PASS Content Standard 1.3 Matter has characteristic properties, such as boiling points, melting points, and density, which distinguish pure substances and can be used to separate one substance from another. Mass Weigh Volume Density Specific Gravity Boiling Point Melting Point The amount of matter in an object. The SI units of mass are Kilograms. A measure of the pull of gravity on an object. QuickTime™ and a Sorenson Video decompressor are needed to see this picture. Mass & Weight - 2 min Gravity accelerates all objects downward 2 at 9.8 m/s All objects fall at the same rate. The SI units of weight are Newtons, 2 kg m/s The amount of space an object takes up. The SI units of volume are Liters. What is the volume of this object? 4 cm 3 cm 5 cm 4 cm X 5 cm X 3 cm = 60 4 cm 3 cm 5 cm 3 cm Mass per unit volume D= m /V QuickTime™ and a Sorenson Video decompressor are needed to see this picture. Density - 3 min The density of water is 1 gram / 3 cm A ratio of density of a substance to the density of water. The density of iron g is 7.9 /cm3, what is its specific gravity? Density of iron : Density of water = Specific Gravity of Iron Think of this as DIVIDE Density of iron 7.9 : g/cm3 Density of water : = Specific Gravity of Iron 1 g/cm3 = 7.9 Density of iron 7.9 : g/cm3 Density of water : = Specific Gravity of Iron 1 g/cm3 = 7.9 Since specific gravity is a ratio, there are no units for the number. Take in water to dive Release water to surface The temperature at which a solid becomes a liquid. o Water melts at _ C o Table salt melts at _ C o Diamond melts at _ C The temperature at which a solid becomes a liquid. o Water melts at 0 C o Table salt melts at 801 C o Diamond melts at 3700 C The temperature at which a liquid becomes a vapor. o Water boils at _ C o Table salt boils at _ C o Diamond boils at _ C The temperature at which a liquid becomes a vapor. o Water boils at 100 C o Table salt boils at 1413 C o Diamond boils at 4200 C QuickTime™ and a Sorenson Video decompressor are needed to see this picture. Melting & Vaporization - 3 min Elements are the simplest pure substances. An element cannot be changed into simpler substances by any chemical process. QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. Fireworks - 3 min Compounds are pure substances made of more than one element. Atoms of elements in a compound are chemically bonded together to form molecules. Chemical bonds form as the valence electrons of atoms interact. Valence electrons are those in the outer energy level of an atom. Atoms form chemical bonds to get 8 electrons in their outer energy level. The tendency of an atom to attract electrons. Metals generally have a low electron affinity. Nonmetals generally have a high electron affinity. Ionic bonds form when electrons are transferred from one atom to another. Covalent bonds form when electrons are shared between atoms. Valence electrons can be thought of as being the property of all the atoms. A way of drawing the valence electrons of an atom. Ne The chemical symbol represents the nucleus and all electrons except valence electrons Ne Dots indicate the number and sub-level location of the valence electrons Ne Begin adding dots with the "s"sublevel electrons... Add the "p" sublevel electrons one at a time, beginning at the top and going counterclockwise. Na Mg Al C N O F Ne What is the electron-dot diagram for iron? What is the electron-dot diagram for silver? What is the electron-dot diagram for uranium? Electron-dot diagrams can be drawn to represent simple compounds. Draw the electron-dot diagram for hydrochloric acid. H Cl Draw the electron-dot diagram for water. H H O Polyatomic ions are groups of covalently bonded atoms that have an overall charge. Chemical formulas use combinations of chemical symbols to represent compounds. Oxidation numbers are used to write chemical formulas. Oxidation numbers indicate the number of valence electrons an atom will gain or lose when forming compounds. Elements and ions with a positive oxidation number will lose electrons. Elements and ions with a negative oxidation number will gain electrons. The sum of the oxidation numbers in a compound is always equal to zero. You can think of a chemical formula as having two parts a positive part and a negative part. The positive part is always written first The negative part is always written second. Metals are almost always the positive part of a formula. Nonmetals are usually the negative part of a formula. 1. Write the name of the positive element. 2. Write the name of the negative element with an "ide" ending. Iron (II) chloride Magnesium iodide Silver nitride Aluminum bromide Nickel (II) sulfide Chromium (IV) oxide CuS AgF Ca3N2 Hg2C PbO KBr Some compounds contain polyatomic ions. A polyatomic ions is: a group of atoms with an overall charge. Know these 12 polyatomic ions: ammonium - NH4 acetate - C2H3O2 chlorate - ClO3 -1 +1 -1 Know these 12 polyatomic ions: hydroxide - OH nitrate - NO3 nitrite - NO2 -1 -1 -1 Know these 12 polyatomic ions: carbonate - CO3 sulfate - SO4 sulfite - SO3 -2 -2 -2 Know these 12 polyatomic ions: phosphate - PO4 cyanide - -3 -1 CN hexafluorosilicate - SiF6 -2 Formulas with polyatomic ions The charge on a polyatomic ion is its oxidation number Never change a subscript in a polyatomic ion. If more than one polyatomic ion is needed to make the oxidation numbers total zero.... put the polyatomic ion in parenthesis before adding the subscript. When a chemical reaction occurs, there is always a change in properties and energy • Color change • Heat change • Gas produced • Precipitate formed QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. Chemical Reactions - 3 min There are five basic types of chemical reactions: Two simple substances combine to form a more complex one. element + element compound QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. Synthesis Reactions - 3 min A complex substance breaks into simple substances. compound element + element QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. Decomposition Reactions - 2 min A single element replaces an element in a compound. element + compound element + compound QuickTime™ and a Sorenson Video decompressor are needed to see this picture. Single Displacement Reactions - 5 min Two different elements in two different compounds switch places. compound + compound compound + compound QuickTime™ and a Sorenson Video decompressor are needed to see this picture. Double Displacement Reactions - 3 min A hydrocarbon reacts with oxygen to form carbon dioxide and water. CH4 + O2 CO2 + H2O QuickTime™ and a Sorenson Video decompressor are needed to see this picture. Combustion Reactions - 7 min Chemical equations represent chemical reactions on paper. H2 + O2 H2 O The Law of Conservation of Matter and Energy says that matter can be neither created nor destroyed during chemical reactions. Because of this, the products of a chemical reaction must contain the same atoms as the reactants. Reactants Products Correctly written chemical equations must be balanced. 2H2 + O2 2H2O Coefficients indicate the number of molecules. 2H2 + O2 2H2O Subscripts indicate the number of atoms. 2H2 + O2 2H2O Equations are balanced by changing coefficients, never by changing the subscripts in correctly written chemical formulas. Seven steps are used to balance equations by inspection. These steps must be done in order. Check for diatomic molecules. All diatomic molecules must have a subscript of 2. H 2 N 2 O 2 F2 Cl2 Br2 I2 Balance metals. Balance nonmetals. Balance oxygen. Balance hydrogen. At this point, the equation should be balanced. Recount all atoms. If the numbers are not the same, go back to step #1 and work through the steps. Reduce coefficients, if needed. Do this only if every coefficient is divisible by the same number. S8 + O2 SO3 S8 + 12O2 8SO3 HgO Hg + O 2HgO 2Hg + O2 Na + H2O NaOH + H 2Na + 2H2O 2NaOH + H2 C10H16 + Cl C + HCl C10H16 + 8Cl2 10C + 16HCl FeS2 + O2 Fe2O3 + SO2 4FeS2 + 11O2 2Fe2O3 + 8SO2 Two or more substances are physically combined, but not chemically combined. Homogeneous mixtures have identical properties throughout. Heterogeneous mixtures are not identical throughout. QuickTime™ and a Sorenson Video decompressor are needed to see this picture. Mixtures - 6 min Special mixtures formed when one substance dissolves in another. All solutions have 2 parts Solvent - the most abundant substance. Solute - the least abundant substance. Solutions may have several solutes, but they will have only one solvent. Solution concentration compares the amounts of solvent and solutes. Concentration terms like "strong" and "dilute" do not describe the solution well enough for most scientific needs. The most common concentration used in chemistry is "molarity". Molarity indicates the number of moles of solute per liter of solution One mole, in solution One dozen equals 12 One mole equals 6.02 X 10 23 A mole of any solute is equal to its formula mass in grams. How many grams of sodium chloride are needed to make 1 mole? NaCl Na = 23 Cl = 35 58 grams/mole A liter of hydrochloric acid solution contains 72 grams of HCl. What is the molarity of this acid solution? 72 g 36 g/mole = 2M Acids produce hydronium ions, + H3O in solution. Acids produce protons in chemical reactions. Acids taste sour. QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. Acids & Bases - 4 min Common acids contain hydrogen that is ionized in aqueous (water) solution. Whether an acid is strong or weak depends on the amount of hydrogen that is ionized. QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. strong & weak - 3 min Common Industrial Acids: • Hydrochloric Acid HCl • Nitric Acid HNO3 • Sulfuric Acid H2SO4 Bases produce hydroxide ions, OH in solution. Bases accept protons in chemical reactions. Bases taste bitter. QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. Properties - 2 min Common Industrial Bases: • Sodium Hydroxide NaOH • Calcium Hydroxide Ca(OH)2 • Ammonium Hydroxide NH4OH pH is a measure of + H3O concentration QuickTime™ and a Sorenson Video 3 decompressor are needed to see this picture. pH Scale - 3 min pH of some substances Even "concentrated" acids and bases are solutions containing water: Concentrated HCl is 12 M Concentrated H2SO4 is 18 M Concentrated HNO3 is 16 M Concentrated NaOH is 19 M Use caution when diluting acids and bases. When Chemists take acid trips Composed of the positive part of a base and the negative part of an acid. Formed during a neutralization reaction between an acid and base. HCl + NaOH Hydrochloric Acid Sodium Hydroxide Acid + Base NaCl + H2O Sodium Chloride Water Salt + Water End Content Standard 1.3