Table 01 Chemicals used for Titration of NaOH Lab Name Formula Molar Mass (g/mol) Acetic Acid (Vinegar) CH3COOH 60.05 Sodium Hydroxide NaOH 40.00 Potassium Hydrogen Phthalate KHC8H4O4 204.23 This is a table that displays the relevant properties for the chemicals used in the lab Table 02 Titration for the Standardization of NaOH Trial 1 Trial 2 Trial 3 Mass KHP (g) 1.165 1.276 1.345 Moles KHP (mol) 0.005704 0.006248 0.006586 Volume KHP (mL) 100.0 100.0 100.0 Molarity KHP (mol/L) 0.05704 0.06248 0.06586 V1 NaOH (mL) 0.23 0.56 0.05 V2 NaOH (mL) 23.08 24.01 26.41 VT NaOH (mL) 22.85 23.45 26.36 Avg Molarity of NaOH Molarity of NaOH (mol/L) 0.2496 0.2664 0.2498 0.2553 This is table providing raw data for the Standardization of NaOH using KHP. The average molarity of NaOH was then used to titrate a known volume of acetic acid (vinegar) Table 03 Titration of Vinegar by NaOH Trial 1 Trial 2 Trial 3 Trial 4 Trial 5 Molarity NaOH (mol/L) 0.2553 0.2553 0.2553 0.2553 0.2553 V1 NaOH (mL) 0.35 0.08 0.25 0.01 5.70 V2 NaOH (mL) 33.95 43.69 29.89 32.65 40.10 VT NaOH (mL) 33.60 43.61 29.64 32.64 34.40 Molarity Vinegar (mol/L) 0.8535 0.9089 0.7915 0.8375 0.8782 AVG Molarity of Vinegar 0.8539 Volume Vinegar (mL) 10.05 12.25 9.56 9.95 10.00 This is a table providing raw data for the titration of Vinegar (acetic acid) with NaOH. The average molarity of vinegar was then used to determine the percent by mass of acetic acid in vinegar. Table 04 Results Experimental Theoretical Percent Error (%) Molarity NaOH (mol/L) 0.2553 0.30 14.90% Molarity Vinegar (mol/L) 0.8539 0.83 2.88% %Acetic Acid in Vinegar 5.128 5.0 2.55% This is a table to display the major results of the Titration Lab Table 05 Equation Example Explanation ππ‘ = ππ − ππ ππ = 0.04 ππΏ ππ = 34.56 ππΏ ππ‘ = 34.56 − 0.04 = 34.52 ππΏ This calculation was used for finding the volume of NaOH dispensed by the buret in both the Standardizatio n and Neutralization The mass of KHP was measured out during the lab and dissolved into water, in order for the molarity to be calculated the #moles was needed The moles of solute dissolved in 1.0 L solution is the concentration (molarity) The titration equation is very similar to the dilution equation and is used to determine equivalent moles of each This is the simple average, calculated since 2nd grade ο The percent error is a display of the difference between the accepted and experimental values Volume Dispensed by buret Calcul ation πππππ = πππππ πππππ 20.00 π π»2π π₯ 1 πππ π»2π = 1.11 πππ π»2π 18.02 π π»2π g --> mol conversion πππππ π₯ ππππ π πππ’π‘π πππ‘πππ ππ π πππ’π‘πππ Molarity πππππππ‘π¦ = 20 πππππ 4.0 πΏ When 20moles of solute is dissolved in 4.0 L of solution, a 5.0 M solution results ππ π₯ ππ = ππ π₯ ππ 0.5π π₯ 100ππΏ = 0.25π π₯ 200ππΏ Titration The amount of moles in 100 mL of 5.0M solution is the same as that in twice the volume of diluted solution ½ the concentration Average π΄π£πππππ ππ π΄&π΅ = % πΈππππ = | Percent Error 5.0 = π΄+π΅ 2 πβπππππ‘ππππ − πΈπ₯ππππππππ‘ππ | π₯100 πβπππππ‘ππππ 5= 4% = | 4+6 2 25 − 24 | π₯100 25 The percent difference between the theoretical and experimental values were calculated as 4% Percent Acetic Acid in Vinegar πππ ππππ π ππππ πΏ π»2π ππΏ π»2π π₯ π₯ π₯ π₯100 πΏ π»2π πππ ππππ ππΏ π»2π ππ»2π π ππππ = π π»2π 0.83 πππ ππππ 60.05 ππππ πΏ π»2π π₯ π₯ πΏ π»2π πππ ππππ 1000ππΏ π»2π 1 ππΏ π»2π π₯ π₯100 = 4.98% 1 ππ»2π The percent acetic acid in vinegar is found using the molarity of vinegar found during titration, the molar mass of vinegar, and known properties of water In order to solve for the percent acetic acid in vinegar, the units must be tracked and % AA by mass solved for