GEOS 470R/570R Volcanology L28, 4 May 2015 Handing out PowerPoint slides for today Lecture final Wednesday, 13 May 2015, 10:30-12:30pm, G-S 203 Early offering: Monday, 11 May 2015, 1:00-3:00pm, G-S 321 Time of lecture review session? Friday afternoon? “The reward of a thing well done, is to have done it.” --Ralph Waldo Emerson Readings from textbook For L28 from Lockwood and Hazlett (2010) Volcanoes—Global Perspectives Chapters 15 and 13 Last time: Extraterrestrial volcanism, II. Venus Mars Io Cryovolcanism Comparative planetology revisited Press and Siever, 2001, Fig. 1.10 Venus Size and density similar to Earth Diameter only 330 km less than Earth Covered with dense atmosphere rich in carbon dioxide Capped with clouds with sulfuric acid droplets Clouds circulate planet once every four days High winds aloft, but mostly calm at surface Explored by Pioneer Venus radar Earth-based radar Soviet Venera 15-16 orbital imaging radar Soviet Venera and Vegas landers Magellan radar, altimetry, and gravity (1990-1994) Lunar and Planetary Institute, 1997, Venus Slide Set, #2 Volcanologic implications of atmospheric pressure and heat High atmospheric surface pressure Everything else being equal, will inhibit vesiculation of magma, leading to less explosive eruption (some ash suspected; no ashflow tuffs documented) Makes wind velocities very low (few dunes observed on Venus) High ambient surface temperature Slow the rate of solidification of lavas Prevent water from existing on or below surface Everything else being equal, would diminish potential to form maars, tuff rings, etc. Potentially could increase long term rates of geological strain in areas of high, mountainous relief Types of magmatic features on Venus Volcanoes Large volcanoes Intermediate volcanoes Small volcanoes and fields of small shield volcanoes (colles) Calderas (often, patera, irregular depressions) Lava flows and channels Plains lavas Lava flow fields (fluctii) Unusual lava flows Lava channels (canali) Magmatic structures Coronae Arachnoids Radial (stellate) fracture centers Large volcanoes Chloris Mons Shield volcano 300 km in diameter Numerous light and dark lava flows and radiating fractures Distal ends of flows are radar bright Relatively rough and blockier? Several small volcanoes with steepsided dome morphology near the summit Crumpler and Aubele, 2000, Fig. 2 Intermediate volcanoes Diameter 20 - 100 km Morphologic types Radially patterned domes Steep-sided domes Pancake domes (farra) Scalloped domes Modified or fluted domes Tholi Volcano of intermediate size A simple intermediate volcano 20 km in diameter Radial bright and dark lava flows Summit caldera Crumpler and Aubele, 2000, Fig. 3 Steep-sided dome Steep-sided dome Convex profile ~40 km in diameter Located on set of annular fractures defining the margins of a corona Crumpler and Aubele, 2000, Fig. 4 Pancake domes (farra) Steep sided domes that are Broad and flat Very circular Steep along their perimeter Apparent emplacement in a single episode of volcanism Seem to require highly viscous, perhaps silicic magma Located just southeast of Alpha Regio at 30°S, 12°E Fluted dome Fluted dome on right Convex profile ~25 km in diameter Deep central crater with inverted conical profile Pancake-like steepsided dome at left ~35 km in diameter Crumpler and Aubele, 2000, Fig. 5 Tholi Intermediate volcano in which the flanks appear steep relative to most volcanoes on Venus Mahuea Tholus Located at 37.3°S, 165.1°E The bright, ridged flows stand about 600 m above the surrounding plains Inner tier sits >1000 m high Thickness suggests that they were unusually viscous at time of emplacement Lunar and Planetary Institute, 1997, Venus Slide Set, #25 Small volcanic field “Shield field” Centered at 78.4°S, 43.0°E Located in the volcanic plains Lunar and Planetary Institute, 1997, Venus Slide Set, #26 Caldera Circular caldera with ring fractures Radar altimetry profile Demonstrating depth of caldera of 1 km Crumpler and Aubele, 2000, Fig. 7A, B Types of magmatic structures Coronae Almost unique to Venus But also observed on Miranda, a moon of Uranus Arachnoids Radial (stellate) fracture centers Coronae Dominantly circular to elliptical structures May be associated with mantle plumes or hot spots Characteristics Annulus of concentric ridges or fractures Interior that may be high or low Peripheral moat or trough Large and small volcanoes frequently present within the corona or on its margins But exhibit a variety of topographic forms Interpreted origin Rising plumes push the crust upward into a dome Dome collapses in center Molten lava leaks out around sides Crumpler and Aubele, 2000, Fig. 10 Arachnoids Similar to coronae, but with strongly developed radial patterns Annular structural patterns consisting of Concentric or circular pattern of fractures or ridges, With Radial arrays of fractures or ridges extending outward for several radii Interior flows and small shield volcanoes Radial fractures frequently merge outward with the linear patterns of the fracture belts on which arachnoids are arranged Hence the name: spiders along webs of linear fracture belts Arachnoids Crumpler and Aubele, 2000, Fig. 12A, B Mars Explored by Flybys of Mariner 4 (1965), Mariners 6 and 7 (1969), and Mariner 9 (1971) Viking 1 and 2 orbiters and landers (1976) Mars Pathfinder and Sojourner Rover (19971998) Mars Global Surveyor (1999-present) Mars Odyssey (2002present) Mars Express (2003present) Mars Exploration Rovers Spirit and Opportunity (2004) Phoenix Lander (2008) Curiosity Rover (2012) Press and Siever, 2001, Fig. 1.10 Volcanic features on Mars Mons Large isolated mountain Tholus (pl. tholi) Isolated domical small mountain or hill, with slopes much steeper than that of a patera Patera (pl. paterae) Irregular or complex crater with scalloped edges, surrounded by shallow flank slopes Olympus Mons A shield volcano on Mars the size of Arizona Diameter ~600 km Relief: 21 km above datum (akin to sea level) Tholi Isolated, domical mountains or hills Slopes much steeper than that of most paterae Smaller than 200 km in diameter Ceraunius Tholus Lava dome Elongate crater at top created by oblique impact at northern base Dimensions 150 X 100 km Lava channel flowed into crater Zimbelman, 2000, Fig. 3 Paterae Irregular or complex craters Scalloped edges Surrounded by shallow flank slopes Possibly have an important pyroclastic component Flows or falls? Suggestive of increased volatile content of magmas? Paterae Tyrrhena Patera (FOV ~ 120 km) Highland Paterae Irregular or complex crater with scalloped edges that are surrounded by shallow flank slopes Intensely eroded appearance Removal of friable material? Zimbelman, 2000, Fig. 4 Volcanic fields (white) Volcanic plains Lava flow margins (FOV ~ 54 km) Zimbelman, 2000, Fig. 1 Zimbelman, 2000, Fig. 6 Volcanoes and ice on Mars HiRISE image of possible rootless cones east of Elysium region. Chains of rings interpreted to be caused by steam explosions when lava moved over ground that was rich in water ice. Large amounts of water ice Believed to be present in Martian subsurface Interaction of ice with molten rock Produces distinct landforms Features identified recently include "Rootless Cones" on Mars – due to lava flows interacting with water (MRO, January 4, 2013) Rootless cones created by phreatic explosions (e.g., Hamilton et al., 2010) Lahars or debris flows Images from Wikipedia Site, Volcanology of Mars Io Galilean satellites (four largest satellites of Jupiter) Io Europa Ganymede Callisto Io Innermost satellite of Jupiter Intense magmatism on Io Driven not by internal heat But by gravitational attractions of Jupiter and Europa Io Most volcanically active object in the solar system Heat flow much higher than Earth’s Several volcanoes erupt lavas that are hotter than any erupted on the Earth today Lopes-Gautier, 2000, Fig. 1 Surface features Mountains Smooth plains Volcanic constructs Absence of large volcanic edifices Shield volcanoes are low Magmas of low viscosity? Calderas Steep walls and flat floors 20 – 200 km in diameter As deep as 2 km Lockwood and Hazlett, 2010, Fig. 12.21 Scalloped (possibly sapped) volcanic tableland and compound caldera of Tvashtar patera on Io; ongoing effusive eruption on left) Eruptive products Red materials Ephemeral (lasting a few years?) Pyroclastic deposits—fall deposits from plumes? Associated with hot spots and plumes Very dark deposits Also associated with hot spots Different colors may reflect different allotropes (crystal structures) of sulfur Cooled rapidly from different temperatures Cryovolcanism Definition Eruption of liquid or vapor phases (with or without entrained solids) of water or other volatiles that would be frozen solid at the normal temperature of an icy satellite’s surface Known to occur Geyser-like plumes of nitrogen were discovered on Triton, a moon of Neptune, by Voyager 2 Indirect evidence that it has taken place elsewhere Might be active today South pole of Triton, Neptune’s only planet-sized moon Bright polar cap Made up of relatively mobile N2 ice, subliming in the summer sunshine Dark streaks are active or recent plumes Geissler, 2000, Fig. 3 Cryovolcanic flows on Triton Evidence of extensive melting Perhaps when moon was gravitationally captured into orbit about Neptune Two large calderalike lake features near the equator Rimless pits to the right of the impact crater may be the source of the smooth materials Geissler, 2000, Fig. 5 Summary: Extraterrestrial volcanism, II. Venus Volcanoes: Large volcanoes, intermediate volcanoes (various domes), small volcanoes and fields of small shield volcanoes, calderas, lava flows and channels Magmatic structures characterized by surface deformation associated with large-scale subsurface magmatism: Coronae, arachnoids, radial fracture centers Mars Volcanically inactive planet with huge volcanoes Io Vigorous volcanism driven by tidal forces; sulfur is an important product Cryovolcanism May be common on outer planets and their satellites Comparative planetology, revisited Many features are similar on various planetary bodies Lecture 28: Societal applications Volcanic contributions to climate change Review of atmospheric structure and processes Eruptions and atmospheric anomalies Volcanism and extinctions Volcanic contributions to S and C fluxes Volcanic materials for consumers Volcanic contributions to soils Geothermal systems and resources Petroleum maturation and reservoirs Definitions Colloid Any finely divided substance (finer than clay size) that does not occur in crystalline form Any fine-grained material in suspension Sol Homogeneous suspension or dispersion of colloidal matter in a fluid (liquid or gas) A sol is more fluid than a gel Aerosol A sol in which the dispersion medium is a gas (usually air) and the dispersed or colloidal phase consists of solid or liquid droplets e.g., mist, haze, most smoke, and some fog Homospheric portion of the atmosphere Mesosphere T decreases with altitude to a minimum at the top (the mesopause) Stratosphere Temperature increases with altitude to a maximum at the top (the stratopause, ~50 km altitude) Warm air is less dense than cold air, so is more stable than troposphere because air enters stratosphere from convective storms in tropics; particles not rained out Air leaves stratosphere only by infolding into troposphere at midlatitudes (3/4; residence time two years) and by descending toward surface at poles during winter (1/4) Troposphere Region closest to Earth; “dirty” Temperature decreases with altitude to a minimum at the top (the tropopause, ~18 km altitude at equator, ~8 km at poles) Absoption of solar radiation causes instabilityweather Precipitation causes rainout of particles within weeks Mills, 2000, p. 933-934 Residence times in stratosphere Fine ash Resides in stratosphere for <3 months because of its relatively large size Sulfuric acid aerosol Resides in stratosphere for several years Consequences of atmospheric structure Volcanic eruptions have little chance to impact global atmosphere unless volcanic plumes penetrate the tropopause Only explosive eruptions will affect the stratosphere Ash not of major concern regarding climate Short residence time Sulfuric acid aerosols are important if injected into stratosphere Explosive, SO2-rich eruptions will have the greatest impact on climate Mafic eruptions (especially if explosive, but are uncommonly explosive) and eruptions of oxidized intermediate magmas Eruptions in the tropics have the best chance to have a global impact Better chance for eruptive products to reach both the northern and southern hemispheres (because their air masses do little mixing) Famous global impacts of Tambora (1815), Krakatau (1883), Pinatubo (1991 were all equatorial, highly explosive eruptions More definitions Climate Average weather conditions (temperature, meteorological conditions) of a place over a period of years Weather Daily changes or weekly and monthly patterns “Climate is what you expect; weather is what you get” Climate and global change Dust and especially gases (CO2, SO2, H2S) from large eruptions have short-term impacts on climate Numerous atmospheric anomalies correlate with historic volcanic eruptions, commonly in a different part of the world Typically hemispheric spatial extents Typically 1- to 2-year temporal effects Ancient eruptions and atmospheric anomalies Santorini (Thera), Aegean Sea ~ 1620 BC Atmospheric effects felt globally China: Floods, followed by 7 years of drought Etna, Sicily ~42 BC Correlates with anomalies in Rome, China, Greenland Kuwae, Vanuatu, S. Pacific, ~1453 AD Eclipse, hailstorm, dense fog in Constantinople (Istanbul) Frost and snow in China same year 9 years of crop damage in Sweden and Germany beginning in 1453 Tree ring evidence for frost damage globally for several years More recent eruptions and atmospheric anomalies Laki fissure, Iceland Laki fissure eruption, Iceland, 1783 Largest historic series of lava flows (~15 km3) Europe’s “dry fog” may have caused cold winter in 1783-1784 and cold summer of 1784 Tambora, Sumbawa, Indonesia, Apr 1815 Largest eruption in last 10,000 yrs (~100 km3) 1816: “Year without a summer” because of lower temperatures in New England and Europe France: Famines and riots at end of Napoleonic wars Ireland and British Isles: Famine and typhus epidemic India: Crop failures, famine, cholera P. Kresan Krakatau, 1883 Several years of brilliant sunsets Brilliant sunsets Major explosive eruptions Produce smog-like silvery midday skies and colorful sunsets Krakatau eruption (1883) impressed European observers Inspired a number of paintings Perhaps Edvard Munch’s The Scream (1893) Lockwood and Hazlett, 2010, Fig. 13.3 Lockwood and Hazlett, 2010, Fig. 13.4 Volcanic eruptions and short-term changes in climate Eruption of Tambora, Indonesia, in 1815 shortened growing season in New England Annual and 5-year running average ME NH Sigurdsson, 2000, Fig. 5 MA Extraordinarily large eruptions Toba, Indonesia Eruption at 74,000 yr BP Largest eruption of last several hundred thousand years (~280,000 km3) Ice core studies indicate that Toba aerosols remained in stratosphere for ~6 yr Fisher et al., 1997, Fig. 9-2; adapted from AGU Report, “Volcanism and Climate Change” Fate and impact of volcanic SO2 Within one month SO2 is converted to H2SO4 Combines with water vapor to form stratospheric sulfate aerosol Volcanic aerosol May cool the Earth’s surface by reflecting solar energy back to space May warm the stratosphere by absorbing infrared radiation escaping the from the surface and troposphere Chemical reactions between gaseous and aerosol components activate anthropogenic halogens Amplifies ozone depletion at midlatitudes and poles Aerosol eventually is taken up by clouds in troposphere May again increase planetary albedo by decreasing average size of droplets in cirrus clouds, modifying their optical properties Mills, 2000, p. 935-936 Eruptive plume that penetrates the stratosphere and forms aerosols Mills, 2000, Fig. 1 SAGE II Stratospheric aerosol and gas experiment (SAGE) Satellite-borne instrument that monitors distribution of stratospheric aerosol Observations of effects of Pinatubo eruption of June 1991 Eruption of Pinatubo, June 1991 Aerosol initially confined to tropics Increased the 1-μm optical depth by two orders of magnitude Over 6 months spread to higher latitudes Global increase in 1μm optical depth by one order of magnitude Stratospheric aerosol layer continued to be dominated by steadily decreasing volcanic aerosol for 3 yr Self et al., 1996, Fig. 6; from McCormick et al., 1995 Effects of El Chichón 1982 and Pinatubo 1991 Self et al., 1996, Fig. 9 Variability in sulfur loading Mills, 2000, Table 1 Temperature decreases correlate with sulfur yield of eruptions Fisher et al., 1997, Fig. 9-1; adapted from Sigurdsson, 1990 Laki fissure eruptions, Iceland, 1783-4 Rampino and Self, 2000, Fig. 3 Flood basalt provinces of last 250 Ma Rampino and Self, 2000, Table I Flood basalts and faunal events Rampino and Self, 2000, Table II Volcanism and extinctions Unclear relationship between volcanism and extinctions Best temporal correlation is with eruption of flood basalts Does a large extinction require Combination of bolide impact + eruption? Does bolide impact somehow trigger eruption of flood basalts? Can short-term climate-changes associated with volcanic event somehow trigger longer term climate change Which may be required to cause massive extinctions? Outgassing of the Earth Midocean ridge volcanism Intraplate volcanism Convergent margin (arc) volcanism Subduction zone and collision zone metamorphism Volatile loss during burial diagenesis of sediments Volcanic contributions to global C and S fluxes Volcanic outgassing represents ~50% of the total flux of CO2 to the atmosphere Proportions of CO2 flux assigned to various tectonic settings of volcanism remain uncertain Volcanic volatile sulfur flux from subaerial volcanism amounts to 20 – 30% of preanthropogenic riverine sulfur flux Impact of submarine volcanism is difficult to assess because of uncertainties assigned to hydrothermal sinks and sources Volcanoes for consumers Metals from mineral deposits formed in volcanic settings Ski mountains Construction materials Volcanic soils Geothermal baths Geothermal energy Petroleum maturation and reservoir rocks Properties of volcanic materials Dehn and McNutt, 2000, Table 1 Building stone Ignimbrite column in Guadalajara, México Ignimbrite Welded tuff Sillar Lightweight Relatively high strength Fisher et al., 1997, Fig. 11-6; photo by G. Heiken Building stone Blocks from ignimbrite quarry near Naples, Italy Church in central Naples, constructed in 13th century out of cut blocks of Campanian Ignimbrite and yellow tuff Fisher et al., 1997, Fig. 11-8A, B; photos by R. V. Fisher Cinders Road construction and surfacing “Sand” for traction on ice Ornamental stones and pathways Cinder cone at Little Lake, CA Fisher et al., 1997, Ch. 11 Frontispiece; photo by R. V. Fisher Volcanic ash in soil Volcanic ash is made predominantly of volcanic glass Glass is easily weathered Producing clay minerals Releasing elements not accommodated in clay minerals Clay minerals can provide base for roots, help soil hold water, and exchange nutrients Some elements released are nutrients for plant growth (K, Ca, Na, trace elements) Ash Ashfall from Parícutin, México Where thin, it enriched soils if tilled in with a plow Where thick, nothing would grow; farms were abandoned Fisher et al., 1997, Fig. 13-3 Soils and more Volcanoes contribute to fine coffees of Guatemala in several ways Coffee finca (plantation) near Volcán Tecuamburro, southern Guatemala Volcanic soils Effect of elevation (2,000-3,000 m) on temperature and rainfall Fisher et al., 1997, Fig. 13-5; photo by G. Heiken Geothermal benefits Blue Lagoon, Iceland: Bathers in foreground; geothermal power plant in background Fisher et al., 1997, Frontispiece for Ch. 12; photo by G. E. Sigvaldason Volcanic lakes Delmelle and Bernard, 2000, Fig. 3 Fumaroles Fumaroles, boiling acid-sulfate springs, and acid sublimates produced bleached “wasteland” Bumpass Hell, Lassen Volcanic National Park, CA Goff and Janik, 2000, Fig. 6A Surface manifestations of geothermal systems Silica sinter mound around boiling spring Sumurup, Lempur, central Sumatra, Indonesia Hochstein and Browne, 2000, Title Banner Geothermal fluids Valles caldera, Jemez Mountains, New Mexico Well VC-2A, Sulphur Springs,, May 1987 Active geothermal system with small reservoir Wall rocks altered to native sulfur and kaolinite Well producing fluids from a single fracture in the Bandelier Tuff Uneconomic for electricity when explored from 19621984 Goff, 2010, Fig. 4 Geothermal fluids Neutral-chloride water erupts during flow test of well VC-2B, Sulphur Springs, Valles caldera, Jemez Mountains, New Mexico Mean T of fluid production during test 250°C Bottom hole T 295°C Scale: Well head 2.2 m tall Reservoir conditions (adjusted for steam loss) pH = 6.2 Cl- content = 3000 ppm Goff and Janik, 2000, Fig. 6B Volcanic-hydrothermal system Conceptual model of a “volcanic-hydrothermal system” with characteristic surface manifestations Based on Suretimeat system, Vanuatu Isotherms: T1 = ~150°C; T2 = ~350°C Hochstein and Browne, Fig. 2 Liquid-dominated, high-temp. system Conceptual model of a liquid-dominated, high-temperature system beneath a partially eroded, high-standing volcanic complex Exhibiting lateral zonation (downstream) of surface manifestations Large amount of heat discharged by concealed outflows that are partially sealed by mineral deposition Based in part on Palinpinon system, Philippines Hochstein and Browne, Fig. 3 High-temp., steaming ground system Conceptual model of a high-temperature, steaming ground system beneath a broad volcanic center Natural two-phase (L + V) reservoir Showing restricted variety of surface manifestations in a semi-arid environment Based in part on Olkaria, Kenya, and others in East African rift valley Hochstein and Browne, Fig. 4 Vapor-dominated system Conceptual model of a vapor-dominated system beneath a broad, high-standing volcanic system Reservoir has a condensate layer on top Heat transferred within the reservoir is discharged at the surface by steam and hot condensates (bicarbonate waters) Model similar to Kamojang system, Java, Indonesia Hochstein and Browne, Fig. 5 The Geysers, CA A vapor-dominated geothermal system P. Kresan Liquid-dominated, high-temp. system Conceptual model of a liquid-dominated system in rather flat terrain Heat source is an extensive layer of hot crustal rocks that contains some partial melts and intrusions Similar to Wairakei system, New Zealand Hochstein and Browne, Fig. 6 Geothermal resources Fisher et al., 1997, Fig. 12-2 How much geothermal energy is available? Global arc volcanism produces 2 km3 magma per year U.S. electrical power consumption is roughly 500 watts (joules / second) per person How do these compare? Cooling 1 gram of magma 1˚C releases about 1 joule of heat What is a typical magma T in round numbers? 1000˚ to 0˚C releases 1000 joules / gram Mass magma per year: 2.5 x 109 (t/km3) x 2 x 106 (g/t) Thus, 5 x 1015 grams or 5 x 1018 joules per year joules per sec (= watts) is 5 x 1018 / 3 x 107 = 2 x 1011 W from global arc volcanism US consumption is 500 x 300 x 106 = 1.5 x 1011 W Shocking, isn’t it? M. D. Barton Reservoir defined by distribution of wet vs. dry volcanic products Hydrothermal reservoir geometry (dotted line) defined by geological mapping of young volcanic products Dry volcanic products (pumiceous) Wet volcanic products (phreatomagmatic) Wohletz and Heiken, 1992, Fig. 2-42 Economic significance Hypothetical water : magma ratio (Rm) as a function of near-vent median grain sizes of tephra Finer grain sizes from phreatomagmatic eruptions Why are the phreatomagmatic eruptions more significant economically? Wohletz and Heiken, 1992, Fig. 2-43 Power generation schemes Goff and Janik, 2000, Fig. 8 Potential environmental and safety issues H2S pollution of atmosphere Brine pollution of groundwater Hydrothermal explosions Landslides Reservoir interference, depletion, subsidence, and induced seismicity Earthquakes and volcanic hazards Goff and Janik, 2000, p. 933 P. Kresan Hydrothermally generated oil Heat from magmatic processes Can contribute to maturation of hydrocarbons Can lead to overmaturation of hydrocarbons Depends on prior thermal history and temperature + time exposure to hydrothermal system Oil generated by interaction with hydrothermal fluids at modern mid-ocean ridges receiving pelitic sediment Temperatures >300°C--twice those at top of “normal” oil window, i.e., in amagmatic sedimentary basins Oil commonly found in many paleohydrothermal systems hosted by organic-rich sedimentary rocks Volcanic rocks as reservoirs Volcanic rocks uncommon reservoirs Why? An important petroleum reservoir in Railroad Valley, eastern Nevada, is Tertiary ignimbrite Summary Volcanic contributions to climate change Review of atmospheric structure and processes Eruptions and atmospheric anomalies Volcanism and extinctions Volcanic contributions to S and C fluxes Volcanic materials for consumers Volcanic contributions to soils Geothermal systems and resources Petroleum maturation and reservoirs Thanks for participating in Volcanology classes during Spring of 2015!