Review Self-Quiz for Stoichiometry 1. Write the formula for a compound made from sodium and chlorine. Na and Cl → NaCl 2. Write a chemical reaction for the following: Na reacts with chlorine, Cl2, to form sodium chloride. 2 Na + Cl2 → 2 NaCl 3. Find the gram formula weight of Cl2. 2 Cl = 35 x 2 = 70 g/mole 4. Find the gram formula weight of NaCl Na = 23 + Cl = 35 58 g/mole - Basic Skills • Looking up the mass of elements in the periodic table: 6.941 amu or g/mole 1. Li 22.989 768 amu or g/mole 2. Na 3. Ca 40.078 amu or g/mole 63.546 amu or g/mole 4. Cu 55.847 amu or g/mole 5. Fe 14.006 74 amu or g/mole 6. N 15.999 4 amu or g/mole 7. O 35.452 7 amu or g/mole 8. Cl 32.066 amu or g/mole 9. S 10.Br 79.904 amu or g/mole Basic Skills needed • Finding the gram formula mass • separate the elements • look up the atomic mass in the periodic table • figure out how many of each atom are in the formula • subtotal the masses of the elements • Find the total mass of the compound. ex: 2 Al 3 S 12 O Al2(SO4)3 27 32 16 x 2 = 54 x 3 = 96 x 12 = 192 = 342g mole Stoichiometry (Chapter 9 Black Book) • READ and UNDERLINE important parts of the problem. • Write Balanced Formulas •+=- • Write Balanced Equations • use coeficients to make atoms in reactants = same atoms in products • Find moles of “known” • Find moles of “unknown” • Make sure the questions are answered. Your Turn: Find the gfw for the following compounds: 1. 2. 3. 4. 5. 6. 7. Ca (OH)2 NaOH CaCl2 MgF2 K2O Zn3(PO4)2 NaCl answers: Ca(OH)2 = 74 g/mole NaOH = 40 g/mole CaCl2 = 110 g/mole MgF2 = 62 g/mole K2 O = 94 g/mole Zn3(PO4)2= 385 g/mole NaCl = 58 g/mole What mass of NH4Cl __________________________________ can be produced from _______________________________ 7.87 grams of NH3. NH3 + HCl → NH4Cl First, identify knowns and unknowns • Known: 7.87 g NH3 • Unknown: ? g NH4Cl Next, to convert the mass of NH3 to moles you must find the gram formula weight (gfw) of ammonia, NH3 N = 14 3H = 1 =14 x3 =3 -----17 g/mole NH3 What mass of NH4Cl __________________________________ can be produced from _______________________________ 7.87 grams of NH3. NH3 + HCl → NH4Cl • Known: 7.87 g NH3 = ? mole • Unknown: ? g NH4Cl Now that you know that NH3 has a gfw (gram formula weight of 17 g/mole, you convert grams ammonia to moles of ammonia. 7.87 g NH3 -----17 g/mole NH3 = 0.463 moles NH3 What mass of NH4Cl __________________________________ can be produced from _______________________________ 7.87 grams of NH3. NH3 + HCl → NH4Cl • Known: 7.87 g NH3 = 0.463 mole • Unknown: ? g NH4Cl = .463 mole Now that you know that we have 0.463 mole of NH3, we use the balanced chemical equation to determine that for every 1 mole of NH3 we make 1 mole of NH4Cl. 0.463 moles NH3 1 mole NH4Cl ----------------------1 mole NH3 = 0.463 moles NH4Cl What mass of NH4Cl __________________________________ can be produced from _______________________________ 7.87 grams of NH3. NH3 + HCl → NH4Cl • Known: 7.87 g NH3 = 0.463 mole • Unknown: ? g NH4Cl = 0.463 mole Now that you know that we have 0.463 mole of NH4Cl, we find the gfw (gram formula weight) of NH4Cl. 4 N = 14 H= 1 Cl = 35 =14 x4 =4 =35 53 g/mole NH4Cl What mass of NH4Cl __________________________________ can be produced from _______________________________ 7.87 grams of NH3. NH3 + HCl → NH4Cl • Known: 7.87 g NH3 = 0.463 mole • Unknown: ? g NH4Cl = 0.463 mole Now that you know that we have 0.463 mole of NH4Cl, and the gfw (gram formula weight) of NH4Cl is 53g/mole, we can calculate the number of grams ammonium chloride. (0.463 mole NH4Cl) 53 g/mole NH4Cl = 24.5 g NH4Cl Try another: • What mass of Mg(OH)2 will react with 1.20 grams of HCl. •1Mg(OH)2 + 22 HCl -> MgCl2 + 2 H2O 0.97 grams 1.20 g (36 g/mole HCl) x 58g/mole 0.033 moles HCl 0.017 Mg = 24 2O = 32 2H = 2 = 58g/mole Try another: • What mass of Ca(OH)2 will react with 2.40 grams of HCl. •1Ca(OH)2 + 22 HCl -> CaCl2 + 2 H2O 2.5 grams 2.40 g (36 g/mole HCl) x 74 g/mole 0.067 moles HCl 0.033 Ca = 40 2O = 32 2H = 2 = 74g/mole Try another: • What mass of CaCl2 will form when 2.40 grams of HCl react. • Ca(OH)2 + 22 HCl ->1CaCl2 + 2 H2O 2.40 g 3.7 g CaCl2 ? (36 g/mole HCl) Ca 2Cl = 40 = 70 = 110g/mole x 110 g/mole CaCl2 0.067 moles HCl 0.033 moles CaCl2