1 UNIVERSITY OF IDAHO & SANDIA NATIONAL LABS Thermopile Test Bench Interim Design Document Adrian Aspinall, David Eld, Tyler Merritt, Paul Sowinski 8/5/2010 2 Executive Summary For our senior design project Sandia National Labs has submitted a project to develop and build a thermopile test bench. This test bench will measure the electrical characteristics and efficiency of thermopiles. Sandia is currently working on energy harvesting technology using thermopile, and the ability to determine the electrical characteristics and thermal efficiency is needed. The test stand will need to take a host of thermal and electrical measurements under controlled conditions. For the electrical characteristics measurements the test bench will measure open circuit and load output voltages, internal impedance, and electrical output power. During the first semester of our project we laid down the foundation for building the test bench. We conducted initial research into the background of the projects looking into the theory of operation behind thermopiles and sensor and instruments that would be useful in developing the test bench. The various systems we would need for the test bench were defined, and we began testing and selecting the sensors and other hardware that will used. In this report will go over the systems we looked into and finally chose for heating, cooling, heat flux measurement, and axial loading systems. Ultimately we chose a system using a ceramic heater, a thermoelectric cooling system, thin film heat flux sensors, and an electrically driven linear actuator. These systems will be controlled and monitored by a program developed in Labview. We have also developed a plan and tentative schedule for the following semester. 3 Contents 1.0 Background ......................................................................................................................................................4 1.1 Project Introduction ....................................................................................................................................4 1.2 Motivation ...................................................................................................................................................4 2.0 Problem Definition ..........................................................................................................................................5 2.1 Problem Statement .....................................................................................................................................5 2.2 Measurement and Control ..........................................................................................................................5 2.3 Heat Flux Calculation ...................................................................................................................................5 2.4 Voltage Calculation......................................................................................................................................6 2.5 Efficiency Calculation...................................................................................................................................6 2.6 Radiation Calculation...................................................................................................................................8 3.0 Concepts Considered .......................................................................................................................................9 3.1 Heat Flux Sensors ........................................................................................................................................9 3.2 Heaters ..................................................................................................................................................... 10 3.3 Coolers ...................................................................................................................................................... 11 3.4 Axial Load Application .............................................................................................................................. 12 3.5 Vacuum Chamber ..................................................................................................................................... 13 4.0 Concept Selection ......................................................................................................................................... 15 5.0 Design Solution ............................................................................................................................................. 18 6.0 Future Work ................................................................................................................................................. 22 References .......................................................................................................................................................... 25 Appendix A: Sources for Project Learning .......................................................................................................... 26 Appendix B: Axial Load Test ............................................................................................................................... 27 Appendix C: Water Block Cooling Test ............................................................................................................... 29 Appendix D: Thermoelectric Cooler Data Sheet................................................................................................. 32 Appendix E: Heat Flux Sensor Data Sheet .......................................................................................................... 35 Appendix F: Linear Actuator Data Sheet ............................................................................................................ 36 4 1.0 Background 1.1 Project Introduction The premise of the project is to create a test bench for thermopiles. A thermopile is a thermoelectric device. It converts heat energy into electrical energy. To do this it relies on two thermoelectric effects, the Seebeck effect and the Peltier effect. When an isolated conductor is exposed to a temperature gradient a voltage is set up in the material, this is known as the Seebeck effect. When two conductors of different composition are connected there is a voltage set up in each, but the voltage realized by each is different, thus there is a change in voltage across the material. When two conductors are connected under a temperature gradient a voltage is set up and current flows through the material. The opposite is also true, when current runs through two connected conductors a temperature gradient is setup up across the conductors. Those are the underlying effects of a thermopile. To further increase the output power of a thermopile many pairs of conductors are connected in series to create a larger change in voltage. To test the thermopiles they must be exposed to vacuum so heat loss is minimized and efficiency is maximized. Also, by exposing it to a vacuum the heat transfer through the material becomes much simpler. Quantities such as heat flux can be measured more accurately (1D problem instead of 2 or 3D) since there is no error associated with empirical correlations. The test bench must also exert axial load on the thermopile, this is done to minimize contact resistance. By minimizing contact resistance the hot side and cold side temperatures of the device can more accurately be measured. 1.2 Motivation Sandia National Laboratories has sponsored this project, to acquire a test bench, allowing thermopile devices to be tested in a controlled environment. As the previous solution has been described to our team, the prior test bench was a rudimentary setup and was not very user friendly. Heat flux could not be directly measured so efficiency could not be accurately determined. Also the Lab view VI was poorly put together and did not have good documentation. The new test bench will be beneficial to Sandia because it will allow users to test these devices and determine their overall efficiency, which they are not currently able to do effectively. Sandia also hopes that this project design will allow them to test their devices at various test conditions. 5 2.0 Problem Definition 2.1 Problem Statement To design and fabricate test equipment to accurately and easily determine efficiency and electrical performance of thermopiles under an imposed temperature gradient. The device must withstand vacuum, apply axial load, and display and record relevant data. 2.2 Measurement and Control The Test Bench will need to accurately measure and control the conditions of the test to determine the thermopile characteristics and efficiency. The test bench will measure the following values. Open circuit and load voltage produced by the thermopile The impedance of the thermopile The load resistance Electrical power produced by the thermopile Heat flow through the thermopile The temperature of the hot and cold sides of the thermopile The axial load applied to the thermopile The pressure of the vacuum chamber Along with measuring the test conditions the test bench must carefully control several aspects of the test these include. The hot and cold side temperatures Heat flow through the thermopile The axial load applied to the thermopile The load resistance 2.3 Heat Flux Calculation Estimate of heat flux, compare to measured heat flux. By taking T_hot and T_cold as constants and knowing an effective thermal conductivity k we can estimate the heat flux through the material with the following equation: 𝑞 ′′ = 𝑘 ∗ 𝑑𝑇 𝑑𝑥 (1) 6 q'' [W/m^2] k [W/m-K] dT [K] dx [m] s [m] A [m^2] q [W] 6769 1.1 80 0.013 0.018 0.000324 2.193 21150 1.1 250 0.013 0.025 0.000625 13.221 13750 1.1 250 0.02 0.025 0.000625 8.594 9167 1.1 250 0.03 0.025 0.000625 5.729 6875 1.1 250 0.04 0.025 0.000625 4.297 5500 1.1 250 0.05 0.025 0.000625 3.438 Table 1 Calculated values for varying thermopile sizes and temperatures Probable flux for first unit Possible fluxes for next unit (depends on dx and effective thermal conductivity) These estimates can be used to validate what our heat flux sensors return, though our flux out will be lower than our flux in as some energy will be converted to electrical energy. These values are rough estimates based on approximate thermal conductivity and approximate dimensions. 2.4 Voltage Calculation Estimate voltage from thermopile, compare to measured voltage The output voltage should agree with the following equation: 𝑉=𝛼∗ 𝑛𝑝𝑖𝑙𝑙𝑎𝑟 ∗ ∆𝑇 (2) 2 Where alpha is the Seebeck coefficient of the material, n_piller/2 would represent the number of junctions in the thermopile. This is an approximation as the Seebeck coefficient depends on the proportion of Bi and Te in the material, also not all the thermo-electric elements are in series. 2.5 Efficiency Calculation Estimate thermopile efficiency, compare to efficiency based on measurements An equation for theoretical efficiency is as follows: (Taken from the CRC Handbook of Thermoelectrics [1]) 𝜂= 𝑇1 − 𝑇2 𝑀 − 1 ∗ 𝑇 𝑇1 𝑀 + 𝑇2 1 (3) 𝑤ℎ𝑒𝑟𝑒 𝑀 = (1 + 𝑍 ∗ 𝑇𝑚 )0.5 (4) 𝑇𝑚 = 𝑚𝑒𝑎𝑛 𝑡𝑒𝑚𝑝. = 𝑇1 + 𝑇2 2 (5) 7 Figure 1 AT for different materials [2] For smaller unit 𝑇𝑚 =40°C For larger unit 𝑇𝑚 =125°C ZT will be read off the above graph rather than calculated as we do not have the required information to calculate it for our specific material. For both TE units ZT ~ 0.95 First Unit Efficiency 4.14% T1 [C] T2 [C] M 80 0 T1 [K] T2 [K] 353 1.396 ZTm Tm 0.95 40 273 Second Unit Efficiency 9.87% T1 [C] T2 [C] M 250 0 T1 [K] T2 [K] 523 ZTm Tm 1.396 0.95 125 273 Table 2 Calculated values for the first and second units Above are the calculations for efficiency, these will be used later to help validate our measurements. Measurements have yet to be performed as we have just acquired our flux sensors. Rough measurements will be made starting late august. More accurate measurement can be made when we acquire a vacuum chamber. 8 2.6 Radiation Calculation Use flux and power (based on measurements) to estimate energy lost to radiation and determine if radiation shielding must be used. By using measured heat fluxes and calculating electrical power out we can check to see if there are other losses. 𝑃𝑜𝑢𝑡 = 𝑞𝑖𝑛 = 𝑞"𝑖𝑛 ∗ 𝐴 & 𝑉2 𝑅 (6) 𝑞𝑜𝑢𝑡 = 𝑞"𝑜𝑢𝑡 ∗ 𝐴 (7) & (8) If there are no losses from the system to convection (should not be losses to convection if in a vacuum) or radiation then: qin − Pout = q out (9) If equation (9) does not hold largely true it is likely that there are appreciable losses to radiation. The equation would then take the form: qin − Pout − qradiation = qout (10) If Q_radiation is large enough to throw the efficiency calculation (9) off by say a percent or two, then the thermopile must be shielded as to minimize radiation loss. 9 3.0 Concepts Considered Figure 2 shows the initial visualization of the test bench and outlines basic components. Components in this figure correspond to the concepts considered in this section. Figure 2 Initial visualization of test bench 3.1 Heat Flux Sensors All of our heat flux sensors operate on the same principle. This principle is best described on the RdF corporation website: http://rdfcorp.com/anotes/pa-hfs/pa-hfs_02.shtml. Here are some excerpts from this page that describe the construction and operation of the heat flux sensor. “The principle of operation of the sensor is a differential thermocouple type sensor which utilizes a thin foil type thermopile bonded to both sides of a thermal barrier as shown below. The temperature difference across the thermal barrier is proportional to the heat flow through the sensor… Only one pair of junctions is required for a completed sensor; however the output signal and sensitivity are directly proportional to the number of paired junctions… Multiple pairs of junctions in series are used to increase signal and resolution.” 10 Figure 3 diagram of a heat flux sensor [3] ∆𝑇 = 𝑄 𝑆 𝐾 Where ΔT is temperature difference across the thermal barrier, Q is the heat flux through the thermal barrier, S is the thickness of the thermal barrier, and K is the thermal conductivity of the thermal barrier. For best results maximize thermal conductivity and minimize thickness. 3.2 Heaters All of our heaters operate on the same principle: Joule heating. Pass current through a wire and it will produce heat. Minimizing the cross sectional area will affect the current density allowing for lower current draw and higher voltages to attain direct conversion of electrical energy into thermal energy. The performance of our heaters therefore depends largely on the material that contains the resistive elements, in all cases some sort of etched foil. This substrate has a certain breakdown temperature after which it fails when that temperature is exceeded. Four substrates were considered: ceramic, polyimide, Teflon, and silicone. The ceramic being the only non rubber substrate can obviously withstand higher temperatures but is limited in its construction by the high temperature solder applied to attach the leads. Another drawback to the ceramic heater is that it is brittle. The rubber heaters vary in breakdown temperature and malleability and as such have inherent problems. The breakdown temperature of the rubber substrates are below our specified temperature of the heater. The picture below shows a visualization of the ceramic heater with its foil heating element. 11 Figure 4 Diagram of the ceramic heater [4] 3.3 Coolers Three principle effects where considered for our cooling device. We considered thermoelectric coolers, heat sinks, and water bath cooling. The thermoelectric cooler operates on the Peltier effect, cooling one side of the device while heating the other thus creating a temperature difference proportional to the electrical power through the device. This allows a certain amount of controllability but requires another device to remove heat from the heated side of the device. Next we considered water bath cooling with a water block removing the heat, transferring it to the water. Water can contain a lot of thermal energy, but ideally this also requires an additional device to remove thermal energy from the system. The third type of device we considered is the heat sink. The heat sink removes heat through convection and this is not ideal for our application as we intend to minimize convection within our test fixture. Figure 5 picture of the water block(left) [5] and Thermoelectric module(right) [6] 12 3.4 Axial Load Application Concepts Considered 1. Pneumatic Actuator 2. Linear Actuators (Electric) 3. Mechanical Application Overview of Pneumatic Actuator The load would be applied with a pneumatic cylinder; the load would have to be calculated by the Labview VI based on the input of a pressure sensor. Besides a pressure sensor, air lines, valves, and an air compressor would be needed (unless shop air was available). If the actuator was double acting or spring loaded that would be convenient, otherwise an external spring might need to be used to retract the actuator when thermopiles needed to be switched. Since the forces exerted by the pneumatic actuator would not be directly proportional to its displacement, measures may need to be taken to prevent damage to thermopiles- unless the actuator was sized so max load was not Figure 6 Pneumatic Actuator [7] much beyond 300 lbf with max pressure supplied A load would be generated by an electric motor with a gear reduction extending a rod. For a range of loads to be applied a spring in series may need to be used to ramp on the load. Determining load would be trivial if a spring was used in that many linear actuators have linear potentiometers built in so a force could be calculated based on a known spring constant. Alternatively, a force or pressure transducer could be used to determine the force. Either way, the signal could be passed to the Labview VI and the input to the actuator could be varied to further extend or retract. Figure 7 Electric Linear Actuator [8] 13 Overview of Mechanical Application (arbor press or clamp) The last, and obviously worst idea for axial load application is some sort of mechanical/manual load application. This could be carried out as an arbor press or a clamp with a built in mechanical advantage. The obvious problem with this from the start is that it would be difficult to control by software. For an arbor press a stepper motor or servo could possibly be implemented, for some sort of clamp a servo or solenoid could be used (with no capability of automatic load adjustment with the latter). Either way such a solution would be clumsy and roundabout. So it was not looked into too seriously from the start. Figure 8 Arbor Press [9] 3.5 Vacuum Chamber Concepts Considered 1. Custom Fabricated Chamber 2. Bell Jar 3. Pre-fabricated Chamber Overview of Custom Fabricated Chamber The vacuum chamber has not been considered at great depth yet, however these are the options considered thus far. There are a number of options for making a vacuum chamber. 1. 2. 3. 4. 5. Thick plastic sheets adhered (acrylic, Plexiglas, etc) Thick plastic tubing Round metal tubing (probably steel) Square metal tubing Modifying a pressure vessel Figure 9 Materials for fabrication With either round option sealing the door may be awkward as it may need to be on the curved side due to the likely proportions and layout of the rest of the apparatus. So the door could consist of a section of a pipe with an ID equal to the OD of the wall. The door for either material would ideally be transparent. Besides using a section of slightly larger pipe for a door (may be hard to find compatible sizes) a sheet could be thermal formed. The advantage of the plastic sheets is that sealing the doors would be trivial as they would just be flat sheets. 14 Overview of Bell Jar This would be a simple option which would require less time designing and fabricating so time could be spent elsewhere on the project. A bell jar of about the size we would need would cost roughly $700. However, there would still be fabrication required for some sort of base plate for mounting, passing wires, and passing tubing. While the amount of fabrication for the bell jar may be less, the fabrication may have to be done by us, where as fabrication of a vacuum chamber, say from round or square steel tubing, may be outsourced largely to some sort of Figure 10 Bell Jars [10] fabrication shop- so this is yet another aspect to further consider. Overview of Pre-Fabricated Chamber A prefabricated vacuum chamber may be purchased that would require little to no modifications (including vacuum pass thrus and inspection windows). However, along with that convenience is a hefty price tag and the inability to closely choose size and proportion (which may not be fully known until later in the project). A very rough estimate of cost would be $3000+. Figure 11 Pre-fabricated Chambers [11] 15 4.0 Concept Selection When considering our heat flux sensors our most important attributes included the ability to withstand our maximum temperature, operate within our power range, and have low thermal impedance. Our table below shows that again we have one option that can withstand our maximum temperature, but there are other options that come close to our specifications. Table 3 Decision matrix for flux sensor options When considering heaters our most important attributes included the ability to reach our maximum temperature, deliver thermal energy in our power range, and have a large usable area. Our decision matrix below shows that only one heater fits our maximum temperature requirement although there are a few options that come close. Table 4 Decision matrix for heating options The most important aspects for the cooling to the team were the minimum temperature, length of cooling and controllability. The minimum temperature was the most important because the cold side of the 16 thermopile can be no higher 15°C. The length of cooling refers to how long the cooling source can maintain its cold temperature. For example, an aluminum block would eventually reach the temperature of the system. The last aspect of importance was controllability. This was important because we wanted the user to be able to control the cold side temperature and not just have it fixed. Table 5 shows the different options we considered for cooling the cold side of the thermopile. All the options except the thermoelectric cooler were used by themselves. The thermoelectric cooler had to be cooled on its hot side somehow though, so we used the water block in series with it. The aluminum and stainless steel blocks and the aluminum heat sink were not chosen because they have no controllability over how cold they are and eventually would become the same temperature of the system, since they cannot rely on convective cooling in a vacuum. The water block and thermoelectric cooler were excellent choices, but using the thermoelectric cooler with the water block allowed us to have fine control over the temperature as well as having the water block consistently removing heat with water. Table 5 Decision matrix for cooling options The two most important aspects for the axial loading device were the ability to apply a 300 lbf and that it was software controlled. Table 6 shows the different options we considered for the axial load. The arbor press was not selected due to the fact that we could not think of a way to easily control it with software. The pneumatic and linear actuators were both adequate choices since both of them provided all the functions and worked in similar ways. 17 Table 6 Decision matrix for axial loading options 18 5.0 Design Solution The design of our test stand is based on the scores from our design matrices. Through these design matrices we were able to select the best components to use in our design based on how well they performed the necessary tasks. Not all components of our design have been fully considered yet, but are included in our future work to be accomplished next semester. Figure 11 shows the components that we have selected so far. Cooling Axial Loading Heat Flux Sensors Heaters Thermoelectric Cooler with Water Block Linear Actuator [12] RDF hfs-a [13] Thermostone Beryllium Oxide Heater [4] Figure 12 Selected components for design Since we do not have all the parts yet, we modeled a three-dimensional view of what the design will look like, this can be seen in figure 13. Below the thermopile is the thermoelectric cooler and water block. Above the thermopile is the heating block (copper or some other highly conductive material), the heater isolation block, and the linear actuator. This is all contained in a vacuum chamber, which we will be researching next semester. + Figure 13 Current 3D design of test stand (not all parts proportional) 19 To confirm that the thermoelectric cooler and water block meet our specifications, we tested the cooler against different options of cooling the hot side. The detailed results can be found in the Water Block Test write-up in the appendices, but using room temperature water with the water block, we achieved -7.5°C. This exceeded our goal temperature of 10°C at the beginning of the project. This setup is also ideal because the thermoelectric cooler allows the tester to accurately control the temperature by regulating the voltage to the cooler and the water block keeps a consistent temperature on the hot side of the cooler. The cooler and thermal paste used in testing is shown in figure 14. Figure 14 the thermoelectric cooler and thermal paste To heat the hot side of the thermopile, we have chosen the Thermostone ceramic heater. The main reason for choosing this heater is because it can reach the necessary temperature of 250°C. The heater also has a thickness of 0.04 inches which allows us to easily isolate it from the load. To apply the axial load, we have decided to use a linear actuator. We had considered pneumatic and electric actuators, but due to client preference, we choose the electric linear actuator. The reasons that linear actuators were appealing were because they could be controlled by the software and some have potentiometers built-in them, which will help with interfacing it with the software. 20 The heat flux sensor that we want to use is the hfs-a Micro-Foil Heat Flux Sensor from Rdf Corporation. The reason we want to use this heat flux sensor is because it was the only one that we could find that could withstand a temperature of 250°C. This is a crucial component to determine the overall efficiency of the thermopile and must be able to reach our max temperature. This sensor also has a thickness of 0.003 inches and a response time of 0.05 seconds, which will help keep the design compact and gather data quickly and accurately. These sensors also have thermocouples built into them, allowing the software to record the temperature and not just the heat flux. The heat flux sensors will be placed on the top and bottom of the thermopile, on the faces of the heating block and thermoelectric cooler. We have a tentative solution to use a heater isolation block that is just a hollowed out piece of metal that allows the heater to sit under it, without taking any of the axial load so that it does not break. Not shown in figure 13 are the electrical wires and water tubing from the water block routing out of the vacuum chamber. Since we have not decided on a vacuum chamber yet, we still have not decided how to route these items. The software we have decided to use is LabVIEW. We have chosen this software because of its simplicity and it is user-friendly. Data will be acquired from the test stand, through a data acquisition system, and recorded in LabVIEW. From the software interface, users will be able to monitor the test and change certain aspects of the test. Figure 15 shows the current concept of what the LabVIEW interface will look like. Users will be able to monitor the real time measurements for the electrical, heat transfer, and environmental aspects of the test in the ‘Measurements’ section. The calculations being performed by the software will be displayed in the ‘Calculations’ section. The parameters to be set by the user will be controlled in ‘Test Control Inputs’ section. Figure 16 shows the layout of how the Labview program will acquire input from the test stand and control and measure the experiment. 21 Figure 15 Current concept LabVIEW interface Figure 16 system control map 22 6.0 Future Work As we move forward into the next semester there is a significant amount of work ahead of us. To help maximize the effectiveness of our remaining time we have planned out the rest of our project and established a preliminary time line and schedule for next semester. First after returning from the break between semesters we will have a teleconference with our client to update everyone on the current state and future tasks of the project. In early September we will be finishing the testing of components to become familiar with their functions and verify that they will work for our application. We will make our test writeups available for review. We will want to have finalized the specifications for the data acquisition and control system around the same time we complete initial component testing. We will be using out newly acquired flux sensor to set up PID temperature control in Labview. An image of our flux sensor is shown in figure 17. Figure 17 Thin film heat flux sensor With the flux sensor we will also be able to start gathering some preliminary data on heat flux and efficiency. We have also acquired a thin film thermocouple for testing purposes. We will use this for preliminary measurements and to test the effects of axial load on contact resistance. Our thin film thermocouple is shown in figure 18 23 Figure 18 thin film thermocouple Since the cross section of the thermopiles, the flux sensor, and the thermocouple are all different we will be using polyimide tape to fill in any gaps to maintain a flux as uniform as possible. The two sensors are constructed largely from polyimide, so we can maintain a near constant thermal conductivity. The polyimide tape is shown in figure 19. Figure 19 Polyimide tape 24 The next phase of the project will be developing the detailed design. We will need to create a drawing package, detailed list of hardware, and cost estimate for approval of the final design. Upon approval of the design construction of the prototype would begin in late September. The prototype is to be complete and testing its functionality by mid October. Once the functionality is verified a manual draft for the test bench will be written and submitted for review.. From this point the remaining time will go into writing the final design report and preparing for the final snapshot day. Below is table 7 with our current schedule. Client Meeting Late August Complete initial testing Mid September Complete Detailed Design Mid September Detail design review Mid September Finish Prototype Late October Finish Verification Tests Mid November Submit Manual Draft Mid November Final Snapshot 12/3/10 Final Report 12/15/10 Table 7. Schedule for next semester 25 References [1] CRC Handbook of Thermoelectrics, Edited by D.M. Rowe, 1995 [2] The Science of Thermoelectric Materials, http://www.thermoelectrics.caltech.edu/science_page.htm [3] RdF, Heat Flow Measurement (construction and principal of operation), http://rdfcorp.com/anotes/pa-hfs/pa-hfs_02.shtml [4] Thermo-Stone, Thin Film Heaters, http://www.thermostone.com/index.cfm/products.htm [5] Newegg, Thermaltake CL-W0075 Liquid Cooling System, http://www.newegg.com/Product/ImageGallery.aspx?CurImage=35-106-077-S01&SCList=35-106-077S01,35-106-077-S02,35-106-077-S03,35-106-077-S04,35-106-077-S05,35-106-077-S06,35-106-077-S07,35106-077-S08,35-106-077S09&S7ImageFlag=2&Item=N82E16835106077&Depa=0&WaterMark=1&Description=Thermaltake%20CLW0075%20Liquid%20Cooling%20System [6] Parts Express, Peltier Thermo-Electric Cooling Module 3 Amp, http://www.parts-express.com/pe/showdetl.cfm?partnumber=320-252&source=googleps [7] RS, P1D 2 acting pneumatic cylinder,63x100mm, http://radionics.rsonline.com/web/search/searchBrowseAction.html?method=getProduct&R=4939564#header [8] Supertech Machinery & Electric Co., Linear Actuator-IMD3 (GD23), http://www.ecvv.com/product/1411025.html [9] Northern Tool & Equipment, JET Arbor Press — 1 Ton, Model# AP-1 333610, https://www.northerntool.com/shop/tools/product_200406671_200406671 [10] Great Glass, Pyrex Bell Jars, http://www.greatglas.com/PyrexBellJars.htm [11] Terra Universal, Vacuum Chambers, http://www.terrauniversal.com/environmental_chambers/vacuum_chambers_index.php [12] Surplus Center, Electric Linear Actuators, https://www.surpluscenter.com/item.asp?item=5-15772&catname=electric [13] Rdf, Heat Flux Sensors, http://www.rdfcorp.com/products/hflux/hfs-a_01.shtml 26 Appendix A: Sources for Project Learning Websites: Topic Website Transtutors URL Seebeck Effect Seebeck Coefficient Electronics Cooling http://www.electronicscooling.com/2006/11/the-seebeckcoefficient/ Heat Flux Sensors RdF Temperature Controllers Omega http://www.rdfcorp.com/anotes/ pa-hfs/pa-hfs_01.shtml http://www.omega.com/prodinfo /temperaturecontrollers.html Thermopiles PID Theory Wikipedia National Instruments Peltier Effect Transtutors Thomson Effect Transtutors Thermoelectrics The Science of Thermoelectric Materials Books: CRC Handbook of Thermoelectrics (Edited by D.M. Rowe) http://www.transtutors.com/phy sics-homework-help/currentelectricity/seebeck-effect.aspx http://en.wikipedia.org/wiki/Thermopiles http://zone.ni.com/devzone/cda/tut/p/id/378 2 http://www.transtutors.com/physicshomework-help/current-electricity/peltiereffect.aspx http://www.transtutors.com/physicshomework-help/current-electricity/thomsoneffect.aspx http://www.thermoelectrics.caltech.edu/scie nce_page.htm 27 Appendix B: Axial Load Test Axial Load Test- Peltier Cooler Purpose: The purpose of this experiment is to make sure our pettier cooling units can withstand axial loads up to 300 pounds. The other reason was to see how high of loads they can withstand- which would be important if there were a failure (of a sensor or in software) which may cause a higher than desired load. Experimental Setup: Arbor Press Rack y Arbor Press Arm Force Gauge W_rod W_rack Al Plate Cooler Base W_scale+W_applied An equation for the axial force would be: 𝑟𝑎𝑡𝑖𝑜 𝐹𝑎𝑥𝑖𝑎𝑙 = 𝑊𝑟𝑎𝑐𝑘 + ( 2 ) ∗ 𝑊𝑟𝑜𝑑 + 𝑟𝑎𝑡𝑖𝑜 ∗ (𝑊𝑎𝑝𝑝𝑙𝑖𝑒𝑑 + 𝑊𝑠𝑐𝑎𝑙𝑒 ) Measurements: The weight of the rack was estimated to be 11.7 lbf The weight of the lever arm was measured to be 5.20 lbf The weight of the scale was measured to be 3.46 lbf One revolution of the arm was made for a ∆𝑦 of 6.825”, with a arm length of 22.5” from axis, the ratio between axial force and force applied to the lever arm is 20.7. The aluminum plate used (placed between the cooler and rack) was cut to 1”x1” to represent the largest thermopile the test fixture will use. Plugging values into the previous equation yields: 𝐹_𝑎𝑥𝑖𝑎𝑙 = 137 + 20.7 ∗ 𝑊𝑎𝑝𝑝𝑙𝑖𝑒𝑑 28 Results: Applied Load (lbf) 0.64 3.0 5.44 7.84 20 (max) Axial Load (lbf) 150 200 250 300 551 Compression Stress (psi) 150 200 250 300 551 After these loads were applied, the 1”x1” block was replaced with a 0.7”x0.7” block effectively doubling the amount of stress the cooler could experience- this was done because the force gauge could not read out more than 20 lbf. The data corresponding to the smaller block is as follows: Applied Load (lbf) 0.64 3.0 5.44 7.84 20 (max) Axial Load (lbf) 150 200 250 300 551 Compression Stress (psi) 300 400 500 600 1100 Under these loads (in either case) no damage was obvious upon visual inspection. Conclusion: After the first tests were done the cooler was supplied with power and it was verified that is still functioned correctly. Again, after the smaller block was used, the cooler was again supplied with power and it was verified that is still functioned. It was initially thought that with a 300 pound load the brittle ceramic material might be crushed- though that seems to not be the case. Upon reflection it makes sense that the cooler could resist at least 1100 psi in that the load was completely compressive. Not only does it seem likely the coolers will not have any problem resisting loads the apparatus is likely to operate under, but it could also resist loads in excess of what the linear actuators under consideration could produce. Verification of Method: Initially there was some doubt that the arbor press could produce 65 lbf with only the weight of the rack and rod (horizontal) alone. The spring rate of a coil spring was experimentally determined. The spring had a rate of 28.4 lbf/in. With no load applied (and the scale removed) the arbor press could compress the coil spring from its free length of 2.9” to its solid length of 1”. This corresponded to a force of at least 54 pounds (at which time the spring bottomed out, at which point the lever arm was no longer horizontal which would correspond to a shorter effective lever arm) - so it was determined that our model was at least sufficiently accurate. 29 Appendix C: Water Block Cooling Test Water Block Cooling Test Purpose: The purpose of this experiment is to make sure our water block cooling system would be able to provide enough cooling to the peltier cooler so that low temperatures could be maintained on the cold side of the thermopile. We wanted to see that if ambient temperature water flowing through the water block would be adequate enough or if we would have to circulate water through an ice bath. It also served as a test to see that if this setup would work as our cooling solution for our design. We were also able to regulate the voltage through the peltier cooler and compare our experimental outputs with the data supplied from the manufacturer. Experimental Setup: Water Block Pump 5 gal Bucket 16 oz. Cup Ice Aluminum Block Stainless Steel Block Potentiometer Peltier Cooler 12 V Power Supply Type K Thermocouple (with LabView VI) Thermal paste Water Block Test Setup Thermoelectric Cooler Attached to Water Block Measurements: ● ● ● Water at room temperature was around 20°C Water with ice was around 0°C The voltage output from the potentiometer ranged from 3-10V Experiment: The power supply that we used to power the system (the peltier cooler and water pump) was a 12V computer power supply. To be able to control the voltage to the peltier cooler, we used a potentiometer, which allowed us to control the voltage from 3-10V. Although we could get 10V from the potentiometer, it would start to heat up quickly, so we kept the voltage level around 7V. To compare the effectiveness of the water block, we found two other metals to use as a heat sink. For all the cooling blocks, we used thermal paste between the cooling block and the peltier cooler to help conduct heat better. 30 Results: Cooling Block Temp. (°C) Time to Steady State Temp. (s) Aluminum Stainless Steel Water Block Water Block (Ice Bath) ~ -5 ~2 ~ -7.5 ~ -10 ~ 60 ~ 60 ~ 60 ~ 35 Conclusion: The specifications given to us, by our client, was to have the cold side of the thermopile at 1015°C, which was obtained by all the cooling blocks we tested. Since our final design will be in a vacuum, we will have to rely on conduction for cooling, since there will be no convection heat transfer and all of our cooling blocks in this test did remove heat by conduction. If a single thermopile test will take a couple of hours though, using just conduction into a material will eventually raise the temperature of the material to the hot side of the thermoelectric cooler. This is why the water block was an appealing solution, since the water flowing through the system will remove heat from the block and our data shows that it will still work with room temperature water and give comparable results to the other cooling blocks tested. Plots of Temperature vs. Time Plot of Temperature vs. Time for Stainless Steel Block Plot of Temperature vs. Time for Aluminum Block 31 Plot of Temperature vs. Time for Water Block with Room Temperature Water Plot of Temperature vs. Time for Water Block with Ice Bath Water 32 Appendix D: Thermoelectric Cooler Data Sheet 33 34 35 Appendix E: Heat Flux Sensor Data Sheet 36 Appendix F: Linear Actuator Data Sheet