Name: _________________________ Date: ____________ Period: _______ AP Chemistry – OHS – Chapter 2B Practice Mr. Daniel Reviewing Important Concepts 1. A model of the cancer chemotherapy agent cisplatin is given here. How many N atoms are in one molecule? How many H atoms occur in one molecule? How many H atoms are in 1 mol of the compound? What is its molar mass? 3. a) How many electrons are in a strontium atom (Sr)? b) Does an atom of Sr gain or lose electrons when forming an ion? c) How many electrons are gained or lost by the atom? d) When Sr forms an ion, the ion has the same number of electrons as which one of the noble gases? 7. Which has the larger mass, 0.5 mol of BaCl2 or 0.5 mol of SiCl4? Practice Skills Molecular Formulas 10. Write the molecular formula of each of the following compounds: (a) An organic compound, heptanol, has 7 carbon atoms, 16 hydrogen atoms, and 1 oxygen atom. (b) Vitamin C, ascorbic acid, has six carbon atoms, eight hydrogen atoms, and six oxygen atoms per molecule. (c) A molecule of aspartame, an artificial sweetener, has 14 carbon atoms, 18 hydrogen atoms, 2 nitrogen atoms, and 5 oxygen atoms. 12. Give the total number of atoms of each element in one formula unit for each of the following compounds: (a) CaC2O4 (b) C6H5CHO (c) K4Fe(CN)6 Molecular Models Ions & Ion Charges 16. What charges are most commonly observed for monatomic ions of the following elements? (a) Magnesium (c) Nickel (b) Zinc (d) Gallium 1 JLD 9-22-14 18. Give the symbol, including the correct charge, for each of the following ions: (a) Barium ion (e) Sulfide ion (b) Hydrogen carbonate ion (f) Titanium(IV) ion (c) Phosphate ion (g) Perchlorate ion (d) Cobalt(II) ion (h) Sulfate ion 20. a) When potassium becomes a monatomic ion, how many electrons does it lose or gain? b) What noble gas atom has the same number of electrons as a potassium ion? Ionic Compounds 24. For each of the following compounds, give the formula, charge, and number of each ion that makes up the compound: (a) K2S (b) CoSO4 (c) KMnO4 (d) (NH4)3PO4 (e) Ca(ClO)2 26. Cobalt is a transition metal and forms ions with at least two different charges. Write the formula for the two different cobalt oxides. 28. Which of the following are the correct formulas for ionic compounds? For those that are not, give the correct formula. (a) AlCl2 (b) KF2 (c) Ga2O3 (d) MgS 30. Write all of the formulas for the compounds that can be made by combining the cations Mg2+ and Al3+ with the anions O2− and PO43−. Naming Ionic Compounds 32. Name each of the following ionic compounds: (a) K2S (b) CoSO4 (c) (NH4)3PO4 (d) Ca(ClO)2 34. Give the formula for each of the following ionic compounds: (a) Ammonium carbonate (b) Calcium iodide (c) Copper(II) bromide (d) Aluminum phosphate (e) Silver(I) acetate 2 JLD 9-22-14 Coulomb’s Law 38. Sodium ion, Na+, forms ionic compounds with fluoride, F−, and iodide, I−. You know that the radii of these ions are: Na+ = 116 pm; F− = 119 pm; and I− = 206 pm. In which compound, NaF or NaI, are the forces of attraction between cations and anions stronger? Explain your answer. Naming Binary, Nonmetal Compounds 40. Give the name for each of the following binary, nonionic compounds: (a) NF3 (b) HI (c) BI3 (d) PF5 42. Give the formula for each of the following nonmetal compounds: (a) Sulfur dichloride (b) Dinitrogen pentaoxide (c) Silicon tetrachloride (d) Diboron trioxide (commonly called boric oxide) Molecules, Compounds, and the Mole 44. Calculate the molar mass of each of the following compounds: (a) Fe2O3 (iron(III) oxide) (b) BCl3 (boron trichloride) (c) C6H8O6 (ascorbic acid, vitamin C) 46. Calculate the molar mass of each hydrated compound. Note that the water of hydration is included in the molar mass. (See section 3.7.) (a) Ni(NO3)2 · 6 H2O (b) CuSO4 · 5 H2O 48. What amount (moles) is represented by 1.00 g of each of the following compounds? (a) C3H7OH, propanol, rubbing alcohol (b) C9H8O4, aspirin 52. Sulfur trioxide, SO3, is made industrially in enormous quantities by combining oxygen and sulfur dioxide, SO2. a) What amount of SO3 (moles) is represented by 1.00 kg of sulfur trioxide? b) How many molecules would that be? c) How many sulfur atoms? d) How many oxygen atoms? 3 JLD 9-22-14 Percent Composition 54. Calculate the mass percent of each element in the following compounds. (a) PbS (lead(II) sulfide: also known as the mineral galena) (b) C3H8 ( propane) 56. Using your answer from question 54a, calculate the mass of lead in 10.0 g of PbS. 58. If you wish to obtain 100.0 g of hydrogen gas from propane (C3H8) what mass of C3H8 must you start with? (Use your data from question 54b) Empirical & Molecular Formulas 62. Complete the following chart: 64. Acetylene is a colorless gas used as a fuel in welding torches, among other things. It is 92.26% C and 7.74% H. Its molecular mass is 26.02 g/mol. Calculate the empirical and molecular formulas of acetylene. 68. Mandelic acid is an organic acid composed of carbon (63.15%), hydrogen (5.30%), and oxygen (31.55%). Its molecular mass is 152.14 g/mol. Determine the empirical and molecular formulas of the acid. 70. If Epsom salt, MgSO4· x H2O, is heated to 250°C, all the water of hydration is lost. On heating a 1.687-g sample of the hydrate, 0.824 g of MgSO4 remains. How many molecules of water occur per formula unit of MgSO4? 72. A new compound containing xenon and fluorine was formed by shining sunlight on a mixture of 0.526 g Xe and excess F2 gas. If 0.678 g of the new compound was produced, what is its empirical fomula? 4 JLD 9-22-14