Effect of late Cenozoic aridification on sedimentation in the Eastern Cordillera of northwest Argentina (Angastaco basin) Sharon Bywater-Reyes1, Barbara Carrapa1, Mark Clementz1, and Lindsay Schoenbohm2 1 Department of Geology and Geophysics, University of Wyoming, 1000 E University Avenue, Laramie, Wyoming 82071, USA School of Earth Sciences, Ohio State University, 275 Mendenhall Laboratory, 125 South Oval Mall, Columbus, Ohio 43210, USA 2 75° W 70° W 65° W A 25°30' S ABSTRACT This study evaluates the effect of climate on facies, grain size, and sedimentation rates using sedimentology, geochronology, and stable isotope geochemistry for Miocene–Pliocene deposits in the Angastaco basin (Eastern Cordillera, northwest Argentina). U-Pb zircon data from ash layers constrain the transition between the finer grained fluvial-lacustrine Palo Pintado Formation and the coarser grained fluvial-alluvial San Felipe Formation to ca. 5.2 Ma and the first deposition of sediment derived from the present-day orographic barrier to ca. 4 Ma. δ13C values from pedogenic carbonate nodules range from −15.4‰ to −10.2‰ for the Palo Pintado Formation and from −9.5‰ to −8.2‰ for the San Felipe Formation; this can be best explained by increased, sustained aridity since ca. 5 Ma. The δ18O values range from −9.6‰ to −5.9‰ for the Palo Pintado Formation and from −6.1‰ to −5.2‰ for the San Felipe Formation, corroborating this interpretation. The shift toward more arid conditions correlates with a significant increase in grain size but no significant change in sedimentation rate. Because aridity precedes the development of an orographic effect, we interpret the grain size increase in the Angastaco basin since ca. 5 Ma to be a response of the sedimentary system to aridification resulting from regional climate change. INTRODUCTION A major challenge in determining the interaction of climate and tectonics on erosion and deposition is measuring all the variables that affect these processes (e.g., Molnar, 2009). In the Central Andes of northwest Argentina, late Cenozoic conglomerates are preserved along the margin of the Puna Plateau in a series of basins. One such basin, the Angastaco (Fig. 1), has a well-understood structural history (e.g., Carrera and Muñoz, 2008; Trimble et al., 2008), allowing for comparison between tectonics and the sedimentary record. The aim of this study is to evaluate important variables affecting sedimentation via sedimentology, U-Pb geochronology, and stable isotope geochemistry in order to determine, for the Angastaco basin in the Miocene–Pliocene, whether there is a correlation between deposition of coarse fluvial-alluvial deposits and climate, or whether local tectonics can explain the grain size increase. This study comes to the conclusion that, although the basin was affected by deformation during the Miocene–Pliocene (Carrera and Muñoz, 2008), deposition of coarse-grained deposits in the Angastaco basin is a function of climate, and not tectonics. GEOLOGICAL SETTING The Angastaco basin preserves >6 km of Eocene–Pliocene continental clastic strata of the Payogastilla Group (e.g., Díaz and Malizzia, 1983; B Angastaco Basin Range sin ra Ba Cerro Negro Balbuena Subgroup (Cretaceous-Eocene) Puca Santa Barbara Subgroup (Paleocene) ange Luracatao R Measured section Cumbres de Anticline 25°45' S 25° S Thrust nge Syncline Angastaco Ra dos lora 400 km s Co e lo 20° S ra d Sier 15° S N Pirgua Subgroup (Cretaceous) Intrusive basement (Neoproterozoic-Ordovician) San Carlos 4 km Puncaviscana Fm. (Precambrian-Paleozoic) 66°15'W 66°00'W Figure 1. A: General map of Andes with tectonomorphic domains. B: Geologic map of Angastaco basin and vicinity (modified from Coutand et al., 2006) indicating location of measured stratigraphic sections. © 2010 Geological Society of America. For permission to copy, contact Copyright Permissions, GSA, or editing@geosociety.org. GEOLOGY, March 2010 Geology, March 2010; v. 38; no. 3; p. 235–238; doi: 10.1130/G30532.1; 2 figures; Data Repository item 2010064. 235 Starck and Vergani, 1996). The basin is bounded to the west by an east-vergent reverse fault placing the Precambrian–early Cambrian metasedimentary Puncoviscana Formation over the Cenozoic basin strata. To the east, a west-vergent reverse fault places Cretaceous rocks of the Sierra de los Colorados over the basin strata (Fig. 1B; e.g., Carrera and Muñoz, 2008). Starck and Anzotegui (2001) interpreted the middle to upper Miocene fluvial-lacustrine strata of the Palo Pintado Formation to reflect a period of increased humidity coinciding with the onset of the South American monsoon ca. 9 Ma. A poorly documented source-area shift within the San Felipe Formation, which overlies the Palo Pintado Formation, has been linked to uplift of the Sierra de los Colorados to the east and development of orographic aridity within the basin (Coutand et al., 2006). locations within the lower San Felipe Formation, and 5 locations within the upper San Felipe Formation (n = 100 for each location; Fig. 2C). Average clast compositions within the Palo Pintado Formation and lower San Felipe Formation consist mainly of metamorphic, intrusive, volcanic, and clastic sedimentary rocks characteristic of lithologies exposed in ranges to the west and southwest. A marked change in clast composition occurs between the lower and upper San Felipe Formation with the first occurrence of limestone clasts, which are only exposed in ranges to the east (Fig. 1B; Sierra de los Colorados; Hongn et al., 1999). From these data, it can be deduced that the Sierra de los Colorados was not a source of sediment for the basin until upper San Felipe Formation time (ca. 4 Ma; see discussion of U-Pb geochronology). SEDIMENTOLOGY Nine stratigraphic sections were measured within the Angastaco basin in order to determine depositional environment (Fig. 1B; our own work). The Palo Pintado Formation consists of ~2000 m of trough crossstratified sandstones interpreted by us as fluvial channel sand bodies (e.g., Davis, 1983) interbedded with green ripple- and planar-laminated mudstones interpreted as associated lacustrine and floodplain deposits (e.g., Allen, 1970; Miall, 1996). Overall, facies associations indicate that the Palo Pintado Formation was deposited within a relatively fine grained, nonmarine setting with meandering rivers, floodplains, and lakes. The San Felipe Formation is transitional with the Palo Pintado Formation, and consists of ~650–1000 m of clast-supported cobble conglomerates and coarse sandstones with crude horizontal stratification and occasional imbrications. In contrast to the Palo Pintado Formation, we interpret the San Felipe Formation strata as higher energy, high-density stream flows deposited in an ephemeral fluvial to alluvial fan environment (e.g., Stanistreet and McCarthy, 1993; DeCelles et al., 1991). Paleocurrents Paleocurrents were measured along measured stratigraphic sections from trough cross-stratification axes and clast imbrication directions at 12 locations within the Palo Pintado Formation, 23 locations within the lower San Felipe Formation, and 7 locations within the upper San Felipe Formation (n = 10 for each location; Fig. 2C). Average flow directions for the Palo Pintado, lower San Felipe, and upper San Felipe Formations are northeast, east, and southwest, respectively. These measurements corroborate provenance data and convincingly show that the Sierra de los Colorados was not a source of sediment for the basin until upper San Felipe Formation time. Provenance Conglomerate provenance analyses were conducted along measured stratigraphic sections at 4 locations within the Palo Pintado Formation, 18 U-Pb ZIRCON GEOCHRONOLOGY OF ASHES We collected two samples from ash beds from the Palo Pintado Formation and seven from the San Felipe Formation (see the GSA Data Repository1 and Table DR1). Zircons were analyzed for 206Pb/238U dates (see the Data Repository) in order to determine geochronologic age (Fig. 2D; Table DR1) and deposition rate (Fig. 2D). These dates constrain the timing of the transition from the Palo Pintado Formation to the San Felipe Formation to ca. 5.2 Ma (interpolated using a constant sedimentation rate and the dates of two ashes, AT7–1 and AT2–2; Table DR1) and the timing of the Palo Pintado Fm. lower San Felipe Fm. upper San Felipe Fm. Figure 2. A: Stable isoB Generalized A Stable isotope C Paleocurrent D Geochronologic tope values of pedogenic values stratigraphy age (Ma) and provenance carbonate nodules and 8 7 6 5 4 3 2 rodent incisor enamel plotted as error weighted 2000 m 0.25 mm/yr means (Tables DR3, DR4; for more informa0.20 mm/yr 13 C Nodule tion, see the Data Repos18 1.64 mm/yr O Nodule 0.14 mm/yr 13 itory [see footnote 1]). C Enamel 18 VPDB—Vienna Peedee O Enamel 1.58 mm/yr belemnite. B: General0.49 mm/yr ized stratigraphy show1000 m ing Palo Pintado Forma0.34 mm/yr tion, lower San Felipe Formation, and upper San Felipe Formation 0.32 mm/yr boundaries in bold black Phyllite/ Gneiss lines; mr—mudrock; fs— Quartzite fine sandstone; ms—meIntrusive Schist dium sandstone; gr— Volcanic Limestone 0m granule conglomerate; mr -16 -14 -12 -10 -8 -6 -4 Clastic fs Quartz ms cgl—cobble conglomerSedimentary gr (‰) V-PDB ate. C: Respective avercgl age paleocurrent and conglomerate clast count data for three formations. D: Geochronologic age with 2σ error (see Table DR1 and the Data Repository) versus generalized stratigraphy (note that the youngest age, 2.3 ± 0.02 Ma, is from John Trimble [2009, personal commun.]); sedimentation rate (in mm/yr) is shown. Data presented here indicate increasing aridity within basin starting ca. 6 Ma and sustained by ca. 5 Ma (A) correlating with increase in grain size (B). These changes occur prior to significant changes in paleocurrent and provenance data (C), indicating that aridity and grain size increase occur prior to uplift of Sierra de los Colorados, and with no significant change in sedimentation rate (D). 1 GSA Data Repository item 2010064, description of analytical procedures, further discussion, and tables of raw analytical data, is available online at www.geosociety.org/pubs/ft2010.htm, or on request from editing@geosociety.org or Documents Secretary, GSA, P.O. Box 9140, Boulder, CO 80301, USA. 236 GEOLOGY, March 2010 first appearance of sediments derived from the Sierra de los Colorados and the paleocurrent shift to ca. 4 Ma (interpolated using a constant sedimentation rate and the dates of two ashes, AT6–7 and AT6–1; Table DR1). The possibility of the grain size shift representing a time-transgressive progradation of coarse material into the basin was ruled out (for discussion, see the Data Repository). Calculated sedimentation rates are displayed in Figure 2D. Throughout the Palo Pintado Formation and over the transition to the San Felipe Formation sedimentation rates do not change significantly, changing from 0.32 ± 0.02 mm/yr to 0.34 ± 0.05 mm/yr, and finally to 0.49 ± 0.05 mm/yr over the formation boundary. The sedimentation rates throughout the San Felipe Formation are much more varied, changing from 0.49 ± 0.05 mm/yr to 1.58 ± 0.15 mm/yr, 0.14 ± 0.03 mm/yr, 1.64 ± 0.95 mm/yr, 0.20 ± 0.02 mm/yr, and finally to 0.25 ± 0.02 mm/yr. We propose that this variability is inherent to the depositional system: the higher sedimentation rates represent short-term high-flux events within the alluvial fan system, whereas the lower sedimentation rates represent times of depositional hiatus between these events. Although the sedimentation rates for the San Felipe Formation are more varied, on average they are not significantly different, suggesting that the increase in grain size was not accompanied by a significant increase in average sedimentation rate, and presumably source erosion rate. The lack of a distinct change over the transition from the finer-grained fluvial-lacustrine Palo Pintado Formation to the coarser-grained fluvialalluvial lower San Felipe Formation suggests that neither subsidence nor sediment supply was controlling grain size distribution at this time, and that an external forcing, such as change in source rock or climate, was (Paola et al., 1992). Because no known change in source rock occurred during the transition of interest, climate is favored as the primary control. STABLE ISOTOPE ANALYSIS Pedogenic Carbonate Nodules In order to evaluate the late Cenozoic paleoenvironment, stable isotope analyses were performed on pedogenic carbonate collected from 11 stratigraphic locations along measured stratigraphic sections (Table DR2 in the Data Repository). δ13C and δ18O values (Vienna Peedee belemnite, VPDB) are reported as error-weighted means and range, respectively, from −15.4‰ to −10.2‰ and −9.6‰ to −5.9‰ for the Palo Pintado Formation and from −9.5‰ to −8.2‰ and −6.1‰ to −5.2‰ for the San Felipe Formation (Fig. 2A; Table DR2). δ13C values of pedogenic carbonate reflect, in part, the proportion of plants in an ecosystem that used either the C3 photosynthetic pathway (e.g., most plants as well as grasses from regions with cool growing seasons) versus those that use the C4 photosynthetic pathway (e.g., warm growing season grasses; O’Leary, 1988; Farquhar et al., 1989). Carbon isotope values for C3 plants growing today range from −30‰ to −25‰ and are typically lower than δ13C values for C4 plants (−13‰ to −11‰) (Kohn and Cerling, 2002). Typically, carbonate precipitated in a completely C3 environment can be as high as −10‰, and carbonate precipitated in a completely C4 environment can be as low as −8‰ (Cerling, 1984; Cerling et al., 1989). As plants become stressed, respiration rates slow, allowing the diffusion of atmospheric CO2 to greater soil depth, which results in higher δ13C values of pedogenic carbonates (Garzione et al., 2008). δ18O values of pedogenic carbonate reflect the combined effects of temperature and soil water composition, which is related to precipitation composition (Koch, 1998). As precipitation moves inland and through increasing elevation, the heavy isotope of oxygen, 18O, is preferentially removed, leaving the remaining precipitation depleted in this species; thus there is a predictable relationship between δ18O and elevation. If soil waters are evaporatively enriched (light species, 16O, evaporates), this relationship may be overprinted (Faure, 1977). The δ13C values in the Palo Pintado Formation suggest a C3 woodland or montane C3 grassland environment (Cerling et al., 1993). The GEOLOGY, March 2010 increased range in δ13C values (5.3‰) in the upper part of this formation suggests a shift from wetter conditions at the base to a mosaic habitat with significant spatial heterogeneity in vegetation type. At the very top of the Palo Pintado Formation and through the San Felipe Formation, δ13C values become more positive, which suggests either contribution from C4 plants or increasingly stressed conditions, and these higher values are associated with a significant decrease in total range (1.3‰), which implies that the environment was becoming less varied spatially. Likewise, the δ18O values in the Palo Pintado Formation are initially low (−9.6‰) but increase ca. 6 Ma (−5.9‰); aside from a few high values (−4‰), this is maintained through the remainder of this formation and into the San Felipe Formation. As with the carbon isotope values, variation in δ18O values in the San Felipe Formation (1.3‰) is much less than that determined for the Palo Pintado Formation (3.7‰); this suggests that environmental conditions had stabilized during this depositional period. These higher δ18O values and the significant correlation (see the Data Repository) between δ13C and δ18O values for the Palo Pintado Formation (Pearson Product Moment [PPM], r = 0.549, P = 0.03) and San Felipe Formation (PPM, r = 0.615, P = 0.01) support an interpretation of progressive aridification starting ca. 6 Ma, with sustained aridity by ca. 5 Ma. Fossil Rodent Enamel Enamel from fossil rodent incisors was sampled from 75 m below and 84 m above the Palo Pintado Formation–San Felipe Formation transition and was analyzed for δ13C and δ18O values (VPDB) in order to evaluate the presence of C3 versus C4 plants (Table DR4; for discussion, see the Data Repository). The values from below the transition indicate the predominance of C3 plants, whereas the values above the transition indicate C4 grasses or 13C-enriched plants that perform Crassulacean acid metabolism (CAM) during photosynthesis (e.g., cacti and other succulents; Kluge and Ting, 1978; Osmond, 1978) made up at least 35% and possibly as much at 87% of the diet of these rodents (see the Data Repository). This indicates that prior to ca. 5 Ma, C4 and CAM plants were not present in any substantial quantity. Therefore, the trend in stable isotope values of samples older than ca. 5 Ma (from the Palo Pintado Formation) can be attributed to a change in environmental stress on resident C3 plants. C4 grasses and CAM plants generally take advantage of arid conditions, since they can tolerate drier conditions than C3 grasses, so it seems reasonable that the ecosystem would be replaced by C4 grasses or include a greater proportion of CAM plants as conditions became drier (Ehleringer et al., 1997). For a discussion of δ18O values, see the Data Repository. DISCUSSION AND CONCLUSIONS Provenance and paleocurrent data demonstrate that the eastern basinbounding range, the Sierra de los Colorados, was not a sediment source for the Angastaco basin until ca. 4 Ma, suggesting that it did not exhibit the relief necessary to inhibit moisture as an orographic barrier until that time. The timing of the shift from the fluvial-lacustrine Palo Pintado Formation to the fluvial-alluvial San Felipe Formation is constrained to ca. 5.2 Ma. Sedimentation rates, and presumably source erosion rates, did not change significantly for the studied time interval. This suggests that tectonic subsidence and change in sediment supply are not controlling grain size distribution (Paola et al., 1992) and that, in the case of the Angastaco basin, aridity is not associated with a significant increase in sedimentation, and thus erosion, rates (e.g., Molnar, 2001). Since formation of the eastern orographic barrier and structural deformation are not synchronous with the initiation of coarse-grained deposition in the Angastaco basin, another mechanism is required. Stable isotope data from pedogenic carbonates demonstrate relatively more humid conditions prior to ca. 6 Ma, consistent with previous interpretations (e.g., Starck and Anzotegui, 2001). Aridity increased in the basin since ca. 6 Ma, with sustained aridity by ca. 5 Ma, synchronous with the 237 shift from fine-grained fluvial-lacustrine deposition to coarse-grained fluvial-alluvial deposition ca. 5.2 Ma, suggesting a genetic link between climate and change in facies. Stable isotope values of fossil rodent incisor enamel reveal the expansion of C4 plants synchronous with aridity and increased grain size ca. 5 Ma. Expansion of glaciation, particularly of the West Antarctic Ice Sheet ca. 5–6 Ma, is linked to an increase in aridity in Chile (e.g., Lamb and Davis, 2003; Hepp et al., 2006). Regional climatic changes are thus likely to have affected the Angastaco basin. The data presented here show a temporal link between the onset of coarse-grained fluvial-alluvial deposition in the Angastaco basin and regional climatedriven aridification, supporting a cause-and-effect relationship between climate and deposition of coarse clastics. ACKNOWLEDGMENTS The National Science Foundation funded this research (grant EAR-0635630). The ion microprobe facility at UCLA is partly supported by a grant from the Instrumentation and Facilities Program, Division of Earth Sciences, National Science Foundation. We thank Shikha Sharmathe and the University of Wyoming Stable Isotope Facility. We also thank Snehalata Huzurbazar, Peter DeCelles, Paul Heller, Peter Molnar, Andrew Leier, Gregory Hoke, Nicoletta Mancin, and an anonymous reviewer for constructive criticism. Laura Vietti is kindly acknowledged for field support and Tim Reed for analytical support. 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Trimble, J., Carrapa, B., Stockli, D., and Stutz, J., 2008, New constraints on the timing and magnitude of deformation and basin exhumation in the Eastern Cordillera of NW Argentina: American Geophysical Union, Fall Meeting 2008, abs. T53B–1925. Manuscript received 16 July 2009 Revised manuscript received 8 October 2009 Manuscript accepted 14 October 2009 Printed in USA GEOLOGY, March 2010