Chemistry CPA Unit 6: Chemical Quantities Test Study Guide Test Date(s): Your test will be taken in two parts: 1. Lab Practical: Thursday, March 27 2. Written Exam: Friday, March 28 Main Ideas for Unit 6: Define the mole as a counting number Relate counting particles to weighing samples of substances Calculate the percent composition of atoms of elements within substances Solve stoichiometric problems using molar mass (converting between grams and moles) Determine mole ratios from balanced chemical equations Determine the limiting reactant of a chemical reaction based on mole ratios Unit 6 Materials to Review: Green Notes Packet Purple Assignment Packet Coral Lab Packet Do-Quizzes and Exit Passes Graded Quizzes Unit 6 Equations and Calculations: Molar Mass Percent Composition Moles Grams Grams Moles Comparing Mole Ratios Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 1 Percent Yield Define the following terms: 1. Mole 2. Avagadro’s Number 3. Molar Mass 4. Stoichiometry 5. Percent Yield 6. Theoretical Yield 7. What is the purpose of the mole? Why do we need it? 8. The mole has two different equivalent statements/definitions. What are they, and which one is practical and necessary for lab work? Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 2 9. Find the molar mass of the following substances. The first two types are done for you as a model. SHOW ALL WORK!! CaCl2 Silver nitrate Ag: 1x107.87=107.87 Ca: 1 X 40.08 = 40.08 Ag1+ N: 1 x 14.01= 14.01 Cl: 2 x 35.45 = 70.90 = AgNO3 (NO3)1- O: 3 x 16.00 = 48.00 = 169.88 g = 110.98 g C2H4O2 Calcium hydroxide (NH4)2CO3 sodium phosphate Fe3(PO4)2 diboron hexahydride Zn(C2H3O2)2 sulfur hexachloride Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 3 Find the percent composition of each element in the compounds below. 10. Silver perchlorate, AgClO4 %Ag=_______________ %Cl= _______________ %O= _______________ ________________________________________________________________ 11. Barium acetate, Ba(C2H3O2)2 %Ba = ______________ %C = _______________ %H = _______________ %O = _______________ ________________________________________________________________ 12. Acetone, C3H6O %C = _______________ %H = _______________ %O = _______________ ________________________________________________________________ Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 4 For # 13-16, convert the following quantities from grams to moles. Use the example below to help you: “How many moles are in 98.3 grams of aluminum hydroxide, Al(OH)3?” Step 1: Find the molar mass. Al(OH)3 is 26.98 + (3 x 16.00) + (3 x 1.01) = 78.01 g/ mole Step 2: Set up the equation and solve 98.3 grams x 1 mole____ = 1.2601 moles Al(OH)3 = 1.26 moles 78.01 grams 13. How many moles are there in 12.3 grams of carbon dioxide? 14. How many moles are there in 89 grams of Pb(C2H3O2)4? 15. How many moles are there in 110 grams of sodium bicarbonate? 16. How many moles are there in 98.3 grams of aluminum hydroxide, Al(OH)3? Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 5 For # 17-20, convert the following quantities from moles to grams. Use the example below to help you: “How many grams are in 4.5 moles of sodium fluoride, NaF?” Step 1: Find the molar mass of NaF: 22.99 + 19.00 = 41.99 g/ mole Step 2: Set up the equation and solve 4.5 moles x 41.99 grams 1 mole = 188.955 g NaF = 190 g NaF 17. How many grams are in 0.02 moles of beryllium iodide? 18. How many grams are in 5.6 moles of C6H6? 19. How many grams are in 1.2 moles of (NH4)3PO3? 20. How many grams are in 5.4 moles of potassium sulfate? Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 6 Stoichiometry – Mole Ratios 21. Zn + 2HCl ZnCl2 + H2 A. How many moles of Zn are needed to completely react with 2 moles of HCl? B. How many moles of H2 are produced with 1 mole of Zn? C. How many moles of Zn are needed to completely react with 4 moles of HCl? 22. 2 Ag2O 4 Ag + O2 A. How many moles of oxygen are produced by the decomposition of 2 moles of Ag2O? B. How many moles of oxygen are produced by the decomposition of 4 moles of Ag2O? C. How many moles of Ag are produced by the decomposition of 4 moles of Ag2O? Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 7 23. NaBr + CaF2 NaF + CaBr2 A. Balance the reaction. B. For every one mole of CaF2, how many moles of NaBr are needed? C. How many moles of NaF are produced from the reaction of 4 moles of NaBr? Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 8 Stoichiometry - Percent Yield 24. Balance the following equation: KClO3 KCl + O2 A. For every 2 moles of KClO3, __________ moles of KCl should be produced. B. For every 2 moles of KClO3, __________ moles of O2 should be produced. C. For every 4 moles of KClO3, __________ moles of O2 should be produced. 25. Lab Scenario The above decomposition reaction was completed in the lab using 245.1 g KClO3. Use the steps below to find the mole ratio between KClO3 and O2. A. Find the molar mass of KClO3. B. Convert the amount of KClO3 used in the lab (245.1 g KClO3) to moles of KClO3. C. After the reaction was completed, 90 grams of O2 were produced and collected. Convert this to moles of O2 D. Determine the mole ratio of KClO3 to O2 from the lab data. This would be your answer from B and C written as a ratio. E. Compare your ratio from D to the ratio in the balanced equation (answer to #2). Determine the percent yield. % yield = Actual moles of O2 x 100 Theoretical # of moles O2 Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 9 26. Stoichiometry – Limiting Reagent The following chemical reaction was performed: N2 + H2 NH3 A. Balance the chemical equation. B. 7 grams of N2 were reacted with 0.5 grams of H2. Fill in the information below to find out which reactant was the limiting reactant: 1. How many moles are in 7 grams of N2? 2. How many moles are in 0.5 grams of H2? 3. What is the mole ratio of N2:H2 according to the balanced chemical equation? ____ mol N2 : ____ mol H2 4. What is the mole ratio of N2:H2 according to the calculations you did for 1 and 2? ____ mol N2 : ____ mol H2 5. Which must be the limiting reactant, N2 or H2? Explain why using your answers from 3 & 4. Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 10