Chapter 3 Stoichiometry
Conservation of mass – Balancing Chemical
Reactions
Combustion in air
Formula weight / Molecular weight
Percent composition from formulas
The Mole – Avogadro’s number
Empirical formulas from analysis
Molecular formula from empirical formula
Quantitative calculations
Limiting reactants
Chapter 4 Solution Stoichiometry
Concentrations of Solutions – Molaritry
Chemical Analysis – Titration
Chapter 10 Gases
Measuring Pressure
Boyle’s Law
& Charles’ Law
Avogadro’s Hypothesis / Law
Ideal Gas Law - STP
Molecular Weight from gas density
Dalton’s Law of partial pressures
Mole Fraction
Gas collection over water
Kinetic molecular theory of gases
Kinetic Energy and Temperature
Effusion, Diffusion and Graham’s Law
van der Waals equation
Chapter 5 Thermochemistry
Nature of Energy – Units of Energy
Conservation of Energy - First Law of
Thermodynamics
State function
Pressure Volume work
Enthalpy Exothermic / Endothermic
Calorimetry
Heat Capacity
Hess’s Law
Standard Enthalpy of Formation
Enthalpy of Reaction
Thermochemistry & Food
Chapter 11 Itermolecular Forces, Liquids
and Solids
Condensed Phases
Characteristics of gases, liquids, and solids
Ion-dipole
Dipole-dipole
London dispersion forces
Hydrogen bonding
Viscosity
Surface tension
Adhesion
Vapor pressure
Boiling point
Clausius-Claperon equation
Phase diagrams
Structure of solids
Unit cell
Close packing of spheres
Types of crystalline solids
Chapter 13 Properties of Solutions
When will a solution form?
Hydration of ions
Spontaneity and disorder
Entropy of mixing
Solubility (like dissolves like)
Pressure and temperature effects
Henry’s Law
Molality
Colligative properties
Vapor pressure lowering – Raoult’s Law
Boiling point elevation
Freezing point depression
Ideal solution
Osmosis & Osmotic pressure
Reverse osmosis
Hypertonic, isotonic, hypotonic
Chapter 14 Chemical Kinetics
Factors that determine the speed of a
reaction
Reaction rates and Stoichiometry
Order of a reaction
Concentration dependence of reaction rate
Determining Rate laws
First and second order reactions
Half life
Reaction mechanisms
Elementary step
Molecularity
Temperature and Rate
Collision model
Activation energy
Arrhenius model
Reaction Pathway
Chapter 15 Chemical Equilibrium
Achieving equilibrium
Equilibrium constant and Stoichiometry
Gaseous equilibrium
Haber Process
Calculating equilibrium constants
Characteristics of equilibrium constants
Reaction Quotient
Le Chatelier’s Principle
Effect of concentration, volume, temperature
changes
Heterogeneous equilibrium
Chapter 16 Acids & Bases
Arrhenius, Bronstead-Lowry, Lewis
Conjugate acids and bases
Strong acids and bases
Weak acids and bases
Auto ionization of water - pH and pOH
Polyprotic acids
Relationship between Ka and Kb
Acid Base properties of salt solutions
Binary acids, oxyacids, and carboxylic acids
and acid strengths
Chapter 19
Chemical Thermodynamics
Spontaneous Processes and Enthalpy
Entropy, Disorder & Boltzmann
Spontaneous expansion of a gas
qrev
∆S =
T
Absolute entropy of a substance
Third Law of Thermodynamics
Second Law of Thermodynamics
Entropy change in chemical reactions
Gibbs free energy
Spontaneity and Gibbs free energy
Standard states of entropy and free energy
Temperature dependence of ∆G
Free energy at non-standard conditions /
reaction quotient
∆G and equilibrium constant
Chapter 20
Electrochemistry
Oxidation Reduction Reactions
Oxidation Numbers
Balancing Oxidation-Reductions reactions
Voltaic Cells, Anode, Cathode, Salt Bridge
EMF, Volt, Faraday
Half-Cell reactions
Standard Reduction Potentials
Reference electrode Hydrogen electrode
Nernst Equation
Concentration Cells
Strengths of oxidizing and reducing agents
EMF and equilibrium
Batteries
Corrosion of iron
Cathodic Protection
Electrolysis
Quantitative aspects of electrolysis
( amperes)