CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic I. II. Distinguish between hypotheses, laws, theories, and models Identify key factors that limit science’s ability to unambiguously answer all questions Define the desirability quotient and apply it in a given situation Describe the steps in the FiLCHeRS approach to evaluating claims Apply the FiLCHeRS approach to given situations Define chemistry as the study of matter and the changes it undergoes Identify physical and chemical properties Identify physical and chemical changes Given a description of matter, classify it as either a pure substance or a mixture If matter is a pure substance, further classify it as either and element or a compound If matter is a mixture, further classify it as either a homogeneous or heterogeneous mixture i. States of matter ii. Pure substance 1. element 2. compound iii. Mixture 1. Homogeneous 2. Heterogeneous UNIT 3 UNIT 2 Desirability quotient – benefits/risks (1.5) Critical thinking – FiLCHeRS approach ( a modification called FLaReS is in Section 1.13) Characteristics of Chemistry- Study of Matter and its Transformations a. The study of chemistry (Introduction to Chapter 1) b. Properties (1.8) i. physical ii. chemical c. Transformations (1.8) i. physical ii. chemical d. Classification of matter (1.9) c. d. Unit # UNIT 1 Science and Its Methods a. Basic characteristics of science (1.3) i. Hypothesis – testable and reproducible ii. Law – summary of many observations iii. Theory – tentative attempt to explain observations iv. Model – attempt to explain abstract ideas with more familiar scale examples b. The limitations of science (1.4) Learning Objectives CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic III. c. i. Review of exponential notation (Appendix A-1) ii. Basic prefixes and their interconversions Key derived units d. i. Volume (1.10) ii. Density (1.11) Temperature units and their interconversion (1.12) e. Energy units and their interconversion (1.12) Atoms – History and Early Indications a. Greek view of atoms (2.1) b. Fundamentals laws that led to early conclusions about atoms Write numbers in exponential notation Convert numbers from exponential notation to standard form Convert metric units from one prefix to another Convert area and volume units Define density Use the density definition to find missing information Carry out conversions between the three temperature scales given the mathematical relationships Distinguish between energy and heat Convert between various energy units Describe the contrast in views between Aristotle and Democritus in relation to matter State the law of conservation of mass State the law of definite proportions State the law of multiple proportions Apply the law of multiple proportions in straightforward numerical problems UNIT 6 i. Lavoisier: The law of conversation of mass (2.2) ii. Proust: The law of definite proportions (2.3) iii. Dalton: The law of multiple proportions (2.3) List the seven SI units in use Recognize the kilogram as the only prototype SI unit UNIT 5 b. i. SI units ii. Current definitions of seven base units The metric system (1.10) Unit # UNIT 4 IV. Measurement a. The International System (SI) (1.10) Learning Objectives CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic c. John Dalton’s atomic theory of matter (2.4) Learning Objectives State the current number of chemical elements known (this semester) Describe two of the electrical experiments, the workers involved, and the conclusions drawn regarding atomic structure UNIT 9 i. Electrolysis (Davy and Faraday) – atoms electrical in nature ii. Cathode ray tubes (Crookes) –stream of particles leaves cathode iii. Determination of mass-to-charge ratio (Thomson) – particles leaving cathode are negatively charged – named the particles electrons iv. Discovery of positive particles (Goldstein) – positive particles also produced in cathode ray tubes when negative particles are produced; positive particles are called protons v. Determination of electron charge (Millikan) – found charge on electron in oil-drop experiment; also provided mass because of Thomson’s mass-to-charge ratio Identify the primary individual associated with the development of today’s periodic table State the historical driving force behind creating the periodic table in its current arrangement UNIT 8 VI. i. Dobereiner’s “Triads” ii. De Chancourtois’s “Telluric Helix” iii. Newland’s “Law of Octaves” iv. Meyer’s system of elements v. Mendeleev’s version b. Current state – number of elements, physical arrangement, etc. (2.5) Historical Physical Evidence for Atoms a. Relationship between electricity and the atom (3.1) UNIT 7 V. i. Four points of Dalton’s atomic theory (2.4) ii. Physical phenomena explained by Dalton’s atomic theory (2.4) iii. Points in Dalton’s theory modified by more current findings (2.4) iv. Solving mass and atom ratios using Dalton’s approach (2.4) The Periodic Table a. Historic development of the periodic table (2.5) State the four premises of Dalton’s atomic theory Suggest in a given situation which of Dalton’s premise may be capable of explaining observed behavior Use proportions to carry out straightforward mass calculations for chemical compounds Unit # CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic Learning Objectives The arrangement of particles in the nucleus c. i. Three fundamental particles (3.5) 1. Proton – positive, relatively massive 2. Neutron – neutral, relatively massive (slightly more than the proton) 3. Electron – negative , relatively light (about 1/2000th of the other two particles) ii. Rutherford - small positive center surrounded by electrons in mostly empty space (Rutherford) (3.4) The atomic nucleus (3.5) List the three subatomic particles and their charges and relative masses Describe Rutherford’s scattering experiment and its implications for atomic structure Identify an element by the number of protons in the nucleus Define the term isotope Define the term mass number Write the symbolic representation for an isotope given sufficient information Given the symbolic representation for an isotope provide missing information UNIT 10 b. i. Atomic number (Z) – identifies element and indicates number of protons in the nucleus ii. Isotopes – two nuclei of the same element that differ in the number of neutrons in the nucleus; mass number (A) is sum of protons (Z) and neutrons d. X where X is the chemical symbol Electron arrangement – the Bohr model (3.6) i. Relationship between wavelength and energy ii. Bohr’s description of the relationship of colors emitted in spectra to electron energy levels Electron arrangement – the quantum model (3.7) i. The concept of an orbital ii. Writing electron configurations for atoms Relate color of light to wavelength and energy Describe the electronic processes that lead to the color in line spectra Determine the maximum number of electrons in a given shell Write electron configurations for elements in the first three periods UNIT 12 e. A Z UNIT 11 iii. Symbolic representation of isotopes - Unit # CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic f. i. Identification of valence electrons with group numbers ii. Identification of named groups and regions in the periodic table Chemical Bonds (Chapter 4) a. Identifying criteria for stable electron configurations (4.1) b. Lewis symbols and ionic compounds Draw a Lewis symbol for a given atom or ion State the octet rule Write formulas for binary ionic compounds Name binary ionic compounds Draw Lewis structures for covalent molecules and ions Write formulas for a select set of polyatomic ions Name a select set of polyatomic ions Name covalent compounds Determine the molecular shape of covalent compounds from their Lewis structures State whether a given molecule is nonpolar or polar i. ii. iii. iv. i. Relating Lewis structure to molecular shape – The VSEPR Theory (4.12) ii. Relate shape to polarity of molecules (4.13) UNIT 16 UNIT 15 d. i. Writing Lewis structures for covalent bonds (4.6-4.8) ii. Rules for writing Lewis structures (4.10) iii. Identify and work with polyatomic ions (4.9) iv. Name covalent compounds (4.6, 4.9) Relating shape and polarity to Lewis structure Use the periodic table to identify the number of valence electrons in an atom of an element Use the periodic table to describe the location of groups, periods, main group elements, transitions elements, metals, nonmetals, alkali metals, alkaline earth metals, and halogens UNIT 14 c. Lewis symbols for individual atoms (4.2) Lewis forms for ionic compounds (4.3-4.4) The octet rule (4.4) Writing formulas for and naming binary ionic compounds (4.5) Lewis structures and covalent species Unit # UNIT 13 VII. Relationship between electron configurations and the periodic table Learning Objectives CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic VIII. Chemical Accounting a. Chemical equations (5.1) Learning Objectives d. i. Identification of Avogadro’s number and its significance ii. Definition of the term mole and its relationship to Avogadro’s number iii. Introduction to formula (or molecular mass for molecules) mass and its relationship to Avogadro’s number and the mole Working with Avogadro’s number, mass, and the mole (5.4) Give the significance of Avogadro’s number Give Avogadro’s number Relate formula mass to numbers of moles Interconvert between grams, moles, and numbers of particles Apply the mass and mole relationships to chemical reactions UNIT 19 i. Mole-to-mass and mass-to-mole conversions ii. Relationships in chemical equations 1. Mole relationships in chemical equations 2. Mass relationships in chemical equations State Gay-Lussac’s law of combining volumes Apply Gay-Lussac’s law of combining volumes to a chemical reaction scenario State Avogadro’s hypothesis regarding the numbers of molecules in equal volumes of gases UNIT 18 c. i. Law of combining volumes (Gay-Lussac) ii. Avogadro’s hypothesis (Avogadro) Introduction to Avogadro’s number and the mole (5.3) Identify reactants and products in a chemical equation Convert a verbal description of a reaction to a balanced chemical equation Balance chemical equations UNIT 17 i. Identifying reactants and products ii. Balancing chemical equations b. Volume relationships in chemical equations (5.2) Unit # CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic Solutions – Qualitative (5.5) f. i. Definition of a solution ii. Qualitative terms related to solutions 1. Unsaturated 2. Saturated 3. Supersaturated 4. Dilute 5. Concentrated Solutions – Quantitative (5.5) i. Definition of molarity and its applications 1. Relating molarity, moles, and volume of solution 2. Relating molarity, mass, and volume of solution 3. Preparation of solutions of given molarity ii. Percent concentrations 1. Percent by volume 2. Percent by mass Define the term solution Define the qualitative terms unsaturated, saturated, and supersaturated, dilute, and concentrated Classify a given solution description according to the above terms Define the terms molarity, percent by mass, and percent by volume Determine missing information in solution problems Unit # UNIT 20 e. Learning Objectives CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic IX. Gases, Liquids, Solids, and Intermolecular Forces (Chapter 6) a. Solids, liquids, and gases (6.1) c. Identify molecular level differences between solids, liquids, and gases Define the terms associated with phase transitions – boiling point, melting point, freezing point, condensation, freezing and sublimation Describe the physical meaning of term critical point State key physical differences between ionic and molecular compounds Define the three primary types of intermolecular forces Identify situations in which each of the intermolecular forces is important Given a species identify the intermolecular forces which play a role in that species i. d. Identify the key forces that determine the solubility of a solute in a solvent UNIT 22 Dipole-dipole forces ii. Dispersion forces iii. Hydrogen bonding Forces in solution (between solute and solvent) (6.4) Unit # UNIT 21 b. i. Identification of molecular level differences ii. Identification of terminology associated with changes from one phase to another 1. Melting (freezing) 2. Boiling (condensing) 3. Sublimation (deposition or condensation) iii. Supercritical fluids Comparison of properties of ionic and molecular compounds (6.2) i. Physical state at room temperature ii. Relative melting points iii. Energy required to melt iv. Conductivity in water solution v. Brittleness Forces between molecules (intermolecular forces) (6.3) Learning Objectives CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic f. i. Atomic level particles in rapid, constant motion, and move in straight lines ii. Particles are tiny compared to volume of the container iii. Very little attraction between particles iv. Energy is conserved when particles collide v. Temperature is a measure of the average kinetic energy of gas molecules Simple gas laws (6.6) g. iv. Introduction to pressure measurement and units v. Boyle’s Law: relates pressure and volume at constant temperature and number of moles of gas vi. Charles’s Law: relates temperature and volume at constant pressure and number of moles of gas Ideal gas law (6.7) i. Combined gas law: relates pressure, volume, and temperature at constant number of moles of gas ii. Ideal gas law: relates pressure, volume, temperature, and number of moles of gas iii. Molar volume at standard temperature and pressure State the five postulates of the kinetic molecular theory of gases Describe how the kinetic molecular theory accounts for observed properties of gases State Boyle’s Law State Charles’s Law State the combined gas law Apply Boyle’s Law, Charles’s Law, and the combined gas law to gases in a variety of situations State the ideal gas law Apply the ideal gas law to gases in a variety of situations State standard temperature and pressure conditions (STP) State the molar volume of an ideal gas at STP Unit 24 Gases: The kinetic-molecular theory (6.5) Unit # Unit 23 e. Learning Objectives CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic X. Acids and Bases (Chapter 7) a. Experimental definitions of acids and bases (7.1) b. Acids, bases, and salts (7.2) Learning Objectives Identify oxides as acidic or basic Describe the difference between strong and weak acids Describe the difference between strong and weak bases Identify hydrochloric, sulfuric, and nitric acid as strong acids Complete the chemical equation for a neutralization reaction given the reactants Recognize the pH scale is logarithmic Identify pH regions which are acidic, neutral, and basic Estimate pH from hydrogen concentration and hydrogen concentration from pH Identify conjugate acid-base pairs e. i. Define the terms strong and weak acids and bases ii. Identify strong and weak acids and bases Neutralization of acids and bases (7.5) f. The pH scale (7.6) g. h. Buffers and conjugate acid-base pairs (7.7) Applications (7.8-7.10) i. Acid rain ii. Antacids iii. Use in industry iv. Use in health and disease issues c. UNIT 27 d. i. Arrhenius theory – acid is proton donor in aqueous solution, base is hydroxide donor in aqueous solution ii. Brønsted-Lowry Acid-Base Theory – acid is proton donor, base is proton acceptor iii. Salt – product of neutralization reaction between acid and base Acidic and basic anhydrides (7.3) i. Nonmetal oxides – acidic anhydrides ii. Metallic oxides – basic anhydrides Strong and weak acids and bases (7.4) UNIT 26 Give physical characteristics of acids and bases State the Arrhenius theory of acids and bases Identify acids and bases using the Arrhenius theory State the Brønsted-Lowry theory of acids and bases Identify acids and bases using the Brønsted-Lowry theory Identify salts Identify the specific acids and bases that produce a given salt UNIT 25 Unit # CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic XI. Oxidation and Reduction (Chapter 8) a. Three views of oxidation-reduction (8.1) Learning Objectives b. c. i. Oxidation – gain of oxygen atoms; reduction is the loss of oxygen atoms ii. Oxidation – loss of hydrogen atoms; reduction is the gain of hydrogen atoms iii. Oxidation – loss of electrons; reduction is the gain of electrons Oxidizing and reducing agents (8.2) i. Oxidizing agent – substance that is reduced ii. Reducing agent – substance that is oxidized Electrochemistry: cells and batteries (8.3) Identify oxidizing and reducing agents in a given chemical equation Given a redox reaction break it into two half-reactions and identify each as oxidation or reduction Given two unbalanced half-reactions, balance them and combine them into one overall reaction For a given electrochemical cell identify the anode and the cathode Identify the role of oxidation-reduction in corrosion processes Describe the function of a sacrificial anode Write balanced chemical equations for the reaction of oxygen with elements and compounds Identify ozone as an allotrope of oxygen Describe ozone’s dual role in environmental issues Describe some of the uses of chlorine as an oxidizing agent Give examples of hydrogen as a reducing agent in applications UNIT 29 d. i. Separating reactions into two half-reactions ii. Balancing half-reactions and combining into one reaction iii. Terminology: electrochemical cell, electrodes, cathode, anode iv. Descriptions of basic cells and batteries Corrosion (8.4) e. i. The rusting of iron ii. Protecting materials from corrosion Common oxidizing agents (8.7) Common reducing agents (8.8) f. UNIT 28 State the definitions of oxidation and reduction considering oxygen atoms State the definitions of oxidation and reduction considering hydrogen atoms State the definitions of oxidation and reduction considering the transfer of electrons Apply the definitions of oxidation and reduction to identify species oxidized and reduced in a given chemical equation Unit # CHEM 1004 Descriptive Chemistry (Summer 2011) Course Outline (Numbers in parentheses refer to section numbers in the course textbook, Chemistry for Changing Times, John W. Hill, Terry W. McCreary, Doris K. Kolb, Prentice Hall, 2010, ISBN 0-13-605449-8) The links on the right (Unit 1, etc.) will bring you directly to the Unit PowerPoint slides. Topic XII. Nuclear Chemistry (Chapter 11) a. Exposure to natural radioactivity (11.1) b. Writing nuclear equations (11.2) Learning Objectives d. i. Describe constancy for a specimen ii. Relate to radioisotopic dating (11.4) Artificial transmutations (11.5) e. f. Uses of radioisotopes (11.6) Penetrating power of radiation (11.7) g. Energy from the nucleus (11.8) h. i. i. E = mc2 ii. Binding energy iii. Nuclear fission iv. Conditions for chain reactions Radioactive Fallout (11.10) Nuclear power plants (11.11) j. Thermonuclear reactions (11.12) Identify the three natural sources of radiation exposure State the three most common types of radiation and their characteristics – alpha particles, beta particles, and gamma rays Complete given nuclear equations by supplying particles, mass numbers, and/or atomic numbers UNIT 30 c. i. Identification of basic subatomic particles ii. Review of writing atomic symbols with atomic numbers and mass numbers iii. Complete nuclear reactions by ensuring the sum of atomic numbers and the sum of mass numbers is the same on each side of the equation Half-life (11.3) Unit # Use half-life information to determine quantities of material remaining after specific lengths of time Given sufficient information, determine the age of a specimen Describe the reason for prolonged radioactive fallout from a release State a key difference between the technology involved in nuclear power plants compared to nuclear weapons State two key problems to be faced with nuclear power plants Distinguish between nuclear fission and nuclear fission UNIT 31 Recognize artificial transmutation as man-made process for producing new elements Identify three radioisotopes and describe their applications Rate alpha particles, beta particles, and gamma rays in terms of their penetrating power Describe key aspects that lead to the nuclear fission process Describe three key technical issues that had to be overcome to build the first nuclear weapon