Gases KMS 8th Grade Science Ms. Bormann The Nature of Gases The first gas to be studied was air & it was a long time before it was discovered that air was actually a mixture of particles rather than a single gas. Although air is a mixture of several different gases, it behaves much the same as any single gas. Regardless of their chemical identity, gases tend to exhibit similar physical behaviors Characteristics of Gases The Kinetic Molecular Theory Kinetic = Motion Molecular = Molecules The theory states the tiny particles in all forms of matter are in constant motion. Boyle’s Law Robert Boyle was among the first to note the relationship between pressure and volume of a gas. During his experiments temperature and the amount of gas were NOT allowed to change. Boyle’s Law states The pressure exerted by a gas held at constant temperature varies inversely with the volume of the gas. For example: If the volume is halved, the pressure would be doubled Pressure Pressure – amount of force exerted per unit of area. • Pa = Pascal. SI unit for pressure. One Pascal of pressure is 1 Newton per square meter – therefore a Pascal is a very small unit. • kPa = kilopascal. A kilopascal is 1,000 Pa. Example: At sea level atmospheric pressure is 101.3 kPa. This means that at Earth’s surface, the atmosphere exerts a force of 101,300 Newton’s on every square meter (this is about the weight of a large truck) • Atm = standard atmosphere. 101.3 kPa or 101,300 Pa Boyle’s Mathematical Law P1V1 = P2V2 A gas has a volume of 3.0 L at 2 atm. What is its volume at 4 atm? Boyle’s Law 1. Determine which variables you have P1 = 2 atm V1 = 3.0 L P2 = 4 atm V2 = ? 2. Determine which law is being represented P and V = Boyle’s Law 3. Rearrange the equation for the unknown variable. 4. Plug in the variables and solve. Charles’s Law Jacques Charles was among the first to note the relationship between temperature and volume of a gas. During his experiments pressure and the amount of gas are NOT allowed to change. Charles’s Law states At constant pressure, the volume of a fixed number of particles of gas is directly proportional to the absolute (Kelvin) temperature For example: If the temperature is increased, the pressure will increase Temperature Charles' Law must be used with the Kelvin temperature scale. This scale is an absolute temperature scale. At 0 K, there is no kinetic energy (Absolute Zero). According to Charles' Law, there would also be no volume at that temperature. This condition cannot be fulfilled because all known gases will liquefy or solidify before reaching 0 K. oC 273 Kelvin Charles’s Mathematical Law Eg: A gas has a volume of 3.0 L at 127°C. What is its volume at 227 °C? Charles’s Law 1. Determine which variables you have T1 = 127°C + 273 = 400K V1 = 3.0 L T2 = 227°C + 273 = 5ooK V2 = ? 2. Determine which law is being represented. 3. Plug in variables 4. Cross multiply and solve