Unit 4: Chemical Quantities Review Nov 2013 Instructions: This review is intended to prepare you for the problem solving (application/communication) section of the test. You should be able to complete this section of the test in 45 minutes. Communication Criteria Formula provided Significant digit rules obeyed Never 0 0 Rarely 1 1 Sometimes 2 2 Frequently 3 3 Always 4 4 Units provided 0 1 2 3 4 1. Copper (II) hydroxide, Cu(OH)2, is found in nature as the mineral spertiniite. Copper (II) hydroxide can be reacted to produce copper metal, the material that makes everything from roofing materials to wiring. a) Calculate the percent composition of copper (II) hydroxide. [A 3] b) What mass of copper can be produced from 1 tonne (1000 kg) of spertiniite? [ A 1] 2. The combustion of 3.42 g of a compound known to contain only nitrogen and hydrogen gave 9.23 g of NO2 and 5.43 g of H2O. What is the empirical formula of this compound? [5 A] 3. Using a mass spectrometer it was determined the molar mass of a certain hydrocarbon known as “chrysene” is 228.3 g/mol. If the empirical formula of the compound was C3H2, what is the molecular formula? [2 A] 4. When 27.40 g of hydrated cobalt (II) chloride undergoes hydrate analysis, 14.94 g of anhydrous CoCl2 are formed. Calculate the chemical formula of the hydrate. [3 A] 5. In the textile industry, chlorine is used to bleach fabrics. Any of the toxic chlorine that remains after the bleaching process is destroyed by reacting it with a sodium thiosulfate solution, Na2S2O3 (aq). What mass of Na2S2O3 must be added to destroy 25 kg of chlorine, assuming excess water is present. [3 A] Na2S2O3 (aq) + 4Cl2(g) + 5H2O (l) 2NaHSO4(aq) + 8HCl (aq) 6. A 56.5 g sample of magnesium hydroxide (Mg(OH)2 (s)) was reacted with 45.0 g of hydrochloric acid (HCl (aq)) to form magnesium chloride and water. a) Write the balanced chemical equation. [1 A] b) Calculate the theoretical yield of MgCl2 produced in the reaction. [5 A] c) How many grams of the excess reactant will remain after the reaction? [2 A]