Section 1: Measuring Matter Chemists use the mole to count atoms, molecules, ions, and formula units. K What I Know W What I Want to Find Out L What I Learned • 8(A) Define and use the concept of a mole. • 8(B) Use the mole concept to calculate the number of atoms, ions, or molecules in a sample of material. • 2(G) Express and manipulate chemical quantities using scientific conventions and mathematical procedures, including dimensional analysis, scientific notation, and significant figures. Copyright © McGraw-Hill Education Measuring Matter Essential Questions • How is a mole used to indirectly count the number of particles of matter? • What is a common everyday counting unit to which the mole can be related? • How can moles be converted to number of representative particles and vice versa? Copyright © McGraw-Hill Education Measuring Matter Vocabulary Review New • Molecule: forms when two or • Mole: the SI Unit used to more atoms covalently bond and measure the amount of a is lower in potential energy than substance its constituent atoms • Ex. The number of carbon • Atomic mass: the weighted atoms in exactly 12 g of pure average mass of the isotopes of carbon that element • Amount 6.02 x 1023 • Avogadro’s number: 6.02 X 1023 • Atomic mass Unit (amu): one twelfth the mass of a carbon-12 atom Copyright © McGraw-Hill Education Measuring Matter Practice Review • Write the following in scientific notation – 0.00582 – 24,367 – 400 • Circle the significant figures in the number below – 75,600,000 – 0.00033 – 3.140 Counting Particles Chemists need a convenient method for accurately counting the number of atoms, molecules, or formula units of a substance. The mole is the SI base unit used to measure the amount of a substance. 1 mole is the amount of atoms in 12 g of pure carbon-12, or 6.02 ×1023 representative particles, which is any kind of particle – an atom, a molecule, a formula unit, an electron, an ion, etc. The number is called Avogadro’s number. Mole- SI based unit used to measure the quantity of matter Copyright © McGraw-Hill Education Measuring Matter Avogadro's Number List common counting units and their values • • • • Dozen – PairGrossReam - Why the need for a new counting number • A convenient method for accurately counting atoms, molecules, or formula units in a sample of a substance. • Atoms are so small and there are so many of them that it is impossible to count them directly. What can be measured using a mole • atom Molecule • Formula unit Converting Between Moles and Particles Conversion factors must be used. Moles to particles: • Number of molecules in 3.50 mol of sucrose: Copyright © McGraw-Hill Education Measuring Matter Converting Between Moles and Particles Particles to moles Use the inverse of Avogadro’s number as the conversion factor. Copyright © McGraw-Hill Education Measuring Matter PARTICLES-TO-MOLES CONVERSION KNOWN Use with Example Problem 1. Problem Zinc (Zn) is used as a corrosion-resistant coating on iron and steel. It is also an essential trace element in your diet. Calculate the number of moles of zinc that contain 4.50 × 1024 atoms. Number of atoms = 4.50 × 1024 atoms Zn 1 mol Zn = 6.02 × 1023 atoms Zn UNKNOWN Moles Zn = ? mol SOLVE FOR THE UNKNOWN Response ANALYZE THE PROBLEM You are given the number of atoms of zinc and must find the equivalent number of moles. If you compare 4.50 × 1024 atoms Zn with 6.02 × 1023, the number of atoms in 1 mol, you can predict that the answer should be less than 10 mol. Copyright © McGraw-Hill Education Use a conversion factor—the inverse of Avogadro’s number—that relates moles to atoms. • Apply the conversion factor. 1 mol number of atoms = 6.02 × 1023 atoms = number of moles Measuring Matter PARTICLES-TO-MOLES CONVERSION SOLVE FOR THE UNKNOWN EVALUATE THE ANSWER • Both the number of Zn atoms and Avogadro’s number have three significant figures. Therefore, the answer is expressed correctly with three digits. The answer is less than 10 mol, as predicted, and has the correct unit, moles. Substitute the number of Zn atoms = 4.50 × 1024. Multiply and divide numbers and units. 1 mol Zn 4.50 × 1024 atoms Zn = 6.02 × 1023 atoms Zn = 7.48 mol Zn Copyright © McGraw-Hill Education Measuring Matter Conversion Practice • Calculate the number of molecules in 11.5 mol of water. Conversion Practice • Silver Nitrate is used to make several different silver halides used in photographic films. How many formula units of silver nitrate are there in 3.25 mol of silver nitrate? Review Essential Questions • How is a mole used to indirectly count the number of particles of matter? • What is a common everyday counting unit to which the mole can be related? • How can moles be converted to number of representative particles and vice versa? Vocabulary • mole • Avogadro’s number Copyright © McGraw-Hill Education Measuring Matter