MOL AIRLINES Jacob Jeter, Maccoy Merrell, Levi Villarreal, Bryce Mottley ALL HAIL HONORABLE JUDGE RESTIVO! Number Carbon Hydrogen Nitrogen Oxygen Found Formula Chemical Person 1 67.31 6.98 4.62 21.10 Blood and luggage C17H21NO4 Cocaine Bill Cadillac Seville 2a 63.15 5.30 X 31.55 briefcase 2b 46.66 4.48 31.10 17.76 stomach 3 72.15 7.08 4.68 16.03 4 15.87 2.22 18.15 5a 75.42 6.63 5b 37.01 6 C8H8O3 Vanillin JemCreme Leclaire C₇H₈N₄O₂ Theobromine “ pockets C18H21NO3 Codeine Reno Bob Henderson 63.41 blood and pockets C3H5N3O9 Nitroglycerin Amadeo G. Seville 8.38 9.57 blood C21H22N2O2 Strychnine Norman Anderson 2.22 18.50 42.27 luggage and blast site C7H5N3O6 Trinitrotoluene “ 57.14 6.16 9.52 27.18 briefcase C14H18N2O5 Aspartame Archer Starr 7a 80.94 7.45 9.39 2.68 briefcase C40H44N4O Curare Lisa Jo Elderberry 7b 81.58 8.90 9.52 X luggage C20H26N2 Dimetacrine “ 8a 60.00 4.48 X 35.53 pocket and briefcase C9H8O4 Aspirin Connie Lou Majors 8b 63.56 6.00 9.27 21.17 pocket and briefcase C8H9NO2 Acetaminophen “ Amadeo G. Oldere Who was Amadeo G. Oldere and what was his part in the Mole Air disaster? Explain the chemical and mathematical proof to show this to be correct with as any absolutes as possible. Mr. Oldere suffered from a heart condition which prevented him from flying planes. Nitroglycerin was found in the blood of suspect 4, leading to the conclusion that suspect 4 must be Mr. Oldere. While nitroglycerin is explosive, it must be concentrated beyond that of a regular prescription pill and ignited by various means. Mr. Oldere’s influence in the crashing of the plane can therefore be exempted. Archer Starr Who was Archer Starr and what was her part in the Mole Air disaster? Explain the chemical and mathematical proof to show this to be correct with as any absolutes as possible. Our findings show that Archer Starr is the most likely candidate for owning the briefcase belonging to suspect 6. While conventionally, a teacher would not pack obstructive chemicals with her work, we do not know the day nor the destination of the plane she was on. Also, only aspartame was found in the briefcase. This leads to the conclusion that Archer Starr was suspect 6, which had no explosives nor poisons tied chemically. Suspect #1 Deductions Seville, Bill Cadillac Used car salesman and suspected drug dealer Bill is a suspected drug dealer, and since cocaine is one of the most popular illegal drugs, we can assume that he was the one who had the drug in his blood and luggage, and was smuggling it to another location. Empirical Formula Cocaine– C17H21NO4 – Illegal drug Smallest PreEmpirical % (Grams) GFWT Quotient Carbon 67.31 12 5.61 16.998 16.998 (17) Hydrogen 6.98 1 6.98 21.15 21.15 (21) .33 Factor # of atoms Element 1 Nitrogen 4.62 14 .33 1 1 (1) Oxygen 21.10 16 1.31875 3.9962 3.9962 (4) Percent Composition Cocaine– C17H21NO4 – Illegal drug Element Number of Atoms GFWT Work % Composition Carbon 17 12x17=204 204/303 67.3 Hydrogen 21 21x1=21 21/303 6.9 Nitrogen 1 1x14=14 14/303 4.6 Oxygen 4 16x4=64 64/303 21.1 Total 43 303 X 100 Suspect #2 Deductions LeClaire, JemCreme French Pastry Chef Vanillin is the main ingredient in vanilla extract and flavoring. This would be something a chef would use daily. This was found in his suitcase, so we can assume he was transporting the vanilla to another location. Theobromine, an alkaloid found in chocolate was also found in their stomach. Since a pastry chef is sure to have recently been around chocolate, we can assume that the Theobromine belonged to JemCreme. Empirical Formula Element % (Grams) GFWT Quotient Smallest Carbon 63.15 12 5.2625 2.6700 Hydrogen 5.30 1 5.3 2.6877 Nitrogen X 14 X X Oxygen 31.55 16 1.9719 1 1.9719 Pre-Empirical Factor # of atoms 8.010 (8) 8.063 (8) 3 X 3 (3) Theobromine– C7H8N4O2 – Found in chocolate Vanillin – C8H8O3 – Found in Vanilla Element % (Grams) GFWT Quotient Smallest Pre-Empirical Carbon 46.66 12 3.8883 3.503 Hydrogen 4.48 1 4.48 4.036 1.11 Factor 7.005 (7) 8.072 2 Nitrogen 31.10 14 2.221 2.0009 Oxygen 17.76 16 1.11 1 # of atoms (8) 4.002 (4) 2 (2) Percent Composition Element Number of Atoms GFWT Work % Composition Carbon 8 12x8=96 96/152 63.1 Hydrogen 8 1x8=8 8/152 5.2 Nitrogen 0 14x0=0 0/152 0 Oxygen 3 16x3=48 48/152 31.57 Total 19 152 X 100 Vanillin – C8H8O3 – Found in Vanilla Theobromine– C7H8N4O2 – Found in chocolate Element Number of Atoms GFWT Work % Composition Carbon 7 12x7=84 84/180 46.67 Hydrogen 8 1x8=8 8/180 4.44 Nitrogen 4 14x4=56 56/180 31.11 Oxygen 2 16x2=32 32/180 17.77 Total X 180 X 100 Suspect #3 Deductions Henderson, Reno Bob Pro Athlete suspended for drug violations Codeine is a medicine that can be easily abused, and since Reno Bob was suspended for drug abuse, he could be the one with the Codeine. Also, Codeine can be picked up on drug tests, so Reno would be busted if he had been overdosing. The Codeine was found in his pockets, showing that he had taken it recently. Empirical Formula Codeine– C18H21NO3 – Pain or cough medicine Element % (Grams) GFWT Quotient Smallest Pre-Empirical Carbon 72.15 12 6.0125 18.001 Hydrogen 7.08 1 7.08 21.197 .334 Factor 18.001 (18) 21.197 1 Nitrogen 4.68 14 .334 1 Oxygen 16.03 16 1.002 3 # of atoms (21) 1 (1) 3 (3) Percent Composition Codeine– C18H21NO3 – Pain or cough medicine Element Number of Atoms GFWT Work % Composition Carbon 18 12x18=216 216/299 72.24 Hydrogen 21 1x21=21 21/299 7 Nitrogen 1 14x1=14 14/299 4.68 Oxygen 3 16x3=48 48/299 16.05 Total X 299 X 100 Suspect #4 Deductions Oldere, Amadeo G. Suspended pilot because of heart condition. Suspect 4 was found with Nitroglycerin in their blood and pockets. Nitroglycerin treats chest pain and can lower the risk of heart disease. Because Amadeo has a heart condition, we can assume that he was taking medication for it. Empirical Formula Nitroglycerin – C3H5N3O9 – Lowers chance of heart attack Element % (Grams) GFWT Quotient Smallest Pre-Empirical Carbon 15.87 12 1.3225 1.020 Hydrogen 2.22 1 2.22 1.7124 1.2964 Factor 3.06 (3) 5.1372 3 Nitrogen 18.15 14 1.2964 1 Oxygen 63.41 16 3.96 3.055 # of atoms (5) 3 (3) 9.165 (9) Percent Composition Nitroglycerin – C3H5N3O9 – Lowers chance of heart attack Element Number of Atoms GFWT Work % Composition Carbon 3 12x3=36 36/227 15.85 Hydrogen 5 1x5=5 5/227 2.2 Nitrogen 3 14x3=42 42/227 18.5 Oxygen 9 16x9=144 144/227 63.4 Total X 227 X 100 Suspect #5 Deductions Anderson, Norman Suspected leader of terrorist organization The only suspect left for chemical set 5 is Norman Anderson, the suspected leader of a terrorist organization. Furthermore, as a suspected terrorist, it makes sense that he would have TNT on a plane, to try and blow it up. The poison was found in his blood, showing that he had already ingested it, while the TNT was in his luggage, waiting to be detonated. Empirical Formula Smallest PreEmpirical Element % (Grams) GFWT Quotient Carbon 75.42 12 6.285 10.510 Hydrogen 6.63 1 6.63 11.087 .598 Factor 21.02 (21) 22.174 2 Nitrogen 8.38 14 .599 1.002 Oxygen 9.57 16 .598 1 # of atoms Strychnine – C21H22N2O2 - Poison (22) 2.004 (2) 2 (2) Trinitrotoluene – C7H5N3O6 - Explosive Smallest PreEmpirical Element % (Grams) GFWT Quotient Carbon 37.01 12 3.084 2.334 Hydrogen 2.22 1 2.22 1.6 1.3214 Factor 7.002 (7) 4.8 3 Nitrogen 18.50 14 1.3214 1 Oxygen 42.27 16 2.6419 1.999 # of atoms (5) 3 (3) 5.997 (6) Percent Composition Element Number of Atoms GFWT Work % Composition Carbon 21 12x21=252 252/334 75.45 Hydrogen 22 1x22=22 22/334 6.6 Nitrogen 2 14x2=28 28/334 8.4 Oxygen 2 16x2=32 32/334 9.6 Total X 334 X 100 Trinitrotoluene – C7H5N3O6 - Explosive Strychnine – C21H22N2O2 - Poison Element Number of Atoms GFWT Work % Composition Carbon 7 12x7=84 84/227 37 Hydrogen 5 1x5=5 5/227 2 Nitrogen 3 14x3=42 42/227 18.5 Oxygen 6 16x6=96 96/227 42.3 Total X 227 X 100 Suspect #6 Deductions Star, Archer Science teacher addicted to sugar free drinks and candy Suspect 6 was found with aspartame, an artificial sweetener in their briefcase. This was most likely Archer Starr, who is addicted to artificial sweeteners. Empirical Formula Aspartame– C14H18N2O5 – Artificial sweetener Element % (Grams) GFWT Quotient Smallest Pre-Empirical Carbon 57.14 12 4.7617 7.0025 Hydrogen 6.16 1 6.16 9.0588 .68 Factor 14.005 (14) 18.118 2 Nitrogen 9.52 14 .68 1 Oxygen 27.18 16 1.699 2.498 # of atoms (18) 2 (2) 4.996 (5) Percent Composition Aspartame– C14H18N2O5 – Artificial sweetener Element Number of Atoms GFWT Work % Composition Carbon 14 12x14=168 168/294 57.14 Hydrogen 18 1x18=18 18/294 6.1 Nitrogen 2 14x2=28 28/294 9.5 Oxygen 5 16x5=80 80/294 27.21 Total X 294 X 100-ish Suspect #7 Deductions Elderberry, Lisa Jo Severely depressed environmental engineer Since Lisa is an environmental engineer, she would have access to many different plants perhaps including the Curare plant, from which poison is derived. Also, she is depressed, so it is safe to assume that she would be taking anti-depressant medicine. The poison was found in her briefcase, while the antidepressant was in her briefcase. Empirical Formula Element % (Grams) GFWT Quotient Smallest Pre-Empirical Carbon 80.94 12 6.745 40.269 Hydrogen 7.45 1 7.45 44.478 .1675 Factor 40.269 (40) 44.478 (44) 1 Nitrogen 9.39 14 .6707 4.004 Oxygen 2.68 16 .1675 1 # of atoms 4.004 (4) 1 (1) Dimetacrine – C10H13N (or C20H26N2) – Anti-Depressant Curare – C40H44N4O - Poison * This one was even but was not the correct formula, so we multiplied it by 2 and got the formula for the desired chemical. Element % (Grams) GFWT Quotient Smallest Carbon 81.58 12 6.7983 9.9975 Hydrogen 8.90 1 8.90 13.088 Nitrogen 9.52 14 .68 1 Oxygen X 16 X X .68 Pre-Empirical Factor # of atoms 19.995 (20) 26.176 2 (26) 2 (2) X Percent Composition Element Number of Atoms GFWT Work % Composition Carbon 40 12x40=480 480/596 80.53 Hydrogen 44 1x44=44 44/596 7.38 Nitrogen 4 14x4=56 56/596 9.4 Oxygen 1 16x1=16 16/596 2.7 Total X 596 X 100 Curare – C40H44N4O - Poison Dimetacrine – C7H5N3O6 – Anti-Depressant Element Number of Atoms GFWT Work % Composition Carbon 20 12x20=240 240/294 81.63 Hydrogen 26 1x26=26 26/294 8.84 Nitrogen 2 14x2=28 28/294 9.5 Oxygen 0 16x0=0 0/294 0 Total X 294 X 100 Suspect #8 Deductions Majors, Connie Lou Chemist/Pharmacist Since both aspirin and acetaminophen are readily available over the counter medicines, we know suspect 8 is somebody with access to those kind of drugs. Connie is a pharmacist, so she would be able to access both of those medicines due to her profession. These drugs were found in her suitcase, showing that she was transporting them for work. Empirical Formula Element % (Grams) GFWT Quotient Smallest Carbon 60.00 12 5 2.25 Hydrogen 4.48 1 4.48 2.017 Nitrogen X 14 X X Oxygen 35.53 16 2.22 1 2.22 Pre-Empirical Aspirin– C9H8O4 – Treats pain Factor # of atoms 9.006 (9) 8.0699 4 (8) X 4 (4) Tylenol – C8H9NO2 – Treats aches Smallest PreEmpirical Element % (Grams) GFWT Quotient Carbon 63.56 12 5.297 7.999 Hydrogen 6.00 1 6.00 9.0615 .662 Factor 7.999 (8) 9.0615 1 Nitrogen 9.27 14 .662 1 Oxygen 21.17 16 1.323 1.9982 # of atoms (9) 1 (1) 1.9982 (2) Percent Composition Element Number of Atoms GFWT Work % Composition Carbon 9 12x9=108 108/180 60 Hydrogen 8 1x8=8 8/180 4.44 Nitrogen 0 14x0=0 0/180 0 Oxygen 4 16x4=64 64/180 35.55 Total X 180 X 100 Aspirin– C9H8O4 – Treats pain Tylenol – C8H9NO2 – Treats aches Element Number of Atoms GFWT Work % Composition Carbon 8 12x8=96 96/151 63.58 Hydrogen 9 1x9=9 9/151 6 Nitrogen 1 14x1=14 14/151 9.27 Oxygen 2 16x2=32 32/151 21.2 Total X 151 X 100 CONCLUSION ■ The chemical found at the blast site had the same percent composition as chemical 5b, which was also found in someone’s luggage. Deriving the empirical formula for this chemical showed that it was Trinitrotoluene, more commonly known as TNT, which is a high grade explosive. Thus, Norman Anderson is at fault for causing the crash. ■ There was also a death an hour before the explosion. Strychnine, a powerful rat poison, was found in Norman Anderson. This leads to the conclusion that Norman Anderson, the suspected leader of a terrorist organization, died one hour before the crash via strychnine. This is due to the fact that the other chemicals found in the passengers, were not lethal in normal amounts. The only substance capable of lethal dosage would be strychnine, requiring a mere 2 mg per kg, or 136 mg for the average adult male. However Strychnine is a very ineffective at killing leading to the question of whether Mr. Anderson committed suicide or was killed by outside means.