Vocabulary 14 • • • • • organic hydrocarbon alkane alkene alkyne • • • • • ubiquitous woolgathering sophistry meretricious sylvan Difference in all of the bonds… Ionic Polar Covalent Non-Polar Covalent 1.7 4.0 0.3 1.7 0 0.3 High melting point Low melting point Low melting point Solids Solids and liquids Liquids and gases No dipoles Dipoles No dipoles Dissolves in Dissolves in Dissolve in nonpolar covalent polar covalent polar covalent “Like dissolves like” • Ionic substances will dissolve in polar covalent because both contain charges • Think NaCl and H2O – NaCl = 3.0 – 0.9 = 2.1 = ionic – H2O = 3.5 – 2.1 = 1.4 = polar covalent “Like dissolves like” • Polar and non-polar will not mix • Non-polar contains no charges to attract polar molecules • Think water and oil – H2O = 3.5 – 2.1 = 1.4 = polar covalent – Oil = non-polar covalent “Like dissolves like” • When would this come in handy? “Like dissolves like” • Sugar = polar • Water = polar “Like dissolves like” • Gasoline = non-polar Ionic • Oil = non-polar Ionic Polar Soluble NonPolar Not Soluble Polar Polar Soluble Polar NonPolar Not Soluble NonPolar NonPolar Soluble • worksheet Lab: Covalent Bonds • Predict Bond Type 4.0 1.7 1.7 0.3 0.3 0 Ionic Polar Covalent Non-polar Covalent Add this table to the front page of your lab… Test Tube Sugar Soluble (yes/no) 1 (water) 2 (water) --------------------- 3 (alcohol) 4 (alcohol) Mineral Oil Soluble (yes/no) ----------------------------------------- --------------------- 1 1 1 2 2 2 3 3 3 4 4 4 5 5 5 6 6 6 Well plate Test conductivity Test solubility in water Test solubility in alcohol Test Tubes 1 2 •distilled water •distilled water •sugar •Mineral oil 3 •alcohol •sugar 4 •alcohol •Mineral oil Quiz Thursday!! • Make sure you know… – Electronegativity – Covalent bond strength – What creates polar and non-polar bonds? • Unequal or equal sharing? – Be able to calculate electronegativity difference and predict bond type – Solubility of bond types – Naming ionic and covalent bonds Lewis Dot Structures • Used to predict and show structural arrangement of molecules • Follows OCTET RULE • For example PH3 – Phosphorus has 5 valence electrons – Hydrogen has 1 valence electrons Lewis Dot Structures • Hydrogen only has one electron to share terminal atom (on the end) • All atoms have full outer energy level (2 or 8 electrons) Lewis Dot Structures • Another technique is to substitute lines for electrons Lewis Dot Structure Practice • H2 H H H—H • H2O – H = 1 valence e– O = 6 valence e- H O H H—O—H • CCl4 More practice… – C has 4 valence e– Cl has 7 valence e- Cl Cl C Cl Cl Cl Cl—C—Cl Cl Steps for Lewis Dot Structures 1. Determine number of valence electrons for each element 2. Determine central atom (atom with lowest electronegativity value) 3. Write central atom and valence electron dots 4. Fill in remaining elements with their valence electron dots