WEIGHT HANGING FROM A PISTON Statement In a vertical cylinder, of 10 cm in diameter and 0.5 m of height, open on the bottom, a 10 kg piston with its top surface at 20 cm from the cylinder closed end, encloses a certain amount of carbon dioxide. Find: a) The equilibrium pressure. b) The amount of gas trapped. En un cilindro vertical de 10 cm de diámetro y 0,5 m de altura, abierto por abajo, un émbolo de 10 kg cuya cara superior está a 20 cm del fondo del cilindro, encierra una cierta cantidad de dióxido de carbono. Determinar a) La presión en el equilibrio. b) La cantidad de gas atrapado. Solution a) The equilibrium pressure. First a sketch to help visualise the system: Fig. 1. Sketch of a cylinder with a hanging piston, and the piston free-body force diagram. Assuming that friction between piston and cylinder is not dominant; what prevents the piston falling down out of the cylinder? Suction of the trapped gas? Vacuum? Can pressure be negative? A main advantage of science is that, once the basic Principles of Nature have been mastered, applying the fundamental laws solves the problem with no hesitation; the force balance on the piston as a free body at rest, gives the answer: pA m g p A p p F 0 P 0 0 mP g 10 9.8 105 87.5 kPa 2 D 0.12 4 4 where a standard value of 100 kPa for the ambient pressure is assumed, in lack of more precise data. In practise, friction would never be totally negligible, and, if such an experiment were tried in the lab (e.g. with a tight-fitting self-lubricating graphite piston in a precision-machined cylinder), a range of acceptable values might be 87..88 kPa. And do not forget that the less friction, the more difficult to keep the piston seal air-tight (a low-friction piston will eventually fall down the cylinder). Weight hanging from a piston 1 b) The amount of gas trapped. From pV=nRT, n=pAz/(RT)=87.5·103·(0.12/4)/(8.3·288)=0.058 mol (2.5 g), where a standard value of 288 K (15 ºC) for the ambient temperature is assumed, in lack of more precise data. Comments A lesson to learn The author regrets to point out the sad fact that, having proposed such an exercise to some 100 entryuniversity-students, only some 20% of them managed to solve the first part of this problem (accepting as valid such offending nonsense as p=87555.282 Pa!). There were many types of mistakes, from which we (all, students and teachers) should learn a good lesson: 1. Some 30% were unaware of the force balance, and simply answered p=100 kPa at equilibrium, or looked for a solution through some astray relation like pV=constant (or worse, reasoning 2. 3. 4. 5. that "if gases at STP-conditions occupy 22.4 litres, to the given 1.6 litres of CO2 should correspond a pressure of 100·1.6/22.4=7 kPa"). Some 30% made 'just a sign mistake' and answered p=p0+mg/A=112 kPa. Some 20% did not pay attention to atmospheric pressure (perhaps induced by the generalised used of manometric pressure in most ordinary-life instances (e.g. tyre pressure, hydrostatic pressure, and so on). Some 20% made mistakes on geometrical calculations, setting e.g. V=Dz, V=Dz, V=D2z, or A=D2, or on trivial unit conversions like setting 10 cm=0.01 m. For the second question, some 20% used the expression m=V with the density taken from a tabulation of liquid data. 6. For the second question, some 10% used the expression m=RT/(pV), in spite that it was an open-book exercise. 7. For the second question, some 10% made mistakes using the gas constant, mixing-up units. Back Weight hanging from a piston 2