Chapter 1 Chemistry: The Science of Matter Section 1.1: The Puzzle of Matter Section 1.2: Properties and Changes of Matter Section 1.1 Objectives Classify matter according to its composition. Distinguish among elements, compounds, homogeneous mixtures, and heterogeneous mixtures. Relate the properties of matter to its structure. Composition, Structure and Behavior Chemistry- the science that investigates and explains the structure and properties of matter. Matter- anything that takes up space and has mass Mass- the measure of the amount of matter that an object contains Matter Matter is all around you. Phone Your neighbor The desk The metal of your chair The air you are breathing What isn’t matter Heat Light Thoughts Ideas Radio waves Magnetic fields Mass On earth we equate mass with weight. A bowling ball has a larger mass than a tennis ball. I have more mass than the text book. Matter The structure of matter refers to its composition-what is it made of and how is it organized The properties of matter describe the characteristics and behavior of matter. Changes matter undergoes Comparing Composition and Behavior (Figure 1.2 page 5) Salt and Water Salt is Na and Cl Water is H and O You can wash you hair in water, but not in salt. And you sprinkle water over popcorn. Aspirin and Sucrose Both are composed of C, H, and O You wouldn’t use aspirin to sweeten cereal or use sucrose for a headache Properties You can determine some of the properties of a particular chunk of matter by examination and manipulation. What is its color? Is it a solid, liquid or gas? Is it soft or hard? Does it dissolve in water? Properties of Iron Strong, but can be flattened and stretched Does not dissolve in water Turns to a liquid at high temperatures Is a gray, shiny solid Is attracted to a magnet Conduct electricity Properties and Composition You may be able to determine many properties of a piece of matter by examining it and doing some simple tests. However, you can not determine what it is composed of just by looking at it. Examining Matter: The Macroscopic View of Matter The macroscopic view of matter is one in which you touch, smell, taste and see. The Submicroscopic View of Matter Gives you a glimpse into the world of atoms You cannot see this world even with the most powerful microscopic. Matter is made up of atoms Atoms are so small that a period at the end of a sentence is made up of 100,000,000,000,000,000,000 (100 quintillion) carbon atoms. If you could count all 100 quintillion atoms at a rate of three per second it would take you a trillion years to finish counting. Macro, micro, submicro Macroscopic – I can see with my “naked” eye Microscopic – I need a microscope to see Submicroscopic – I can’t see even with the most powerful microscope Scanning Tunneling Microscope (STM) Although you cannot see atoms the STM can produce images on a computer screen that show the location of individual atoms. Platinum Using Models in Chemistry In chemistry you will use macroscopic and sub-microscopic models to understand certain concepts. Scientific model- a thinking device, built on experimentation, that helps us to understand and explain macroscopic observations. Models A model for the atom was discussed in Greece about 2,500 years ago. However, this was not a scientific model. The scientific model of the atom was not proposed until the 1800’s and it has with stood much experimentation with little changes. Classifying Matter Matter can be classified by its composition There are two main types of classifications Qualitative- an observation made without measurement. Quantitative- an observation made with measurement Qualitative vs. Quantitative Qualitative There are students in this room Sucrose contains carbon, oxygen and hydrogen Quantitative There are 24 students in this room Sucrose contains 42.1 g of carbon, 51.4 g of oxygen and 6.5 g of hydrogen. Pure vs. Mixture Matter can be classified by its purity. Is the matter pure or is it a mixture? Pure in chemistry means it contains only the same substance. Substance- matter with the same fixed composition and properties. Can be an element or a compound Any sample of pure matter is a substance Substances The bag of sugar you buy at the store is pure sucrose. It all has the same properties and a fixed composition. Therefore, it is a substance. Mixed Matter Mixed matter is referred to as a mixture. Mixture- combination of two or more substances in which the basic identity of the substances are not changed. Mixtures do not have a specific composition. Mixtures can be separated into its components by physical means. Separating Mixtures One way is by physical changes. Physical change- a change in matter that does not involve a change in the identity of individual substances. Boiling Freezing Melting Evaporation Dissolving Crystallization Physical Properties Separation by physical changes takes advantage of the physical properties of the mixture. Physical properties- characteristics that a sample of matter exhibits without any changes in its identity Solubility Melting and boiling point Color Density Electrical conductivity Physical state (solid, liquid or gas) Types of Mixture There are two types of mixtures: Heterogeneous Hetero means “different” Homogeneous Homo means “the same” Heterogeneous Mixture Heterogeneous Mixture- a mixture that does not have a uniform composition. You can see the different composition. Examples: Granite Chef Salad Lucky Charms Cereal Orange Juice with pulp Homogeneous Mixture Homogeneous Mixture- a mixture with a uniform composition. You cannot tell that it is composed of more than one substance Another name is a solution Examples: Salt water Tea Sugar water Solutions Homogeneous mixture Examples: Salt water Gasoline Air Steel Alloys Alloys- solid solutions that contain different metals and sometimes nonmetallic substance Table 1.1 page 23 Table 1.1 Some Common Alloys Name of Alloy % Composition Stainless Steel 73-79% iron (Fe) 14-18% chromium (Cr) 7-9% nickel (Ni) Bronze 70-95% copper (Cu) 1-25% zinc (Zn) 1-18% tin (Sn) Brass 50-80% copper (Cu) 20-50% zinc (Zn) Sterling Silver 92.5% silver (Ag) 7.5% copper (Cu) 14-karat gold 58% gold (Au) 14-28% silver (Ag) 14-28% copper (Cu) 18-karat white gold 75% gold (Au) 12.5% silver (Ag) 12.5% copper (Cu) Solder (electronic) 63% tin (Sn) 37% lead (Pb) Solutions When you are dissolving a substance into another substance there are two important terms: – the substance being dissolved Solvent – the dissolving agent Solute Salt Water Solute = NaCl Solvent = H2O Aqueous Solution Aqueous Solution- a solution in which the solvent is water. Examples: Soda Tea Contact-lens cleaner Clear cleaning liquids Most processes of life take place in aqueous solutions. Substance: Pure Matter You and everything around you is made up of chemicals. Elements: The Building Blocks If you classify an unknown piece of matter as pure; it means that it is made up of one substance There are two types of substances Compounds Elements Elements Elements- a substance that cannot be broken down into simpler substances. Simplest form of matter Building blocks for other types of matter All substance in the universe are: Elements Compounds formed from elements Or mixtures of elements and compound Elements 118 elements Examples: Gold Carbon Lead Elements combine to form millions of compounds. Chemical elements are often referred to as the building blocks of matter Elements 118 elements 90 occur naturally Less than half of these are abundant The remainder are synthesized Organizing the Elements Elements are organized in the Periodic Table The periodic table tells you: Name Symbol Atomic mass Symbols The symbols of the elements are extremely important to know. You will only have to know the most common ones. The symbols are a one to two letter representation of the elements. Not all the symbols are the first or second letter of the elements name Symbols Oxygen O Hydrogen H Bromine Br Chlorine Cl Table 1.2 Some Historic Chemical Symbols Element Symbol Origin Language Antimony Sb Stibium Latin Copper Cu Cuprum Latin Gold Au Aurum Latin Iron Fe Ferrum Latin Lead Pb Plumbum Latin Potassium K Kalium Latin Silver Ag Argentum Latin Sodium Na Natrium Latin Tin Sn Stannum Latin Tungsten W Wolfram german Compounds Are More Than One Element Compound – a chemical combination of two or more different elements joined together in a fixed proportion. Every compound has its own fixed composition Therefore, every compound has unique chemical and physical properties. The properties of a compound are different from the properties of the elements that make them up. Compounds More than 10 million are known (still growing) New natural compounds are being isolated from plants and colonies of bacteria. New compounds are also being synthesized in labs. Examples Sucrose Salt Water Formulas of Compounds Formula – a combination of the chemical symbols that show what elements make up a compound and the number of atoms of each element. Sucrose: Aspartame: Table 1.3 Some Common Compounds Compound Name Formula Acetaminophen C8H9NO2 Acetic Acid C2H4O2 Ammonia NH3 Aspartame C14H18N2O5 Propane C3H8 Salt NaCl Sodium Hydroxide NaOH Sucrose C12H22O11 Water H2O Review What is the difference between an element and a compound? What is the difference between a homogeneous mixture and a heterogeneous mixture? What is the difference between a mixture and a compound?