Name_________KEY___________________ Chemistry Date______________________ Unit: The Chemistry of Biofuels Heat Calculations Assignment Specific Heat 1. Rearrange the equation, algebraically, for specific heat, cp = q/m·∆T , to solve for : a) Final temperature Tf = __q___ + Ti cp m b) Mass m = __q___ cp ∆T a) Heat energy q= cp m∆T 2. How much heat is needed to raise the temperature of a 55g sample of aluminum from 22.4˚C to 94.6˚C? The specific heat (cp) for aluminum is 0.897 J/g·˚C. 3.56 kJ 3. A total of 3.5 kJ of heat are added to a 28.2g sample of iron at 20˚C. What is the final temperature of the iron? The specific heat of iron is 0.449J/g·˚C. 296.72 ˚C 4. A 123.5 g sample of an unknown metal loses 235.8 J of energy as its temperature falls from 100.8˚C to 83.5˚C. What is the specific heat of this metal? 0.11 J/g·C *because it’s losing heat, q is negative but ∆T is also negative, giving us a positive specific heat 1 Name_________KEY___________________ Chemistry Date______________________ Unit: The Chemistry of Biofuels Calorimetry For these problems, assume mL = g. THIS ONLY WORKS FOR WATER because of it’s density. The specific heat of water is 4.18 J/g·˚C. 5. A small pebble is heated and placed in a coffee cup calorimeter containing 25.0mL of water at 25.0˚C. The water reaches a maximum temperature of 26.4˚C. How many joules of heat were released by the pebble? 146.3 J 6. If 596 J of heat are added to 29.6g of water at 22.9˚C in a coffee cup calorimeter, what will be the final temperature of the water? 27.72 ˚C 7. How much heat is released from a reaction occurring in a coffee cup calorimeter filled with 135g of water, when a temperature change is observed to rise from 23.4˚C to 35.4˚C? ~ 6.77 kJ 8. How much heat is absorbed from a reaction occurring in a coffee cup calorimeter filled with 88.4˚Cg of water, when a temperature change is observed to fall from 24.8˚C to 18.7˚C? ~ -2.25 kJ 9. Which reactions (problems) were endothermic? Exothermic? How do you know? Endothermic 2,3, and 8 , heat is absorbed, or needed, by the system Exothermic 4, 5, 6, and 7, heat is released, or lost, by the system 2