Jack Skrainka Mr. Kark – Purple February 28, 2013 The Specific Heat of a Metal Goals: Measure the specific heat of lead. Identify an unknown metal from its specific heat (optional). Procedure: As you perform the experiment, record your data in Table 15.1. 1. Heat 250ml of water in a 400ml beaker, until it is boiling gently. 2. While the water is heating, determine the mass of a clean, dry 50ml beaker to the nearest .01g and record. Add between 80g and 120g of lead shot to the beaker. Measure the combined mass of the beaker and lead to the nearest .01g and record measurement. 3. Transfer the lead shot to a large, dry test tube. Use the utility clamp to suspend the test tube in the boiling water as shown in Figure 15.1. The lead shot should be below the level of water in the beaker. Leave the test tube in the boiling water bath for at least 10 minutes. 4. While the lead shot is heating, measure 100ml of distilled water in a graduated cylinder. Pour the water into a plastic foam cup, and place the cup in a 250ml beaker for support, as shown in Figure 15.2. 5. Measure and record the temperature of the water in the plastic foam cup and of the water in the boiling bath. 6. Remove the test tube from the boiling water and quickly pour the lead shot into the water filled plastic foam cup. Place a thermometer and a glass stirring rod into the cup. Use the stirring rod to gently stir the lead shot. Do not stir the shot with the thermometer. Note the temperature frequently, and record the maximum temperature reached. 7. Pour the water off, and return the lead shot to your teacher. 8. (Optional) Follow the same procedure to determine the specific heat of an unknown metal. Table 15.1 Data Sample Data Trial 1 Trial 2 Mass of lead shot 75.31g 75.13g Initial temperature of water in cup Initial temperature of lead shot (temperature of boiling water) Maximum temperature of lead + water Mass of water 19.8°C 20.0°C 100.0°C 100.0°C 21.8°C 25.6°C 91.37g 90.26g Skrainka 2 Calculation Section Calculating the Energy Gained by the Water: Calculating the temperature gained by water: Lead ∆Twater = Tf - Ti =21.8°C – 19.8°C =2.0°C Energy gained by the water: Q = m x c x ∆T =91.37g x 4.184J/g°C x 2.0°C =760J Copper ∆Twater = Tf - Ti =25.6°C – 20.0°C =5.6°C Q = m x C x ∆T =90.26g x 4.184J/g°C x 5.6°C = 2.1 x 103J Calculating the temperature lost by metal: ∆TPb = Tf - Ti =21.8°C – 100.0°C = -78.2°C ∆TCu = Tf - Ti = 25.6°C – 100.0°C = -74.4°C Energy Gained by the water = Energy lost by metal: Calculating the specific heat capacity: Lead CPb = Q/ m x ∆T =-760J/ 75.31g x -78.2°C = .13 J/g°C Copper CCu = Q/ m x ∆T = -2.1 x 103J/ 75.13g x -74.4°C = .38 J/g°C Calculating % Error: % Error Pb = |Accepted value – Experimental Value| x 100% Accepted Value = |.16 J/g°C - .13 J/g°C| x 100% .16 J/g°C = 20% error Pb % Error Cu = |Accepted value – Experimental Value| x 100% Accepted Value = |.385 J/g°C - .38 J/g°C| x 100% .385 J/g°C = 1% error Cu Skrainka 3 Specific Heat Capacities 3000 2500 E n 2000 e 1500 r g 1000 y 500 Lead Copper 0 0 2000 4000 6000 8000 M∆T Average Percent Error: Pb % Error = |Accepted value – Experimental value| x 100% Accepted Value = |.16 J/g°C - .106 J/g°C| x 100% .16 J/g°C = 30% error Pb Cu % Error = |Accepted value – Experimental value| x 100% Accepted value = |.385 J/g°C - .3139 J/g°C| x 100% .385 J/g°C =18.5% error Cu Results Table Temperature Gained by H2O (°C) Energy Gained by H2O (J) Temperature lost by metal (°C) Specific Heat Capacity (J/g°C) Percent Error (%) Average Specific Heat Capacity (J/g°C) Average Percent Error (%) Pb 2.0 760 -78.2 .13 20 .106 30 Cu 5.6 2.1 x 103 -74.4 .38 1 .3139 18.5 Skrainka 4 Discussion of Results: The results that should have occurred were a specific heat capacity of .16 J/g°C for Pb and .385 J/g°C for Cu. The results that actually occurred were .13 J/g°C for Pb and .38 J/g°C for Cu. There was a percent error of 1% for Pb and 20% of Cu. The results that occurred were lower than expected. This means the energy of H2O was too small, the final temperature of H2O was too small, or the change in temperature in H2O was too low. Other problems that occurred were the change in temperature of Cu was too large. Also if the temperature of the final metal was lower than expected, then the results would be lower than expected. These things occurred because the metal was delayed from being put in. To fix this the metal should be put in the H2O quicker. Another problem was that the metal did not heat up enough. This means it took longer to heat all the way, and to fix this the metal should be left to heat up longer. Lastly, the metal was not submerged all the way in the boiling H2O, or it lost heat to the surrounding environment. To fix these it must be submerged more, and the top of the test tube should be lightly covered. Conclusion: The purpose was to measure the specific heat capacity of Pb and Cu. The Pb and Cu were heated to the temperature of boiling water. The temperature of the metals was taken, and the specific heat capacity was found. The results that should have occurred were a specific heat capacity of .16 J/g°C for Pb and .385 J/g°C for Cu. The results that actually occurred were .13 J/g°C for Pb and .38 J/g°C for Cu. There was a percent error of 1% for Pb and 20% of Cu. The results that occurred were lower than expected. The major source of error was the metal was not moved from the boiling water quick enough, and it lost too much heat in the process. The results of Pb were not supported. The results of Cu were supported.