Physical Science Chapter 4 Elements & The Periodic Table Today’s lesson…… The Modern Atomic Model…… Objective of today’s lesson -Describe the mass of an atom and its parts in terms of amu -Explain what the atomic number of an element is -Calculate atomic mass number or number of neutrons Read pages 106 to 108 and complete the following idea tree/concept map in your notes…………… The modern atomic model has three fundamental particles The Electron Has a negative charge Relative mass is 1/1836 Found in clouds outside the nucleus The Proton Has a positive charge Is in the nucleus Has a relative mass of 1 (~1836X more than an electron) The Neutron Has no charge Is in the nucleus Has about the same mass as a proton (1 amu) Parts of an Atom An atom consists of a nucleus surrounded by one or more electrons Atoms are electrically neutral w/ the same number of protons as electrons. Majority of the atom is empty space. If nucleus were the size of a pencil eraser, the closest electron would be 100 yards away! Subatomic Particles – Protons – Neutrons – Electrons Nucleus: Tightly packed Protons & Neutrons Electrons Orbiting nucleus @ ~ speed of light!! Atomic Mass How much does an atom “weigh”? What is the mass of an atom? SI Unit for mass is the Gram…. Way toooo big to accurately “mass” an atom Came up w/ new unit, an AMU (atomic mass unit) 1 AMU = mass of 1 Proton mass of subatomic particles – Proton = 1 AMU – Neutron = 1 AMU – Electron = .0005 AMU Atomic Mass = the total # of both Protons & Neutrons in the atom – ( we don’t worry about the mass of the electrons since they have almost no mass) Atomic Number By definition: – The Atomic Number = the number of Protons present in the nucleus of an atom Each Element in the Periodic Table has a different number of Protons, therefore each element has a different, unique, atomic number. “Smaller” number is always the atomic #, therefore the number of protons present “Large” number is always the Atomic Mass which tells us the total # of both Protons & Neutrons present When reading the Periodic table notice each element has a unique 1 or 2 letter symbol and “big” & “small” number listed Electrical Atomic Charge Electrical charge – all atoms have a neutral charge – ( a zero net electrical charge) Protons have a positive (+) electrical charge Neutrons have a neutral (0) electrical charge Electrons have a negative (-) electrical charge Since the net electrical charge is 0 (neutral), if you have 10 Protons (10 “+” charges) then there must be 10 “-” charges (10 electrons) present to balance out the atom. Therefore, as long as you know the Atomic #, you know the # of Protons and also the # of Electrons!! For example: Carbon has an atomic # of 6, it therefore has 6 Protons which has an electrical charge of +6, to make the atom neutral we need 6 negative charges found in the 6 electrons orbiting the nucleus. How many Neutrons are there? Remember: – The Atomic # = the # of Protons – The Atomic mass = The # of both Protons & Neutrons. – Therefore, if you subtract the Atomic # (the number of Protons) from the Atomic mass (the number of both Protons & Neutrons) what is left over must be the number of Neutrons!! For Example w/ Carbon: Atomic Mass-Atomic # = # Neutrons Atomic Mass = 12, Atomic # 6 12 – 6 = 6 neutrons present in the Carbon nucleus What makes an Element? What are isotopes? What makes an Element? Over 117 different elements http://www.privatehand.com/flash/elements. html OBJECTIVES: –Explain how the atomic number identifies an element. How Do Atoms of Different Elements Differ? • Starting Simply The hydrogen atom has one proton and one electron. • Now for Some Neutrons The helium atom has two protons, two neutrons, and two electrons. Elements Review……………… The number of protons determines the element and it’s atomic number – Atomic Number = the number of protons – Atomic Mass Units (amu) = # of protons + # of neutrons A neutral atom has the same number of electrons as protons Elements Review……………… Atoms have larger atomic numbers and more mass as you add more protons and neutrons – Carbon (C): 6 protons + 6 neutrons = 12 amu – Gold (Au): 79 protons + 118 neutrons = 197 amu An atom does not have to have equal numbers of protons and neutrons Hydrogen H 1 1 Protons: 1 Neutrons: 0 Electrons: 1 Sodium Na 11 23 Protons: 11 Neutrons: 12 Electrons: 11 Rhenium Re 186 75 Protons: 75 Neutrons: 111 Electrons: 75 EXAMPLE How many protons, neutrons and electrons are found in an atom of Cs 55 133 Atomic number = protons and electrons There are 55 protons and 55 electrons Mass number = sum of protons and neutrons 133 – 55 = 78 There are 78 neutrons Isotopes What are they? Isotopes Review… Isotopes are atoms that have the same number of protons but different numbers of neutrons (they are still the same element) Why? They have the same number of protons Which means? They have the same atomic number Lets review this more closely………. Isotopes…....... Isotopes…....... Telling Isotopes Apart You can identify each isotope of an element by its mass number. The mass number is the sum of the protons and neutrons in an atom. Isotopes Atoms with the same number of protons but different numbers of NEUTRONS Carbon-12 N NN N N N Atomic # 6 Mass #12 ? 6 6 12 N Carbon-14 N NNN N N N N Atomic # 6 Mass #14 6 8 14 N Name: ________________ Period : ______ Isotopes Atoms with the same number of protons but different numbers of NEUTRONS B-11 Atomic # Mass # N B-10 Atomic # Mass # N Isotopes Atoms of the same element can have different numbers of neutrons The number of Neutrons in an atom will sometimes vary, that’s why the atomic mass of the elements is not an even number. For Hydrogen, the mass is 1.008. Most atoms of Hydrogen have 0 neutrons, but some have 1 neutron and a very very few will have 2 neutrons. When you “weigh” trillions of Hydrogen atoms you find that almost all of them will not have any Neutrons, & several of the atoms will have 1 neutron and maybe 1 or 2 will have 2 Neutrons. If you were to take an average of all of the Hydrogen atoms in your sample, the atomic mass would reflect the different Isotopes present and be 1.008 AMU’s. Organizing the Elements Objectives: • What is the periodic table ? • What information can be obtained from the table ? • How the periodic table is organized • How an elements properties can be predicted The scientists who organized it….. •1829 J.W. Dobereiner (German) organized elements into triads based on similar properties and atomic mass •1869 Dmitri Mendeleev (Russia) published a classification schemes for all elements (in order of atomic mass) • Lothar Meyer (Germany) published a nearly identical classification also in 1869 • Later, Henri Moseley (England) 1887-1915, established that each element has a unique atomic number, which is how the current periodic table is organized Organizing the Elements 1 The periodic table is laid out by increasing atomic number as you go across and down the table 1 IA 1 H Periodic Table 2 IIA Atomic # increases 1.00797 2 3 Li 13 IIIA 4 5 Be B 6.939 9.0122 3 5 6 7 Atomic # increases 4 11 Na 12 Mg 22.9898 24.305 19 20 K Ca 14 IVA 6 C 15 VA 7 N 16 VIA 8 O 17 VIIA 9 F 18 VIIIA 2 He 4.0026 10 Ne 10.811 12.0112 14.0067 15.9994 18.9984 20.179 3 IIIB 21 Sc 4 IVB 22 Ti 5 VB 23 V 6 VIB 24 Cr 7 VIIB 25 Mn 8 26 Fe 9 VIIIB 27 Co 10 28 Ni 11 IB 29 Cu 39.102 40.08 44.956 47.90 50.942 51.996 54.9380 55.847 58.9332 58.71 63.54 37 38 39 40 41 42 43 44 45 46 47 17 Cl 18 Ar 26.9815 28.086 30.9738 32.064 35.453 39.948 31 32 33 34 35 36 Ga 65.37 65.37 48 49 As Se Br Kr 72.59 74.9216 78.96 79.909 83.80 50 51 52 53 54 [99] 75 101.07 102.905 106.4 107.870 112.40 114.82 118.69 121.75 127.60 126.904 131.30 76 77 78 79 80 81 82 83 84 85 86 132.905 137.34 138.91 178.49 180.948 183.85 186.2 87 88 89 104 105 106 107 Fr Ra Ac Ku [223] [226] [227] [260] Os Ir Pt Au Hg In Ge 87.62 88.905 91.22 92.906 95.94 56 57 72 73 74 Re Cd S 85.47 55 W Ag 16 Ru Ta Pd P Tc Hf Rh 15 Mo La Nb Zn 14 Si Sr Ba Zr 30 13 Al Rb Cs Y 12 IIB Tl Sn Pb Sb Bi Te Po 190.2 192.2 195.09 196.967 200.59 204.37 207.19 208.980 [210] 108 109 I Xe At Rn [210] [222] Across the Periodic Table • Periods: Are arranged horizontally across the periodic table (rows 1-7) • All elements in a period (row) have the same number of electron shells. (not the same as quantum orbitals) 1 IA 1 2 IIA 13 IIIA 2nd Period 2 3 3 IIIB 4 IVB 5 VB 4 5 6th Period 6 7 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 14 IVA 15 VA 16 VIA 18 VIIIA 17 VIIA Down the Periodic Table •Groups or Families: Are arranged vertically down the periodic table (columns or groups, 1- 18 or I-VIII A,B) •Elements in a group have the same number electrons in their outer most shells, the valence shell. 1 IA 1 18 VIIIA Alkali Family: 1 e- in the valence shell 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 2 3 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 4 5 6 7 Halogen Family: 7 e- in the valence shell 17 VIIA When using a table with groups 3A to 8A Listed, the group # equals the number of Valence 8A electrons (These are Groups 3A-8A) 1A 2A 3A (Groups 3B-12B) 4A 5A 6A 7A C. Bohr Models Rings represent electron shells/energy levels Dots represent the electrons in each shell (e-). Pair them! Center circle is the nucleus with the number of protons and neutrons Example: Two elements in period 3 (three electron shells) Sodium 1e- 7e- 8e- 8e- 2eP11 N12 Chlorine 2eP17 N18 *Add the electrons to each shell according to the number of elements in a row up to the element you are modeling C. Dot Diagrams Dots represent the valence e-. EX: Sodium EX: Chlorine C. Electron Shells & Energy Levels When electrons in an atom are excited by electricity, light or heat they can jump up to another energy level When they come down they emit a specific wave length of light unique to that element! This is called an atomic emissions spectra 7e8e2eP17 N18 Online Animations: http://einstein.byu.edu/~masong/htmstuff/Absorb2.html http://ircamera.as.arizona.edu/NatSci102/NatSci102/lectures/spectroscopy.htm “Need-to-Know Families “Old Fashion Names” of certain Families Alkali Metals Alkaline Earth Metals Noble Gases Halogens Chalogens Transition Metals The Alkali Metals – Group 1 Very reactive metals that have only one valence electron in the outer orbit and will freely give it away to become stable. Very soft metal (you could cut it w/ a plastic knife!). They form ionic bonds w/ Halogens and Chalogens. Examples include Sodium and Potassium. The Alkaline Earth Metals – Group 2 not as reactive as Alkali Metals, but still very reactive. They have two valence electrons and generally give them up to nonmetals to form ionic bonds. Examples include Calcium and Magnesium Transition Metals – Groups 3 thru 12 These all vary dramatically in reactivity, Their oxidation states (# of valence electrons) vary. They are a bridge between the very reactive Alkali and Alkaline Earth Metals and the nonmetals. Chalogens AKA: Oxygen Family – Group 16 nonmetals w/ 6 valence electrons, need 2 electrons to fill the outer shell. Most common oxidation state is -2. Examples are Oxygen (ozone is one of its allotropes), Sulfur (responsible for that rotten egg smell when it combines w/ oxygen to form sulfur dioxide) and Selenium (one of the few non metals that are also a good conductor of electricity). Halogens – Group 17 Very reactive nonmetals w/ 7 valence electrons. Need only one more electron to fill their outer shell. Will steal an electron from a reactive metal to form ionic bonds. Examples include Chlorine (the most abundant halogen), Iodine and Bromine (found in Seawater). Noble Gases - Group 18 Non reactive, have a full compliment of valence electrons, 8 and are called the “Inert Gases” because they do not react w/ other elements. Examples include Helium (very low mass and is used in filling children’s balloons and even airships and the “Goodyear Blimp) and Neon used in lighted bulbs to make a red glowing light ( a neon light). More Need-to-Knows Transition Metals Actinides Lanthanides Rare Earth Elements – AKA Inner Transition Metals Properties of Metals Metals are good conductors of heat and electricity. Metals are shiny. Metals are ductile (can be stretched into thin wires). Metals are malleable (can be pounded into thin sheets). A chemical property of metal is its reaction with water which results in corrosion. The Metals Examples include: Iron, Tin, Sodium, Calcium, Gallium Most of the elements are metals. Metals tend to form positive (+) ions. (They lose electrons) Physical Properties – Such as hardness, shiny, malleability (pounded into shapes), – ductility (stretched or pulled into a wire) electrical conductivity and magnetic. Chemical Properties – Form metallic bonds with metals and form Ionic bonds w/ nonmetals. Properties of Non-Metals Non-metals are poor conductors of heat and electricity. Non-metals are not ductile or malleable. Solid non-metals are brittle and break easily. They are dull. Many non-metals are gases. Sulfur 17 Nonmetals a. There are 17 nonmetals, each are located to the right of the zigzag line in the periodic table. b. Non metals tend to steal electrons when they form negative (-) ions. c. Physical Properties – in general the physical properties of nonmetals are opposite those of metals. non conductive, dull, not ductile or malleable, brittle, gaseous d. Chemical properties – usually form ionic bonds when combined w/ metals (NaCl, FeO2, and CaCl2 ) and usually form covalent bonds when combined w/ other nonmetals (CO2, O2, C6H12O6) e. Even though Hydrogen (H) is located in Group 1, it is still a nonmetal and exhibits Nonmetals are the oxidation states of +1 and -1. light blue elements Properties of Metalloids Metalloids (metal-like) have properties of both metals and non-metals. They are solids that can be shiny or dull. They conduct heat and electricity better than nonmetals but not as well as metals. They are ductile and malleable. Silicon Metalloids AKA “semi metals” 7 elements on the zigzag border between metals and the non metals. Their properties will sometimes make them act like a metal and then sometimes act like a nonmetal. Most important characteristic is their varying ability to conduct electricity. Silicon is used to make Semiconductors which are used in making computer chips. Isotopes And Radioactivity Isotopes Review… Isotopes are atoms that have the same number of protons but different numbers of neutrons (they are still the same element) Why are they still the same element? They have the same number of protons Which Lets means? They have the same atomic number review this more closely………. Isotopes…....... Isotopes of Carbon What did we learn?… Isotopes are atoms that have the same number of protons but different numbers of neutrons (they are still the same element) Why? They have the same number of protons Which means? They have the same Atomic Number but different atomic mass (they can also be radioactive!) Lets talk about radioactivity………. What is Radioactivity? Radioactivity occurs when certain elements literally fall apart because their nucleus is unstable Usually protons and neutrons are emitted by the nucleus Sometimes an electron is emitted by the nucleus, which changes a neutron to a proton Sometimes just high energy gamma radiation is emitted Stopping Radiation Half Life……. The time it takes for ½ the mass of a radioactive element to decay into another element Some Half Lives Carbon-14: 5,730 years Uranium-235: 704 MY Potassium-40: 1.3 BY Uranium-238: 4.5 BY Rubidium-87: 48.8 BY Each half-life, the amount of atoms gets cut in half. One half-life. Two half-lives. Three half-lives. Four half-lives. Don’t worry about the last atom. You start with so many trillions that you never really get there. (It will just decay and then they’re all gone.) http://lectureonline.cl.msu.edu/~mmp/applist/decay/decay.htm WE B FINISHED !! All Done !