TECTONIC SETTING OF MESOZOIC MAGMATISM AND RELATED MINERALIZATION IN THE MIDDLE AND LOWER YANGTZE RIVER VALLEY, EASTERN CHINA by Chao Li A Thesis Submitted to the Faculty of the DEPARTMENT OF GEOSCIENCES In Partial Fulfillment of the Requirements for the Degree of MASTER OF SCIENCE In the Graduate College THE UNIVERSITY OF ARIZONA 2008 3 TABLE OF CONTENTS LIST OF FIGURES...........................................................................................................5 LIST OF TABLES.............................................................................................................8 ABSTRACT........................................................................................................................9 1. Introduction .........................................................................................................10 2. Timing of the subduction of the paleo-Pacific plate .................................12 3. Location of magmatic activities .....................................................................16 4. Mechanism of flat subduction ........................................................................17 5. Yanshanian Magmatism ..................................................................................20 5.1 Rock types ..........................................................................................................20 5.2 Major Elements..................................................................................................24 5.3 REE ....................................................................................................................29 5.4 Trace elements ...................................................................................................29 5.5 Nd and Sr isotope compositions ........................................................................30 5.6 Lead isotope compositions.................................................................................32 6. Discussion .............................................................................................................37 7. Conclusions ..........................................................................................................38 REFERENCES.................................................................................................................39 APPENDIX A: K-Ar Age Data of Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley……...……………………..………………………….……44 4 APPENDIX B: Age Data of Ore Deposits in the Middle and Lower Yangtze River Valley……...…………………………………………………...………..…………49 APPENDIX C: Major Elements Compositions for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley……...……………………..…………51 APPENDIX D: Rare Earth Elements Concentrations for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley………………………..……….....70 APPENDIX E: Trace Elements Concentrations for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley…………………………...……….….80 APPENDIX F: Nd and Sr Isotopic Data for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley……………………………………...…………86 APPENDIX G: Lead Isotope Data for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley…………….……………………………….....……94 REFERENCES...............................................................................................................100 5 LIST OF FIGURES Figure 1 Distribution of polymetallic deposits and Yanshanian magmatism in the Middle and Lower Yangtze River Valley. ..........................................................................11 Figure 2.K-Ar age distribution of Mesozoic igneous rocks in the Middle and Lower Yangtzer River Valley. ..........................................................................................13 Figure 3. Age distribution of Mesozoic ore deposits in the Middle and Lower Yangtzer River Valley ..........................................................................................................13 Figure 4. Temporal and spacial distribution of Mesozoic magmatism in the southeastern China . ...................................................................................................................14 Figure 5. Jurassic magmatism and accretionary complex belts in East Asia ..................14 Figure 6 Subduction velocities of Izanagi plate and Pacific plate relative to fixed Eurasia plate.......................................................................................................................18 Figure 7 QAP diagrams of Yanshanian plutonic igneous rocks in the Middle and Lower Yangtze River Valley.............................................................................................21 Figure 8 TAS diagram for Yanshanian volcanic rocks in the Middle and Lower Yangtze River Valley. .........................................................................................................21 Figure 9 Diagrams of contents of SiO2 vs. major elements of igneous rocks in the Middle and Lower Yangtze River. .....................................................................................22 Figure 10 K2O vs. SiO2 diagram of the igneous rocks in the Middle and Lower Yangtze River Valley. .........................................................................................................23 Figure 11 SiO2 vs. FeO* / (FeO* + MgO) diagram of the igneous rocks in the Middle and Lower Yangtze River Valley..................................................................................23 6 Figure 12 FeO / MgO vs. SiO2 of Yanshanian igneous rocks diagram in the Middle and Lower Yangtze River Valley..................................................................................24 Figure 13 AFM diagram of the Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley.............................................................................................24 Figure 14 REE diagrams of seven districts in the Middle and Lower Yangtze River Valley....................................................................................................................25 Figure 15 Spider diagrams of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley.............................................................................................26 Figure 16 Y vs. Nb diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley.............................................................................................27 Figure 17 Y + Nb vs. Rb diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley ............................................................................................27 Figure 18 Trace element of Yb vs. Ta discrimination diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Vally .............................................28 Figure 19 Ta / Yb vs. Th / Yb covariation diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley ..............................................................28 Figure 20 Isotopic compositions of Nd and Sr of Mesozoic intrusions in the Middle and Lower Yangtze River Valley..................................................................................30 Figure 21 Isotope composition of Nd and Sr of Mesozoic igneous rocks in the Middle and Lower Yangtzer River Valley. .......................................................................................31 Figure 22 Isotope ratios of lead from Yanshannian igneous rocks in the middle and lower Yangtzer River Valley. ..........................................................................................33 7 Figure 23 Isotope ratios of lead from Yanshannian igneous rocks in the middle and lower Yangtzer River Valley.. .........................................................................................34 8 LIST OF TABLES Table 1 The mixing parameters used in Figure 21............................................................31 Table 2 Three genetic models and their corresponding tectonic settings..........................38 9 ABSTRACT Mesozoic magmatism in the vicinity of the Middle and Lower Yangtze River hosts one of the most important metallogenic belts in China with more than 200 polymetallic (Cu, Fe, Au, Mo, Ag, W, Zn, Pb) deposits. Understanding the setting and origin of Mesozoic magmatism in the region is critical to understanding the origin of the polymetallic deposits in the Middle and Lower Yangtze River Valley. A new synthesis of isotope geochemical data and trace element data suggest that the Yanshanian granitoids originated from the mixture of the mantle and the lower crust, involving little if any material from the upper crust. Furthermore, geological data in the Middle and Lower Yangtze River Valley imply that the subduction of Paleo-Pacific plate underneath the Eurasian plate might have been the main tectonic drive, similar to other continental margin orogens around the world. 10 1. Introduction Yanshanian (160-100 Ma) extensive granitoid magmatism of the Middle and Lower Yangtze River Valley in east-central China is associated with more than 200 polymetallic (Cu, Fe, Au, Mo, Ag, W, Zn, Pb) deposits, forming one of the most important metallogenic belts in China (Figure 1). Patterns in magmatism and mineralization have been recognized and emphasized since the 1950s by Chinese geologists (Chang et al., 1991; Shu et al., 1992; Wang et al., 1987; Zhai et al., 1992). However, the mechanism of Mesozoic extensive magmatism in the Middle and Lower Yangtze River Valley remains controversial and continues to be vigorously debated in the literature (Xing and Xu, 1999; Deng et al., 1992, Wang et al., 2001, Zhang et al., 2001). There are several different tectonic events proposed to lead to Yanshanian magmatism in this region. The main models include subduction of the Paleo-Pacific plate (Deng et al., 1992; Li and Li, 2007; Pan and Dong, 1999; Pei and Hong, 1995; Wang et al., 2004; Wu et al., 1982; Yang, 1999; Zhou and Li, 2000), reactivation of the Changjiang fracture zone (Qi, 1998; Qi et al., 2002; Xing and Xu, 1999), and delamination and mafic magmatic underplating in a continental crust extensional setting (Wang et al., 2007; Wang et al., 2001; Zhang et al., 2001). In this paper, we investigate the possibility that subduction of the paleo-Pacific plate beneath the Eurasian plate during the Mesozoic induced extensive magmatism and related metallogenesis in the Middle and Lower Yangtze River Valley. Some geologists argue against the model of subduction of the Paleo-Pacific plate because of two evident points (Li, 2000; Zhang et al., 2001). First, they argue that 11 Figure 1. Distribution of polymetallic deposits and Yanshanian magmatism in the Middle and Lower Yangtze River Valley (original data from China 1:500000 digital geological map database). subduction of the paleo-Pacific plate underneath the Eurasian plate did not begin until Cretaceous (Shao et al., 1999; Xu et al., 1993; Zhang et al., 2001). The time is late than the beginning time of magmatic activity in this region, which is Middle Jurassic (Xing and Xu, 1999). Second, they argue that the location of magmatic activity in the Middle and Lower Yangtze River is unrealistically far away from the trench, about 1000 km (Li, 2000). In active arc-trench systems, the distance from trench axis to main magmatic front normally varies from as little as 75 km to as much 400 km (Dickinson, 1973; Hatherton and Dickinson, 1969) and magmatism linked to a subduction boundary can exist far inland, as for example in the Laramide province of the western United States (Coney and Reynolds, 1977). 12 This study synthesizes the published geological and geochemical characteristics and investigates the temporal, spatial, and genetic relationship of subduction of paleopacific plate and Yanshanian magmatism in the Middle and Lower Yangtze River Valley and discusses a tectonic model based on subduction of paleo-Pacific plate. 2. Timing of the subduction of the paleo-Pacific plate The data compiled for this study demonstrate that extensive Yanshanian magmatism in the Middle and Lower Yangtze River Valley occurred between 175 Ma and 95 Ma, peaking in the period of 145 Ma to 120 Ma (Figure. 2). Related Cu-Fe-AuMo polymetallic mineralization occurred from 160 Ma to 90 Ma, peaking in the range of 145 Ma to 120 Ma (Figure. 3). Presumably, if subduction of the paleo-Pacific plate was the principal drive for extensive magmatism and related mineral depositsin this region, subduction must have begun earlier than 175 Ma. The subduction of the Izagani plate underneath the Eurasian plate began no later than 145 Ma according to an analysis of plate motions (Engebretson et al., 1985). However, no practical constrain was given for the Jurassic period due to the lack of information. Because of lack of data for relative plate motions during 250 Ma – 180 Ma, the relative motions between oceanic plates and continental plates were estimated from the ages and locations of accretionary complexes and volcanic-plutonic activity in the continental margins. 13 !"#$%&'(")*+, 02 01 / . 34 0-4 004 014 054 0.4 044 024 7+,)89*: 064 0/4 034 1-4 104 Figure 2.K-Ar age distribution of Mesozoic igneous rocks in the Middle and Lower Yangtzer River Valley (n=146). Data listed in Appendix A 5 4 Frequency 3 2 1 0 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 185 190 195 200 205 210 215 220 More Age (Ma) Figure 3. Age distribution of Mesozoic ore deposits in the Middle and Lower Yangtzer River Valley( n=31) Data listed in Appendix B. 14 Figure 4. Temporal and spacial distribution of Mesozoic magmatism in the southeastern China (after Li et al., 2007). Figure 5. Jurassic magmatism and accretionary complex belts in East Asia (after Isozaki, 1997). 15 Between 205 and 180 Ma, there was no continental magmatism in the eastern China coastal region (Li et al., 2007). Maruyama et al. (1996) argue that this lack of continental magmatism was due to transcurrent motion of the Farallon Plate. Since 180 Ma, magmatic activity occurred along the eastern continental margins of the Eurasian plate. The typical examples include the Middle-Late Jurassic (ca 180-150 Ma) Daebo granite in the Korean Peninsula (Takahashi, 1983), the Middle Jurassic granitic rocks of the Hida belt in central Japan (Isozaki, 1997), and the Early Yanshannian (ca. 180-150 Ma) granitoids in the southeastern China (Cheng, 1986) (Figure 4). Maruyama and Seno (1986) argue that “The magmatism indicates that the active subduction of the Izanagi plate underneath the Eurasian plate took place along East Asia since 180 Ma.” In addition, a Jurassic accretionary complex occurs along the Japanese islands stretching for more than 3000 km from Ishigaki Island in the southern Ryukyus on the southwest, to western Hokkaido on the northeast, and for up to 200 km wide across-arc, and around 20 km thick (Isozaki, 1997) (Figure 5). Furthermore, microfossil dating data at thousands of localities indicate that the Jurassic accretionary complex in southwestern Japan grew predominantly in the Middle Jurassic (Isozaki, 1997). Combining information of magmatism and accretionary complex infers that the subduction of the paleo-Pacific plate underneath the Eurasian plate began at ca. 180 Ma. 16 3. Location of magmatism For several reasons the distance from magmatism activities to the trench was not over 1000 km (Li, 2000), rather it was less than 500 km in the Mesozoic. First, the distance of 1000 km is from Wuhan at the western end of the middle and lower Yangtze River valley to the modern trench. However, the Mesozoic convergent margin was the eastern coastal region of China. All marginal seas near the Eurasian plate including the Japan Sea, Bohai Sea, Donghai Sea, Huanghai Sea, and Nanhai Sea formed in Cenozoic (Maruyama et al., 1997). The width of the zone averagely ranges about 500 km. Therefore the distance from Wuhan to the Mesozoic trench should be ca. 500 km after subtracting the Cenozoic marginal seas’ width of 500 km. In addition, Isozaki’s research proposed that the eastern continental margin of the eastern Asia has grown toward ocean for ca. 200 km in width since the Jurassic (Isozaki, 1997). Therefore, the magmatism in this region should not have been any more than 500 km from the trench in Mesozoic. Although the distance from the magmatic front to the trench in Mesozoic was 500 km, it is still not usual for subduction zones. In active arc-trench systems, distance from the trench axis to the main magmatic front normally varies from as little as 75 km to 400 km (Dickinson, 1973; Hatherton and Dickinson, 1969). However, in flat subduction zones magmatism can generate at significant distance inboard of the trench (up to 1000 km). Although the mechanisms of flat subduction are not been fully established, it is agreed that flat subduction occurs, and is demonstrated for both modern and ancient convergent margins. Flat subduction is a relatively common at modern convergent 17 margins, occurring in 10% present-day subduction zones, including central Chile, central Mexico, Ecuador, NW Colombia, Costa Rica, Cascades, western New Guinea, and the Nankai Trough (Gutscher et al., 2000; Jarrard, 1986). Among these modern regions, flat subduction below south Peru is the best-known example, where the Nazca plate subducts with a ca. 14° dip angle to 100 km depth, bends back to zero dip angle, and moves up to 700 km inland (Gutscher et al., 2000; Jarrard, 1986; Sacks, 1983). The well-known example during geological time is that the large flat subduction was present below the Western United States around 65 Ma (Bird, 1988; Cross and Pilger Jr., 1978; Dickinson and Snyder, 1978). In this region, horizontal subduction was proposed to explain the inboard migration of the Laramide orogeny which extends over 1200 km from assumed marginal trenches during ca. 80-45 Ma (Coney and Reynolds, 1977; Livaccari et al., 1981). Some geologists proposed that flat subduction occurred in southeastern China in Mesozoic to explain ca. 1000 km wide magmatism (Li and Li, 2007; Zhou and Li, 2000), although it is contested. 4. Mechanism of flat subduction One of the probable mechanisms of flat subduction is subduction of oceanic plateaus, aseismic ridges or seamount chains because oceanic plateaus with thicker crust and underlying less-dense harzburgite layer could significantly reduce the buoyancy and the subduction of such abnormally buoyant topographic highs can produce a decrease in the dip of the subducted plate (Hunen et al., 2004). The classic examples are in Peru, Chile, and the Nankai trough. 18 250 Izanagi Normal Velocity ( km/m.y.) 200 150 100 50 Pacific 0 -50 175 150 125 100 75 50 25 0 Time (Ma) 200 Right Lateral Izanagi 100 Pacific 50 0 -50 Left Lateral Tangential Velocity (km/m.y.) 150 -100 175 150 125 100 75 50 25 0 T ime (Ma) Figure 6 Subduction velocities of Izanagi plate and Pacific plate relative to fixed Eurasia plate. Normal velocity and tangential velocity are respectively normalized velocities in 315 degree direction and in 45 degree direction. (data from Engebretson et al., 1985) 19 In Mesozoic, it was believed that there were many oceanic plateaus and seamounts in the paleo-Pacific ocean (Maruyama et al., 1997). Based on the evidence found in Jurassic and Early Cretaceous accretionary complexes, the prominent Mikabu oceanic plateau formed in the southern Pacific subducted underneath the eastern Asia plate in Early Cretaceous (Kimura, 1997; Maruyama et al., 1997), and the AkasakaKuzzu seamount swarm in the Izanagi plate subducted below the Asian plate in Middle Jurassic (ca. 180 Ma) (Maruyama et al., 1997). In addition, rapid convergence has also been suggested as a possible mechanism of flat subduction (Coney and Reynolds, 1977; Luyendyk, 1970). The dip angle of Benioff zone might be controlled by the relative velocity of the two converging plates based on a good correlation between the dip angle and the relative velocity (Luyendyk, 1970; Yokokura, 1981). The higher is the rate of convergence; the lower is the angle of dip. The analysis of relative plate motions in the Pacific domain attempted by Engebretson et al., (1985) indicates that the Eurasian plate and the Izanagi plate converged at very fast speed of 20-30 cm/y in the period of 135Ma to 85 Ma (Engebretson et al., 1985). The rapid convergence of the Izanagi plate and Eurasian plate might produce flat subduction in Mesozoic along the eastern Asian continental margin. Furthermore, extensive magmatism and relative metallogeny peaked in the period of 135125 Ma (Figure 2), which coordinates with the time of fastest speed of ca. 30 cm/y during 135 Ma to 127 Ma (Figure 6) (Engebretson et al., 1985). 20 5. Yanshanian Magmatism 5.1 Rock types Our synthesis of Yanshanian igneous compositions (Appendix C) in the Middle and Lower Yangtze River Valley shows that plutonic rock types include gabbrodiorite, diorite, quartz diorite, granodiorite, quartz monzodiorite, monzodiorite, monzonite, quartz monzonite, granite, and quartz porphyry (Figure 7). Based on analysis of size, shape, and evolution stages of plutons in this region, the main plutonic rock types are diorite, quartz diorite, granodiorite, and granite. Using the same method as plutonic rocks, we obtain that volcanic rock types include trachyte, andesite and trachyandesite (Figure 8). The main volcanic rock type is trachyandesite. Common ferromagnesian minerals in the igneous rocks are amphibole and biotite with a little pyroxene. 5.2 Major Elements Concentration of silica in Yanshanian igneous rocks in the middle and lower Yangtze River widely range from 48% to 77% (Appendix C). The characteristics of relationship of major elements and the silica in all igneous rocks are: 1) major elements of Fe, Mg, Ca, Ti, and P display right-dip curvilinear trends with systematic variation over the silica concentration (Figure 9); 2) major element of Al shows little change with variation of the silica concentration (Figure 9); 3) alkali elements of K and Na do not display well-defined linear relationship with systematic variation of the silica concentration (Figure 9). Yanshanian igneous rocks have high contents of K2O (mostly > 2 %, up to 5.4 %), classified as calc-alkaline, high K calc-alkaline rocks, even shoshonitic rocks (Figure 10). Most of them are high K series (Figure 10). In addition, Yanshanian 21 Quartz granite granodiorite Tonalite quartz monzodiorite quartz monzonite syenite quartz diorite monzodiorite monzonite diorite Alkali Feldspar Plagioclase Figure 7 QAP diagrams of Yanshanian plutonic igneous rocks in the Middle and Lower Yangtze River Valley. Data from Appendix C. 18 16 14 Na 2O + K 2O (wt%) 12 trachyte 10 trachyandesite 8 6 andesite 4 2 0 40 45 50 55 60 65 70 75 80 SiO 2 (wt%) Figure 8 TAS diagram for Yanshanian volcanic rocks in the Middle and Lower Yangtze River Valley. Data from Appendix C. 22 10 MgO (wt%) 8 6 4 2 0 50 55 60 65 70 75 80 15 5 12 4 TiO 2 (wt%) CaO (wt%) SiO 2 (wt%) 9 6 3 2 1 3 0 0 50 55 60 65 70 75 50 80 55 60 SiO 2 (wt%) 70 75 80 SiO 2 (wt%) 6 25 20 P2 O5 (wt%) Al2 O3 (wt%) 65 15 4 2 10 0 5 50 55 60 65 70 75 80 50 55 60 SiO 2 (wt%) 70 75 80 8 10 6 K2O (wt%) 8 Na 2O (wt%) 65 SiO 2 (wt%) 6 4 4 2 2 0 0 50 55 60 65 SiO2 (wt%) 70 75 80 50 55 60 65 70 75 80 SiO 2 (wt%) Figure 9. Diagrams of contents of SiO2 vs. major elements of igneous rocks in the Middle and Lower Yangtze River. Data from Appendix C. 23 8 K2 O (wt%) 6 Shoshonitic High-K calc-alkaline 4 Calc-alkaline 2 Tholeiitic 0 50 55 60 65 70 75 80 SiO 2 (wt%) Figure 10 K2O vs. SiO2 diagram of the igneous rocks in the Middle and Lower Yangtze River Valley. Data from Appendix C. 1.2 FeO*/(Feo*+MgO) Tholeiite series 1.0 0.8 0.6 0.4 0.2 Calc-alkaline series 0.0 40 50 60 SiO 2 (wt%) 70 80 Figure 11 SiO2 vs. FeO* / (FeO* + MgO) diagram of the igneous rocks in the Middle and Lower Yangtze River Valley. Data from Appendix C. 24 5 FeO*/MgO 4 Tholeiite Series 3 Calc-alkaline Series 2 1 0 45 50 55 60 65 70 75 80 SiO2 (wt %) Figure 12 FeO / MgO vs. SiO2 of Yanshanian igneous rocks diagram in the Middle and Lower Yangtze River Valley. Data from Appendix C. FeO* Tholeiite Series Calc-alkaline Series Na2O+K 2O MgO Figure 13 AFM diagram of the Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley. Data from Appendix C. 25 1000 1000 Anqing-Guichi Rocks/Chrondrite (C1) Rocks/Chrondrite (C1) Edong 100 10 100 10 1 1 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y 1000 1000 Luzong Rocks/Chrondrite (C1) Rocks/Chrondrite (C1) Jiurui 100 10 100 10 1 1 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 1000 Y 1000 Ningzhen Rocks/Chrondrite (C1) Ningwu Rocks/Chrondrite (C1) Y 100 10 100 10 1 1 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y 1000 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y 1000 Rocks/Chrondrite (C1) Tongling 100 100 10 10 1 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y 1 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Figure 14. REE diagrams of seven districts in the Middle and Lower Yangtze River Valley. Data from Appendix D. 26 Rocks/Chrondrite (C1) 1000 100 10 1 Rb Ba Th U Ta Nb K 1000 La Ce Sr Nd Sm Y 10000 Edong Ningwu Rocks/Chrondrite (C1) Rocks/Chrondrite (C1) 1000 100 10 100 10 1 1 Rb Ba Th U Ta Nb K La Ce Sr Nd Sm Y Rb 1000 Ba Th U Ta Nb K La Ce Nd Sm Y Ningzhen Rocks/Chrondrite (C1) Tongling Rocks/Chrondrite (C1) Sr 1000 100 10 1 100 10 1 Rb Ba Th U Ta Nb K La Ce Sr Nd Sm Y Rb Ba Th U Ta Nb K La Ce Sr Nd Sm Y Figure 15. Spider diagrams of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley. Data from Appendix E. 27 10000 Nb 1000 WPG 100 VAG+syn-COLG 10 ORG 1 1 10 100 1000 Y Figure 16. Y vs. Nb diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley (after Pearce et al., 1984). Abbreviations: WPG = within-plate granite; VAG = volcanic-arc granite; syn-COLG = syn-collisional granite; ORG = oceanridge granite. Data from Appendix E. 10000 Syn-COLG Rb (ppm) 1000 WPG 100 VAG 10 ORG 1 1 10 100 1000 10000 Y+Nb (ppm) Figure 17. Y + Nb vs. Rb diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley (after Pearce, 1996). Data from Appendix E. 28 100 WPG 10 Ta (ppm) syn-COLG 1 ORG 0.1 VAG 0.01 0.1 1 10 100 Yb (ppm) Figure 18. Trace element of Yb vs. Ta discrimination diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Vally (after Pearce et al., 1984). Data from Appendix E. 100 WPB VAB Th/Yb 10 1 0.1 0.01 0.01 MORB 0.1 1 Ta/Yb 10 100 Figure 19. Ta / Yb vs. Th / Yb covariation diagram of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley (after Pearce et al., 1981, Wood et al., 1979). Data from Appendix E. 29 igneous rocks have high contents of Na2O (average values over 4%) (Figure 9). Furthermore, FeO / (FeO + MgO), FeO / MgO vs. SiO2, and AFM diagrams indicate that Yanshanian igneous rocks are calc-alkaline (Figure 11, Figure 12, and Figure 13), the classic magma series occurring in convergent continental margins. 5.3 REE Yanshanian igneous rocks in the Middle and Lower Yangtze River show similar REE patterns (Figure 14). The REE patterns of all Yanshanian igneous rocks in this region are characterized by enrichment in LREE, deplete in HREE, and no or a little negative Eu anomaly (Figure 14). The total REE concentration in igneous rocks is high (Figure 14). The REE patterns of Yanshanian igneous rocks in the Middle and Lower Yangtze River Valley are similar to the patterns of igneous rocks emplaced along convergent continental margins (Wilson, 1997). 5.4 Trace elements Yanshanian magmatism in the Middle and Lower Yangtze River are enriched in large ion lithophile elements and depleted in high field strength elements (Figure 15). Spider diagrams of Yanshanian magmatism in this region (Figure 15) show that all igneous rocks are deplete in Ta and Nb. Geochemical diagrams based on key elements or element ratios have been much used to integrate magmatic geochemistry into the plate tectonic framework (Pearce, 1996). Bivariate diagrams of Y against Nb (Figure 16), Rb against (Y + Nb) (Figure 17), Ta against Yb (Figure 18), Ta/Yb against Th/Yb (Figure 19) indicate that Yanshanian magmatism occurred in volcanic arc setting (active continental margins). 30 5.5 Nd and Sr isotope compositions Diagram of εNd vs. ISr (Figure 20) shows those characteristics: 1) Shaxi intrusions in Luzong district and Anjishan intrusions in Ningzhen district lie in the enriched extension of the ‘mantle array’ defined by mantle-derived rocks; 2) Intrusions from Anqing-Guichi and Tongling districts shift to right away from the enriched extension of the ‘mantle array’; 3) Intrusions from Tongling are distinguished from other intrusions. They have higher initial 87Sr/86Sr ratios and lower εNd values. Based on the diagram of εNd vs. ISr (Figure 20), we infer the explanation: 1) Magma sources are mixture of mantle and lower crust; 2) Magma sources of intrusions in Tongling have more lower crustal 5 Ma eA n tl 0 contamination y rr a AFC Upper Crust !Nd -5 -10 -15 -20 Lower Crust -25 0.702 0.704 Anqing-Guichi 0.706 Edong 0.708 ISr Ningzhen 0.710 Tongling 0.712 0.714 Luzong-Shaxi Figure 20. Isotopic compositions of Nd and Sr of Mesozoic intrusions in the Middle and Lower Yangtze River Valley. The initial 87Sr/86Sr ratios are calculated assuming rocks crystallized at 130 Ma. Data from Appendix F. 31 T=130Ma 10 UM B 80 !Nd 0 60 80 40 80 -10 upper crust 60 40 UCC 40 -20 80 60 -30 -40 0.7 basalt lower crust 0.705 LCC 0.71 Anqing-Guichi Edong 0.715 ISr Luzong Ningwu 0.72 Ningzhen Tongling 0.725 Shaxi Figure 21. Isotope composition of Nd and Sr of Mesozoic igneous rocks in the Middleand Lower Yangtze River Valley. The initial 87Sr/86Sr ratio values are calculated assuming that rocks crystallized at 130 Ma. UM denotes upper mantle peridotites; UCC, upper continental crust (Taylor and McLennan, 1985); MCC-LCC, middle to lower crust (Rudnick and Fountain, 1995); Yangtze lower crust and upper continental crust (Jahn et al., 1999). The curves represent the mixtures of upper mantle peridotites with upper continental crust and lower continental crust, and the mixtures of basalt with upper continental crust and lower continental crust. The mixing parameters used are given in the table 1. Data from Appendix F. Table 1. The mixing parameters used in Figure 21. UM Basalt UCC MCC-LCC 0.703 0.704 0.72 0.71 Sr ppm 20 150 350 300 εNd 8 8 -10 -30 Sm ppm 0.42 3.5 5.2 4.8 Nd ppm 1.2 15 26 24 Sr/Nd 16.7 10 13.5 12.5 87 86 Sr/ Sr 32 material involved; 3) Magma of intrusions from Tongling and Anqing-Guichi material involved; 3) Magma of intrusions from Tongling and Anqing-Guichi districts have upper continental crustal contamination. From an extensive compilation of Nd and Sr isotopic compositions (εNd = 18.1— +2.7, ISr = 0.7046—0.71015), we argue that crustal contamination played a significant role either in the magma sources, or during magma ascent. The Nd-Sr isotopic compositions presented that the upper crust is not likely a good candidate as the major contaminant. A simple modeling (Figure 21) for source contamination indicates that mixing 90% of the upper mantle peridotite with about 10% of the lower crustal materials would explain the characteristics of Nd and Sr isotopic composition of the Yanshanian igneous rocks in this region. In addition, the higher Sr isotopic ratios of some igneous rocks from Tongling district, Anqing-Guichi district, and part of Ningwu district required that their sources might involve a little upper continental crustal materials (Figure 20). 5.6 Lead isotope compositions Lead isotope compositions (Figure 22 and Figure 23) of Yanshanian magmatism in the middle and Lower Yangtze Valley indicate the similar characteristics as Nd and Sr isotopes. The diagram of lead isotope ratios shows that magma resources are mixture of crust and mantle. In addition, lead isotope ratios require the upper crust involved in magma processes. In order to obtain the value of the upper crust involved in magmatism, 33 UC 15.6 50 Pb/ 207 80 90 204 Pb 15.8 70 95 80 M 15.4 90 Mesozoic basalt 80 LC MIX UC-LC MIX UC-LC-M MIX LC-M 15.2 16 17 18 206 Pb/ 204 19 20 Pb Figure 22. Isotope ratios of lead from Yanshannian igneous rocks in the middle and lower Yangtzer River Valley. Assumed that the ratios of lead of Mesozoic basalts represent those values of the mantle in the middle and lower Yangtze River Valley. The upper crust and lower crust growth curves are followed Zhang (Zhang et al., 1991). Data from Appendix G. 34 207Pb/ 204Pb 15.8 Pacific sediments Mesozoic basalt UC PS 15.6 M 15.4 LC 15.2 16 17 18 206Pb/ 204Pb 19 41 20 UC LC Mesozoic basalts 208Pb/ 204Pb 40 UC 39 38 LC 37 36 16.5 17 NHRL 17.5 18 18.5 206Pb/ 204Pb 19 19.5 Figure 23. Isotope ratios of lead from Yanshannian igneous rocks in the middle and lower Yangtzer River Valley. The upper crust and lower crust growth curves are followed Zhang (Zhang et al., 1991). Data from Appendix G. 35 Anqing-Guichi Pacific sediments Mesozoic basalt 15.6 15.4 17 18 19 UC PS M LC 18 206Pb/ 204Pb UC NHRL LC 17 17.5 18 18.5 206Pb/ 204Pb LC 18 206Pb/ 204Pb 19 UC PS LC 17 18 206Pb/ 204Pb 19 38 NHRL LC 37 17 17.5 18 18.5 206Pb/ 204Pb 20 19 19.5 Luzong UC LC Mesozoic basalts 40 M 15.4 UC 41 Pacific sediments Mesozoic basalt 19.5 UC LC Mesozoic basalts 39 36 16.5 20 Luzong 15.6 19 Jiurui 41 208Pb/ 204Pb 207Pb/ 204Pb UC LC Mesozoic basalts 40 M 17 19.5 Edong 37 36 16.5 20 UC PS 15.4 19 38 Pacific sediments Mesozoic basalt 15.8 207Pb/ 204Pb 19 15.6 15.2 16 17.5 18 18.5 206Pb/ 204Pb Jiurui 15.8 15.2 16 17 39 208Pb/ 204Pb 17 NHRL LC 37 40 208Pb/ 204Pb 207 Pb/ 204 Pb Pacific sediments Mesozoic basalt 15.6 15.2 16 38 41 Edong 15.4 UC 39 36 16.5 20 206Pb/204Pb 15.8 UC LC Mesozoic basalts 40 208Pb/ 204Pb 207Pb/ 204Pb 15.8 15.2 16 Anqing-Guichi 41 UC 39 38 LC 37 36 16.5 17 NHRL 17.5 18 18.5 206Pb/ 204Pb 19 19.5 Figure 23 . Isotope ratios of lead from Yanshannian igneous rocks in the middle and lower Yangtzer River Valley. The upper crust and lower crust growth curves are followed Zhang (Zhang et al., 1991). Data from Appendix G. 36 Ningwu UC PS M 15.4 LC 17 18 206Pb/ 204Pb 207Pb/ 204Pb 36 16.5 20 UC PS LC 17 18 206Pb/ 204Pb 17.5 18 18.5 206Pb/ 204Pb 19 19 Ningzhen 41 UC LC Mesozoic basalts UC 39 38 LC 37 36 16.5 20 19.5 17 NHRL 17.5 18 18.5 206Pb/ 204Pb 19 19.5 Tongling 15.8 Pacific sediments Mesozoic basalt LC 17 18 206Pb/ 204Pb 19 UC LC Mesozoic basalts 40 M 15.4 Tongling 41 UC PS 15.6 15.2 16 17 40 M 15.4 NHRL LC 37 Pacific sediments Mesozoic basalt 15.6 15.2 16 38 Ningzhen 15.8 207Pb/ 204Pb 19 UC 39 208Pb/ 204Pb 15.2 16 UC LC Mesozoic ba salts 40 208Pb/ 204Pb 15.6 Ningwu 41 Pacific sediments Mesozoic basalt 208Pb/ 204Pb 207Pb/ 204Pb 15.8 20 UC 39 38 LC 37 36 16.5 17 NHRL 17.5 18 18.5 206Pb/ 204Pb 19 19.5 Figure 23. Isotope ratios of lead from Yanshannian igneous rocks in the middle and lower Yangtzer River Valley. The upper crust and lower crust growth curves are followed Zhang (Zhang et al., 1991). Data from Appendix G. we accept the simple models of mixture of 90% of the mantle and 10% of the lower crust obtained by analysis of Nd and Sr isotope compositions. Then, we draw the mixing line 37 between the upper crust and the mixture of the lower crust and the mantle. Finally, it shows that magma sources may have 5% - 10% of the upper crust involved (Figure 22). The characteristics of Nd, Sr, and Pb isotope compositions indicate that the sources of Yanshanian magmatism in the Middle and Lower Yangtze River are mixture of most of the mantle (ca. 85%) and the crust (ca. 15%). There were not extensive crustal components although some plutons in the Tongling and Anqing-Guichi districts show crustal contamination. These isotopic data for Nd, Sr, and Pb are thus consistent with proposed subduction-related origin for Yanshanian magmatism, presumably along the active continental margin above the subducted paleo-Pacific plate. 6. Discussion The genetic models of Yanshanian magmatism in the Middle and Lower Yangtze River are controversial. The main three different models are subduction of the paleoPacific plate underneath the Eurasian plate, reactiviation of the Changjiang fracture zone, and the delamination and underplating in a continental crust extensional setting. We classify the three models into three corresponding tectonic settings (Table 1): active continental margins, rift (withinplate), post-collision (delamination) (Pearce, 1996). Geochemical characteristics of the Yanshanian magmatism in the region preclude the possibility of rift (withinplate). The distinct feature of the rift setting should be the principal rock types bi-model (basalt and rhyolite) rock types, instead granodiorites are typically in the Yangtze Valley. 38 Table 2 Three genetic models and their corresponding tectonic settings Genetic models Tectonic setting subduction of the Paleo-Pacific plate active continental margins deep fracture zone rift (within plate) delamination and underplating post-collision Post-collision granites are the most difficult to classify because they have the greatest range of sources. In addition, there is extensive interaction between the mantlederived sources and the crust (Pearce, 1996). However, the characteristics of Nd, Sr, and Pb isotope compositions indicate that the sources of Yanshanian magmatism in the Middle and Lower Yangtze River are mixture of the mantle (ca. 85%) and the crust (ca. 15%). Thus there appear to be no crustally-dominated magmas present, which would be expected with collisional granitoids. 7. 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K-Ar Age Data of Mesozoic Igneous Rocks in the Middle And Lower Yangtzer River Valley district name Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Echeng Echeng Echeng Echeng Echeng Echeng Echeng Tieshan Tieshan Tieshan Tieshan Tieshan Tieshan Tieshan Tonglushan Tonglushan Jinshandian Jinshandian Jinshandian Tongshankou Tongshankou Lingxiang Lingxiang Lingxiang Yinzu Yinzu Yinzu Longjiaoshan Yangxin mineral rock type wr wr bt wr wr bt hbl wr bt wr wr wr bt bt wr bt bt bt bt granite qtz monzonite granite porphyry qtz monzonite-monzogranite qtz monzonite-monzogranite granite granite granodiorite qtz syenodiorite pyx-bt diorite qtz syenodiorite qtz syenodiorite granodiorite diorite qtz diorite qtz syenodiorite porphyry qtz diorite monzogranite pyx diorite granodiorite granodiorite qtz diorite diorite diorite pyx diorite qtz diorite qtz diorite hbl qtz monzodiorite porphyrite granodiorite age quality references 132 127 118 109 134 121 126 157 138 150 123 132 106 156 145 127 142 115 109 127 153 157 93 143 153 160 150 118 157 5 5 5 5 5 5 5 3 5 5 5 5 5 5 5 5 5 5 5 3 3 5 5 5 5 5 5 5 5 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 Lu, 2003 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 Xia et al., 2003 Xia et al., 2003 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 Zhai et al., 1992 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 Hubei Geology, 1990 China Isotope Geology Conference, 1979 45 district name mineral rock type age quality references Edong Edong Edong Edong Edong Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Yangxin Yangxin Yangxin Yangxin Yangxin Chengmenshan Chengmenshan Chengmenshan Chengmenshan Chengmenshan Chengmenshan Chengmenshan Wushan Dingjiashan Yangjishan Fengshandong Fengshandong Jilongshan Tongshan Tongshan Tongshan Yueshan Huangtun Huangtun Huangtun Huangtun Huangtun Xiaoling Luohe Luohe Luohe wr wr bt bt fsp bt bt bt wr wr 153 156 140 139 152 148 155 142 120 118 112 146 147 146 205 126 106 138 139 150 135 138 125 128.1 124.9 79 128.8 125.7 100 102 140 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 3 5 4 4 5 5 5 5 5 5 5 5 5 5 wr bt bt wr bt wr wr wr wr bt bt bt wr qtz syenodiorite qtz syenodiorite qtz syenodiorite qtz syenodiorite granodiorite granodiorite granodiorite granodiorite quartz porphyry quartz porphyry qtz porphyry granodiorite porphyry granodiorite porphyry granodiorite porphyry granodiorite porphyrite hbl granodiorite porphyry granodiorite granodiorite granodiorite qtz diorite qtz diorite diorite diorite porphyrite hbl trachyandesite hbl trachyandesite trachyandesite porphyry hbl trachyandesite bt trachyte bt trachyte bt trachyte China Isotope Geology Conference, China Isotope Geology Conference, China Isotope Geology Conference, China Isotope Geology Conference, China Isotope Geology Conference, Wu et al., 1997 Wu et al., 1997 Wu et al., 1997 Wu et al., 1997 Wu et al., 1997 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Hubei Geology, 1990 China Isotope Geology Conference, Wu, 1992 zhou, 1997 Anhui Geology, 1988 Anhui Geology, 1988 Zhai et al., 1992 Zhai et al., 1992 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Yu et al., 1997 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 1979 1979 1979 1979 1979 1979 46 district name mineral rock type age quality references Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Luohe Shizishan Shizishan Shizishan Tongguanshan Tongguanshan Jingkouling Fenghuangshan Fenghuangshan Fenghuangshan Fenghuangshan wr bt bt wr wr wr bt wr sanidine wr wr bt wr wr bt bt wr wr wr wr bt bt wr wr wr wr bt bt bt bt wr 166 127 133 139 134.6 106.5 122.6 97.6 124.2 134.7 162.3 127.4 117 107 126.6 127.4 97.4 99.2 131.3 102.4 127.7 127 145 153 142.3 143 137 119 126 133 124 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 4 4 3 4 5 5 5 5 5 basaltic trachyandesite bt trachyte bt trachyte bt trachyte trachyandesite trachyandesite bt trachyandesite bt trachyandesite bt trachyandesite bt trachyte basaltic trachyandesite bt trachyte syenite porphyry bt-pyx monzonite porphyry syenite porphyry bt trachyandesite bt trachyandesite bt trachyandesite trachyandesite trachyandesite bt trachyandesite diorite diorite diorite porphyrite quartz diorite qtz diorite qtz diorite granodiorite granodiorite granodiorite granodiorite Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Hu et al., 1984 Hu et al., 1984 Hu et al., 1984 Hu et al., 1984 Hu et al., 1984 Hu et al., 1984 Zhai et al., 1992 Anhui Geology, 1988 Anhui Geology, 1988 Yu et al., 2002 Anhui Geology, 1988 Zhai et al., 1992 Wu et al., 1996 Wu et al., 1996 Shao et al., 2003 Wu et al., 1996 47 district name mineral rock type age quality references Tongling Tongling Tongling Tongling Tongling Tongling Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningzhen Fenghuangshan Fenghuangshan Jitou Jitou Jitou Jitou Gushan Gushan Meishan Meishan Meishan Meishan Meishan Ningwu Niangniangshan Tongjing Ningwu Yingzishan Longwangshan Ningwu Qilijian Ningwu Ningwu Ningwu Xiaodanyang Longwangshan Xiaodanyang Xiaodanyang Ningwu Ningwu bt bt wr wr wr wr wr wr 131 149 168 110 161 105.1 97 115.7 121.4 91.0 109.7 114.0 130.1 120 99.8 105.5 94.3 113.2 114.6 116.6 120.2 121.4 122.4 124.6 125.3 126.8 129.2 127.1 130.5 125.3 5 5 4 4 5 5 5 5 5 5 5 5 5 3 5 5 5 5 5 5 5 4 4 4 5 5 4 4 4 4 123 5 Anjishan bt wr wr wr wr wr wr bt wr wr bt wr bt bt bt bt wr bt bt bt bt bt granodiorite granodiorite quartz diorite quartz diorite quartz monzodiorite granodiorite pyx diorite porphyrite andesite bt pyx andesite trachyandesite andesite andesite trachyandesite gabbrodiorite porphyrite/pyx diorite phonolite phonolite trachyte andesite trachyandesite andesite trachyandesite andesite trachyte trachyandesite trachyandesite trachyandesite granodiorite Shao et al., 2003 Shao et al., 2003 Xu et al., 2001 Xu et al., 2001 Wu et al., 1996 Wu et al., 1996 Zhai et al., 1992 Wang et al., 2001 Anhui Geology, 1988 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Yu et al., 2002 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Chang et al., 1991 48 district name mineral rock type age quality references Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Anjishan Anjishan Anjishan Anjishan Anjishan wr bt hbl wr bt 106 117 106 123 116 117 116 117 115.4 108.9 57 113.3 85.4 106.9 113.2 104.7 137.7 93.6 94.3 91.6 105.5 89.8 84.5 121.4 5 5 5 5 5 3 3 5 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 Funiushan Funiushan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan Tongshan bt quartz diorite qtz diorite qtz diorite qtz diorite granodiorite granodiorite porphyry qtz diorite porphyrite qtz diorite porphyrite bt gabbro bt gabbro qtz-bearing diorite hbl andesite pyroxene diorite porphyrite qtz monzonite qtz-bearing diorite mt-alb altered diorite porphyrite bt qtz diorite porphyrite syenite porphyry noselite acmite syenite noselite acmite syenite welded breccia noselite phonolite pyx diorite porphyrite bt andesite Chang et al., 1991 Wang et al., 1997 Wang et al., 1997 Wang et al., 1997 Wang et al., 1997 Ye, 1999 Ye, 1999 Wang et al., 1997 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 Cong et al., 1977 49 APPENDIX B. Age data of ore deposits in the Middle and Lower Yangtze River Valley District Name Method Mineral Age Quality References Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Jiurui Jiurui Anqing-Guichi Anqing-Guichi Luzong Luzong Luzong Luzong Luzong Luzong Tongling Ningwu Ningwu Ningwu Ningwu Ningwu Chengchao Chengchao Tieshan Tieshan Tonglushan Tonglushan Tonglushan Tonglushan Tonglushan Tonglushan Jinshandian Jinshandian Lingxiang Chengmenshan Jilongshan Yueshan Yueshan Shaxi Luohe Luohe Luohe Luohe Luohe Fenghuangshan Meishan Meishan Taocun Baixiangshan Gushan K-Ar K-Ar K-Ar K-Ar K-Ar K-Ar K-Ar Rb-Sr Rb-Sr Rb-Sr Rb-Sr K-Ar mt phl phl phl phl phl phl phl phl phl phl phl phl ga 132 137 132 149 104 151 117 131 115 142 128 117 139 136 120 131 131 123.6 135 94 114 143 56 143 122.9 116.8 125 105 93.4 3 5 5 5 5 5 5 5 5 5 5 5 5 3 3 3 3 5 5 5 5 5 5 5 5 3 5 3 3 Shu, 1992 China Isotope Geology Conference, 1979 Song, 1994 Song, 1994 Zhai et al., 1992 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 China Isotope Geology Conference, 1979 Zhai et al., 1992 Luo, 2003 Wu, 1992 Zhou et al., 1997 Zhou et al., 1997 Xu et al., 1999 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Huang et al., 1989 Shao et al., 2003 Yu et al., 2002 Li et al., 1984 Yu et al., 2002 Li et al., 1984 Li et al., 1984 K-Ar K-Ar Re-Os Ar-Ar U-Pb U-Pb U-Pb U-Pb U-Pb U-Pb Ar-Ar Ar-Ar phl mo wr ap ap ap ap ap ga ab ab phl phl 50 District Name Method Mineral Age Quality References Ningzhen Ningzhen Anjishan Tongshan Re-Os Re-Os mo mo 108 106 5 5 Wang et al., 1997 Wang et al., 1997 51 APPENDIX C. Major Elements Compositions for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O other Total References Edong hbl monzodiorite 60.29 0.68 17.01 3.41 1.84 0.04 2.60 3.23 6.02 3.19 0.42 1.04 1.46 101.23 Edong Edong granite bt hbl qtz monzodiorite 71.87 67.67 0.32 0.37 13.58 16.01 1.06 1.39 0.89 1.52 0.03 0.09 0.45 0.97 1.14 3.51 4.84 4.49 3.47 2.72 1.67 0.14 1.09 99.32 99.97 Edong granodiorite 64.38 0.25 17.28 3.18 1.54 0.05 1.22 5.35 5.08 1.88 0.51 100.71 Hubei Geology, 1990 Shu, 1986 Hubei Geology, 1990 Shu, 1986 Edong qtz monzodiorite 68.87 0.48 14.21 1.69 0.80 0.05 1.11 2.23 5.51 3.57 Edong quartz monzonite 65.88 1.72 15.59 1.98 1.56 0.09 1.36 2.48 5.06 3.91 Edong bt hbl qtz monzodiorite 59.78 0.74 17.05 3.45 3.27 0.13 2.26 4.81 4.04 2.76 Edong Edong diorite granodiorite 58.48 64.29 0.76 0.43 16.88 14.28 3.54 1.64 2.68 2.87 0.13 1.91 1.77 5.92 4.55 4.28 3.83 2.93 3.04 Edong hbl monzodiorite 61.37 0.64 16.40 2.88 2.02 0.07 2.44 3.87 5.51 3.46 0.33 0.84 99.83 Edong bt di monzodiorite 59.90 0.66 17.23 3.44 1.80 0.07 1.83 4.15 5.77 3.66 0.38 0.71 99.60 0.10 0.73 99.35 1.60 0.32 1.24 101.23 99.85 2.75 0.72 100.24 97.42 Hubei Geology, 1990 Shu, 1986 Hubei Geology, 1990 Shu, 1986 Shu, 1986 Hubei Geology, 1990 Hubei Geology, 1990 52 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Edong hbl qtz monzodiorite porphyrite 65.30 0.43 16.17 2.38 1.92 0.06 1.39 3.18 5.43 3.22 0.40 Edong Edong diorite pyx hbl diorite 61.09 59.59 0.66 0.68 16.27 16.51 3.13 2.97 2.10 2.70 0.07 0.08 2.64 2.11 3.95 4.75 5.21 5.32 3.47 3.22 Edong Edong pyx diorite porphyritic qtzbearing diorite 55.88 64.68 0.69 0.51 16.52 16.22 2.44 2.68 2.18 1.80 0.08 0.05 2.84 1.29 5.45 2.86 5.84 5.22 Edong bt pyx diorite 55.83 0.95 16.92 3.92 3.01 0.10 3.07 5.74 Edong quartz diorite 61.71 0.63 16.53 2.76 1.94 0.09 1.94 Edong qtz diorite 60.87 0.71 16.29 2.71 2.40 0.11 Edong 61.86 0.66 16.24 2.80 2.70 Edong 55.33 1.19 16.40 3.05 Edong 63.07 0.59 15.84 Edong 66.71 0.32 Edong 66.97 Edong 47.95 other Total References 0.68 100.56 Hubei Geology, 1990 0.34 0.37 1.25 0.74 100.18 99.04 Lu, 1994 Lu, 1994 2.63 3.44 0.32 0.22 0.93 1.22 95.80 100.19 Lu, 1994 Lu, 1994 5.51 3.40 0.32 0.60 99.37 Lu, 1994 4.38 5.39 3.24 99.71 Shu, 1986 2.20 4.42 5.43 3.15 0.33 0.93 99.55 0.09 2.16 4.55 4.59 2.82 0.30 0.99 0.13 99.89 3.82 0.12 3.90 7.61 4.73 2.69 0.67 0.68 0.74 100.93 3.00 2.32 0.10 2.17 3.40 4.74 3.04 0.34 1.29 0.02 99.92 15.55 1.79 1.15 0.12 1.01 2.88 4.93 3.35 0.15 0.77 1.10 99.83 0.35 16.16 0.97 1.69 0.14 0.78 3.10 5.28 3.40 0.32 0.49 0.16 99.81 1.06 14.67 5.49 7.72 0.12 2.31 6.09 3.78 1.17 0.62 3.72 4.19 98.89 Yang, 2001 Zhai et al, 1992 Zhai et al, 1992 Zhai et al, 1992 Zhai et al, 1992 Zhai et al, 1992 Zhai et al, 1992 1.10 53 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 Edong qtz synodiorite porphyrite 62.45 0.51 16.16 2.36 2.11 0.07 1.27 4.74 4.39 3.34 Edong porphyritic qtz diorite 61.53 0.53 16.00 2.02 1.88 0.04 1.60 5.85 4.44 Edong porphyritic qtz synodiorite(early) 63.54 0.52 16.56 2.32 1.79 0.06 1.53 4.34 Edong qtz synodiorite 62.30 0.54 16.17 2.65 2.46 0.08 1.57 Edong Edong Edong diorite qtz diorite granodiorite porphyry 55.79 61.31 63.01 0.72 0.58 0.50 17.16 16.56 16.33 4.64 2.78 2.37 2.22 2.62 2.89 0.11 0.10 0.12 Edong granodiorite 65.34 0.50 16.32 2.05 1.84 Edong Edong diorite granodiorite 56.60 65.74 0.76 0.56 17.12 15.03 4.70 1.45 Edong granodiorite 65.51 0.58 15.07 Edong granodiorite 65.54 0.59 14.79 L.O.I or H2 O other Total References 0.26 97.65 Liu, 2002 3.31 0.21 97.42 Liu, 2002 4.31 3.10 0.29 98.36 Liu, 2002 4.97 4.48 2.96 0.25 98.42 Liu, 2002 1.72 1.54 1.35 6.20 5.39 4.43 4.96 4.52 4.34 2.30 2.83 3.29 0.30 1.45 1.73 96.12 99.68 100.36 Liu, 2002 Zhou, 1985 Zhou, 1985 0.09 1.44 4.00 4.56 3.77 0.79 100.70 Zhou, 1985 3.63 2.58 0.15 0.06 2.36 2.01 5.62 3.55 4.26 3.96 2.94 3.34 0.21 0.96 2.70 0.26 100.84 99.71 1.49 2.58 0.06 2.04 3.51 3.98 3.47 0.21 0.99 0.20 99.69 1.65 2.38 0.05 2.09 3.41 3.80 3.48 0.24 1.24 0.40 99.66 Zhou, 1985 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 54 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O other Total References Edong granodiorite 65.80 0.57 15.10 1.48 2.52 0.04 2.08 3.25 3.85 3.38 0.21 1.08 0.30 99.66 Edong granodiorite 65.83 0.55 14.97 1.41 2.67 0.06 2.21 3.16 3.81 3.45 0.23 1.12 0.20 99.67 Edong granodiorite 65.58 0.57 15.04 1.55 2.52 0.06 2.16 3.22 3.93 3.59 0.21 1.08 0.12 99.63 Edong granodiorite 65.00 0.57 15.23 1.91 2.18 0.05 1.90 3.55 3.98 3.13 0.25 1.35 0.60 99.70 Edong granodiorite 65.82 0.53 15.04 1.85 2.05 0.05 1.88 3.42 4.07 3.13 0.21 1.20 0.45 99.70 Edong granodiorite 64.06 0.45 15.23 5.32 3.55 0.31 1.35 3.76 3.66 3.03 0.19 100.91 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Shu, 1986 Edong hbl qtz monzodiorite 63.91 0.66 15.91 2.38 2.16 0.09 1.72 4.46 4.46 3.33 0.26 0.61 99.95 Edong hbl qtz monzodiorite 61.37 0.71 15.75 3.17 2.62 0.16 2.64 4.48 4.26 3.70 0.33 0.72 99.91 Edong 50.18 1.24 17.34 5.07 4.64 0.18 4.20 8.84 4.01 2.14 0.25 0.75 0.91 99.75 Edong 63.56 0.51 15.60 2.56 2.69 0.15 1.68 4.31 4.31 3.09 0.21 0.39 0.52 99.58 Edong 62.45 0.60 16.76 1.76 2.15 0.15 1.36 5.42 4.32 3.01 0.29 0.51 0.89 99.67 Edong 51.65 0.05 16.49 5.30 5.47 0.25 4.55 5.50 4.52 1.49 0.68 2.39 0.30 98.64 Hubei Geology, 1990 Hubei Geology, 1990 Zhai et al, 1992 Zhai et al, 1992 Zhai et al, 1992 Zhai et al, 1992 55 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O Edong quartz diorite 60.96 0.73 16.66 3.01 2.61 0.13 2.05 5.08 3.96 Edong quartz diorite 61.99 0.55 16.54 2.25 3.12 0.16 1.17 4.62 Edong qtz mozodioirte 70.45 0.25 15.08 1.21 1.23 0.06 0.68 Edong bt hbl qtz diorite 63.03 0.53 16.70 2.56 2.60 0.11 Edong quartz diorite 62.35 0.50 16.57 2.34 3.35 Edong granodiorite 64.20 0.53 16.48 2.44 Edong granodiorite 64.28 0.52 16.63 Edong granodiorite 63.28 0.58 Edong granodiorite 63.68 Edong granodiorite Edong granodiorite Edong P2O5 L.O.I or H2 O other Total References 3.22 1.62 100.01 Shu, 1986 3.96 3.32 2.85 100.54 Shu, 1986 2.58 4.17 3.60 0.08 1.35 100.74 1.78 4.93 3.81 2.64 0.21 1.21 100.11 0.11 1.88 4.96 3.75 2.71 Hubei Geology, 1990 Hubei Geology, 1990 Shu, 1986 2.30 0.09 1.53 5.08 3.64 2.34 0.24 2.15 2.48 0.09 1.47 4.94 3.65 2.32 16.04 2.33 2.88 0.13 1.94 4.99 3.73 0.56 16.03 2.37 2.72 0.13 1.90 4.95 64.53 0.51 16.16 2.35 2.33 0.12 1.45 64.10 0.58 16.01 2.23 2.50 0.10 62.40 0.56 16.93 2.58 2.78 0.09 1.34 99.85 0.84 0.04 99.75 0.23 0.90 0.08 99.74 2.56 0.24 0.85 0.22 99.77 3.68 2.51 0.24 0.74 0.24 99.75 5.07 3.51 2.60 0.24 0.88 0.04 99.79 1.78 4.71 3.65 2.65 0.23 0.93 0.30 99.77 2.06 4.79 3.95 2.55 0.20 1.00 99.89 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Zhai et al, 1992 56 District rock type Edong SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O 70.45 0.25 15.08 1.21 1.23 0.06 0.68 2.58 4.17 3.60 0.08 1.35 other Total References 100.74 Zhai et al, 1992 Wang et al., 1987 Jiurui monzogranite porphyry 65.52 0.52 15.23 1.30 1.71 0.01 1.98 4.08 3.89 3.81 0.20 98.25 Jiurui granodiorite 64.11 0.50 14.80 2.36 1.68 0.06 2.47 3.13 3.91 3.60 0.36 96.98 Jiurui 54.28 1.71 13.67 3.93 3.28 0.12 6.95 6.37 3.60 2.91 0.29 2.32 1.98 101.41 Jiurui 59.58 0.75 14.6 3.15 2.07 0.12 3.35 4.07 3.56 3.38 0.57 2.18 7.4 104.78 AnqingGuichi AnqingGuichi AnqingGuichi qtz diorite 62.64 0.54 15.95 1.92 2.42 0.11 2.49 4.22 3.80 2.94 0.19 2.57 99.79 granodiorite 63.66 0.52 15.38 2.22 2.36 0.14 1.78 3.81 3.51 3.14 0.28 2.53 99.33 qtz diorite 60.97 0.59 16.52 2.59 2.33 0.05 2.61 3.80 4.99 3.41 0.35 1.44 99.65 AnqingGuichi diorite 57.91 0.62 16.65 2.94 2.31 0.05 2.53 5.09 5.52 3.33 0.41 1.12 98.48 AnqingGuichi monzonite 59.44 0.61 16.58 2.76 2.32 0.05 2.57 4.44 5.25 3.37 0.38 1.28 99.05 AnqingGuichi AnqingGuichi AnqingGuichi diorite 57.83 0.83 16.14 3.55 2.79 0.12 3.27 4.04 4.90 4.17 97.64 Jiangxi Geology, 1984 Zhai et al., 1992 Zhai et al., 1992 Yu et al., 1999 Yu et al., 1999 Anhui Geology, 1987 Anhui Geology, 1987 Anhui Geology, 1987 Shu, 2004 diorite 57.26 0.84 16.34 4.64 2.60 0.10 3.19 3.93 5.84 3.57 98.31 Shu, 2004 diorite 59.12 0.73 16.15 3.02 2.75 0.09 2.74 3.77 5.16 4.07 97.60 Shu, 2004 57 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi diorite 59.18 0.61 16.25 2.20 2.29 0.06 2.58 4.58 4.05 diorite 58.56 0.64 16.48 2.71 3.02 0.06 3.04 5.38 diorite 55.84 0.65 16.31 2.36 1.81 0.06 1.27 qtz diorite 60.69 0.62 16.13 2.58 2.79 0.08 diorite 58.63 0.60 16.92 3.36 2.22 qtz diorite 60.68 0.59 16.68 2.57 qtz diorite 67.20 0.41 15.19 qtz diorite 60.61 0.56 qtz diorite 61.62 qtz diorite P2O5 L.O.I or H2 O other Total References 3.82 95.62 Shu, 2004 5.13 2.99 98.01 Shu, 2004 6.62 5.11 4.28 94.31 Shu, 2004 2.86 4.07 4.09 3.69 97.60 Shu, 2004 0.04 2.91 4.18 5.92 3.03 97.81 Shu, 2004 2.28 0.04 2.33 3.84 5.36 3.26 97.63 Shu, 2004 1.98 1.08 0.04 1.24 2.15 4.84 4.23 98.36 Shu, 2004 16.70 2.36 2.51 0.06 2.83 4.36 4.70 3.50 98.19 Shu, 2004 0.62 16.18 2.84 2.22 0.05 2.66 3.21 4.91 3.46 97.77 Shu, 2004 60.11 0.58 16.34 2.50 3.13 0.10 2.67 5.26 4.64 3.20 98.53 Shu, 2004 qtz diorite 59.41 0.72 16.58 2.47 3.20 0.13 2.76 5.23 4.76 3.20 98.46 Shu, 2004 qtz diorite 59.31 0.70 16.63 2.74 3.19 0.09 2.60 4.63 4.88 3.31 98.08 Shu, 2004 58.71 0.68 13.37 2.96 2.74 0.05 2.74 4.57 5.42 3.12 0.29 0.98 95.75 58.56 1.72 16.45 2.46 2.96 0.07 3.28 5.32 5.22 2.55 0.44 0.96 99.99 57.84 0.74 16.51 2.78 3.14 0.06 3.3 5.6 5.16 2.88 0.43 0.62 99.06 Zhai et al., 1992 Zhou et al, 2000 Zhou et al, 2000 0.12 58 District AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi Luzhong Luzhong rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Total References 59.62 0.66 16.4 2.53 2.73 0.06 3.16 4.56 5.05 3.15 0.38 0.7 99 0.62 99.03 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Zhou et al, 2000 Anhui Geology, 1987 Wang et al., 2001 60.44 0.65 15.92 2.25 2.82 0.07 3.38 4.92 4.66 2.93 0.37 56.7 0.8 16.13 1.13 4.47 0.18 3.47 6.06 4.2 2.12 0.46 95.72 58.04 0.8 16.11 2.01 3.16 0.07 2.88 5.78 3.99 1.35 0.41 94.6 59.64 0.74 15.12 2.13 3.42 0.08 3.14 4.94 3.88 2.36 0.37 95.82 58.56 0.64 16.48 2.47 3.24 0.06 3.04 5.38 5.13 2.99 0.43 60.66 0.61 16.12 1.68 3.14 0.08 2.72 5.19 3.83 2.22 0.37 96.62 60.51 0.7 15.58 2 3.2 0.15 3.08 4.54 3.83 2.36 0.32 96.271 58.43 0.67 16.91 2.69 3.58 0.05 2.95 4.74 5 2.97 0.46 0.72 99.17 58.15 0.73 16.46 2.92 3.16 0.06 3.26 5.44 4.65 2.99 0.41 1.3 99.53 57.58 0.78 16.43 3.15 3.01 0.07 3.26 5.66 4.65 2.99 0.43 1.36 99.37 58.71 0.68 13.37 2.51 3.15 0.05 2.74 4.57 5.42 3.12 0.29 0.98 95.59 diorite porphyrite 57.67 0.57 16.68 3.11 3.40 0.10 2.44 4.46 5.14 2.31 0.28 qtz diorite porphyrite 60.70 0.67 14.45 3.39 2.70 0.32 2.32 4.11 4.51 3.94 0.32 0.32 other 98.74 96.16 2.17 99.60 59 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Luzhong 61.00 0.50 15.62 2.09 2.86 0.10 2.26 4.07 4.55 3.97 0.07 61.06 0.72 14.82 2.98 2.93 0.36 2.58 4.93 4.63 3.18 0.36 57.80 0.55 16.95 3.30 2.63 0.04 2.70 5.68 4.70 1.61 0.37 61.00 0.54 17.45 2.44 2.42 0.11 2.77 4.60 5.21 2.28 0.30 Luzhong qtz diorite porphyrite pyx diorite porphyrite qtz diorite porphyrite qtz diorite porphyrite diorite porphyry 61.44 0.31 14.67 1.97 0.92 0.09 2.19 4.10 3.90 2.78 0.16 92.53 Luzhong diorite porphyry 62.27 0.42 15.48 2.40 1.27 0.09 2.02 3.89 5.08 1.82 0.22 94.96 Luzhong 61.67 0.37 15.52 1.37 2.14 0.09 1.95 3.62 4.65 2.32 0.28 5.42 99.40 60.16 0.37 15.86 2.01 2.36 0.12 1.60 4.46 4.96 2.10 0.20 5.89 100.09 Tongling qtz diorite porphyrite qtz diorite porphyrite pyx monzodiorite 50.81 0.21 17.16 2.72 5.55 0.14 3.26 9.63 3.73 3.10 0.56 1.10 97.97 Tongling pyx diorite 53.70 1.14 16.30 3.50 4.71 0.16 3.57 8.69 3.82 2.66 0.57 0.96 99.78 Tongling pyx diorite 50.90 1.24 15.40 3.94 5.20 0.16 4.07 8.97 3.67 2.99 0.65 2.13 99.32 Tongling pyx diorite 53.10 1.15 16.40 3.70 4.86 0.15 3.47 8.40 3.97 3.02 0.59 0.77 99.58 Tongling pyx diorite 54.60 0.96 16.40 3.65 4.21 0.12 3.11 8.27 4.02 2.66 0.50 0.83 99.33 Tongling pyx diorite 54.00 1.02 17.30 3.44 4.25 0.14 3.18 8.44 4.05 2.53 0.52 0.99 99.86 Luzhong Luzhong Luzhong Luzhong other Total References 2.46 99.55 1.22 99.77 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Xu et al, 1997 Xu et al, 1997 Xu et al, 2000 Xu et al, 2000 Fu, 1999 96.33 1.30 100.42 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 60 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O other Total References Tongling pyx diorite 53.40 1.26 16.73 4.36 4.28 0.17 3.52 7.93 3.97 2.94 0.50 0.93 99.99 0.85 100.03 Liang et al., 2000 Wang et al., 2004 Xing et al., 1996 Tongling diorite porphyrite 58.32 0.92 17.02 3.67 2.75 0.13 2.41 6.70 3.87 3.07 0.32 Tongling pyx monzodiorite 53.34 1.14 17.70 3.68 3.29 0.15 2.75 9.25 4.27 2.82 0.67 99.06 Tongling alkali-feldspar gabbro-diorite 55.43 0.86 15.99 0.99 5.58 0.11 1.95 6.28 4.37 4.07 2.00 97.63 Xing et al., 1996 Tongling pyx diorite 53.78 1.13 18.01 3.89 2.98 0.16 2.35 7.79 4.70 3.07 0.26 1.19 99.31 Tongling pyx diorite 52.35 1.21 17.31 4.56 3.23 0.18 3.11 9.41 4.14 2.70 0.65 0.48 99.33 Tongling pyx diorite 53.03 1.10 17.63 1.56 6.31 0.16 2.66 7.60 4.58 2.82 0.52 0.98 98.95 Tongling pyx diorite 53.67 1.00 17.59 2.99 4.22 0.15 2.43 8.72 4.50 3.24 0.52 0.85 99.88 Tongling pyx diorite 50.81 1.21 17.16 2.72 5.55 0.14 3.26 9.63 3.73 3.10 0.56 1.10 98.97 Tongling pyx diorite 53.54 1.14 17.70 3.68 3.29 0.15 2.75 9.52 4.27 2.82 0.12 0.55 99.53 Tongling pyx diorite 52.73 1.14 17.77 1.51 6.03 0.18 2.86 8.50 4.47 2.65 0.63 0.73 99.20 Tongling pyx diorite 62.27 0.69 16.24 2.86 3.30 0.12 1.63 4.53 4.25 3.13 0.58 99.60 Tongling diorite 63.44 0.65 16.04 2.75 3.24 0.10 1.37 4.21 4.25 3.02 0.55 99.62 Zhao et al., 2004 Zhao et al., 2004 Zhao et al., 2004 Zhao et al., 2004 Zhao et al., 2004 Zhao et al., 2004 Zhao et al., 2004 Anhui Geology, 1987 Anhui Geology, 1987 61 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O Tongling bearing-qtz diorite porphyrite 62.85 0.67 16.14 2.80 3.27 0.11 1.50 4.37 4.25 3.07 Tongling qtz monzodiorite porphyry 55.92 0.77 18.65 2.41 2.99 0.10 1.20 8.10 3.79 2.84 0.31 Tongling 65.73 0.58 15.70 2.65 1.65 0.09 1.62 4.04 3.66 3.02 0.21 0.62 99.57 Tongling qtz diorite porphyrite granodiorite 65.77 0.60 15.74 2.70 1.54 0.09 1.53 3.95 3.74 3.12 0.23 0.89 99.90 Tongling granodiorite 64.68 0.60 15.98 3.03 1.44 0.08 1.59 4.24 3.76 3.25 0.26 1.07 99.98 Tongling granodiorite 63.95 0.58 16.02 2.14 3.01 0.09 1.35 4.10 4.38 3.15 0.25 0.98 100.00 Tongling granodiorite 63.35 0.57 15.87 2.12 2.98 0.09 1.34 4.06 4.34 3.12 0.25 2.06 100.15 Tongling qtz diorite 61.77 0.56 15.73 2.41 3.08 0.09 1.40 4.69 4.05 3.26 0.27 3.01 100.32 63.44 0.65 16.06 2.75 3.24 0.10 1.37 4.71 4.71 3.02 0.79 100.84 62.45 0.58 16.23 2.65 1.23 0.08 1.64 4.55 3.75 3.18 0.26 2.91 99.51 Tongling qtz diorite porphyrite granodiorite 60.38 0.7 17.11 2.49 2.43 0.09 1.83 5.17 4.03 2.77 0.29 2.41 99.7 Tongling diorite porphyrite 63.86 0.55 16.61 2.5 1.72 0.08 1.21 4.59 4.48 2.72 Tongling granodiorite 63.76 0.46 17.26 1.5 2.28 0.09 1.36 6.3 4.47 2.36 Tongling Tongling P2O5 L.O.I or H2 O 0.57 other Total References 99.60 Anhui Geology, 1987 Shao et al., 2003 97.08 98.32 0.17 100.01 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wu et al., 1994 Xing et al., 1996 Xing et al., 1997 Zhai et al., 1992 Wang et al., 2004 Wang et al., 2004 Anhui Geology, 1987 Xing et al., 1996 62 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Tongling qtz diorite 62.89 0.57 17.07 2.07 1.24 0.06 1.35 5.93 4.64 2.49 0.29 Tongling granodiorite 63.9 0.66 16.9 1.81 2.2 0.11 1.48 5.53 4.04 3.22 Tongling qtz diorite porphyry qtz diorite porphyry qtz diorite porphyry qtz diorite porphyry qtz diorite porphyry qtz diorite 59.3 0.69 16.4 3.65 2.69 0.12 2.22 5.39 4.14 59.7 0.69 16.6 2.86 3.12 0.08 2.42 4.95 59.7 0.71 17.1 3.3 2.72 0.12 2.36 60 0.72 16.7 1.87 3.56 0.12 64.2 0.55 15.2 1.68 2.52 57.6 0.78 16.6 1.25 qtz diorite porphyrite pyx diorite 67.36 0.36 15.60 55.93 0.88 qtz diorite porphyrite qtz diorite porphyrite qtz diorite porphyrite qtz diorite porphyrite 59.28 Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling other Total References 1.2 99.8 0.22 0.95 101.02 2.93 0.41 1.5 99.44 4.35 3.17 0.42 1.91 100.27 5.35 4.54 2.68 0.41 1.01 100 2.18 5.6 4.29 2.69 0.42 1.2 99.35 0.09 2.02 3.87 3.75 3.74 0.32 1.38 99.32 3.93 0.1 2.63 6.37 4.33 3.17 0.46 2.04 99.26 0.90 0.60 0.06 1.42 3.65 4.55 3.74 0. 12 1.47 99.71 15.83 2.73 4.01 0.15 2.78 6.96 4.29 3.50 0.69 16.44 2.69 3.65 0.12 2.22 5.39 4.14 2.93 0.41 1.50 99.46 59.72 0.69 16.62 3.12 2.86 0.08 2.42 4.95 4.35 3.17 0.42 1.91 100.31 59.68 0.71 17.06 2.72 3.30 0.12 2.36 5.35 4.54 2.68 0.41 1.01 99.94 60.00 0.72 16.68 3.56 1.87 0.12 2.18 5.60 4.29 2.69 0.42 1.20 99.33 Wang et al., 2004 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 Huang et al., 2004 Wang et al., 2004 Anhui Geology, 1987 Jiang et al., 2001 Jiang et al., 2001 Jiang et al., 2001 Jiang et al., 2001 97.06 63 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Tongling 64.24 0.55 15.16 2.52 1.68 0.09 2.02 3.87 3.75 3.74 0.32 Tongling qtz diorite porphyrite granodiorite 64.01 0.57 15.78 1.83 4.09 0.12 1.44 4.08 4.05 3.03 Tongling qtz monzodiorite 61.55 0.68 16.74 1.46 3.44 0.10 2.04 5.93 3.72 Tongling qtz monzodiorite 61.60 0.66 16.94 1.39 3.47 0.10 2.21 6.55 Tongling granodiorite 64.75 0.54 15.70 2.22 2.44 0.07 1.63 Tongling granodiorite 63.66 0.57 15.69 1.82 4.07 0.12 Tongling quartz monzodiorite 59.01 0.82 16.00 1.89 4.53 Tongling 53.08 1.02 18.02 4.32 Tongling 59.60 0.83 16.86 other Total References 1.38 99.32 0.23 0.76 99.99 3.19 0.21 0.93 99.99 Jiang et al., 2001 Wu et al., 1994 Wu et al., 1994 3.60 3.20 0.20 99.92 Wu et al., 1996 4.65 4.17 3.60 0.23 100.00 1.43 4.06 4.03 3.01 0.23 1.31 100.00 0.12 2.32 4.87 4.16 4.02 0.27 1.18 99.19 Wu et al., 1996 Xing et al., 1996 Xing et al., 1996 3.28 0.02 2.21 7.84 4.56 3.04 0.46 0.79 0.39 99.03 7.16 3.46 0.06 1.91 5.57 4.32 2.86 0.25 0.91 0.64 104.43 Tongling alkali feldspar gabbro-diorite 54.07 1.04 16.24 3.06 4.26 0.15 3.01 8.72 4.30 2.84 1.57 Tongling granodiorite 63.19 0.65 15.62 2.37 2.63 0.08 1.79 5.03 4.11 3.08 0.28 0.80 99.63 Tongling granodiorite 62.72 0.67 14.45 3.40 2.55 0.26 2.51 5.04 4.87 2.80 0.37 0.51 100.15 Zhai et al., 1992 Zhai et al., 1992 99.26 Wang et al., 2003 Wang et al., 2003 64 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Tongling qtz diorite 59.31 0.86 15.91 3.77 2.37 0.11 2.21 6.48 4.37 2.80 0.35 Tongling qtz diorite 59.40 0.85 16.20 0.50 4.97 0.11 2.21 6.60 4.37 3.06 Tongling qtz diorite 59.2 0.84 16.02 0.37 5.48 0.1 2.17 6.49 4.39 Tongling pyx diorite 54.47 1.25 14.63 4.46 4.71 0.5 3.42 7.53 Tongling gabbro 53.46 1.26 16.13 4.09 4.83 0.16 3.63 Tongling gabbro 52.61 1.34 14.86 5.18 4.68 0.58 Tongling qtz diorite 61.34 0.74 16.3 2.57 2.63 Tongling granodiorite 63.13 0.62 15.74 0.94 Tongling granodiorite 63.33 0.61 13.8 Tongling granodiorite 63.08 0.62 Tongling granodiorite 58.3 Tongling qtz diorite Tongling Tongling other Total References 1.05 99.59 0.35 0.96 99.58 2.53 0.35 1.64 99.58 4.95 2.18 0.46 0.98 99.54 8.3 3.82 2.52 0.5 0.82 99.52 3.35 8.22 5.14 2.48 0.54 0.54 99.52 0.05 1.85 5.2 4.18 2.66 0.3 1.24 99.06 4.13 0.04 1.7 4.33 3.75 3.35 0.26 1.69 99.68 0.8 3.9 0.04 1.66 4.58 3.89 3.17 0.25 1.64 97.67 13.88 0.8 4 0.04 1.65 4.68 3.87 3.18 0.26 1.61 97.67 0.87 14.41 4.38 3.5 0.37 2.53 5.39 5.69 2.62 0.44 0.98 99.48 63.5 0.58 16.67 2.1 2.35 0.09 1.52 4.7 3.89 2.79 0.27 1.53 99.99 qtz diorite 62.04 0.71 16.11 0.76 4.49 0.1 2.11 4.9 3.65 3.02 0.29 1.7 99.88 granodiorite 63.61 0.55 16.38 2.29 2.08 0.05 1.25 4.6 4.67 2.67 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2004 Wang et al., 2004 Anhui Geology, 1987 98.15 65 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Tongling qtz monzodiorite 62.62 0.55 16.23 1.713 2.47 0.07 1.56 4.6 4.58 2.67 0.29 Tongling qtz monzodiorite (porphyrite) 65.02 0.53 15.88 1.9 2.42 0.05 1.62 3.76 4.59 3.06 Tongling diorite porphyrite 55.78 0.89 16.95 2.2 5.18 0.07 3.3 6.35 3.71 Tongling 54.2 1.22 16.13 3.12 6.29 0.08 4.36 6.12 Tongling andesite porphyry qtz diorite 63.89 0.54 16.64 2.41 2.09 0.08 1.33 Tongling qtz monzodiorite 61.01 0.66 16.48 1.4 3.65 0.13 Tongling quartz monzodiorite 62.68 0.56 16.78 1.92 2.56 Tongling qtz diorite 62.61 0.57 16.83 2.25 Tongling 62.13 0.56 16.78 Tongling 54.63 1.04 Tongling 62.93 Tongling 63.61 other Total References 0.79 98.139 Wang et al., 1987 0.56 0.54 99.93 Wang et al., 1987 3.3 0.32 1.57 99.624 3.39 2.35 0.47 1.68 99.41 4.59 4.44 2.52 0.24 1.08 99.85 1.75 6.41 4.05 3.09 0.3 1.14 100.07 Wang et al., 1987 Wang et al., 1987 Wang et al., 2004 Xing et al., 1996 0.09 1.46 5.29 4.89 2.83 0.28 0.74 100.08 Xing et al., 1996 1.78 0.06 1.66 5.20 4.91 2.52 0.28 0.87 99.54 1.74 2.87 0.14 1.52 5.20 4.86 2.64 0.28 0.32 99.04 15.82 4.24 3.90 0.06 4.70 7.06 4.67 1.69 0.17 0.92 0.17 99.07 0.46 16.97 1.64 2.53 0.03 1.3 5.31 5.07 2.93 0.17 0.42 0.26 100.02 0.55 16.38 2.29 2.08 0.05 1.25 4.6 4.67 2.67 Xing et al., 1997 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 98.15 66 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O other Tongling qtz diorite 61.7 0.55 17.41 2.18 2.61 0.12 1.62 3.64 5.31 2.61 Tongling quartz diorite 61.07 0.51 15.45 2.73 3.27 0.10 2.30 4.64 3.61 3.56 0.20 0.18 97.62 Tongling qtz monzodiorite 60.10 0.64 16.15 3.13 2.84 0.06 1.34 4.92 4.24 2.99 0.25 2.37 99.03 Xing et al., 1996 Tongling bt alkali-feldspar gabbro 50.60 1.35 17.03 4.47 5.30 0.20 4.18 8.98 3.77 2.34 1.52 99.74 Xing et al., 1996 Tongling 62.23 0.55 17.48 2.06 2.79 0.06 1.73 3.80 5.09 2.78 0.23 98.80 Tongling 51.84 1.15 17.44 2.55 6.25 0.18 3.13 8.58 4.08 2.24 0.50 Zhai et al., 1992 Zhai et al., 1992 Wang et al., 2004 Ishihara et al., 1986 0.30 Total References 97.75 Anhui Geology, 1987 Chen, 2003 98.24 Tongling qtz diorite 56.28 0.88 16.90 4.33 2.61 0.11 2.24 6.78 3.21 2.89 0.34 3.36 99.93 Ningwu altered olvorthopyroxeneaugite andesite 54.94 0.81 18.55 5.07 2.44 0.14 1.72 6.31 4.11 3.25 0.54 0.96 98.84 Ningwu altered pyx porphyrite altered hbl-bt andesite 56.9 0.65 16.74 4.19 2.69 0.13 2.89 4.99 3.45 3.29 0.28 1.48 97.68 60.17 0.48 16.53 2.27 2.41 0.1 2.03 5.3 3.84 1.86 0.27 2.07 97.33 altered microdiorite 52.99 0.71 17.96 4.28 2.84 0.08 1.34 8.63 4.04 1.01 0.42 2.15 96.45 Ningwu Ningwu Ishihara et al., 1986 Ishihara et al., 1986 Ishihara et al., 1986 67 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Ningwu orthopyroxene microdiorite 55.36 0.82 17.41 4.59 3.34 0.13 3.75 6.92 4.53 2.32 0.31 Ningwu alterd hbl-bt granodiorite 65.55 0.51 15.15 2.15 1.76 0.04 1.73 3.16 3.73 3.73 Ningwu augite-olivine basalt 44.32 2.22 14.62 3.22 6.86 0.23 9.71 9.58 4.58 Ningwu augite-olivine basalt 47.80 2.36 15.77 5.98 4.92 0.18 5.56 8.32 Ningzhen qtz diorite porphyry 63.04 0.53 16.21 1.77 2.92 0.09 2.53 Ningzhen 64.45 0.46 15.83 1.75 2.07 0.07 Ningzhen qtz diorite porphyry qtz diorite 64.46 0.52 15.53 1.13 2.97 Ningzhen qtz diorite 64.89 0.46 15.80 1.72 Ningzhen qtz diorite 65.05 0.47 14.98 Ningzhen qtz diorite 63.93 0.48 64.82 0.48 Ningzhen Total References 0.4 99.88 Ishihara et al., 1986 0.18 0.70 98.39 Ishihara et al., 1986 1.68 0.98 0.16 98.16 Ishihara et al., 1986 4.22 2.33 0.71 1.68 99.83 Ishihara et al., 1986 4.11 4.33 2.62 0.29 98.44 1.69 3.28 4.34 2.98 0.19 1.57 100.34 Jiangsu Geology, 1984 Xia, 2000 0.08 1.53 5.31 4.88 2.87 0.62 99.90 2.53 0.04 1.69 4.48 4.58 2.67 0.68 99.54 2.56 2.22 0.04 1.52 4.28 4.38 2.98 1.06 99.54 15.93 1.40 2.73 0.06 2.24 4.54 4.62 2.60 0.98 99.51 16.15 4.25 0.1 2.04 4.54 4.35 2.44 0.3 99.47 1.66 other Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Zhai et al., 1992 68 District rock type SiO2 TiO2 Al2O3 Fe2O3 Ningzhen 44.64 1.27 19.98 Ningzhen 64.46 0.44 FeO MnO MgO CaO Na2O K2 O P2O5 12 0.19 4.82 10.5 3.81 0.72 15.64 3.69 0.08 1.58 3.39 4.47 L.O.I or H2 O other Total References 1.27 99.23 2.89 0.25 96.89 Zhai et al., 1992 Zhai et al., 1992 Xia, 2000 Ningzhen granodiorite porphyry 67.02 0.37 14.93 1.52 2.19 0.07 1.65 3 3.83 3.52 0.2 0.9 Ningwu altered olvorthopyroxeneaugite andesite 54.94 0.81 18.55 5.07 2.44 0.14 1.72 6.31 4.11 3.25 0.54 0.96 98.84 Ishihara et al., 1986 Ningwu altered pyx porphyrite altered hbl-bt andesite 56.9 0.65 16.74 4.19 2.69 0.13 2.89 4.99 3.45 3.29 0.28 1.48 97.68 60.17 0.48 16.53 2.27 2.41 0.1 2.03 5.3 3.84 1.86 0.27 2.07 97.33 Ishihara et al., 1986 Ishihara et al., 1986 Ningwu altered microdiorite 52.99 0.71 17.96 4.28 2.84 0.08 1.34 8.63 4.04 1.01 0.42 2.15 96.45 Ishihara et al., 1986 Ningwu orthopyroxene microdiorite 55.36 0.82 17.41 4.59 3.34 0.13 3.75 6.92 4.53 2.32 0.31 0.4 99.88 Ishihara et al., 1986 Ningwu alterd hbl-bt granodiorite 65.55 0.51 15.15 2.15 1.76 0.04 1.73 3.16 3.73 3.73 0.18 0.70 98.39 Ishihara et al., 1986 Ningwu 0.51 99.71 69 District rock type SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2 O P2O5 L.O.I or H2 O Ningwu augite-olivine basalt 44.32 2.22 14.62 3.22 6.86 0.23 9.71 9.58 4.58 1.68 0.98 Ningwu augite-olivine basalt 47.80 2.36 15.77 5.98 4.92 0.18 5.56 8.32 4.22 2.33 0.71 Ningzhen qtz diorite porphyry 63.04 0.53 16.21 1.77 2.92 0.09 2.53 4.11 4.33 2.62 Ningzhen 64.45 0.46 15.83 1.75 2.07 0.07 1.69 3.28 4.34 2.98 0.19 Ningzhen qtz diorite porphyry qtz diorite 64.46 0.52 15.53 1.13 2.97 0.08 1.53 5.31 4.88 2.87 0.62 99.90 Ningzhen qtz diorite 64.89 0.46 15.80 1.72 2.53 0.04 1.69 4.48 4.58 2.67 0.68 99.54 Ningzhen qtz diorite 65.05 0.47 14.98 2.56 2.22 0.04 1.52 4.28 4.38 2.98 1.06 99.54 Ningzhen qtz diorite 63.93 0.48 15.93 1.40 2.73 0.06 2.24 4.54 4.62 2.60 0.98 99.51 Ningzhen 64.82 0.48 16.15 4.25 0.1 2.04 4.54 4.35 2.44 0.3 99.47 Ningzhen 44.64 1.27 19.98 12 0.19 4.82 10.5 3.81 0.72 1.27 99.23 Ningzhen 64.46 0.44 15.64 3.69 0.08 1.58 3.39 4.47 2.89 0.25 96.89 67.02 0.37 14.93 1.52 0.07 1.65 3 3.83 3.52 0.2 Ningzhen granodiorite porphyry 2.19 Total References 0.16 98.16 Ishihara et al., 1986 1.68 99.83 Ishihara et al., 1986 0.29 98.44 1.57 100.34 Jiangsu Geology, 1984 Xia, 2000 1.66 0.9 other 0.51 99.71 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Xia, 2000 70 APPENDIX D Rare earth element concentrations for Mesozoic igneous rocks in the Middle and Lower Yangtze River Valley. District La Ce Pr Nd Sm Eu Gd Tb Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi 46 41.7 36.5 38 49.9 63 77 20.79 27.77 33 40 41.1 49.1 49.38 50.94 56.85 57.56 49.05 50.02 41.8 42.5 46.7 47.99 49.05 50.02 50.28 53.58 54.4 61.48 97.4 77.7 64.9 72.7 105 129 162 40.82 43.03 78 70 83.7 93.1 90.33 95.17 107.98 95.56 93.11 112.20 84.2 76.9 89.4 86.01 93.11 112.2 91.08 98.89 116.9 100.44 12.5 8.71 8.12 48.4 28.7 26.1 31.3 49.6 55 68 18.57 15.17 36 29 39.5 37 38.23 41.17 45.43 47.81 37.03 45.15 32.5 31.5 38.9 37.62 37.03 45.15 38.56 43.83 47.1 50.28 6.67 5.13 4.64 4.96 8.25 9.7 11.6 4.75 7.36 6 4.9 7.57 6.6 6.89 7.31 7.67 7.56 6.59 8.01 6.93 5.13 6.25 6.59 6.59 8.01 6.62 7.32 8.13 7.81 1.68 1.18 1.18 1.24 2.06 2 2.4 1.04 0.50 1.5 1.1 1.84 1.62 1.66 1.75 1.8 1.93 1.62 1.59 1.56 1.38 1.59 1.57 1.62 1.59 1.64 1.84 1.79 1.88 4.82 3.99 3.47 3.26 5.53 6 7 3.61 1.56 3.6 3.3 5.67 4 4.26 4.43 4.77 5.21 3.96 4.68 0.65 2.77 0.5 1.27 0.58 2.99 0.58 1.53 0.55 2.33 0.47 1.06 2.48 1.26 0.68 2.98 0.59 1.64 0.78 3.7 0.64 1.83 0.86 4.3 0.74 2.1 0.60 3.18 0.66 1.80 0.30 1.29 0.27 0.82 2.4 1.14 2.7 1.51 0.88 3.94 0.82 2.1 0.58 0.6 2.51 0.48 1.26 0.64 2.58 0.48 1.26 0.67 2.9 0.55 1.52 0.63 2.21 0.46 1.03 0.58 2.24 0.44 1.08 0.68 2.70 0.52 1.31 0.55 0.42 1.92 0.37 0.97 0.44 2.31 0.37 1.11 0.56 2.4 0.45 1.2 0.58 2.24 0.44 1.08 0.68 2.7 0.52 1.31 0.6 2.65 0.5 1.28 0.67 2.74 0.52 1.29 0.72 0.61 2.21 0.44 0.9 12.7 14 17.4 5.20 4.61 10.9 11.43 12.07 13.52 11.64 11.34 13.66 7.14 8.83 10.9 11.34 13.66 11.19 12.41 12.59 4.08 4.76 4.05 3.96 4.68 4.29 4.61 5.17 Dy Ho Er Tm Yb Lu Y 0.2 1.13 0.16 14.1 0.25 1.46 0.22 15.3 0.23 1.25 0.19 11.1 1.24 12.67 0.25 1.2 0.18 16.6 0.3 1.36 0.22 15.2 0.3 1.61 0.26 18.2 1.76 0.25 17.54 0.95 0.14 8.11 1.1 12.3 1.48 13.8 0.35 2 0.29 19.2 0.94 0.14 0.21 1.11 0.16 0.22 1.09 0.16 0.26 1.45 0.2 0.17 1.14 0.15 0.97 0.14 10.96 1.21 0.17 13.21 1.26 0.17 0.11 0.65 0.14 7.96 0.1 0.68 0.1 9.47 0.2 1.09 0.16 11.42 0.97 0.14 10.96 1.21 0.17 13.21 0.21 1.13 0.17 12.36 0.22 1.16 0.18 12.76 1.83 0.26 0.21 1.1 0.15 11.36 Reference Zhao et al., 1999 Yu et al., 1999 Yu et al., 1999 Wang et al., 1987 Zhao et al., 1999 Zhao et al., 1999 Zhao et al., 1999 Zhai et al., 1992 Zhai et al., 1992 Wang et al., 1987 Wang et al., 1987 Yu et al., 1999 Ma et al., 1997 Yuan et al., 2002 Yuan et al., 2002 Yuan et al., 2002 Yuan et al., 2002 Zhai et al., 1992 Zhai et al., 1992 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 71 District La Ce Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong 54.6 19.06 24.94 54.58 55.08 54.4 43.98 54.44 69.84 75.68 27.99 91.2 40.84 74.75 91.22 102.00 103.6 77.13 103.56 134.60 146.50 63.46 Edong Pr Nd Sm Eu Gd Tb 9.90 12.46 16.56 18.35 8.5 79.5 15.43 23.25 79.45 45.12 42.7 35.10 42.65 58.99 63.56 33.64 4.6 3.37 3.53 4.64 2.00 7.3 6.49 7.33 10.20 12.22 5.48 0.94 0.05 0.52 0.94 1.84 1.51 1.58 1.51 2.49 2.79 1.39 3.4 2.83 2.62 3.41 4.74 4.4 4.57 4.36 6.08 7.84 3.37 0.58 0.57 0.47 0.58 0.56 0.63 0.67 0.63 0.81 1.13 0.48 31.52 69.35 8.92 34.8 5.58 1.44 3.51 0.5 Edong 33.42 70.81 9 34.8 5.39 1.43 3.38 0.48 2.53 0.45 1.2 0.17 1.15 0.18 12.3 Edong 35.86 74.21 9.4 36.15 5.75 1.45 3.34 0.5 0.17 1.1 Edong 38.75 81.17 9.98 37.26 5.82 1.44 3.22 0.51 2.55 0.46 1.25 0.17 1.13 0.18 12.9 Edong 40.52 78.37 9.5 35.48 5.35 1.34 2.98 0.46 2.33 0.42 1.13 0.15 0.99 0.15 10.6 Edong 48.52 91.47 10.65 38.12 5.56 1.39 3.14 0.46 2.4 0.43 1.18 0.16 1.06 0.18 12.3 Edong 49 91.98 10.67 38.6 5.72 1.43 3.23 0.48 2.52 0.44 1.24 0.17 1.14 0.18 12.8 Edong Edong Edong Edong Edong Edong 48.97 50.87 51.48 71.03 78.47 22 95.74 105.60 89.58 113.00 130.70 48.44 11.23 13.70 10.13 13.58 14.83 5.69 36.82 49.09 32.79 47.81 48.45 21.89 6.55 9.30 5.63 9.08 9.67 4.02 1.60 2.52 1.47 1.50 1.92 1.08 4.37 6.17 3.62 5.98 6.60 3.37 0.69 0.89 0.53 0.87 0.96 0.48 1.53 1.52 1.34 1.90 2.16 0.21 1.38 4.62 6.98 9.95 12.40 Dy Ho Er 3.71 2.55 2.74 2.88 0.83 0.60 0.59 0.57 2.75 1.91 1.73 1.46 3.03 2.63 2.89 4.83 2.53 0.59 0.52 0.55 0.93 0.44 1.49 1.30 1.26 2.35 1.2 2.58 0.45 1.26 2.6 2.91 3.83 2.36 3.95 4.31 2.68 0.45 1.25 0.59 0.72 0.47 0.76 0.85 0.51 1.54 1.79 1.26 1.99 2.22 1.43 Tm Yb Lu 2.04 3.38 2.63 2.04 1.43 1.2 1.35 1.20 1.04 2.07 0.17 1.09 0.3 0.45 0.38 0.30 0.21 0.17 0.19 0.17 0.15 0.28 0.18 Y 23.40 15.98 16.02 14.26 15.99 13.59 13.77 24.77 12.7 0.18 1.13 0.19 12.9 0.18 12.8 0.22 0.21 0.20 0.27 0.31 0.22 15.36 18.46 13.09 20.32 22.34 13.3 Reference Ma et al., 1997 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Ma et al., 1997 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Wang Qiang et al., 2004 72 District La Edong Ce Pr Nd 28.21 58.71 7.2 Edong 28.44 56.44 Edong Eu Gd Tb 28.23 4.87 1.4 3.84 0.54 2.94 0.55 1.52 0.21 1.39 0.22 15.2 6.81 27.01 4.91 1.33 3.98 0.56 3.11 0.57 1.6 0.23 1.47 0.24 15.9 28.47 52.78 6.04 23.71 4.11 1.13 3.29 0.46 2.63 0.49 1.36 0.2 Edong 29.19 54.4 6.51 24.96 4.3 1.2 3.39 0.52 2.81 0.53 1.42 0.21 1.45 0.23 14.6 Edong 31.6 61.74 7.24 28 4.77 1.32 3.86 0.54 2.87 0.53 1.43 0.2 Edong Edong Edong Edong Edong Edong Edong Edong Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui Jiurui 27.76 37.31 87.35 11.50 10.70 13.20 10.50 10.30 23.88 22.5 49 28.26 39.7 38.6 38.00 32.00 46.8 46.00 46.97 64.11 52.13 40.15 21 56.25 69.416 86.007 23.50 22.10 26.40 21.70 21.50 43.96 36.7 88 61.78 58 66.3 73.00 61.00 87.1 89.00 87.99 128.58 105.20 73.404 46.161 7.00 6.614 8.321 3.11 2.90 3.35 2.87 2.85 23.70 26.64 34.83 14.60 13.70 15.20 13.40 13.20 17.15 18.4 40 21.42 23.6 26.6 28.00 27.00 32.9 33.00 34.28 54.97 46.26 30.05 22.2 4.57 4.219 5.67 3.89 3.58 3.75 3.59 3.51 3.79 3.5 7.1 3.66 5 4.3 7.20 4.98 5.2 6.80 5.75 9.57 8.89 4.926 4.363 1.24 1.07 1.591 1.23 1.17 1.17 1.14 1.13 0.83 0.84 1.94 1.06 1.37 1.13 1.50 1.28 1.28 1.40 1.32 2.01 2.19 1.329 1.208 3.65 2.769 4.067 3.71 3.36 3.53 3.40 3.32 2.26 2.5 5.6 2.76 3.8 3.3 4.00 3.75 3.5 4.00 3.92 6.7 6.52 3.491 3.905 0.58 0.31 0.51 0.63 0.56 0.57 0.56 0.56 0.12 0.21 0.29 0.26 0.25 0.26 0.25 6.41 7.7 11.41 15.25 13.31 7.15 5.07 Sm Dy 2.71 1.75 2.87 4.03 3.63 3.60 3.67 3.64 1.92 Ho 0.54 0.32 0.44 0.83 0.75 0.74 0.76 0.74 Er 1.46 0.838 1.45 2.05 1.89 1.83 1.87 1.84 1.22 Tm Yb 0.71 3.5 1.86 0.38 1.87 0.34 0.95 0.8 2.3 0.3 1.26 0.62 3.10 1.64 2.36 1.24 0.73 2.70 1.21 0.62 2.4 0.49 1.19 0.52 3.5 0.93 1.28 1.00 4.37 0.81 1.97 0.45 2.42 0.44 1.165 0.62 3.38 0.67 1.821 0.14 0.35 0.23 0.33 0.17 0.28 Lu Y 1.34 0.22 13.6 1.3 0.21 14.5 1.43 0.79 1.41 1.89 1.74 1.67 1.73 1.69 1.14 0.92 1.88 0.95 1 0.84 1.43 1.27 0.87 1.19 0.99 1.07 1.69 1.09 1.76 0.27 0.12 0.22 0.28 0.25 0.25 0.26 0.25 14.27 8.889 14.75 22.1 19.8 19.4 20 19.6 9.45 0.13 21 0.14 9.71 0.15 12.4 0.18 15.05 11.29 0.15 12.40 0.23 10.85 0.55 13.71 0.25 20.01 0.17 11.69 0.27 17.04 Reference Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Wang Qiang et al., 2004 Zhai et al., 1992 Zhang et al., 1994 Zhang et al., 1994 Xue et al., 2004 Xue et al., 2004 Xue et al., 2004 Xue et al., 2004 Xue et al., 2004 Wang et al., 1987 Ma et al., 1997 Wang et al., 1987 Liu et al., 2005 Liu et al., 2006 Ma et al., 1997 Wang et al., 1987 Wang et al., 1987 Ma et al., 1997 Wang et al., 1987 Wang et al., 1994 Wang et al., 1994 Zhai et al., 1992 Zhang et al., 1994 Zhang et al., 1994 73 District La Ce Pr Nd Sm Eu Gd Tb Dy Ho Jiurui Jiurui Luzhong Luzhong Luzhong Luzhong Luzhong Luzhong Luzhong Luzhong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong 45.23 24.3 22.9 29.57 25.8 27.83 19.42 17.62 19.65 17.7 19.65 15.47 17.92 21.65 24.92 28.48 22.19 53.51 30.03 58.3 49.1 56.7 40.6 55.3 68.7 38 29.6 25.8 17.3 17.2 26.4 19.4 85.658 50.326 46.9 59.34 48.86 58.88 39.34 40.66 37.99 39.24 37.99 32.48 31.71 36.58 44.32 56.15 43.97 95.68 57.05 115.6 104.8 107.2 79.3 87.5 122 94.7 59.3 48.9 34.6 34.7 54.9 39.3 8.174 4.696 5.35 6.47 6.15 6.68 4.39 5.52 4.99 5.49 4.99 4.61 3.79 5.16 6.118 7.671 6.07 11.97 7.15 13.3 11.9 11.8 8.22 9.8 14.7 12.9 6.47 6.15 3.84 4.23 6.41 4.39 33.23 19.58 23.82 23.12 23.41 26.85 17.71 19.12 17.69 20.72 17.69 16.62 13.98 19.31 23.76 30.61 21.62 42.87 23.75 49.2 46 43.9 29.1 31.2 50.8 52.7 23.1 23.4 14.9 16.6 25.7 17.1 5.304 3.439 4.29 4.87 4.84 5.7 2.97 4.09 3.52 4.69 3.52 3.43 3.03 3.44 4.556 6.216 4.36 7.22 4.36 9.91 9.69 8.7 5.74 5.49 9.48 11.85 4.87 4.84 3 2.85 5.27 2.97 1.306 0.693 1.13 1.12 0.98 1.25 0.99 1.49 1.03 1.31 1.03 0.83 0.74 0.903 1.277 1.583 1.29 1.76 1.02 1.8 1.82 1.56 1.32 1.45 1.73 3.3 1.12 0.984 0.793 0.755 1.63 0.985 3.564 2.927 3.56 3.85 3.57 4.61 2.67 3.97 3.09 4.15 3.09 2.58 2.41 2.806 3.909 5.747 3.3 4.6 3 7.1 7.18 6.71 4.69 4.46 7.21 8.6 3.85 3.57 2.13 2.14 4.17 2.67 0.43 2.26 0.42 0.57 3.27 0.65 2.78 0.35 0.55 3.05 0.58 0.46 2.44 0.46 0.6 3.39 0.67 0.39 1.94 0.34 0.52 2.7 0.55 0.46 2.35 0.49 0.57 2.6 0.51 0.46 2.35 0.49 0.37 1.88 0.39 0.35 1.7 0.36 0.51 2.08 0.49 0.67 2.88 0.66 0.97 4.09 0.88 0.46 2.13 0.43 0.62 2.53 0.49 0.52 2.29 0.46 0.89 4.42 0.85 0.9 4.66 0.89 0.8 4.21 0.8 0.78 4.48 0.95 0.55 3.18 0.66 0.97 5.1 1.03 1.22 6.68 1.31 0.55 3.05 0.58 0.46 2.44 0.46 0.32 1.72 0.36 0.3 1.74 0.33 0.53 2.62 0.49 0.39 1.94 0.34 Er Tm Yb Lu Y Reference 1.042 1.945 1.59 1.78 1.28 1.89 0.95 1.29 1.3 1.29 1.3 1.04 0.99 1.028 1.7 2.276 1.1 1.22 1.24 2.39 2.51 2.47 2.84 2.03 3.06 3.71 1.78 1.28 0.917 0.953 1.26 0.95 0.16 0.32 0.35 0.25 0.2 0.3 0.11 0.15 0.2 0.19 0.2 0.16 0.15 0.26 0.3 0.36 0.16 0.2 0.21 0.38 0.38 0.37 0.41 0.37 0.49 0.58 0.25 0.2 0.15 0.14 0.15 0.11 0.15 0.3 0.25 0.25 0.19 0.31 0.13 0.12 0.19 0.18 0.19 0.17 0.16 0.19 0.26 0.29 0.16 0.17 0.19 0.38 0.39 0.39 0.42 0.45 0.51 0.57 0.25 0.19 0.15 0.15 0.17 0.13 10.5 17.68 14.5 17 9 19 9 10 12 12 12.3 9.55 8.61 10.76 15.35 22.01 10.98 12.12 12.39 25.3 26.3 24.5 31 19.7 29 38.3 16.9 8.55 9.62 9.32 12.4 9.41 Zhang et al., 1994 Zhang et al., 1994 Qiu et al., 1990 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Xu et al., 1997 Xu et al., 1997 Xu et al., 1997 Xu et al., 2000 Xu et al., 2000 Xu et al., 2000 Xu et al., 2000 Zhang et al., 1994 Zhang et al., 1994 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 0.95 1.99 1.54 1.73 1.29 1.97 0.8 0.87 1.26 1.16 1.26 1.04 0.97 1.08 1.58 1.85 1.03 1.1 1.24 2.5 2.55 2.54 2.58 2.73 3.35 3.76 1.73 1.29 0.98 0.91 1.07 0.8 74 District La Ce Pr Nd Sm Eu Gd Luzong Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningzhen Ningzhen Ningzhen 20.7 19.48 14.9 20.3 94.2 15.63 23.31 19.13 19.13 20.26 26.89 26.56 34.13 35.72 25.84 21.89 37.92 41 53.76 49.77 26.91 28.86 19.48 16.85 20.14 30.34 28.84 99.62 38.91 38.00 41.3 48.6 40.1 41 36.8 43.9 156.5 35.26 47.09 40.09 39.75 42.08 54.01 54.45 66.54 69.46 53.04 45.2 76.29 71.47 102 95.36 53.16 54.81 41 36.69 40.69 66.14 56.05 206.3 78.94 69.50 70.9 73.8 5.27 4.54 5.45 6.07 21.34 4.14 5.12 4.38 4.61 4.98 5.95 6.07 7.03 7.45 6.03 5.08 8.32 18.7 19.32 18.3 21 49.37 17.41 21.59 18.23 19.86 20.78 23.22 25.28 27.5 29.19 24.26 21.11 34.04 35.1 38.92 41.66 23.27 24.35 19.32 19.62 18.03 31.3 23.29 88.27 35.97 29.50 28.3 23.2 3.82 4.44 4.65 5.2 9.7 3.71 4.5 4.04 4.3 4.62 4.46 5.49 5.52 5.79 5.03 4.44 6.52 5.82 7.31 6.75 4.96 4.91 4.44 4.65 3.85 6.34 4.27 16.81 6.95 4.76 4.50 3.58 1.09 1.34 1.59 1.68 0.88 0.78 1.2 0.98 1.26 1.48 1.23 1.45 1.48 1.56 1.31 1.29 1.74 1.61 2.47 2.34 1.33 1.33 1.34 1.38 1.13 1.89 1.39 4.01 1.83 1.25 1.26 0.94 3.26 4.13 5.19 5.65 11.97 3.36 4.01 3.52 3.94 4.43 4.11 4.76 4.38 4.78 4.4 3.97 5.67 10.08 5.82 4.54 4.33 4.31 8.52 24.14 9.64 7.6 7.0 Tb 0.49 0.66 0.75 0.8 1.74 0.5 0.54 0.52 0.55 0.62 0.57 0.67 0.63 0.65 0.61 0.56 0.72 0.67 5.64 0.81 0.7 4.29 0.63 0.64 4.13 0.66 4.6 0.73 3.62 0.6 5.59 0.9 0.82 11.12 1.35 5.14 0.81 3.16 3.48 0.36 2.93 0.30 Dy Ho Er Tm Yb Lu Y 2.48 3.79 3.81 4.54 9.9 3.27 3.51 3.1 3.36 3.67 3.28 4.01 3.64 3.64 3.45 3.39 4.19 0.52 0.77 0.93 0.83 2.63 0.73 0.7 0.67 0.75 0.77 0.67 0.79 0.71 0.71 0.7 0.71 0.76 1.37 2.1 2.24 2.14 10.03 2.21 2.14 2 2.16 2.21 1.91 2.37 2.05 2.04 2.1 2.14 2.46 0.21 0.32 0.37 0.4 1.19 0.32 0.33 0.34 0.28 0.34 0.3 0.34 0.32 0.31 0.3 0.3 0.2 0.31 0.68 0.27 2.35 0.32 0.3 0.33 0.28 0.28 0.28 0.31 0.3 0.29 0.3 0.3 0.29 0.19 0.29 0.25 0.29 0.19 0.31 0.37 0.29 0.37 0.28 0.34 0.3 13.1 3.85 0.73 1.89 0.3 3.47 0.68 1.85 0.3 3.79 4.21 3.35 4.7 0.77 0.84 0.67 0.94 2.1 2.36 1.83 2.53 0.32 0.37 0.29 0.41 6.73 3.93 2.45 2.31 2.12 1.11 2.94 0.78 2.2 1.16 0.39 1.10 0.38 1.10 0.39 0.31 1.33 2.06 2.49 2.42 10.6 0.28 2.32 2.23 2.18 2.19 2.08 2.19 2.09 2.1 1.98 2.09 1.93 1.36 1.92 1.7 1.89 1.39 2.06 2.4 1.9 2.47 2.01 2.32 1.91 1.12 0.90 0.99 Reference Wang et al., 2006 Xu et al., 1999 Xu et al., 1999 Xu et al., 1999 Xu et al., 1999 19.5 Wang et al., 2001 19.2 Wang et al., 2001 18.1 Wang et al., 2001 19.2 Wang et al., 2001 20.1 Wang et al., 2001 17.8 Wang et al., 2001 21.2 Wang et al., 2001 18.8 Wang et al., 2001 19.6 Wang et al., 2001 18.8 Wang et al., 2001 18.7 Wang et al., 2001 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 11.68 Wang et al., 1987 0.15 Xia, 2000 0.15 Xia, 2000 75 District La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y Reference Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen 32.5 34.9 36.7 37.4 37.5 37.7 40.1 42.0 45.1 37.00 45.00 37 27.21 29.41 35.54 40.31 22.1 47.11 49.93 35.00 46.00 35.44 38.11 45.1 37.5 37.4 40.1 36.7 37.7 32.5 34.9 42 59.0 67.1 68.7 73.1 71.9 60.9 78.1 84.1 73.7 60.00 81.00 60 53.41 50.71 65.41 69.89 38.8 72.76 99.39 69.00 97.00 63.014 64.542 73.7 71.9 73.1 78.1 68.7 60.9 59 67.1 84.1 6.1 6.6 6.7 7.2 6.8 7.1 7.8 8.3 8.0 7.90 12.00 22.6 23.2 23.0 25.2 23.5 25.2 26.9 30.7 27.6 75.00 40.00 75 21.36 24.31 21.40 27.27 17.9 22.57 43.07 38.00 50.00 22.82 23.64 27.6 23.5 25.2 26.9 23 25.2 22.6 23.2 30.7 3.91 3.89 3.56 4.00 3.71 4.07 4.20 5.20 4.41 6.00 6.10 6 5.10 4.88 4.44 4.60 2.47 3.44 7.78 6.30 8.90 3.7 3.756 4.41 3.71 4 4.2 3.56 4.07 3.91 3.89 5.2 1.16 1.36 1.28 1.40 1.33 1.35 1.39 1.53 1.36 1.05 1.53 1.05 1.25 1.30 1.10 1.16 0.62 0.88 1.37 1.65 2.60 1.124 1.099 1.36 1.33 1.4 1.39 1.28 1.35 1.16 1.36 1.53 2.80 3.55 3.36 3.44 3.44 3.48 3.40 3.82 3.69 2.70 4.70 2.7 3.66 3.97 2.71 3.38 2.09 2.84 5.78 4.50 6.40 2.708 2.654 3.69 3.44 3.44 3.4 3.36 3.48 2.8 3.55 3.82 0.39 0.37 0.37 0.39 0.37 0.40 0.42 0.55 0.47 0.30 0.62 0.3 0.81 0.79 0.28 0.36 0.3 0.33 1.00 0.63 0.79 0.35 0.32 0.47 0.37 0.39 0.42 0.37 0.4 0.39 0.37 0.55 1.95 1.93 1.92 2.01 1.92 2.10 2.12 2.80 2.29 1.47 2.80 0.30 0.30 0.32 0.32 0.31 0.34 0.35 0.47 0.40 0.34 0.79 0.81 0.85 0.84 0.89 0.84 0.89 0.94 1.28 1.04 0.81 1.75 0.10 0.10 0.11 0.11 0.11 0.12 0.12 0.16 0.14 8.9 8.4 8.2 8.1 7.5 8.8 9.2 12.4 10.4 8.80 17.10 2.87 2.61 1.87 3.31 1.56 2.01 4.57 3.40 4.20 2 1.75 2.29 1.92 2.01 2.12 1.92 2.1 1.95 1.93 2.8 0.68 0.69 0.30 0.39 0.3 0.36 0.86 0.76 0.83 0.37 0.33 0.4 0.31 0.32 0.35 0.32 0.34 0.3 0.3 0.47 1.72 1.70 0.91 1.19 0.83 1.01 2.41 1.53 1.67 1.107 0.847 1.04 0.84 0.89 0.94 0.84 0.89 0.81 0.85 1.28 0.21 0.11 0.18 0.17 0.1 0.12 0.11 0.13 0.13 0.12 0.14 0.14 0.19 0.16 0.30 0.60 0.3 0.11 0.15 0.21 0.18 0.08 0.15 0.34 0.31 0.30 0.15 0.12 0.16 0.12 0.13 0.14 0.13 0.14 0.12 0.11 0.19 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Xu et al., 2001 Zhai et al., 1992 Zhai et al., 1992 Ma et al., 1997 Zhang, 1998 Zhang, 1998 Zhang, 1998 Zhang, 1998 Zhao et al., 1999 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhang et al., 1994 Zhang et al., 1994 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 5.78 5.88 6.33 7.64 4.57 6.88 12.74 8.90 11.80 5.68 6.049 8.04 6.8 7.18 7.76 6.68 7.08 6.14 6.58 8.27 0.15 0.11 0.14 0.11 0.11 0.12 0.11 0.12 0.1 0.1 0.16 0.78 0.79 0.88 0.86 0.81 0.91 0.94 1.16 1.06 0.74 1.23 0.74 0.87 0.96 1.47 1.41 0.76 0.99 2.08 1.35 1.30 0.97 0.79 1.06 0.81 0.86 0.94 0.88 0.91 0.78 0.79 1.16 13.98 14.79 10.51 10.48 8.02 0.00 23.40 15.60 18.40 10.09 8.517 10.4 7.5 8.1 9.2 8.2 8.8 8.9 8.4 12.4 76 District La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Ningzhen Ningzhen Suzhou Suzhou Suzhou Suzhou Suzhou Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling 75.4 48.6 20.69 34.80 42.90 53.10 62.10 33.77 34.94 37.09 42.67 42.97 45.84 46.4 45.27 39.12 42.96 45.71 48.52 50.98 51.07 45.5 50.99 57.98 46.7 51.2 45.63 20.7 50.4 37.35 39.56 40.1 142 102 40.03 71.70 81.50 94.90 113.00 75.66 73.02 82.84 85.26 95.13 89.19 88.9 87.62 84.12 87.22 95.7 103 102.1 92.94 96.6 100.93 113.37 83.7 91.1 85.64 43.2 104.9 74.45 81.27 79.59 13.8 10.3 4.36 7.30 10.50 11.00 13.90 8.97 8.96 10.19 10.12 11.08 10.56 9.99 9.11 11.57 11.33 12.9 12.33 12.76 12.71 11.9 11.91 14.29 11.1 11.34 9.64 6.54 49.3 39.9 16.20 27.40 37.20 34.00 47.20 30.53 28.57 35.29 33.85 37.12 35.56 35.2 37.12 36.72 39.67 44.42 46.35 45.94 43.25 46.7 43.74 48.44 42.9 27 34.58 22.3 50.2 30.28 35.32 33.91 7.79 7.08 3.85 5.60 8.70 8.40 10.30 6.17 5.95 7.22 6.69 6.97 7.04 6.59 7.36 8.25 8.18 9.44 9.34 9.44 8.85 8.9 8.8 9.06 7.73 7.36 6.57 3.69 9.6 5.81 7.29 6.93 2.38 2.04 0.65 1.28 0.44 0.88 0.76 2.31 2.18 2.44 2.51 2.57 2.44 1.83 2.04 2.06 2.08 2.29 2.15 2.28 2.07 2.16 2.26 2.35 2.08 2.16 1.64 0.78 2.58 1.51 1.9 1.82 5.9 4.95 3.48 4.80 8.80 5.40 10.52 9.21 8.73 10.29 9.63 10.61 10.09 6.79 5.92 8.46 6.91 7.68 7.18 7.51 7.43 6.6 6.37 6.63 6.63 6.2 4.58 2.98 6.4 4.26 5.69 5.36 0.72 0.77 0.70 2.50 2.10 2.40 0.10 1.08 1.04 1.17 1.08 1.17 1.13 0.86 0.88 0.95 0.81 0.87 0.86 0.85 0.84 0.92 1.12 1.01 0.92 0.84 0.7 0.4 0.89 0.55 0.81 0.81 3.54 3.93 3.47 3.80 12.40 15.20 12.13 4.83 4.65 5.35 4.84 5.31 5.09 4.2 4.65 4.78 4.66 5.09 4.81 4.88 4.77 4.29 5.17 4.57 4.76 4.19 3.99 2.16 0.55 0.67 0.84 0.90 3.10 3.80 0.00 0.98 0.89 1.08 1.02 1.05 1.04 0.84 0.92 1.07 0.95 1.03 0.99 1.02 1.01 0.91 0.93 0.94 0.9 0.8 0.69 0.4 1.41 1.74 2.33 2.70 8.60 11.11 7.00 2.47 2.43 2.68 2.51 2.55 2.49 2.44 2.5 2.28 2.05 2.32 2.12 2.12 2.2 2.14 2.25 2.58 2.35 2.08 1.86 1.16 0.17 1.23 0.19 0.23 1.64 0.26 2.61 0.34 2.50 0.40 11.80 1.70 15.70 2.20 9.30 1.30 0.3 1.92 0.21 0.29 1.97 0.22 0.31 2.08 0.22 0.29 1.98 0.21 0.32 2.27 0.24 0.33 2.22 0.22 0.34 2.38 0.37 0.39 2.34 0.34 0.4 2.6 0.68 0.31 2.11 0.31 0.34 2.31 0.32 0.31 2.08 0.28 0.32 2.17 0.3 0.36 2.34 0.32 0.33 2.26 0.36 0.3 2.35 0.4 2.25 0.32 0.32 2.11 0.32 0.27 1.75 0.27 0.32 1.89 0.3 0.2 1.07 0.18 1.61 0.21 0.28 1.89 0.23 0.4 2.64 0.36 0.38 2.57 0.34 7.85 9.12 8.69 3.32 0.62 1.77 4.48 0.9 2.92 4.44 0.88 2.79 Lu Y Reference 13.7 Wang et al., 2006 16.9 Wang et al., 2006 22.00 Zhai et al., 1992 22.70 Zhai et al., 1992 86.00 Zhai et al., 1992 102.80 Zhai et al., 1992 73.60 Zhai et al., 1992 18.3 Huang et al., 2004 18.1 Huang et al., 2004 19.8 Huang et al., 2004 18.9 Huang et al., 2004 20.9 Huang et al., 2004 19.2 Huang et al., 2004 21 Wang et al., 2004 Xu et al., 1999 Xu et al., 2004 Xu et al., 2004 Xu et al., 2004 Xu et al., 2004 Xu et al., 2004 Xu et al., 2004 25.7 Zhao et al., 2004 24.89 Zhao et al., 2004 24.02 Zhao et al., 2004 21.8 Tian et al., 2004 21.7 Tian et al., 2004 Ling et al., 2003 12 Zhao et al., 1999 Ma et al., 1997 15.93 Shao et al., 2003 24.45 Shao et al., 2003 25.28 Shao et al., 2003 77 District La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling 43.84 44.37 48.16 33.6 40.6 43.9 50.40 36.5 40.4 59.28 60.98 41.5 37.46 36.2 45.18 35.86 32.3 36.73 47.48 51.39 51.41 52.12 53.92 21.6 26.1 35.5 38.8 32.3 36.73 47.48 49.43 51.4 75.08 86.48 87.45 70.7 87.7 86.9 104.90 69.3 78.1 125.61 115.68 79.7 69.34 76.3 88.64 60.58 63.66 75.29 88.24 98.25 96.15 99.75 101.9 47.9 55.5 95.8 72.7 63.64 75.29 88.24 91.96 98.25 8 9.57 9.18 7.68 9.69 9.44 13.75 7.69 8.33 15.17 12.01 9.62 8.6 8.96 10.78 7.88 7.78 8.02 10.59 10.86 10.61 10.69 11.29 5.48 6.22 7.39 9.51 7.78 8.02 10.5 10.34 10.86 30.02 37.37 34.67 28.4 35.4 33.3 50.52 27 30 53.4 47.97 32.98 29.21 32.4 35.10 28.34 27.03 29.59 37.58 38.49 39.42 40.02 41.87 20.3 23.4 29.7 37 27.03 29.59 37.58 37.99 38.5 5.53 7.57 6.95 5.3 6.96 5.83 9.62 5.01 5.48 9.74 8.71 6.36 5.33 6.19 6.50 4.88 4.72 5.29 6.52 6.51 6.82 6.76 7.38 4 4.29 5.59 5.89 4.72 5.29 6.52 6.72 6.51 1.44 1.69 1.81 1.41 1.58 1.48 2.58 1.39 1.58 2.69 2.38 1.61 1.38 1.92 1.64 1.22 1.39 1.38 1.87 1.88 1.86 1.91 2.01 1.07 0.98 1.64 1.6 1.39 1.38 1.87 1.91 1.88 4.53 6.07 5.83 5.42 6.57 6.45 6.40 5.2 5.93 7.83 6.95 4.73 3.95 6.27 4.98 2.94 4.43 4.99 6.32 6.17 5.84 6.35 6.82 3.62 4.24 4.86 4.84 4.43 4.99 6.14 6.15 6.17 0.65 0.89 0.91 0.61 0.75 0.71 0.89 0.58 0.67 1.12 1.01 0.8 0.6 0.71 0.80 0.54 0.48 0.53 0.7 0.69 0.66 0.73 0.75 0.37 0.39 0.64 0.7 0.48 0.53 0.7 0.67 0.69 3.7 4.68 4.97 3.34 4.17 3.8 3.90 2.59 3.35 4.76 5.04 3.67 2.65 3.32 3.75 2.61 2.53 2.79 3.43 3.39 3.55 3.58 3.96 1.59 1.65 3.15 3.65 2.53 2.79 3.43 3.62 3.39 0.71 0.87 0.99 0.64 0.83 0.74 0.75 0.48 0.69 0.96 0.97 0.71 0.52 0.63 0.75 0.68 0.52 0.55 0.72 0.72 0.72 0.71 0.81 0.31 0.32 0.65 0.7 0.52 0.55 0.72 0.74 0.72 2.14 2.65 3 1.96 2.28 2.15 1.85 1.38 1.96 2.81 2.59 1.89 1.38 1.67 2.05 1.49 1.44 1.52 2.04 2.03 2 2.03 2.22 0.81 0.78 1.79 1.85 1.44 1.52 2.04 2.04 2.03 0.35 0.36 0.42 0.31 0.35 0.35 0.29 0.33 0.38 0.27 0.35 0.31 0.21 0.2 0.29 0.38 0.37 0.29 0.18 0.22 0.31 0.17 0.21 0.23 0.3 0.29 0.31 0.3 0.32 0.11 0.12 0.22 0.22 0.21 0.23 0.3 0.3 0.3 18.92 25.08 28.5 15 20 18 18.58 14 19 0.2 0.32 0.44 0.39 0.37 0.23 0.23 0.37 0.21 0.22 0.28 0.28 0.29 0.28 0.31 0.12 0.13 0.3 0.3 0.21 0.22 0.28 0.29 0.28 2.08 2.13 2.74 1.87 2.39 2.04 1.61 1.34 1.96 2.55 2.49 1.91 1.29 1.39 2.04 1.14 1.19 1.32 1.76 1.68 1.76 1.81 1.85 0.72 0.87 1.39 1.62 1.19 1.32 1.76 1.76 1.68 Reference Shao et al., 2003 Shao et al., 2003 Shao et al., 2003 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Zhai et al., 1992 Wang et al., 2004 Wang et al., 2004 Xu et al., 1999 Xu et al., 1999 18.91 Qiu et al., 1994 13.41 Qiu et al., 1994 15 Wang et al., 2004 19.21 Zhai et al., 1992 Huang et al., 2004 12.5 Huang et al., 2004 13.4 Huang et al., 2004 16.9 Huang et al., 2004 17.3 Huang et al., 2004 16.5 Huang et al., 2004 17 Huang et al., 2004 19.6 Huang et al., 2004 8 Wang et al., 2004 8 Wang et al., 2004 19.9 Zhao et al., 1999 19.8 Zhao et al., 1999 Jiang et al., 2001 Jiang et al., 2001 Jiang et al., 2001 Jiang et al., 2001 Jiang et al., 2001 78 District La Ce Pr Nd Sm Eu Gd Tb Dy Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling 51.41 53.92 34.4 38.2 38.84 31.31 34.89 35.16 36.3 37.04 41.77 41.96 42.19 42.57 42.65 42.8 44.28 44.56 38.3 45.8 25.79 38.16 58.27 54.2 43.7 39.7 38.39 32 37 37 33.3 39.72 96.15 102 64.69 69.3 73.18 66.37 75.36 68.36 69.85 71.99 80.08 83.07 82.67 82.95 85.42 83.56 91.93 85.81 75.1 91.2 58.35 69.29 111.50 94.3 83.2 75.7 72.86 60 73 74.6 65.4 75.69 10.61 11.29 7.34 39.42 41.87 26.35 28.1 31.04 31.29 36.17 27.75 28.08 28.83 32.69 34.32 34.06 33.87 37.92 35.14 44.01 38.66 30.1 36.8 37.60 28.13 45.95 49.1 33.2 32.1 31.59 27.33 34 38.5 27.9 32.14 6.82 7.38 5.02 5.3 5.91 6.5 7.8 5.23 5.03 5.08 5.84 6.21 6.08 6.22 7.51 6.29 9.13 7.75 5.68 6.62 8.04 5.33 8.41 7.65 5.74 5.9 5.83 4.57 5.6 7.5 4.89 5.92 1.86 2.01 1.32 1.37 1.56 1.58 1.87 1.47 1.36 1.35 1.64 1.75 1.64 1.71 1.91 1.72 2.12 1.82 1.62 1.9 2.43 1.37 2.11 1.93 1.67 1.54 1.57 1.25 1.73 1.845 1.38 1.54 5.84 6.82 3.42 3.8 4.46 4.98 5.95 4.53 4.42 4.19 5.01 5.16 5.07 5.44 6.15 5.26 6.79 5.77 5.89 7.64 6.74 3.76 5.94 6.12 6.52 4 4.41 3.5 5.1 5.95 5.48 3.99 0.66 0.75 0.63 0.6 0.67 0.63 0.76 0.62 0.61 0.58 0.67 0.71 0.72 0.69 0.81 0.69 0.85 0.7 0.66 0.91 1.11 0.60 0.91 0.9 0.8 0.58 0.66 3.55 0.72 2 3.96 0.81 2.22 2.96 0.53 1.33 8.63 7.84 8.91 7.4 7.62 7.59 8.68 9.04 8.79 8.96 9.43 8.96 10.96 10.1 8.39 9.96 8.87 8.24 13.21 13 9.11 8.91 7.4 9.15 3.56 3.33 4.1 3.48 3.26 3.42 3.99 3.87 3.79 3.94 4.29 3.86 4.4 3.71 3.48 4.21 4.70 2.91 4.29 4.12 3.82 Ho 0.66 0.63 0.78 0.6 0.61 0.6 0.74 0.75 0.7 0.71 0.81 0.71 0.79 0.68 0.63 0.78 0.87 0.60 0.84 0.8 0.83 Er 1.77 1.68 2.11 1.64 1.78 1.82 1.92 2.02 1.94 2.11 2.28 1.96 2.21 1.85 1.66 2.43 2.16 1.69 2.22 2.02 2.36 2.65 0.52 1.38 1.93 0.93 3.5 1.74 5.5 3.1 0.61 2.88 0.41 1.45 0.58 2.64 0.51 1.29 Tm Yb Lu 0.29 1.76 0.31 0.31 1.85 0.32 1.3 0.21 1.8 0.27 0.34 1.71 0.27 0.26 1.75 0.26 0.32 2.02 0.31 0.22 1.71 0.25 0.23 1.73 0.24 0.23 1.72 0.25 0.25 1.97 0.29 0.29 1.96 0.31 0.28 1.91 0.3 0.26 2.06 0.29 0.29 2.04 0.28 0.28 1.96 0.3 0.32 2.08 0.32 0.28 1.82 0.28 0.26 1.57 0.24 0.36 2.36 0.36 1.66 0.25 1.80 0.27 2.15 0.30 0.3 1.82 0.28 0.34 2.18 0.34 1.24 0.17 0.23 1.29 0.18 0.92 1.76 2.7 0.21 1.28 0.21 1.24 0.17 Y 17.24 19 22 18 17 18 20 20 20 20 22 20 23 20 15 20 20.63 16.88 22.70 22.1 20 14.82 9.8 17.4 28.5 13 13.65 Reference Jiang et al., 2001 Jiang et al., 2001 Ling et al., 1998 Ma et al., 1997 Qiu et al., 1994 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2003 Wang et al., 2004 Wang et al., 2004 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhao et al., 1999 Wang et al., 2004 Ma et al., 1997 Qiu et al., 1994 Wang et al., 1987 Wang et al., 1987 Wang et al., 1987 Wang et al., 2004 Zhai et al., 1992 79 District La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling 42.17 43.3 29.1 25.41 48.67 29.02 67.8 14.92 31.96 38.47 80.00 86 59.9 54.35 98.79 59.38 140 88.6 66.272 76.996 9.53 9.39 7.08 7.08 12.06 7.43 15.9 8.983 8.874 7.664 33.58 35 26 24.99 41.29 25.23 60.8 38.92 33.49 32.75 6.75 6.43 4.74 4.83 7.62 4.85 9.92 7.05 5.952 5.737 2.33 1.79 1.49 1.42 2.04 1.32 2.26 2.059 1.736 1.652 4.72 7.02 4.82 3.45 5.89 3.79 7.46 5.655 4.567 4.186 0.70 0.88 0.51 0.54 0.94 0.64 0.92 0.88 0.6 0.51 3.25 4.82 2.33 2.15 4.49 3.04 3.75 4.62 3.46 2.91 0.63 0.92 0.45 0.39 0.92 0.60 0.76 0.89 0.69 0.55 0.61 2.8 1.1 0.97 2.55 1.73 2 2.431 1.666 1.395 1.52 0.22 0.43 2.77 0.43 0.15 0.98 0.15 0.86 0.13 2.53 0.39 1.80 0.28 0.3 1.42 0.23 0.4 2.38 0.36 0.22 1.56 0.22 0.21 1.23 0.19 Y Reference 16.59 24 10 10.12 23.89 16.21 23.1 14.75 17.01 14.14 Zhai et al., 1992 Wang et al., 2004 Wang et al., 2004 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Zhao et al., 1999 Zhang et al., 1994 Zhang et al., 1994 Zhang et al., 1994 83 Appendix E Lead Isotope Data for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley. District Locality Number Sample Sample description 206 Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Jiurui Jiurui Jiurui Jiurui Hongzhen Huaining Tongshan Tongshan Tongshan Tongshan Tongshan Yueshan Yueshan Yueshan Yueshan Echeng Echeng Jinshandian Jinshandian Lingxiang Tieshan Tieshan Tieshan Tieshan Tieshan Tieshan Tieshan Tonglushan Tongshankou Tongshankou Yangxin Yangxin Yinzu Chengmenshan Chengmenshan Fenshandong Wushan AHZ3-M2 01LJ025 T-1 T-2 T-3 WR WR WR WR WR WR WR Pl Pl WR Pl Fsp WR WR WR WR Fsp WR WR WR Zrn Zrn Fsp Fsp Fsp WR WR WR WR Kfs Kfs WR Pl granite basalt granodiorite qtz diorite monzogranite qtz diorite granodiorite quartz diorite diorite monzodiorite qtz monzodiorite granite diorite gabbro quartz diorite basalt quartz diorite diorite diorite xenolith augite diorite augite diorite quartz diorite quartz diorite granodiorite granodiorite diorite xenolith diorite granodiorite porphyry quartz porphyry granodiorite granodiorite 17.947 18.179 18.518 18.438 19.082 18.44 18.52 17.846 17.813 17.99 18.093 18.123 17.998 17.921 18.446 18.149 17.886 17.933 17.917 17.811 18.871 18.663 17.92 18.047 18.109 18.024 18.273 18.244 17.813 18.042 18.833 18.08 17.8 AC-148 AY2-m3 AYS-1 Y345 2 HE2-M1 groug2 groug3 86-99 14 group4 HT12-M3 HT1-B1 T01 T02 T1 16 18 HY2-M1 HY3-B1 AY2-M3 c20 c21 f21 w323 Pb/204Pb 207 Pb/204Pb 15.557 15.462 15.529 15.545 15.617 15.55 15.53 15.484 15.52 15.67 15.561 15.506 15.458 15.31 15.481 15.463 15.453 15.442 15.513 15.491 16.053 15.897 15.5 15.517 15.534 15.508 15.548 15.573 15.52 15.572 15.72 15.57 15.555 208 Pb/204Pb 38.23 38.101 38.645 38.629 39.025 38.63 38.65 37.811 38.067 38.262 38.073 38.408 38.26 38.233 39.257 38.522 37.498 38.141 38.151 38.147 39.833 39.287 38.4 38.381 38.353 38.233 38.527 38.568 38.067 37.933 37.814 38.47 37.743 References Zhai et al., 1992 Yan et al., 2003 Yu, 2001 Yu, 2001 Yu, 2001 Yu, 2000 Yu, 2000 Xing et al., 1996 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Pan et al., 1999 Zhai et al., 1992 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Zhai et al., 1992 Zhai et al., 1992 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Zhang, 1994 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Pan et al., 1999 Pan et al., 1999 Liu et al., 2004 Pan et al., 1999 84 District Locality Number Sample Sample description 206 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb Jiurui Jiurui Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Wushan Wushan Bajiatan Bajiatan Chengshan Chengshan Chengshan Chengshan Dalongshan Dalongshan Dalongshan Dalongshan Fushan formation w323 w34 B-44 B-58 1005 1059 1079 2005 1030 1249 1295 3003 98LZ082 Py Kfs WR WR Kfs Kfs Kfs Kfs WR Kfs Kfs Kfs WR granodiorite granodiorite pyx monzonite bt monzonite alkali fsp granite bt qtz syenite alkali fsp granite qtz syenite hbl qtz syenite alkali fsp granite bt syenite alkali fsp granite shoshonitic volcanic rocks 18.002 17.954 18.151 18.02 17.902 17.952 18.34 18.019 18.016 18.775 18.11 18.526 18.384 15.524 15.536 15.559 15.529 15.479 15.52 15.541 15.495 15.453 15.567 15.492 15.564 15.517 37.991 38.131 38.196 38.07 38.187 38.096 38.538 38.317 38.151 38.785 38.283 39.112 38.537 Luzong Jiaochong 98LZ056 WR shoshonitic intrusive rocks 18.352 15.496 38.296 Luzong 98LZ043 WR shoshonitic volcanic rocks 18.834 15.544 38.796 Luzong Luzong Luzong Longmenyuan formation Luzong Luzong Luzong 1 2 98LZ087 WR WR WR latitie latitie A-type granite 18.37 18.613 18.216 15.535 15.464 15.48 38.64 38.76 38.436 Luzong Luzong 98LZ101 WR A-type granite 18.883 15.537 39.075 Luzong Luzong Shuangmiao Maowangmiao 01AQ139 98LZ097 WR WR basalt shoshonitic intrusive rocks 18.204 18.094 15.625 15.533 38.482 38.284 Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Maowangmiao Maowangmiao Maowangmiao Maowangmiao Maowangmiao Quekou Quekou Quekou Shaxi WR WR WR WR WR WR WR WR WR monzonite porphyry syenite monzogranite monzonite porphyry monzonite porphyry pyx diorite gabbro gabbro adakitic intrusive rocks 18.206 18.345 17.992 17.914 18.253 18.365 18.182 18.302 18.383 15.657 15.72 15.497 15.635 15.627 15.552 15.492 15.51 15.477 38.735 39.039 38.249 38.314 38.437 38.432 38.113 38.174 38.282 Luzong Shuangmaio YT-006-1 YT-012-1 YT-015 YT-029-6 YX-005-3 01LJ030 01LJ032 01LJ035 98LZ0041 98LZ060 WR shoshonitic volcanic rocks 18.249 15.494 38.205 References Pan et al., 1999 Pan et al., 1999 Yang et al., 1993 Yang et al., 1993 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Yu, 1981 Yu, 1981 Wang et al., 2006 Wang et al., 2006 Yan et al., 2003 Wang et al., 2006 Yang et al., 1993 Yang et al., 1993 Yang et al., 1993 Yang et al., 1993 Yang et al., 1993 Yan et al., 2003 Yan et al., 2003 Yan et al., 2003 Wang et al., 2006 Wang et al., 85 District Locality Number Sample Sample description 206 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb 98LZ062 WR shoshonitic volcanic rocks 18.207 15.492 38.161 AC-99 31 34 146 288 Surficial 98LZ045 WR Py Py Py Py Gn WR basalt trachyandesite porphyry trachyandesite porphyry trachyandesite porphyry trachyandesite porphyry trachyandesite porphyry shoshonitic volcanic rocks 17.405 18.1129 18.3026 18.317 18.206 18.2485 18.413 15.472 15.5588 15.7455 15.572 15.7622 15.5775 15.618 37.647 38.2891 38.8924 38.4261 38.9719 38.2584 38.546 17.592 18.375 18.22 18.171 15.52 15.589 15.52 15.532 38.096 38.371 38.4 38.143 Wang et al., 2006 Xing, 1998 Ge et al., 1989 Ge et al., 1989 Ge et al., 1989 Ge et al., 1989 Ge et al., 1989 Wang et al., 2006 Pan et al., 1999 Xing, 1996 Xing et al., 1998 Zhou et al., 2000 formation Luzong References 2006 Luzong Luzong Luzong Luzong Luzong Luzong Luzong Shuangmaio formation Shuangmiao Yueshan Yueshan Yueshan Yueshan Yueshan Zhuanqiao formation Luzong Ningwu Ningwu Ningwu 213 Aoshan Bingjiang Fangshan Kfs Pl Fang-1 WR syenite gabbrodiorite granite basalt Ningwu Fangshan Fang-2 WR basalt 18.206 15.522 38.099 Zhou et al., 2000 Ningwu Ningwu Ningwu Ningwu Ningwu Fangshan Fushan Gushan Huoli Huoli AC-23 222 AHO51 WR WR Pl Kfs Fsp basalt basalt gabbro granite alkali feldspar granite 18.252 18.15 18.83 18.388 18.392 15.547 15.574 15.74 15.52 15.548 38.369 38.369 38.87 38.27 38.497 Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Huoli Jiangmiao Jiangmiao Jiangmiao Jiangmiao Kedoushan Kedoushan Kedoushan Ma'anshan Nushan 01TL084 01TL085 AC-64 220 NS-1 Kfs Pl WR Pl Pl WR WR WR Pl WR monzogranite gabbro gabbro gabbro gabbro basalt basalt basalt gabbro basalt 18.388 18.592 17.72 18.592 18.473 17.973 17.955 18.062 18.073 17.821 15.52 15.591 15.423 15.591 15.528 15.462 15.439 15.439 15.473 15.44 38.27 38.467 37.702 38.467 38.258 37.947 37.866 37.862 37.951 37.654 Xing, 1998 Xing, 1998 Xing, 1996 Pan et al., 1999 Zhang et al., 1993 Xing, 1996 Pan et al., 1999 Yan et al., 2003 Xing, 1996 Xing, 1996 Yan et al., 2003 Yan et al., 2003 Xing, 1996 Pan et al., 1999 Zhou et al., 2000 Ningwu Nushan NS-19 WR basalt 17.802 15.435 37.636 Zhou et al., 2000 Ningwu Nushan NS-26 WR basalt 17.833 15.448 37.709 Zhou et al., 2000 Ningwu Nushan NS-29 WR basalt 17.852 15.455 37.743 Zhou et al., 2000 Ningwu Nushan NS-30 WR basalt 17.802 15.435 37.661 Zhou et al., 2000 219 01JM001 AC-10 86 District Locality Number Sample Sample description 206 Ningwu Nushan NS-7 WR basalt 17.887 15.464 37.783 Zhou et al., 2000 Ningwu Ningwu Taocun Tashan Ta-1 Ab WR albitite basalt 18.335 18.029 15.63 15.486 38.543 37.856 Xing, 1996 Zhou et al., 2000 Ningwu Tashan Ta-2 WR basalt 18.02 15.484 37.853 Zhou et al., 2000 Ningwu Ningwu Ningwu Ningwu Ningwu Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Yanghutang Yanghutang Yanghutang Yanghutang Zhongjiu Anjishan Anjishan Anjishan Anjishan Anjishan Anjishan 01M110 01M115 01M119 AC-22 WR WR WR Pl Ab WR WR WR WR WR WR pyx diorite pyx diorite pyx diorite gabbro ab diorite intermediate to acid rocks mafic rocks intermediate to acid rocks intermediate to acid rocks diorite granodiorite 18.421 18.375 18.34 18.073 18.268 17.045 17.997 17.148 17.18 17.785 17.318 15.477 15.489 15.542 15.473 15.59 15.479 15.534 15.487 15.483 15.541 15.462 38.369 38.381 38.439 37.951 38.264 37.353 38.267 37.465 37.484 38.012 37.39918 Ningzhen Funiushan WR granodiorite 17.299 15.434 37.357 Ningzhen Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Shima Baimangshan Baimangshan Baimangshan Bijiashan Fenghuangshan Fenghuangshan Fenghuangshan Fenghuangshan Jiguanshan Jiguanshan Jiguanshan Jiguanshan Jinkouling Jinkouling WR WR WR Pl pyx Fsp Fsp Pl WR WR WR hbl py WR WR granodiorite porphyrite pyx diorite pyx diorite gabbro diorite gabbro granodiorite granodiorite granodiorite granodiorite pyx diorite pyx diorite hbl gabbro amphibolite quartz diorite quartz diorite 18.049 18.487 18.463 18.35 18.78 18.683 18.849 18.58 18.213 18.512 18.514 18.268 18.27 17.81 17.49 15.584 15.537 15.532 15.6 15.46 15.578 15.606 15.58 15.577 15.523 15.556 15.578 15.47 15.34 15.35 38.359 38.418 38.355 38.46 37.85 38.776 38.727 38.48 38.41 38.347 38.455 38.117 38.027 37.79 36.69 Yan et al., 2003 Yan et al., 2003 Yan et al., 2003 Xing, 1996 Xing, 1996 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Zhai et al., 1992 Zhang et al., 1994 Zhang et al., 1994 Zhai et al., 1992 Yan et al., 2003 Yan et al., 2003 Xing et al., 1996 Xing et al., 1996 Pan et al., 1999 Pan et al., 1999 Xing et al., 1996 Zhai et al., 1992 Yan et al., 2003 Yan et al., 2003 Xing et al., 1996 Xing et al., 1996 Pan et al., 1999 Pan et al., 1999 Tongling Jinkouling WR qtz diorite 17.49 15.32 36.69 Yang et al., 1989 Tongling Jinkouling Pl diorite 17.934 15.501 37.991 Huang, 1991 25 29 30 31 Ja14-M1 JW3-M1 01TL072 01TL075 AC-21 AC-20 85 86 AC-12 AF1-M1 01TL078 01TL080 AC-409 AC-47 91 NO ck1033102 CK1033102 diorite 201 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb References 87 District Locality Number Sample Sample description 206 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb Tongling Tongling Tongling Tongling Tongling Tongling Jinkouling Jinkouling Jinkouling Maoliantou Maoliantou Mashan diorite 202 diorite 203 M1 01TL101 01TL103 CK342 Pl Pl WR WR WR WR diorite diorite qtz diorite gabbro pyx diorite diorite 17.913 17.8 17.81 18.646 17.672 18.3 15.566 15.492 15.34 15.498 15.454 15.77 38.242 37.976 37.79 38.49 38.248 40.14 Tongling Tongling Tongling Mashan Mashan Mashan diorite 204 diorite 49 Tobdl Pl Pl WR diorite diorite diorite 17.995 17.943 18.19 15.605 15.535 15.6 38.431 38.199 39.84 Tongling Tongling Tongling Tongling Tongling Tongling Tongling Miaojia Shizishan Shizishan Shizishan Shizishan Shizishan Tongguanshan AMS-M1 146 AS 1-M1 AS8-B S-1 85P-16 WR Fsp WR WR Pl WR Fsp diorite porphyrite quartz diorite diorite xenolith granodiorite diorite qtz diorite 18.42 18.219 18.198 18.251 17.9 17.703 17.566 15.592 15.55 15.564 15.574 15.47 15.154 15.411 38.494 38.346 38.342 38.388 38.09 36.422 37.689 Tongling Tongguanshan 85P-19 Fsp qtz diorite 17.512 15.244 37.281 Tongling Tongguanshan A-4-10 Fsp qtz diorite 17.704 15.425 37.763 Tongling Tongguanshan A-4-2 Fsp qtz diorite 18.091 15.691 38.375 Tongling Tongguanshan A-4-4 Fsp qtz diorite 17.769 15.449 38.844 Tongling Tongguanshan A-4-7 Fsp qtz diorite 18.08 15.571 38.122 Tongling Tongguanshan A-4-7 Fsp qtz diorite 18.426 15.589 38.407 Tongling Tongguanshan A-4-9 Fsp qtz diorite 17.938 15.581 38.199 Tongling Tongling Tongling Tongling Tongling Tongling Tongguanshan Tongguanshan Tongguanshan Tongguanshan Tongguanshan Tongguanshan AT1-B1 AT1-M1 CK371-1 diorite 205 diorite 206 diorite 207 WR WR WR Pl Pl Pl xenolith quartz diorite quartz diorite diorite diorite diorite 18.02 17.942 18.13 17.926 17.896 17.678 15.573 15.608 15.67 15.646 15.527 15.446 38.256 38.398 38.5 38.458 38.099 37.766 References Huang, 1991 Huang, 1991 Yang et al., 1989 Yan et al., 2003 Yan et al., 2003 Wang et al., 1996 Huang, 1991 Huang, 1991 Wang et al., 1996 Zhai et al., 1992 Pan et al., 1999 Zhai et al., 1992 Zhai et al., 1992 Xing et al., 1996 Yang et al., 1997 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhai et al., 1992 Zhai et al., 1992 Pan et al., 1999 Huang, 1991 Huang, 1991 Huang, 1991 88 District Locality Tongling Tongling Tongling Tongling Tongling Anqing-Guichi Edong Ningwu Ningwu Ningwu Pacific ocean Pacific ocean Pacific ocean Pacific ocean Pacific ocean Pacific ocean Pacific ocean Tongguanshan Tongguanshan Xinqiao Xinqiao Yaoshan Huaining Lingxiang Kedoushan Kedoushan Kedoushan Number AXQ-Ml AYS-M1 01LJ025 86-99 01TL084 01TL085 AC-64 Sample Sample description 206 Pl WR WR Gn WR WR WR WR WR WR Gn qtz diorite monzodiorite diorite qtz diorite diorite porphyrite Mesozoic basalt Mesozoic basalt Mesozoic basalt Mesozoic basalt Mesozoic basalt mine Ridge mine mine mine mine mine 17.67 18.29 18.433 18.303 18.387 18.179 18.149 17.973 17.955 18.062 18.245 18.355 18.455 18.463 18.47 18.475 18.712 Gn Gn Gn Gn Gn Pb/204Pb 207 Pb/204Pb 15.446 15.59 15.691 15.762 15.652 15.462 15.463 15.462 15.439 15.439 15.569 15.477 15.582 15.589 15.646 15.607 15.621 208 Pb/204Pb 37.776 38.44 38.544 40.362 38.433 38.101 38.522 37.947 37.866 37.862 38.417 37.838 38.552 38.623 38.966 38.633 38.669 References Xing et al., 1996 Qiu, 1994 Zhai et al., 1992 Chen, 2003 Zhai et al., 1992 Yan et al., 2003 Pan et al., 1999 Yan et al., 2003 Yan et al., 2003 Xing, 1996 Doe et al., 1979 Zindler, 1982 Doe et al., 1979 Doe et al., 1979 Doe et al., 1979 Doe et al., 1979 Doe et al., 1979 86 APPENDIX F. Nd and Sr Isotopic Data for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley. District Rock type Sm (10-6) Nd (10-6) 147 Sm/144Nd AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi quartz diorite 2.766 15.82 0.1057 quartz diorite 4.141 19.66 quartz diorite 8.75 143 Nd/144Nd eNd Rb (10-6) Sr (10-6) 87 Rb/86Sr 0.5122 -7 3.304 329 0.029 0.127 0.5122 -6.5 72.6 748 53.02 0.0998 0.5122 -7.4 103 87 Sr/86Sr Isr Reference 0.7076 0.7076 0.2802 0.7067 0.7062 1208 0.2465 0.7070 0.7065 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 6.92 40.4 0.104 0.5121 -9.3 198 120 4.76 0.7177 0.7089 trachyandesite syenite 18.2 87.4 0.126 0.5122 -8 129 101 3.71 0.7146 0.7077 qtz monzonite 5.93 32.5 0.111 0.5121 -8.2 58.3 1589 0.106 0.7066 0.7064 granodiorite 2.77 15.8 0.106 0.5122 -7 92.8 558 0.482 0.7083 0.7074 qtz diorite 10.05 63.93 0.0956 0.5121 -9.08 112.2 527 0.6166 0.7095 0.7084 qtz diorite 8.83 53.05 0.1013 0.5121 -9.77 21.8 569 0.62 0.7092 0.7080 diorite 6.1 35.16 0.1055 0.5122 -6.08 54.4 818 0.1923 0.7068 0.7064 adakitic granite adakitic granite adakitic granite adakitic rocks 3.15 21.6 0.0887 0.5117 99.1 454 0.6323 0.7082 0.7070 3.27 21.86 0.0909 0.5117 97.6 433 0.6528 0.7084 0.7071 3.11 19.47 0.0967 0.5116 100.8 452 0.6451 0.7082 0.7070 6.01 38.86 0.0941 0.5122 17.47 17.01 18.13 -7.55 47.5 1569 0.0875 0.7067 0.7065 87 AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi AnqingGuichi Edong adakitic rocks 4.23 26.12 0.0986 0.5121 -9.62 38.4 1566 0.071 0.7070 0.7069 adakitic rocks 6.28 38.6 0.099 0.5122 -6.63 76.8 1533 0.1449 0.7067 0.7065 adakitic rocks 6.24 37.56 0.1011 0.5122 -7.29 65.3 1507 0.1254 0.7068 0.7066 adakitic rocks 5.75 35.38 0.0989 0.5121 -8.13 60.8 1478 0.119 0.7067 0.7065 adakitic rocks 6.29 39.54 0.0968 0.5122 -7.16 62.3 1664 0.1083 0.7066 0.7064 adakitic rocks 7.57 48.96 0.0936 0.5121 -8.2 6.59 1498 0.0127 0.7065 0.7065 adakitic rocks 6.85 41.67 0.0997 0.5121 -8.42 76.8 1450 0.1534 0.7068 0.7065 adakitic rocks 6.4 39.92 0.097 0.5121 -8.67 79.6 1456 0.1582 0.7067 0.7064 adakitic rocks 6.51 39.72 0.0992 0.5121 -7.99 78.2 1287 0.1759 0.7068 0.7065 adakitic rocks 7.11 42.96 0.1001 0.5121 -8.16 74.2 1530 0.1404 0.7067 0.7065 adakitic rocks 6.99 43.06 0.0981 0.5122 -7.68 75.3 1538 0.1416 0.7068 0.7065 monzodiorite 4.761 30.44 0.0946 0.5121 -8 113.9 870.1 0.379 0.7068 0.7061 Edong qtz diorite 6.062 38.78 0.0945 0.5119 68.77 1504 0.1323 0.7078 0.7076 Luzong qtz diorite porphyry qtz diorite porphyrite pyx qtz diorite porphyrite basalt 4.068 20.17 0.1219 0.5124 12.59 -3.5 36.7 761 0.1392 0.7057 0.7055 4.853 26.85 0.1093 0.5123 -5.05 158.7 470.8 0.9755 0.7069 0.7051 4.99 43.95 0.1136 0.5123 -4.98 104.4 725.6 0.4164 0.7061 0.7053 6.94 59.22 0.1172 0.5123 -4.65 142 899 0.4571 0.7068 0.7059 Luzong Luzong Luzong Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Chen et al., 1998 Chen et al., 1994 Fu et al., 1997 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 88 Luzong basalt 7.307 63.74 0.1146 0.5123 -5.76 139.5 938.7 0.4302 0.7067 0.7059 Luzong basalt 7.14 38.11 0.1132 0.5123 -6 134 663.4 0.5831 0.7067 0.7057 Luzong 3.437 18.86 0.1102 0.5123 -6.12 46.61 1395 0.09667 0.7058 0.7056 4.068 20.17 0.1219 0.5124 -3.47 36.7 761 0.1392 0.7057 0.7055 Luzong quartz diorite porphyrite quartz diorite porphyrite phonolite 7.485 71.87 0.1041 0.5124 -3.22 245.8 227.2 3.132 0.7108 0.7050 Luzong trachyte 7.879 44.91 0.1061 0.5124 -3.29 281.6 312.1 2.612 0.7104 0.7056 Luzong trachyte 7.06 41.7 0.1118 0.5123 -4.95 199.8 254.7 2.102 0.7098 0.7059 Luzong shoshonite 6.684 34.94 0.1157 0.5123 -6.03 160.9 874.4 0.5327 0.7067 0.7057 Luzong shoshonite 5.885 34.79 0.1023 0.5123 -5.64 133.03 947.9 0.4062 0.7066 0.7058 Luzong shoshonite 7.14 38.11 0.1132 0.5123 -5.91 134 663.4 0.5831 0.7067 0.7057 Luzong shoshonite 7.5 41.6 0.106 0.5122 -6.2 149.8 1123 0.3898 0.7068 0.7061 Luzong trachyandesite 7.065 63.96 0.1105 0.5123 -5.56 179.3 969.2 0.5356 0.7072 0.7062 Luzong trachyandesite 6.28 33.66 0.1128 0.5122 -6.55 147.06 971.4 0.438 0.7067 0.7059 Luzong trachyandesite 7.43 40.7 0.107 0.5123 -5.73 163.5 994 0.4824 0.7070 0.7061 Luzong trachyandesite 6.191 58.3 0.1062 0.5122 -6.84 187.5 277.6 1.955 0.7098 0.7062 Luzong syenite 4.936 54.67 0.0903 0.5123 -5.01 201 230.5 2.525 0.7108 0.7061 Luzong syenite 8.38 84.14 0.0996 0.5123 -5.42 177.8 383.8 1.341 0.7087 0.7062 Luzong Wang et al., 2001 Wang et al., 2001 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 89 Luzong syenite 6.712 45.01 0.0902 0.5122 -6.67 360.7 162.9 6.41 0.7179 0.7061 Luzong monzonite 7.8 40.36 0.1196 0.5122 -7.04 102.1 1137 0.2599 0.7065 0.7060 Luzong a-type granite 6.17 69.63 0.08861 0.5123 -5.69 397.7 48.11 24.02 0.7501 0.7057 Luzong quartz diorite porphyrite quartz diorite porphyrite quartz diorite porphyrite quartz diorite porphyrite monzodiorite porphyry px. monzonite bi. monzonite 4.853 26.85 0.1093 0.5123 -5.05 517.1 530.1 0.9755 0.7069 0.7051 4.99 43.95 0.1136 0.5123 -4.99 340.1 816.9 0.4164 0.7061 0.7053 2.91 16.85 0.1045 0.5122 -6.28 34.97 1184 0.0855 0.7058 0.7057 5.578 28.55 0.1182 0.5124 -3.98 49.95 929.5 0.1555 0.7055 0.7052 4.07 20.2 0.122 0.5124 -3.5 36.7 761 0.139 0.7057 0.7055 7.801 40.36 0.189589 0.5122 -8.2 102 1137 0.26 0.7065 0.7060 5.61 33.2 0.102 0.5122 -7.7 159 1613 0.285 0.7066 0.7060 5.96 32.5 0.111 0.5121 -8.5 133 510 0.753 0.7081 0.7067 21.8 117 0.113 0.5124 -2.5 234 114 5.81 0.7199 0.7092 qtzsyenite porphyry syenite porphyry qtz syenite 6.71 45 0.09 0.5122 -6.7 361 163 6.41 0.7179 0.7061 7.99 48.2 0.1 0.5124 -2.2 452 559 2.34 0.7097 0.7053 14.5 108 0.081 0.5121 -7.9 1.33 348 0.011 0.7071 0.7070 monzodiorite porphyrite alkali gabbro 6.54 34.5 0.1146 0.5122 -7.4 123 685 0.52 0.7086 0.7077 4.12 20.99 0.1187 0.5126 1.4 118.7 883 0.3874 0.7053 0.7046 Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Ningwu Ningwu trachyandesite bi qtz syenite Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Xing et al., 1996 90 Ningwu alkali gabbro 7.96 44.39 0.1084 0.5126 1.3 149.1 1151 0.3735 0.7060 0.7053 Ningwu alkali gabbro 2.84 12.66 0.1356 0.5122 -7.7 58.13 774 0.2164 0.7070 0.7066 Ningwu gabbro-diorite porphyrite gabbro-diorite 4.1 19.08 0.13 0.5124 -2.8 116.6 609 0.5524 0.7075 0.7065 2.5 9.58 0.1576 0.5123 -5.8 60.56 519 0.3363 0.7071 0.7065 4.09 23.79 0.1039 0.5120 -10.2 241.8 197 3.5476 0.7127 0.7062 Ningwu k-feldspar granite basalt 6.06 30.21 0.1213 0.5122 -7.1 24.98 1169 0.0165 0.7068 0.7068 Ningwu trachyandesite 4.462 23.74 0.1136 0.5125 -1.8 103.8 216 1.3872 0.7099 0.7073 Ningwu phonolite tuff 11.79 61.63 0.1156 0.5124 -3.3 209.5 304 1.9878 0.7087 0.7050 Ningwu alkali basalt 8.57 44.16 0.1173 0.5127 2.7 17.8 1196 0.0431 0.7047 0.7046 Ningwu 3.129 15.27 0.124 0.5122 -6.9 176 187 2.719 0.7132 0.7082 4.225 21.53 0.1187 0.5122 -7.3 187.8 119 4.537 0.7160 0.7076 Ningwu anorthoclase trachyte olivine trachyandesite latite 4.019 19.01 0.1278 0.5124 -4.5 50.93 239.4 0.6144 0.7076 0.7065 Ningwu andesite 3.619 17.19 0.1273 0.5123 -4.9 43.07 625 0.2021 0.7054 0.7050 Ningwu latite 5.022 24.03 0.1264 0.5123 -5.2 60.16 696.9 0.2492 0.7062 0.7058 Ningwu basalt 5.432 28.37 0.1158 0.5124 -3.4 100.1 742.1 0.3895 0.7061 0.7054 Ningwu andesite 4.62 22.92 0.1219 0.5124 -3.5 85.1 675.4 0.3637 0.7060 0.7053 Ningwu andesite 4.084 19.87 0.1243 0.5124 -4 97.13 381.4 0.7354 0.7069 0.7055 Ningwu Ningwu Ningwu Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 Wang et al., 2001 91 Ningwu 6.59 34.1 0.117 0.5123 -5.2 25.4 1176 0.062 0.7070 0.7069 Ningwu basaltic trachyandesite syenite 22.45 101.7 0.1336 0.5116 -3.3 151.1 3362 0.12809 0.7075 0.7073 Ningwu phonolite 21.06 98.56 0.12972 0.5116 -3.4 156.3 535.5 0.83185 0.7084 0.7069 Ningzhen 4.41 27.6 0.097 0.5122 -6.8 50.4 845 0.173 0.7056 0.7053 3.71 23.5 0.096 0.5121 -9.7 38.1 822 0.134 0.7059 0.7057 4 25.2 0.097 0.5122 -7.8 47.6 972 0.142 0.7057 0.7054 4.2 26.9 0.095 0.5122 -6.8 43.8 906 0.14 0.7056 0.7053 3.56 23 0.094 0.5122 -7.8 44.6 1093 0.118 0.7057 0.7055 4.07 25.2 0.098 0.5122 -7.6 25.3 843 0.087 0.7059 0.7057 3.91 22.6 0.105 0.5122 -7.1 35.3 550 0.186 0.7068 0.7065 3.89 23.2 0.102 0.5122 -7.5 21 1210 0.05 0.7063 0.7062 Ningzhen intermediate to acid rocks intermediate to acid rocks intermediate to acid rocks intermediate to acid rocks intermediate to acid rocks intermediate to acid rocks intermediate to acid rocks intermediate to acid rocks mafic rocks 7.79 49.3 0.096 0.5123 -4.9 41.3 1974 0.061 0.7054 0.7053 Ningzhen mafic rocks 7.08 39.9 0.108 0.5125 -1.1 27.2 1667 0.047 0.7070 0.7069 Tongling 8.003 44.57 0.1085 0.5122 -6.5 71.72 787.9 0.2633 0.7066 0.7061 7.05 37.97 0.1122 0.5121 -7.9 71.8 1102 0.18786 0.7074 0.7071 Tongling pyx monzodiorite pyx monzodiorite granodiorite 5.253 30.06 0.1056 0.5117 -16.3 152.6 855 0.5166 0.7110 0.7100 Tongling quartz diorite 5.71 31.28 0.1104 0.5119 -12.5 68.8 1082 0.0636 0.7081 0.7080 Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Tongling Chen et al., 2001 Chen et al.,1992 Chen et al.,1992 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Chen et al., 1993 92 Tongling quartz diorite 5.341 29.66 0.1088 0.5120 -11.7 75.95 990 0.222 0.7078 0.7074 Tongling 5.718 26.37 0.1311 0.5121 -9.8 42.77 531 0.2331 0.7078 0.7073 Tongling xenolith pyroxenite quartz diorite 4.215 25.13 0.1014 0.5119 -11.9 69.81 1142 0.1769 0.7075 0.7072 Tongling quartz diorite 5.5 31.51 0.1055 0.5119 73.19 1225 0.1729 0.7079 0.7076 Tongling qtz diorite 5.13 28.78 0.1078 0.5120 11.85 -11 61.25 1080.7 0.164 0.7078 0.7075 Tongling qtz diorite 4.965 27.95 0.1074 0.5120 -10.5 80.16 911.77 0.254 0.7082 0.7078 Tongling 4.94 28.05 0.1065 0.5121 -9.5 95.81 765.89 0.362 0.7100 0.7093 Tongling qtz diorite porphyrite granodiorite 5.61 31.77 0.1068 0.5121 -10 110.23 782.05 0.408 0.7099 0.7091 Tongling granodiorite 5.588 31.62 0.1069 0.5120 -11.6 159.99 850.66 0.544 0.7109 0.7099 Tongling granodiorite 4.77 26.9 0.1072 0.5122 -6.9 74.33 880.53 0.244 0.7074 0.7070 Tongling quartz diorite 5 28.42 0.1063 0.5119 -11.9 80.77 1032 0.2265 0.7077 0.7072 Tongling diorite 6.88 42.35 0.0983 0.5120 -11.5 79 876.8 0.0901 0.7086 0.7084 Tongling diorite 3.53 24.24 0.0881 0.5119 -12.2 99.6 711.8 0.14 0.7088 0.7086 Tongling quartz diorite 5.86 31.87 0.1112 0.5120 -10.6 70.5 1074 0.066 0.7078 0.7077 Tongling gabbro 8 44.57 0.1085 0.5122 -6.5 71.72 788 0.2633 0.7066 0.7061 Tongling gabbro 6.54 36.86 0.10724 0.5122 -7.6 68.1 999.7 0.1967 0.7073 0.7069 Tongling py. monzodiorite 7.05 38 0.112 0.5121 -9.9 71.8 1102 0.188 0.7074 0.7071 Xing et al., 1996 Xing et al., 1996 Xing et al., 1996 Chen et al., 1993 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Wang et al., 2004 Chen et al., 1993 Chen et al., 1993 Chen et al., 1998 Chen et al., 1998 Xing et al., 1998 Xing et al., 1998 Chen et al., 2001 93 Tongling 6.54 36.8 0.107 0.5122 -7.7 68.1 1000 0.197 0.7073 0.7069 Tongling py. monzodiorite qtz diorite 5.5 31.5 0.106 0.5119 -11.8 73.2 1225 0.173 0.7079 0.7076 Tongling qtz diorite 4.22 25.1 0.101 0.5119 -11.9 69.8 1142 0.177 0.7075 0.7072 Tongling granodiorite 5 28.4 0.106 0.5119 -11.9 80.8 1032 0.227 0.7077 0.7073 Tongling qtz diorite 6.88 42.4 0.098 0.5120 -11.5 79 877 0.09 0.7086 0.7084 Tongling granodiorite 3.53 24.2 0.088 0.5119 -12.2 99.6 712 0.14 0.7088 0.7086 Tongling qtz diorite 5.71 31.3 0.11 0.5119 -12.5 68.8 1082 0.064 0.7081 0.7080 Tongling qtz diorite 5.86 31.9 0.111 0.5120 -10.6 70.5 1074 0.066 0.7078 0.7077 Tongling qtz diorite 5.51 29.2 0.114 0.5117 -16.5 74.3 921 0.081 0.7095 0.7094 Tongling qtz diorite 5.18 27.7 0.113 0.5120 -11.7 78.2 1158 0.068 0.7092 0.7091 Tongling 6.61 33.6 0.119 0.5119 -12.6 23.5 900 0.026 0.7091 0.7090 6.5 34.5 0.114 0.5118 -15 68.3 808 0.845 0.7098 0.7082 Tongling diorite porphyry diorite porphyry qtz diorite 5.46 28.5 0.116 0.5119 -13.8 55.3 960 0.058 0.7089 0.7088 Tongling qtz diorite 5.34 29.7 0.109 0.5120 -11.7 75.4 990 0.22 0.7078 0.7074 Tongling qtz diorite 5.25 30.1 0.106 0.5117 -16.3 151 855 0.512 0.7111 0.7102 Tongling Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 Chen et al., 2001 94 Appendix G Lead Isotope Data for Mesozoic Igneous Rocks in the Middle and Lower Yangtze River Valley. District Locality Number Sample Sample description 206 Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Anqing-Guichi Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Edong Jiurui Jiurui Jiurui Jiurui Hongzhen Huaining Tongshan Tongshan Tongshan Tongshan Tongshan Yueshan Yueshan Yueshan Yueshan Echeng Echeng Jinshandian Jinshandian Lingxiang Tieshan Tieshan Tieshan Tieshan Tieshan Tieshan Tieshan Tonglushan Tongshankou Tongshankou Yangxin Yangxin Yinzu Chengmenshan Chengmenshan Fenshandong Wushan AHZ3-M2 01LJ025 T-1 T-2 T-3 WR WR WR WR WR WR WR Pl Pl WR Pl Fsp WR WR WR WR Fsp WR WR WR Zrn Zrn Fsp Fsp Fsp WR WR WR WR Kfs Kfs WR Pl granite basalt granodiorite qtz diorite monzogranite qtz diorite granodiorite quartz diorite diorite monzodiorite qtz monzodiorite granite diorite gabbro quartz diorite basalt quartz diorite diorite diorite xenolith augite diorite augite diorite quartz diorite quartz diorite granodiorite granodiorite diorite xenolith diorite granodiorite porphyry quartz porphyry granodiorite granodiorite 17.947 18.179 18.518 18.438 19.082 18.44 18.52 17.846 17.813 17.99 18.093 18.123 17.998 17.921 18.446 18.149 17.886 17.933 17.917 17.811 18.871 18.663 17.92 18.047 18.109 18.024 18.273 18.244 17.813 18.042 18.833 18.08 17.8 AC-148 AY2-m3 AYS-1 Y345 2 HE2-M1 groug2 groug3 86-99 14 group4 HT12-M3 HT1-B1 T01 T02 T1 16 18 HY2-M1 HY3-B1 AY2-M3 c20 c21 f21 w323 Pb/204Pb 207 Pb/204Pb 15.557 15.462 15.529 15.545 15.617 15.55 15.53 15.484 15.52 15.67 15.561 15.506 15.458 15.31 15.481 15.463 15.453 15.442 15.513 15.491 16.053 15.897 15.5 15.517 15.534 15.508 15.548 15.573 15.52 15.572 15.72 15.57 15.555 208 Pb/204Pb 38.23 38.101 38.645 38.629 39.025 38.63 38.65 37.811 38.067 38.262 38.073 38.408 38.26 38.233 39.257 38.522 37.498 38.141 38.151 38.147 39.833 39.287 38.4 38.381 38.353 38.233 38.527 38.568 38.067 37.933 37.814 38.47 37.743 References Zhai et al., 1992 Yan et al., 2003 Yu, 2001 Yu, 2001 Yu, 2001 Yu, 2000 Yu, 2000 Xing et al., 1996 Zhou et al., 2001 Zhou et al., 2001 Zhou et al., 2001 Pan et al., 1999 Zhai et al., 1992 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Zhai et al., 1992 Zhai et al., 1992 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Pan et al., 1999 Zhang, 1994 Zhai et al., 1992 Zhai et al., 1992 Zhai et al., 1992 Pan et al., 1999 Pan et al., 1999 Liu et al., 2004 Pan et al., 1999 95 District Locality Number Sample Sample description 206 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb Jiurui Jiurui Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Wushan Wushan Bajiatan Bajiatan Chengshan Chengshan Chengshan Chengshan Dalongshan Dalongshan Dalongshan Dalongshan Fushan formation w323 w34 B-44 B-58 1005 1059 1079 2005 1030 1249 1295 3003 98LZ082 Py Kfs WR WR Kfs Kfs Kfs Kfs WR Kfs Kfs Kfs WR granodiorite granodiorite pyx monzonite bt monzonite alkali fsp granite bt qtz syenite alkali fsp granite qtz syenite hbl qtz syenite alkali fsp granite bt syenite alkali fsp granite shoshonitic volcanic rocks 18.002 17.954 18.151 18.02 17.902 17.952 18.34 18.019 18.016 18.775 18.11 18.526 18.384 15.524 15.536 15.559 15.529 15.479 15.52 15.541 15.495 15.453 15.567 15.492 15.564 15.517 37.991 38.131 38.196 38.07 38.187 38.096 38.538 38.317 38.151 38.785 38.283 39.112 38.537 Luzong Jiaochong 98LZ056 WR shoshonitic intrusive rocks 18.352 15.496 38.296 Luzong 98LZ043 WR shoshonitic volcanic rocks 18.834 15.544 38.796 Luzong Luzong Luzong Longmenyuan formation Luzong Luzong Luzong 1 2 98LZ087 WR WR WR latitie latitie A-type granite 18.37 18.613 18.216 15.535 15.464 15.48 38.64 38.76 38.436 Luzong Luzong 98LZ101 WR A-type granite 18.883 15.537 39.075 Luzong Luzong Shuangmiao Maowangmiao 01AQ139 98LZ097 WR WR basalt shoshonitic intrusive rocks 18.204 18.094 15.625 15.533 38.482 38.284 Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Luzong Maowangmiao Maowangmiao Maowangmiao Maowangmiao Maowangmiao Quekou Quekou Quekou Shaxi WR WR WR WR WR WR WR WR WR monzonite porphyry syenite monzogranite monzonite porphyry monzonite porphyry pyx diorite gabbro gabbro adakitic intrusive rocks 18.206 18.345 17.992 17.914 18.253 18.365 18.182 18.302 18.383 15.657 15.72 15.497 15.635 15.627 15.552 15.492 15.51 15.477 38.735 39.039 38.249 38.314 38.437 38.432 38.113 38.174 38.282 Luzong Shuangmaio YT-006-1 YT-012-1 YT-015 YT-029-6 YX-005-3 01LJ030 01LJ032 01LJ035 98LZ0041 98LZ060 WR shoshonitic volcanic rocks 18.249 15.494 38.205 References Pan et al., 1999 Pan et al., 1999 Yang et al., 1993 Yang et al., 1993 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Zhang, 1994 Wang et al., 2006 Wang et al., 2006 Wang et al., 2006 Yu, 1981 Yu, 1981 Wang et al., 2006 Wang et al., 2006 Yan et al., 2003 Wang et al., 2006 Yang et al., 1993 Yang et al., 1993 Yang et al., 1993 Yang et al., 1993 Yang et al., 1993 Yan et al., 2003 Yan et al., 2003 Yan et al., 2003 Wang et al., 2006 Wang et al., 96 District Locality Number Sample Sample description 206 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb 98LZ062 WR shoshonitic volcanic rocks 18.207 15.492 38.161 AC-99 31 34 146 288 Surficial 98LZ045 WR Py Py Py Py Gn WR basalt trachyandesite porphyry trachyandesite porphyry trachyandesite porphyry trachyandesite porphyry trachyandesite porphyry shoshonitic volcanic rocks 17.405 18.1129 18.3026 18.317 18.206 18.2485 18.413 15.472 15.5588 15.7455 15.572 15.7622 15.5775 15.618 37.647 38.2891 38.8924 38.4261 38.9719 38.2584 38.546 17.592 18.375 18.22 18.171 15.52 15.589 15.52 15.532 38.096 38.371 38.4 38.143 Wang et al., 2006 Xing, 1998 Ge et al., 1989 Ge et al., 1989 Ge et al., 1989 Ge et al., 1989 Ge et al., 1989 Wang et al., 2006 Pan et al., 1999 Xing, 1996 Xing et al., 1998 Zhou et al., 2000 formation Luzong References 2006 Luzong Luzong Luzong Luzong Luzong Luzong Luzong Shuangmaio formation Shuangmiao Yueshan Yueshan Yueshan Yueshan Yueshan Zhuanqiao formation Luzong Ningwu Ningwu Ningwu 213 Aoshan Bingjiang Fangshan Kfs Pl Fang-1 WR syenite gabbrodiorite granite basalt Ningwu Fangshan Fang-2 WR basalt 18.206 15.522 38.099 Zhou et al., 2000 Ningwu Ningwu Ningwu Ningwu Ningwu Fangshan Fushan Gushan Huoli Huoli AC-23 222 AHO51 WR WR Pl Kfs Fsp basalt basalt gabbro granite alkali feldspar granite 18.252 18.15 18.83 18.388 18.392 15.547 15.574 15.74 15.52 15.548 38.369 38.369 38.87 38.27 38.497 Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Ningwu Huoli Jiangmiao Jiangmiao Jiangmiao Jiangmiao Kedoushan Kedoushan Kedoushan Ma'anshan Nushan 01TL084 01TL085 AC-64 220 NS-1 Kfs Pl WR Pl Pl WR WR WR Pl WR monzogranite gabbro gabbro gabbro gabbro basalt basalt basalt gabbro basalt 18.388 18.592 17.72 18.592 18.473 17.973 17.955 18.062 18.073 17.821 15.52 15.591 15.423 15.591 15.528 15.462 15.439 15.439 15.473 15.44 38.27 38.467 37.702 38.467 38.258 37.947 37.866 37.862 37.951 37.654 Xing, 1998 Xing, 1998 Xing, 1996 Pan et al., 1999 Zhang et al., 1993 Xing, 1996 Pan et al., 1999 Yan et al., 2003 Xing, 1996 Xing, 1996 Yan et al., 2003 Yan et al., 2003 Xing, 1996 Pan et al., 1999 Zhou et al., 2000 Ningwu Nushan NS-19 WR basalt 17.802 15.435 37.636 Zhou et al., 2000 Ningwu Nushan NS-26 WR basalt 17.833 15.448 37.709 Zhou et al., 2000 Ningwu Nushan NS-29 WR basalt 17.852 15.455 37.743 Zhou et al., 2000 Ningwu Nushan NS-30 WR basalt 17.802 15.435 37.661 Zhou et al., 2000 219 01JM001 AC-10 97 District Locality Number Sample Sample description 206 Ningwu Nushan NS-7 WR basalt 17.887 15.464 37.783 Zhou et al., 2000 Ningwu Ningwu Taocun Tashan Ta-1 Ab WR albitite basalt 18.335 18.029 15.63 15.486 38.543 37.856 Xing, 1996 Zhou et al., 2000 Ningwu Tashan Ta-2 WR basalt 18.02 15.484 37.853 Zhou et al., 2000 Ningwu Ningwu Ningwu Ningwu Ningwu Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Ningzhen Yanghutang Yanghutang Yanghutang Yanghutang Zhongjiu Anjishan Anjishan Anjishan Anjishan Anjishan Anjishan 01M110 01M115 01M119 AC-22 WR WR WR Pl Ab WR WR WR WR WR WR pyx diorite pyx diorite pyx diorite gabbro ab diorite intermediate to acid rocks mafic rocks intermediate to acid rocks intermediate to acid rocks diorite granodiorite 18.421 18.375 18.34 18.073 18.268 17.045 17.997 17.148 17.18 17.785 17.318 15.477 15.489 15.542 15.473 15.59 15.479 15.534 15.487 15.483 15.541 15.462 38.369 38.381 38.439 37.951 38.264 37.353 38.267 37.465 37.484 38.012 37.39918 Ningzhen Funiushan WR granodiorite 17.299 15.434 37.357 Ningzhen Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Tongling Shima Baimangshan Baimangshan Baimangshan Bijiashan Fenghuangshan Fenghuangshan Fenghuangshan Fenghuangshan Jiguanshan Jiguanshan Jiguanshan Jiguanshan Jinkouling Jinkouling WR WR WR Pl pyx Fsp Fsp Pl WR WR WR hbl py WR WR granodiorite porphyrite pyx diorite pyx diorite gabbro diorite gabbro granodiorite granodiorite granodiorite granodiorite pyx diorite pyx diorite hbl gabbro amphibolite quartz diorite quartz diorite 18.049 18.487 18.463 18.35 18.78 18.683 18.849 18.58 18.213 18.512 18.514 18.268 18.27 17.81 17.49 15.584 15.537 15.532 15.6 15.46 15.578 15.606 15.58 15.577 15.523 15.556 15.578 15.47 15.34 15.35 38.359 38.418 38.355 38.46 37.85 38.776 38.727 38.48 38.41 38.347 38.455 38.117 38.027 37.79 36.69 Yan et al., 2003 Yan et al., 2003 Yan et al., 2003 Xing, 1996 Xing, 1996 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Xu et al., 2002 Zhai et al., 1992 Zhang et al., 1994 Zhang et al., 1994 Zhai et al., 1992 Yan et al., 2003 Yan et al., 2003 Xing et al., 1996 Xing et al., 1996 Pan et al., 1999 Pan et al., 1999 Xing et al., 1996 Zhai et al., 1992 Yan et al., 2003 Yan et al., 2003 Xing et al., 1996 Xing et al., 1996 Pan et al., 1999 Pan et al., 1999 Tongling Jinkouling WR qtz diorite 17.49 15.32 36.69 Yang et al., 1989 Tongling Jinkouling Pl diorite 17.934 15.501 37.991 Huang, 1991 25 29 30 31 Ja14-M1 JW3-M1 01TL072 01TL075 AC-21 AC-20 85 86 AC-12 AF1-M1 01TL078 01TL080 AC-409 AC-47 91 NO ck1033102 CK1033102 diorite 201 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb References 98 District Locality Number Sample Sample description 206 Pb/204Pb 207 Pb/204Pb 208 Pb/204Pb Tongling Tongling Tongling Tongling Tongling Tongling Jinkouling Jinkouling Jinkouling Maoliantou Maoliantou Mashan diorite 202 diorite 203 M1 01TL101 01TL103 CK342 Pl Pl WR WR WR WR diorite diorite qtz diorite gabbro pyx diorite diorite 17.913 17.8 17.81 18.646 17.672 18.3 15.566 15.492 15.34 15.498 15.454 15.77 38.242 37.976 37.79 38.49 38.248 40.14 Tongling Tongling Tongling Mashan Mashan Mashan diorite 204 diorite 49 Tobdl Pl Pl WR diorite diorite diorite 17.995 17.943 18.19 15.605 15.535 15.6 38.431 38.199 39.84 Tongling Tongling Tongling Tongling Tongling Tongling Tongling Miaojia Shizishan Shizishan Shizishan Shizishan Shizishan Tongguanshan AMS-M1 146 AS 1-M1 AS8-B S-1 85P-16 WR Fsp WR WR Pl WR Fsp diorite porphyrite quartz diorite diorite xenolith granodiorite diorite qtz diorite 18.42 18.219 18.198 18.251 17.9 17.703 17.566 15.592 15.55 15.564 15.574 15.47 15.154 15.411 38.494 38.346 38.342 38.388 38.09 36.422 37.689 Tongling Tongguanshan 85P-19 Fsp qtz diorite 17.512 15.244 37.281 Tongling Tongguanshan A-4-10 Fsp qtz diorite 17.704 15.425 37.763 Tongling Tongguanshan A-4-2 Fsp qtz diorite 18.091 15.691 38.375 Tongling Tongguanshan A-4-4 Fsp qtz diorite 17.769 15.449 38.844 Tongling Tongguanshan A-4-7 Fsp qtz diorite 18.08 15.571 38.122 Tongling Tongguanshan A-4-7 Fsp qtz diorite 18.426 15.589 38.407 Tongling Tongguanshan A-4-9 Fsp qtz diorite 17.938 15.581 38.199 Tongling Tongling Tongling Tongling Tongling Tongling Tongguanshan Tongguanshan Tongguanshan Tongguanshan Tongguanshan Tongguanshan AT1-B1 AT1-M1 CK371-1 diorite 205 diorite 206 diorite 207 WR WR WR Pl Pl Pl xenolith quartz diorite quartz diorite diorite diorite diorite 18.02 17.942 18.13 17.926 17.896 17.678 15.573 15.608 15.67 15.646 15.527 15.446 38.256 38.398 38.5 38.458 38.099 37.766 References Huang, 1991 Huang, 1991 Yang et al., 1989 Yan et al., 2003 Yan et al., 2003 Wang et al., 1996 Huang, 1991 Huang, 1991 Wang et al., 1996 Zhai et al., 1992 Pan et al., 1999 Zhai et al., 1992 Zhai et al., 1992 Xing et al., 1996 Yang et al., 1997 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhang et al., 1993 Zhai et al., 1992 Zhai et al., 1992 Pan et al., 1999 Huang, 1991 Huang, 1991 Huang, 1991 99 District Locality Tongling Tongling Tongling Tongling Tongling Anqing-Guichi Edong Ningwu Ningwu Ningwu Pacific ocean Pacific ocean Pacific ocean Pacific ocean Pacific ocean Pacific ocean Pacific ocean Tongguanshan Tongguanshan Xinqiao Xinqiao Yaoshan Huaining Lingxiang Kedoushan Kedoushan Kedoushan Number AXQ-Ml AYS-M1 01LJ025 86-99 01TL084 01TL085 AC-64 Sample Sample description 206 Pl WR WR Gn WR WR WR WR WR WR Gn qtz diorite monzodiorite diorite qtz diorite diorite porphyrite Mesozoic basalt Mesozoic basalt Mesozoic basalt Mesozoic basalt Mesozoic basalt mine Ridge mine mine mine mine mine 17.67 18.29 18.433 18.303 18.387 18.179 18.149 17.973 17.955 18.062 18.245 18.355 18.455 18.463 18.47 18.475 18.712 Gn Gn Gn Gn Gn Pb/204Pb 207 Pb/204Pb 15.446 15.59 15.691 15.762 15.652 15.462 15.463 15.462 15.439 15.439 15.569 15.477 15.582 15.589 15.646 15.607 15.621 208 Pb/204Pb 37.776 38.44 38.544 40.362 38.433 38.101 38.522 37.947 37.866 37.862 38.417 37.838 38.552 38.623 38.966 38.633 38.669 References Xing et al., 1996 Qiu, 1994 Zhai et al., 1992 Chen, 2003 Zhai et al., 1992 Yan et al., 2003 Pan et al., 1999 Yan et al., 2003 Yan et al., 2003 Xing, 1996 Doe et al., 1979 Zindler, 1982 Doe et al., 1979 Doe et al., 1979 Doe et al., 1979 Doe et al., 1979 Doe et al., 1979 100 REFERENCES Bird, P., 1988, Formation of the Rocky Mountains, Western United States: a continuum computer model: 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