Dow Construction Chemicals Formulating two-component cementitious waterproofing membranes PRIMAL™ AS-8012 Styrene Acrylic Emulsion Polymer Next generation environmentally advanced binder Long-term protection of building structures Version March 2014 Dow Construction Chemicals Introducing PRIMAL™ AS-8012 Styrene Acrylic Emulsion Polymer – Dow’s latest generation of binders specially designed to support durable waterproofing – Offering high flexibility and elongation as well as tensile strength – Supporting long-term protection of building structures – Helping to raise construction and environmental quality A watertight approach to polymer development Whether it’s protecting concrete and masonry substrates from wet weather conditions, surface water splash, ground moisture ingress or the destructive action of soluble salts, responsible building designers and owners want to ensure the best possible defences. Critical requirements of two-component cementitious waterproofing membranes: – Flexibility: crack bridging – Water impermeability: water tightness – Adhesion to concrete – Low water absorption Such performance benefits have led to their widespread use in applications such as waterproofing wet areas, basement walls, swimming pools, balconies, facades terraces and wastewater drains. Flexible systems are also used as protective surface-coatings for concrete structures. The importance of polymer choice Highly flexible cementitious waterproofing membranes, applied with a brush, roller or spray cure to form a flexible coating preventing water penetration and providing crackbridging. Key to the performance capabilities of the final membrane are the technical characteristics of the polymer which must provide essential properties to the waterproofing mortar including adhesion at the mortar-substrate interface and act as an effective binder to hold together filler particles. Performance requirements Cementitious membranes are expected to offer excellent resistance to water and long-term weathering, even when permanently exposed. High water vapour permeability helps avoiding issues such as blistering, and high toughness and scratch resistance offer durability. The systems must be easy to apply, even on complex, uneven surface shapes, and result in fully-bonded surfaces with no joints. 2 – PRIMAL™ AS-8012 Styrene Acrylic Emulsion Polymer Polymers act as the binder to bring adhesion, flexibility and water resistance to waterproofing membranes – which are core requirements for such systems. Effective polymers must therefore offer: – Good film formation behaviour: suitable emulsion polymers deflocculate particles which results in a tight, non-porous, film – Stability in cement-based mixtures – Wet mortar properties (ease of application) – Water and alkali resistance – A good balance between flexibility and tensile strength – Low glass transition temperature (Tg) Today’s market also demands materials with a good environmental profile alongside effective product performance. PRIMAL™ AS-8012 Acrylic Emulsion Polymer – performance features and benefits PRIMAL™ AS-8012 Acrylic Emulsion Polymer has been designed to offer manufacturers of two-component, cementitious waterproofing systems an excellent balance of performance features and mechanical properties. This next generation polymer imparts high flexibility, elongation and excellent crack-bridging ability. PRIMAL™ AS-8012 also helps the formulation of membranes with market-leading environmental performance and compatibility with key construction standards, including potable water applications. Supporting potable water certification A sample two-component, cementitious, flexible waterproofing membrane containing PRIMAL™ AS-8012 was certified as compliant with BS 6920: Part 2: 2000 “Suitability of non-metallic products for use in contact with water intended for human consumption with regard to their effect on the quality of the water” (including high temperature tests up to 50°C in accordance with BS 6920: Part 3: 2000). Formulation recommendations and a BS 6920: Part 2 compliance letter are available in order to help producers meet regulatory requirements. Environmental performance Features Benefits ü Balanced mechanical properties ü Imparts high tensile strength as well as elongation ü Tailored polymer design ü Good water and alkali resistance ü Specifically designed for waterproof coating ü Supports formulation of a final product with excellent impermeability and crack bridging performance ü Excellent powder compatibility ü Improved formulation stability and workability compared to previous polymers PRIMAL™ AS-8012 Styrene Acrylic Emulsion Polymer is APEOfree 1) and formaldehyde-free 2), and has very low Volatile Organic Content (VOC), helping manufacturers to fulfil required product standards without compromising on their commitment to the environment. Production and packaging PRIMAL™ AS-8012 Styrene Acrylic Emulsion Polymer is produced at Dow’s expanded manufacturing site in the Jebel Ali Free Zone (JAFZA), a state-of-the-art facility producing speciality products. The product is available in drums and in bulk. Typical Properties Appearance Milky White Polymer Type Styrene acrylic Solid, by weight, % 56 pH 6 MFFT, °C <0 Tg Viscosity (LV_S3; 30rpm; 25°C) For more information on how you could benefit from PRIMAL™ AS-8012 Styrene Acrylic Emulsion Polymer in your two-component, cementitious, flexible waterproofing systems, contact your local Dow sales representative or visit www.dowcc.com. -8 <1100 Please note that the values shown are typical values for your guidance. They are not to be taken as specifications and are subject to certain variability. Please consult the sales specifications for details. Supporting standards Selecting the right polymer is vital in the production of qualified waterproofing materials that can meet key standards in the sector. European standard EN 14891-2007: covering liquid applied water impermeable products for use beneath ceramic tiling bonded with adhesives PRIMAL™ AS-8012 has been designed to help achieve required performance standards in classes O (external application, crack-bridging capability at low temperatures) and P (swimming pool application, resistant to contact with chlorinated water). 1) APEO is not intentionally added and is not knowingly introduced from another raw material 2) Made without formaldehyde or formaldehyde-generating materials and does not release formaldehyde under normal operating conditions. Dow however does not routinely analyze PRIMAL™ AS-8012 for formaldehyde or any other substances that are not listed in the Safety Data Sheet or Sales Specification ®™ Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow. 3 About Dow in the Middle East Dow has a longstanding relationship with the Middle East beginning with the establishment of manufacturing and commercial facilities in the United Arab Emirates more than 35 years ago. Since then, Dow has established a solid presence in the Middle East petrochemicals industry, partnering with leading regional companies to set up stateof-the-art petrochemical complexes across the region. For 17 years, Dow and Petrochemical Industries Company K.S.C. (PIC) of Kuwait have shared one successful milestone after another, partnering on six industry-leading joint ventures. Saudi Aramco and Dow have formed a joint venture to build, own and operate a world-scale integrated chemicals complex in the Eastern Province of the Kingdom of Saudi Arabia. From the entrepreneurship initiatives of Young Arab Leaders to the new Dow Middle East and Africa R&D Center at the King Abdullah University of Science and Technology in Saudi Arabia, Dow actively supports the social and economic aspirations of the communities where it operates. For more information about Dow in the Middle East, please visit: www.dowmiddleeast.com. About Dow in Africa Dow established its first sales office in Africa more than 50 years ago. Today the company enjoys a growing commercial and manufacturing presence with 11 locations across the continent in Algeria, Egypt, Ghana, Kenya and South Africa. Dow’s growing presence in Africa demonstrates the company’s commitment to the continent and aims to deliver industry leadership, technical innovation and expertise with a commitment to sustainability to help transform the region into a key player in the global chemicals industry. Dow is focusing all its efforts towards being an active social and community member and an employer and partner of choice on the continent. Through innovative and sustainable initiatives like the Habitat for Humanity project in Egypt and Osizweni Mobile Science lab in South Africa, Dow is playing a pivotal social and development role in the region. Dow serves approximately 700 customers across 38 countries in Africa. For more information about Dow in Africa, please visit: www.dow.com/africa. About Dow Dow (NYSE: DOW) combines the power of science and technology to passionately innovate what is essential to human progress. 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The product shown in this literature may not be available for sale and/or available in all geographies where Dow is represented. The claims made may not have been approved for use in all countries. Dow assumes no obligation or liability for the information in this document. References to “Dow” or the “Company” mean the Dow legal entity selling the products to Customer unless otherwise expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED. Form No. 840-02501-0314 ®™ Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow. Version March 2014