MINISTRY OF SCIENCE AND EDUCATION OF THE REPUBLIC OF
KAZAKHSTAN
STATE UNIVERSITY OF SEMEY named after SHAKARIM
Document of SQM
EMCD
rd
of 3 level
EMCD
EMCD
042-18-34.1.106/01-2014
The programme of discipline of
Edition №2 from
«Physical and Colloidal
«11» 09 2014
Chemistry» for lecturer
EDUCATIONAL-METHODOLOGICAL COMPLEX OF DISCIPLINE
on
«PHYSICAL AND COLLOIDAL CHEMISTRY»
for the specialty
5B011200– «Chemistry»
THE PROGRAMME OF DISCIPLINE
FOR LECTURER
Semey
2014
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Preface
1 WORKED OUT
Compiled by: ______________ B.B. Bayakhmetova, Ph.D. in Chemistry, senior
teacher of the Chemistry and Geography Department
2 DISCUSSED
2.1 At the meeting of Chemistry Department
Protocol _1__, September _2__, 2014
Head of the Department ____________ D.R. Ontagarova
2.2 At the meeting of Educational-Methodological Bureau of the EngineeringTechnological Faculty
Protocol _1__, September _3__, 2014
Head of the Bureau____________ Z.V. Abdisheva
3 APPROVED
Approved and recommended for publishing at the meeting of the TeachingMethodological Council of the University
Protocol _1__, September _11__, 2014
Head of the TMC, Vice-principal__________________ G.К. Iskakova
4 INTRODUCED instead of edition №1 from 18.09.2013
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Content
1. Sphere of application
2. Normative references
3. General provisions
4. The content of the training courses (modules)
5. The list of topics for individual work of students
6. Provision map of instructional literature
7. Literature
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1 FIELD OF APPLICATION
Discipline program for teachers as a part of the educational complex by the
discipline " Physical and Colloidal Chemistry " is intended for students of specialty
"5B011200" - "Chemistry".
2 NORMATIVE REFERENCES
This program for the teacher establishes the procedure of the organization of
the educational process by the discipline " Physical and Colloidal Chemistry " in
accordance with the requirements and recommendations of the following
documents:
- Standard curriculum for specialty "5B011200" - "Chemistry", decree # 158 from
10.04.2012;
- СТУ 042-ГУ-4-2014 University standard - "General requirements for the
elaborationand design of the Disciplines’educational - methodological complexes";
- ДП 042-1.01-2014 Documented procedure - "The structure and content of
Disciplines’ educational - methodological complexes".
3 GENERAL PROVISIONS
3.1Course " Physical and Colloidal Chemistry " is the base for a more conscious
understanding the basics of analytical, organic chemistry, organic and inorganic
synthesis and chemical technology by the students .
3.2 The purposeof the discipline: The purpose of this course is to study the patterns
of chemical, physical-chemical and colloidal-chemical processes, theoretical and
experimental methods of chemistry and physics.
3.3 The main objective of studyingthe discipline:
- To learn performing thermodynamic calculations for determine the direction
and limit of chemical reactions.;
- To study theoretical basis of Physical and Colloidal Chemistry;
- To teach students how to use laboratory equipment in a concrete method
3.4 Learning Outcomes:
After the end of the studying discipline a student must be possessed with the
following knowledge and skills (competencies)
to know:
- Goals and objectives of physical and colloid chemistry, ways and means of
solving them.
- Role and importance of methods of physical and colloid chemistry in for
researchers .
- Main sections of physical and colloid chemistry .
- Main stages of development of physical and colloid chemistry, its current
state.
- Fundamentals of chemical thermodynamics.
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-
Fundamentals of chemical equilibrium.
Thermodynamics of physical balance.
Fundamentals of solutions.
Basic concepts and methods of electrochemistry.
Fundamentals of formal chemical kinetics, the concept of the theory of
chemical kinetics.
- Basic Fundamentals of adsorption and catalysis.
- Basic concepts, laws and methods of colloid chemistry.
- Basic rules of labor protection and safety instructions at work in the
chemical laboratory.
be able to:
- Work independently with educational and reference literature on physical
and colloid chemistry.
- Use the basic techniques and methods of physical and chemical
measurements.
- Work with the major types of instruments used in physical and colloid
chemistry.
- Process, analyze and summarize the results of physico-chemical
observations and measurements.
- Apply knowledge gained in the study of inorganic, analytical chemistry
3.5 Prerequisites of course:
- Theoretical foundations of organic chemistry. Polymers.Isomerism.Natural
and synthetic polymers.
- Analytical chemistry. Preparative methods of analysis.Qualitative analysis of the
substance.Modern
physico-chemical
methods
of
analysis.Chromatography.Spectrophotometry.
- Chemistry of functional derivatives of organic molecules.Condensation
reactions, polymerization, copolymerization.
3.6 Postrequisites of course:
- Chemical Technology - control over the composition of the product, qualitative
determination of impurities
- Chemical Synthesis - interpretation of the spectra of molecules and atoms
3.7 Extract from the working curriculum:
Cour Semester Credits
se
4
7
4
Lectu
res,
hours
30
Labs,
hours
OH
hours
SSS
hours
Total
hours
Table 1
Formoffin
alcontrol
30
30
90
180
exam
4 CONTENT OF DISCIPLINE (MODULE)
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Table 2
Name of topics and content
1
Number of
hours
2
Lectures
Subject of Physical Chemistry. Fundamentals of Thermodynamics.
1. The first law of thermodynamics. Thermochemistry.
2. The second law of thermodynamics. Entropy and its change in
various processes.
3. Thermodynamic functions of the state. Helmholtz energy, Gibbs
energy, Gibbs-Helmholtz equations, chemical potential.
4. Thermodynamics of chemical equilibrium. Isotherm equation,
isobars and isochores of chemical reactions.
Thermodynamics of phase equilibria.
1. Rule of Gibbs phase.
2. Clapeyron- Clausius equation.
3. State diagrams of one-component systems.
4. State diagrams of two-component systems.
5. State diagrams of three-component systems.
Thermodynamics of solutions of strong electrolytes.
1. Conductivity of electrolyte solutions.
2. Thermodynamics of electrode processes.
Kinetics of Chemical Reactions.
1. Effect of temperature on the rate of chemical reactions.
2. Theory of active collisions. Basic concepts of the theory of the
activated complex.
Thermodynamics of multicomponent systems with the presence of
phase interface.
1. Gibbs surface energy. Surface tension.
2. Adsorption at the boundary of liquid-liquid, liquid-gas. Gibbs
adsorption isotherm equation.
3. Adsorption at the interface between gas-solid, liquid- solid.
Langmuir adsorption isotherm equation.
Colloidal chemistry. Nature, classification, methods of preparation
of disperse systems.
1. Osmosis. Sedimentation. Optical properties of disperse systems.
2. The structure and electrical charge of the colloidal particle.
3. Stability and coagulation of dispersed systems.
4. Types of resistance. Sustainability factors. Coagulation of sols
by electrolytes.
5. Coagulation kinetics of disperse systems. Gelation. Colloidal
protection. Coagulation theory.
6. Classes of disperse systems. Sprays, suspensions, emulsions,
6
6
4
4
4
6
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their properties.
7. Lyophilic disperse systems formed micelle-forming surface active substances.
Laboratory works
Construction of the phase diagram of boiling
system of acetone-benzene
Construction of melting diagram of the binary system: phenol naphthalene
Adsorption
Determining of the rate constant of the sucrose inversion reaction
Determination of the rate constant and activation energy of
acetone iodination reaction
Studying of homogeneous chemical reaction equilibrium in
solutions
Coagulation of sols and studying of their properties
Preparation of iron(III) hydroxide colloidal solution
Investigation of adsorption of acetic acid on the carbon surface
depending on the concentration at a constant temperature
Selective adsorption. Influence of solvent on the adsorption
3
3
3
3
3
3
3
3
3
3
5 LIST OF TOPICS FOR INDEPENDENT WORK OF STUDENTS
1. The first law of thermodynamics.
2. Thermochemistry.
3. The second law of thermodynamics.
4. Entropy and its change in various processes.
5. Thermodynamic functions of the state.
6. Helmholtz energy, Gibbs energy, Gibbs-Helmholtz equations, chemical
potential.
7. Thermodynamics of chemical equilibrium.
8. Isotherm equation, isobars and isochores of chemical reactions.
9. Rule of Gibbs phase.
10. Clapeyron- Clausius equation.
11. State diagrams of one-component systems.
12. State diagrams of two-component systems.
13. State diagrams of three-component systems.
14. Conductivity of electrolyte solutions.
15. Thermodynamics of electrode processes.
16. Effect of temperature on the rate of chemical reactions.
17. Theory of active collisions.
18. Basic concepts of the theory of the activated complex.
19. Gibbs surface energy.
20. Surface tension.
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21. Adsorption at the boundary of liquid-liquid, liquid-gas.
22. Gibbs adsorption isotherm equation.
23. Adsorption at the interface between gas-solid, liquid- solid.
24. Langmuir adsorption isotherm equation.
25. Osmosis. Sedimentation. Optical properties of disperse systems.
26. The structure and electrical charge of the colloidal particle.
27. Stability and coagulation of dispersed systems.
28. Types of resistance. Sustainability factors. Coagulation of sols by electrolytes.
29. Coagulation kinetics of disperse systems. Gelation.
30. Colloidal protection.
31. Coagulation theory.
32. Classes of disperse systems.
33. Sprays, suspensions, emulsions, their properties.
34. Lyophilic disperse systems formed micelle-forming surface - active
substances.
6 PROVISION MAP OF INSTRUCTIONAL LITERATURE
Table 4
Name of textbooks, study guides
Number of Number Percentag
copies
of
e of
students provision
Physical chemistry in brief //Prof. Ing. Anatol electronic
5
100
Malijevsk´y, csc., et al. (september 30, 2005)
version
7 LITERATURE
7.1 Basic literature
7.1.1 Mortimer, Robert G. Physical chemistry / Robert G. Mortimer. – 3rd ed.
p. cm. Elsevier Academic Press 2008007675, ISBN 978-0-12-370617-1
(hardcover: alk. paper) 1. Chemistry, Physical and theoretical. I. Title.
QD453.2.M67 2008, 541–dc22
7.1.2 Physical chemistry in brief //Prof. Ing. Anatol Malijevsk´y, csc., et al.
(september 30, 2005)
7.1.3 Евстратова К.И., Купина Н.А., Малахова Н.Е., "Физическая и
коллоидная химия". Москва, "Высшая школа", 2005 г.
7.1.4 Фролов Ю.Г. Курс коллоидной химии. Москва, "Химия", 2002 г.
7.2 Additional literature
7.2.1 Фридрихсберг Д. "Курс коллоидной химии". Л., 1994.
7.2.2 Захарченко В.Н. Сборник задач и упражнений по физической и
коллоидной химии. М., 1998.
7.2.3 Захарченко В.Н. "Коллоидная химия", М., 1999.
7.2.4 Никольский Б.П. (ред.) Физическая химия. – Ленинград, 2007.