2C Copy the title Task C1 Equations P7 Match the word symbol and balanced equations For each reaction identify the reactants and products Explain what s l g mean Identify the number and types of atoms in balanced chemical equations Word equation: Magnesium + oxygen magnesium oxide Word equation: Hydrogen + nitrogen ammonia Word equation: Sodium + chlorine sodium chloride Word equation: Carbon + oxygen carbon dioxide Symbol equation: Mg(s) + O2(g) MgO (s) Balanced equation: 2Mg(s) + O2(g) 2MgO (s) Symbol equation: H2(g) + N2 (g) NH3(s) Balanced equation: 2H2 (g) + 3N2 (g) 2NH3 (g) Symbol equation: Na (s) + Cl2 (g) NaCl (s) Balanced equation: 2Na (s) + Cl2 (g) 2NaCl (s) Symbol equation: C (s) + O2 (g) CO2 Word equation: Magnesium + oxygen magnesium oxide Word equation: Hydrogen + nitrogen ammonia Word equation: Magnesium + oxygen magnesium oxide Word equation: Hydrogen + nitrogen ammonia Word equation: Sodium + chlorine sodium chloride Word equation: Carbon + oxygen carbon dioxide Word equation: Sodium + chlorine sodium chloride Word equation: Carbon + oxygen carbon dioxide Symbol equation: Mg(s) + O2(g) MgO (s) Balanced equation: 2Mg(s) + O2(g) 2MgO (s) Symbol equation: Mg(s) + O2(g) MgO (s) Balanced equation: 2Mg(s) + O2(g) 2MgO (s) Symbol equation: H2(g) + N2 (g) NH3(s) Balanced equation: 2H2 (g) + 3N2 (g) 2NH3 (g) Symbol equation: H2(g) + N2 (g) NH3(s) Balanced equation: 2H2 (g) + 3N2 (g) 2NH3 (g) Symbol equation: Na (s) + Cl2 (g) NaCl (s) Balanced equation: 2Na (s) + Cl2 (g) 2NaCl (s) Symbol equation: Na (s) + Cl2 (g) NaCl (s) Balanced equation: 2Na (s) + Cl2 (g) 2NaCl (s) Symbol equation: C (s) + O2 (g) CO2 Symbol equation: C (s) + O2 (g) CO2 In a chemical reaction, reactants usually react to form products reactants products In a reversible reaction, the products of the reactant can react to produce the original reactants reactants products The symbol below represents a reversible reaction reactants products Heating copper sulphate - What happened? • Hydrated copper sulphate is blue. • When it is heated it turns into anhydrous copper sulphate (white) • When this is left to cool it turns back into hydrated copper sulphate. • The reverse reaction is used as a test for water. When water is added to anhydrous copper sulphate 2 things happen: 1.) White solid turns blue 2.) Reaction gives out heat. (Takes in) Heat Endothermic Hydrated Copper Sulphate (Blue Solid) (Cool + Steam) Exothermic Anhydrous Copper Sulphate (White Solid) P7 Explain what irreversible and reversible reactions are 1. What is a reversible reaction? 2. Draw the symbol that represents reversible reactions: 3. What happens to blue hydrated copper sulphate when it is heated? 4. What happens to anhydrous copper sulphate when it is left to cool and a little water is added? 5. What type of reaction is this? Types of reactionsreversible or irreversible Types of reactions- neutralisation P7 Explain what a neutralisation reaction is Give an example Write the word and symbol equation • • • • • Draw a diagram and explain what a neutralisation reaction is Explain if it is reversible or irreversible Write down the word equation Copy the symbol equation below and explain everything that it tells us H2SO4 (aq) + 2NaOH (aq) Na2SO4 (aq) + 2H20 (l) P7 Explain what the reactivity series is Types of reactions- displacement • Draw the diagram above • Explain which is the most reactive and which is the least reactive P7 Explain what displacement is using your knowledge of the reactivity series • • • • Types of reactions- displacement Draw a before and after diagram Explain what happens in this displacement reaction Explain if it is reversible or irreversible Copy down the word and symbol equation below – Fe(s) + CuSO4(aq) --> FeSO4(aq) + Cu(s) P7 Explain what displacement is using your knowledge of the reactivity series Types of reactions- displacement • Draw a before and after diagram • Explain what happens in this displacement reaction • Explain if it is reversible or irreversible Displacement experiment Magnesium Magnesium Sulphate Iron Sulphate Zinc Sulphate Copper Sulphate Iron Zinc Copper Copy the title Task C2 Equations C.2 Reaction rates: a. Effect of catalysts (lowering the energy needed for a reaction to occur), surface area, concentration and temperature on rate of reaction b. Use of reaction rate graphs c. Collision theory Factors affecting the rate of a reaction P6 Using the following slides fill in the summary sheet The collision theory Explanation of what the collision theory is Factor How it affects the rate of reaction Temperature High temperature diagram Low temperature diagram Concentration High concentration diagram Low concentration diagram Pressure High pressure diagram Low pressure diagram Surface area Small surface area: Volume Large surface area: Volume Catalyst Diagram of activation energy with and without a catalyst The collision theory Explanation of what the collision theory is Factor How it affects the rate of reaction Temperature High temperature diagram Low temperature diagram Concentration High concentration diagram Low concentration diagram Pressure High pressure diagram Low pressure diagram Surface area Small surface area: Volume Large surface area: Volume Catalyst Diagram of activation energy with and without a catalyst Temperature Changing temperature Low temp • • • • Less energy Particles move slowly Less collisions Slow rate of reaction high temp • More energy • Particles move faster • More frequent successful collisions • faster rate of reaction Changing temperature Graphs Increasing the temperature increases the speed of the reacting particles so that they collide more frequently and more energetically. This increases the rate of reaction Changing temperature Summary Concentration Magnesium and hydrochloric acid Changing concentration Increasing the concentration of reactants in solutions increases the frequency of collisions and so increases the rate of reaction. Low conc • Less frequent collisions • Slower rate of reaction High conc • More frequent successful collisions • Faster rate of reaction Changing concentration Pressure Effect of pressure on rate of reaction As the pressure increases, the space in which the gas particles are moving becomes smaller. The gas particles become closer together, increasing the frequency of collisions. This means that the particles are more likely to react. lower pressure higher pressure Surface area Changing surface area Increasing the surface area of solid reactants increases the frequency of collisions and so increases the rate of reaction. Changing surface area Catalysts What are catalysts? Catalysts are substances that change the rate of a reaction without being used up in the reaction. energy (kJ) Catalysts never produce more product – they just produce the same amount more quickly. Ea without catalyst Different catalysts work in different ways, but most lower the reaction’s activation energy (Ea). Ea with catalyst reaction (time) P6 Copy the graph and explain what it shows A rate of reaction graph P6 Explain why the rat graph curves A rate of reaction graph Copy the title Task C3 Industrial processes M5 Answer the questions in full sentences Rates and industryMargarine Margarine is made in food factories from vegetable oils. Hydrogen gas is bubbled through the liquid oil. When the hydrogen reacts with the liquid vegetable oil it hardens to form a solid fat. This process is hydrogenation. At room temperature there is no reaction and hydrogenation doesn’t happen. But the rate of reaction can be increased by using: • A nickel catalyst (lowers activation energy and speeds up the reaction) • A temperature of 175-190C (which increased the number of successful collisions) • A high pressure (which increases the number of successful collisions) The higher the temperature, pressure and catalyst increase the rate of reaction 1. 2. 3. 4. What raw product is used to make margarine? What happens when hydrogen is bubbled through he liquid oil? What 3 factors can increase the rate of reaction? Explain how each of these factors increases the rate of reaction M5 Answer the questions in full sentences Rates and industryMaking smells The chemical Methanol CH3OH is used to make a compound that smells like apple and pineapple. The way that Methanol is made is below Carbon monoxide + Hydrogen methanol CO (g) + 2H2 (g) CH3OH (l) The rate of reaction can be increased by • Increasing the temperature to 250 C (this increases the chance of successful collisions) • A pressure of 50-100 atmospheres (this forces the reactants to collide more often as they are pushed closer together) • Using a catalyst made from copper zinc oxide and aluminium oxide (this lowers the activation energy and increases the rate of reaction) 1. Why is methanol useful? 2. Write down the word and symbol equations. And explain which one are reactants and products 3. What happens when hydrogen is bubbled through he liquid oil? 4. What 3 factors can increase the rate of reaction? 5. Explain how each of these factors increases the rate of reaction M5 Answer the questions in full sentences Rates and industry- The HABER PROCESS for producing AMMONIA The production of ammonia is a very important process as it is used to make fertilizers to grow more food crops. The Haber Process H is a reversible N reaction where Ammonia is made from: H H both reactants and N N • nitrogen, which is removed from the air the product are • hydrogen, made from methane (natural gas) H H GASES. •To give the best yeild of ammonia a temperature of 450°C and a pressure of 200 atmospheres is used. 1. 2. 3. 4. What is the formula for ammonia? Why is ammonia important? What are the 2 reactants for making ammonia? What are the 2 conditions to make the most amount of ammonia? HYDROGEN & NITROGEN IN hydrogen + nitrogen ammonia HYDROGEN NITROGEN AMMONIA TEMPERATURE and PRESSURE of the reaction vessel can be controlled UNUSED HYDROGEN & NITROGEN RECYCLED % YIELD = % AMMONIA in main reaction vessel M5 Copy the diagram LIQUID AMMONIA REMOVED Mixture cooled here. AMMONIA condenses M6 Copy the 2 key words down Key definitions Yield – • The amount of product made in the reaction Atom economy – • A way of measuring the amount of atoms in the reactants that become useful products