CONTACT ANGLE,
WETTABILITY AND
Festschrift in honor of
Professor Robert J. Good
Editor: K.L. Mittal
IIIVSPM
Utrecht, The Netherlands, 1993
CONTENTS
Preface
xi
Robert J. Good, innovator in colloid and surface chemistry
CJ. van Oss
xiii
Part 1: General Papers
Contact angle, wetting, and adhesion: a critical review
RJ. Good
Capillary rise of a liquid on a solid grafted with long polymer chains
F. Brochard-Wyart and P.G.de Gennes
37
Roles of molecular interacüons in adhesion, adsorption, contact angle,
and wettability
L.-H. Lee
45
Spreading, wetüng and contact angles
J.F. Padday
97
3
Sessile drops: do they really stand on solid surfaces?
M.E. Schröder
109
Part 2: Factors Influencing Contact Angle Measurements
Contact angle equilibrium: the intrinsic contact angle
A. Marmur
Microscopic studies of static and dynamic contact angles
P.A. Thompson, W.B. Brinckerhoff and M.O. Robbins
125
139
Effects of surface flaws on the wettability of solids
M.EJi. Shanahan
159
On surface roughness effects in wetting phenomena
R.D. Hazlett
173
Structural interacüons in the wetüng and spreading of van der Waals fluids
GJ. Hirasaki
183
Local deviation in contact angles on heterogeneous fibrous solids
M. Tagawa, A. Yasukawa, K. Gotoh, M. Tagawa, N. Ohmae
andM.Umeno
221
vi
contents
Direct measurement of the contact angle on plates and on thin fibers:
some theoretical aspects
BJ. Carroll
235
Pore size distribution in Separon using mercury contact angles in pores
and hysteresis in porosimetry
J. Kloubek
247
Determination of contact angles and pore sizes of porous media by column
and thin layer wicking
CJ. van Oss, R.F. Giese, Z. Li, K. Murphy, J. Norris, M.K. Chaudhury
andRJ.Good
269
Wettability and the evaporation rates of fluids from solid surfaces
K.S. Birdi and DJ. Vu
285
Electric field induced variations in the wettability of stainless steel by ionic
Surfactant and electrolyte Solutions
S. Wahal, C. Owiti and A. Böse
295
Contact angles of binary liquids and their Interpretation
D.Li, C. Ng and A.W. Neumann
311
The effects of velocity and viscosity on solid-liquid interfacial behavior
during dynamic contact angle measurement
M. Morra, E. Occhiello and F. Garbassi
321
Direct measurement of molten poly(ethylene terephthalate) contact angles
on Single aminopropylsilane coated glass fibers
B.B. Sauer
335
Some observations on the surface wetting relaxation of latex rubbers
L.W. Schroeder
349
A microtechnique for determining the surface tension of a liquid
B. Miller and I. Tyomkin
361
Part 3: Wettability Behavior and Surface Characterization of
Various Materials
Contact angle studies of surface-hydrophilic elastomer films
/. Noda
373
The wetting properties of grafted cellulose films
A.F. Toussaint and P. Luner
383
Contact angle measurements as a way to analyse synthetic rubber surfaces
modified by chlorination
J.M. Martin-Martinez, J.C. Fernändez-Garcia and A.C. Orgilis-Barcelö
397
Contents
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Dynamic wetting behavior of Silicon wafers in alkaline Solutions of
interest to semiconductor processing
J.-G. Park and S. Raghavan
421
Assessment of the wettability of pharmaceutical powders
G. Buckton
437
Improving the wettability of aluminum foil with oxygen plasma treatments
B.R. Strohmeier
453
Wettability of weathered wood
MA. Kalnins and M.T. Knaebe
469
Wettability of kraft pulps - effect of surface composition and oxygen
plasma treatment
G. Ström and G. Carlsson
475
Analysis of air-corona-treated polypropylene and poly(ethylene
terephthalate) films by contact-angle measurements and X-ray
photoelectron spectroscopy
M. Strobel, CS. Lyons, J.M. Strobel and R.S. Kapaun
493
Changes in wettability with time of plasma-modified perfluorinated polymers
X. Xie, T.R. Gengenbach and HJ. Griesser
509
A glow discharge treatment to immobilize poly(ethylene oxide)/poly
(propylene oxide) Surfactants for wettable and non-fouling biomaterials
M.S. Sheu, A.S. Hoffman and J. Feijen
531
Self-assembled monolayers of alkanethiols on gold: the adsorption
and wetting properties of monolayers derived from two components
with alkane chains of different lengths
J.P. Folkers, P.E. Laibinis and GM. Whitesides
547
Control of wettability of polymers using organic surface chemistry
T.G. Bee, EM. Cross, AJ. Dias, K.-W. Lee, M.S. Shoichet
andTJ. McCarthy
Effects of hydroxypropyl cellulose and hydroxyethyl cellulose
adsorption on the wetting of low energy solid surfaces
E.J. McNally, C.-S. Gau and G. Zografi
561
575
Modification of the surface free energy components of a polymer
by adsorption of poly(oxyethylene)-poly(oxypropylene) block
co-polymers
F. Boury and J.-E. Proust
585
Time dependent wettability of mineral and metal surfaces in the presence
of thiol Surfactants
R.S. Farinato and D.R. Nagaraj
597
viii
contents
Surface properties of some styrene/vinyl pyridine diblock co-polymers
F. Bosse, A. Eisenberg, M. El Kindi, A. Deng and H.P. Schreiber
613
Estimation of the dispersive component of surface energy of polymergrafted lignocellulosic fibers with inverse gas chromatography
B. Riedl and P.D. Kamdem
625
Solid surface free energy components determination by the thin-layer
wicking technique
E. Chibowski
641
Surfactant modification of the surface energetics by hydrophobic polymers
and protein adsorption
E. Ruckenstein and J.H. Chen
663
Surface tension parameters of ice obtained from contact angle data and from
positive and negative particle adhesion to advancing freezing fronts
CJ. van Oss, R.F. Giese, R. Wentzek, J. Norris and EM. Chuvilin
677
Surface free energies of alkylsiloxane monolayers supported on elastomeric
polydimethylsiloxanes
MX. Chaudhury
691
Surface properties of an anhydride-epoxy resin cured against
different mold surfaces
T. Chihani, P. Bergmark, P. Flodin and T. Hjertberg
699
Surface modification of epoxy polymer with different perfluoroacids
T. Chihani, P. Flodin and T. Hjertberg
713
Part 4: Wettabüity and Adhesion, and Applied Aspects of
Contact Angle/Wettability
Contact angle data and adhesive Performance for smooth surfaces with
attached molecular chains
Y.C. Tsai, CT. Chou and LS. Penn
729
Enhancement of polymer film adhesion using acid-base interactions
determined by contact angle measurements
M.B. Kaczinski and D.W. Dwight
739
The effect of surface energetics and molecular interdiffusion on adhesion in
multicomponent polymer Systems
C. Bonnerup and P. Gatenholm
753
Wettabüity and adhesion studies of grafted poly(/?-phenylene terephthalamide)
fiber surfaces
V. Ravichandran and S.K. Obendorf
769
contents
ix
Investigation of the surface free energy of pharmaceutical materials
from contact angle, Sedimentation, and adhesion measurements
W. Duncan-Hewitt and R. Nisman
791
Effects on protein adsorption, bacterial adhesion and contact angle
of grafting PEG chains to polystryrene
K. Holmberg, K. Bergström, C. Brink, E. Österberg, F. Tiberg
and JM. Harris
813
Relating contact surface hydrophobicity to molecular events
influencing biological adhesion
/ . McGuire and V. Krisdhasima
829
The influence of metallic surface wettability on bacterial adhesion
L. Boulange-Petermann, B. Baroux and M.-N. Bellon-Fontaine
839
Role of water wettability, water transport, and adhesion in vision
F.J. Holly
849
Adhesive-free adhesion of grafted surfaces with different wettabilities
K.-S. Chen, Y. Uyama and Y. Ikada
865
Adhesion of anionic Surfactants to polymer surfaces and
low-energy materials
CJ. van Oss and P.M. Costanzo
879
The influence of contact angle, wettability, and reactivity on the
development of indirect-bonded metallization for aluminum nitride
M.G.Norton
891
Influence of alloying elements on wettability and adhesion energy in liquid
metal-ceramic Systems
N. Eustathopoulos and L. Coudurier
909
Application of the surface free energy concept in polymer processing
H.-J. Jacobasch, K. Grundke, E. Mäder, K.-H. Freitag and U. Panzer
921
Some surface tension and contact angle problems in industry
S.B.G.M. O'Brien
937
The wettability of coal and its relevance to the control of dust
during coal mining
H.W. Kilau
953