Weathering Mechanical and Chemical What Caused This? What is Weathering? • First step to forming soil and sedimentary rock. – Breakdown of rock into smaller pieces – The smaller pieces do not move to a new location, but remain next to one another until erosion carries them away. – Mostly occurs at the surface but can also occur below ground – Many types of weathering What is Mechanical Weathering? • Breakdown of rock into smaller pieces without any change in the chemical composition of its minerals. – Sometimes called “physical” weathering – Rock is torn apart by physical force, rather than by chemical breakdown. – Smaller pieces do not move to a new location, but remain next to one another until erosion carries them away. Mechanical - Ice Wedging Ice Wedging – Water fills joints of rocks and freezes – Water expands 10% when it freezes, pushes rock apart – Repeated freeze and thaw cycles over the years causes rock to break along joint Mechanical - Exfoliation • Exfoliation or unloading – Rock breaks off into leaves or sheets along joints which are parallel to the ground surface – Caused by expansion of rock due to uplift and removal of surface material that covered the rock Mechanical - Thermal • Thermal expansion – Repeated daily heating and cooling of rock – Heat causes expansion; cooling causes contraction – Different minerals expand and contract at different rates causing the rock to split Mechanical - Biotic • Biotic – means life – Weathering caused by living organisms – Plant roots most common cause, act as a wedge and widen cracks – Other causes of biotic weathering are digging animals, microscopic plants and animals, algae and fungi. What is Chemical Weathering? • Breakdown of rock into smaller pieces because of change in the chemical composition of its minerals. – Chemical reactions break down the bonds holding the rocks together, causing them to fall apart. – Chemical weathering occurs in all types of rock but smaller rocks are more susceptible because they have a greater amount of surface area. – Chemical weathering is more common in locations with lots of water and heat speeds it up. – Rock reacts with water, gases and solutions (may be acidic); these reactions will add or remove elements from minerals. Chemical - Oxidation • Oxidation - oxygen combines with other elements in rocks to form new types of rock – New substances are usually much softer than original, easier for other forces to break rock apart – Causes a “rusting” of the rock, often causes a color change in the rock Chemical - Hydrolysis • Hydrolysis - water combines with the substances in rocks to form new types of substances – New substances are softer than the original rock types – Most common reaction is the hydrolysis of feldspars producing clay minerals – e.g. feldspar kaolinite Chemical - Carbonation • Carbonation – Carbon dioxide is dissolved in water making carbonic acid – Weak acid is formed when carbon dioxide in the air mixes with rain. This is the same acid found in soft drinks. – Acid is too weak to harm plants and animals but slowly causes feldspars and limestone to decompose. – Occurs when carbonic acid reacts with a rock to form a new substance Chemical - Biotic • Organisms - can change the chemistry of their environment – Plants lower the local pH to make it more acidic – Bacteria act as catalysts in various geochemical processes Equilibrium • The forces of weathering stabilize the build up of new land formations that follows volcano eruptions.