DO NOT WRITE ON THIS TEST VER A Mississippi Chemistry Summative 2010 2A. CLASSIFYING MATTER Table of Densities Element g/cm3 Scandium 2.99 Actinium 10.07 Palladium 12.02 Rhenium 21.04 1. Donovan is trying to find the density of an unknown element. He found that the mass of the element is about 6 grams and the volume is 2cm3. Using the table above what is the unknown element? A. Actinium B. Palladium C. Scandium D. Rhenium 4. Which of the following could be considered as a molecule and an element? A. H2O B. Kr C. CH3OH D. I2 The graph below represents the uniform cooling of a sample of lauric acid starting as a liquid above freezing point. Below is an atomic model. 5. Using the graph above, what is the phase change that takes place from point C and B? A. Condensation B. Sublimation C. Melting D. Freezing 2. What matter is displayed in the atomic model above? A. Compound B. Heterogeneous mixture C. Element D. Homogeneous mixture 3. As molecules of a substance goes from a gas liquid solid, what happens to the molecular motion of the molecules? A. Molecules speed up. B. Molecules slow down. C. Molecules remain at constant speed. D. It is impossible to determine what happens to the molecules. 2B. HISTORY OF THE ATOM 6. Which best describes the current model of an atom? A. A central nucleus containing protons with electrons orbiting in specific paths B. A solid sphere with electrons and protons embedded C. A solid sphere unique for everything that exists D. A central nucleus containing protons and neutrons with electrons orbiting in levels of high probability DO NOT WRITE ON THIS TEST VER A 7. The most current model of the model is the wave-mechanical model. Which scientist discovered that the protons in the center of the atom and what experiment did he use to discover these particles? A. Rutherford used the Gold Foil Experiment to determine protons are in the center of the atom. B. Thomson used the Cathode Ray Experiment to determine protons are in the center of the atom. C. Dalton used the Gold Foil Experiment to determine protons are in the center of the atom. D. Bohr used the Cathode Ray Experiment to determine protons are in the center of the atom. 3A. ATOMIC STRUCTURE 11. Which two particles make up both the nucleus and the atomic mass? A. electron and neutron B. proton and neutron C. proton and electron D. electron and positron 12. An atom in the ground state contains a total of 7 electrons, 7 neutrons, and 7 protons. Which Lewis electron-dot diagram represents this atom? 8. Which of the following researchers and their model is incorrectly paired? A. Thomson : Plum Pudding Model B. Bohr : Nuclear Theory C. Rutherford : Nuclear Theory D. Dalton : Atomic Theory 13. Which of the following electronic configurations for Nitrogen is written correctly? A. 1s2 2s2 2p6 B. 1s2 2s2 2p1 C. 1p2 2p2 2s6 D. 2p6 9. What element does the Bohr model below represent? A. B. C. D. 14. How many neutrons are in an atom of Iridium-192 (atomic number 77)? A. 115 B. 92 C. 77 D. 125 15. Which two notations represent different isotopes of the same element? 32 A. 73 Li and 73 Li C. 32 15 P and 16 S Carbon Boron Nitrogen Beryllium 10. The atomic number of an atom always equal to the number of its A. neutrons, only B. protons plus neutrons C. protons, only D. protons plus electrons B. 14 7 Be and 14 6 Be 32 D 15 P and 2D. NUCLEAR CHEMISTRY Which nuclear emission 16. has the greatest penetrating power? A. gamma radiation B. beta particle C. positron D. alpha particle 30 15 P DO NOT WRITE ON THIS TEST VER A 17. Which nuclear emission has the greatest mass? A. B. + C. D. 22. What two types of atoms bond together in ionic bonding? A. nonmetal and nonmetal B. metal and nonmetal C. metal and metal D. metal and metalloids 18. The nucleus of a radium-226 atom is unstable. What does this cause the nucleus to spontaneously do as a result of the instability? A. oxidize B. absorb protons C. decay D. absorb electrons 23. How many more electrons does a Hydrogen atom at ground state need to complete the octet rule? A. 1 electrons B. 7 electrons C. 2 electrons D. It already satisfies the octet rule. 19. In the third step of Uranium decay, Protactium-234 goes through BETA DECAY. Which equation represents the decay? 0 234 A. 234 91Pa1 e + 92 U B. 234 91 Pa 10 e 23490Th C. 234 91 Pa42 He + D. 234 91 Pa 42 He 23490Th 234 92 U 20. If 100g of Uranium-239 went through 2 half-lives, then how much is left? A. 50g B. 120g C. 12.5g D. 25g 2E. CHEMICAL BONDS 21. What type of bond would be predicted when Oxygen and Sulfur form SO2? A. covalent bond B. hydrogen bond C. isotopic bond D. ionic bond 24. Which symbol represents a particle with a total of 7 electrons? A. B2+ B. F2+ C. B2D. Both B and C 25. Which covalent bond has the greatest polarity? A. H-N B. H-B C. H-C D. H-O 2G. THREE-DIMMENSIONAL ATOM 26. Which Lewis electron-dot diagram is correct for S2- ion? DO NOT WRITE ON THIS TEST Below is a student drawn Lewis Dot Diagram of COH2. 27. Which of the following statements is FALSE? A. Ten valence electrons can be used to create the bonds in the atom. B. A lone pair from oxygen needs to form a double bond with carbon. C. The two hydrogen atoms satisfy the octet rule. D. The oxygen atom has three lone pairs. Below is a student drawn Lewis Dot Diagram drawing of NH3. 28. What should the student do to finish the Lewis Dot Diagram above? A. Do nothing because everything satisfies the octet rule. B. Substitute the nitrogen with boron and the molecule will be stable. C. Add a double bond between an N and H. D. Add a lone pair to the nitrogen. 29. In a molecule what is the behavior of valence electrons? A. Valence electrons move close to each other. B. Valence electrons constantly trade places with each other. C. Valence electrons are neutral, so they do not display attractive or repulsive behavior. D. Valence electrons move away to each other. VER A 30. What is the name for the molecule below? A. B. C. D. Trigonal Pyramidal Trigonal Planar Bent Tetrahedral 3C. CHEMICAL REACTIONS 31. What type of reaction is the following? 2AlCl3 +3H2 6HCl + 2 Al A. B. C. D. Double displacement Decomposition Combustion Single displacement 32. What type of reaction is the following? C3H8 + 5 O2 3 CO2 + 4 H2O A. B. C. D. Combustion Double displacement Decomposition Single displacement 33. What are the coefficients of the following equations? _______LiN3 (s) ____N2 (g) + ____Li (s) A. B. C. D. 1, 1, 2 2, 6, 2 1, 3, 1 2, 3, 2 34. Which of the following metals cannot replace Lead? A. Gold B. Iodine C. Lithium D. Both A and B DO NOT WRITE ON THIS TEST 35. What are the products of the single replacement reaction below? F2 + KBr _________ A. B. C. D. Br + KF2 F2 + KBr2 Br2 + KF KBr + F2 VER A 40. What is the molecular formula of a compound with the empirical formula O and molar mass of 48g/mol? A. 2O B. 3O C. O2 D. O3 CONVERSIONS 3D. THE PERIODIC TABLE 36. What is the relationship between chemical reactions and chemical equations? A. A chemical reaction symbolically represents a chemical equation. B. Chemical equations and chemical reactions have no similarities. C. A chemical equation symbolically represents a chemical reaction. D. Chemical equations and chemical reactions are the same thing. 37. What is the approximate molecular mass of Ca(OH)2? A. 72amu B. 74amu C. 114amu D. 43amu 41. Convert 300K to Celsius. A. 0oC B. 573oC C. 27oC D. 300oC 42. How do you represent 3,040,000 in scientific notation? A. 3.04 x 106 B. 3.040000 x 106 C. 3.040000 x 10-6 D. 3.04 x 10-6 43. How many molecules are inside 3 moles of H2O? A. 18.06 x 1023 B. 24.08 x 1023 C. 12.04 x 1023 D. 6.02 x 1023 38. What is the percent composition by mass of aluminum in Al2(SO4)3 (atomic mass = 342 grams/mole)? A. 7.89% B. 20.8% C. 36.0 % D. 15.8 % 44. If you have 4 moles of Lithium, then how many grams do you have? A. 7g B. 14g C. 21g D. 28g 39. Which of the following molecules is a molecular formula? A. CH3COOH B. Hg C. P2O5 D. C2H6O 45. If you 320g of Br2 then how many moles do you have? A. 1 moles B. 4 moles C. 2 moles D. 3 moles DO NOT WRITE ON THIS TEST 4B. IDEAL GAS VER A 4C. IDEAL GAS EQUATION 46. Real gases act most like ideal gas under what conditions? A. High pressure, high temperature B. High pressure, low temperature C. Low pressure, high temperature D. Low pressure, low temperature 51. What is the pressure of 2 moles of gas in a 100L container at 500K? A. 10 atm B. 100 atm C. 0.82 atm D. 8.2 atm 47. Jordan made an observation of nitrogen gas. She found that the gas moved at had attractive forces and the energy was conserved in the reactions. What can he conclude about the gas? A. The gas is a real gas. B. We cannot conclude anything about the gas. C. The gas is in a supersaturated state. D. The gas is an ideal gas. 52. How many moles of air are there in a .200L Erlenmeyer flask if the pressure is 760 mmHg and the temperature is 40 °C? A. .008 moles B. 8 moles C. .006 moles D. 6 moles 48. What are the two differences between an ideal gas and a real gas? A. Real gases have attractive forces and have mass. B. Real gases do not have attractive forces and do not have mass. C. Real gasses do not have attractive forces and have mass. D. Real gases have attractive forces and do not have mass. 49. Convert 1500mL to L. A. 1.5L B. .15L C. 150L D. 15L 50. Convert 1520mmHg to atm. A. 1mol B. 3mol C. 4mol D. 2mol 53. If I put 5 moles of Oxygen gas into a balloon at STP, then what will the volume of the balloon be? A. 111.9L B. 0.002L C. 4.47L D. 0.41L 54. A bag of chips in a truck travelled from 1atm and moved to a state with a pressure of 0.5atm. If the volume of the bag started at 25mL, then what is its final volume assuming the truck was at constant temperature and number of moles remained constant? A. 50mL B. 100mL C. 5mL D. 10mL 55. A scuba tank changed from 5atm to 10atm as it sunk below the water. If the scuba diver’s tank started at 350K, then what is the tank’s new temperature? (Assume there are constant moles and volume) A. 700K B. 17,500K C. 70K D. 175K DO NOT WRITE ON THIS TEST 4E. SOLUTIONS 56. What is another term for to solutions that cannot mix? A. Miscible B. Solute C. Immiscible D. Solvent 57. Which of the following will NOT increase the solubility of a substance in a solution? A. Increasing the surface area B. Crushing the solute C. Heating the solution D. Cooling the solution Use the solubility curve chart on your reference page for the following question. 58. If I dissolve 100g of NaNO3 in 100g of H2O at 50oC then what state will the solution be in? A. Saturated B. Supersaturated C. Unsaturated D. Equalized 59. A reaction calls for 20mL of a 2.5 M solution of potassium iodide. You only have 4M and 1M solutions in your stock cabinet. Which could you do to make your solution? A. Mix 10mL of each of the 4M and 1M solutions B. Obtain 12.5mL of the 4M solution and dilute it to 20mL C. Obtain 12.5mL of the 1M solution and dilute it to 20mL D. Add 15mL of 1M solution to 5mL of 4M solution VER A Use the equation below to answer the following questions. H2(g) + F2(g) ⇌2HF(g) 60. If the reaction is at equilibrium, and I add more F2(g), then what will happen to the reaction? A. The reaction will shift right. B. The reaction will shift left. C. The reaction will not shift. D. The reaction will shift left, then right. 5A. ACIDS AND BASE PROPERTIES 61. Like litmus paper, cabbage juice changes color based on a substance’s pH. Therefore, both cabbage juice and litmus paper are what? A. Detectors B. Notifies C. Magic D. Indicators 62. Acids have a _________ taste, whereas bases have a __________ taste. A. bitter, sour B. sour, sour C. bitter, bitter D. sour, bitter 63. If the pH of a substance is 4, then what is the pOH? A. 16 B. 12 C. 10 D. 0 64. The pH of a solution was once 2 but now is 100 times more basic. What is its new pH? A. 4 B. 0 C. 200 D. 6 DO NOT WRITE ON THIS TEST 65. The pH of a solution changed from 7 to 6. What happened to the concentration of H+ ions? A. decreased by a factor of 10 B. increased by a factor of 100 C. increased by a factor of 10 D. decreased by a factor of 100 5B. BRØNSTED-LOWRY AND ARRHENIUS ACID/BASE REACTIONS 66. In the following reaction what does the role of water play? H2O + NH3 NH4+ + OHA. B. C. D. It is a BrØnsted acid It is a BrØnsted base It is both an acid and a base It neither an acid or a base 67. Which substance is an Arrhenius base in the following reaction? HCl + LiOH H2O + LiCl A. B. C. D. LiOH H2O LiCl HCl 68. What is the product of the neutralization reaction below? H2S + 2KOH A. B. C. D. KS + H2O H3O+ + SOK K2S + 2H2O The products cannot be determined 69. Which volume of 10 M KOH(aq) exactly neutralizes 200 milliliters of 5 M HNO3 (aq)? A. 10mL B. 100mL C. 10000mL D. 0.25mL VER A Information related to a titration experiment is given in the balanced equation and table below. H2SO4+ NaOH H2O + NaF Titration Experiment Results Volume of H2SO4 (aq) used 5.0 mL Concentration of H2SO4(aq) ? Volume of NaOH (aq) used Concentration of NaOH (aq) 10 mL 2.5 M 70. Based on the equation and the titration results, what is the concentration of the H2SO4(aq)? A. 5M B. 1 M C. 4 M D. 3 M