafer Crystalline Si L Cox Knowlton o r A tox tox o kox A tox 2 1 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Ee- Ef n++-Si p- Si p- Si n++-Si p- Si n++-Si SiO2 SiO2 Flat band Knowlton MSE 310/ECE 340 Electrical Properties of Materials SiO2 What condition is this? 3 Part 5: Quantum Effects in MOS Devices EeTreat as IF a p-n junction p- Si n++-Si n++-Si p- Si p- Si n++-Si e- flow only one way SiO2 Flat band Knowlton SiO2 What condition is this? 4 2 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Poly-depletion eVRev p- Si n++-Si Knowlton MSE 310/ECE 340 Electrical Properties of Materials Poly depletion Biased into Strong Inversion 5 Part 5: Quantum Effects in MOS Devices Depeletion in poly-Si C Cox x 1 C D , poly C Si ox , physical 1 Colinge & Colinge, S/C Devices Other: Relativistic Carriers (hot emissionoxide damage) Knowlton 6 3 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Quantization: (cont.) 2D gas in channel Inversion layer thickness is similar to the gate oxide thickness tox ,eff tox , physical Changes oxide thickness ox x Si Davies, The Physics of Low Dimensional Semiconductors, (Cambridge, 1998) p. 343 See also: KnowltonHareland, IEEE Transactions on Electron Devices, 1996 Anderson & Anderson. Fundamentals of Semiconductor Devices, (McGraw Hill, 2005) p. 504-506 7 MSE 310/ECE 340 Part 5: Quantum Effects in MOS Devices Quantization (Cont.) – Consider Quantization in MOS Channel Electrical Properties of Materials EC,S-C Ee- Oxide Semiconductor Where are: Ψ and lΨl2 located??? Knowlton From Principles of Electronic Materials and Devices, Third Edition, S.O. Kasap (© McGraw-Hill, 2005) 8 4 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices 8 Quantization: (cont.) - Recall “Particle in a Box” or “Infinite Potential Well” or “Quantum Well”? Chapter 3 of Kasap V= 8 V= 8 V(x) Electron V=0 Energy of electron Ψ and lΨl2 is always zero at the boundary! 0 0 a 0 E4 n=4 E3 n=3 E2 n=2 E1 n=1 x 4 3 2 x=0 x=a Energy levels in the well 1 0 x (x) sin(nx/a) a0 a Probability density |(x)|2 Electron in a one-dimensional infinite PE well. The energy of the electron is quantized. Possible wavefunctions and the probability distributions for the electron are shown. Knowlton From Principles of Electronic Materials and Devices, Third Edition, S.O. Kasap (© McGraw-Hill, 2005) MSE 310/ECE 340 Electrical Properties of Materials 9 Part 5: Quantum Effects in MOS Devices Quantization: (cont.) 2D gas in channel Inversion layer thickness is similar n ~1 to the gate oxide thickness Changes oxide thickness tox ,eff tox , physical Knowlton ox x Si Energy States of e-: Bound versus Unbound (continuum) Davies, The Physics of Low Dimensional Semiconductors, (Cambridge, 1998) p. 343 10 5 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Tunneling: Drain Induced Barrier Lowering (DIBL) Fowler-Nordheim (FN) [cold emission – oxides] Direct (oxides) Band-to-Band Barrier lowering Vgate= 0n Vg Drain Contact Poly Si Gate Contact VD=VDD Vd Drain Contact SiO2 - Gate oxide n+source n+drain channel p-Si Wafer This results because… …this occurs. Knowlton Streetman & Banerjee , Solid State Electronic Circuits (Prentice Hall,2000) MSE 310/ECE 340 Electrical Properties of Materials Muller & Kamins (Wiley-Interscience,2003) Fig. 9.17 p. 452 Part 5: Quantum Effects in MOS Devices Gate Induced Drain Leakage (GIDL) Tunneling: Vgate=0 Vg Poly Si Gate Contact Colinge & Colinge, S/C Devices Fowler-Nordheim (FN) [cold emission – oxides] Direct (oxides) Band-to-Band Barrier lowering Drain Contact 11 VD=VDD Vd Drain Contact SiO2 - Gate oxide n+source n+drain channel P-Si Wafer Knowlton GIDL Sze, Modern S/C Device Physics (Wiley-Interscience,1998) Ch. 3 by SlJ. Hillenius 12 6 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Quantization: (cont.) 2D gas in channel SOI Gate-all-around (GAA) MOSFET: Knowlton MSE 310/ECE 340 Electrical Properties of Materials Colinge & Colinge, S/C Devices 13 Part 5: Quantum Effects in MOS Devices Bandgap Engineering of Channel Consider: Bandgap, mobility, effective mass, lattice matching, quantum confinement of carriers Lattice Constants: aSi = 5.4309 Å aGe = 5.6577 Å Knowlton Cullity, Elements of X-ray Diffraction, 2nd Ed (1978) Appendix 5 From Principles of Electronic Materials and Devices, Third Edition, S.O. Kasap (© McGraw-Hill, 2005) 14 7 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Bandgap Engineering of Channel Consider: Bandgap, mobility, effective mass, lattice matching, quantum Lattice Constants: confinement of carriers aSi = 5.4309 Å aGe = 5.6577 Å Cullity, Elements of X-ray Diffraction, 2nd Ed (1978) Appendix 5 Knowlton Science M. Ieong, B. Doris, J. Kedzierski, K. Rim, M. Yang, Silicon Device Scaling to Sub-10nm Regime (2004) MSE 310/ECE 340 Electrical Properties of Materials 15 Part 5: Quantum Effects in MOS Devices Bandgap Engineering of Channel Consider: Bandgap, mobility, effective mass, lattice matching, quantum Lattice Constants: confinement of carriers aSi = 5.4309 Å aGe = 5.6577 Å Cullity, Elements of X-ray Diffraction, 2nd Ed (1978) Appendix 5 Knowlton IBM RJ Antoniadis et al., Continuous MOFET Performance Inc with Scaling - Strain & Channel Matl (2006) 16 8 MSE 310/ECE 340 Bandgap Engineering for Light Emitting Devices Electrical Properties of Materials Type 1 Type 2 Type 3 Herbert Kroemer, Nobel Lecture: Quasielectric fields and band offsets: teaching electrons new tricks*, REVIEWS OF MODERN PHYSICS, VOLUME 73, JULY 2001, *The 2000 Nobel Prize in Physics was shared by Zhores I. Alferov, Jack S. Kilby, and Herbert Kroemer. This lecture is the text of Professor Knowlton Kroemer’s address on the occasion of the award. MSE 310/ECE 340 Electrical Properties of Materials Knowlton Anderson & Anderson, Fundamentals of Semiconductor Devices, (McGraw Hill, 2005) Ch. 6.3 p. 317-331 Bandgap Engineering: Three types Note that the band offsets are not the same! 17 Heterojunctions – Type 2 & 3 18 9 MSE 310/ECE 340 Electrical Properties of Materials Knowlton MSE 310/ECE 340 Electrical Properties of Materials Knowlton Tunnel FET (TFET) IRPS Datta HTFET for Energy Efficient Computing 2013 19 Tunnel FET (TFET) Mayberry-Intel Pushing Past Frontiers of Technology final [3 2013] 20 10 MSE 310/ECE 340 Electrical Properties of Materials Part 5: Quantum Effects in MOS Devices Quantization: (cont.) 2D gas in channel SOI Gate-all-around (GAA) MOSFET: Gate-All-Around (GAA) MOSFET is an SOI transistor in which the gate oxide and the gate electrode are wrapped around the channel region. Fabricated using an SOI CMOS process to which two process steps are added a photolithographic step a wet etch step during which a cavity is formed under previously patterned silicon islands. The remarkable features of this MOSFET are that there are two channels (at the top and the bottom of the silicon film, The entire channel area is surrounded by good-quality gate oxide and the gate electrode. Knowlton Colinge & Colinge, S/C Devices 21 11