EVERGREEN AMERICA CORPORATION FACT OR FRICTION The Most Advanced Technology In Lubrication Represented by: Will Monsell, President GREEN ENERGY PRODUCTS, LLC Damariscotta, Maine ©Evergreen America Corporation, 2003, 2004 Lubrication Lubrication is the act of applying lubricants and lubrication substances which are capable of reducing friction between moving mechanical parts Meta l Sub stra te Meta l Sub stra te Asperities All surfaces, no matter how smooth they may appear to the unaided eye, when sufficiently magnified are rough and uneven. This unevenness is know as asperities. Asperities Asperities when rubbed together generate particulate Friction Consumes Power Friction is the resistance to relative motion between two bodies in contact. According to the Department of Energy, 62.4% of energy is lost to friction in the engine resulting in the loss of fuel, horsepower & components Greatest friction occurs by particles the same size as the oil film thickness Adhesion and Cohesion Adhesion is the property of a lubricant that causes it too stick or adhere to the parts lubricated. Cohesion is the property which holds a lubricant together and resist a breakdown of the lubricant under pressure. Moving Surface Adhesion Cohesion Oil molecules Oil molecules slide over each other Relationship of Friction, Cohesion, Adhesion and Lubrication Friction always consumes power and produces heat Any fluid when placed between two surfaces tends to keep them apart and change sliding friction into fluid friction, thus they are said to be lubricated The extent to which lubrication reduces the friction between two surfaces is governed by two factors: 1) The selection of the fluid which has the best proportion of cohesive & adhesive properties. 2) The amount of pressure between the two surfaces To insure lubrication, the layer of fluid must be kept intact, the greater the pressure the more difficult this becomes 3 Common Types of Wear as a Result of Friction (1) ABRASIVE WEAR (3) SURFACE FATIGUE Stress Risers Cutting away (2) ADHESION Weld Junctions Surface Roughness Denting Affect *High pressure pump *Bearings *Gears *Rings & cylinders *Valves *Seals Tribology Since the late 1960’s the field of Tribology – the study of friction, wear and lubrication in fluid systems - has developed sophisticated tests to gain much knowledge into the effects of friction and ways to reduce friction in order to reduce wear, heat and particle contamination. The Problem Thus far you have seen the effects of friction and the challenge facing lubricants under pressure, heat and particle contamination Friction and heat cause the destruction of asperities resulting in metal particles interrupting the oil film between two surfaces generating more particles These particles react with moisture, impurities and lubricant additives creating corrosive acids that further pit the surface creating new asperities These acids oxidize the lubricant, accelerate wear and rapidly deteriorate the functions of the lubricant resulting in the 3-common wears in the fluid system PARTICLES UNDER 5µ CAUSE THE MOST COMPONENT DAMAGE -Dr. E. Rabinowicz of M.I.T. (American Society Of Lubrication Engineers 1981) 5 Functions of the Lubricant 1) 2) 3) 4) 5) Friction Reduction Seal Heat removal Cleanse Absorb Shock Challenge of the Lubricant A good lubricant must reduce particulate wear from the interaction of metal-metal contact Even the best lubricants degrade over time, as a result of friction and chemical in the additive package reacting with particulate, moisture, heat and oxygen resulting in acidic properties These acids react with the metal surface causing micro-pitting (asperities) and the vicious cycle begins anew The very anti-wear additive package designed to protect metal-metal contact, turns acidic and become part of the problem The Downfall of Lubricants The typical downfall of a lubricant occurs as a result of an imperfect, temporary and sacrificial boundary layer between surfaces allowing asperity-asperity contact thus introducing particulate into the lube Heat, moisture, air, and metal particulates combined with certain additives interact causing acids which micro pit the surfaces and oxidizes the oil The efficiency & longevity of a lubricant dramatically increases as the asperity-asperity contact decreases The goal is to reduce friction through a solid and permanent boundary layer on the surfaces Boundary Additives The intent of boundary additives are to form a boundary layer of molecules to prevent surface-surface contact Additives in use are Graphite, Molybdenum, Zinc, Phosphorous, and Sulfur Downside of these additives are their chemical reaction with metal and other contaminates such as moisture causing them to become acidic, corrosive and a part of the problem they are intended to solve These additives are also highly toxic; such as Zinc that is linked to cancer and other illnesses The field of Tribology over the years has researched for a solid boundary lubricant that is biodegradable and permanent. The Present Condition of Friction Loss of horsepower or power in hydraulics Graduated loss of fuel economy Frequent oil drains due to degradation Component wear Increased emissions Rising maintenance cost Rising labor cost Dept. Of Energy “Wear promoted by particles (under 10µ) leads to diminished fuel efficiency, reduced component life, oil service, and power output” -Needelman, Filtration For Wear Control & Affects of Contamination 18% Decrease in Horsepower Extending oil drains without friction protection this engine dropped from 365 HP to 300HP Cummins engine America's First National Laboratory THE DISCOVERY The “Big Bang” Discovery In Friction Reduction Technology Following years of research in support of the US space program, a discovery in 1990 by scientist at the prestigious Argonne National Laboratory redefined the potential of lubrication technology Argonne Website: www.anl.gov The Discovery In 1991 the DOE patented boric acid as a solid boundarylayer lubricant. Developed by Dr. Erdemir, Boron CLS Bond was the result of years of research at the Argonne National Laboratories Tribology Department under the Department of Energy Winner of the prestigious R&D 100 award Holds a U.S. DOE Government patent #5,431,830 BORON CLS BOND has been tested worldwide under the harshest conditions with millions spent and producing the same consistent results every time Written up in Journals of Tribology. Lubrication Engineers and many other publications as a self replenishing solid boundary lubricant The Technology Biodegradable Boric Acid is used to form a permanent solid boundary layer lubricant on Metal Surfaces NO additive in oil has the ability to form a permanent solid boundary layer Step One: Boric Acid is Introduced METAL SUBSTRATE BORIC ACID METAL SUBSTRATE A new permanent surface is about to be created Step 2: Interaction between Boric Acid, moisture and the metallic substrate forms Boric Oxide H2O METAL SUBSTRATE AIR BORIC OXIDE METAL SUBSTRATE Step 3: Boric Oxide bonds to the metallic substrate and forms a solid surface barrier on the substrate preventing metal-to-metal contact. METAL SUBSTRATE BORIC OXIDE Boric Acid BORIC OXIDE METAL SUBSTRATE 85% hardness of a diamond Step 4: Interaction between Boric Oxide and moisture reforms Boric Acid into crystalline platelets METAL SUBSTRATE BORIC ACID PLATELETS BORIC OXIDE BORIC OXIDE METAL SUBSTRATE An effective new technology protecting surfaces Step 5: Crystalline Boric Acid Platelets Form Crystal Lattice Structure - CLS Electron microphotograph of boric acid Crystal Lattice Structure (15 micron field Of view) Like a deck of brand new playing cards sliding over each other Step 6: Boric Acid platelets align themselves parallel to the metal surface and conform to the direction of movement METAL SUBSTRATE BORIC OXIDE BORIC OXIDE METAL SUBSTRATE “70% of component replacement is the result of surface degradation” –Dr. Rabinowitz, MIT at American Society of Engineers workshop NO LUBRICANT CAN ACHIEVE THIS LOW COEFFICIENT Virtually eliminates particle generation EXTREME LOW FRICTION COEFFICIENT* LESS THAN 0.01% (80% REDUCTION IN FRICTION) *The ratio of the force that maintains contact between an object and a surface and the frictional force that resists the motion of the object. Step 7: Weak van-der-Waals forces* between the crytalline layers allows very low friction movement between layers METAL SUBSTRATE Weak interplatelet bonds BORIC OXIDE BORIC OXIDE METAL SUBSTRATE *A weak attractive force between atoms or nonpolar molecules Resists High Pressure LOAD EXTREME PRESSURE PERFORMANCE Extreme hardness of crystalline structures prevents metal-to-metal contact when load is applied LOAD METAL SUBSTRATE BORIC OXIDE BORIC OXIDE METAL SUBSTRATE Step 8: Self-renewing cycle: Interaction between Boric Acid, Boric Oxide, Air and Moisture leads to self-replenishing cycle. BORIC ACID AIR + MOISTURE MOISTURE BORIC OXIDE Lubrication Performance Friction Coefficient Less Than 0.01 Timken Load Greater Than 90+ Reduces wear up to 90% Reduces Friction up to 80% Increases Engine Efficiency 5-7%+ Increases Fuel Efficiency 2-12%+ Reduces Friction Heat 40-50% Added Values Biostat Anti-Corrosive Anti-Oxidant Reactive Coating Water Resistant Displaces carbon, varnish and sludge previously built up in Engine/machinery Prevents deposit formation in new engines TEST RESULTS Visit test results at http://www.evergreenamerica.com/technology/test.html Partial Test List Pin on disk Ball on three disk Friction Coefficient HFRR Engine test: Fuel consumption, emissions, horsepower Scar width Spectrographic analysis Timken load Corrosion Oxidation Prevention & protection from deposit formation … And more Engine Oil Treatment Test Test performed at BNM Research, Sweden in March 2002 Test indicated a 5% reduction in fuel consumption. Long term benefits are reduced wear due to reduced friction Significant reduction of metal residue in drain oil Significant reduction of corrosion Diesel Fuel Treatment Test Test performed at BNM Research, Sweden in March 2002 Results indicate a >5% increase in fuel economy Long term reduced wear, due to reduced friction Lower emissions (HC) Pin On Disk Test With diesel fuel treatment, grease, gear/engine treatment combined with different ceramic compounds Low sulfur diesel fuel without Boron CLS Bond Low sulfur diesel fuel with Boron CLS Bond Treatment Corrosion Standard comparative corrosion test using metal in a corrosive environment Boron CLS Bond resists corrosion even in salt water Solvency Test Test coupons immersed in beakers for 4-days alternately heating to @ 100C, lightly stirring with coupon, cooling & repeating. Motor Silk sample displaced a greater portion of the carbon deposits leaving more visible metal with a slight varnish coating. Overall carbon thickness reduced within 4-days. Pennzoil Pennzoil & Motor Silk The most Advanced Friction Reduction Technology Available Argonne Tribology Labs has contributed the greatest development in lubrication and friction reduction technology available today. Taking advantage of the Boron CLS Bond technology for your fluid system will have the greatest impact for you financially, mechanically, and environmentally. Fluid Treatments to Custom Formulations Motor Silk for engines is a 10-1 dilution so 16 ounces treats 5 quarts and is a one time treatment Some Companies Already Using Allied Signal Bartell Yachts Bimba Corporation Boeing Aerospace & Aircraft Robert Bosch Chem Tool Enron Wind General Petroleum Haliburton Corporation Henkel Chemical Hitachi Refrigeration Florida Light and Power Ford Motor Company Fujikoshi Husqvarna Idemetsu Kaiman Aerospace Marine Industries Matsushita Mitsubishi Heavy Industries Mitsubishi Metals Mitsui Mabuchi Motors Navistar Neste/Fortum Oil Nihon Chemical Kogyo Nihon Victor Oil Disney Florida Plus Many More World Wide Evergreen America Corporation Proactive Maintenance Engineering Thank you for your time investigating the most advanced fluid system protection available anywhere in the world The Proactive Maintenance Consultants Visit www.evergreenamerica.com for more technical info. NO RISK INVOLVED Equipment Inventory Data Cost Analysis (ROI within 2 weeks to 2 months) Integrate on a monthly basis Savings from present maintenance budget invested into a permanent solution Money Back Guarantee (pay for itself or money back) In-House Performance Evaluation We work with you every step of the way