Physics B Modern Physics Notes Packet Name:________________ Quantum Physics What is meant by the term “quantized”? Which has more energy in its photons, a red laser or a green laser? Why? When are we likely to use quantum physics, as opposed to Newton’s Laws, for example? The “electron-volt” (eV) When is it useful? How do we convert from eV to Joules? Light as a wave Draw a picture of a wave of light. Indicate the wavelength. Sample Problem (similar to 30.10) What is the frequency and wavelength of a photon whose energy is 4.0 x 10-19J? How do we relate the speed of light to its frequency and wavelength? Equation: Sample Problem The bonding energy of H2 is 104.2 kcal/mol. Determine the frequency and wavelength of a photon that could split one atom of H2 into two separate atoms. (1 kcal = 4186 J). Light as a particle When does light behave like a particle? What particle characteristics does it possess? Calculating photon energy. Equation: Sample Problem How many photons are emitted per second by a He-Ne laser that emits 3.0 mW of power at a wavelength of 632.8 nm? Which has more energy in its photons, a very bright, powerful red laser or a small key-ring red laser? Why? 3/6/2008 1 Bertrand Absorption Spectrum What does an absorption spectrum look like? Emission of photon by atom What happens when an atom absorbs a photon? Quantized atomic energy levels As the energy of an atom gets more negative, what happens to the stability of the atom? Emission Spectrum What does an emission spectrum look like? What does the ionization level in the figure represent? Sample Problem What does the ground state represent? What are states between the ground state and the ionization level called? Can the atom exist at energy levels in between the allowed states shown? A. What is the frequency and wavelength of the light that will cause the atom shown to transition from the ground state to the first excited state? B. Draw the transition. Absorption of photon by atom What happens when an atom absorbs a photon? 3/6/2008 2 Bertrand Sample Problem Photoelectric Effect Describe what happens in the ‘photoelectric effect. What is meant by the term “photoelectron”. A. What is the longest wavelength of light that when absorbed will cause the atom whose energy levels are shown above to ionize from the ground state? What is meant by the “work function”? B. Draw the transition. Sample Problem Ionization level 0.0 eV -8.0 eV A. Assume the atom whose energy levels are shown above is in the second excited state. What frequencies of light are seen in its emission spectrum? Ground state (lowest energy level) -12.0 eV Draw transitions representing the photoelectric effect on the figure above, labeling the following: Energy of the photon Work Function Kinetic Energy of the photoelectron. B. Draw the transitions. Sample Atomic Transition Problems (HW #2 at the back of the packet) 3/6/2008 3 Bertrand Sample problem Photoelectric Effect equation in equation form: The photoelectric equation is Kmax = hf – φ. Suppose you shine various colors of light on a certain metal. You measure Kmax for photoelectrons ejected from this metal as a function of the frequency of the incident light. A) How will you graph this data so that you get a linear graph? Sample problem Suppose the maximum wavelength a photon can have and still eject an electron from a metal is 340 nm. What is the work function of the metal surface? The Photoelectric Effect experiment Describe briefly in words. Sample problem Zinc and cadmium have photoelectric work functions given by WZn = 4.33 eV and WCd = 4.22 eV. A) If illuminated with light of the same frequency, which one gives photoelectrons with the most kinetic energy? Sketch the experimental apparatus. B) Calculate the maximum kinetic energy of photoelectrons from each surface for 275 nm light. Question: Suppose you collect Kmax and frequency data for a metal at several different frequencies. You then graph Kmax for photoelectrons on y-axis and frequency on x-axis. What information can you get from the slope and intercept of your data? 3/6/2008 What are some strange results from the photoelectric experiment? 4 Bertrand Mass and Momentum of Photons Voltage versus current for different intensities of light. Number of electrons (current) increases with brightness, but energy of electrons doesn’t! Does a photon have a “rest mass”. Why or why not? I I3 I2 I1 How do you calculate how much mass must be destroyed to create a given photon? V Vs Vs, the voltage needed to stop the electrons, doesn’t change with light intensity. That means the kinetic energy of the electrons is independent of how bright the light is. “Stopping Potential” Voltage versus current for different frequencies of light. Energy of electrons increases as the energy of the light increases. f3 f2 I Sample problem Calculate the mass that must be destroyed to form a photon of 340 nm light. f3 > f2 > f1 f1 Vs,3 Vs,2 Vs,1 “Stopping Potential” V Even though it doesn’t have mass, does a photon have momentum? Vs changes with light frequency. That means the kinetic energy of the photoelectrons is dependent on light color. How do you determine the kinetic energy of photoelectrons from the voltage? How would we calculate the momentum of a photon; with what equation? Describe Compton scattering: Sketch a graph that might be used to analyze the photoelectric effect. Sample Problem What is the momentum of photons that have a wavelength of 620 nm? Sample Photoelectric Problems (HW #4 at the back of the packet) 3/6/2008 5 Bertrand Sample problem What is the momentum of photons that have a wavelength of 620 nm? Sample Problem What is the frequency of a photon that has the same momentum as an electron with speed 1200 m/s? Sample problem What is the wavelength of a 2,200 kg elephant running at 1.2 m/s? Sample Problems S-115b, S-113 (at back of packet) Wave-Particle Duality What does this term mean? Nuclear Physics Draw the symbolic representation of a typical nucleus, and label the parts of the figure. When is this phenomenon most pronounced? Energy: Particle: Photon: Momentum: Particle: Photon: What is meant by the word isotope? What do isotopes of an element have in common? Wavelength: Particle: Photon: What differs between isotopes? What is the wavelength of a particle called? Examples of isotopes: What did the Compton scattering experiment prove? Nuclear Particles What did the Davisson-Germer experiement prove? 3/6/2008 List the two nuclear particles, or nucleons, and draw their symbols. 6 Bertrand Nuclear reactions Neutrino and Anti-Neutrino List three nuclear decay reactions, and describe the nuclear decay particle emitted from each. Definition: When are neutrinos and antineutrinos produced? Gamma Radiation, γ Sample alpha decay Definition: Sample beta decay Calculation of energy released in nuclear reactions 1. 2. Sample positron decay 3. 4. 5. Add up the mass (in atomic mass units) of the reactants. You can find the mass in Appendix E of your textbook. Add up the mass (in atomic mass units) of the products. Find the difference between reactant and product mass. The missing mass has been converted to energy. Convert to kg ( 1 u = 1.66 x 10-27 kg) Use E = mc2 to calculate energy released. Fission Definition: Sample Problem Complete the reaction and identify the type of decay. 234 90 Th → 230 88 Ra+... When does fission occur? Sample fission reaction Sample Problem Find the identity of X in the reaction and identify the type of decay. x→ 234 91 3/6/2008 Pa+ -10 e 7 Bertrand Sample problem Mass defect Complete the following reaction, and calculate the energy released. Definition: 235 92 1 U+ 01 n → 132 51 Sb+5 0 n+... Sample problem What is the mass defect of 12C in atomic mass units? How does this relate to mass in kg and energy in eV and J? Fusion Definition: When does fusion occur? Sample fusion reaction Sample problem You fuse a free proton with a free neutron to form a deuterium nucleus. How much energy is released? 3/6/2008 8 Bertrand Ionization level Problem 1 0.0 eV Third excited state Using the diagram at right, show the following, using arrows to represent transitions: a) The transition of the atom from the ground state to the second excited state by absorption of one photon. Calculate the wavelength and frequency of the photon. Second excited state -3.0 eV First excited state -5.5 eV Ground state (lowest energy level) b) The transition of the atom from the ground state to the second excited state by absorption of two photons. Calculate the wavelengths and frequencies of these photons, and label the order in which they must be absorbed. -1.0 eV -11.5 eV Ionization level 0.0 eV Third excited state Second excited state -1.0 eV -3.0 eV First excited state -5.5 eV Ground state (lowest energy level) -11.5 eV Problem 2 Using the diagram shown, draw all emissions representing the transition of the atom from the third excited state to the ground state. Calculate the frequency of all photons emitted. You must consider single and multiple-step transitions. Ionization level 0.0 eV Third excited state Second excited state -1.0 eV -3.0 eV First excited state -5.5 eV Ground state (lowest energy level) 3/6/2008 9 Bertrand -11.5 eV Problem 3 It is observed that a certain atom in the ground state ionizes in a single transition when 129 nm light is shown upon it, but it will not ionize in a single transition at longer wavelengths. It is also observed that the same atom in its ground state will absorb 250 nm, 175 nm, and 140 nm photons. A) Draw an energy level diagram for this atom. Use electron-volts (eV) as your energy unit. Clearly label the ground state, ionization level, and each excited state. B) On the energy level diagram you have constructed above, show one way that the atom can ionize in a twostep transition. Label each step of the transition with the frequency of the photon associated with that step. 3/6/2008 10 Bertrand A080 B3. In a photoelectric experiment, radiation of several different frequencies was made to shine on a metal surface and the maximum kinetic energy of the ejected electrons was measured at each frequency. Selected results of the experiment are presented in the table below: Maximum Kinetic Frequency (Hz) Energy of Electrons (eV) 0.5 x 1015 No electrons ejected 1.0 x 1015 1.0 15 3.0 1.5 x 10 15 a. 2.0 x 10 5.0 On the axes below, plot the data from this photoelectric experiment. b. Determine the threshold frequency of the metal surface. c. Determine the work function of the metal surface. d. When light of frequency 2.0 x 1015 hertz strikes the metal surface, electrons of assorted speeds are ejected from the surface. What minimum retarding potential would be required to stop all of the electrons ejected from the surface by light of frequency 2.0 x 1015 hertz? e. Investigation reveals that some electrons ejected from the metal surface move in circular paths Suggest a reasonable explanation for this electron behavior. 3/6/2008 11 Bertrand (S-116 Bb7—10 points) A monochromatic source emits a 2.5 mW beam of light of wavelength 450 nm. a. Calculate the energy of a photon in the beam. b. Calculate the number of photons emitted by the source in 5 minutes. The beam is incident on the surface of a metal in a photoelectric-effect experiment. The stopping potential for the emitted electron is measured to be 0.86 V. c. Calculate the maximum speed of the emitted electrons. d. Calculate the de Broglie wavelength of the most energetic electrons. 3/6/2008 12 Bertrand S-115B b6 (10 points) An incident gamma ray photon of wavelength 1.400 x 10-14 m is scattered off a stationary nucleus. The shift in wavelength of the photon is measured for various scattering angles, and the results are plotted on the graph shown below. (a) On the graph, sketch a best-fit curve to the data. In one of the trials, the photon is scattered at an angle of 120° with its original direction. (b) Calculate the wavelength of this photon after it is scattered off the nucleus. (c) Calculate the momentum of this scattered photon. (d) Calculate the energy that this scattering event imparts to the recoiling nucleus. 3/6/2008 13 Bertrand S-113 B7. (10 points) A photon of wavelength 2.0 x 10-11 m strikes a free electron of mass me that is initially at rest, as shown above left. After the collision, the photon is shifted in wavelength by an amount ∆λ = 2h/mec, and reversed in direction, as shown above right. (a) Determine the energy in joules of the incident photon. (b) Determine the magnitude of the momentum of the incident photon. (c) Indicate below whether the photon wavelength is increased or decreased by the interaction. Increased Decreased Explain your reasoning. (d) Determine the magnitude of the momentum acquired by the electron. 3/6/2008 14 Bertrand